CN108362658A - Talcum powder content analysis and analysis method in a kind of polypropylene plastics - Google Patents

Talcum powder content analysis and analysis method in a kind of polypropylene plastics Download PDF

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Publication number
CN108362658A
CN108362658A CN201810187889.7A CN201810187889A CN108362658A CN 108362658 A CN108362658 A CN 108362658A CN 201810187889 A CN201810187889 A CN 201810187889A CN 108362658 A CN108362658 A CN 108362658A
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talcum powder
powder content
polypropylene
content
characteristic peak
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徐大伟
高扬之
丁冉
王维新
陈明
李成东
时圣杰
陆楚楚
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Suzhou Ahest Bot Detection Technology Co Ltd
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Suzhou Ahest Bot Detection Technology Co Ltd
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    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N21/00Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
    • G01N21/17Systems in which incident light is modified in accordance with the properties of the material investigated
    • G01N21/25Colour; Spectral properties, i.e. comparison of effect of material on the light at two or more different wavelengths or wavelength bands
    • G01N21/31Investigating relative effect of material at wavelengths characteristic of specific elements or molecules, e.g. atomic absorption spectrometry
    • G01N21/35Investigating relative effect of material at wavelengths characteristic of specific elements or molecules, e.g. atomic absorption spectrometry using infrared light
    • G01N21/3563Investigating relative effect of material at wavelengths characteristic of specific elements or molecules, e.g. atomic absorption spectrometry using infrared light for analysing solids; Preparation of samples therefor

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  • Spectroscopy & Molecular Physics (AREA)
  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
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Abstract

The invention discloses talcum powder content analysis and analysis method in a kind of polypropylene plastics of detection and analysis technical field, instrument parameter is arranged in (2):Wave number scanning range:4000cm‑1~650cm‑1, scan number:32, resolution ratio:4cm‑1;(3) polypropylene plastics that polypropylene, talcum powder and talcum powder content are 5%, 10%, 15%, 20%, 25%, 30% is scanned respectively carry out IR spectrum scanning;(4) determine that characteristic peak is 2950.69cm from polyacrylic infrared spectrogram‑1, 2919.21cm‑1, 2867.51cm‑1, 2850.39cm‑1, 1458.10cm‑1, 1376.43cm‑1;(5) determine that characteristic peak is 3675.56cm from the infrared spectrogram of talcum powder‑1, 1006.74cm‑1, 668.68cm‑1;(6) characteristic peak 1458.10cm is determined from the polypropylene plastics infrared spectrogram that talcum powder content is 5%, 10%, 15%, 20%, 25%, 30%‑1And 1006.74cm‑1Peak height, calculating compares;(7) matched curve, y=0.369x 1.048 are done according to content and ratio;(8) polypropylene specimen for scanning unknown talcum powder content, passes through characteristic peak 1458.10cm‑1And 1006.74cm‑1Peak height ratios bring curve into, acquire talcum powder content.

Description

Talcum powder content analysis and analysis method in a kind of polypropylene plastics
Technical field
The present invention relates to detection and analysis technical field, talcum powder content analysis and analysis in specially a kind of polypropylene plastics Method.
Background technology
Decaying total reflection (ATR) is a kind of sample mode of infrared spectrum, is difficult to detect in sample, non-destructive testing and sample There is advantageous advantage in terms of the acquisition of product surface information.Plastics in process of production, due to additives such as addition color masterbatch, lead to Translucidus is not often had, therefore conventional projective method sampling is difficult to directly prove effective.The convenience of ATR is mainly reflected in sample Surface information directly acquires, and sampling efficiency is improved relative to traditional solvent method.
Polypropylene (PP) is a kind of thermoplastic resin made of propylene polymerization, and methyl is arranged in the same side of molecular backbone Claim isotactic polypropylene, if the chaotic both sides for being arranged in molecular backbone of methyl claim random polypropylene, when methyl is arranged alternately in The both sides of molecular backbone claim syndiotactic polypropylene.In the acrylic resin of general industry production, isotactic structural content is about 95%, Remaining is random or syndiotactic polypropylene.Industrial products are using isotactic object as main component.Polypropylene also includes propylene and a small amount of ethylene Including copolymer.Usually translucent colorless solid is odorless nontoxic.The highly crystallized due to compound with regular structure, therefore fusing point can be high Up to 167 DEG C.Heat-resisting, corrosion-resistant, product can be its outstanding advantages with moise-heat sterilization.Density is small, is most light general-purpose plastics.Disadvantage It is that low-temperature impact resistance is poor, it is more easy to aging, but can be overcome respectively by modification.
PP has stronger competitiveness for auto industry, but because its modulus and heat resistance are relatively low, impact strength is poor, because This cannot be directly used as auto parts machinery, and what is used in car is MODIFIED PP product.Talcum powder is in the row such as medicine, food, makeups The application of industry is relatively broad.It is then often used in the adjustment of plastics mechanical property in plastic industry, the talcum powder of different content adds Add, the performance of base material can be influenced in various degree.
Practical content
The purpose of the present invention is to provide talcum powder content analysis and analysis methods in a kind of polypropylene plastics, in solution State the problem of being proposed in background technology.
To achieve the above object, the present invention provides the following technical solutions:
(1) chosen material, connects external power supply, control switch detector device whether normal function;
(2) instrument parameter is set:Wave number scanning range:4000cm-1~650cm-1, scan number:32, resolution ratio:4cm-1
(3) it is 5%, 10%, 15%, 20%, 25%, 30% to scan polypropylene, talcum powder and talcum powder content respectively Polypropylene plastics carry out IR spectrum scanning;
(4) determine that characteristic peak is 2950.69cm from polyacrylic infrared spectrogram-1, 2919.21cm-1, 2867.51cm-1, 2850.39cm-1, 1458.10cm-1, 1376.43cm-1
(5) determine that characteristic peak is 3675.56cm from the infrared spectrogram of talcum powder-1, 1006.74cm-1, 668.68cm-1
(6) from the polypropylene plastics infrared spectrogram that talcum powder content is 5%, 10%, 15%, 20%, 25%, 30% Determine characteristic peak 1458.10cm-1And 1006.74cm-1Peak height, calculating compares;
(7) matched curve, y=0.369x-1.048 are done according to content and ratio;
(8) polypropylene specimen for scanning unknown talcum powder content, passes through characteristic peak 1458.10cm-1And 1006.74cm-1's Peak height ratios bring curve into, acquire talcum powder content
Compared with prior art, the beneficial effects of the invention are as follows:
1, in the polypropylene plastics talcum powder content analysis new method, it is easy to operate, it is easy to use, can be rapidly and efficiently Retrieval PP in talcum powder content;
2 at the same the polypropylene plastics in talcum powder content analysis new method cost it is quick with respect to other analysis modes;
3 and suitable for QC departments carry out typical products in mass production tracking and analysis.
Description of the drawings
Fig. 1 is that content of the present invention and ratio make matched curve schematic diagram.
Specific implementation mode
Following will be combined with the drawings in the embodiments of the present invention, and technical solution in the embodiment of the present invention carries out clear, complete Site preparation describes, it is clear that described embodiments are only a part of the embodiments of the present invention, instead of all the embodiments.It is based on Embodiment in the present invention, it is obtained by those of ordinary skill in the art without making creative efforts every other Embodiment shall fall within the protection scope of the present invention.
Referring to Fig. 1, the present invention provides a kind of technical solution:Talcum powder content analysis and analysis in a kind of polypropylene plastics Method,
Embodiment 1:
(1) chosen material, connects external power supply, control switch detector device whether normal function;
(2) instrument parameter is set:Wave number scanning range:4000cm-1~650cm-1, scan number:32, resolution ratio:4cm-1
(3) the polypropylene plastics progress infrared spectrum that polypropylene, talcum powder and talcum powder content are 5% is scanned respectively to sweep It retouches;
(4) determine that characteristic peak is 2950.69cm from polyacrylic infrared spectrogram-1, 2919.21cm-1, 2867.51cm-1, 2850.39cm-1, 1458.10cm-1, 1376.43cm-1
(5) determine that characteristic peak is 3675.56cm from the infrared spectrogram of talcum powder-1, 1006.74cm-1, 668.68cm-1
(6) characteristic peak 1458.10cm is determined from the polypropylene plastics infrared spectrogram that talcum powder content is 5%-1With 1006.74cm-1Peak height, calculating compare ratio be 1.042;
(7) matched curve, y=0.369x-1.048 are done according to content and ratio;
(8) polypropylene specimen for scanning unknown talcum powder content, passes through characteristic peak 1458.10cm-1And 1006.74cm-1's Peak height ratios bring curve into, acquire talcum powder content.
Content/% 1458.10cm-1 1006.74cm-1 Ratio
5 3.191 3.325 1.042
Talcum powder content analysis and analysis method in a kind of polypropylene plastics,
Embodiment 2:
(1) chosen material, connects external power supply, control switch detector device whether normal function;
(2) instrument parameter is set:Wave number scanning range:4000cm-1~650cm-1, scan number:32, resolution ratio:4cm-1
(3) polypropylene plastics that polypropylene, talcum powder and talcum powder content are 10% is scanned respectively carry out infrared spectrum Scanning;
(4) determine that characteristic peak is 2919.21cm from polyacrylic infrared spectrogram-1
(5) determine that characteristic peak is 3675.56cm from the infrared spectrogram of talcum powder-1, 1006.74cm-1, 668.68cm-1
(6) characteristic peak 1458.10cm is determined from the polypropylene plastics infrared spectrogram that talcum powder content is 5%-1With 1006.74cm-1Peak height, calculating compares;
(7) matched curve, y=0.369x-1.048 are done according to content and ratio;
(8) polypropylene specimen for scanning unknown talcum powder content, passes through characteristic peak 1458.10cm-1And 1006.74cm-1's Peak height ratios bring curve into, acquire talcum powder content.
Content/% 1458.10cm-1 1006.74cm-1 Ratio
10 3.133 8.236 2.629
Talcum powder content analysis and analysis method in a kind of polypropylene plastics,
Embodiment 3:
(1) chosen material, connects external power supply, control switch detector device whether normal function;
(2) instrument parameter is set:Wave number scanning range:4000cm-1~650cm-1, scan number:32, resolution ratio:4cm-1
(3) polypropylene plastics that polypropylene, talcum powder and talcum powder content are 15% is scanned respectively carry out infrared spectrum Scanning;
(4) determine that characteristic peak is 2950.69cm from polyacrylic infrared spectrogram-1, 2919.21cm-1, 2867.51cm-1, 2850.39cm-1, 1458.10cm-1, 1376.43cm-1
(5) determine that characteristic peak is 3675.56cm from the infrared spectrogram of talcum powder-1, 1006.74cm-1, 668.68cm-1
(6) characteristic peak 1458.10cm is determined from the polypropylene plastics infrared spectrogram that talcum powder content is 5%-1With 1006.74cm-1Peak height, calculating compares;
(7) matched curve, y=0.369x-1.048 are done according to content and ratio;
(8) polypropylene specimen for scanning unknown talcum powder content, passes through characteristic peak 1458.10cm-1And 1006.74cm-1's Peak height ratios bring curve into, acquire talcum powder content.
Content/% 1458.10cm-1 1006.74cm-1 Ratio
15 3.027 12.972 4.285
Talcum powder content analysis and analysis method in a kind of polypropylene plastics,
Embodiment 4:
(1) chosen material, connects external power supply, control switch detector device whether normal function;
(2) instrument parameter is set:Wave number scanning range:4000cm-1~650cm-1, scan number:32, resolution ratio:4cm-1
(3) polypropylene plastics that polypropylene, talcum powder and talcum powder content are 20% is scanned respectively carry out infrared spectrum Scanning;
(4) determine that characteristic peak is 2950.69cm from polyacrylic infrared spectrogram-1, 2919.21cm-1, 2867.51cm-1, 2850.39cm-1, 1458.10cm-1, 1376.43cm-1
(5) determine that characteristic peak is 3675.56cm from the infrared spectrogram of talcum powder-1, 1006.74cm-1, 668.68cm-1
(6) characteristic peak 1458.10cm is determined from the polypropylene plastics infrared spectrogram that talcum powder content is 5%-1With 1006.74cm-1Peak height, calculating compares;
(7) matched curve, y=0.369x-1.048 are done according to content and ratio;
(8) polypropylene specimen for scanning unknown talcum powder content, passes through characteristic peak 1458.10cm-1And 1006.74cm-1's Peak height ratios bring curve into, acquire talcum powder content.
Content/% 1458.10cm-1 1006.74cm-1 Ratio
20 3.05 18.21 5.970
Talcum powder content analysis and analysis method in a kind of polypropylene plastics,
Embodiment 5:
(1) chosen material, connects external power supply, control switch detector device whether normal function;
(2) instrument parameter is set:Wave number scanning range:4000cm-1~650cm-1, scan number:32, resolution ratio:4cm-1
(3) polypropylene plastics that polypropylene, talcum powder and talcum powder content are 25% is scanned respectively carry out infrared spectrum Scanning;
(4) determine that characteristic peak is 2950.69cm from polyacrylic infrared spectrogram-1, 2919.21cm-1, 2867.51cm-1, 2850.39cm-1, 1458.10cm-1, 1376.43cm-1
(5) determine that characteristic peak is 3675.56cm from the infrared spectrogram of talcum powder-1, 1006.74cm-1, 668.68cm-1
(6) characteristic peak 1458.10cm is determined from the polypropylene plastics infrared spectrogram that talcum powder content is 5%-1With 1006.74cm-1Peak height, calculating compares;
(7) matched curve, y=0.369x-1.048 are done according to content and ratio;
(8) polypropylene specimen for scanning unknown talcum powder content, passes through characteristic peak 1458.10cm-1And 1006.74cm-1's Peak height ratios bring curve into, acquire talcum powder content.
Content/% 1458.10cm-1 1006.74cm-1 Ratio
25 2.795 23.333 8.348
Talcum powder content analysis and analysis method in a kind of polypropylene plastics,
Embodiment 6:
(1) chosen material, connects external power supply, control switch detector device whether normal function;
(2) instrument parameter is set:Wave number scanning range:4000cm-1~650cm-1, scan number:32, resolution ratio:4cm-1
(3) polypropylene plastics that polypropylene, talcum powder and talcum powder content are 30% is scanned respectively carry out infrared spectrum Scanning;
(4) determine that characteristic peak is 2950.69cm from polyacrylic infrared spectrogram-1, 2919.21cm-1, 2867.51cm-1, 2850.39cm-1, 1458.10cm-1, 1376.43cm-11
(5) determine that characteristic peak is 3675.56cm from the infrared spectrogram of talcum powder-1, 1006.74cm-1, 668.68cm-1
(6) characteristic peak 1458.10cm is determined from the polypropylene plastics infrared spectrogram that talcum powder content is 5%-1With 1006.74cm-1Peak height, calculating compares;
(7) matched curve, y=0.369x-1.048 are done according to content and ratio;
(8) polypropylene specimen for scanning unknown talcum powder content, passes through characteristic peak 1458.10cm-1And 1006.74cm-1's Peak height ratios bring curve into, acquire talcum powder content.
Content/% 1458.10cm-1 1006.74cm-1 Ratio
30 2.823 28.775 10.193
It although an embodiment of the present invention has been shown and described, for the ordinary skill in the art, can be with Understanding without departing from the principles and spirit of the present invention can carry out these embodiments a variety of variations, modification, replace And modification, the scope of the present invention is defined by the appended.

Claims (1)

1. talcum powder content analysis and analysis method in a kind of polypropylene plastics, including,
(1) chosen material, connects external power supply, control switch detector device whether normal function;
(2) instrument parameter is set:Wave number scanning range:4000cm-1~650cm-1, scan number:32, resolution ratio:4cm-1
(3) scan polypropylene respectively, talcum powder and talcum powder content be 5%, 10%, 15%, 20%, 25%, 30% it is poly- Acrylic plastic carries out IR spectrum scanning;
(4) determine that characteristic peak is 2950.69cm from polyacrylic infrared spectrogram-1, 2919.21cm-1, 2867.51cm-1, 2850.39cm-1, 1458.10cm-1, 1376.43cm-1
(5) determine that characteristic peak is 3675.56cm from the infrared spectrogram of talcum powder-1, 1006.74cm-1, 668.68cm-1
(6) it is determined from the polypropylene plastics infrared spectrogram that talcum powder content is 5%, 10%, 15%, 20%, 25%, 30% Characteristic peak 1458.10cm-1And 1006.74cm-1Peak height, calculating compares;
(7) matched curve, y=0.369x-1.048 are done according to content and ratio;
(8) polypropylene specimen for scanning unknown talcum powder content, passes through characteristic peak 1458.10cm-1And 1006.74cm-1Peak height Ratio brings curve into, acquires talcum powder content.
CN201810187889.7A 2018-03-07 2018-03-07 Talcum powder content analysis and analysis method in a kind of polypropylene plastics Pending CN108362658A (en)

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CN111398209A (en) * 2020-05-04 2020-07-10 中钢集团郑州金属制品研究院有限公司 Infrared spectrum method for measuring polyvinyl chloride content in hard polyvinyl chloride pipe
CN112485215A (en) * 2020-11-12 2021-03-12 北方华锦化学工业股份有限公司 Method for quantitatively analyzing ethylene content in impact-resistant polypropylene by infrared spectroscopy
CN114235735A (en) * 2021-11-26 2022-03-25 北方华锦化学工业股份有限公司 Method for quantitatively analyzing content of transparent agent in industrial transparent polypropylene by infrared spectroscopy

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CN114235735A (en) * 2021-11-26 2022-03-25 北方华锦化学工业股份有限公司 Method for quantitatively analyzing content of transparent agent in industrial transparent polypropylene by infrared spectroscopy

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