CN108366919A - Aerosol type hair dyeing is used or hair decoloration applies some make up - Google Patents
Aerosol type hair dyeing is used or hair decoloration applies some make up Download PDFInfo
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- CN108366919A CN108366919A CN201680074395.7A CN201680074395A CN108366919A CN 108366919 A CN108366919 A CN 108366919A CN 201680074395 A CN201680074395 A CN 201680074395A CN 108366919 A CN108366919 A CN 108366919A
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- SXQCTESRRZBPHJ-UHFFFAOYSA-M lissamine rhodamine Chemical compound [Na+].C=12C=CC(=[N+](CC)CC)C=C2OC2=CC(N(CC)CC)=CC=C2C=1C1=CC=C(S([O-])(=O)=O)C=C1S([O-])(=O)=O SXQCTESRRZBPHJ-UHFFFAOYSA-M 0.000 description 1
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- 235000008390 olive oil Nutrition 0.000 description 1
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- 230000001590 oxidative effect Effects 0.000 description 1
- ATGUVEKSASEFFO-UHFFFAOYSA-N p-aminodiphenylamine Chemical compound C1=CC(N)=CC=C1NC1=CC=CC=C1 ATGUVEKSASEFFO-UHFFFAOYSA-N 0.000 description 1
- WVDDGKGOMKODPV-ZQBYOMGUSA-N phenyl(114C)methanol Chemical compound O[14CH2]C1=CC=CC=C1 WVDDGKGOMKODPV-ZQBYOMGUSA-N 0.000 description 1
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- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 229910000027 potassium carbonate Inorganic materials 0.000 description 1
- 229910001414 potassium ion Inorganic materials 0.000 description 1
- 239000002243 precursor Substances 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 230000002335 preservative effect Effects 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- VHNQIURBCCNWDN-UHFFFAOYSA-N pyridine-2,6-diamine Chemical class NC1=CC=CC(N)=N1 VHNQIURBCCNWDN-UHFFFAOYSA-N 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 238000000518 rheometry Methods 0.000 description 1
- WBHHMMIMDMUBKC-XLNAKTSKSA-N ricinelaidic acid Chemical compound CCCCCC[C@@H](O)C\C=C\CCCCCCCC(O)=O WBHHMMIMDMUBKC-XLNAKTSKSA-N 0.000 description 1
- 229960003656 ricinoleic acid Drugs 0.000 description 1
- FEUQNCSVHBHROZ-UHFFFAOYSA-N ricinoleic acid Natural products CCCCCCC(O[Si](C)(C)C)CC=CCCCCCCCC(=O)OC FEUQNCSVHBHROZ-UHFFFAOYSA-N 0.000 description 1
- 238000007665 sagging Methods 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 229910000077 silane Inorganic materials 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 229910001415 sodium ion Inorganic materials 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000000600 sorbitol Substances 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 229940012831 stearyl alcohol Drugs 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000005720 sucrose Substances 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- 229940117986 sulfobetaine Drugs 0.000 description 1
- 239000002600 sunflower oil Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- KUCOHFSKRZZVRO-UHFFFAOYSA-N terephthalaldehyde Chemical compound O=CC1=CC=C(C=O)C=C1 KUCOHFSKRZZVRO-UHFFFAOYSA-N 0.000 description 1
- 239000005028 tinplate Substances 0.000 description 1
- DVKJHBMWWAPEIU-UHFFFAOYSA-N toluene 2,4-diisocyanate Chemical compound CC1=CC=C(N=C=O)C=C1N=C=O DVKJHBMWWAPEIU-UHFFFAOYSA-N 0.000 description 1
- AISMNBXOJRHCIA-UHFFFAOYSA-N trimethylazanium;bromide Chemical compound Br.CN(C)C AISMNBXOJRHCIA-UHFFFAOYSA-N 0.000 description 1
- XFNJVJPLKCPIBV-UHFFFAOYSA-N trimethylenediamine Natural products NCCCN XFNJVJPLKCPIBV-UHFFFAOYSA-N 0.000 description 1
- UJMBCXLDXJUMFB-UHFFFAOYSA-K trisodium;5-oxo-1-(4-sulfonatophenyl)-4-[(4-sulfonatophenyl)diazenyl]-4h-pyrazole-3-carboxylate Chemical compound [Na+].[Na+].[Na+].[O-]C(=O)C1=NN(C=2C=CC(=CC=2)S([O-])(=O)=O)C(=O)C1N=NC1=CC=C(S([O-])(=O)=O)C=C1 UJMBCXLDXJUMFB-UHFFFAOYSA-K 0.000 description 1
- 239000006097 ultraviolet radiation absorber Substances 0.000 description 1
- 235000021122 unsaturated fatty acids Nutrition 0.000 description 1
- 239000011782 vitamin Substances 0.000 description 1
- 229940088594 vitamin Drugs 0.000 description 1
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- 235000013343 vitamin Nutrition 0.000 description 1
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Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/22—Peroxides; Oxygen; Ozone
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/08—Preparations for bleaching the hair
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/10—Preparations for permanently dyeing the hair
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Emergency Medicine (AREA)
- Cosmetics (AREA)
Abstract
The aerosol type hair dyeing of the present invention is used or hair decoloration applies some make up and has following outer container, the outer container stores the first content and second inner container, filled with first dose containing alkaline agent in the first content, filled with second dose containing hydrogen peroxide in second inner container, and, the propellant of 0.2~0.8MPa of internal pressure is filled in space between outer container and each inner pressurd vessel, the flexural rigidity E (f) and E (s) for forming the sheet material of first and second inner pressurd vessel are 0.15~3.0gfcm2/ cm or less, ratio E (f)/E (s) of E (f) and E (s) is 0.3 or more and 5 or less, first dose of viscosity V (f) is 10,000~145,000mPas, second dose of viscosity V (s) is 8,000~100,000mPas, V (f)/V (s) is 1.5~5, and the ratio between mass M (f) in mass M (s) and the first content in second inner container M (s)/M (f) is 1.2~3.
Description
Technical field
It is used the present invention relates to a kind of hair dyeing of aerosol type or hair decoloration applies some make up.
Background technology
Dual structure container as described below (hereinafter referred to as " separation filling-while spray of pressurizeing are proposed in the prior art
Go out the dual structure container of type "), have and first dose of hair cosmetic composition and second dose are separated into filling, and utilizes same
The structure that a pressurization ejection system sprays simultaneously.Such as such separation is disclosed in patent document 1 and patent document 2 and is filled out
Fill-while squirt-type of pressurizeing dual structure container.
The dual structure container of these separation fillings-while squirt-type of pressurizeing is usually while spraying same amount of be filled in
First dose in pocket with second dose of design, it is also with mass ratio 1 to be filled in first dose therein with second dose：1 equivalent
Ground carries out mixing after spraying and is applied to hair.About this point, discloses in patent document 3 and carried by adjusting rheological behavior
High first dose with the content of second dose of equivalent ejection.
(patent document 1) Japanese Patent Laid-Open 2012-229318 bulletins
(patent document 2) Japanese Patent Laid-Open 2013-043659 bulletins
(patent document 3) Japanese Patent Laid-Open 2015-010087 bulletins
Invention content
A kind of aerosol type hair dyeing of present invention offer is used or hair decoloration applies some make up, and has following outer container, this is outer
Container stores the first content and second inner container, and first dose containing alkaline agent, second inner container are filled in the first content
In filled with second dose containing hydrogen peroxide, and
In space between the outer container and each inner pressurd vessel, to press to 0.2MPa or more and 0.8MPa at 30 DEG C
Mode below is filled with propellant,
The first content and second inner container are to be bonded innermost layer to have the multilayered structure of polyolefin resin layer respectively
Sheet material and formed, the flexural rigidity E of the flexural rigidity E (f) of the sheet material of the first content and the sheet material of the second inner container
(s) it is respectively 0.15gfcm2/ cm or more and 3.0gfcm2/ cm is hereinafter, ratio E (f)/E (s) of E (f) and E (s) is 0.3
Above and 5 hereinafter,
This first dose viscosity V (f) at 30 DEG C is 10,000mPas or more and 145,000mPas hereinafter, this
Two doses of viscosity V (s) at 30 DEG C are 8,000mPas or more and 100,000mPas are hereinafter, the ratio between V (f) and V (s) V
(f)/V (s) be 1.5 or more and 5 hereinafter,
The ratio between first dose of mass M (f) in second dose of mass M (s) and the first content in second inner container M
(s)/M (f) is 1.2 or more and 3 or less.
Specific implementation mode
In order to improve hair dyeing effect or decolorizing effect, most direct technological means is to improve decolorizing ability, wherein effective side
Method is the concentration of hydrogen peroxide improved in second dose.However, about separation filling-while the dual structure container for squirt-type of pressurizeing
Hair dye or decolorising agent for, if only improve concentration of hydrogen peroxide, then the fluid tightness of inner pressurd vessel can be deteriorated, at any time
Between by that can have the risk of liquid leakage.Therefore, the present inventor thinks, if improving second dose relative to first dose
Spray volume ratio, then can increase the amount of hydrogen peroxide when use, so as to improve decolorizing ability, so, carry out
Further investigation.However, since the dual structure container of separation filling-while squirt-type of pressurizeing is using by identical propellant
Ejection pressure and spray the structure of first dose and second dose simultaneously, so, especially first dose and second dose in hair cosmetic composition
In the case of for relatively highly viscous creams shape preparation, if first dose and second dose of respective rheology spy cannot be suitably adjusted
Property (ejection caused by flowing when by pressurizeing), then be actually unable to control the ratio of first dose and second dose of spray volume
Example.When the ratio of set spray volume is damaged to more than certain degree, due to cannot achieve first dose and second dose of filling
The commodity value of the setting of hair cosmetic composition to made of in dual structure container, so the ratio of spray volume need to be made to stablize.
Further, when hair cosmetic composition is, for example, the oxide hair dye or hair decolorising agent of double-formulation, in first dose
It is at least combined with alkaline agent (and oxidation dye), oxidant is combined in second dose.Due to being limited by this composition,
It, can be due to first dose and second dose if cannot first dose and second dose be sprayed with the ratio of specific spray volume from beginning to end
Mixing ratio variation and tone can be made to change, to can not ensure commodity value.In addition, the ratio of the spray volume is necessary
Pass through at any time and steadily realize, other than first dose with second dose of rheological behavior, which kind of composition of progress also confirmed
Design, Vessel Design etc. could realize these effects, understand these and are very difficult.
Therefore, it is used the present invention relates to a kind of hair dyeing of aerosol type or hair decoloration applies some make up, detaching filling-simultaneously
In the dual structure container for squirt-type of pressurizeing, second dose of ratio relative to first dose of spray volume is being set as high value
In the case of, the ratio of its spray volume can be maintained from beginning to end, and passes through the ratio for also maintaining its spray volume at any time.
The present inventor studies through making great efforts, as a result, it has been found that：Using separation filling-while squirt-type of pressurizeing is dual
Hair dyeing use or the hair decoloration of structural container apply some make up, by by the flexural rigidity of the pressure of propellant, inner bag material and
Material and first dose and second dose of ratio of viscosities adjust separately as specific range, can be opposite by second dose from beginning to end
It is set as high value in the ratio of first dose of spray volume, and passes through the ratio for also maintaining the higher spray volume at any time.
In the present specification, so-called to refer to " in first dose and the content in second dose of mixture ", accurately to set
The ratio of fixed spray volume spray first dose with second dose in the case of mixture in content.
[outer container]
The aerosol type hair dyeing of the present invention is used or hair decoloration applies some make up and has following outer container, outer container storage the
One inner pressurd vessel and second inner container, filled with first dose containing alkaline agent in the first content, filled with containing in second inner container
There is second dose of hydrogen peroxide.
The outer container can use the synthesis trees such as metals or polyethylene terephthalate, polyarylate such as aluminium, tin plate
Fat.
Especially, in the case where using synthetic resin as outer container, it is however preferred to have the synthetic resin material of translucency
Material.About the outer container of this synthetic resin, it can be formed and obtain in the following way, that is, for by being extruded into
The semi-finished product of bottomed tube obtained from shape are implemented to internally while axially stretching to be blown into pair that air makes it expand
Axis draw blow molding.Alternatively, it is also possible to be formed by direct blow molding, that is, so that the semi-finished product of tubular is expanded, cut
It cuts off portion and bond and form bottom.In addition, about outer container, carbon, aluminium oxide, silica etc. can also be made to become gas
Body shape, to which evaporation film be arranged in inner surface and/or outer surface.
[inner pressurd vessel]
Inner pressurd vessel in the present invention is to be bonded the sheet material of multilayered structure of the innermost layer with vistanex and formed.Make
For the inner pressurd vessel, can enumerate：Two sheets are overlapped, bag made of being bonded edge part by thermal welding or ultrasonic welding etc.
(pouch).As the vistanex of innermost layer, polyvinyl resin (PE), acrylic resin (PP) etc. can be enumerated.From easy shape
At the viewpoint of inner bag, reduce the viewpoint of first dose and second dose of surplus in each inner pressurd vessel for, preferably polyethylene tree
Fat.
The flexural rigidity E of the flexural rigidity E (f) of the sheet material of the first content in the present invention and the sheet material of second inner container
(s) it is 0.15gfcm2/ cm or more and 3.0gfcm2/ cm is hereinafter, from the ejection for maintaining first dose and second dose from beginning to end
The viewpoint of the ratio of amount, the viewpoint for reducing by first dose and second dose of surplus in each inner pressurd vessel, when will accommodate content
The Deformation control of inner pressurd vessel is for the viewpoint in the range of appropriateness, preferably 0.2gfcm2/ cm or more, more preferably
0.4gf·cm2/ cm or more, further preferably 0.5gfcm2/ cm or more, further preferably 0.6gfcm2/ cm or more,
In addition, for being operated from the ejection with content and inner pressurd vessel being made to follow the viewpoint deformed, preferably 2.5gfcm2/ cm with
Under, more preferably 2.3gfcm2/ cm is hereinafter, further preferably 2.1gfcm2/ cm is hereinafter, further preferably 2.0gf
cm2/ cm or less.
In addition, ratio E (f)/E (s) about E (f) and E (s), from the ejection for maintaining first dose and second dose from beginning to end
The viewpoint of the ratio of amount reduces first dose and the viewpoint of second dose of surplus in each inner pressurd vessel, initial stage spray excellent sight
Point for, preferably 0.4 or more, more preferably 0.5 or more, in addition, from reduce first dose with second dose in each inner pressurd vessel
For the viewpoint of surplus, preferably 4 hereinafter, more preferably 3.3 hereinafter, further preferably 3 hereinafter, further preferably
2.5 hereinafter, further preferably 2.2 hereinafter, further preferably 2 or less.
About the flexural rigidity of sheet material, KES (Kawabata Evaluation System, river end evaluation system can be used
System) Apparatus for Bending at low-temp etc. (for example, multi-functional pure bending test machine KES-FB2-S (manufacture of Kato Tech companies)) surveyed
It is fixed.
The sheet material about the innermost layer for constituting the first content with the multilayered structure of polyolefin resin layer, from taking into account sheet material
Appropriateness flexural rigidity and low damage viewpoint for, preferably there is outermost layer and middle layer.
As outermost layer, polyester such as the polyamide such as nylon (NY), polyethylene terephthalate (PET) etc. can be enumerated.Make
For middle layer, it is preferable to use metal foil can enumerate the light metals such as aluminium foil (Al foils) as the metal foil.
The combination of the outermost layer, middle layer, innermost layer of sheet material as the first content, can suitably select according to content
It selects, for example, according to the sequence of outermost layer/middle layer/innermost layer, can enumerate：PE/Al foils/PE, PP/Al foil/PE, PET/Al foil/
PE, NY/Al foil/PE etc..In addition, the sheet material of the first content can also be that outermost double-layer structure is omitted, can also be
It is further provided with four layers or more of structure of middle layer.
The sheet material about the innermost layer for constituting second inner container with the multilayered structure of polyolefin resin layer, from taking into account sheet material
Appropriateness flexural rigidity and low damage viewpoint for, preferably there is outermost layer and middle layer.
As outermost layer, in the same manner as the sheet material of the first content, the polyamide such as nylon (NY), poly- terephthaldehyde can be enumerated
Polyester such as sour second diester (PET) etc..As middle layer, the polyamides such as ethylene-vinyl alcohol copolymer (EVOH), nylon (NY) can be enumerated
Amine etc. has the synthetic resin layer of barrier properties for gases and chemical resistance or silica is deposited in outermost layer or innermost layer
(SiOX) non-metallic layer of vapor deposition layer etc. such as.
The combination of the outermost layer, middle layer, innermost layer of sheet material as second inner container, can suitably select according to content
It selects, for example, according to the sequence of outermost layer/middle layer/innermost layer, can enumerate：PE/EVOH/PE、PP/EVOH/PE、PET/EVOH/
PE、PE/NY/PE、PP/NY/PE、PET/NY/PE、PE/SiOX/PE、PP/SiOX/PE、PET/SiOX/PE、PE/Al2O3/PE
Deng.For taking into account viewpoint of the easiness to be formed with low damage, more preferably synthetic resin layer is used in middle layer.Separately
Outside, the sheet material of second inner container can also be that outermost double-layer structure is omitted, and can also be and is further arbitrarily provided with
Four layers or more of structure of synthetic resin layer or nonmetallic gas-barrier layer.In addition, the case where outer container is set as translucency
Under, second inner container is also preferably set as translucency.
[internal pressure]
Into the space between outer container and each inner pressurd vessel, with press to 0.2MPa or more at 30 DEG C and 0.8MPa with
Under mode fill propellant.About the internal pressure, the viewpoint for the spray volume that collateral security is easily processed maintains first dose from beginning to end
With the viewpoint of the ratio of second dose of spray volume, reduce first dose and second dose of surplus in each inner pressurd vessel viewpoint and
Speech, preferably 0.3MPa or more, more preferably 0.4MPa or more, further preferably 0.5MPa or more, in addition, from from beginning to end
Maintain first dose with the viewpoint of the risk of rupture of the outer container under the viewpoint of the ratio of second dose of spray volume, inhibition high temperature and
Speech, preferably 0.75MPa is hereinafter, more preferably 0.7MPa or less.
In addition, internal pressure when about 30 DEG C, it is, for example, possible to use Bourdon tube pressure gauge, strain gage pressure gauge, flat
Neat diaphragm (flush diaphragm) U-tube manometer etc. (specifically, instrument recorded in embodiment) is measured.
As the propellant filled, can enumerate：The compressed gas such as nitrogen, compressed air, carbon dioxide, nitrous oxide
Body, liquid gas such as liquefied petroleum gas, HF hydrocarbon etc..
[viscosity]
About viscosity V (f) of first dose in the first content at 30 DEG C, from being prevented under preparation when being applied on hair
Vertical viewpoint, for the ratio of the spray volume with second dose is set as the viewpoint of particular range, preferably 15,000mPas with
On, more preferably 30,000mPas or more, in addition, from be easy to make viewpoint that preparation extends when being applied to hair, will be with the
The ratio of two doses of spray volume be set as the viewpoint of particular range, the viewpoint for reducing by first dose of surplus in inner pressurd vessel, make with
For second dose of the good viewpoint of Combination, preferably 140,000mPas hereinafter, more preferably 120,000mPas with
Under, further preferably 75,000mPas hereinafter, further preferably 69,000mPas hereinafter, further preferably 60,
000mPas or less.In addition, the viscosity V (s) about second dose in second inner container at 30 DEG C, from being applied on hair
When prevent preparation sagging viewpoint, the ratio of the spray volume with first dose is set as the viewpoint of particular range for, preferably 9,
000mPas or more, more preferably 12,000mPas or more, further preferably 15,000mPas or more, in addition, from
It is easy the viewpoint for making preparation extend when being applied on hair, the ratio of the spray volume with first dose is set as to the sight of particular range
Point, to the end until all from inner pressurd vessel spray second dose viewpoint, make the good viewpoint of Combination with first dose for, preferably
For 90,000mPas hereinafter, more preferably 80,000mPas hereinafter, further preferably 60,000mPas hereinafter, into one
Step is preferably 40,000mPas or less.
In addition, the ratio between V (f) and V (s) V (f)/V (s) are 1.5 or more and 5 hereinafter, from maintaining first dose and the from beginning to end
For the viewpoint of the ratio of two doses of spray volume, preferably 1.6 or more, more preferably 1.7 or more, further preferably 1.8 with
On, further preferably 2 or more, in addition, from maintain from beginning to end first dose with the viewpoint of the ratio of second dose of spray volume, subtract
For the viewpoint of few first dose and second dose of surplus in each inner pressurd vessel, preferably 4.5 hereinafter, more preferably 4 hereinafter, into
One step is preferably 3.5 hereinafter, further preferably 3 or less.
About the first dose and second dose viscosity at 30 DEG C, can be measured using Brookfield viscometer.In addition, about
First dose be contained in the first content and second dose of viscosity at 30 DEG C being contained in second inner container, can be from outer
Container takes out each inner pressurd vessel, and after taking out first dose and second dose in each inner pressurd vessel, is measured using Brookfield viscometer.Separately
Outside, specifically, can be measured by method recorded in embodiment.
[mass ratio]
About first dose of mass M (f) in second dose of mass M (s) and the first content in second inner container it
Than M (s)/M (f), for maintaining first dose of viewpoint with the ratio of second dose of spray volume from beginning to end, M (s)/M (f) is
1.2 or more, preferably 1.3 or more, more preferably 1.45 or more, in addition, the sight of the stimulation from hair damages are reduced or to scalp
For point, M (s)/M (f) is for 3 hereinafter, preferably 2.5 hereinafter, more preferably 1.8 or less.
[alkaline agent]
Contain alkaline agent in first dose.As alkaline agent, can enumerate：Ammonia and its salt (such as ammonium hydrogen carbonate)；It is monoethanolamine, different
Alkanolamines and its salt such as Propanolamine, 2- amino-2-methyls propyl alcohol, 2- amino butanols；The alkane such as 1,3- propane diamine diamines and its salt；
Carbonate such as guanidine carbonate, sodium carbonate, potassium carbonate, sodium bicarbonate, saleratus etc..For these alkaline agents, can also and with two kinds
More than.About the content of the alkaline agent in first dose, from make the abundant swelling of hair and for obtaining the viewpoint of hair dyeing effect, preferably
0.1 mass % or more, more preferably 0.2 mass % or more, further preferably 0.4 mass % or more, in addition, from hair is reduced
Damage or for the viewpoint of the stimulation of scalp, preferably 14 mass % hereinafter, more preferably 12 mass % hereinafter, further it is excellent
It is selected as 8 mass % or less.About the content of the alkaline agent in first dose of mixture with second dose, from the sight of sufficient hair dyeing effect
For point, preferably 0.05 mass % or more, more preferably 0.1 mass % or more, further preferably 0.2 mass % or more,
Further preferably 0.5 mass % or more, further preferably 1 mass % or more, in addition, from reduction hair damages or to scalp
Stimulation viewpoint for, preferably 7 mass % hereinafter, more preferably 6 mass % hereinafter, further preferably 5 mass % with
Under, further preferably 4 mass % or less.
[hydrogen peroxide]
Contain hydrogen peroxide in second dose.About the content of the hydrogen peroxide in second dose, from decomposition hair melanin
And for ensuring the coupling reaction of oxidation dye and obtaining the viewpoint of sufficient hair dyeing effect, preferably 1 mass % or more, more
Preferably 3 mass % or more, in addition, from hair damages or for the viewpoint of the stimulation of scalp are reduced, preferably 9 mass % with
Under, more preferably 6 mass % or less.About the content of the hydrogen peroxide in first dose of mixture with second dose, preferably 1 matter
Measure % or more, more preferably 2 mass % or more, additionally, it is preferred that for 6 mass % hereinafter, more preferably 5 mass % or less.
[surfactant]
It can contain surfactant in first dose, any one of second dose or both.It, can as surfactant
It enumerates：Cationic surfactant, nonionic surfactant, amphoteric surfactant and anion surfactant.These
Among, for the viewpoint of the stability of formula composition, preferably anion surfactant, nonionic surfactant.
As anion surfactant, can enumerate：Alkylbenzene sulfonate, alkyl ether sulfate, alkenyl ether sulfates, alkane
Base sulfate, alkenyl sulfate, alkene sulfonate, alkane sulfonate, saturation or unsaturated fatty acid salt, alkyl ether carboxy acid salt,
Alkenyl ether carboxylate, alpha-sulfo-fatty acid salt, N- acyl aminos hydrochlorate, phosphate monoester or di-phosphate ester, sulfosuccinate etc..
As alkyl ether sulfate, polyoxyethylene alkyl ether sulfate salt can be enumerated.Anion as these anion surfactants
The gegenion (counter ion) of property group, can enumerate：The alkali metal ions such as sodium ion, potassium ion；Calcium ion, magnesium ion
Equal alkaline-earth metal ions；Ammonium ion；Alkanolamine (such as monoethanolamine with the silane alcohol base that 1~3 carbon atom number is 2 or 3
Salt, diethanolamine salt, triethanolamine salt, triisopropanolamine salt etc.).
As cationic surfactant, for the hair after contaminating hair assigns the viewpoint of excellent sense of touch, preferably
Monoalkyl trimethyl ammonium chloride, dialkyl dimethyl ammonium chloride, monoalkyl trimethyl ammonium bromide, wherein more preferably stearyl
Trimethyl ammonium chloride (Steartrimonium chloride), hexadecyltrimethylammonium chloride (Cetrimonium
Chloride), lauryl trimethyl ammonium chloride (Lauryl Trimonium chloride), preferably also will be two or more mixed
It closes.
As nonionic surfactant, can enumerate：Polyoxyalkylene alkyl, polyoxyalkylene alkenyl ether, higher fatty acids
It is sucrose ester, polyglyceryl fatty acid ester, higher fatty acids single ethanol amide or higher fatty acids diglycollic amide, polyethylene glycol hydrogenated
Castor oil, polyoxyethylene sorbitan fatty acid ester, polyoxyethylene sorbitol aliphatic ester, alkyl carbohydrate, alkyl oxidation
Amine, alkylamide amine oxide etc..Among these, preferably polyoxyalkylene alkyl, Crodaret, alkyl candy
Class, more preferably polyxyethylated (12~14) ether, alkyl polyglucoside.
As amphoteric surfactant, can enumerate：Imidazoline, carbobetaine, amide betaine, sulfobetaines, hydroxyl
Base sulfobetaines, amide sulfo betaine etc., more preferably alkyl dimethyl oxyneurine, fatty amide propyl sweet tea
The beet alkali surface activators such as dish alkali, further preferably fattyamidopropyl betaine.
These surfactants can be used alone any, or two or more combinations be used.About first dose with
The content of surfactant in second dose of mixture, for good sense of touch, the viewpoint of emulsifiability, preferably 0.1
Quality % or more, more preferably 0.2 mass % or more, further preferably 0.5 mass % or more, in addition, from obtaining adequately
For the viewpoint of hair dyeing effect, preferably 30 mass % hereinafter, more preferably 25 mass % hereinafter, further preferably 20 matter
% is measured hereinafter, further preferably 10 mass % are hereinafter, further preferably 5 mass % or less.
[higher alcohol]
It can contain higher alcohol in first dose, any one of second dose or both.It, can be under use as higher alcohol
State the compound represented by general formula (1).
R-OH (1)
[in formula, R indicates that carbon atom number is the alkyl of 12 or more and 24 linear chain or branched chains below.]
As higher alcohol, can enumerate：Laruyl alcohol, myristyl alcohol, cetanol, stearyl alcohol, isooctadecanol, arachidic alcohol, behenyl
Alcohol, tetracosanol, oleyl alcohol etc..It for higher alcohol, can be used alone, or two or more combinations used.
About higher alcohol, for the viewpoint for the viscosity change for inhibiting to pass through at any time, preferably (1a) above-mentioned general formula (1)
In R be higher alcohol that carbon atom number is 12 or more and 18 straight chained alkyls below, be carbon with the R in (1b) above-mentioned general formula (1)
Atomicity is the combination of the higher alcohol of 20 or more and 24 straight chained alkyls below, and the more preferably R in (1a) above-mentioned general formula (1) is
Carbon atom number is the higher alcohol of 14 or more and 18 straight chained alkyls below, is that carbon atom number is with the R in (1b) above-mentioned general formula (1)
The combination of the higher alcohol of 20 or more and 22 straight chained alkyls below.Mass ratio [(1a) about ingredient (1a) and ingredient (1b)：
(1b)], for the viewpoint for the viscosity change for inhibiting to pass through at any time, preferably 0.5：9.5~9.5：0.5, more preferably 1：9
~9：1, further preferably 1.5：8.5~8.5：1.5, further preferably 1：4~4：1.
About the content of the higher alcohol in first dose of mixture with second dose, conduct is set as from by the viscosity after rigid manufacture
The viewpoint of hair dye and range appropriate, for inhibiting the viewpoint of the viscosity change passed through at any time, preferably 3 mass % with
On, more preferably 4 mass % or more, further preferably 5 mass % or more, in addition, becoming from the viscosity for inhibiting to pass through at any time
For the viewpoint of change, preferably 12 mass % hereinafter, more preferably 11 mass % hereinafter, further preferably 10 mass % with
Under, further preferably 9 mass % or less.
[hydrocarbon]
It can contain hydrocarbon in first dose, any one of second dose or both.It about hydrocarbon, can be used alone, or will
It is two or more combination and use.As the hydrocarbon of the present invention, can enumerate：Liquid paraffin, liquid isoalkane, lightweight isoalkane, lightweight
Liquid isoalkane, heavy liquid isoalkane, saualane etc..Among these, from the viewpoint for the viscosity change for inhibiting to pass through at any time
For, preferably liquid paraffin.
About the content of the hydrocarbon in first dose of mixture with second dose, the brightness after improving hair dyeing or hair decoloration
Viewpoint for, preferably 1 mass % or more, more preferably 2 mass % or more, further preferably 3 mass % or more, separately
Outside, preferably 20 mass % hereinafter, more preferably 15 mass % hereinafter, further preferably 10 mass % hereinafter, further it is excellent
It is selected as 8 mass % or less.
[ester oil]
It can contain ester oil in first dose, any one of second dose or both.About ester oil, can be used alone,
Or two or more combinations are used.As the ester oil of the present invention, can enumerate：Myristic acid octyldodecyl alcohol ester, nutmeg
The different tridecane alcohol ester of isopropyl propionate, isopropyl isostearate, isononyl isononanoate, isononanoic acid, butyl stearate, oleyl oleate,
Ricinoleic acid octyldodecyl alcohol ester, two capric acid neopentyl glycol ester, two isooctadecanol ester of malic acid, octyl hydroxystearate, Australia
Continent macadamia nut oil, olive oil, castor oil, Jojoba Oil, avocado oil, sunflower oil, two isostearic acid polyglycerol esters, three isostearic acids
Polyglycerol ester, two glyceryl isostearates, three glyceryl isostearates, three (caprylic/capric) glyceride, three (2 ethyl hexanoic acids)
Glyceride, Pentaerythrityl tetraoctanoate etc..Among these, for the higher viewpoint of emulsion stability, it is preferably belonging to be saturated
The following substance of the branch alcohol ester of aliphatic acid：It is isopropyl myristate, isopropyl isostearate, two different stearyl ester of malic acid, different
The different nonyl ester of n-nonanoic acid, the different tridecane alcohol ester of isononanoic acid, palmitic acid 2- ethylhexyls, myristic acid octyldodecyl alcohol ester, oleic acid are pungent
Base dodecane alcohol ester, erucic acid octyldodecyl alcohol ester etc..
About the content of the ester oil in first dose of mixture with second dose, the light after improving hair dyeing or hair decoloration
For the viewpoint of degree, preferably 0.01 mass % or more, more preferably 0.03 mass % or more, in addition, from mixture in hair
On sufficient ductility viewpoint for, preferably 5 mass % hereinafter, more preferably 3 mass % hereinafter, further preferably
2 mass % or less.
[organic solvent]
It can contain organic solvent in first dose, any one of second dose or both.As organic solvent, can arrange
It lifts：The low-grade alkane alcohols such as ethyl alcohol, 1- propyl alcohol, 2- propyl alcohol；The aromatic alcohols such as benzylalcohol, 2- benzyloxyethanol, phenoxetol；The third two
The polyalcohols such as alcohol, 1,3 butylene glycol, diethylene glycol, glycerine；The ethers such as ethoxy ethanol, ethoxydiglycol, methyl cellosolve
Alcohol；The N- alkyl pyrrolidones such as N-Methyl pyrrolidone, N- ethyl pyrrolidones；The carbonic acid alkane diol ester such as propylene glycol carbonate；
The lactones such as gamma-valerolactone, γ-hexalactone.
These organic solvents can be used alone, or two or more combinations are used, in addition, about it at first dose and
Content in second dose of mixture, from the viewpoint for preventing oxidation dye to be precipitated from first dose of mixture with second dose and
Speech, preferably 0.1 mass % or more, more preferably 0.5 mass % or more, further preferably 1.0 mass % or more, in addition,
For preventing mixture to be separated into viewpoint of the aqueous layer with oil phase layer, preferably 35 mass % are hereinafter, more preferably 30 matter
Measure % hereinafter, further preferably 25 mass % hereinafter, further preferably 20 mass % hereinafter, further preferably 15 matter
% is measured hereinafter, further preferably 10 mass % or less.
[dyestuff]
It is used or hair decoloration applies some make up in the case of applying some make up for hair dyeing in the hair dyeing of the aerosol type of the present invention, the
Contain oxidation dye intermediates or direct dyes in one.
(oxidation dye intermediates)
As oxidation dye intermediates, the well known predecessor usually used in hair dye can be used
(precursor) and colour coupler (coupler).As predecessor, such as can enumerate：P-phenylenediamine, Toluene-2,4-diisocyanate, 5- diamines, neighbour
Chlorine p-phenylenediamine, 4-aminodiphenylamine, N, bis- (hydroxyethyl) p-phenylenediamine of N-, 3- methyl -4-aminophenol, 2- hydroxyl second
Base p-phenylenediamine, para-aminophenol, p-methylaminophenol, 4- amino metacresol, o-aminophenol and their salt etc..
In addition, as colour coupler, such as can enumerate：Resorcinol, 2- methyl resorcinols, 1- naphthols, 1,5- dihydroxy
Naphthalene, 5- amino o-cresol, m-phenylene diamine (MPD), o-aminophenol, m-aminophenol, para-aminophenol, 2,4- diamino phenoxy second
Alcohol, 2,6- diamino-pyridines, 2- methyl -5- Hydroxy-ethylaminos phenol, 2- amino -3- pyridones and their salt etc..
For predecessor and colour coupler respectively for, can be used alone, or by it is two or more combination and use.First
Predecessor and the respective content of colour coupler in agent are preferably 0.01 mass % or more, more preferably 0.1 mass % or more, separately
Outside, preferably 5 mass % are hereinafter, more preferably 4 mass % or less.
(direct dyes)
As direct dyes, can enumerate：Acid dyes, nitro dye, disperse dyes, basic dye etc..More specifically,
As acid dyes, can enumerate：Blue 1, purple 401, black 401, No. 205 orange, No. 227 red, red 106
Number, (1) of yellow 202, (2) of yellow 202, yellow 203, acid orange 3 etc., as nitro dye, can enumerate：2- nitre
The chloro- 4- nitrophenols of base p-phenylenediamine, 2- amino -6-, 3- nitros are to Hydroxy-ethylamino phenol, 4-nitro-o-phenylenediamine, 4-
Amino-3-nitro phenol, 4- hydroxypropylamino -3- nitrophenols, HC indigo plants 2, HC oranges 1, HC be red 1, HC Huangs 2, HC Huangs 4, HC are yellow
5, HC is red 3, N, and bis- (2- hydroxyethyls) -2- nitro p-phenylenediamines of N- etc. as disperse dyes, can enumerate：Disperse violet 1, dispersion
Indigo plant 1, dispersion black 9 etc., as basic dye, can enumerate：Alkali blue 99, bismarck brown 16, bismarck brown 17, alkalinity is red 76, basic yellow
76, Basic Orange 31, alkalinity red 51 etc..
It for direct dyes, can be used alone, or two or more combinations used, it can also be with oxidation dye
Intermediate is used in combination.The content of direct dyes in first dose is preferably 0.001 mass % or more, more preferably 0.01 mass % with
On, additionally, it is preferred that for 5 mass % hereinafter, more preferably 3 mass % or less.
[any other ingredient]
In first dose or second dose that the aerosol type hair dyeing use of the present invention or hair decoloration apply some make up, in addition to above-mentioned
Other than ingredient, the other compositions for being typically used as cosmetic material can also be added.As this any ingredient, can enumerate：Finish,
Polysiloxane-based, non-volatile hydrophilic solvent, animal and plant fat, natural or synthetic macromolecule, ethers, protein derived
Object, aminosal, amino acids, preservative, chelating agent, stabilizer, antioxidant, botanical extract, extracts from crude drugs,
Vitamins, fragrance, ultra-violet absorber etc..
[pH value]
First dose of pH value (25 DEG C) is preferably 8 or more and 12 or less.For the viewpoint of the stability of hydrogen peroxide, the
Two doses of pH value (25 DEG C) is preferably 2 or more and 5 or less.Further, about first dose with second dose of mixture when in use
PH value (25 DEG C), from make hair swelling and for obtaining the viewpoint of sufficient hair dyeing effect, preferably 8.0 or more, more preferably
Be 8.5 or more, further preferably 9.0 or more, in addition, for the viewpoint for preventing the stimulation to scalp, preferably 11.5 with
Under, more preferably 11.0 hereinafter, further preferably 10.5 or less.In addition, the pH value in the present invention is to make institute using hole field
The value that the pH meter F-22 of manufacture is measured under room temperature (25 DEG C).
[hair dyeing tool]
Hair dyeing tool can be used to apply some make up and be applied to hair the aerosol type hair dyeing use of the present invention or hair decoloration
On.As hair dyeing tool, it can use and have comb section as recorded in the flat 10-71020 bulletins of Japanese Patent Laid-Open
And bristle portion hair dyeing tool or as in Japanese Patent Laid-Open 2006-326081 bulletins it is recorded have comb section and
The hair dyeing tool of bristle portion (bristle portion has to keep the recess portion of preparation).
[dosage form]
About first dose and second dose of dosage form, creams shape, gel, paste etc. can be set as.
[hair is had hair dyed or hair discoloration method]
For the hair dyeing of the aerosol type of the present invention is used or hair decoloration applies some make up, held in the palm to pre-prepd mixing
First dose and second dose is sprayed in disk, utilizes hair dyeing work recorded in the flat 10-71020 bulletins of such as Japanese Patent Laid-Open
After the bristle portion of tool mixes first dose with second dose, the mixture obtained is applied on hair, it is possible thereby to by hair
Dyeing or decoloration.
In addition, for the hair dyeing of the aerosol type of the present invention is used or hair decoloration applies some make up, to such as Japan Patent text
First dose and second dose of the recess portion ejection of the bristle portion of hair dyeing tool recorded in special open 2006-326081 bulletins is offered, and
The bristle portion is directly used in hair, thus, it is possible to make first dose to be mixed on hair with second dose on one side, it is whole in hair on one side
It smears and opens on body, thus by hair-dyeing or decoloration.
About the implementation described above, the preferred embodiment of the present invention is recorded further below.
A kind of aerosol type hair dyeings of 1 ＞ of ＜ are used or hair decoloration applies some make up, wherein have following outer container, the outer appearance
Device stores the first content and second inner container, first dose containing alkaline agent is filled in the first content, in second inner container
Filled with second dose containing hydrogen peroxide, also,
In space between the outer container and each inner pressurd vessel, to press to 0.2MPa or more and 0.8MPa at 30 DEG C
Mode below is filled with propellant,
The first content and second inner container are to be bonded innermost layer to have the multilayered structure of polyolefin resin layer respectively
Sheet material and formed, the flexural rigidity E of the flexural rigidity E (f) of the sheet material of the first content and the sheet material of the second inner container
(s) it is respectively 0.15gfcm2/ cm or more and 3.0gfcm2/ cm is hereinafter, ratio E (f)/E (s) of E (f) and E (s) is 0.3
Above and 5 hereinafter,
This first dose viscosity V (f) at 30 DEG C is 10,000mPas or more and 145,000mPas hereinafter, this
Two doses of viscosity V (s) at 30 DEG C are 8,000mPas or more and 100,000mPas are hereinafter, the ratio between V (f) and V (s) V
(f)/V (s) be 1.5 or more and 5 hereinafter,
The ratio between first dose of mass M (f) in second dose of mass M (s) and the first content in second inner container M
(s)/M (f) is 1.2 or more and 3 or less.
The hair dyeing of recorded aerosol type is used in 1 ＞ of ＜ 2 ＞ such as ＜ or hair decoloration applies some make up, wherein first content
The vistanex of device and the innermost layer of second inner container is preferably polyvinyl resin or acrylic resin.
The hair dyeing of recorded aerosol type is used in 2 ＞ of ＜ 3 ＞ such as ＜ 1 ＞ or ＜ or hair decoloration applies some make up, wherein E
(f) and E (s) is preferably 0.2gfcm2/ cm or more, more preferably 0.4gfcm2/ cm or more, further preferably 0.5gf
cm2/ cm or more, further preferably 0.6gfcm2/ cm or more, additionally, it is preferred that being 2.5gfcm2/ cm is hereinafter, more preferably
2.3gf·cm2/ cm is hereinafter, further preferably 2.1gfcm2/ cm is hereinafter, further preferably 2.0gfcm2/ cm or less.
Aerosol type hair dyeings of 4 ＞ of ＜ as recorded in any one of 3 ＞ of ＜ 1 ＞ to ＜ is used or hair decoloration makeup
Product, wherein ratio E (f)/E (s) of E (f) and E (s) are preferably 0.4 or more, more preferably 0.5 or more, additionally, it is preferred that for 4 with
Under, more preferably 3.3 hereinafter, further preferably 3 hereinafter, further preferably 2.5 hereinafter, further preferably 2.2 hereinafter,
Further preferably 2 or less.
Aerosol type hair dyeings of 5 ＞ of ＜ as recorded in any one of 4 ＞ of ＜ 1 ＞ to ＜ is used or hair decoloration makeup
Product, wherein preferably comprise the multilayered structure of the first content sheet material have outermost layer and middle layer, outermost layer be polyamide or
Polyester, middle layer are metal foil.
Aerosol type hair dyeings of 6 ＞ of ＜ as recorded in any one of 5 ＞ of ＜ 1 ＞ to ＜ is used or hair decoloration makeup
Product, wherein preferably comprise the multilayered structure of second inner container sheet material have outermost layer and middle layer, outermost layer be polyamide or
Polyester, middle layer are synthetic resin layer or silica vapor deposition layer with barrier properties for gases and chemical resistance.
Aerosol type hair dyeings of 7 ＞ of ＜ as recorded in any one of 6 ＞ of ＜ 1 ＞ to ＜ is used or hair decoloration makeup
Product, wherein internal pressure at 30 DEG C is preferably 0.3MPa or more, more preferably 0.4MPa or more, further preferably 0.50MPa with
On, additionally, it is preferred that for 0.75MPa hereinafter, more preferably 0.70MPa or less.
Aerosol type hair dyeings of 8 ＞ of ＜ as recorded in any one of 7 ＞ of ＜ 1 ＞ to ＜ is used or hair decoloration makeup
Product, wherein V (f) is preferably 15,000mPas or more, more preferably 30,000mPas or more, additionally, it is preferred that be 140,
000mPas hereinafter, more preferably 120,000mPas hereinafter, further preferably 75,000mPas hereinafter, further it is excellent
69,000mPas is selected as hereinafter, further preferably 60,000mPas or less.
Aerosol type hair dyeings of 9 ＞ of ＜ as recorded in any one of 8 ＞ of ＜ 1 ＞ to ＜ is used or hair decoloration makeup
Product, wherein V (s) is preferably 9,000mPas or more, more preferably 12,000mPas or more, further preferably 15,
000mPas or more, additionally, it is preferred that for 90,000mPas hereinafter, more preferably 80,000mPas is hereinafter, further preferably
For 60,000mPas hereinafter, further preferably 40,000mPas or less.
Aerosol type hair dyeings of 10 ＞ of ＜ as recorded in any one of 9 ＞ of ＜ 1 ＞ to ＜ is used or hair decoloration makeup
Product, wherein V (f)/V (s) is preferably 1.6 or more, more preferably 1.7 or more, further preferably 1.8 or more, further preferably
Be 2 or more, additionally, it is preferred that for 4.5 hereinafter, more preferably 4 hereinafter, further preferably 3.5 hereinafter, further preferably 3 with
Under.
Aerosol type hair dyeings of 11 ＞ of ＜ as recorded in any one of 10 ＞ of ＜ 1 ＞ to ＜ is used or hair decoloration makeup
Product, wherein M (s)/M (f) is preferably 1.3 or more, and more preferably 1.45 or more, additionally, it is preferred that for 2.5 hereinafter, more preferably
1.8 following.
Aerosol type hair dyeings of 12 ＞ of ＜ as recorded in any one of 11 ＞ of ＜ 1 ＞ to ＜ is used or hair decoloration makeup
Product, wherein preferably further contain surfactant in first dose, any one of second dose or both.
The hair dyeing of recorded aerosol type is used in 12 ＞ of ＜ 13 ＞ such as ＜ or hair decoloration applies some make up, wherein is lived on surface
Property agent is preferably selected from cationic surfactant, nonionic surfactant, amphoteric surfactant and anionic surface are lived
One or more of property agent.
The hair dyeing of recorded aerosol type is used in 13 ＞ of ＜ 14 ＞ such as ＜ 12 ＞ or ＜ or hair decoloration applies some make up,
In, the content of the surfactant in first dose of mixture with second dose is preferably 0.1 mass % or more, and more preferably 0.2
Quality % or more, further preferably 0.5 mass % or more, additionally, it is preferred that for 30 mass % hereinafter, more preferably 25 mass %
Hereinafter, further preferably 20 mass % hereinafter, further preferably 10 mass % hereinafter, further preferably 5 mass % with
Under.
Aerosol type hair dyeings of 15 ＞ of ＜ as recorded in any one of 14 ＞ of ＜ 1 ＞ to ＜ is used or hair decoloration makeup
Product, wherein preferably further contain higher alcohol in first dose, any one of second dose or both.
The hair dyeing of recorded aerosol type is used in 15 ＞ of ＜ 16 ＞ such as ＜ or hair decoloration applies some make up, wherein preferred high
Grade alcohol is the compound represented by the following general formula (1),
R-OH (1)
In formula, R indicates that carbon atom number is the alkyl of 12 or more and 24 linear chain or branched chains below.
The hair dyeing of recorded aerosol type is used in 16 ＞ of ＜ 17 ＞ such as ＜ or hair decoloration applies some make up, wherein higher alcohol
It with (1b) R be carbon atom number is 20 that preferably (1a) R, which is higher alcohol that carbon atom number is 12 or more and 18 straight chained alkyls below,
Above and the combination of the higher alcohol of 24 straight chained alkyls below, more preferably (1a) R be carbon atom number are 14 or more and 18 or less
Straight chained alkyl higher alcohol and (1b) R be the higher alcohol that carbon atom number is 20 or more and 22 straight chained alkyls below combination.
The hair dyeing of recorded aerosol type is used in 17 ＞ of ＜ 18 ＞ such as ＜ or hair decoloration applies some make up, wherein ingredient
The mass ratio [(1a) of (1a) and ingredient (1b)：(1b)] it is preferably 0.5：9.5~9.5：0.5, more preferably 1：9~9：1, into one
Step preferably 1.5：8.5~8.5：1.5, further preferably 1：4~4：1.
Aerosol type hair dyeings of 19 ＞ of ＜ as recorded in any one of 18 ＞ of ＜ 15 ＞ to ＜ is used or hair decoloration
Cosmetic, wherein the content of the higher alcohol in first dose of mixture with second dose is preferably 3 mass % or more, more preferably 4 matter
Measure % or more, further preferably 5 mass % or more, additionally, it is preferred that for 12 mass % hereinafter, more preferably 11 mass % with
Under, further preferably 10 mass % are hereinafter, further preferably 9 mass % or less.
Aerosol type hair dyeings of 20 ＞ of ＜ as recorded in any one of 19 ＞ of ＜ 1 ＞ to ＜ is used or hair decoloration makeup
Product, wherein preferably further contain hydrocarbon in first dose, any one of second dose or both.
The hair dyeing of recorded aerosol type is used in 20 ＞ of ＜ 21 ＞ such as ＜ or hair decoloration applies some make up, wherein first dose
Content with the hydrocarbon in second dose of mixture is preferably 1 mass % or more, more preferably 2 mass % or more, further preferably
For 3 mass % or more, additionally, it is preferred that for 20 mass % hereinafter, more preferably 15 mass % are hereinafter, further preferably 10 matter
% is measured hereinafter, further preferably 8 mass % or less.
Aerosol type hair dyeings of 22 ＞ of ＜ as recorded in any one of 21 ＞ of ＜ 1 ＞ to ＜ is used or hair decoloration makeup
Product, wherein preferably further contain ester oil in first dose, any one of second dose or both.
The hair dyeing of recorded aerosol type is used in 22 ＞ of ＜ 23 ＞ such as ＜ or hair decoloration applies some make up, wherein first dose
Content with the ester oil in second dose of mixture is preferably 0.01 mass % or more, more preferably 0.03 mass % or more, separately
Outside, preferably 5 mass % hereinafter, more preferably 3 mass % hereinafter, further preferably 2 mass % or less.
Aerosol type hair dyeings of 24 ＞ of ＜ as recorded in any one of 23 ＞ of ＜ 1 ＞ to ＜ is used or hair decoloration makeup
Product, wherein the content of the alkaline agent in first dose is preferably 0.1 mass % or more, more preferably 0.2 mass % or more, further
Preferably 0.4 mass % or more, additionally, it is preferred that for 14 mass % hereinafter, more preferably 12 mass % are hereinafter, further preferably
8 mass % or less.
Aerosol type hair dyeings of 25 ＞ of ＜ as recorded in any one of 24 ＞ of ＜ 1 ＞ to ＜ is used or hair decoloration makeup
Product, wherein the content of the hydrogen peroxide in second dose is preferably 1 mass % or more, more preferably 3 mass % or more, in addition, excellent
9 mass % are selected as hereinafter, more preferably 6 mass % or less.
[embodiment]
Then, the embodiment of the present invention and comparative example are illustrated.The technical scope of the present invention is not limited to following
Examples and Comparative Examples.
<Examples 1 to 39, comparative example 1~14>
According to common method, first dose, the Yi Ji of the formula 1-1~1-11 formed shown in the table 6 of the end of writing are prepared
Second dose of the 2-1~2-11 formed shown in table 7.These first dose is emulsified creams shape preparation with second dose.
In each table, indicate that the numerical value of the content of each ingredient is the numerical value of the quality % units in first dose or second dose.
These first dose and second dose is filled with combination shown in table 1~5 to separation filling-while ejection of pressurizeing
In the first content and second inner container of the dual structure container of type, and carry out measurement below and evaluation.
[sheet material of the first content and second inner container]
The first content use according to outermost layer/middle layer/innermost layer sequence be PET/Al foils/PE material as piece
Material.In addition, second inner container use according to outermost layer/middle layer/innermost layer sequence be PET/NY/PE material as piece
Material.In addition, using nitrogen as the propellant of filling.
[viscosimetric analysis]
About first dose be contained in the first content and be contained in second inner container second dose at 30 DEG C
Viscosity uses B shapes viscosimeter (manufacture of Dong Ji industry companies, model TVB-10R, the T-BAR STAGE TS- with helical mount
10).Specifically, cutting off outer container using cutter, followed by scissors cut the first content and second inner container, and take
Go out first dose and second dose.After first dose of gained and second dose is placed 1 day respectively, then taken if it is less than 50,000mPas
Value after being rotated 1 minute with 12rpm at 30 DEG C using main shaft No.M4, if it is 50,000mPas or more if, takes using main shaft
No.T-C 30 DEG C with 10rpm rotate 1 minute after value.Be measured according to the sequence of main shaft No.M4, T-C, show value not
Terminate to measure more than indication range and at the time of being measured to, measurement thereafter no longer carries out.
In addition, in each table, " V (f)/V (s) " indicates first dose of the V (f) measured by said determination method and the
The value of the ratio " V (f)/V (s) " of two doses of viscosity V (s).
[initial stage spray volume]
With mass ratio shown in table 1~5 by first dose and second dose of creams shape recorded in the table 6~7 of total 80g
In filling to separation filling-while the dual structure container for squirt-type of pressurizeing.Thereafter, 30 points are impregnated in 30 DEG C of thermostat
Clock carries out first dose of ejection simultaneously and second dose of operation 5 seconds, thus measures each dose of spray volume.
[ratio of spray volume]
Respectively with mass ratio shown in table 1~5 by first dose of creams shape recorded in the table 6~7 of total 80g and the
In two doses of fillings to separation filling-while the dual structure container for squirt-type of pressurizeing.Thereafter, 30 are impregnated in 30 DEG C of thermostat
Minute, and it is repeated while spraying the operation of first dose and second dose, 25 matter of second dose of known quantity for often spraying filling
When measuring %, first dose of spray volume is measured, stops at the time of spraying filled whole amount while spraying operation.Also, it will
The ratio of the spray volume of quality criteria of the spray volume of second dose measured of quality criteria relative to first dose is shown in each table
In " ratio of spray volume " column.
[evaluation test of surplus]
Respectively with mass ratio shown in table 1~5 by creams recorded in the table 6~7 of total 80g (quality before ejection)
In first dose of shape and second dose filling to separation filling-while the dual structure container for squirt-type of pressurizeing.Carry out ejection operation
Until first dose be contained in container or second dose can not spray (full dose ejection), and to remaining on after full dose ejection
First dose and second dose of quality (quality after full dose ejection) in inner pressurd vessel is measured.Specifically, utilizing cutter
Outer container is cut off, followed by scissors cut the first content and second inner container, and takes out the remained in each inner pressurd vessel
It is one and second dose, then quality measurement.For first dose and second dose, the surplus ratio in inner pressurd vessel is calculated by following formula
Rate.
Surplus ratio (%)=(quality after full dose ejection)/(quality before ejection) × 100
[inner voltage detecting]
Used as the instrument WGA-710c (manufacture of republicanism utility companies) of adjuster, as small pressure converter
Internal pressure when PGM-10KEZ1 (manufacture of republicanism utility companies) is to 30 DEG C is measured.The pressure of small pressure interpreter is imported
Portion withstands on separation filling-while the compression bar position of the outer container of the dual structure container for squirt-type of pressurizeing is kept for the stipulated time, at
For fixed value when, which is set as internal pressure.
[measurement of flexural rigidity]
Under the conditions of 20 DEG C, piece is measured using multi-functional pure bending test machine KES-FB2-S (manufacture of Kato Tech companies)
The flexural rigidity of material.Specifically, by the shape that the sheet cutting of the multilayered structure used in inner pressurd vessel is vertical 2cm × horizontal 4cm
Shape.The sheet material of the cut-out is sandwiched between the fixed chuck of testing machine and movable chuck.Then, the maximum curvature of testing machine is set
It is set to 2.5cm-1, recurring number is set as 2 times, and is measured.It is respectively 0.5cm according to curvature-1And 1.5cm-1When each value ask
Go out moment-curvature slope of a curve, and the value is set as flexural rigidity.
[table 1]
Claims (16)
1. a kind of aerosol type hair dyeing is used or hair decoloration applies some make up, wherein
The aerosol type hair dyeing is used or hair decoloration applies some make up and has following outer container, which stores the first content
And second inner container, filled with first dose containing alkaline agent in the first content, filled with containing peroxidating in second inner container
Second dose of hydrogen, also,
In space between the outer container and each inner pressurd vessel, to press to 0.2MPa or more and 0.8MPa or less at 30 DEG C
Mode be filled with propellant,
The first content and second inner container are to be bonded the sheet material for the multilayered structure that innermost layer has polyolefin resin layer respectively
And formed, flexural rigidity E (s) points of the flexural rigidity E (f) of the sheet material of the first content and the sheet material of the second inner container
It Wei not 0.15gfcm2/ cm or more and 3.0gfcm2/ cm hereinafter, ratio E (f)/E (s) of E (f) and E (s) be 0.3 or more and
5 hereinafter,
This first dose viscosity V (f) at 30 DEG C is 10,000mPas or more and 145,000mPas are hereinafter, this second dose
Viscosity V (s) at 30 DEG C is 8,000mPas or more and 100,000mPas are hereinafter, the ratio between V (f) and V (s) V (f)/V
(s) be 1.5 or more and 5 hereinafter,
The ratio between first dose of mass M (f) in second dose of mass M (s) and the first content in second inner container M (s)/M
(f) it is 1.2 or more and 3 or less.
2. aerosol type hair dyeing as described in claim 1 is used or hair decoloration applies some make up, wherein
The vistanex of the innermost layer of the first content and second inner container is polyvinyl resin.
3. aerosol type hair dyeing as claimed in claim 1 or 2 is used or hair decoloration applies some make up, wherein
E (f) and E (s) is respectively 0.6gfcm2/ cm or more and 2.0gfcm2/ cm or less.
4. the aerosol type hair dyeing as described in any one of claims 1 to 3 is used or hair decoloration applies some make up, wherein
Further contain surfactant in first dose, any one of second dose or both.
5. aerosol type hair dyeing as claimed in claim 4 is used or hair decoloration applies some make up, wherein
Surfactant is selected from cationic surfactant, nonionic surfactant, amphoteric surfactant and anion
One or more of surfactant.
6. the aerosol type hair dyeing as described in any one of Claims 1 to 5 is used or hair decoloration applies some make up, wherein
Further contain higher alcohol in first dose, any one of second dose or both.
7. aerosol type hair dyeing as claimed in claim 6 is used or hair decoloration applies some make up, wherein
Higher alcohol is the compound represented by the following general formula (1),
R-OH (1)
In formula, R indicates that carbon atom number is the alkyl of 12 or more and 24 linear chain or branched chains below.
8. aerosol type hair dyeing as claimed in claim 7 is used or hair decoloration applies some make up, wherein
Higher alcohol is that (1a) R is the higher alcohol that carbon atom number is 12 or more and 18 straight chained alkyls below and (1b) R is carbon atom
Number is the combination of the higher alcohol of 20 or more and 24 straight chained alkyls below.
9. aerosol type hair dyeing as claimed in claim 8 is used or hair decoloration applies some make up, wherein
The mass ratio (1a) of ingredient (1a) and ingredient (1b)：(1b) is 0.5：9.5~9.5：0.5.
10. the aerosol type hair dyeing as described in any one of claim 6~9 is used or hair decoloration applies some make up, wherein
The content of higher alcohol in first dose of mixture with second dose is 3 mass % or more and 12 mass % or less.
11. the aerosol type hair dyeing as described in any one of claim 1~10 is used or hair decoloration applies some make up, wherein
Further contain hydrocarbon in first dose, any one of second dose or both.
12. aerosol type hair dyeing as claimed in claim 11 is used or hair decoloration applies some make up, wherein
The content of hydrocarbon in first dose of mixture with second dose is 1 mass % or more and 20 mass % or less.
13. the aerosol type hair dyeing as described in any one of claim 1~12 is used or hair decoloration applies some make up, wherein
Contain ester oil in first dose, any one of second dose or both.
14. aerosol type hair dyeing as claimed in claim 13 is used or hair decoloration applies some make up, wherein
The content of ester oil in first dose of mixture with second dose is 0.01 mass % or more and 5 mass % or less.
15. the aerosol type hair dyeing as described in any one of claim 1~14 is used or hair decoloration applies some make up, wherein
The content of alkaline agent in first dose is 0.1 mass % or more and 14 mass % or less.
16. the aerosol type hair dyeing as described in any one of claim 1~15 is used or hair decoloration applies some make up, wherein
The content of hydrogen peroxide in second dose is 1 mass % or more and 9 mass % or less.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202410091734.9A CN117898952A (en) | 2015-12-28 | 2016-12-27 | Cosmetic for aerosol-type dyeing or bleaching of hair |
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2015257085 | 2015-12-28 | ||
| JP2015-257085 | 2015-12-28 | ||
| PCT/JP2016/088989 WO2017115821A1 (en) | 2015-12-28 | 2016-12-27 | Aerosol-type cosmetic for use in hair coloring or hair decoloring |
Related Child Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202410091734.9A Division CN117898952A (en) | 2015-12-28 | 2016-12-27 | Cosmetic for aerosol-type dyeing or bleaching of hair |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN108366919A true CN108366919A (en) | 2018-08-03 |
Family
ID=59224801
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202410091734.9A Pending CN117898952A (en) | 2015-12-28 | 2016-12-27 | Cosmetic for aerosol-type dyeing or bleaching of hair |
| CN201680074395.7A Pending CN108366919A (en) | 2015-12-28 | 2016-12-27 | Aerosol type hair dyeing is used or hair decoloration applies some make up |
Family Applications Before (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202410091734.9A Pending CN117898952A (en) | 2015-12-28 | 2016-12-27 | Cosmetic for aerosol-type dyeing or bleaching of hair |
Country Status (4)
| Country | Link |
|---|---|
| JP (1) | JP6857026B2 (en) |
| CN (2) | CN117898952A (en) |
| TW (1) | TWI728025B (en) |
| WO (1) | WO2017115821A1 (en) |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2003205983A (en) * | 2002-01-15 | 2003-07-22 | Hoyu Co Ltd | Double aerosol container and duplex can container |
| CN103726279A (en) * | 2012-10-12 | 2014-04-16 | 苏州三星电子有限公司 | Condensation type drying device |
| JP2014237621A (en) * | 2013-06-10 | 2014-12-18 | 株式会社ダリヤ | Two agent type hair dye which are ejected simultaneously |
| WO2014208735A1 (en) * | 2013-06-28 | 2014-12-31 | ホ－ユ－株式会社 | Hair cosmetic material composition and oxide-containing composition thereof, hair cosmetic material, and hair cosmetic product |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP4324455B2 (en) * | 2003-02-21 | 2009-09-02 | 株式会社ダイゾー | Packaging products |
| JP2005194207A (en) * | 2003-12-26 | 2005-07-21 | Kao Corp | Two-pack type hair cosmetic |
| JP2005194205A (en) * | 2003-12-26 | 2005-07-21 | Kao Corp | Two-pack type hair cosmetic |
| JP5986786B2 (en) * | 2012-04-12 | 2016-09-06 | 東洋製罐株式会社 | Interior pouch housed in double structure aerosol can |
| JP6058950B2 (en) * | 2012-08-31 | 2017-01-11 | ホーユー株式会社 | Aerosol type foamy hair dye composition |
| JP6502007B2 (en) * | 2013-06-28 | 2019-04-17 | ホーユー株式会社 | Aerosol hair cosmetic composition |
| JP6338329B2 (en) * | 2013-07-02 | 2018-06-06 | ホーユー株式会社 | Hair cosmetics and hair cosmetic products |
-
2016
- 2016-12-27 WO PCT/JP2016/088989 patent/WO2017115821A1/en active Application Filing
- 2016-12-27 CN CN202410091734.9A patent/CN117898952A/en active Pending
- 2016-12-27 JP JP2016253418A patent/JP6857026B2/en active Active
- 2016-12-27 CN CN201680074395.7A patent/CN108366919A/en active Pending
- 2016-12-28 TW TW105143504A patent/TWI728025B/en active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2003205983A (en) * | 2002-01-15 | 2003-07-22 | Hoyu Co Ltd | Double aerosol container and duplex can container |
| CN103726279A (en) * | 2012-10-12 | 2014-04-16 | 苏州三星电子有限公司 | Condensation type drying device |
| JP2014237621A (en) * | 2013-06-10 | 2014-12-18 | 株式会社ダリヤ | Two agent type hair dye which are ejected simultaneously |
| WO2014208735A1 (en) * | 2013-06-28 | 2014-12-31 | ホ－ユ－株式会社 | Hair cosmetic material composition and oxide-containing composition thereof, hair cosmetic material, and hair cosmetic product |
Also Published As
| Publication number | Publication date |
|---|---|
| JP2017119695A (en) | 2017-07-06 |
| JP6857026B2 (en) | 2021-04-14 |
| CN117898952A (en) | 2024-04-19 |
| TWI728025B (en) | 2021-05-21 |
| WO2017115821A1 (en) | 2017-07-06 |
| TW201725029A (en) | 2017-07-16 |
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