CN108359283A - A kind of Chinese herbal medicine insect prevention woodwork coating and preparation method thereof - Google Patents
A kind of Chinese herbal medicine insect prevention woodwork coating and preparation method thereof Download PDFInfo
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- CN108359283A CN108359283A CN201810055408.7A CN201810055408A CN108359283A CN 108359283 A CN108359283 A CN 108359283A CN 201810055408 A CN201810055408 A CN 201810055408A CN 108359283 A CN108359283 A CN 108359283A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D1/00—Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1687—Use of special additives
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Plant Pathology (AREA)
- Inorganic Chemistry (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Paints Or Removers (AREA)
Abstract
A kind of Chinese herbal medicine insect prevention woodwork coating of present invention offer and preparation method thereof, belongs to technical field of coatings.The Chinese herbal medicine insect prevention woodwork coating is grouped as in terms of parts by weight by following group：10 30 parts of deionized water, 0.1 0.2 parts of cellulose, 0.1 0.3 parts of pH adjusting agent, 0.1 0.5 parts of wetting agent, 0.2 0.4 parts of dispersant, 0.2 0.6 parts of antifoaming agent, 1 1.5 parts of antifreezing agent, 100 250 parts of titanium dioxide, 15.3 25 parts of filler, 30 60 parts of Chinese herbal medicine expelling parasite lotion, 0.1 0.15 parts of coalescents, 0.1 0.8 parts of thickener, 0.3 0.8 parts of levelling agent.
Description
Technical field
The present invention relates to a kind of Chinese herbal medicine insect prevention woodwork coatings and preparation method thereof, belong to paint field.
Background technology
Because its is cheap, easy for construction is the mainstream of woodcare paint for traditional artificial woodcare paint such as polyurethane paint, nitrate paint
Product, but these traditional woodcare paints can discharge a large amount of toxic, harmful solvent, free TDIs when brushing and after brushing, and some is also
Containing heavy metal, the environmental requirement of today is not met.And aqueous woodware paint is broken through in the environmental protection of coating, because it is
With water as medium, using a variety of unsaturated chemical monomers, the woodenware of the thermosetting property, high glaze that are formed under specific process conditions
Paint has many advantages, such as non-toxic and tasteless, pollution-free, water-fast, wear-resisting, acid and alkali-resistance, easy to use.But current aqueous woodware paint there is also
Many disadvantages, one of them is to cause the insect prevention performance of aqueous woodware paint not as good as traditional artificial woodenware because it is non-toxic
Paint.
Currently, timber is immersed in containing the molten of drug mainly based on infusion method and brushing method by wood preservation from decay processing
In liquid, or by the solution brushing containing drug on wood surface.The disadvantage is that drug is easy to run off, duration of efficacy is short；Medicine
Object is harmful, environmental pollution；After the solution of wood surface brushing drug, affects and effect is adornd to the paint of wood surface.
Therefore, at present the insect prevention pesticide application technology of timber or plank be not applied for modern wooden furniture aqueous environment protection paint application and family
Decorations.
Invention content
The technical problem to be solved by the present invention is to aqueous environment protecting paint for wooden articles in the prior art do not have insect prevention function, into
And a kind of Chinese herbal medicine insect prevention woodwork coating of function admirable is provided and preparation method thereof.
In order to solve the above technical problem, the present invention provides a kind of Chinese herbal medicine insect prevention woodwork coatings, in terms of parts by weight,
It is composed of the following components：
Further, the Chinese herbal medicine insect prevention woodwork coating, it is composed of the following components in terms of parts by weight：
Further, the Chinese herbal medicine expelling parasite lotion is Blumea oil miniemulsion.
Further, the manufacture craft of the Blumea oil miniemulsion includes the following steps：
(1) emulsifier Span-80 and Tween-60 are added in Blumea oil selection phase inversion, and heating stirring at 40 DEG C makes
Emulsifier is completely dissolved in Blumea oil；
(2) under agitation, to deionized water is added in the step (1) to forming emulsion oil-in-water；
(3) emulsion oil-in-water of preparation is placed in magnetic stirring apparatus, temperature is set as 40 DEG C, after stirring 30min
Obtain the thick lotion of finely dispersed Blumea oil；
(4) that the thick lotion of the Blumea oil made is obtained Blumea oil with high-speed shearing machine in 600 rotating speed down cut 10min is carefully newborn
Liquid；
Wherein in above-mentioned steps, the Span-80, Tween-60, Blumea oil and water the mass ratio of additive amount be 1:3:1:
5。
Further, the wetting agent is polyoxyethylated alkyl phenol, polyoxyethylene aliphatic alcohol ether or polyoxyethylene polyoxy
Any one in propylene-based block copolymer；The thickener rises for alkali soluble in class thickener or polyacrylate-type thickeners
Any one；The cellulose is hydroxyethyl cellulose；The coalescents are alcohol ester 12.
Further, the dispersant is ammonium polyacrylate salt dispersant；The antifoaming agent is mineral oil defoaming agent；
The titanium dioxide is rutile titanium white powder；The levelling agent is polyurethanes levelling agent；The filler is calcined kaolin, diatom
One or more combinations in soil, powdered whiting.
Further, the preparation method of the Chinese herbal medicine insect prevention woodwork coating, includes the following steps：
(1) above-mentioned substance is weighed according to said ratio, deionized water is added in retort A, with the speed of 100-200rpm
Degree stirring sequentially adds cellulose, pH adjusting agent, wetting agent, dispersant, antifoaming agent, antifreezing agent, with the speed of 500-800rpm
2min is stirred to uniform；
(2) according to formula ratio, titanium dioxide, filler are slowly added to successively in retort A, with the speed of 1000-1200rpm
30min is stirred, is shut down, tests fineness, it is desirable that fineness≤55um；
(3) according to formula ratio, Chinese herbal medicine mosquito repellent lotion, levelling agent, with 800-1200rpm are slowly added in retort A
Speed stir 5 minutes, survey initial viscosity, according to initial viscosity, the thickener that formula ratio is added carries out being thickened to 25 DEG C, Si Tuo
Silent viscosimeter 80-100KU, is made the mosquito-proof woodwork coating of Chinese herbal medicine.
The present invention has the following advantages that compared with prior art：
(1) Chinese herbal medicine insect prevention woodwork coating of the present invention, by be arranged it is specific addition type and specific proportioning it is aqueous
Environmental protection coating material, and specific Chinese herbal medicine expelling parasite lotion is added thereto, each component synergistic effect, the Chinese herbal medicine insect prevention wood being prepared
Device coating has anthelminthic effect outstanding, and will not be had an impact to the physical property of aqueous environment protection paint.
(2) Chinese herbal medicine insect prevention woodwork coating of the present invention further limits folium artemisiae argyi oil treatment process, specific by this
Treatment process treated Blumea oil is prepared after being added in the formula of specific Environmental Protective Water-paint of the present invention
Chinese herbal medicine insect prevention woodwork coating has splendid anthelminthic effect, and when the drying for the aqueous, environmental protective woodwork coating being prepared
Between, the excellent physical properties such as hardness, water resistance, alkali resistance, stain resistance.
Specific implementation mode
With reference to embodiments, the present invention is further described in detail, but not limited to this.
Raw material employed in following embodiments is marketable material unless otherwise specified.In order to clearly illustrate this hair
The bright embodiment, it is following specifically to list the specific type of feed selected in embodiment of the present invention.
The dispersant is polyacrylic acid ammonia salt dispersant, the section of being selected as it is peaceful 963；
The antifoaming agent is the A10 of BASF.
The titanium dioxide is the rutile titanium white powder of chloridising production, is selected as the LR996 of imperial boa；
The filler is one or more combinations in calcined kaolin, diatomite, powdered whiting；The calcining is high
Ridge soil is calcined kaolin DB80, and the diatomite is Celite C499, and the powdered whiting is the heavy of wide good fortune
Calcium carbonate CC-700；
The thickener is any one that alkali soluble rises in class and polyacrylate；
The levelling agent is no-solvent polyurethane class levelling agent, is specifically chosen the 2025 of France Gao Tai；
The coalescents are 12 coalescents of alcohol ester, selected from the graceful extraordinary Chemical Co., Ltd. of neat Tracie Ruiz-Conforto
TEXANOL；
The wetting agent is polyoxyethylated alkyl phenol, polyoxyethylene aliphatic alcohol ether, and polyoxyethylene polyoxypropylene block is total
Any one in polymers；
The pH adjusting agent is selected from the AMP-95 of DOW Chemical；
The Chinese herbal medicine expelling parasite lotion is Blumea oil miniemulsion, and manufacture craft is：Select phase inversion by certain proportion
Span-80 and Tween-60 be added Blumea oil in, 40 DEG C of heating stirrings, make emulsifier completion be dissolved in Blumea oil, under stiring
The water that deionized water is initially added into is slowly added into tiny droplet distribution in oil phase, is w/o type lotion, is continuing to add water,
With the increase of rate of water added, micro- conversion occurs for emulsion, becomes O/W type lotions, the water-based emulsion of preparation is placed on magnetic agitation
In device, temperature is set as 40 DEG C, and the thick lotion of finely dispersed Blumea oil is obtained after stirring 30min, and the Blumea oil made is slightly newborn
Liquid obtains Blumea oil miniemulsion with the high-speed shearing machine shearing regular hour；In the preparation process, the Span-80, tween-
60, the mass ratio of the additive amount of Blumea oil and water is 1:3:1:5.
Embodiment 1
The woodwork coating of Chinese herbal medicine insect prevention described in the present embodiment, it is composed of the following components in terms of parts by weight：By such as the following group
It is grouped as：10 parts of deionized water, 0.15 part of cellulose, 0.3 part of pH adjusting agent, 0.1 part of wetting agent, 0.3 part of dispersant, antifoaming agent
0.6 part, 1 part of antifreezing agent, 250 parts of titanium dioxide, 15.3 parts of filler, 60 parts of Chinese herbal medicine expelling parasite lotion, 0.1 part of coalescents, thickening
0.5 part of agent, 0.8 part of levelling agent.
In present embodiment, the filler is calcined kaolin, diatomite, the powdered whiting mixed with arbitrary proportion
Mixed fillers；The thickener is that alkali soluble rises class thickener；The wetting agent is polyoxyethylated alkyl alcohol.
The preparation method of the woodwork coating coating of Chinese herbal medicine insect prevention described in the present embodiment, includes the following steps：
(1) according to said ratio, above-mentioned substance is weighed, deionized water is added in retort A, is stirred with the speed of 100rpm
It mixes and sequentially adds cellulose, pH adjusting agent, wetting agent, dispersant, antifoaming agent, antifreezing agent, 2min is stirred with the speed of 500rpm
To uniform；
(2) according to formula ratio, titanium dioxide, filler are slowly added to successively in retort A, is stirred with the speed of 1000rpm
30min is shut down, and tests fineness, it is desirable that fineness≤55um；
(3) according to formula ratio, Chinese herbal medicine expelling parasite lotion, levelling agent, with the speed of 800rpm are slowly added in retort A
Initial viscosity is surveyed in stirring 5 minutes, and according to initial viscosity, the thickener that formula ratio is added carries out being thickened to 25 DEG C, stormer viscosity
80-100KU is counted, Chinese herbal medicine insect prevention woodwork coating is made.
Chinese herbal medicine insect prevention woodwork coating is made in embodiment 1 to be detected, it is as follows to obtain table 1：
Chinese herbal medicine insect prevention woodwork coating the performance test results described in 1 embodiment 1 of table
Embodiment 2
The woodwork coating of Chinese herbal medicine insect prevention described in the present embodiment, it is composed of the following components in terms of parts by weight：By such as the following group
It is grouped as：18 parts of deionized water, 0.12 part of cellulose, 0.2 part of pH adjusting agent, 0.2 part of wetting agent, 0.3 part of dispersant, antifoaming agent
0.4 part, 1.2 parts of antifreezing agent, 140 parts of titanium dioxide, 18 parts of filler, 47 parts of Chinese herbal medicine expelling parasite lotion, 0.12 part of coalescents, thickening
0.5 part of agent, 0.5 part of levelling agent.
The thickener is polyacrylate；
The wetting agent is polyoxyethylated alkyl phenol；
The filler is calcined kaolin；
The preparation method of the woodwork coating of Chinese herbal medicine insect prevention described in the present embodiment, includes the following steps：
(1) mass percent described in accordance with the claim 1 weighs above-mentioned substance, and deionized water is added in retort A,
Cellulose, pH adjusting agent, wetting agent, dispersant, antifoaming agent, antifreezing agent are sequentially added with the speed stirring of 150rpm, with
The speed of 600rpm stirs 2min to uniform；
(2) according to formula ratio, titanium dioxide, filler are slowly added to successively in retort A, is stirred with the speed of 1100rpm
30min is shut down, and tests fineness, it is desirable that fineness≤55um；
(3) according to formula ratio, Chinese herbal medicine expelling parasite lotion, levelling agent, with the speed of 1000rpm are slowly added in retort A
Degree stirring 5 minutes, surveys initial viscosity, according to initial viscosity, be added formula ratio thickener be thickened to 25 DEG C, Stormer it is viscous
Degree meter 80-100KU, is made Chinese herbal medicine insect prevention woodwork coating.
Chinese herbal medicine insect prevention woodwork coating coating is made in embodiment 2 to be detected, it is as follows to obtain table 2：
Chinese herbal medicine insect prevention woodwork coating the performance test results described in 2 embodiment 2 of table
Embodiment 3
The woodwork coating of Chinese herbal medicine insect prevention described in the present embodiment, it is composed of the following components in terms of parts by weight：By such as the following group
It is grouped as：29 parts of deionized water, 0.2 part of cellulose, 0.3 part of pH adjusting agent, 0.5 part of wetting agent, 0.4 part of dispersant, antifoaming agent
0.6 part, 1.5 parts of antifreezing agent, 250 parts of titanium dioxide, 24 parts of filler, 60 parts of Chinese herbal medicine expelling parasite lotion, 0.15 part of coalescents, thickening
0.8 part of agent, 0.7 part of levelling agent.
The wetting agent is polyoxyethylene polyoxypropylene block copolymer；
The thickener is the swollen class thickener of alkali soluble；
The filler is powdered whiting.
The preparation method of the woodwork coating of Chinese herbal medicine insect prevention described in the present embodiment, includes the following steps：
(1) mass percent described in accordance with the claim 1 weighs above-mentioned substance, and deionized water is added in retort A,
Cellulose, pH adjusting agent, wetting agent, dispersant, antifoaming agent, antifreezing agent are sequentially added with the speed stirring of 200rpm, with
The speed of 800rpm stirs 2min to uniform；
(2) according to formula ratio, titanium dioxide, filler are slowly added to successively in retort A, is stirred with the speed of 1200rpm
30min is shut down, and tests fineness, it is desirable that fineness≤55um；
(3) according to formula ratio, Chinese herbal medicine expelling parasite lotion, levelling agent, with the speed of 1200rpm are slowly added in retort A
Degree stirring 5 minutes, surveys initial viscosity, according to initial viscosity, be added formula ratio thickener be thickened to 25 DEG C, Stormer it is viscous
Degree meter 80-100KU, is made Chinese herbal medicine insect prevention woodwork coating.
Chinese herbal medicine insect prevention woodwork coating is made in embodiment 3 to be detected, it is as follows to obtain table 3：
Chinese herbal medicine insect prevention woodwork coating the performance test results described in 3 embodiment 3 of table
Comparative example：
In order to illustrate advantageous effect possessed by the present invention, the present invention also provides following comparative examples to carry out further
Explanation.
Comparative example 1：The Chinese herbal medicine expelling parasite lotion implemented in 2 is all removed, remaining component is constant, and coating is prepared
Afterwards, by its be coated on test wooden unit to be tested after, then by its dip-coating in the Chinese herbal medicine expelling parasite lotion certain time, test the survey
The performance indicator for trying wooden unit is as shown in table 4.
Chinese herbal medicine insect prevention woodwork coating the performance test results described in 4 comparative example 1 of table
By table 1, table 2, table 3 it is found that Chinese herbal medicine insect prevention woodwork coating of the present invention, specific Chinese herbal medicine Blumea oil miniemulsion
With the synergistic effect of other components, on the basis of meeting the basic property of conventional woodwork coating, while there are the work(such as expelling parasite
Can, while the active ingredient of Chinese herbal medicine expelling parasite lotion slow release, long-term role in paint film.And table 4 the results show that
After carrying out the solution that surface coats insect prevention medicament to timber, the paint of wood surface decorations effect is a greater impact, paint film appearance by
After the solution of insect prevention medicament impregnates, surface is easy to breakage, and hardness, water resistance, alkaline-resisting, stain resistance also decline, especially anti-
The worm time is shorter, has seriously affected the service life of product.Therefore, the present invention has advantageous effect outstanding.
Obviously, the above embodiments are merely examples for clarifying the description, and does not limit the embodiments.It is right
For those of ordinary skill in the art, can also make on the basis of the above description it is other it is various forms of variation or
It changes.There is no necessity and possibility to exhaust all the enbodiments, and it is extended from this it is obvious variation or
Among changing still in the invention scope of the claims.
Claims (7)
1. a kind of Chinese herbal medicine insect prevention woodwork coating, which is characterized in that composed of the following components in terms of parts by weight：
2. Chinese herbal medicine insect prevention woodwork coating according to claim 1, which is characterized in that in terms of parts by weight, by following components
Composition：
3. Chinese herbal medicine insect prevention woodwork coating according to claim 1 or claim 2, which is characterized in that the Chinese herbal medicine expelling parasite lotion is
Blumea oil miniemulsion.
4. Chinese herbal medicine insect prevention woodwork coating according to claim 3, which is characterized in that the making work of the Blumea oil miniemulsion
Skill includes the following steps：
(1) emulsifier Span-80 and Tween-60 are added in Blumea oil selection phase inversion, and heating stirring at 40 DEG C makes emulsification
Agent is completely dissolved in Blumea oil；
(2) under agitation, to deionized water is added in the step (1) to forming emulsion oil-in-water；
(3) emulsion oil-in-water of preparation is placed in magnetic stirring apparatus, temperature is set as 40 DEG C, is obtained after stirring 30min
The finely dispersed thick lotion of Blumea oil；
(4) the thick lotion of the Blumea oil made is obtained into Blumea oil miniemulsion with high-speed shearing machine in 600 rotating speed down cut 10min；
Wherein in above-mentioned steps, the Span-80, Tween-60, Blumea oil and water the mass ratio of additive amount be 1:3:1:5.
5. according to any Chinese herbal medicine insect prevention woodwork coating of Claims 1 to 4, which is characterized in that the wetting agent is polyoxy
Any one in vinyl alkyl phenolic ether, polyoxyethylene aliphatic alcohol ether or polyoxyethylene polyoxypropylene block copolymer；The increasing
Thick dose of any one to rise for alkali soluble in class thickener or polyacrylate-type thickeners；The cellulose is hydroxy ethyl fiber
Element；The coalescents are alcohol ester 12.
6. according to any Chinese herbal medicine insect prevention woodwork coating of Claims 1 to 5, which is characterized in that the dispersant is poly- third
Enoic acid ammonium salt class dispersant；The antifoaming agent is mineral oil defoaming agent；The titanium dioxide is rutile titanium white powder；The levelling
Agent is polyurethanes levelling agent；The filler is one or more groups in calcined kaolin, diatomite, powdered whiting
It closes.
7. the preparation method of any Chinese herbal medicine insect prevention woodwork coating of claim 1~6, includes the following steps：
(1) above-mentioned substance is weighed according to said ratio, deionized water is added in retort A, is stirred with the speed of 100-200rpm
It mixes and sequentially adds cellulose, pH adjusting agent, wetting agent, dispersant, antifoaming agent, antifreezing agent, stirred with the speed of 500-800rpm
2min is to uniform；
(2) according to formula ratio, titanium dioxide, filler are slowly added to successively in retort A, is stirred with the speed of 1000-1200rpm
30min is shut down, and tests fineness, it is desirable that fineness≤55um；
(3) according to formula ratio, Chinese herbal medicine mosquito repellent lotion, levelling agent, with the speed of 800-1200rpm are slowly added in retort A
Degree stirring 5 minutes, surveys initial viscosity, according to initial viscosity, be added formula ratio thickener be thickened to 25 DEG C, Stormer it is viscous
Degree meter 80-100KU, is made the mosquito-proof woodwork coating of Chinese herbal medicine.
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| CN201810055408.7A CN108359283A (en) | 2018-01-19 | 2018-01-19 | A kind of Chinese herbal medicine insect prevention woodwork coating and preparation method thereof |
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| CN201810055408.7A CN108359283A (en) | 2018-01-19 | 2018-01-19 | A kind of Chinese herbal medicine insect prevention woodwork coating and preparation method thereof |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109337462A (en) * | 2018-09-12 | 2019-02-15 | 河北晨阳工贸集团有限公司 | A kind of antibiotic paint and preparation method thereof |
| CN114085575A (en) * | 2021-11-23 | 2022-02-25 | 江苏久诺新材科技股份有限公司 | Chinese herbal medicine mosquito-repelling children paint soft-light coating and preparation method thereof |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107384198A (en) * | 2017-07-10 | 2017-11-24 | 河北晨阳工贸集团有限公司 | A kind of Chinese herbal medicine mosquito repellent coating and preparation method thereof |
-
2018
- 2018-01-19 CN CN201810055408.7A patent/CN108359283A/en not_active Withdrawn
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107384198A (en) * | 2017-07-10 | 2017-11-24 | 河北晨阳工贸集团有限公司 | A kind of Chinese herbal medicine mosquito repellent coating and preparation method thereof |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109337462A (en) * | 2018-09-12 | 2019-02-15 | 河北晨阳工贸集团有限公司 | A kind of antibiotic paint and preparation method thereof |
| CN114085575A (en) * | 2021-11-23 | 2022-02-25 | 江苏久诺新材科技股份有限公司 | Chinese herbal medicine mosquito-repelling children paint soft-light coating and preparation method thereof |
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