CN108338178A - A kind of Herbicidal combinations containing triazole sulphur humulone - Google Patents
A kind of Herbicidal combinations containing triazole sulphur humulone Download PDFInfo
- Publication number
- CN108338178A CN108338178A CN201810242382.7A CN201810242382A CN108338178A CN 108338178 A CN108338178 A CN 108338178A CN 201810242382 A CN201810242382 A CN 201810242382A CN 108338178 A CN108338178 A CN 108338178A
- Authority
- CN
- China
- Prior art keywords
- triazole sulphur
- sulphur humulone
- herbicidal combinations
- tembotrions
- nicosulfuron
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000005864 Sulphur Substances 0.000 title claims abstract description 38
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 title claims abstract description 37
- RMFGNMMNUZWCRZ-UHFFFAOYSA-N Humulone Natural products CC(C)CC(=O)C1=C(O)C(O)(CC=C(C)C)C(O)=C(CC=C(C)C)C1=O RMFGNMMNUZWCRZ-UHFFFAOYSA-N 0.000 title claims abstract description 36
- VMSLCPKYRPDHLN-NRFANRHFSA-N humulone Chemical compound CC(C)CC(=O)C1=C(O)C(CC=C(C)C)=C(O)[C@@](O)(CC=C(C)C)C1=O VMSLCPKYRPDHLN-NRFANRHFSA-N 0.000 title claims abstract description 36
- 150000003852 triazoles Chemical class 0.000 title claims abstract description 35
- 230000002363 herbicidal effect Effects 0.000 title claims abstract description 25
- RTCOGUMHFFWOJV-UHFFFAOYSA-N nicosulfuron Chemical compound COC1=CC(OC)=NC(NC(=O)NS(=O)(=O)C=2C(=CC=CN=2)C(=O)N(C)C)=N1 RTCOGUMHFFWOJV-UHFFFAOYSA-N 0.000 claims abstract description 20
- 239000005586 Nicosulfuron Substances 0.000 claims abstract description 19
- 239000004480 active ingredient Substances 0.000 claims abstract description 4
- 241000196324 Embryophyta Species 0.000 claims description 20
- 239000000203 mixture Substances 0.000 claims description 12
- 240000008042 Zea mays Species 0.000 claims description 5
- 235000002017 Zea mays subsp mays Nutrition 0.000 claims description 5
- 239000003795 chemical substances by application Substances 0.000 claims description 3
- 239000000375 suspending agent Substances 0.000 claims description 3
- 239000004562 water dispersible granule Substances 0.000 claims description 3
- 239000004563 wettable powder Substances 0.000 claims description 3
- 235000016383 Zea mays subsp huehuetenangensis Nutrition 0.000 claims description 2
- 150000003851 azoles Chemical group 0.000 claims description 2
- 235000009973 maize Nutrition 0.000 claims description 2
- -1 compound compound Chemical class 0.000 description 12
- 238000013329 compounding Methods 0.000 description 9
- 239000000575 pesticide Substances 0.000 description 9
- 230000000694 effects Effects 0.000 description 8
- 239000004009 herbicide Substances 0.000 description 7
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 6
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 6
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 6
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 4
- 239000003814 drug Substances 0.000 description 4
- 244000025254 Cannabis sativa Species 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 3
- 229920001732 Lignosulfonate Polymers 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 description 3
- 150000008051 alkyl sulfates Chemical class 0.000 description 3
- 239000012752 auxiliary agent Substances 0.000 description 3
- 210000000481 breast Anatomy 0.000 description 3
- 239000004202 carbamide Substances 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 235000005822 corn Nutrition 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- PSZYNBSKGUBXEH-UHFFFAOYSA-M naphthalene-1-sulfonate Chemical compound C1=CC=C2C(S(=O)(=O)[O-])=CC=CC2=C1 PSZYNBSKGUBXEH-UHFFFAOYSA-M 0.000 description 3
- 229920005646 polycarboxylate Polymers 0.000 description 3
- 229940051841 polyoxyethylene ether Drugs 0.000 description 3
- 229920000056 polyoxyethylene ether Polymers 0.000 description 3
- 238000011160 research Methods 0.000 description 3
- 230000002195 synergetic effect Effects 0.000 description 3
- 230000001988 toxicity Effects 0.000 description 3
- 231100000419 toxicity Toxicity 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- 239000000080 wetting agent Substances 0.000 description 3
- 239000005995 Aluminium silicate Substances 0.000 description 2
- 240000006122 Chenopodium album Species 0.000 description 2
- 235000009344 Chenopodium album Nutrition 0.000 description 2
- 206010059866 Drug resistance Diseases 0.000 description 2
- 244000058871 Echinochloa crus-galli Species 0.000 description 2
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- 229910019142 PO4 Inorganic materials 0.000 description 2
- 239000004372 Polyvinyl alcohol Substances 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 description 2
- 229930006000 Sucrose Natural products 0.000 description 2
- 150000008052 alkyl sulfonates Chemical class 0.000 description 2
- 235000012211 aluminium silicate Nutrition 0.000 description 2
- 229960000892 attapulgite Drugs 0.000 description 2
- WQZGKKKJIJFFOK-VFUOTHLCSA-N beta-D-glucose Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 229910000019 calcium carbonate Inorganic materials 0.000 description 2
- 235000019504 cigarettes Nutrition 0.000 description 2
- 239000004927 clay Substances 0.000 description 2
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 description 2
- 239000002270 dispersing agent Substances 0.000 description 2
- 229940079593 drug Drugs 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 239000000945 filler Substances 0.000 description 2
- 239000010419 fine particle Substances 0.000 description 2
- 239000008103 glucose Substances 0.000 description 2
- IGMNYECMUMZDDF-UHFFFAOYSA-N homogentisic acid Chemical compound OC(=O)CC1=CC(O)=CC=C1O IGMNYECMUMZDDF-UHFFFAOYSA-N 0.000 description 2
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 2
- 150000002576 ketones Chemical class 0.000 description 2
- 229910052625 palygorskite Inorganic materials 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 2
- 239000010452 phosphate Substances 0.000 description 2
- 230000029553 photosynthesis Effects 0.000 description 2
- 238000010672 photosynthesis Methods 0.000 description 2
- 229920002451 polyvinyl alcohol Polymers 0.000 description 2
- 230000003449 preventive effect Effects 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 239000002689 soil Substances 0.000 description 2
- 239000005720 sucrose Substances 0.000 description 2
- ZDXMLEQEMNLCQG-UHFFFAOYSA-N sulfometuron methyl Chemical group COC(=O)C1=CC=CC=C1S(=O)(=O)NC(=O)NC1=NC(C)=CC(C)=N1 ZDXMLEQEMNLCQG-UHFFFAOYSA-N 0.000 description 2
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 2
- 238000010998 test method Methods 0.000 description 2
- DMAXMXPDVWTIRV-UHFFFAOYSA-N 2-(2-phenylethyl)phenol Chemical compound OC1=CC=CC=C1CCC1=CC=CC=C1 DMAXMXPDVWTIRV-UHFFFAOYSA-N 0.000 description 1
- WTLNOANVTIKPEE-UHFFFAOYSA-N 2-acetyloxypropanoic acid Chemical compound OC(=O)C(C)OC(C)=O WTLNOANVTIKPEE-UHFFFAOYSA-N 0.000 description 1
- LRWZZZWJMFNZIK-UHFFFAOYSA-N 2-chloro-3-methyloxirane Chemical compound CC1OC1Cl LRWZZZWJMFNZIK-UHFFFAOYSA-N 0.000 description 1
- 241001290610 Abildgaardia Species 0.000 description 1
- 240000006995 Abutilon theophrasti Species 0.000 description 1
- 240000001592 Amaranthus caudatus Species 0.000 description 1
- 235000009328 Amaranthus caudatus Nutrition 0.000 description 1
- 240000001579 Cirsium arvense Species 0.000 description 1
- 235000005918 Cirsium arvense Nutrition 0.000 description 1
- 241000207894 Convolvulus arvensis Species 0.000 description 1
- 229920002261 Corn starch Polymers 0.000 description 1
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 1
- 208000030453 Drug-Related Side Effects and Adverse reaction Diseases 0.000 description 1
- 102000004190 Enzymes Human genes 0.000 description 1
- 108090000790 Enzymes Proteins 0.000 description 1
- 244000068988 Glycine max Species 0.000 description 1
- 235000010469 Glycine max Nutrition 0.000 description 1
- 240000007594 Oryza sativa Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- FKUYMLZIRPABFK-UHFFFAOYSA-N Plastoquinone 9 Natural products CC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCC1=CC(=O)C(C)=C(C)C1=O FKUYMLZIRPABFK-UHFFFAOYSA-N 0.000 description 1
- 241000209504 Poaceae Species 0.000 description 1
- 244000292697 Polygonum aviculare Species 0.000 description 1
- 235000006386 Polygonum aviculare Nutrition 0.000 description 1
- 229920001214 Polysorbate 60 Polymers 0.000 description 1
- 235000019484 Rapeseed oil Nutrition 0.000 description 1
- 235000010086 Setaria viridis var. viridis Nutrition 0.000 description 1
- HVUMOYIDDBPOLL-XWVZOOPGSA-N Sorbitan monostearate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O HVUMOYIDDBPOLL-XWVZOOPGSA-N 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- 229940100389 Sulfonylurea Drugs 0.000 description 1
- 206010070863 Toxicity to various agents Diseases 0.000 description 1
- 101100339555 Zymoseptoria tritici HPPD gene Proteins 0.000 description 1
- 238000012271 agricultural production Methods 0.000 description 1
- 239000003905 agrochemical Substances 0.000 description 1
- WMGSQTMJHBYJMQ-UHFFFAOYSA-N aluminum;magnesium;silicate Chemical compound [Mg+2].[Al+3].[O-][Si]([O-])([O-])[O-] WMGSQTMJHBYJMQ-UHFFFAOYSA-N 0.000 description 1
- 239000004178 amaranth Substances 0.000 description 1
- 235000012735 amaranth Nutrition 0.000 description 1
- BIGPRXCJEDHCLP-UHFFFAOYSA-N ammonium bisulfate Chemical compound [NH4+].OS([O-])(=O)=O BIGPRXCJEDHCLP-UHFFFAOYSA-N 0.000 description 1
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 description 1
- 229910052921 ammonium sulfate Inorganic materials 0.000 description 1
- 235000011130 ammonium sulphate Nutrition 0.000 description 1
- 230000008485 antagonism Effects 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 150000005693 branched-chain amino acids Chemical class 0.000 description 1
- 229930002875 chlorophyll Natural products 0.000 description 1
- 235000019804 chlorophyll Nutrition 0.000 description 1
- ATNHDLDRLWWWCB-AENOIHSZSA-M chlorophyll a Chemical compound C1([C@@H](C(=O)OC)C(=O)C2=C3C)=C2N2C3=CC(C(CC)=C3C)=[N+]4C3=CC3=C(C=C)C(C)=C5N3[Mg-2]42[N+]2=C1[C@@H](CCC(=O)OC\C=C(/C)CCC[C@H](C)CCC[C@H](C)CCCC(C)C)[C@H](C)C2=C5 ATNHDLDRLWWWCB-AENOIHSZSA-M 0.000 description 1
- 239000007859 condensation product Substances 0.000 description 1
- 235000005687 corn oil Nutrition 0.000 description 1
- 239000002285 corn oil Substances 0.000 description 1
- 239000008120 corn starch Substances 0.000 description 1
- 229940099112 cornstarch Drugs 0.000 description 1
- GVJHHUAWPYXKBD-UHFFFAOYSA-N d-alpha-tocopherol Natural products OC1=C(C)C(C)=C2OC(CCCC(C)CCCC(C)CCCC(C)C)(C)CCC2=C1C GVJHHUAWPYXKBD-UHFFFAOYSA-N 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 239000007884 disintegrant Substances 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 239000002552 dosage form Substances 0.000 description 1
- QYDYPVFESGNLHU-UHFFFAOYSA-N elaidic acid methyl ester Natural products CCCCCCCCC=CCCCCCCCC(=O)OC QYDYPVFESGNLHU-UHFFFAOYSA-N 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 229940125532 enzyme inhibitor Drugs 0.000 description 1
- 239000002532 enzyme inhibitor Substances 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 229920001249 ethyl cellulose Polymers 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- NVVZQXQBYZPMLJ-UHFFFAOYSA-N formaldehyde;naphthalene-1-sulfonic acid Chemical compound O=C.C1=CC=C2C(S(=O)(=O)O)=CC=CC2=C1 NVVZQXQBYZPMLJ-UHFFFAOYSA-N 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 244000230342 green foxtail Species 0.000 description 1
- 208000006278 hypochromic anemia Diseases 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- 230000003211 malignant effect Effects 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 230000010534 mechanism of action Effects 0.000 description 1
- QYDYPVFESGNLHU-KHPPLWFESA-N methyl oleate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OC QYDYPVFESGNLHU-KHPPLWFESA-N 0.000 description 1
- 229940073769 methyl oleate Drugs 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 235000019198 oils Nutrition 0.000 description 1
- 229920001568 phenolic resin Polymers 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- FKUYMLZIRPABFK-IQSNHBBHSA-N plastoquinone-9 Chemical compound CC(C)=CCC\C(C)=C\CC\C(C)=C\CC\C(C)=C\CC\C(C)=C\CC\C(C)=C\CC\C(C)=C\CC\C(C)=C\CC\C(C)=C\CC1=CC(=O)C(C)=C(C)C1=O FKUYMLZIRPABFK-IQSNHBBHSA-N 0.000 description 1
- 230000008092 positive effect Effects 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000000979 retarding effect Effects 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- 239000001587 sorbitan monostearate Substances 0.000 description 1
- 235000011076 sorbitan monostearate Nutrition 0.000 description 1
- 229940035048 sorbitan monostearate Drugs 0.000 description 1
- 239000000600 sorbitol Substances 0.000 description 1
- 235000012424 soybean oil Nutrition 0.000 description 1
- 239000003549 soybean oil Substances 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- YROXIXLRRCOBKF-UHFFFAOYSA-N sulfonylurea Chemical class OC(=N)N=S(=O)=O YROXIXLRRCOBKF-UHFFFAOYSA-N 0.000 description 1
- 230000008961 swelling Effects 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- 229960001295 tocopherol Drugs 0.000 description 1
- 229930003799 tocopherol Natural products 0.000 description 1
- 235000010384 tocopherol Nutrition 0.000 description 1
- 239000011732 tocopherol Substances 0.000 description 1
- XZZNDPSIHUTMOC-UHFFFAOYSA-N triphenyl phosphate Chemical compound C=1C=CC=CC=1OP(OC=1C=CC=CC=1)(=O)OC1=CC=CC=C1 XZZNDPSIHUTMOC-UHFFFAOYSA-N 0.000 description 1
- GVJHHUAWPYXKBD-IEOSBIPESA-N α-tocopherol Chemical compound OC1=C(C)C(C)=C2O[C@@](CCC[C@H](C)CCC[C@H](C)CCCC(C)C)(C)CCC2=C1C GVJHHUAWPYXKBD-IEOSBIPESA-N 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/28—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
- A01N47/36—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N< containing the group >N—CO—N< directly attached to at least one heterocyclic ring; Thio analogues thereof
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N41/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom
- A01N41/02—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom containing a sulfur-to-oxygen double bond
- A01N41/10—Sulfones; Sulfoxides
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/56—1,2-Diazoles; Hydrogenated 1,2-diazoles
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The present invention provides a kind of Herbicidal combinations containing triazole sulphur humulone, and active ingredient is made of triazole sulphur humulone, tembotrions and nicosulfuron, and the weight ratio of the triazole sulphur humulone, tembotrions and nicosulfuron is 1 60:1‑50:1‑25.
Description
Technical field
The invention belongs to pesticide fields, and in particular to a kind of Herbicidal combinations and application thereof containing triazole sulphur humulone.
Background technology
Triazole sulphur humulone is HPPD enzyme inhibitor class compounds, has excellent bioactivity, can effectively prevent and kill off rice
The a variety of malignant weeds in field.The mechanism of action of such compound is the work by inhibiting plant to control photosynthesis key pigment enzyme
Property, so that its substrate is converted into alcapton process and be obstructed, can not normally be synthesized so as to cause tocopherol and plastoquinone, influences plant
Interior photosynthesis is normally carried out, final thoroughly dead.
Tembotrions are a kind of novel three ketones herbicides, can effectively prevent main broadleaved herb and some grassy weeds,
By destroying the formation of chlorophyll, cause aggrieved weeds chlorosis withered, to green bristlegrass, barnyard grass, lamb's-quarters, field bindweed, field thistle, piemarker
Fiber crops, three-coloured amaranth, lamb's-quarters, knotweed, barnyard grass, lady's-grass etc. have preferable control effect, can be used for before bud cauline leaf process after Seal treatment and bud.
Nicosulfuron is a kind of sulfonylurea corn field herbicide, can effectively prevent and kill off a variety of annual grass in corn field
Section weeds, broad leaved weed and sedge weed.It is absorbed rapidly by leaf and root, and is conducted rapidly by xylem and bast.
The synthesis of branched-chain amino acid is prevented by acetolactate synthestase.
Since the herbicide type applied in current agricultural production is various, drug toxicity is big, and residual quantity is high, is easier to make miscellaneous
Grass generates resistance, when the herbicide of single active ingredient is in use, being influenced its herbicidal efficacy by factors such as resistances can substantially reduce.
If the novel herbicide active compound compound of initiative, the initiative period of noval chemical compound is longer, and input is huge, at present pesticide enterprise of the country
Industry is limited by scale, research strength, and it is unpractical to carry out creative research to active compound compound.And the compounding between pesticide was both
It can solve the problems, such as that pesticide single dose toxicity is big, effect is poor, and less investment, R＆D cycle are short, meet the present situation of domestic agricultural chemicals enterprise,
And it is used interchangeably the generation for capableing of retarding action object drug resistance between different pesticides, there is ideal using effect,
Therefore the compounding of pesticide is current research focus in the field of pesticide between different role mechanism.Triazole sulphur is not careless in the prior art
The relevant report of ketone, tembotrions and nicosulfuron compounding
Invention content
The purpose of the present invention is to provide a kind of component is reasonable, drug cost is low, is not likely to produce the herbicide group of drug resistance
Object is closed, all there is preferable control effect to corn field grassy weed and broad leaved weed, to slowing down Weed Resistance etc. tool
There is positive effect.
The present invention provides following technical scheme
A kind of Herbicidal combinations containing triazole sulphur humulone, active ingredient is by triazole sulphur humulone, tembotrions and nicosulfuron
Composition, the weight ratio of the triazole sulphur humulone, tembotrions and nicosulfuron are followed successively by 1-60:1-50:1-25.
A kind of Herbicidal combinations containing triazole sulphur humulone of the present invention, the preferably described triazole sulphur humulone, tembotrions
It is followed successively by 10-50 with the weight ratio of nicosulfuron:15-35:5-15.
Triazole sulphur humulone, tembotrions and cigarette described in a kind of Herbicidal combinations containing triazole sulphur humulone of the present invention
The total weight percentage composition of Sulfometuron Methyl in the composition is 1-90%.
Triazole sulphur humulone, tembotrions and cigarette described in a kind of Herbicidal combinations containing triazole sulphur humulone of the present invention
The total weight percentage composition of Sulfometuron Methyl in the composition is 20-65%.
The present composition can be configured to the suitable formulations agriculturally needed, and preferred combination dosage form is suspending agent, can
One kind in wet powder, water dispersible granules etc..
For water dispersible granules, those skilled in the art are very familiar with completes the present invention using corresponding auxiliary agent.Dispersion
It is one or more in agent such as polycarboxylate, lignosulfonates, alkylnaphthalene sulfonate；Wetting agent such as alkyl sulfate, alkyl sulphur
It is one or more in hydrochlorate, naphthalene sulfonate；It is one or more in disintegrant such as ammonium sulfate, urea, sucrose, glucose；Binder
As one or more in diatomite, cornstarch, PVA, carboxymethyl (ethyl) cellulose family；Filler for example diatomite, kaolin,
White carbon, fine particle calcium carbonate, talcum powder, attapulgite, clay are one or more.
To suspending agent, workable auxiliary agent has：Dispersant for example polycarboxylate, lignosulfonates, alkylnaphthalene sulfonate,
It is one or more in TERSPERSE 2425 (Huntsman Corporation of the U.S. produces, alkyl naphthalene sulfonic acid salt)；Emulsifier such as agriculture breast
700# (common names：Alkyl phenol formaldehyde resin polyoxyethylene ether, agriculture breast 2201, this disk -60# (common name sorbitol anhydride monostearates
Ester), Tween-60 # (common names：Sorbitan monostearate polyoxyethylene ether), agriculture breast 1601# (common names：Phenethyl benzene
Phenol polyethenoxy polyethenoxy ether), (U.S. is prosperous by TERSPERSE 4894 (Huntsman Corporation of U.S. product) TERSPERSE 2500
Si Mai companies produce) in it is one or more；Wetting agent such as alkylphenol polyoxyethylene ether formaldehyde condensate sulfate, alkyl phenol
Polyoxyethylene groups ether phosphate, phenethyl phenol polyoxyethylene groups ether phosphate, alkyl sulfate, alkylsulfonate, naphthalene sulfonate,
It is one or more in TERSPERSE 2500 (Huntsman Corporation of U.S. product)；Thickener such as white carbon, polyvinyl alcohol, swelling
It is one or more in soil, aluminium-magnesium silicate；One in antifreezing agent such as ethylene glycol, propylene glycol, glycerine, urea, inorganic salts such as sodium chloride
Kind is a variety of；It is one or more in stabilizer such as epoxidized soybean oil, epoxychloropropane, triphenyl phosphate；Decentralized medium such as soybean
It is one or more in oil, rapeseed oil, corn oil, methyl oleate.
To wettable powder, workable auxiliary agent has：Dispersant such as polycarboxylate, lignosulfonates, alkyl naphthalene sulfonic acid
It is one or more in salt；It is one or more in wetting agent such as alkyl sulfate, alkylsulfonate, naphthalene sulfonate；Filler such as sulfuric acid
Ammonium, urea, sucrose, glucose, diatomite, kaolin, white carbon, fine particle calcium carbonate, talcum powder, attapulgite, clay are one or more.
A kind of Herbicidal combinations containing triazole sulphur humulone of the present invention are suitable for Control Weeds in Maize Field, described miscellaneous
Grass selection grass family or broad leaved weed.
The present invention obtains following advantageous effects：
Herbicidal combinations provided by the invention show apparent synergistic effect, the control effect ratio of composition to lady's-grass
Single dose is significantly improved, and reduces the dosage of pesticide.Herbicidal combinations provided by the invention, expand herbicidal spectrum, and one
Secondary medication solves various weed problems, compensates for defect and limitation when single dose uses.
Specific implementation mode
The specific implementation mode of the present invention is described in detail with reference to embodiment, it is to be understood that the guarantor of the present invention
Shield range is not restricted by specific implementation.
Embodiment one：Triazole sulphur humulone, tembotrions and nicosulfuron compounding are to lady's-grass Toxicity Determination.
Test method：Experiment carries out under greenhouse experiment, the consistent weeds lady's-grass of growth selection, water drenching, waits for that blade is dried
Cauline leaf spraying treatment is carried out afterwards.After processing 10 days, fresh weight is measured, calculates preventive effect.
Herbicide associated form is evaluated according to Colby methods.Evaluation criterion：As E ﹣ E0 ＞ 10%, it is expressed as synergistic effect；
As ﹣ 10%≤E ﹣ E0≤10%, summation action is shown as；As E ﹣ E0 ＜ ﹣ 10%, antagonism is shown as.
1 azoles sulphur humulone of table, tembotrions and nicosulfuron compounding are to lady's-grass Toxicity Determination
As seen from the above table, triazole sulphur humulone, tembotrions and nicosulfuron compounding have apparent synergistic effect to lady's-grass.Three
Kind substance, which is applied in combination, can effectively reduce Pesticide use dosage.
Embodiment two：Triazole sulphur humulone, tembotrions and nicosulfuron compounding are to lady's-grass field efficacy.
Test medicine：Medicament 1：55% triazole sulphur humulone tembotrions nicosulfuron wettable powder (triazole sulphur humulone
25%, tembotrions 20%, nicosulfuron 10%, naphthalene sulfonic acid-formaldehyde condensation product sodium salt 7%, neopelex 5%, bumps
100%) stick soil adds to.
Test method：The field annual grassy weeds lady's-grass 1-3 leaf phases carry out cauline leaf and spray 1 time, and fresh weight is anti-after investigation 15 days
Effect.Preventive effect (%)=[(clear water control group weeds fresh weight-processing group weeds fresh weight)/clear water group weeds fresh weight] * 100.
2 triazole sulphur humulone of table, tembotrions and nicosulfuron compounding are to lady's-grass field efficacy
As seen from the above table, compared with single dose, triazole sulphur humulone, tembotrions and nicosulfuron compounding application can significantly improve
Its control effect to weeds, has significant synergies.And field observation is to crop safety.
The above is only a preferred embodiment of the present invention, to those skilled in the art, this hair is not being departed from
It under the premise of bright raw material, can be suitably modified, these are improved also within protection scope of the present invention.
Claims (6)
1. a kind of Herbicidal combinations containing triazole sulphur humulone, it is characterised in that：Active ingredient by triazole sulphur humulone, tembotrions and
Nicosulfuron forms, and the weight ratio of the triazole sulphur humulone, tembotrions and nicosulfuron is 1-60:1-50:1-25.
2. a kind of Herbicidal combinations containing triazole sulphur humulone according to claim 1, it is characterised in that：The triazole sulphur
The weight ratio of humulone, tembotrions and nicosulfuron is 10-50:15-35:5-15.
3. a kind of Herbicidal combinations containing triazole sulphur humulone according to claim 1 or 2, it is characterised in that：Described three
The total weight percentage composition of azoles sulphur humulone, tembotrions and nicosulfuron in the composition is 1-90%.
4. a kind of Herbicidal combinations containing triazole sulphur humulone according to claim 3, it is characterised in that：The triazole sulphur
The total weight percentage composition of humulone, tembotrions and nicosulfuron in the composition is 20-65%.
5. according to a kind of Herbicidal combinations containing triazole sulphur humulone of claim 1-4 any one of them, it is characterised in that：Group
It is one kind in suspending agent, wettable powder, water dispersible granules etc. to close agent type.
6. a kind of Herbicidal combinations containing triazole sulphur humulone according to claim 1 are suitable for Control Weeds in Maize Field.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810242382.7A CN108338178B (en) | 2018-03-22 | Weeding composition containing triazolesulfonone |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810242382.7A CN108338178B (en) | 2018-03-22 | Weeding composition containing triazolesulfonone |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111955466A (en) * | 2020-07-20 | 2020-11-20 | 京博农化科技有限公司 | Weeding composition containing topramezone, tembotrione and nicosulfuron, preparation and application |
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| WO2003047340A2 (en) * | 2001-12-07 | 2003-06-12 | Bayer Cropscience Gmbh | Synergistic herbicidal agents |
| CN104920415A (en) * | 2015-06-10 | 2015-09-23 | 王万平 | Herbicide for wheat fields |
| CN105831123A (en) * | 2016-04-15 | 2016-08-10 | 青岛清原抗性杂草防治有限公司 | Corn field weeding composition and application thereof |
| CN106922676A (en) * | 2017-03-10 | 2017-07-07 | 合肥星宇化学有限责任公司 | Ring sulphur ketone and triazole sulphur humulone complex herbicidal composition and its preparation and application |
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| WO2003047340A2 (en) * | 2001-12-07 | 2003-06-12 | Bayer Cropscience Gmbh | Synergistic herbicidal agents |
| CN104920415A (en) * | 2015-06-10 | 2015-09-23 | 王万平 | Herbicide for wheat fields |
| CN105831123A (en) * | 2016-04-15 | 2016-08-10 | 青岛清原抗性杂草防治有限公司 | Corn field weeding composition and application thereof |
| CN106922676A (en) * | 2017-03-10 | 2017-07-07 | 合肥星宇化学有限责任公司 | Ring sulphur ketone and triazole sulphur humulone complex herbicidal composition and its preparation and application |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN111955466A (en) * | 2020-07-20 | 2020-11-20 | 京博农化科技有限公司 | Weeding composition containing topramezone, tembotrione and nicosulfuron, preparation and application |
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