CN108355615A - 一种离子液体改性的玉米芯基材料的制备方法及其在降解土壤农药残留中的应用 - Google Patents
一种离子液体改性的玉米芯基材料的制备方法及其在降解土壤农药残留中的应用 Download PDFInfo
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- CN108355615A CN108355615A CN201810202402.8A CN201810202402A CN108355615A CN 108355615 A CN108355615 A CN 108355615A CN 201810202402 A CN201810202402 A CN 201810202402A CN 108355615 A CN108355615 A CN 108355615A
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- corncob
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- 238000002360 preparation method Methods 0.000 title claims abstract description 11
- 239000007788 liquid Substances 0.000 title claims abstract description 9
- 239000002689 soil Substances 0.000 title abstract description 15
- 230000000593 degrading effect Effects 0.000 title abstract description 4
- 239000000463 material Substances 0.000 claims abstract description 22
- 239000002608 ionic liquid Substances 0.000 claims abstract description 10
- 239000000447 pesticide residue Substances 0.000 claims abstract description 8
- 150000002500 ions Chemical class 0.000 claims abstract description 7
- 239000003993 organochlorine pesticide Substances 0.000 claims abstract description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 21
- 238000004321 preservation Methods 0.000 claims description 16
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 14
- 230000008030 elimination Effects 0.000 claims description 10
- 238000003379 elimination reaction Methods 0.000 claims description 10
- 238000001035 drying Methods 0.000 claims description 8
- 239000012535 impurity Substances 0.000 claims description 8
- 238000010792 warming Methods 0.000 claims description 8
- 238000002156 mixing Methods 0.000 claims description 7
- 229910052757 nitrogen Inorganic materials 0.000 claims description 7
- 239000002244 precipitate Substances 0.000 claims description 7
- PBIDWHVVZCGMAR-UHFFFAOYSA-N 1-methyl-3-prop-2-enyl-2h-imidazole Chemical compound CN1CN(CC=C)C=C1 PBIDWHVVZCGMAR-UHFFFAOYSA-N 0.000 claims description 5
- -1 1- allyl -3- methylimidazole halogens Chemical class 0.000 claims description 3
- CVXBEEMKQHEXEN-UHFFFAOYSA-N carbaryl Chemical compound C1=CC=C2C(OC(=O)NC)=CC=CC2=C1 CVXBEEMKQHEXEN-UHFFFAOYSA-N 0.000 claims description 3
- 229910052736 halogen Inorganic materials 0.000 claims description 3
- 239000011261 inert gas Substances 0.000 claims description 3
- VOEYXMAFNDNNED-UHFFFAOYSA-N metolcarb Chemical compound CNC(=O)OC1=CC=CC(C)=C1 VOEYXMAFNDNNED-UHFFFAOYSA-N 0.000 claims description 3
- LCCNCVORNKJIRZ-UHFFFAOYSA-N parathion Chemical compound CCOP(=S)(OCC)OC1=CC=C([N+]([O-])=O)C=C1 LCCNCVORNKJIRZ-UHFFFAOYSA-N 0.000 claims description 3
- 239000000126 substance Substances 0.000 claims description 3
- KXDHJXZQYSOELW-UHFFFAOYSA-M Carbamate Chemical compound NC([O-])=O KXDHJXZQYSOELW-UHFFFAOYSA-M 0.000 claims description 2
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims description 2
- 239000003814 drug Substances 0.000 claims description 2
- 239000000575 pesticide Substances 0.000 claims description 2
- 231100000572 poisoning Toxicity 0.000 claims description 2
- 230000000607 poisoning effect Effects 0.000 claims description 2
- 239000002253 acid Substances 0.000 claims 2
- 150000004657 carbamic acid derivatives Chemical class 0.000 claims 1
- 238000002242 deionisation method Methods 0.000 claims 1
- KOUKXHPPRFNWPP-UHFFFAOYSA-N pyrazine-2,5-dicarboxylic acid;hydrate Chemical compound O.OC(=O)C1=CN=C(C(O)=O)C=N1 KOUKXHPPRFNWPP-UHFFFAOYSA-N 0.000 abstract description 8
- 240000008042 Zea mays Species 0.000 abstract description 5
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 abstract description 5
- 235000002017 Zea mays subsp mays Nutrition 0.000 abstract description 5
- 235000005822 corn Nutrition 0.000 abstract description 5
- 238000005067 remediation Methods 0.000 abstract description 3
- 239000003795 chemical substances by application Substances 0.000 abstract description 2
- 230000002000 scavenging effect Effects 0.000 abstract description 2
- 239000000152 carbamate pesticide Substances 0.000 abstract 1
- 239000000047 product Substances 0.000 description 17
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 9
- 229910001385 heavy metal Inorganic materials 0.000 description 9
- 239000008367 deionised water Substances 0.000 description 6
- 229910021641 deionized water Inorganic materials 0.000 description 6
- 239000011651 chromium Substances 0.000 description 5
- 238000002474 experimental method Methods 0.000 description 5
- 238000001556 precipitation Methods 0.000 description 5
- 239000005416 organic matter Substances 0.000 description 3
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 239000006227 byproduct Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000001914 filtration Methods 0.000 description 2
- 125000000524 functional group Chemical group 0.000 description 2
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- 229910052786 argon Inorganic materials 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- ZBJBRUSGEJORQL-UHFFFAOYSA-N diphenan Chemical compound C1=CC(OC(=O)N)=CC=C1CC1=CC=CC=C1 ZBJBRUSGEJORQL-UHFFFAOYSA-N 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 238000005342 ion exchange Methods 0.000 description 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 239000012086 standard solution Substances 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/22—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising organic material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B09—DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
- B09C—RECLAMATION OF CONTAMINATED SOIL
- B09C1/00—Reclamation of contaminated soil
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/28—Treatment of water, waste water, or sewage by sorption
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/28—Treatment of water, waste water, or sewage by sorption
- C02F1/286—Treatment of water, waste water, or sewage by sorption using natural organic sorbents or derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/10—Inorganic compounds
- C02F2101/20—Heavy metals or heavy metal compounds
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/30—Organic compounds
- C02F2101/306—Pesticides
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/30—Organic compounds
- C02F2101/36—Organic compounds containing halogen
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/30—Organic compounds
- C02F2101/38—Organic compounds containing nitrogen
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Environmental & Geological Engineering (AREA)
- Organic Chemistry (AREA)
- Hydrology & Water Resources (AREA)
- Water Supply & Treatment (AREA)
- Soil Sciences (AREA)
- Analytical Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Processing Of Solid Wastes (AREA)
Abstract
Description
Claims (7)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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CN201810202402.8A CN108355615B (zh) | 2018-03-10 | 2018-03-10 | 一种离子液体改性的玉米芯基材料的制备方法及其在降解土壤农药残留中的应用 |
Applications Claiming Priority (1)
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CN201810202402.8A CN108355615B (zh) | 2018-03-10 | 2018-03-10 | 一种离子液体改性的玉米芯基材料的制备方法及其在降解土壤农药残留中的应用 |
Publications (2)
Publication Number | Publication Date |
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CN108355615A true CN108355615A (zh) | 2018-08-03 |
CN108355615B CN108355615B (zh) | 2020-12-25 |
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CN201810202402.8A Expired - Fee Related CN108355615B (zh) | 2018-03-10 | 2018-03-10 | 一种离子液体改性的玉米芯基材料的制备方法及其在降解土壤农药残留中的应用 |
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109225172A (zh) * | 2018-10-08 | 2019-01-18 | 长安大学 | 一种麦田土壤中碳酸镉吸附材料、制备及应用 |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106955666A (zh) * | 2017-03-30 | 2017-07-18 | 黑龙江大学 | 一种用农林废弃物制备生物质磁性碳微球的方法 |
CN107098426A (zh) * | 2017-05-18 | 2017-08-29 | 付主枝 | 一种低碳环保降解染料废水的方法 |
CN107459992A (zh) * | 2017-08-11 | 2017-12-12 | 中南大学 | 硫基‑巯基改性生物炭的制备方法及改性生物炭 |
-
2018
- 2018-03-10 CN CN201810202402.8A patent/CN108355615B/zh not_active Expired - Fee Related
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106955666A (zh) * | 2017-03-30 | 2017-07-18 | 黑龙江大学 | 一种用农林废弃物制备生物质磁性碳微球的方法 |
CN107098426A (zh) * | 2017-05-18 | 2017-08-29 | 付主枝 | 一种低碳环保降解染料废水的方法 |
CN107459992A (zh) * | 2017-08-11 | 2017-12-12 | 中南大学 | 硫基‑巯基改性生物炭的制备方法及改性生物炭 |
Non-Patent Citations (4)
Title |
---|
应博等: ""玉米芯生物炭对2,4-D 在土壤中吸附性能的研究"", 《环境科学学报》 * |
景明: ""生物炭对土壤中六价铬和莠去津的吸附锁定作用研究"", 《中国优秀硕士学位论文全文数据库 工程科技Ⅰ辑》 * |
沈雁等: ""经离子液体水溶液预处理玉米芯对亚甲基蓝吸附性能的研究"", 《安徽科技学院学报》 * |
王静等: ""响应面法优化巯基纤维素膜去除Cr6+的吸附条件"", 《环境科学与技术》 * |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109225172A (zh) * | 2018-10-08 | 2019-01-18 | 长安大学 | 一种麦田土壤中碳酸镉吸附材料、制备及应用 |
CN109225172B (zh) * | 2018-10-08 | 2021-05-18 | 长安大学 | 一种麦田土壤中碳酸镉吸附材料、制备及应用 |
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CN108355615B (zh) | 2020-12-25 |
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GR01 | Patent grant | ||
GR01 | Patent grant | ||
CB03 | Change of inventor or designer information |
Inventor after: Chen Huajin Inventor after: Duan Chenggang Inventor after: Li Jie Inventor after: Zou Shusheng Inventor before: Chen Huajin Inventor before: Duan Chenggang |
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CB03 | Change of inventor or designer information | ||
TR01 | Transfer of patent right |
Effective date of registration: 20210402 Address after: 516000 No. 1206, traditional Chinese medicine incubator, xitianyitang, Luofu Avenue, Pufu village committee, Changning Town, BOLUO County, Huizhou City, Guangdong Province Patentee after: Guangdong Tianyitang Agricultural Technology Co.,Ltd. Address before: 225127 No. 199, Yang Hua Xi Road, Yangzhou, Jiangsu Patentee before: YANGZHOU POLYTECHNIC INSTITUTE |
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CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20201225 |
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CF01 | Termination of patent right due to non-payment of annual fee |