CN108344082A - A kind of air-conditioning and detection method of Applied Electrochemistry compressor - Google Patents

A kind of air-conditioning and detection method of Applied Electrochemistry compressor Download PDF

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Publication number
CN108344082A
CN108344082A CN201710054899.9A CN201710054899A CN108344082A CN 108344082 A CN108344082 A CN 108344082A CN 201710054899 A CN201710054899 A CN 201710054899A CN 108344082 A CN108344082 A CN 108344082A
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China
Prior art keywords
metal hydride
air
inert gas
flow
conditioning
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CN201710054899.9A
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CN108344082B (en
Inventor
王美术
朱百发
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Qingdao Haier Air Conditioner Gen Corp Ltd
Haier Smart Home Co Ltd
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Qingdao Haier Air Conditioner Gen Corp Ltd
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    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F24HEATING; RANGES; VENTILATING
    • F24FAIR-CONDITIONING; AIR-HUMIDIFICATION; VENTILATION; USE OF AIR CURRENTS FOR SCREENING
    • F24F5/00Air-conditioning systems or apparatus not covered by F24F1/00 or F24F3/00, e.g. using solar heat or combined with household units such as an oven or water heater
    • F24F5/0007Air-conditioning systems or apparatus not covered by F24F1/00 or F24F3/00, e.g. using solar heat or combined with household units such as an oven or water heater cooling apparatus specially adapted for use in air-conditioning
    • F24F5/001Compression cycle type
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F24HEATING; RANGES; VENTILATING
    • F24FAIR-CONDITIONING; AIR-HUMIDIFICATION; VENTILATION; USE OF AIR CURRENTS FOR SCREENING
    • F24F13/00Details common to, or for air-conditioning, air-humidification, ventilation or use of air currents for screening
    • F24F13/30Arrangement or mounting of heat-exchangers

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Sustainable Development (AREA)
  • Fuel Cell (AREA)
  • Measuring Volume Flow (AREA)

Abstract

The invention discloses a kind of air-conditioning of Applied Electrochemistry compressor, detection method and device, belong to air-conditioning technical field.Air-conditioning includes electrochemical compressor, at least two metal hydride heat exchangers, and air-conditioning further includes:Air accumulator, is filled with inert gas, and each metal hydride heat exchanger is connected with an individual air accumulator;Flowmeter is provided with individual flowmeter on the connecting line between each air accumulator and corresponding metal hydride heat exchanger;Controller, the flow for obtaining the inert gas that flowmeter detects, and determine according to flow the dusting degree of the metal hydride in metal hydride heat exchanger.The gas filling device there are one inert gas is arranged in the air-conditioning of the present invention in its hydrogen circulation line, inert gas can be filled in metal hydride heat exchanger, flow of the air-conditioning using front and back be filled with inert gas is filled by comparing, the variation of spatial volume in metal hydride can be obtained, and then can determine the dusting degree of metal hydride.

Description

A kind of air-conditioning and detection method of Applied Electrochemistry compressor
Technical field
The present invention relates to air-conditioning technical field, the air-conditioning more particularly to a kind of Applied Electrochemistry compressor and detection side Method.
Background technology
Currently, electrochemical compressor technology has begun gradually to be applied to air-conditioning technical field, the original of electrochemical compressor Reason is:It is operated by making proton be placed through the amberplex among two gas-diffusion electrodes with pump, these proton meetings Non- fluorinated refrigerant is driven to pass through amberplex;Behind the other side that refrigerant reaches film, it can be discharged with high pressure, be followed into refrigeration In loop system.Using and being filled out metal hydride using hydrogen as refrigerant Be charged in heat exchanger, metal hydride, which has, to be inhaled hydrogen heat release and hydrogen release and inhales thermal property, in the suction hydrogen of metal hydride or The air flowed through is heated up or cooled down during hydrogen release.
Hydrogen enters absorbed by metal hydride after, since it is stored in the molecular structure of metal hydride, meeting The crystal structure of metal hydride is caused to increase, and in hydrogen release, hydrogen atoms are detached from metal hydride so that metal hydride Crystal structure reduce again, repeatedly carry out inhaling hydrogen and hydrogen release after, the problem of metal hydride is susceptible to dusting, close Bronze will increase packing density, and container local pressure is made because of expansion, lead to hydrogen gas leakage or reduce heat transfer efficiency etc..Cause This, electrochemical compression air conditioner needs the dusting degree for being accurately obtained metal hydride, so as to right after prolonged work The excessively high metal hydride of dusting degree is replaced or is refilled.
Invention content
The invention discloses a kind of air-conditionings and detection method of Applied Electrochemistry compressor, it is intended in accurate detection heat exchanger Metal hydride dusting degree.In order to the embodiment to disclosure some aspects there are one basic understanding, be given below Simple summary.The summarized section is not extensive overview, nor to determine key/critical component or describe these realities Apply the protection domain of example.Its sole purpose is that some concepts are presented with simple form, in this, as following detailed description Preamble.
According to the first aspect of the invention, a kind of air-conditioning of Applied Electrochemistry compressor is provided, air-conditioning includes electrification Compressor, at least two metal hydride heat exchangers are learned, electrochemical compressor is respectively communicated with metal hydride by hydrogen feeding pipe road Heat exchanger, metal hydride heat exchanger further include with the chamber filled with metal hydride, air-conditioning:Air accumulator is filled with lazy Property gas, each metal hydride heat exchanger are connected with an individual air accumulator;Flowmeter, each air accumulator and corresponding metal The individual flowmeter is provided on connecting line between hydride heat exchanger;Controller, for obtaining flowmeter detection The flow of obtained inert gas, and determine according to flow the dusting degree of the metal hydride in metal hydride heat exchanger.
Further, controller determines the dusting degree of the metal hydride in metal hydride heat exchanger according to flow, Including:The initial residual volume of chamber is obtained, initial residual volume is the remaining appearance determined according to the initial flow of inert gas Product;According to flow, the residual volume of chamber is determined;Determine the volume difference of residual volume and initial residual volume;Determine volume The dusting degree of metal hydride corresponding to difference.
Further, chamber is provided with pressure sensor;Controller obtains the stream for the inert gas that flowmeter detects Amount, including:Obtain the corresponding initial pressure of initial residual volume;It obtains air accumulator and is filled with indifferent gas to the chamber of metal hydride Pressure when body, when pressure reaches initial pressure, stopping is filled with inert gas, and obtains the indifferent gas that flowmeter detects The flow of body.
Further, chamber has top port and bottom port, wherein hydrogen feeding pipe road is connected to top port, air accumulator It is connected to bottom port.
Further, air-conditioning further includes the air supply tank for being connected to hydrogen feeding pipe road, and hydrogen is filled in air supply tank.
According to the second aspect of the invention, it additionally provides a kind of for detecting the metal hydride dusting degree of air-conditioning Method, including:Obtain the flow for the inert gas that flowmeter detects;According to flow, determine in metal hydride heat exchanger Metal hydride dusting degree.
Further, according to flow, the dusting degree of the metal hydride in metal hydride heat exchanger is determined, including: The initial residual volume of chamber is obtained, initial residual volume is the residual volume determined according to the initial flow of inert gas;Root According to flow, the residual volume of chamber is determined;Determine the volume difference of residual volume and initial residual volume;According to preset volume The incidence relation of difference and metal hydride dusting degree determines the dusting degree of the metal hydride corresponding to volume difference.
Further, the flow for the inert gas that flowmeter detects is obtained, including:Initial residual volume is obtained to correspond to Initial pressure;Pressure when detection air accumulator is filled with from inert gas to the chamber of metal hydride, reaches initial pressure in pressure When power, stopping is filled with inert gas, and obtains the flow for the inert gas that flowmeter detects.
The gas filling device there are one inert gas is arranged in the air-conditioning of the present invention in its hydrogen circulation line, can incite somebody to action Inert gas is filled in metal hydride heat exchanger, fills flow of the air-conditioning using front and back be filled with inert gas by comparing, The variation of spatial volume in metal hydride can be obtained, and then can determine the dusting degree of metal hydride.
It should be understood that above general description and following detailed description is only exemplary and explanatory, not It can the limitation present invention.
Description of the drawings
The drawings herein are incorporated into the specification and forms part of this specification, and shows the implementation for meeting the present invention Example, and be used to explain the principle of the present invention together with specification.
Fig. 1 is the structural schematic diagram of the air-conditioning of the present invention shown by an exemplary embodiment;
Fig. 2 is the flow chart of the detection method shown by an exemplary embodiment.
Specific implementation mode
The following description and drawings fully show specific embodiments of the present invention, to enable those skilled in the art to Put into practice them.Other embodiments may include structure, logic, it is electrical, process and other change.Embodiment Only represent possible variation.Unless explicitly requested, otherwise individual components and functionality is optional, and the sequence operated can be with Variation.The part of some embodiments and feature can be included in or replace part and the feature of other embodiments.This hair The range of bright embodiment includes equivalent obtained by the entire scope of claims and all of claims Object.Herein, each embodiment individually or can be indicated generally with term " invention ", and it is convenient that this is used for the purpose of, And if in fact disclosing the invention more than one, it is not meant to automatically limit ranging from any single invention of the application Or inventive concept.Herein, relational terms such as first and second and the like be used only for by an entity or operation with Another entity or operation distinguish, and without requiring or implying, there are any actual relationships between these entities or operation Or sequence.Moreover, the terms "include", "comprise" or any other variant thereof is intended to cover non-exclusive inclusion, to So that the process, method or equipment that include a series of elements include not only those elements, but also include being not explicitly listed Other element, or further include for this process, method or the intrinsic element of equipment.In the feelings not limited more Under condition, the element that is limited by sentence "including a ...", it is not excluded that in process, method or equipment including the element In there is also other identical elements.Each embodiment herein is described by the way of progressive, and each embodiment stresses Be all difference from other examples, just to refer each other for identical similar portion between each embodiment.For implementing For method, product etc. disclosed in example, since it is corresponding with method part disclosed in embodiment, so the comparison of description is simple Single, reference may be made to the description of the method.
As shown in Figure 1, the present invention provides a kind of air-conditioning of Applied Electrochemistry compressor, air-conditioning includes electrochemical compressor 1, at least two metal hydride heat exchanger 2, electrochemical compressor 1 are respectively communicated with metal hydride heat exchanger by hydrogen feeding pipe road 2, metal hydride heat exchanger 2 has the chamber filled with metal hydride;Air-conditioning further includes:Air accumulator 3, is filled with indifferent gas Body, each metal hydride heat exchanger 2 are connected with an individual air accumulator 3;Flowmeter 4, each air accumulator 3 and corresponding metal Individual flowmeter 4 is provided on connecting line between hydride heat exchanger 2;Controller is detected for obtaining flowmeter 4 The flow of the inert gas arrived, and determine according to flow the dusting degree of the metal hydride in metal hydride heat exchanger 2.This Invention can accurately determine the volume change of metal hydride according to the flow of inert gas, and then obtain the reality of metal hydride Dusting degree situation in border is effectively guaranteed convenient for the excessively high metal hydride of dusting degree is replaced or refilled The heat exchange efficiency of air-conditioning reduces the problems such as excessive caused stress of localized metallic hydride powder density expands.
Operation principle of the present invention is:After absorbing hydrogen repeatedly, crystal structure goes to pot metal hydride, and density increases Greatly, whole the space occupied volume is reduced, therefore the amount of the inert gas poured in metal hydride heat exchanger 2 can reflect The remaining space capacity of chamber can obtain the occupied space of metal hydride by comparing the variation of remaining space capacity The situation of change of volume, that is, the reduction amount that volume is occupied after the incrementss for the inert gas being filled with, with metal hydride dusting are big Cause it is identical, thus may determine that the dusting degree of metal hydride.
In one embodiment of the invention, controller determines the metallic hydrogen in metal hydride heat exchanger 2 according to flow The dusting degree of compound, detailed process include:The initial residual volume of chamber is obtained, initial residual volume is to dispatch from the factory in air-conditioning Before, according to the residual volume that the initial flow of inert gas determines, since air-conditioning not yet uses before air-conditioning manufacture, metal hydride Dusting degree it is relatively low, therefore the present invention dispatched from the factory using air-conditioning before initial residual volume as measuring basis;According to flow, determine The residual volume of chamber;Determine the volume difference of residual volume and initial residual volume;According to preset volume difference and metal The incidence relation of hydride dusting degree determines the dusting degree of the metal hydride corresponding to volume difference.
In an embodiment of the present invention, it to improve measurement accuracy, reduces inert gas and generates flow error because of compression, originally Invention is also provided with pressure sensor in the chamber of metal hydride;Flowmeter 4, which is obtained, in controller detects obtained inertia In the step of flow of gas, the specific process that combination pressure parameter carries out flow control includes:Obtain initial residual volume Corresponding initial pressure;Pressure when air accumulator 3 is filled with inert gas to the chamber of metal hydride is obtained, is reached just in pressure When beginning pressure, control stops being filled with inert gas, and obtains the flow that flowmeter 4 detects obtained inert gas.
For example, the initial residual volume of chamber is V1, when being filled with the inert gas of initial flow Q1, detected is first Beginning pressure is P1;When detecting, control air accumulator 3 is filled with inert gas to the chamber of metal hydride, and obtains pressure P, When pressure P reaches P1, control stops being filled with inert gas, obtains flow Q at this time, then can calculate determining chamber according to flow Q The residual volume V of room, and then can determine the volume difference of residual volume V and initial residual volume V1.
In one embodiment of the invention, chamber has top port and bottom port, wherein hydrogen feeding pipe road connection top Portion port, air accumulator 3 is connected to bottom port, and when air-conditioning normal use, bottom port is closed, and hydrogen inputs or defeated from top port Go out chamber;And when the dusting degree of the detection of air-conditioning metal hydride in the present invention, first make detected metal hydride hydrogen release, The indoor hydrogen of chamber to be discharged, then closure tip port and bottom port is opened, and be filled with into chamber from bottom port Inert gas, this kind have the advantage that, the light specific gravity due to hydrogen than inert gas, so upon completion of the assays, passing through Open top part port and bottom port, it is the top in chamber to re-fill the indoor hydrogen of chamber, and inert gas is to be in chamber Inert gas can be gradually expelled to from bottom port in air accumulator 3 by the lower part of room with increasing for chamber, to not On the basis of influencing the normal hydrogen conveying of air-conditioning, the storage again of inert gas can also be realized, to meet the need of repeated detection It wants.
Inert gas of the present invention includes the gas types such as helium, neon, argon, krypton, xenon and radon, it should be noted that this The gas being filled with when invention detection can not also be limited to inert gas, not reacted with hydrogen, not by metal as long as disclosure satisfy that The gas of the conditions such as hydride absorption can also be used as the gas being filled with when present invention detection.
In one embodiment of the invention, it is contemplated that when the inert gas of chamber being expelled to air accumulator 3 using hydrogen, It still has a small amount of hydrogen and enters air accumulator 3, lead to the reduction of defeated hydrogen total amount, so air-conditioning further includes the tonifying Qi for being connected to hydrogen feeding pipe road Tank 5 is filled with hydrogen in air supply tank 5, suitable hydrogen can be filled with into hydrogen feeding pipe road after the completion of each detection, to mend Repay the loss of hydrogen in detection process.
As shown in Fig. 2, the present invention also provides a kind of method for detecting the metal hydride dusting degree of air-conditioning, step Suddenly include:
S101, the flow for obtaining the inert gas that flowmeter detects;
S102, according to flow, determine the dusting degree of the metal hydride in metal hydride heat exchanger.
In one embodiment of the invention, the gold in metal hydride heat exchanger is determined according to flow in step S102 Belong to the dusting degree of hydride, detailed process includes:The initial residual volume of chamber is obtained, initial residual volume is in air-conditioning Before manufacture, according to the residual volume of the initial flow of inert gas determination;According to flow, the residual volume of chamber is determined;It determines The volume difference of residual volume and initial residual volume;According to being associated with for preset volume difference and metal hydride dusting degree Relationship determines the dusting degree of the metal hydride corresponding to volume difference.
In one embodiment of the invention, the flow for the inert gas that flowmeter detects is obtained in step S101, Process includes:Obtain the corresponding initial pressure of initial residual volume;Detection air accumulator is filled with inertia to the chamber of metal hydride Pressure when gas, when pressure reaches initial pressure, control stops being filled with inert gas, and obtains what flowmeter detected The flow of inert gas.
The present invention also provides a kind of devices for detecting the metal hydride dusting degree of air-conditioning, and the device is using upper It states the control method disclosed in embodiment to be detected the metal hydride of air-conditioning, device includes:Acquiring unit, for obtaining The flow for the inert gas that flowmeter detects;Determination unit, for according to flow, determining in metal hydride heat exchanger The dusting degree of metal hydride.
In one embodiment of this invention, acquiring unit is used to obtain the initial residual volume of chamber, initial residual volume For the residual volume before air-conditioning dispatches from the factory, determined according to the initial flow of inert gas;Determination unit is used for:According to flow, really Determine the residual volume of chamber;Determine the volume difference of residual volume and initial residual volume;According to preset volume difference and gold The incidence relation for belonging to hydride dusting degree, determines the dusting degree of the metal hydride corresponding to volume difference.
In one embodiment of this invention, acquiring unit is additionally operable to obtain the corresponding initial pressure of initial residual volume;With And obtain pressure of air accumulator when being filled with inert gas to the chamber of metal hydride;Device further includes main control unit, is used for When pressure reaches initial pressure, control stops being filled with inert gas.
Innovative point of the other devices or structure of air-conditioning due to not being related to this case, does not repeat.
It should be understood that the invention is not limited in the flow and structure that are described above and are shown in the accompanying drawings, And various modifications and changes may be made without departing from the scope thereof.The scope of the present invention is only limited by the attached claims System.

Claims (8)

1. a kind of air-conditioning of Applied Electrochemistry compressor, which is characterized in that the air-conditioning includes electrochemical compressor (1), at least Two metal hydride heat exchangers (2), the electrochemical compressor (1) are respectively communicated with the metal hydride by hydrogen feeding pipe road Heat exchanger (2), the metal hydride heat exchanger (2) further include with the chamber filled with metal hydride, the air-conditioning:
Air accumulator (3), is filled with inert gas, and each metal hydride heat exchanger (2) is connected with an individual storage Gas tank (3);
Flowmeter (4), the connecting line between each air accumulator (3) and the corresponding metal hydride heat exchanger (2) On be provided with the individual flowmeter (4);
Controller, the flow for obtaining the inert gas that the flowmeter (4) detection obtains, and institute is determined according to the flow State the dusting degree of the metal hydride in metal hydride heat exchanger (2).
2. air-conditioning according to claim 1, which is characterized in that the controller determines the metallic hydrogen according to the flow The dusting degree of metal hydride in compound heat exchanger (2), including:
The initial residual volume of the chamber is obtained, the initial residual volume is true according to the initial flow of the inert gas Fixed residual volume;
According to the flow, the residual volume of the chamber is determined;
Determine the volume difference of the residual volume and the initial residual volume;
Determine the dusting degree of the metal hydride corresponding to the volume difference.
3. air-conditioning according to claim 2, which is characterized in that
The chamber is provided with pressure sensor;
The controller obtains the flow for the inert gas that flowmeter (4) detection obtains, including:
Obtain the corresponding initial pressure of the initial residual volume;
Obtain the pressure when air accumulator (3) is filled with inert gas to the chamber of the metal hydride;
When the pressure reaches the initial pressure, stopping is filled with inert gas, and obtains the flowmeter (4) detection and obtain The inert gas flow.
4. air-conditioning according to claim 1, which is characterized in that the chamber has top port and bottom port, wherein The hydrogen feeding pipe road is connected to the top port, and the air accumulator (3) is connected to the bottom port.
5. air-conditioning according to claim 1, which is characterized in that the air-conditioning further includes the tonifying Qi for being connected to the hydrogen feeding pipe road Tank (5), the air supply tank (5) is interior to be filled with hydrogen.
6. a kind of method for detecting the metal hydride dusting degree of air-conditioning, which is characterized in that including:
Obtain the flow for the inert gas that the flowmeter detects;
According to the flow, the dusting degree of the metal hydride in the metal hydride heat exchanger is determined.
7. according to the method described in claim 6, it is characterized in that, according to the flow, the metal hydride heat exchange is determined The dusting degree of metal hydride in device, including:
The initial residual volume of the chamber is obtained, the initial residual volume is true according to the initial flow of the inert gas Fixed residual volume;
According to the flow, the residual volume of the chamber is determined;
Determine the volume difference of the residual volume and the initial residual volume;
According to the incidence relation of preset volume difference and metal hydride dusting degree, determine corresponding to the volume difference The dusting degree of metal hydride.
8. the method according to the description of claim 7 is characterized in that obtaining the stream for the inert gas that the flowmeter detects Amount, including:
Obtain the corresponding initial pressure of the initial residual volume;
The pressure when air accumulator is filled with inert gas to the chamber of the metal hydride is detected, is reached in the pressure When to the initial pressure, control stops being filled with inert gas, and obtains the institute for the inert gas that the flowmeter detects State flow.
CN201710054899.9A 2017-01-24 2017-01-24 Air conditioner applying electrochemical compressor and detection method Active CN108344082B (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115265022A (en) * 2022-08-10 2022-11-01 珠海格力电器股份有限公司 Air conditioning unit and control method thereof

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