CN108355670B - Preparation method and application of catalyst composition for degrading low-concentration formaldehyde - Google Patents
Preparation method and application of catalyst composition for degrading low-concentration formaldehyde Download PDFInfo
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- CN108355670B CN108355670B CN201711418263.4A CN201711418263A CN108355670B CN 108355670 B CN108355670 B CN 108355670B CN 201711418263 A CN201711418263 A CN 201711418263A CN 108355670 B CN108355670 B CN 108355670B
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- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/889—Manganese, technetium or rhenium
- B01J23/8892—Manganese
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- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
- B01D53/86—Catalytic processes
- B01D53/8668—Removing organic compounds not provided for in B01D53/8603 - B01D53/8665
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- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/002—Mixed oxides other than spinels, e.g. perovskite
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- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/03—Precipitation; Co-precipitation
- B01J37/031—Precipitation
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- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/08—Heat treatment
- B01J37/082—Decomposition and pyrolysis
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- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
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- B01D2257/704—Solvents not covered by groups B01D2257/702 - B01D2257/7027
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/70—Organic compounds not provided for in groups B01D2257/00 - B01D2257/602
- B01D2257/708—Volatile organic compounds V.O.C.'s
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
Abstract
The invention provides a preparation method and application of a catalyst composition for degrading low-concentration formaldehyde. The composite oxide in the catalyst composition is a bismuth antimony copper manganese composite oxide. The method comprises the following steps: 1. dissolving raw materials and alkalifying the solution; 2. adding a potassium persulfate solution; 3. drying; 4. and (4) calcining. The catalyst composition prepared by the invention has high activity, can quickly and efficiently catalyze, oxidize and degrade formaldehyde in wastewater in a short time, can be used for treating wastewater at normal temperature and normal pressure without oxidant and illumination, has the characteristics of simple process flow, no secondary pollution, low operation cost and the like, can be repeatedly used, and has high practical application value.
Description
The technical field is as follows:
the invention relates to the field of inorganic material preparation, in particular to a preparation method and application of a catalyst composition for degrading low-concentration formaldehyde.
Background art:
formaldehyde is readily soluble in water and has a strong pungent odor. It is an important chemical raw material, and can be extensively used in the fields of disinfection, sterilization, anticorrosion, pharmacy, pesticide, dye, plastics and building industry, etc. Formaldehyde, however, is highly toxic and has been identified by the world health organization as a carcinogenic and teratogenic substance. At present, as a method for removing formaldehyde in wastewater, there are an adsorption method, an ozone oxidation method, a photocatalytic method, a thermal wet oxidation method, a biological method, a stripping method, and the like. The adsorption method has poor selectivity and difficult regeneration. Ozone used in the ozone oxidation method is extremely harmful to human health. Photocatalytic treatment requires the use of a specific excitation light source. The titanium dioxide photocatalysts which are most widely used at present can only utilize ultraviolet light. The heat-wet oxidation process is high in energy consumption. The biological method has low treatment cost, but has slow reaction speed and large floor area of treatment facilities. The blow-off method has poor effect.
Catalytic oxidation of formaldehyde at room temperature is an effective way to remove formaldehyde. Has received much attention in recent years. The catalysts of the process all comprise at least one noble metal. Pt/SnO invented by US patent US55850832The catalyst can completely degrade formaldehyde into carbon dioxide and water at room temperature. However, this catalyst contains a noble metal Pt at a mass fraction of 12%. Chinese patent CN103071489A discloses a preparation method of a supported activated carbon catalytic material for removing formaldehyde at room temperature. The catalytic material contains 0.1-2% of precious metal active components of one or the combination of gold, palladium, platinum, rhodium and ruthenium. Chinese patent CN102139234A discloses a supported catalyst for removing formaldehyde at room temperature. The active component is one or more noble metals of gold, palladium, platinum, rhodium and ruthenium. The content of the noble metal accounts for 0.1-2% of the weight of the catalyst. The precious metal resources are rare and the price is high, which limits the popularization and application of catalytic oxidation for removing formaldehyde in the greenhouse.
The invention content is as follows:
the invention aims to provide a preparation method and application of a catalyst composition for degrading low-concentration formaldehyde. In view of the above, the present invention is designed to solve the above technical problems in the prior art, and provide a preparation method and application of a catalyst composition for simply and effectively treating formaldehyde in wastewater.
In order to achieve the purpose, the technical scheme of the invention is as follows:
the catalyst composition for degrading the low-concentration formaldehyde comprises a composite oxide, wherein the composite oxide in the catalyst composition is a bismuth antimony copper manganese composite oxide, and the bismuth antimony copper manganese composite oxide serving as a catalyst can catalyze, oxidize and degrade the formaldehyde in the wastewater.
A preparation method of a catalyst composition for degrading low-concentration formaldehyde comprises the following steps:
1. raw material dissolution and solution alkalization: taking bismuth nitrate, antimony trichloride, copper nitrate and manganese nitrate as raw materials, adding deionized water into a beaker, stirring until the deionized water is dissolved, and then dropwise adding ammonia water with the concentration of 6mol/L until the solution is alkalescent, wherein the pH value is 8-10;
2. adding a potassium persulfate solution: adding 5mL of potassium persulfate solution with the volume percentage concentration of 5% into the alkalescent solution obtained in the step 1, heating to boil, cooling to room temperature, and then carrying out suction filtration;
3. drying: putting the precipitate obtained in the step 2 into an oven to be dried at the temperature of 105-150 ℃;
4. and (3) calcining: and (4) putting the dried precipitate obtained in the step (3) into a muffle furnace, calcining for 3-8 hours at the temperature of 300-900 ℃, and calcining to obtain the bismuth antimony copper manganese composite oxide powder.
In the method, the molar ratio of bismuth nitrate to antimony trichloride to copper nitrate to manganese nitrate is 22.6:16.9: 8.9:1.0.
The application of the catalyst composition for degrading low-concentration formaldehyde is characterized in that the obtained bismuth-antimony-copper-manganese composite oxide is added into wastewater according to the proportion of 0.5-4.0 g/L, and stirring treatment is carried out for 30-60 minutes at normal temperature and normal pressure.
The invention relates to a method for treating formaldehyde wastewater by applying a bismuth-antimony-copper-manganese composite oxide catalyst, which comprises the following steps: taking the composite oxide as a catalyst, and the degradation reaction conditions are as follows: the concentration of formaldehyde is less than 5%, the dosage of a catalyst for treating formaldehyde wastewater per liter is 0.5-4.0 g, and a wastewater system is at normal temperature and normal pressure. In the test, when the volume of the formaldehyde wastewater is 40mL and the concentration is 1.0%, 0.1g of the catalyst is added under stirring, the catalytic degradation is carried out for 30 minutes, and the degradation rate of the formaldehyde reaches more than 90%. And replacing the residual solution with a new formaldehyde solution and then recycling the catalyst. The result shows that the degradation rate of formaldehyde of the catalyst in the second circulation and the third circulation reaches more than 90.0 percent.
The invention has the positive effects that
1. The catalyst composition used in the invention has simple preparation method, low cost of raw materials and convenient operation;
2. the catalyst composition prepared and treated by the method has high activity, and can quickly and efficiently degrade pollutants in a short time;
3. the wastewater treatment method can be carried out at normal temperature and normal pressure without oxidant or illumination, has the characteristics of simple process flow, no secondary pollution, low operation cost and the like, and has high practical application value;
4. the catalyst composition prepared and treated by the method can be repeatedly used for many times.
Detailed Description
The technical solution of the present invention is further clearly and completely described below with reference to the following examples.
Example 1:
1. raw material dissolution and solution alkalization: weighing 1.82g (5.04X 10)-3mol) bismuth nitrate pentahydrate, 0.86g (3.77X 10)-3mol) antimony trichloride, 0.48g (1.99X 10)-3mol) copper nitrate trihydrate and 0.08g (2.23X 10)-4mol) manganese nitrate (50% solution), adding deionized water into a beaker, stirring until the solution is completely dissolved, and then dropwise adding ammonia water with the concentration of 6mol/L until the solution is alkalescent, wherein the pH value is 8-10;
2. adding a potassium persulfate solution: adding 5mL of potassium persulfate with the volume percentage concentration of 5% into the alkalescent solution obtained in the step 1, heating to boil, cooling to room temperature, and then carrying out suction filtration;
3. drying: putting the precipitate obtained in the step 2 into an oven to be dried at the temperature of 105-150 ℃;
4. and (3) calcining: and (4) putting the dried precipitate obtained in the step (3) into a muffle furnace, and calcining for 8 hours at 300 ℃ to obtain bismuth antimony copper manganese composite oxide powder.
0.1g of the bismuth antimony copper manganese composite oxide catalyst prepared by the method is added into formaldehyde wastewater with the volume of 40mL and the concentration of 1.0%, and formaldehyde is catalytically degraded for 30 minutes under the stirring action at normal temperature and pressure. The mixture was then centrifuged in a centrifuge for 10 minutes, and the supernatant was taken to measure the residual concentration of formaldehyde. As a result, as shown in Table 1, the formaldehyde degradation rate was 90.0% when the degradation time was 30 minutes.
TABLE 1 degradation time and degradation rate of Formaldehyde in wastewater
| Catalyst degradation time/min | 15 | 30 | 45 | 60 |
| Formaldehyde reducing agentRate of solution/%) | 85.6 | 90.0 | 91.3 | 92.0 |
Example 2
1. Raw material dissolution and solution alkalization: weighing 1.82g (5.04X 10)-3mol) bismuth nitrate pentahydrate, 0.86g (3.77X 10)-3mol) antimony trichloride, 0.48g (1.99X 10)-3mol) copper nitrate trihydrate and 0.08g (2.23X 10)-4mol) manganese nitrate (50% solution), adding deionized water into a beaker, stirring until the solution is completely dissolved, and then dropwise adding ammonia water with the concentration of 6mol/L until the solution is alkalescent, wherein the pH value is 8-10;
2. adding a potassium persulfate solution: adding 5mL of potassium persulfate with the volume percentage concentration of 5% into the alkalescent solution obtained in the step 1, heating to boil, cooling to room temperature, and then carrying out suction filtration;
3. drying: putting the precipitate obtained in the step 2 into an oven to be dried at the temperature of 105-150 ℃;
4. and (3) calcining, namely putting the dried precipitate obtained in the step (3) into a muffle furnace, and calcining for 5 hours at 750 ℃ to obtain bismuth antimony copper manganese composite oxide powder.
0.1g of the bismuth antimony copper manganese composite oxide catalyst prepared by the method is added into formaldehyde wastewater with the volume of 40mL and the concentration of 1.0%, and formaldehyde is catalytically degraded for 30 minutes under the stirring action at normal temperature and pressure. The mixture was then centrifuged in a centrifuge for 10 minutes, and the supernatant was taken to measure the residual concentration of formaldehyde. When the degradation time is 30 minutes, the formaldehyde degradation rate is 92.2%.
Example 3
1. Raw material dissolution and solution alkalization: weighing 1.82g (5.04X 10)-3mol) bismuth nitrate pentahydrate, 0.86g (3.77X 10)-3mol) antimony trichloride, 0.48g (1.99X 10)-3mol) copper nitrate trihydrate and 0.08g (2.23X 10)-4mol) manganese nitrate (50% solution), deionized water was added to the beakerStirring until the mixture is completely dissolved, and then dropwise adding ammonia water with the concentration of 6mol/L until the solution is alkalescent, wherein the pH value is 8-10;
2. adding a potassium persulfate solution: adding 5mL of potassium persulfate with the volume percentage concentration of 5% into the alkalescent solution obtained in the step 1, heating to boil, cooling to room temperature, and then carrying out suction filtration;
3. drying: putting the precipitate obtained in the step 2 into an oven to be dried at the temperature of 105-150 ℃;
4. and (3) calcining: and (4) putting the dried precipitate obtained in the step (3) into a muffle furnace, and calcining at 900 ℃ to obtain bismuth antimony copper manganese composite oxide powder.
0.1g of the bismuth antimony copper manganese composite oxide catalyst prepared by the method is added into formaldehyde wastewater with the volume of 40mL and the concentration of 1.0%, and formaldehyde is catalytically degraded for 30 minutes under the stirring action at normal temperature and pressure. The mixture was then centrifuged in a centrifuge for 10 minutes, and the supernatant was taken to measure the residual concentration of formaldehyde. When the degradation time is 30 minutes, the formaldehyde degradation rate is 92.8%.
Example 4
In order to examine the recycling condition of the catalyst, the bismuth antimony copper manganese composite oxide obtained by the preparation method of the catalyst described in the embodiment 2 is subjected to three continuous catalytic oxidation degradation tests on formaldehyde, and the degradation time is 30 minutes each time.
0.10g of bismuth-antimony-copper-manganese oxide catalyst is added into a beaker containing 40mL of 1.0% formaldehyde solution, and formaldehyde is catalytically degraded under the action of stirring at normal temperature and pressure for 30 minutes under the action of magnetic stirring. The mixture was then centrifuged in a centrifuge for 10 minutes, and the supernatant was taken to measure the residual concentration of formaldehyde. The centrifuged supernatant was aspirated with a dropper to leave only the catalyst solid, 40mL of a new 1.0% formaldehyde solution was added, and the above formaldehyde degradation process was repeated, so that the second cycle and the third cycle of formaldehyde degradation tests were performed, and the results are shown in Table 2.
TABLE 2 catalyst Cyclic degradation of Formaldehyde
| Number of times of catalyst use | 1 | 2 | 3 |
| Percent formaldehyde degradation/%) | 92.2 | 91.0 | 90.3 |
As can be seen from Table 2, the degradation rate of the catalyst for degrading formaldehyde in three cycles is over 90.0%, which shows that the bismuth antimony copper manganese composite oxide catalyst can be recycled.
All of the features disclosed in this specification, or all of the methods of manufacture and uses disclosed, may be combined in any combination, except combinations and/or steps, or uses thereof, which are mutually exclusive. Any feature disclosed in this specification (including any accompanying claims and abstract) may be replaced by alternative features serving equivalent or similar purposes, unless expressly stated otherwise. That is, unless expressly stated otherwise, each feature is only an example of a generic series of equivalent or similar features.
The above description is only a non-limiting embodiment of the invention, and many embodiments can be derived, and those skilled in the art can make several modifications and improvements without departing from the inventive concept and without making creative efforts, which all belong to the protection scope of the present invention.
Claims (2)
1. A preparation method of a catalyst composition for degrading low-concentration formaldehyde is characterized by comprising the following steps: the method comprises the following steps:
(1) raw material dissolution and solution alkalization: taking bismuth nitrate, antimony trichloride, copper nitrate and manganese nitrate as raw materials, adding deionized water into a beaker, stirring until the bismuth nitrate, the antimony trichloride, the copper nitrate and the manganese nitrate are dissolved, and then dropwise adding ammonia water with the concentration of 6mol/L until the solution is alkalescent, wherein the molar ratio of the bismuth nitrate to the antimony trichloride to the copper nitrate to the manganese nitrate is 22.6:16.9:8.9:1.0, and the pH value is 8-10;
(2) adding a potassium persulfate solution: adding 5mL of potassium persulfate solution with the volume percentage concentration of 5% into the weak alkaline solution obtained in the step (1), heating to boil, cooling to room temperature, and performing suction filtration;
(3) drying: putting the precipitate obtained in the step (2) into an oven to be dried at the temperature of 105-150 ℃;
(4) and (3) calcining: and (4) putting the dried precipitate obtained in the step (3) into a muffle furnace, calcining for 3-8 hours at the temperature of 300-900 ℃, and calcining to obtain the bismuth antimony copper manganese composite oxide powder.
2. The use of a catalyst composition for degrading low concentrations of formaldehyde prepared according to the process of claim 1, wherein: adding the obtained bismuth-antimony-copper-manganese composite oxide into formaldehyde wastewater according to the proportion of 0.5-4.0 g/L, and stirring at normal temperature and normal pressure for 30-60 minutes.
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Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102139234A (en) * | 2011-01-06 | 2011-08-03 | 梁耀彰 | Loaded reduced precious metal catalyst as well as preparation method and application thereof |
| CN103071489A (en) * | 2011-10-25 | 2013-05-01 | 上海纳米技术及应用国家工程研究中心有限公司 | Supported active carbon catalytic material capable of eliminating formaldehyde at room temperature and preparation method thereof |
| CN106238065A (en) * | 2016-07-08 | 2016-12-21 | 宁波钛安新材料科技有限公司 | A kind of composite catalyst being catalyzed Formaldehyde decomposition and preparation method thereof |
| CN106622260A (en) * | 2016-12-09 | 2017-05-10 | 湖北工业大学 | Preparation method and application of catalyst for treating low-concentration formaldehyde wastewater |
| CN106824172A (en) * | 2016-12-09 | 2017-06-13 | 湖北工业大学 | The carbon monoxide-olefin polymeric preparation method and application of low concentration formaldehyde in treatment waste water |
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- 2017-12-25 CN CN201711418263.4A patent/CN108355670B/en not_active Expired - Fee Related
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102139234A (en) * | 2011-01-06 | 2011-08-03 | 梁耀彰 | Loaded reduced precious metal catalyst as well as preparation method and application thereof |
| CN103071489A (en) * | 2011-10-25 | 2013-05-01 | 上海纳米技术及应用国家工程研究中心有限公司 | Supported active carbon catalytic material capable of eliminating formaldehyde at room temperature and preparation method thereof |
| CN106238065A (en) * | 2016-07-08 | 2016-12-21 | 宁波钛安新材料科技有限公司 | A kind of composite catalyst being catalyzed Formaldehyde decomposition and preparation method thereof |
| CN106622260A (en) * | 2016-12-09 | 2017-05-10 | 湖北工业大学 | Preparation method and application of catalyst for treating low-concentration formaldehyde wastewater |
| CN106824172A (en) * | 2016-12-09 | 2017-06-13 | 湖北工业大学 | The carbon monoxide-olefin polymeric preparation method and application of low concentration formaldehyde in treatment waste water |
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