CN108371826A - A kind of distillation column equipment - Google Patents

A kind of distillation column equipment Download PDF

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Publication number
CN108371826A
CN108371826A CN201810423834.1A CN201810423834A CN108371826A CN 108371826 A CN108371826 A CN 108371826A CN 201810423834 A CN201810423834 A CN 201810423834A CN 108371826 A CN108371826 A CN 108371826A
Authority
CN
China
Prior art keywords
distillation column
column equipment
slide
equipment ontology
goods
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201810423834.1A
Other languages
Chinese (zh)
Inventor
饶雨农
饶攀
饶燕
李贤�
李抗
宋冠雄
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Jinxi Remote Leading High Tech Ltd Co
Original Assignee
Jinxi Remote Leading High Tech Ltd Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Jinxi Remote Leading High Tech Ltd Co filed Critical Jinxi Remote Leading High Tech Ltd Co
Priority to CN201810423834.1A priority Critical patent/CN108371826A/en
Publication of CN108371826A publication Critical patent/CN108371826A/en
Pending legal-status Critical Current

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D3/00Distillation or related exchange processes in which liquids are contacted with gaseous media, e.g. stripping
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D1/00Evaporating
    • B01D1/0011Heating features
    • B01D1/0017Use of electrical or wave energy
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D3/00Distillation or related exchange processes in which liquids are contacted with gaseous media, e.g. stripping
    • B01D3/001Processes specially adapted for distillation or rectification of fermented solutions
    • B01D3/002Processes specially adapted for distillation or rectification of fermented solutions by continuous methods

Abstract

The present invention relates to a kind of distillation column equipment, including distillation column equipment ontology, material slide is equipped in distillation column equipment ontology, material slide connects the top and bottom of distillation column equipment ontology, and the top open part of distillation column equipment ontology is equipped with sealing device;In the shape of a spiral, the surface of material slide is spiral helicine Flow of Goods and Materials slot to material slide, and the bottom of distillation column equipment ontology is equipped with material outlet, and one end of Flow of Goods and Materials slot connects the material inlet pipe, and the other end of Flow of Goods and Materials slot connects material outlet.The present invention has sealing effect good, device fabrication and operation expense are relatively low, it does not need agitating device, material automatically forms film along the material slide of internal spiral from top to bottom, serialization is produced, material is short by the time of heating surface, superior product quality, electric power resource is saved simultaneously, and heat utilization rate is high.

Description

A kind of distillation column equipment
Technical field
The present invention relates to a kind of edible oil, oil-fat chemical products, petrochemical industry, other kinds chemical products, plants The equipment of the distilation and separation heterogeneity of extract, specifically a kind of distillation column equipment.
Background technology
Destilling tower be the chemical industry equipment of the materials such as rare metal titanium and its alloy material manufacture have intensity is high, toughness is big, The characteristics such as high temperature resistant, corrosion-resistant, light specific gravity;Therefore be widely used with chemical industry, petrochemical industry, metallurgy, light industry, weaving, alkaline, The fields such as pharmacy, pesticide, plating, electronics.Tower type is various, and destilling tower is a kind of tower gas-liquid contact dress distilled It sets.There are plate column and two kinds of main Types of packed tower.The comparison of plate column and packed tower is a complicated problem, the factor being related to Very much, be considered as when type selecting the manufacture of material properties, operating condition, the performance of tower and tower, installation, operating and Repair etc..Distillation column distillation principle is by liquid mixture partial gasification, using the different characteristic of wherein each component volatility, in fact Now detach.Tower reactor is liquid, overhead gas.
The operation principle of destilling tower is not confined to purification alcohol.The function of destilling tower is primarily to separation mixed liquor Body, at different conditions using different liquids, such as temperature difference, volatility(Boiling point)Different principles carries out liquid separation, from And reach refining effect.
Existing destilling tower is entirely the additional thermal material of tower, many times also needs to reboiler and carries out the outer forced circulation of tower again Heating, absolutely proves that the heat utilization rate of destilling tower is not high, and the big material of yield is more, material cannot form a film well cannot be very Good evaporation, it is also necessary to which the stirring of steam stripping or other forms, which again increases energy consumptions, while affecting vacuum.
Invention content
The purpose of the present invention is to solve defects of the existing technology, provide a kind of distillation column equipment.
To achieve the goals above, the technical solution adopted by the present invention is:
A kind of distillation column equipment, including distillation column equipment ontology, distillation column equipment ontology is interior to be equipped with material slide, distillation column equipment There is sealing device at the top of ontology;The seal body of the sealing device is hollow cylindrical or barrel-shaped structure, seal body Top be equipped with top end socket, top end socket be equipped with material inlet pipe;In the shape of a spiral, material slide is spiral shell to the material slide The Flow of Goods and Materials slot of shape is revolved, the bottom of distillation column equipment ontology is equipped with material outlet.
The top of a kind of above-mentioned distillation column equipment, the distillation column equipment ontology connects vacuum tube, and vacuum tube connection is cold Condenser and vacuum pump.
A kind of above-mentioned distillation column equipment, distillation column equipment ontology is interior to be equipped with assisted heating device.The auxiliary of this destilling tower Heating device can be resistance wire(Electrically heated rod)Heating device, can also be the assisted heating device of heat medium, if It is the assisted heating device of heat medium, necessarily there is the heating system that heat medium is imported and exported.
A kind of above-mentioned distillation column equipment, the assisted heating device be placed in Flow of Goods and Materials slot along material slide or Person is welded on the lower wall of Flow of Goods and Materials slot along material slide.
A kind of above-mentioned distillation column equipment, the assisted heating device be arranged on material slide and with Flow of Goods and Materials slot Extending direction is vertical.
The main function that assisted heating device is arranged on Flow of Goods and Materials slot is:It is heated again to material, multiple auxiliary Heating device is equivalent to multiple reheating, enters the temperature of charge of destilling tower and can suitably reduce;Assisted heating device is arranged Play the role of material baffle in the bottom of Flow of Goods and Materials slot, slow down the flow velocity of material, extend the time of material evaporation, allows object Material has longer time evaporative distillation, the effect of multiple assisted heating devices more preferable;In addition, assisted heating device to material again The effect being dispersed with stirring, material pass through the heating device vertical with the extending direction of Flow of Goods and Materials slot when, from Flow of Goods and Materials slot The vertical heating device of extending direction on roll across, form wave, be equivalent to and play stirring action to material, make Flow of Goods and Materials The material of trench bottom is stirred, and multiple assisted heating devices are equivalent to repeatedly stirring and repeatedly stir.The structure is optimal Assisted heating device mode of heating.
A kind of above-mentioned distillation column equipment, the assisted heating device are the heating tube being located on material slide, heating tube One end be equipped with heat medium import, the other end be equipped with Crude product input, formed a heating system.
The top of a kind of above-mentioned distillation column equipment, the distillation column equipment ontology is equipped with filling body or column plate, vacuum tube It is connect with filling body or column plate.
Beneficial effects of the present invention are:The present invention has sealing effect good, and device fabrication and operation expense are relatively low, it Agitating device is not needed, material automatically forms film along the material slide of internal spiral from top to bottom, produces serialization, object Material is short by the time of heating surface, superior product quality, while saving electric power resource, and heat utilization rate is high, and production cost is low etc. Advantageous effect;If can be widely applied in relevant industries, will be relevant industries lifting means, lifting process technology has The guarantee of power.
Internal structure of the present invention is compact, realizes maximum disengagement area with minimum volume, I was designed can originally The manufacturing costs of several distillation equipments further decrease, be especially suitable for the manufacture processing of large-scale super-huge distillation equipment, be suitble to Large-scale production.
Description of the drawings
Fig. 1 is that 1 spiral material slide distillation column equipment center line of the embodiment of the present invention erects schematic cross-sectional view.
Fig. 2 is Fig. 1 horizontal cross-sectional schematics.
Fig. 3 is that assisted heating device of the present invention distillation column equipment center line on spiral material slide erects section view signal Figure.
Fig. 4 is the horizontal cross-sectional schematic of Fig. 3.
Fig. 5 is that assisted heating device of the present invention erects section view signal in spiral material slide lower wall distillation column equipment center line Figure.
Fig. 6 is the assisted heating device of Fig. 5 in spiral material slide lower wall schematic cross-section.
Fig. 7 is schematic cross-section when assisted heating device of the present invention is vertical with slide extension direction.
Fig. 8 is assisted heating device of the present invention and slide extension direction vertical schematic view.
Fig. 9 is that the spiral material slide distillation column equipment center line with filler erects schematic cross-sectional view.
Figure 10 is the horizontal cross-sectional schematic of Fig. 9.
In figure, material inlet pipe 1, material outlet 2, spiral material slide 3, vacuum tube 4, assisted heating device 5, heating Jie Matter import(Outlet)6, Crude product input(Import)7, filling body 8, assisted heating device when vertical with slide extension direction 9, distillation column equipment ontology 10.
Specific implementation mode
Embodiment 1
A kind of distillation column equipment, including distillation column equipment ontology 10, distillation column equipment ontology is interior to be equipped with spiral material slide 3, steams Evaporating at the top of tower ontology has sealing device;The seal body of the sealing device be hollow cylindrical or barrel-shaped structure, The top of seal body is equipped with top end socket, and top end socket is equipped with material inlet pipe 1;The material slide in the shape of a spiral, object Material slide is spiral helicine Flow of Goods and Materials slot, and the bottom of distillation column equipment ontology is equipped with material outlet 2;Distillation column equipment ontology Top connects vacuum tube 4, and vacuum tube connects condenser and vacuum pump.
As shown in Fig. 1 Fig. 2, material is had been heated to heat exchanger higher than the temperature that evaporate ingredient boiling point outside destilling tower Degree enters the spiral material slide 3 inside destilling tower from material inlet pipe 1, past dirty along internal spiral material slide, from So trickling is at film-form, and material is kicked spiral slide under action uses, and rolling is dispersed with stirring more uniformly.Material is in spiral material Low-boiling substance initially evaporates on slide face, is recycled after being retracted to the condensation of distillation equipment external condenser by vacuum tube 4, remaining High boiling substance all behind spiral material slide face, is finally pooled to bottom, by 2 Collection utilization of material outlet.
Embodiment 2
A kind of distillation column equipment, including distillation column equipment ontology 10, distillation column equipment ontology is interior to be equipped with spiral material slide 3, steams Evaporating at the top of tower ontology has sealing device;The seal body of the sealing device be hollow cylindrical or barrel-shaped structure, The top of seal body is equipped with top end socket, and top end socket is equipped with material inlet pipe 1;The material slide in the shape of a spiral, object Material slide is spiral helicine Flow of Goods and Materials slot, and the bottom of distillation column equipment ontology is equipped with material outlet 2;Distillation column equipment ontology Top connects vacuum tube 4, and vacuum tube connects condenser and vacuum pump.
Since material evaporation takes away many energy, it is therefore necessary to assist heating to material, the auxiliary heating of destilling tower Device is on spiral material slide.
As shown in Fig. 3 Fig. 4, material is had been heated to heat exchanger higher than the temperature that evaporate ingredient boiling point outside destilling tower Degree enters the spiral material slide 3 inside destilling tower from material inlet pipe 1, past dirty along internal spiral material slide 3, Naturally trickling is at film-form, and material is kicked spiral slide under action uses, and rolling is dispersed with stirring more uniformly;Due to material evaporation Many energy are taken away, it is therefore necessary to assist heating to material again, ensure material on entire spiral material slide evaporating surface Reach the temperature of evaporation.Material low-boiling substance on spiral material slide face initially evaporates, and distillation is retracted to by vacuum tube 4 It is recycled after the condensation of equipment external condenser, remaining high boiling substance all behind spiral material slide face, is finally pooled to bottom Portion, by 2 Collection utilization of material outlet.
Embodiment 3
A kind of distillation column equipment, including distillation column equipment ontology 10, distillation column equipment ontology is interior to be equipped with spiral material slide 3, steams Evaporating at the top of tower ontology has sealing device;The seal body of the sealing device be hollow cylindrical or barrel-shaped structure, The top of seal body is equipped with top end socket, and top end socket is equipped with material inlet pipe 1;The material slide in the shape of a spiral, object Material slide is spiral helicine Flow of Goods and Materials slot, and the bottom of distillation column equipment ontology is equipped with material outlet 2;Distillation column equipment ontology Top connects vacuum tube 4, and vacuum tube connects condenser and vacuum pump.
Since material evaporation takes away many energy, it is therefore necessary to assist heating to material again, the auxiliary of destilling tower adds Thermal is welded below spiral material slide.
As shown in Fig. 5 Fig. 6, material is had been heated to heat exchanger higher than the temperature that evaporate ingredient boiling point outside destilling tower Degree enters the spiral material slide 3 inside destilling tower from material inlet pipe 1, past dirty along internal spiral material slide 3, Naturally trickling is at film-form, and material is kicked spiral slide under action uses, and rolling is dispersed with stirring more uniformly;Due to material evaporation Many energy are taken away, it is therefore necessary to assist heating to material again, ensure material on entire spiral material slide evaporating surface Reach the temperature of evaporation.Material low-boiling substance on spiral material slide face initially evaporates, and distillation is retracted to by vacuum tube 4 It is recycled after the condensation of equipment external condenser, remaining high boiling substance all behind spiral material slide face, is finally pooled to bottom Portion, by 2 Collection utilization of material outlet.
Embodiment 4
A kind of distillation column equipment, including distillation column equipment ontology 10, distillation column equipment ontology is interior to be equipped with spiral material slide 3, steams Evaporating at the top of tower ontology has sealing device;The seal body of the sealing device be hollow cylindrical or barrel-shaped structure, The top of seal body is equipped with top end socket, and top end socket is equipped with material inlet pipe 1;The material slide in the shape of a spiral, object Material slide is spiral helicine Flow of Goods and Materials slot, and the bottom of distillation column equipment ontology is equipped with material outlet 2;Distillation column equipment ontology Top connects vacuum tube 4, and vacuum tube connects condenser and vacuum pump.
Since material evaporation takes away many energy, it is therefore necessary to assist heating to material, the auxiliary heating of destilling tower Device is on spiral material slide, and assisted heating device is vertical with slide extension direction.
As shown in Fig. 7 Fig. 8, material is had been heated to heat exchanger higher than the temperature that evaporate ingredient boiling point outside destilling tower Degree enters the spiral material slide 3 inside destilling tower from material inlet pipe 1, past dirty along internal spiral material slide 3, Naturally trickling is at film-form, and material is kicked spiral slide under action uses, and rolling is dispersed with stirring more uniformly;Due to material evaporation Many energy are taken away, it is therefore necessary to assist heating to material again, ensure material on entire spiral material slide evaporating surface Reach the temperature of evaporation.
Material is buffered on spiral material slide face by multiple assisted heating devices vertical with slide extension direction Blocking, is heated, multiple assisted heating devices are equivalent to multiple reheating, enter the material temperature of destilling tower so again to material Degree can be reduced suitably;Assisted heating device is arranged plays the role of material baffle in the bottom of Flow of Goods and Materials slot, slows down object The flow velocity of material extends the time of material evaporation, and material is allowed to have longer time evaporative distillation, the effect of multiple assisted heating devices More preferably.
In addition, this assisted heating device is again stirring for the effect of dispersion to material, material passes through and Flow of Goods and Materials slot The vertical heating device of extending direction, rolls across from the heating device vertical with the extending direction of Flow of Goods and Materials slot, forms wave, It is equivalent to and plays stirring action to material, the material of Flow of Goods and Materials trench bottom is made to be stirred, multiple assisted heating device phases It is repeatedly stirred when in multiple stirring.The structure is optimal assisted heating device mode of heating.
Low-boiling substance initially evaporates in material, is recycled after being retracted to the condensation of distillation equipment external condenser by vacuum tube 4, Remaining high boiling substance all behind spiral material slide face, is finally pooled to bottom, and profit is collected by material outlet 2 With.
Embodiment 5
A kind of distillation column equipment, including distillation column equipment ontology 10, distillation column equipment ontology is interior to be equipped with spiral material slide 3, steams Evaporating at the top of tower ontology has sealing device;The seal body of the sealing device be hollow cylindrical or barrel-shaped structure, The top of seal body is equipped with top end socket, and top end socket is equipped with material inlet pipe 1;The material slide in the shape of a spiral, object Material slide is spiral helicine Flow of Goods and Materials slot, and the bottom of distillation column equipment ontology is equipped with material outlet 2;Distillation column equipment ontology Top connects vacuum tube 4, and vacuum tube connects condenser and vacuum pump.
It is also welded in the upper surface of destilling tower(Connection)There is filling body(Or board-like body)8.
As shown in Fig. 9 Figure 10, material has been heated to be higher than outside destilling tower with heat exchanger will evaporate ingredient boiling point Temperature enters the spiral material slide 3 inside destilling tower, down along internal spiral material slide 3 from material inlet pipe 1 Stream, trickling is at film-form naturally, and material is kicked spiral slide under action uses, and rolling is dispersed with stirring more uniform;Due to material Many energy are taken away in evaporation, it is therefore necessary to assist heating to material, ensure material in entire spiral material slide evaporating surface On reach the temperature of evaporation.Material low-boiling substance on spiral material slide face initially evaporates, vaporized low boilers The steam of material encounters filler, is influenced by filler resistance and temperature, and the purity for reaching the higher substance of height of filler is also higher, This production content that suits the requirements(Purity)Needs and the requirement for reaching 98%, 99% or even 99.5%, 99.9% enterprise, by vacuum Pipe 4 be retracted to distillation equipment external condenser condensation after recycle, remaining high boiling substance all behind spiral material slide face, It is finally pooled to bottom, by 2 Collection utilization of material outlet.
The present invention has sealing effect good, and device fabrication and operation expense are relatively low, it does not need agitating device, material Film is automatically formed along the material slide of internal spiral from top to bottom, produces serialization, the time that material passes through heating surface It is short, superior product quality, while saving electric power resource, the advantageous effects such as heat utilization rate is high, and production cost is low;If can be It is widely applied in relevant industries, will be relevant industries lifting means, lifting process technology sound assurance.
Internal structure of the present invention is compact, realizes maximum disengagement area with minimum volume, I was designed can originally The manufacturing costs of several distillation equipments further decrease, be especially suitable for the manufacture processing of large-scale super-huge distillation equipment, be suitble to Large-scale production.
Because distillation equipment manufacturing process of the present invention is more simple, manufacturing cost is cheap relative to existing distillation equipment, In order to protect distillation equipment of the present invention, require to use distillation equipment of the present invention and use in the production process of any product hereby Present inventive concept belongs to equivalent replacement, all within the protection domain of patent of the present invention.
Apparatus of the present invention are not limited by examples detailed above, and other any examples applied using the present apparatus belong to equivalent Replacement, all within the protection domain of patent of the present invention.

Claims (8)

1. a kind of distillation column equipment, including distillation column equipment ontology, which is characterized in that be equipped with material in distillation column equipment ontology and slide The top of ladder, distillation column equipment ontology is equipped with sealing device;The seal body of the sealing device is hollow cylindrical or drum The top of shape structure, seal body is equipped with top end socket, and top end socket is equipped with material inlet pipe;The material slide is helically Shape, material slide are spiral helicine Flow of Goods and Materials slot, and the bottom of distillation column equipment ontology is equipped with material outlet.
2. a kind of distillation column equipment according to claim 1, which is characterized in that connect at the top of the distillation column equipment ontology Vacuum tube is connect, vacuum tube connects condenser and vacuum pump.
3. a kind of distillation column equipment according to claim 1, which is characterized in that be equipped with auxiliary in distillation column equipment ontology and add Thermal.
4. a kind of distillation column equipment according to claim 3, which is characterized in that the assisted heating device is slided along material Ladder is placed in Flow of Goods and Materials slot or is welded on along material slide the lower wall of Flow of Goods and Materials slot.
5. a kind of distillation column equipment according to claim 3, which is characterized in that the assisted heating device is arranged in material It is on slide and vertical with the extending direction of Flow of Goods and Materials slot.
6. a kind of distillation column equipment according to claim 4 or 5, which is characterized in that the assisted heating device is to be located at One end of heating tube on material slide, heating tube is equipped with heat medium import, and the other end is equipped with Crude product input, forms one A heating system.
7. a kind of distillation column equipment according to claim 4 or 5, which is characterized in that the assisted heating device is setting Heating wire on material slide or electrically heated rod.
8. a kind of distillation column equipment according to claim 1 or 3, which is characterized in that the top of the distillation column equipment ontology Portion is equipped with the top connection vacuum tube of filling body or column plate, filling body or column plate.
CN201810423834.1A 2018-05-07 2018-05-07 A kind of distillation column equipment Pending CN108371826A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201810423834.1A CN108371826A (en) 2018-05-07 2018-05-07 A kind of distillation column equipment

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Application Number Priority Date Filing Date Title
CN201810423834.1A CN108371826A (en) 2018-05-07 2018-05-07 A kind of distillation column equipment

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Publication Number Publication Date
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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109569003A (en) * 2018-12-31 2019-04-05 江西石华精细化工科技协同创新有限公司 A kind of method of purification of trimethyl aluminium crude product
CN111202997A (en) * 2020-01-21 2020-05-29 苏州科舵工程技术有限公司 Large-scale film evaporation equipment
CN114653089A (en) * 2022-03-03 2022-06-24 四川绿艺华福石化科技有限公司 Spiral liquid-falling tower plate and distillation tower

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Publication number Priority date Publication date Assignee Title
CN2512482Y (en) * 2001-12-03 2002-09-25 大连理工大学 Gas carried evaporator concentrated from acrylic amide solution
CN203174068U (en) * 2013-04-01 2013-09-04 成都恒润高新科技有限公司 Biodiesel rectification system and distillation tower thereof
CN204637598U (en) * 2014-11-11 2015-09-16 东台绿丰生物科技有限公司 Plant extract material concentrator
CN106039752A (en) * 2016-06-30 2016-10-26 浙江大学 Rectification tower plate for improving heat transferring and mass transferring performance and rectification tower
CN205948404U (en) * 2016-08-29 2017-02-15 广州市义和化工有限公司 A distillation plant for stearic acid production
CN106390511A (en) * 2016-10-20 2017-02-15 北京玫瑰谷香露有限公司 Low-temperature vacuum distillation extraction equipment for preparation of high-purity essential oil
CN208927616U (en) * 2018-05-07 2019-06-04 金溪遥遥领先高科有限公司 A kind of distillation column equipment

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN2512482Y (en) * 2001-12-03 2002-09-25 大连理工大学 Gas carried evaporator concentrated from acrylic amide solution
CN203174068U (en) * 2013-04-01 2013-09-04 成都恒润高新科技有限公司 Biodiesel rectification system and distillation tower thereof
CN204637598U (en) * 2014-11-11 2015-09-16 东台绿丰生物科技有限公司 Plant extract material concentrator
CN106039752A (en) * 2016-06-30 2016-10-26 浙江大学 Rectification tower plate for improving heat transferring and mass transferring performance and rectification tower
CN205948404U (en) * 2016-08-29 2017-02-15 广州市义和化工有限公司 A distillation plant for stearic acid production
CN106390511A (en) * 2016-10-20 2017-02-15 北京玫瑰谷香露有限公司 Low-temperature vacuum distillation extraction equipment for preparation of high-purity essential oil
CN208927616U (en) * 2018-05-07 2019-06-04 金溪遥遥领先高科有限公司 A kind of distillation column equipment

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109569003A (en) * 2018-12-31 2019-04-05 江西石华精细化工科技协同创新有限公司 A kind of method of purification of trimethyl aluminium crude product
CN111202997A (en) * 2020-01-21 2020-05-29 苏州科舵工程技术有限公司 Large-scale film evaporation equipment
CN114653089A (en) * 2022-03-03 2022-06-24 四川绿艺华福石化科技有限公司 Spiral liquid-falling tower plate and distillation tower

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