CN108339286A - A kind of atomization concentration of injecting type divides salt device - Google Patents

A kind of atomization concentration of injecting type divides salt device Download PDF

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Publication number
CN108339286A
CN108339286A CN201810134702.7A CN201810134702A CN108339286A CN 108339286 A CN108339286 A CN 108339286A CN 201810134702 A CN201810134702 A CN 201810134702A CN 108339286 A CN108339286 A CN 108339286A
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China
Prior art keywords
water
atomizer
constant temperature
constant
raw water
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CN201810134702.7A
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CN108339286B (en
Inventor
王磊
李陈
陈立成
黄丹曦
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Xi'an jinzang membrane Environmental Protection Technology Co., Ltd
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Shaanxi Membrane Separation Technology Research Institute Co Ltd
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D1/00Evaporating
    • B01D1/16Evaporating by spraying
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D1/00Evaporating
    • B01D1/16Evaporating by spraying
    • B01D1/20Sprayers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D1/00Evaporating
    • B01D1/30Accessories for evaporators ; Constructional details thereof

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Vaporization, Distillation, Condensation, Sublimation, And Cold Traps (AREA)
  • Heat Treatment Of Water, Waste Water Or Sewage (AREA)

Abstract

The invention discloses a kind of atomization concentrations of injecting type to divide salt device, including a constant temperature atomising device and the ground-source heat pump system being connected with constant temperature atomising device, the top of constant temperature atomising device is equipped with the constant water bath box being connected with ground-source heat pump system and built-in atomizer, and strong fan is equipped in constant temperature atomising device;Ground-source heat pump system includes interconnected ground-source heat pump host, raw water box and fresh-water tank, fresh-water tank is connected to constant water bath box, raw water box is connected to by being pressurized sewage pump with atomizer, under strong fan effect, saliferous raw water after atomization is sprayed from several nozzles of atomizer, is further atomized under the wiper effect on atomizer.The present invention makes full use of the available energy, it is synchronous to realize raw water atomization, achieve the purpose that evaporable water, concentration divide salt in more dry air, and the device technique is simple, equipment requirement is low, it is easily operated, highly practical, at low cost, it is easy to carry out large-scale industrial production.

Description

A kind of atomization concentration of injecting type divides salt device
Technical field
The invention belongs to be concentrated by evaporation field, and in particular to a kind of atomization concentration of injecting type divides salt device.
Background technology
There are mainly two types of the methods for being presently used for brine evaporation and concentration:1, by brine by salt pan evaporate brine using solar energy, The natural evaporations such as wind energy concentrate.This method is using natural evaporations processes such as solar energy, wind energies, and low energy consumption, but there are salt pan uses Area is big, evaporation efficiency is low, the period is long, the shortcomings of being limited by salt pan natural conditions;2, brine is led to using forced evaporation technique Pervaporation device forced evaporation concentrates, and this method evaporation efficiency is high, and floor space is small, but that there are equipment costs is high, energy consumption is big lacks Point.Brine is sprayed after atomization plant is atomized, can greatly increase the contact area of atomized drop and air, droplet surface Moisture can rapidly be taken away by air, to improve evaporation efficiency.Patent (CN 101385904A) proposes a kind of brine concentration side Method installs atomising head above concentraing pond, by increasing with air contact area to improve evaporation efficiency after brine is atomized, makes Brine is concentrated.This method only controls height and operating pressure of the atomising head apart from concentraing pond, is on the one hand difficult to control Evaporation divides salt process, is not easy to design evaporation efficiency, and evaporation process is single, and another aspect atomising head, which is susceptible to salt crystallization, to be caused to block up Plug, causes equipment to be unable to continuous operation.Based on this, need to develop a kind of evaporation efficiency is high, the period is short, atomising head is not easy to plug, The evaporation and concentration that evaporation process is easy to control, energy consumption is small, at low cost divides salt device.
Invention content
The purpose of the present invention is being directed to, evaporation efficiency existing for existing evaporating concentrating method is low, the period is long, atomising head is easily stifled Plug, the problems such as energy consumption is big, equipment cost is high, it is proposed that a kind of injecting type atomization concentration divides salt device.Utilize ground-source heat pump system The fresh-water tank of circulator bath constant temperature system will be transferred to after the heat absorption in raw water with high salt by heat exchanger, fresh water is heated up For promoting constant temperature atomising device and raw water temperature with high salt, the easy Crystallization Plugging of raw water atomizer with high salt is solved the problems, such as;Raw water box In water because temperature reduce so that part salt due to solubility reduce be precipitated to achieve the purpose that salt is divided in raw water part with high salt;Drop The raw water with high salt of Low-salinity is transferred to constant temperature atomizer through water system, and atomizer sprays raw water with high salt in the form of water mist, mist Change raw water with high salt to come into full contact with so that moisture rapid evaporation, raw water with high salt are concentrated with air by the push of strong fan.
The present invention is realized by following technical proposals.
The present invention provides a kind of atomization concentrations of injecting type to divide salt device, including a constant temperature atomising device and and constant temperature The ground-source heat pump system that atomising device is connected, the top of the constant temperature atomising device is equipped with to be connected with ground-source heat pump system Constant water bath box and built-in atomizer are equipped with strong fan in constant temperature atomising device;
The ground-source heat pump system includes interconnected ground-source heat pump host, raw water box and fresh-water tank, fresh-water tank with it is permanent Warm water bath cabinet is connected to, and raw water box is connected to by being pressurized sewage pump with atomizer, under strong fan effect, the saliferous after atomization Raw water is sprayed from several nozzles of atomizer, is further atomized under the wiper effect on atomizer.
Further, the raw water box is communicated to by being pressurized sewage pump on the high salt concentration water pipeline of atomizer;It is described light Water tank is communicated to the constant water bath box of atomizer by clear water pump circulation.
Further, the raw water box and fresh-water tank pass through refrigerant/water heat exchanger and the interconnected structure of ground-source heat pump host At closed cycle;Refrigerant/water heat exchanger is immersed in draw heat in raw water with high salt in raw water box, refrigerant/hydro-thermal in fresh-water tank Exchanger, which is immersed in fresh water, discharges heat.
Further, the atomizer includes several circumferentially disposed atomizers, and atomizer is tubbiness, is sprayed in atomization It is equipped with spinning wiper at the top of mouth bucket, spinning spiral fixinig plate is equipped in atomizer bung hole;And spinning spiral is scraped Piece and the coaxial arrangement of spinning spiral fixinig plate.
Further, the nebulizer body is immersed in constant water bath box, and the atomizer atomizing nozzle of atomizer is along constant temperature Water-bath babinet stretches out, and is tilted to center of circle direction.
Further, the constant water bath box is in circular babinet, and the temperature in constant water bath box uses local higher than device Temperature.
Further, the constant temperature atomising device is cylindrical shape, and inclined angle is erected on constant temperature atomising device engine base;By force Power wind turbine is respectively provided at up and down at two of constant temperature atomising device cylinder.
Further, the engine base is fixed station, or has moveable wheel.
It compared with, advantages of the present invention and has the beneficial effect that compared with prior art:
Constant temperature atomization system, which is mounted in constant temperature water box, makes atomising head and the preceding raw water temperature of atomization higher, is being atomized Crystallization is not easy close to salt in the raw water with high salt of saturated concentration to be precipitated, easily block and ask for further solution atomising head during ejection Topic installs scraping blade additional at nozzle, is rotated, can be solved in this way from mist using the powerful kinetic energy driving scraping blade of supercharging high concentration brine The problem of changing the easy accumulated solids salt grain of nozzle mouth extension and spout caused to block, while the concentrated water mist with high salt of ejection can also be increased Change, dispersion.Ground-source heat pump system is by the evaporation of refrigerant in refrigerant/water heat exchanger by heat absorption in raw water box to refrigerant In, the raw water temperature with high salt of saturated concentration reduces, and solid can be precipitated in the reduction of partial oxidation potassium solubility with temperature, keep saturation with high salt The salinity of raw water reduces.Again by the condensation of refrigerant in refrigerant/water heat exchanger while refrigerant circulation, by water bath with thermostatic control Fresh water in the circulatory system is by the heat absorption entrained by refrigerant, for ensureing that atomizer is in the constant temperature shape higher than raw water temperature State.Whole process makes full use of the available energy, synchronous to realize raw water atomization, reaches in more dry air evaporable water, dense The purpose of division salt can be widely applied to large area brine efficient concentration and divide salt, the recycling of inorganic salts sintetics, a variety of product salts Between the processes such as separation, impurity removal.
And the device technique is simple, equipment requirement is low.The invention device is simple and fast, easily operated, highly practical, cost It is low, it is easy to carry out large-scale industrial production.
Description of the drawings
Fig. 1 is that injecting type atomization concentration of the present invention divides salt installation drawing.
Fig. 2 is constant temperature atomising device vertical view and nozzle arrangements schematic diagram.
In Fig. 1:1, ground-source heat pump host, 2, refrigerant/water heat exchanger, 3, raw water box, 4, fresh-water tank, 5, water bath with thermostatic control Case, 6, strong fan, 7, constant temperature atomising device, 8, atomizer, 9, clarified water pump, 10, supercharging sewage pump, 11, constant temperature atomising device Engine base, 12, high salt concentration water pipeline.
In Fig. 2:13, wiper, 14, spinning spiral fixinig plate.
Specific implementation mode
With reference to embodiment, the invention will be described in further detail, but be not intended as to invention do any restrictions according to According to.
As shown in Figure 1, a kind of present invention injecting type atomization concentration divides salt device, including a constant temperature atomising device 7 and with The ground-source heat pump system that constant temperature atomising device 7 is connected, the top of constant temperature atomising device 7 is equipped with to be connected with ground-source heat pump system Constant water bath box 5 and built-in atomizer 8, strong fan 6 is equipped in constant temperature atomising device 7;Constant temperature atomising device 7 is cylinder Shape, inclined angle are erected on constant temperature atomising device engine base 11;Strong fan 6 is respectively provided at 7 cylinder of constant temperature atomising device At upper and lower two.Ground-source heat pump system includes interconnected ground-source heat pump host 1, raw water box 3 and fresh-water tank 4, earth source heat pump master Refrigerant/water heat exchanger 2 in machine 1, raw water box 3 in refrigerant/water heat exchanger 2 and fresh-water tank 4, which is interconnected, constitutes closed circuit follow Ring;Refrigerant/water heat exchanger 2 is immersed in draw heat in raw water with high salt in raw water box 3, refrigerant/water heat exchanger in fresh-water tank 4 2 are immersed in fresh water and discharge heat.Fresh-water tank 4 recycles the 5 interlayer wall of constant water bath box for being communicated to atomizer 8 by clarified water pump 9 On, raw water box 3 is connected to by being pressurized sewage pump 10 with the high salt concentration water pipeline 12 of atomizer 8, under the effect of strong fan 6, Raw water after atomization is sprayed from several nozzles of atomizer 8, into traveling one under the effect of wiper 13 on atomizer 8 Step atomization.
As shown in Figure 2, wherein built-in atomizer 8 includes several circumferentially disposed atomizers, and atomizer is bucket Shape is equipped with spinning wiper 13 at the top of atomizer bucket, and spinning spiral fixinig plate 14 is equipped in atomizer bung hole; And spinning wiper 13 and spinning spiral fixinig plate 14 are coaxially disposed.8 main body of built-in atomizer is immersed in water bath with thermostatic control In case 5, the atomizer atomizing nozzle of built-in atomizer 8 is stretched out along 5 body of constant water bath box, and is tilted to center of circle direction.
The built-in atomizer 8 for being immersed in constant water bath box 5 has certain amount, particular number to select as needed.Constant temperature Water bath 5 is in circular babinet, and circular babinet is full of fresh water, and there are two interfaces, are connected with fresh-water tank 4 by clarified water pump, Ensure that the temperature in constant water bath box 5 uses local temperature higher than device;The built-in atomizer being immersed in constant water bath box 5 8 jet hole is directed toward the center of circle of circular constant water bath box, and jet hole, which is directed toward, axially to have certain orientation deflection along being directed toward.
The wiper 13 and nozzle internal orifice of 8 jet hole of atomizer have spinning spiral fixinig plate 14, in supercharging sewage pump Under the effect of 10 very strong driving forces, jet hole is made to have the wiper 13 of helical structure and nozzle internal orifice to have spinning spiral fixinig plate 14 Using the axle center of intermediate connection shaft as center of circle high speed rotation, the analysis salt crystallization that jet hole outer is accumulated in atomization process is scraped off, Raw water is shown in that gap sprays from shaft and nozzle, is further atomized under the effect of wiper 13, jet hole has spiral with jet hole Scraping blade 13 and nozzle internal orifice have spinning spiral fixinig plate 14 that can reach 1-3mm, raw water atomization quantity to connect the gap of shaft Greatly, atomizing effect is good.
Lower section is equipped with strong fan 6 in constant water bath box 5 in constant temperature atomization system, and 6 wind direction of strong fan is along circular The center of circle of babinet is axially outward.
Heating system includes that clarified water pump 9, fresh-water tank 4 and pipeline are connected constant water bath box 5, constitutes closed cycle;For Hot systems ensure that the high strong brine of the nozzle of constant temperature atomization system is less than saturation state, while absorbing heat in raw water box, make part salt Divide and is precipitated, desalination since temperature reduces.
Raw water water system with high salt is made of supercharging sewage pump 10, raw water box 3 and high salt concentration water pipeline 12;It is pressurized sewage Pump 10 makes what high concentration brine passed through constant temperature atomization system to be immersed in constant temperature in raw water box water supply, by high salt concentration water pipeline 12 Built-in atomizer 8 in water bath 5 is atomized, and is strongly pushed in strong fan 6, can be made the brine of atomization that can farthest be delivered 50- 60 meters, scatter and disappear moisture in air, reaches concentrated brine, divides the purpose of salt.
The principle of the present invention is:Raw water becomes the dispersion of water mist form by constant temperature atomizer, since drop is contacted with air Area is big, interaction is strong, and the hydrone of droplet surface is taken away rapidly by air, to make raw water be concentrated.Meanwhile it being atomized Device is mounted in constant temperature water box so that raw water temperature is relatively high before atomising head and atomization, be atomized spray during raw water in salt not Easily crystallization is precipitated, and since atomization water is big, jet hole is big, so that raw water is further atomized by the wiper of jet hole, to Solve the problems, such as that atomising head is susceptible to plugging.Ground-source heat pump system is by the evaporation of refrigerant in refrigerant/water heat exchanger by raw water box In middle heat absorption to refrigerant, raw water temperature reduces, and solid can be precipitated in the potassium chloride solubility with temperature reduction of part monovalence, can For separating-purifying potassium chloride.Again by the condensation of refrigerant in refrigerant/water heat exchanger while refrigerant circulation, by thermostatted water The fresh water in the circulatory system is bathed by the heat absorption entrained by refrigerant, for ensureing that atomising device is in constant temperature.
Steps are as follows for the embodiment of the present invention:
A, the heat of fresh water in fresh-water tank, the releasing that heats up comes from the heat that ground-source heat pump system is absorbed from raw water;
B, constant temperature atomising device is preheated by the heating fresh water in step a, temperature is 10-15 DEG C higher than local temperature;
C, ground-source heat pump system absorbs the heat in high bittern water by refrigerant/water heat exchanger so that former brine reduces The part easily salt solid (salt that temperature reduces, solubility declines) of changes in solubility by temperature change is precipitated in 5-10 DEG C of temperature;
D, atomizer draws the brine for reducing salinity, pair of the constant temperature atomizer nozzle and nozzle wiper by heating Recast is atomized;
E, it is atomized the push that brine passes through strong fan in step d, can make the brine of atomization that can farthest be delivered 50-60 Rice, scatter and disappear moisture in air, reaches concentrated brine, divides the purpose of salt.
The foregoing is only a preferred embodiment of the present invention, but scope of protection of the present invention is not limited thereto, Any one skilled in the art in the technical scope disclosed by the present invention, the change or replacement that can be readily occurred in, It should be covered by the protection scope of the present invention.

Claims (8)

1. a kind of injecting type atomization concentration divides salt device, it is characterised in that:Including a constant temperature atomising device (7) and and constant temperature The top of the ground-source heat pump system that atomising device (7) is connected, the constant temperature atomising device (7) is equipped with and ground-source heat pump system phase The constant water bath box (5) and built-in atomizer (8) of connection are equipped with strong fan (6) in constant temperature atomising device (7);
The ground-source heat pump system includes interconnected ground-source heat pump host (1), raw water box (3) and fresh-water tank (4), fresh-water tank (4) it is connected to constant water bath box (5), raw water box (3) is connected to by being pressurized sewage pump (10) with atomizer (8), in strong fan (6) under acting on, the raw water after atomization is sprayed from several nozzles of atomizer (8), the wiper on atomizer (8) (13) effect is lower is further atomized.
2. a kind of injecting type atomization concentration according to claim 1 divides salt device, it is characterised in that:The raw water box (3) It is communicated on the high salt concentration water pipeline (12) of atomizer (8) by being pressurized sewage pump (10);The fresh-water tank (4) passes through clear water Pump (9) cycle is communicated to the constant water bath box (5) of atomizer (8).
3. a kind of injecting type atomization concentration according to claim 1 divides salt device, it is characterised in that:The raw water box (3) It is interconnected by refrigerant/water heat exchanger (2) and ground-source heat pump host (1) with fresh-water tank (4) and constitutes closed cycle;Raw water box (3) interior refrigerant/water heat exchanger (2) is immersed in draw heat in raw water with high salt, the interior refrigerant/water heat exchanger (2) of fresh-water tank (4) It is immersed in fresh water and discharges heat.
4. a kind of injecting type atomization concentration according to claim 1 divides salt device, it is characterised in that:The atomizer (8) Including several circumferentially disposed atomizers, atomizer is tubbiness, is scraped equipped with spinning spiral at the top of atomizer bucket Piece (13) is equipped with spinning spiral fixinig plate (14) in atomizer bung hole;And spinning wiper (13) and spinning spiral shell It is rotated with stator (14) coaxial arrangement.
5. a kind of injecting type atomization concentration according to claim 4 divides salt device, it is characterised in that:The atomizer (8) Main body is immersed in constant water bath box (5), and the atomizer atomizing nozzle of atomizer (8) is stretched out along constant water bath box (5) body, and to Center of circle direction tilts.
6. a kind of injecting type atomization concentration according to claim 1 divides salt device, it is characterised in that:The constant water bath box (5) it is in circular babinet, the temperature in constant water bath box (5) uses local temperature higher than device.
7. a kind of injecting type atomization concentration according to claim 1 divides salt device, it is characterised in that:The constant temperature atomization dress It is cylindrical shape to set (7), and inclined angle is erected on constant temperature atomising device engine base (11);Strong fan (6) is respectively provided at constant temperature Up and down at two of atomising device (7) cylinder.
8. a kind of injecting type atomization concentration according to claim 7 divides salt device, it is characterised in that:The engine base (11) is Fixed station, or there is moveable wheel.
CN201810134702.7A 2018-02-09 2018-02-09 Injection type atomizing, concentrating and salt separating device Active CN108339286B (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108314066A (en) * 2018-02-09 2018-07-24 陕西省膜分离技术研究院有限公司 A kind of poor lithium brine salt reduction richness lithium method and its device
CN114515437A (en) * 2022-01-29 2022-05-20 无锡恒诚硅业有限公司 Drying nozzle assembly

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0351143A2 (en) * 1988-07-12 1990-01-17 GEOPHYSICAL ENGINEERING COMPANY (a Delaware corporation) Evaporating and cooling liquid
CN1081118A (en) * 1992-07-10 1994-01-26 王抗曝 Method and apparatus with separation of toxic contaminants by nebulization
CN1101009A (en) * 1993-09-29 1995-04-05 吉林省文化发展总公司 Rapid seawater evaporation type salt extraction equipment and method thereof
WO1997013722A1 (en) * 1995-10-11 1997-04-17 Krebs & Co. Ag Salt extraction process and device
CN104495967A (en) * 2014-12-02 2015-04-08 江苏万邦达环保科技有限公司 High-concentration sewage accelerated-evaporation equipment
CN108314066B (en) * 2018-02-09 2019-09-03 陕西省膜分离技术研究院有限公司 A kind of poor lithium brine salt reduction richness lithium method and device thereof

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0351143A2 (en) * 1988-07-12 1990-01-17 GEOPHYSICAL ENGINEERING COMPANY (a Delaware corporation) Evaporating and cooling liquid
CN1081118A (en) * 1992-07-10 1994-01-26 王抗曝 Method and apparatus with separation of toxic contaminants by nebulization
CN1101009A (en) * 1993-09-29 1995-04-05 吉林省文化发展总公司 Rapid seawater evaporation type salt extraction equipment and method thereof
WO1997013722A1 (en) * 1995-10-11 1997-04-17 Krebs & Co. Ag Salt extraction process and device
CN104495967A (en) * 2014-12-02 2015-04-08 江苏万邦达环保科技有限公司 High-concentration sewage accelerated-evaporation equipment
CN108314066B (en) * 2018-02-09 2019-09-03 陕西省膜分离技术研究院有限公司 A kind of poor lithium brine salt reduction richness lithium method and device thereof

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108314066A (en) * 2018-02-09 2018-07-24 陕西省膜分离技术研究院有限公司 A kind of poor lithium brine salt reduction richness lithium method and its device
CN108314066B (en) * 2018-02-09 2019-09-03 陕西省膜分离技术研究院有限公司 A kind of poor lithium brine salt reduction richness lithium method and device thereof
CN114515437A (en) * 2022-01-29 2022-05-20 无锡恒诚硅业有限公司 Drying nozzle assembly

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