CN108373678A - Volcanic rock bamboo charcoal is compound except formaldehyde environmental protection coating material and preparation method thereof - Google Patents
Volcanic rock bamboo charcoal is compound except formaldehyde environmental protection coating material and preparation method thereof Download PDFInfo
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- CN108373678A CN108373678A CN201610995614.7A CN201610995614A CN108373678A CN 108373678 A CN108373678 A CN 108373678A CN 201610995614 A CN201610995614 A CN 201610995614A CN 108373678 A CN108373678 A CN 108373678A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D125/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Coating compositions based on derivatives of such polymers
- C09D125/02—Homopolymers or copolymers of hydrocarbons
- C09D125/04—Homopolymers or copolymers of styrene
- C09D125/08—Copolymers of styrene
- C09D125/14—Copolymers of styrene with unsaturated esters
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1656—Antifouling paints; Underwater paints characterised by the film-forming substance
- C09D5/1662—Synthetic film-forming substance
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1687—Use of special additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Abstract
It is compound except formaldehyde environmental protection coating material that the present invention provides a kind of volcanic rock bamboo charcoal comprising the raw material of following parts by weight：Styrene-acrylic emulsion 50~80, quartz sand 12~16, Pigment white 8~16, powdered whiting 10~14, montmorillonite 5~10, nano-titanium colloidal sol 1~2, nanometer ca silicate fibre 0.6~1, melmac 0.6~1, nano carbon sol 0.5~1, diatomite 0.5~1, volcanic rock 2~2.5, lignin 0.3~0.6, Lysimachia foenum-graecum powder 0.1~0.2, bamboo charcoal 1~1.5, acetylbutyrylcellulose 0.4~1, antifoaming agent 0.5~1.2, polyamide wax 0.2~1, propandiol butyl ether 22~30, water 28~36.The present invention also provides a kind of compound preparation methods except formaldehyde environmental protection coating material of above-mentioned volcanic rock bamboo charcoal.The volcanic rock bamboo charcoal is compound, and except formaldehyde environmental protection coating material PARA FORMALDEHYDE PRILLS(91,95) adsorption rate is fast, Adsorption effect is good, and depollution of environment rate is high, environmentally protective.
Description
Technical field
The invention belongs to paint fields, and in particular to a kind of volcanic rock bamboo charcoal is compound to remove formaldehyde environmental protection coating material and its preparation side
Method.
Background technology
It promulgates within 2010《ISO14020 international standard matched coating technical standards》To specification and promote water paint strong
Kang Fazhan will play very positive effect.Therefore the occupation rate of market for increasing water paint is extremely urgent, by aqueous painting
Expect the strategic products be included in scientific and technical innovation, given priority to, is industry and the responsibilities and obligations of enterprise.Modern science and technology and medical technology
It has been proved that organic solvent endangers environment and human health there is great.The World Health Organization is by room air
Pollution is included in " ten big mankind's Health Killers " list, especially as the formaldehyde of organic solvent.
Formaldehyde is a kind of volatile organic compound, colourless, have special odor, slightly overweights air, soluble easily in water.Formaldehyde is to people
Body health has a major impact, and has strong impulse effect to eyes, respiratory tract, human body mucous membrane and skin；Acute poisoning can cause
It sheds tears, runny nose, the symptoms such as cough, causes various respiratory tract disease；Chronic inhalation of low concentration can lead to unrelenting headache, inability, mistake
Sleep etc.；Chronic skin contact can lead to dermatitis, and bad shadow is generated to the respiratory system, digestive system and central nervous system of human body
It rings, causes lung and liver immunologic dysfunction.Formaldehyde harm to the human body is so serious, produce can effectively degradation of formaldehyde building materials production
Product cause the attention of building trade.
Therefore, formaldehyde can be removed and environmental-friendly water soluble paint by working out, it has also become paint field is important at present
Research direction.
Invention content
In view of this, the present invention is it is necessory to provide, a kind of volcanic rock bamboo charcoal is compound to remove formaldehyde environmental protection coating material and its preparation side
Method, to solve the above problems.
It is compound except formaldehyde environmental protection coating material that the present invention provides a kind of volcanic rock bamboo charcoal comprising the raw material of following parts by weight：Benzene
Acrylic emulsion 50~80, quartz sand 12~16, Pigment white 8~16, powdered whiting 10~14, montmorillonite 5~10, nano-titanium colloidal sol
1~2, nanometer ca silicate fibre 0.6~1, melmac 0.6~1, nano carbon sol 0.5~1, diatomite 0.5~1, fire
Mountain rock 2~2.5, Lysimachia foenum-graecum powder 0.1~0.2, bamboo charcoal 1~1.5, acetylbutyrylcellulose 0.4~1, disappears at lignin 0.3~0.6
Infusion 0.5~1.2, polyamide wax 0.2~1, propandiol butyl ether 22~30, water 28~36.Wherein, in the nano carbon sol
Soluble solids is that mass percentage is 10%~15%.
Based on above-mentioned, the volcanic rock bamboo charcoal is compound except formaldehyde environmental protection coating material includes the raw material of following parts by weight：Phenylpropyl alcohol breast
Liquid 60~70, quartz sand 13~15, Pigment white 10~14, powdered whiting 11~13, montmorillonite 7~9, nano-titanium colloidal sol 1.3
~1.7, nanometer ca silicate fibre 0.7~0.9, melmac 0.7~0.9, nano carbon sol 0.7~0.9, diatomite
0.7~0.9, volcanic rock 2.2~2.4, lignin 0.4~0.5, Lysimachia foenum-graecum powder 0.1~0.2, bamboo charcoal 1.2~1.4, acetate butyrate
Cellulose 0.6~0.9, antifoaming agent 0.7~1, polyamide wax 0.5~0.8, propandiol butyl ether 24~28, water 30~34.
Based on above-mentioned, the antifoaming agent is polyethers antifoaming agent, emulsification dimethicone or dimethyl silicone polymer.
It is described except formaldehyde environmental protection coating material further includes the raw material of following parts by weight based on above-mentioned：Manganese naphthenate 0.2~0.6.
The present invention also provides a kind of compound preparation methods except formaldehyde environmental protection coating material of above-mentioned volcanic rock bamboo charcoal comprising following
Step：
Volcanic rock is impregnated in concentrated sulfuric acid be washed with deionized after 12 h to neutrality dry after be ground into fine powder, then with stone
Sand, melmac, powdered whiting, montmorillonite and nanometer ca silicate fibre are uniformly mixed, in 240 DEG C in Muffle furnace
0.5~1 h is calcined at~255 DEG C, is taken out after cooling, is obtained volcanic rock mixture；
The volcanic rock mixture and nano-titanium colloidal sol, diatomite, nano carbon sol, lignin, Lysimachia foenum-graecum powder and bamboo charcoal are mixed
It is combined, and to disperse 20~30 min under the mixing speed of 2500~3000 r/min, then adds remaining raw material,
Stir 30~40 min.Wherein, described " remaining raw material " refers in raw material in addition to volcanic rock, quartz sand, melamine
Resin, powdered whiting, montmorillonite, nanometer ca silicate fibre, nano-titanium colloidal sol, diatomite, nano carbon sol, lignin, spirit
Other raw materials except vanilla powder and bamboo charcoal.
In the compound raw material except formaldehyde environmental protection coating material of the volcanic rock bamboo charcoal provided by the invention, the nano-titanium colloidal sol
With stronger photocatalytic, bigger specific surface area, stronger chemical bonding adsorptivity, electrically charged hydroxyl, height
The advantages that surface-active, is made so it can remove formaldehyde, purification air, antibacterial and mouldproof, deodorization, extremely strong anti-pollution, automatically cleaning
With.In addition, the nano-titanium colloidal sol also has the effects that increase coating intensity, adhesion strength, wearability, so it is with relatively good
Film forming, and form a film it is smooth, improve coating scrubbing resistant performance.
Diatomite has many advantages, such as that porosity is big, absorbability is strong, chemical property is stable, wear-resisting, heat-resisting；It can also be by water
Molecule resolves into negative ions, since hydrone is wrapped, negative ions group is formed, then using hydrone as carrier, in air
In swim everywhere, possess sterilizing ability.The negative ions to swim can be to formaldehyde, the anaphylaxis substance and other are thin in environment
The harmful substances such as bacterium, mould are surrounded and are isolated, and the most active hydroxide ion of performance and formaldehyde in negative ions group
Etc. harmful substances carry out violent chemical reaction, they are completely decomposed into the harmless objects such as hydrone.
10~100 nm of carbon granules diameter in the nano carbon sol, be in spherical dispersion, have great specific surface area and
High specific surface energy, surface Selective adsorption, excellent electric conductivity；It is imitated with quantum size effect and macroscopic quantum tunnel
It answers；With excellent environmental stability, still there are the singularitys such as high-strength, high-ductility under the high temperature conditions；Hydrophily is extremely strong, in water
Dispersibility it is fabulous, store do not reunite for 3 years at normal temperatures and pressures.
There are microcellular structures for volcanic rock and bamboo charcoal, have higher porosity and high-specific surface area, PARA FORMALDEHYDE PRILLS(91,95), volatility are molten
The pernicious gases such as agent have good Physical Absorption to act on.
Therefore, compared with prior art, the present invention uses nano carbon sol, diatomite, powdered whiting, montmorillonite, receives
The cooperation nano-titanium colloidal sol such as rice ca silicate fibre, bamboo charcoal and volcanic rock, enhances the intensity, bactericidal properties, suction of TiO 2 sol
The performance of attached amount, corrosion resistance and heat resistance etc., enhances adsorption capacity and adsorption rate, has to tiny field trash good
Good adsorption effect, expands adsorption range；Arrange in pairs or groups again Lysimachia foenum-graecum powder and bamboo charcoal of diatomite and nano-titanium colloidal sol uses, can be with
It is chemically reacted with harmful substances such as formaldehyde, to achieve the purpose that remove formaldehyde；So the volcanic rock provided by the invention
Bamboo charcoal is compound, and except formaldehyde environmental protection coating material PARA FORMALDEHYDE PRILLS(91,95) adsorption rate is fast, Adsorption effect is good, and depollution of environment rate is high, environmentally protective,
The compound formaldehyde environmental protection coating material that removes of volcanic rock bamboo charcoal prepared by the present invention has good removal effect to various pollutants, especially right
The removal effect of formaldehyde is high, and preparation method is simple, and operability is strong, at low cost, is conducive to promote and apply.In addition, manganese naphthenate
Addition, can promote it is described except formaldehyde environmental protection coating material in use, coating quickly urges dry film forming.
Specific implementation mode
Below by specific implementation mode, technical scheme of the present invention will be described in further detail.
Embodiment 1
It is compound except formaldehyde environmental protection coating material that the present embodiment provides a kind of volcanic rock bamboo charcoals comprising the raw material of following parts by weight：Phenylpropyl alcohol
Lotion 50, quartz sand 16, Pigment white 8, powdered whiting 14, montmorillonite 10, nano-titanium colloidal sol 1, nanometer ca silicate fibre 0.6,
Melmac 0.6, nano carbon sol 1, diatomite 0.5, volcanic rock 2.5, lignin 0.3, Lysimachia foenum-graecum powder 0.1, bamboo charcoal
1.5, acetylbutyrylcellulose 0.4, polyethers antifoaming agent 0.5, polyamide wax 0.2, propandiol butyl ether 22, water 36.
The present embodiment also provides a kind of above-mentioned volcanic rock bamboo charcoal the compound preparation method except formaldehyde environmental protection coating material comprising with
Lower step：
Volcanic rock is impregnated in concentrated sulfuric acid be washed with deionized after 12 h to neutrality dry after be ground into fine powder, then with stone
Sand, melmac, powdered whiting, montmorillonite and nanometer ca silicate fibre are uniformly mixed, in 240 DEG C in Muffle furnace
0.5 h of lower calcining takes out after cooling, obtains volcanic rock mixture；
The volcanic rock mixture and nano-titanium colloidal sol, diatomite, nano carbon sol, lignin, Lysimachia foenum-graecum powder and bamboo charcoal are mixed
It is combined, and to disperse 30 min under the mixing speed of 2500 r/min, then adds styrene-acrylic emulsion, Pigment white, acetic acid
Cellulose butyrate, polyethers antifoaming agent, polyamide wax, propandiol butyl ether and water stir 30 min.
Embodiment 2
It is compound except formaldehyde environmental protection coating material includes the raw material of following parts by weight that the present embodiment provides a kind of volcanic rock bamboo charcoals：Styrene-acrylic emulsion
60, quartz sand 15, Pigment white 10, powdered whiting 13, montmorillonite 9, nano-titanium colloidal sol 1.3, nanometer ca silicate fibre 0.7, three
Cymel 0.7, nano carbon sol 0.9, diatomite 0.7, volcanic rock 2.4, lignin 0.4, Lysimachia foenum-graecum powder 0.1, bamboo charcoal
1.4, acetylbutyrylcellulose 0.6, emulsification dimethicone 0.7, polyamide wax 0.5, manganese naphthenate 0.2, propandiol butyl ether 24,
Water 34.
The present embodiment provides a kind of above-mentioned preparation methods except methanal paint comprising following steps：
Volcanic rock is impregnated in concentrated sulfuric acid be washed with deionized after 12 h to neutrality dry after be ground into fine powder, then with stone
Sand, melmac, powdered whiting, montmorillonite and nanometer ca silicate fibre are uniformly mixed, in 245 DEG C in Muffle furnace
0.5 h of lower calcining takes out after cooling, obtains volcanic rock mixture；
The volcanic rock mixture and nano-titanium colloidal sol, diatomite, nano carbon sol, lignin, Lysimachia foenum-graecum powder and bamboo charcoal are mixed
It is combined, and to disperse 20 min under the mixing speed of 2700 r/min, then adds styrene-acrylic emulsion, Pigment white, acetic acid
Cellulose butyrate, emulsification dimethicone, polyamide wax, manganese naphthenate, propandiol butyl ether and water, stir 30 min.
Embodiment 3
It is compound except formaldehyde environmental protection coating material includes the raw material of following parts by weight that the present embodiment provides rock bamboo charcoals on a kind of volcano：Phenylpropyl alcohol breast
Liquid 65, quartz sand 14, Pigment white 12, powdered whiting 12, montmorillonite 8, nano-titanium colloidal sol 1.5, nanometer ca silicate fibre 0.8,
Melmac 0.8, nano carbon sol 0.8, diatomite 0.8, volcanic rock 2.3, lignin 0.5, Lysimachia foenum-graecum powder 0.2, bamboo charcoal
1.3, acetylbutyrylcellulose 0.7, emulsification dimethicone 0.9, polyamide wax 0.6, manganese naphthenate 0.4, propandiol butyl ether 26,
Water 32.
The present embodiment provides a kind of above-mentioned preparation methods except methanal paint comprising following steps：
Volcanic rock is impregnated in concentrated sulfuric acid be washed with deionized after 12 h to neutrality dry after be ground into fine powder, then with stone
Sand, melmac, powdered whiting, montmorillonite and nanometer ca silicate fibre are uniformly mixed, in 250 DEG C in Muffle furnace
1 h of lower calcining takes out after cooling, obtains volcanic rock mixture；
The volcanic rock mixture and nano-titanium colloidal sol, diatomite, nano carbon sol, lignin, Lysimachia foenum-graecum powder and bamboo charcoal are mixed
It is combined, and to disperse 25 min under the mixing speed of 2800 r/min, then adds styrene-acrylic emulsion, Pigment white, acetic acid
Cellulose butyrate, emulsification dimethicone, polyamide wax, manganese naphthenate, propandiol butyl ether and water, stir 35 min.
Embodiment 4
It is compound except formaldehyde environmental protection coating material that the present embodiment provides a kind of volcanic rock bamboo charcoals comprising the raw material of following parts by weight：Phenylpropyl alcohol
Lotion 70, quartz sand 13, Pigment white 14, powdered whiting 11, montmorillonite 7, nano-titanium colloidal sol 1.7, nanometer ca silicate fibre
0.9, melmac 0.9, nano carbon sol 0.7, diatomite 0.9, volcanic rock 2.2, lignin 0.5, Lysimachia foenum-graecum powder 0.2,
Bamboo charcoal 1.2, acetylbutyrylcellulose 0.9, dimethyl silicone polymer 1, polyamide wax 0.8, manganese naphthenate 0.5, propandiol butyl ether
28, water 30.
The present embodiment provides a kind of compound preparation methods except formaldehyde environmental protection coating material of above-mentioned volcanic rock bamboo charcoal comprising following
Step：
Volcanic rock is impregnated in concentrated sulfuric acid be washed with deionized after 12 h to neutrality dry after be ground into fine powder, then with stone
Sand, melmac, powdered whiting, montmorillonite and nanometer ca silicate fibre are uniformly mixed, in 255 DEG C in Muffle furnace
0.5 h of lower calcining takes out after cooling, obtains volcanic rock mixture；
The volcanic rock mixture and nano-titanium colloidal sol, diatomite, nano carbon sol, lignin, Lysimachia foenum-graecum powder and bamboo charcoal are mixed
It is combined, and to disperse 20 min under the mixing speed of 3000 r/min, then adds styrene-acrylic emulsion, Pigment white, acetic acid
Cellulose butyrate, dimethyl silicone polymer, polyamide wax, manganese naphthenate, propandiol butyl ether and water stir 35 min.
Embodiment 5
It is compound except formaldehyde environmental protection coating material that the present embodiment provides a kind of volcanic rock bamboo charcoals comprising the raw material of following parts by weight：Phenylpropyl alcohol
Lotion 80, quartz sand 12, Pigment white 16, powdered whiting 10, montmorillonite 5, nano-titanium colloidal sol 2, nanometer ca silicate fibre 1, three
Cymel 1, nano carbon sol 0.5, diatomite 1, volcanic rock 2, lignin 0.6, Lysimachia foenum-graecum powder 0.2, bamboo charcoal 1, acetic acid fourth
Acid cellulose 1, dimethyl silicone polymer 1.2, polyamide wax 1, manganese naphthenate 0.6, propandiol butyl ether 30, water 28.
The present embodiment provides a kind of compound preparation methods except formaldehyde environmental protection coating material of above-mentioned volcanic rock bamboo charcoal comprising following
Step：
Volcanic rock is impregnated in concentrated sulfuric acid be washed with deionized after 12 h to neutrality dry after be ground into fine powder, then with stone
Sand, melmac, powdered whiting, montmorillonite and nanometer ca silicate fibre are uniformly mixed, in 255 DEG C in Muffle furnace
1 h of lower calcining takes out after cooling, obtains volcanic rock mixture；
The volcanic rock mixture and nano-titanium colloidal sol, diatomite, nano carbon sol, lignin, Lysimachia foenum-graecum powder and bamboo charcoal are mixed
It is combined, and to disperse 20 min under the mixing speed of 3000 r/min, then adds styrene-acrylic emulsion, Pigment white, acetic acid
Cellulose butyrate, dimethyl silicone polymer, polyamide wax, manganese naphthenate, propandiol butyl ether and water stir 40 min.
Performance test
To above-described embodiment 1~5 provide volcanic rock bamboo charcoal it is compound except formaldehyde environmental protection coating material according to the test event in the following table 1 into
Row performance test, test result is as follows shown in table 1：
The volcanic rock bamboo charcoal that 1 each embodiment of table provides is compound except formaldehyde environmental protection coating material performance test table
| Test event | Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 | Embodiment 5 |
| State in a reservoir | Without lump, in equal after stirring Even state | Without lump, in equal after stirring Even state | Without lump, in equal after stirring Even state | Without lump, in equal after stirring Even state | Without lump, in uniform after stirring State |
| Application property | It is accessible to brush twice | It is accessible to brush twice | It is accessible to brush twice | It is accessible to brush twice | It is accessible to brush twice |
| Appearance of film | Normally | Normally | Normally | Normally | Normally |
| Drying time | 120 min | 100 min | 95 min | 90 min | 90 min |
| PH value | 7.6 | 7.6 | 7.5 | 7.5 | 7.7 |
| Fineness≤ | 54 μm | 53 μm | 51 μm | 52 μm | 53 μm |
| Viscosity (25 DEG C ± 1 °) | 102 KU | 102 KU | 101 KU | 100 KU | 101 KU |
| Proportion | 1.36 g/cm3 | 1.35 g/cm3 | 1.33 g/cm3 | 1.34 g/cm3 | 1.35 g/cm3 |
| Gloss (60 °) | 4 | 4 | 3 | 3 | 5 |
| Contrast ratio (white/shallow Color) >= | 0.950 | 0.952 | 0.953 | 0.956 | 0.954 |
Purifying property test result
Using《JCT1074-2008 function of purifying indoor air coating material purifying properties》In test method to embodiment 1~
The 5 compound purifying properties except formaldehyde environmental protection coating material of volcanic rock bamboo charcoal provided are tested.The results are shown in Table 2 for average test：
2 purifying property average test result of table
| Project | Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 | Embodiment 5 |
| Purifying formaldehyde rate | 96.4% | 97.2% | 98.0% | 97.9% | 97.7% |
| Toluene purifying rate | 76.1% | 77.4% | 78.6% | 79.5% | 80.3% |
Finally it should be noted that：The above embodiments are merely illustrative of the technical scheme of the present invention and are not intended to be limiting thereof；Although ginseng
According to preferred embodiment, invention is explained in detail, those of ordinary skills in the art should understand that：It still can be with
It modifies to the specific implementation mode of the present invention or equivalent replacement is carried out to some technical characteristics；Without departing from skill of the present invention
The spirit of art scheme should all cover within the scope of the technical scheme claimed by the invention.
Claims (5)
1. a kind of volcanic rock bamboo charcoal is compound to remove formaldehyde environmental protection coating material, which is characterized in that it includes the raw material of following parts by weight：Phenylpropyl alcohol
Lotion 50~80, quartz sand 12~16, Pigment white 8~16, powdered whiting 10~14, montmorillonite 5~10, nano-titanium colloidal sol 1
~2, nanometer ca silicate fibre 0.6~1, melmac 0.6~1, nano carbon sol 0.5~1, diatomite 0.5~1, fire
Mountain rock 2~2.5, Lysimachia foenum-graecum powder 0.1~0.2, bamboo charcoal 1~1.5, acetylbutyrylcellulose 0.4~1, disappears at lignin 0.3~0.6
Infusion 0.5~1.2, polyamide wax 0.2~1, propandiol butyl ether 22~30, water 28~36.
2. volcanic rock bamboo charcoal according to claim 1 is compound to remove formaldehyde environmental protection coating material, which is characterized in that it includes following heavy
Measure the raw material of part：Styrene-acrylic emulsion 60~70, quartz sand 13~15, Pigment white 10~14, powdered whiting 11~13, montmorillonite 7
~9, nano-titanium colloidal sol 1.3~1.7, nanometer ca silicate fibre 0.7~0.9, melmac 0.7~0.9, nano carbon sol
0.7~0.9, diatomite 0.7~0.9, volcanic rock 2.2~2.4, lignin 0.4~0.5, Lysimachia foenum-graecum powder 0.1~0.2, bamboo charcoal
1.2~1.4, acetylbutyrylcellulose 0.6~0.9, antifoaming agent 0.7~1, polyamide wax 0.5~0.8, propandiol butyl ether 24~
28, water 30~34.
3. volcanic rock bamboo charcoal according to claim 1 or 2 is compound to remove formaldehyde environmental protection coating material, which is characterized in that it further includes
The raw material of following parts by weight：Manganese naphthenate 0.2~0.6.
4. volcanic rock bamboo charcoal according to claim 3 is compound to remove formaldehyde environmental protection coating material, which is characterized in that the antifoaming agent is
Polyethers antifoaming agent, emulsification dimethicone or dimethyl silicone polymer.
5. a kind of compound preparation method except formaldehyde environmental protection coating material of Claims 1 to 4 any one of them volcanic rock bamboo charcoal, packet
Include following steps：
Volcanic rock is impregnated in concentrated sulfuric acid be washed with deionized after 12 h to neutrality dry after be ground into fine powder, then with stone
Sand, melmac, powdered whiting, montmorillonite and nanometer ca silicate fibre are uniformly mixed, in 240 DEG C in Muffle furnace
0.5~1 h is calcined at~255 DEG C, is taken out after cooling, is obtained volcanic rock mixture；
The volcanic rock mixture and nano-titanium colloidal sol, diatomite, nano carbon sol, lignin, Lysimachia foenum-graecum powder and bamboo charcoal are mixed
It is combined, and to disperse 20~30 min under the mixing speed of 2500~3000 r/min, then adds remaining raw material,
Stir 30~40 min.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610995614.7A CN108373678A (en) | 2016-11-12 | 2016-11-12 | Volcanic rock bamboo charcoal is compound except formaldehyde environmental protection coating material and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610995614.7A CN108373678A (en) | 2016-11-12 | 2016-11-12 | Volcanic rock bamboo charcoal is compound except formaldehyde environmental protection coating material and preparation method thereof |
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|---|---|
| CN108373678A true CN108373678A (en) | 2018-08-07 |
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| CN201610995614.7A Withdrawn CN108373678A (en) | 2016-11-12 | 2016-11-12 | Volcanic rock bamboo charcoal is compound except formaldehyde environmental protection coating material and preparation method thereof |
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| CN (1) | CN108373678A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111135795A (en) * | 2020-01-21 | 2020-05-12 | 温州子久堂生物科技有限公司 | Preparation method and application of adsorption material for gardenia essential oil head fragrance extraction |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103059679A (en) * | 2013-01-30 | 2013-04-24 | 中国地质大学（武汉） | Odorless anti-formaldehyde environment-friendly internal wall latex paint and preparation method thereof |
| CN104888700A (en) * | 2015-05-21 | 2015-09-09 | 安徽凤凰滤清器股份有限公司 | Formaldehyde adsorbent and preparation method thereof |
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2016
- 2016-11-12 CN CN201610995614.7A patent/CN108373678A/en not_active Withdrawn
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103059679A (en) * | 2013-01-30 | 2013-04-24 | 中国地质大学（武汉） | Odorless anti-formaldehyde environment-friendly internal wall latex paint and preparation method thereof |
| CN104888700A (en) * | 2015-05-21 | 2015-09-09 | 安徽凤凰滤清器股份有限公司 | Formaldehyde adsorbent and preparation method thereof |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111135795A (en) * | 2020-01-21 | 2020-05-12 | 温州子久堂生物科技有限公司 | Preparation method and application of adsorption material for gardenia essential oil head fragrance extraction |
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Application publication date: 20180807 |