CN108372726B - A kind of novel carbon ribbon structure - Google Patents

A kind of novel carbon ribbon structure Download PDF

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Publication number
CN108372726B
CN108372726B CN201810193967.4A CN201810193967A CN108372726B CN 108372726 B CN108372726 B CN 108372726B CN 201810193967 A CN201810193967 A CN 201810193967A CN 108372726 B CN108372726 B CN 108372726B
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China
Prior art keywords
base band
carbon ribbon
layer
pigment
ribbon structure
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CN201810193967.4A
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CN108372726A (en
Inventor
唐国初
倪继超
孙超
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Hunan Ding Yi far Technology Development Co., Ltd.
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Hunan Ding Yi Far Technology Development Co Ltd
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B41PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41JTYPEWRITERS; SELECTIVE PRINTING MECHANISMS, i.e. MECHANISMS PRINTING OTHERWISE THAN FROM A FORME; CORRECTION OF TYPOGRAPHICAL ERRORS
    • B41J2/00Typewriters or selective printing mechanisms characterised by the printing or marking process for which they are designed
    • B41J2/315Typewriters or selective printing mechanisms characterised by the printing or marking process for which they are designed characterised by selective application of heat to a heat sensitive printing or impression-transfer material
    • B41J2/32Typewriters or selective printing mechanisms characterised by the printing or marking process for which they are designed characterised by selective application of heat to a heat sensitive printing or impression-transfer material using thermal heads
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B41PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41JTYPEWRITERS; SELECTIVE PRINTING MECHANISMS, i.e. MECHANISMS PRINTING OTHERWISE THAN FROM A FORME; CORRECTION OF TYPOGRAPHICAL ERRORS
    • B41J31/00Ink ribbons; Renovating or testing ink ribbons
    • B41J31/05Ink ribbons having coatings other than impression-material coatings
    • B41J31/06Ink ribbons having coatings other than impression-material coatings the coatings being directly on the base material, i.e. below impression transfer material; Ink ribbons having base material impregnated with material other than impression material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B41PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41JTYPEWRITERS; SELECTIVE PRINTING MECHANISMS, i.e. MECHANISMS PRINTING OTHERWISE THAN FROM A FORME; CORRECTION OF TYPOGRAPHICAL ERRORS
    • B41J31/00Ink ribbons; Renovating or testing ink ribbons
    • B41J31/05Ink ribbons having coatings other than impression-material coatings
    • B41J31/08Ink ribbons having coatings other than impression-material coatings the coatings being superimposed on impression-transfer material
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D123/00Coating compositions based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Coating compositions based on derivatives of such polymers
    • C09D123/02Coating compositions based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment
    • C09D123/04Homopolymers or copolymers of ethene
    • C09D123/08Copolymers of ethene
    • C09D123/0846Copolymers of ethene with unsaturated hydrocarbons containing other atoms than carbon or hydrogen atoms
    • C09D123/0853Vinylacetate
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D161/00Coating compositions based on condensation polymers of aldehydes or ketones; Coating compositions based on derivatives of such polymers
    • C09D161/04Condensation polymers of aldehydes or ketones with phenols only
    • C09D161/06Condensation polymers of aldehydes or ketones with phenols only of aldehydes with phenols
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D175/00Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
    • C09D175/04Polyurethanes
    • C09D175/14Polyurethanes having carbon-to-carbon unsaturated bonds
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D183/00Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers
    • C09D183/04Polysiloxanes
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/63Additives non-macromolecular organic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/65Additives macromolecular
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend

Abstract

The invention proposes a kind of novel carbon ribbon structures, it is composed of a base tape and a back coating layer and a thermal transfer layer respectively coated on both sides of the base tape, thermal transfer ink layer is made of five parts, one side surface of base band is followed successively by base band side peeling layer from inside to outside, base band side adsorption layer, coat of colo(u)r, pigment side peeling layer and pigment side adsorption layer, the present invention is compared with previously used carbon ribbon structure, adsorption layer and peeling layer have been increased separately before and after coat of colo(u)r, this carbon ribbon structure is more suitable for thermal transfer printer at present on the market, it can be transferred on hard material, improve the carbon ribbon rate of transform and yield rate, simultaneously, also print head can preferably be protected, reduce loss.

Description

A kind of novel carbon ribbon structure
Technical field
The invention belongs to transprint material technical field, especially a kind of novel carbon ribbon structure.
Background technique
Previously used carbon ribbon structure is as shown in Fig. 2, this carbon ribbon structure is 5 layers, suitable for the printing of common thermal transfer Machine is suitable for soft material.As technology innovation develops, present thermal transfer printer adapts to era development, is gradually evolved into Figure can be transferred on hard material by structure as shown in Figure 3, this printer arrangement.But use present carbon Band structure, is easy to appear that the carbon ribbon rate of transform is low, and yield rate is low, and color is unintelligible, and transfer fastness is not high, is easy fade, fade Problem, and easily damage print head.
It needs to find a kind of carbon ribbon structure at present, can solve the above problem.
Summary of the invention
In order to solve the problems such as thermal transfer printing rate of transform mentioned above is low, fastness is not high, the present invention provides one kind Novel carbon ribbon structure.
Specific technical solution is as follows:
A kind of novel carbon ribbon structure, is composed of a base tape and a back coating layer and a thermal transfer layer respectively coated on both sides of the base tape, heat Transfer printing layer is made of five parts, and one side surface of base band is followed successively by base band side peeling layer, base band side adsorption layer, pigment from inside to outside Layer, pigment side peeling layer and pigment side adsorption layer;
The base band is high-strength polyester film;
The back coating is made of the raw material of following weight percents: organic siliconresin 82~88%, organosilicon filler material 12~18%;
Base band side peeling layer is made of the raw material of following weight percents: modified acrylic polyurethane resin 94~ 96%, chlorinated paraffin wax liquor 4~6%;
Base band side adsorption layer is made of the raw material of following weight percents: EVA resin and superchlorinated polyvinyl chloride resin 76~ 83%, OP wax 15~20%, metatitanic acid lipid surfactant 1~2%;
The coat of colo(u)r is made of the raw material of following weight percents: phenolic resin 25~35%, pigment 35~40%, sliding Mountain flour 31~33%;
Pigment side peeling layer is made of the raw material of following weight percents: C14~22Saturated fatty acid and ethylene-vinegar Sour ethylene copolymer resin;
Pigment side adsorption layer is made of the raw material of following weight percents: EVA resin and superchlorinated polyvinyl chloride resin 78~ 89%, OP wax 18~25%, metatitanic acid lipid surfactant 3~8%.
Preferably, in the adsorption layer of base band side, EVA resin is 55~59%, and superchlorinated polyvinyl chloride resin is 21~24%.
Preferably, in the adsorption layer of pigment side, EVA resin is 58~63%, and superchlorinated polyvinyl chloride resin is 20~29%.
Preferably, in the peeling layer of pigment side, C14~22Saturated fatty acid and ethylene-vinyl acetate copolymer resin weight Amount percentage is 2:3~8:5.
Preferably, the high-strength polyester film is the PET film of biaxial tension.
Preferably, in back coating, organic siliconresin is diphenyl dichlorosilane or phenyl siloxane.
Preferably, in back coating, organosilicon filler material is methyl hydrogen siloxane or platinum chloric acid.
Preferably, in the peeling layer of base band side, modified acrylic polyurethane resin is urethane diacrylate, polyurethane three Acrylate, six acrylate of polyurethane tetraacrylate, five acrylate of polyurethane or polyurethane.
Preferably, metatitanic acid lipid surfactant is dodecyl benzene sulfonyl metatitanic acid rouge.
Compared with the existing technology, a kind of novel carbon ribbon structure proposed by the present invention has the advantage that
A kind of novel carbon ribbon structure proposed by the present invention is divided before and after coat of colo(u)r compared with previously used carbon ribbon structure Adsorption layer and peeling layer are not increased, and this carbon ribbon structure is more suitable for thermal transfer printer at present on the market, can transfer On hard material, the carbon ribbon rate of transform and yield rate are improved, meanwhile, print head also can be preferably protected, loss is reduced.
Detailed description of the invention
Fig. 1 is a kind of schematic diagram of novel carbon ribbon structure proposed by the present invention;
Fig. 2 is the schematic diagram of previously used carbon ribbon structure;
Fig. 3 is thermal transfer printer structural schematic diagram at present on the market.
In figure:
11 carbon ribbon driven wheel, 12 carbon ribbon driving wheel, 13 carbon ribbon support shaft, 14 thermal printing head
15 17 cutter of hot glue roller 16 thermal transfer rubber roller of heating layer, 18 Belt Transmission axis
19 stock, 21 back coating, 22 base band, 23 base band side peeling layer
24 base band side 25 coat of colo(u)r of adsorption layer, 26 pigment side peeling layer, 27 pigment side adsorption layer
31 back coating, 32 base band, 33 peeling layer, 34 coat of colo(u)r
35 adsorption layer, 10 base stock, 20 rubber tire
Specific embodiment
In order to make the object, technical scheme and advantages of the embodiment of the invention clearer, below in conjunction with the embodiment of the present invention In attached drawing, technical scheme in the embodiment of the invention is clearly and completely described, it is clear that described embodiment is A part of the embodiment of the present invention, instead of all the embodiments.Based on the embodiments of the present invention, those of ordinary skill in the art Every other embodiment obtained without making creative work, shall fall within the protection scope of the present invention.
Embodiment one
A kind of novel carbon ribbon structure, by base band 22 and the back coating 21 and thermal transfer ink layer group that are respectively coated on 22 two sides of base band At the base band 22 is the PET film of biaxial tension, and the back coating 21 is made of the raw material of following weight percents: 88% Diphenyl dichlorosilane, 18% methyl hydrogen siloxane;Thermal transfer ink layer is made of five parts, and 22 1 side surface of base band is from inside to outside It is followed successively by base band side peeling layer 23, base band side adsorption layer 24, coat of colo(u)r 25, pigment side peeling layer 26 and pigment side adsorption layer 27, Base band side peeling layer 23 is made of the raw material of following weight percents: 96% urethane diacrylate, 6% chlorination Paraffin wax liquor;Base band side adsorption layer 24 is made of the raw material of following weight percents: 83% EVA resin and Vinylidene Chloride Resin (59% EVA resin, 24% superchlorinated polyvinyl chloride resin), 20% OP wax, 2% dodecyl benzene sulfonyl metatitanic acid rouge; The coat of colo(u)r (25) is made of the raw material of following weight percents: 35% phenolic resin, 40% pigment, 33% talcum Powder;Pigment side peeling layer 26 is made of the raw material of following weight percents: weight percent is the C of 8:514~22Saturation Fatty acid and ethylene-vinyl acetate copolymer resin;Pigment side adsorption layer 27 is made of the raw material of following weight percents: 89% EVA resin and superchlorinated polyvinyl chloride resin (63% EVA resin, 26% superchlorinated polyvinyl chloride resin), 25% OP wax, 8% Dodecyl benzene sulfonyl metatitanic acid rouge.
A kind of novel carbon ribbon structure of the present invention the preparation method comprises the following steps:
S1: the methyl hydrogen siloxane of the diphenyl dichlorosilane of 88g and 18g is added in solvent, is stirred evenly, is carried on the back Coating (21) coating fluid;
S2: the one side by 21 coating fluid intaglio plate coating of back coating obtained above in biaxial tension PET film, drying;
S3: the chlorinated paraffin wax liquor of the urethane diacrylate of 96g and 6g are added in solvent, stirs evenly, obtains 23 coating fluid of base band side peeling layer;
23 coating fluid of base band side obtained above peeling layer: being coated on the another side of biaxial tension PET film by S4, dry;
S5: by the EVA resin of 59g, the superchlorinated polyvinyl chloride resin of 24g, the OP wax of 20g, the dodecyl benzene sulfonyl metatitanic acid of 2g Rouge is added in solvent, is stirred evenly, and 24 coating fluid of base band side adsorption layer is obtained;
S6: being coated on the upper surface of base band side peeling layer 23 for 24 coating fluid of base band side obtained above adsorption layer, dry;
S7: the talcum powder of the phenolic resin of 35g, the pigment of 40g, 33g is added in solvent, is stirred evenly, pigment is obtained 25 coating fluid of layer need to select the color of pigment in this step;
S8: being coated on the upper surface of base band side adsorption layer 24 for 25 coating fluid of coat of colo(u)r obtained above, dry;
S9: by the C of 16g14~22Saturated fatty acid and the ethylene-vinyl acetate copolymer resin of 10g be added in solvent, It stirs evenly, obtains 26 coating fluid of pigment side peeling layer;
S10: being coated on the upper surface of coat of colo(u)r 25 for 26 coating fluid of pigment side obtained above peeling layer, dry;
S11: by the EVA resin of 63g, the superchlorinated polyvinyl chloride resin of 26g, the OP wax of 25g, the dodecyl benzene sulfonyl metatitanic acid of 8g Rouge is added in solvent, is stirred evenly, and 27 coating fluid of pigment side adsorption layer is obtained;
S12: being coated on the upper surface of pigment side peeling layer 26 for 27 coating fluid of pigment side obtained above adsorption layer, dry, Finally obtain carbon ribbon of the present invention.
Embodiment two
A kind of novel carbon ribbon structure, by base band 22 and the back coating 21 and thermal transfer ink layer group that are respectively coated on 22 two sides of base band At the base band 22 is the PET film of biaxial tension, and the back coating 21 is made of the raw material of following weight percents: 82% Diphenyl dichlorosilane, 12% methyl hydrogen siloxane;Thermal transfer ink layer is made of five parts, and 22 1 side surface of base band is from inside to outside It is followed successively by base band side peeling layer 23, base band side adsorption layer 24, coat of colo(u)r 25, pigment side peeling layer 26 and pigment side adsorption layer 27, Base band side peeling layer 23 is made of the raw material of following weight percents: 94% urethane triacrylate, 4% chlorination Paraffin wax liquor;Base band side adsorption layer 24 is made of the raw material of following weight percents: 76% EVA resin and Vinylidene Chloride Resin (55% EVA resin, 21% superchlorinated polyvinyl chloride resin), 15% OP wax, 1% dodecyl benzene sulfonyl metatitanic acid rouge; The coat of colo(u)r 25 is made of the raw material of following weight percents: 25% phenolic resin, 35% pigment, 31% talcum Powder;Pigment side peeling layer 26 is made of the raw material of following weight percents: weight percent is the C of 2:314~22Saturation Fatty acid and ethylene-vinyl acetate copolymer resin;Pigment side adsorption layer 27 is made of the raw material of following weight percents: 78% EVA resin and superchlorinated polyvinyl chloride resin (58% EVA resin, 20% superchlorinated polyvinyl chloride resin), 18% OP wax, 3% Dodecyl benzene sulfonyl metatitanic acid rouge.
A kind of novel carbon ribbon structure of the present invention the preparation method comprises the following steps:
S1: the methyl hydrogen siloxane of the diphenyl dichlorosilane of 82g and 12g is added in solvent, is stirred evenly, is carried on the back Coating (21) coating fluid;
S2: the one side by 21 coating fluid intaglio plate coating of back coating obtained above in biaxial tension PET film, drying;
S3: the chlorinated paraffin wax liquor of the urethane triacrylate of 94g and 4g are added in solvent, stirs evenly, obtains 23 coating fluid of base band side peeling layer;
23 coating fluid of base band side obtained above peeling layer: being coated on the another side of biaxial tension PET film by S4, dry;
S5: by the EVA resin of 55g, the superchlorinated polyvinyl chloride resin of 21g, the OP wax of 15g, the dodecyl benzene sulfonyl metatitanic acid of 1g Rouge is added in solvent, is stirred evenly, and 24 coating fluid of base band side adsorption layer is obtained;
S6: being coated on the upper surface of base band side peeling layer 23 for 24 coating fluid of base band side obtained above adsorption layer, dry;
S7: the talcum powder of the phenolic resin of 25g, the pigment of 35g, 31g is added in solvent, is stirred evenly, pigment is obtained 25 coating fluid of layer need to select the color of pigment in this step;
S8: being coated on the upper surface of base band side adsorption layer 24 for 25 coating fluid of coat of colo(u)r obtained above, dry;
S9: by the C of 8g14~22Saturated fatty acid and the ethylene-vinyl acetate copolymer resin of 12g be added in solvent, stir It mixes uniformly, obtains 26 coating fluid of pigment side peeling layer;
S10: being coated on the upper surface of coat of colo(u)r 25 for 26 coating fluid of pigment side obtained above peeling layer, dry;
S11: by the EVA resin of 58g, the superchlorinated polyvinyl chloride resin of 20g, the OP wax of 18g, the dodecyl benzene sulfonyl metatitanic acid of 3g Rouge is added in solvent, is stirred evenly, and 27 coating fluid of pigment side adsorption layer is obtained;
S12: being coated on the upper surface of pigment side peeling layer 26 for 27 coating fluid of pigment side obtained above adsorption layer, dry, Finally obtain carbon ribbon of the present invention.
Increased two layers compared to carbon ribbon structure more proposed by the present invention than previous carbon ribbon structure, base band side peeling layer 23 with Peeling force between base band 22 is less than the adsorption capacity of pigment side adsorption layer 27 and thermal transfer rubber roller 16, the face of such heat transfer image The bed of material 25 can be just transferred on the surface of thermal transfer rubber roller 16, then generated heat by thermal transfer rubber roller 16 and transferred thermal printing head 14 Image to 16 surface of thermal transfer rubber roller is transferred on stock 19, and stock 19 used in this device is hard material;Base Adsorption capacity with side adsorption layer 24 and stock 19 is greater than the peeling force of pigment side peeling layer 26 and thermal transfer rubber roller 16, can just make Coat of colo(u)r 25 is transferred to the surface of stock 19.
The carbon ribbon made is fixed on above carbon ribbon driving wheel 12 and carbon ribbon driven wheel 11 by base stock 10, two carbon ribbons Support shaft 13 supports carbon ribbon, and carbon ribbon is passed through thermal printing head 14, tangent with thermal transfer rubber roller 16.In printer In operational process, carbon ribbon driving wheel 12 and the cooperation operating of carbon ribbon driven wheel 11, carbon ribbon run to the position of thermal printing head 14 When, since the peeling force between base band side peeling layer 23 and base band 22 is less than the suction of pigment side adsorption layer 27 and thermal transfer rubber roller 16 The coat of colo(u)r 25 of attached power, such heat transfer image is transferred on the surface of thermal transfer rubber roller 16, i.e. base band side adsorption layer 24, pigment Layer 25, pigment side peeling layer 26 and pigment side adsorption layer 27 are transferred on the surface of thermal transfer rubber roller 16, and then hot glue roller heats Layer 15 generates heat, and then thermal transfer rubber roller 16 is heated, thermal transfer rubber roller 16 and 20 inverted running of rubber tire, when the face of heat transfer image The bed of material 25 runs to the position tangent with rubber tire 20, i.e., when contacting with stock 19, thermal transfer is beaten in the fever of thermal transfer rubber roller 16 The image that print head 14 is transferred to 16 surface of thermal transfer rubber roller is transferred on stock 19, and stock 19 used in this device is hard Material matter.Since the adsorption capacity of base band side adsorption layer 24 and stock 19 is greater than pigment side peeling layer 26 and thermal transfer rubber roller 16 Peeling force, so coat of colo(u)r 25 can just be transferred to the surface of stock 19.Belt Transmission axis 18 controls the traveling of stock 19, when When having printed a complete picture, system controls cutter 17 and cuts off, and a complete picture just completes.
The present invention extends the service life of thermal printing head, improves the pigment in hard surface of the stock thermal transfer Layer color strong degree, color are clearly vivid.
The present invention is not excluded for solving special printing demand, changes position and the intensity of peeling layer and adsorption layer.
In conclusion a kind of novel carbon ribbon structure proposed by the present invention, compared with previously used carbon ribbon structure, in pigment Layer front and back has increased separately adsorption layer and peeling layer, and this carbon ribbon structure is more suitable for thermal transfer printer at present on the market, It can be transferred on hard material, improve the carbon ribbon rate of transform and yield rate, meanwhile, print head also can be preferably protected, is dropped Low loss.
Above embodiment is the preferred embodiment of the present invention, is not intended to limit patent protection model of the invention It encloses.Those skilled in the art belonging to any present invention, in the premise for not departing from spirit and scope disclosed in this invention Under, the transformation of the equivalent structure and equivalent steps that done to the content of invention each fall within claimed the scope of the patents it It is interior.

Claims (9)

1. a kind of novel carbon ribbon structure, which is characterized in that by base band (22) and be respectively coated on the back coatings of base band (22) two sides (21) it is made of with thermal transfer ink layer composition, thermal transfer ink layer five parts, (22) one side surface of base band is followed successively by base band side from inside to outside Peeling layer (23), base band side adsorption layer (24), coat of colo(u)r (25), pigment side peeling layer (26) and pigment side adsorption layer (27);
The base band (22) is high-strength polyester film;
The back coating (21) is made of the raw material of following weight percents: organic siliconresin 82~88%, organosilicon filler material 12~18%;
Base band side peeling layer (23) is made of the raw material of following weight percents: modified acrylic polyurethane resin 94~ 96%, chlorinated paraffin wax liquor 4~6%;
Base band side adsorption layer (24) is made of the raw material of following weight percents: EVA resin and superchlorinated polyvinyl chloride resin 76~ 83%, OP wax 15~20%, metatitanic acid lipid surfactant 1~2%;
The coat of colo(u)r (25) is made of the raw material of following weight percents: phenolic resin 25~35%, pigment 35~40%, sliding Mountain flour 31~33%;
Pigment side peeling layer (26) is made of the raw material of following weight percents: C14~22Saturated fatty acid and ethylene-vinegar Sour ethylene copolymer resin;
Pigment side adsorption layer (27) is made of the raw material of following weight percents: EVA resin and superchlorinated polyvinyl chloride resin 78~ 89%, OP wax 18~25%, metatitanic acid lipid surfactant 3~8%.
2. a kind of novel carbon ribbon structure according to claim 1, which is characterized in that in base band side adsorption layer (24), EVA tree Rouge is 55~59%, and superchlorinated polyvinyl chloride resin is 21~24%.
3. a kind of novel carbon ribbon structure according to claim 1, which is characterized in that in pigment side adsorption layer (27), EVA tree Rouge is 58~63%, and superchlorinated polyvinyl chloride resin is 20~26%.
4. a kind of novel carbon ribbon structure according to claim 1, which is characterized in that in pigment side peeling layer (26), C14~22 Saturated fatty acid and ethylene-vinyl acetate copolymer resin weight percent be 2:3~8:5.
5. a kind of novel carbon ribbon structure according to claim 1, which is characterized in that the high-strength polyester film is two-way The PET film of stretching.
6. a kind of novel carbon ribbon structure according to claim 1, which is characterized in that in back coating (21), organic siliconresin For diphenyl dichlorosilane or phenyl siloxane.
7. a kind of novel carbon ribbon structure according to claim 1 or 6, which is characterized in that in back coating (21), organosilicon is filled out Charge is methyl hydrogen siloxane or platinum chloric acid.
8. a kind of novel carbon ribbon structure according to claim 1, which is characterized in that modified in base band side peeling layer (23) Acrylated polyurethane resin is urethane diacrylate, urethane triacrylate, polyurethane tetraacrylate, polyurethane five Six acrylate of acrylate or polyurethane.
9. a kind of novel carbon ribbon structure according to claim 1,2 or 3, which is characterized in that metatitanic acid lipid surfactant For dodecyl benzene sulfonyl metatitanic acid rouge.
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