CN108329773A - A kind of mildew resistant paint for crops - Google Patents
A kind of mildew resistant paint for crops Download PDFInfo
- Publication number
- CN108329773A CN108329773A CN201810157247.2A CN201810157247A CN108329773A CN 108329773 A CN108329773 A CN 108329773A CN 201810157247 A CN201810157247 A CN 201810157247A CN 108329773 A CN108329773 A CN 108329773A
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- weight
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- crops
- resistant paint
- mildew resistant
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D129/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal, or ketal radical; Coating compositions based on hydrolysed polymers of esters of unsaturated alcohols with saturated carboxylic acids; Coating compositions based on derivatives of such polymers
- C09D129/02—Homopolymers or copolymers of unsaturated alcohols
- C09D129/04—Polyvinyl alcohol; Partially hydrolysed homopolymers or copolymers of esters of unsaturated alcohols with saturated carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/14—Gas barrier composition
Abstract
This application involves the technical field of coating, more particularly to a kind of mildew resistant paint for crops, by weight score meters, including following components：30~70 parts by weight of matrix resin, 40~80 parts by weight of solvent, 0.2~2 parts by weight of modified rosin and its derivative, 0.2~15 parts by weight of mould inhibitor, 0.3~2 parts by weight of deoxidier, 0.2~1 parts by weight of antifoaming agent；Wherein, the matrix resin includes polyvinylidene chloride and polyvinyl alcohol, and the weight ratio of polyvinylidene chloride and polyvinyl alcohol is 1:2.The mildew resistant paint is using fine and close high-barrier resin, by oxygen and water resistance every the moisture in preservation crops, achieve the effect that anti-mildew fresh-keeping, deoxidier, removal wherein oxygen are added in mildew resistant paint, it prevents crops from going mouldy in respiratory, further extends the shelf-life of crops.
Description
Technical field
This application involves the technical fields of coating, more particularly to a kind of mildew resistant paint for crops.
Background technology
Grain, vegetables are indispensable food in people's daily life, and people therefrom absorb multivitamin, inorganic matter
And other useful components, but due to, containing 80% or more moisture, in its natural state, easily being evaporated in grain, vegetables, then add
Upper fosterization, the effect of enzyme and its infringement of external microbe of itself, causes grain, vegetables to be difficult to store, easily goes mouldy.
In numerous preservation technologies, coating preservation technology is more mature.Currently, having a kind of mildew resistant paint, by polyvinyl alcohol
Class film forming matter is formed with growth regulator and less toxic fungicide compounding, stores 4 months healthy fruits 87.86%, and rotten fruit rate is
2.45%.The mildew resistant paint cost is relatively low, and the mildew resistant paint is for that in the packaging material of grain, can effectively prevent grain mouldy.
However, adding disinfectant use in agriculture in existing mildew resistant paint, there are the harm such as pesticide residue.Therefore, compel at present
Being essential, it is a kind of in nontoxic, harmless and energy long-period freshness preserving crops mildew resistant paints to develop.
Invention content
The application proposes a kind of mildew resistant paint for crops, shelf-life that is nontoxic, harmless and can extending crops.
The application proposes a kind of mildew resistant paint for crops, by weight score meter, including following components：Matrix resin
30~70 parts by weight, 40~80 parts by weight of solvent, 0.2~2 parts by weight of modified rosin and its derivative, 0.2~15 weight of mould inhibitor
Measure part, 0.3~2 parts by weight of deoxidier, 0.2~1 parts by weight of antifoaming agent；
Wherein, the matrix resin includes polyvinylidene chloride and polyvinyl alcohol, polyvinylidene chloride and polyvinyl alcohol
Weight ratio is 1:2.
Optionally, the mildew resistant paint for crops, by weight score meter, including following components：Matrix resin 40
~60 parts by weight, 50~70 parts by weight of solvent, 0.5~1.5 parts by weight of modified rosin and its derivative, 2~12 weight of mould inhibitor
Part, 0.5~1.8 parts by weight of deoxidier, 0.3~0.7 parts by weight of antifoaming agent.
Optionally, the mildew resistant paint for crops, by weight score meter, including following components：Matrix resin 50
Parts by weight, 60 parts by weight of solvent, 1 parts by weight of modified rosin and its derivative, 10 parts by weight of mould inhibitor, 1.5 parts by weight of deoxidier,
0.5 parts by weight of antifoaming agent.
Optionally, the mould inhibitor includes sodium para-aminosalicylate and D-araboascorbic acid sodium, sodium para-aminosalicylate and
The weight ratio of D-araboascorbic acid sodium is 1：2~4.
Optionally, the mould inhibitor further includes xanthoxlin, Chinese herbal medicine extract and catechin, the xanthoxlin, Chinese herbal medicine
The weight ratio of extract and catechin is 2~3:1:0.5~0.75.
Optionally, the solvent is water.
Optionally, the mildew resistant paint for crops, preparation method includes the following steps：
Step 1：Matrix resin is put into reaction kettle, stirring solvent is added；
Step 2：After mould inhibitor is added into deoxidier, it is dissolved in water, obtains mixture；
Step 3：While the mixture is added dropwise into the reaction kettle, first stage stirring is carried out；
Step 4：After dripping the mixture, antifoaming agent is added, carries out second stage stirring, obtains the mould proof painting
Material.
By above technical scheme, present applicant proposes a kind of mildew resistant paints for crops, by weight score meter, including
Following components：30~70 parts by weight of matrix resin, 40~80 parts by weight of solvent, 0.2~2 weight of modified rosin and its derivative
Part, 0.2~15 parts by weight of mould inhibitor, 0.3~2 parts by weight of deoxidier, 0.2~1 parts by weight of antifoaming agent；Wherein, the main body tree
Fat includes polyvinylidene chloride and polyvinyl alcohol, and the weight ratio of polyvinylidene chloride and polyvinyl alcohol is 1:2.The mould proof painting
Material using fine and close high-barrier resin, by oxygen and water resistance every, preserve the moisture in crops, achieve the effect that anti-mildew fresh-keeping,
Deoxidier is added in mildew resistant paint, removal wherein oxygen prevents crops from going mouldy in respiratory, further extends
The shelf-life of crops.
Specific implementation mode
The application proposes a kind of mildew resistant paint for crops, by weight score meter, including following components：Matrix resin
30~70 parts by weight, 40~80 parts by weight of solvent, 0.2~2 parts by weight of modified rosin and its derivative, 0.2~15 weight of mould inhibitor
Measure part, 0.3~2 parts by weight of deoxidier, 0.2~1 parts by weight of antifoaming agent；Wherein, the matrix resin includes polyvinylidene chloride
And polyvinyl alcohol, the weight ratio of polyvinylidene chloride and polyvinyl alcohol is 1:2.
It should be noted that the mildew resistant paint for crops is applied to the packaging of the non-staple food such as crops, lead to
It crosses mildew resistant paint and applies the holding time that can extend the non-staple food such as crops in packaging.
Resin typically refer to it is heated after have hardening or a fusion range, there are liquidity preference, room temperature in when softening under external force
Under be solid-state, semisolid, can also be the organic polymer of liquid sometimes.The polyvinylidene chloride and polyvinyl alcohol are will to prevent
Mould coating firm attachment and the main matter that film is formed in packaging, are the bases for constituting mildew resistant paint, the two has with mould inhibitor
There is good intersolubility so that mould inhibitor can be distributed in resin, prevent fungus growth.
Modified rosin resin main component is various resin acids (molecular formula C19H29COOH), these pass through chemical process
Rosin product.With the addition product of polyhydric alcohol rosin and cis-butenedioic anhydride, obtained modified resin, referred to as Rosin Maleic polyalcohol
Ester is mainly used in the industries such as paint, ink, can improve dried coating film, water-tolerant, and hardness is high.
Deoxidier is absorbable oxygen, slows down the additive of Food Oxidation effect.Deoxidier can effectively inhibit mould and
The growth of aerobic bacteria extends Food Shelf-life, is preventing oxidizing brown stain that is spoiled by rancid oil or fat, preventing meat and preventing food
Loss of middle vitamin etc. can also be played the role of good.Enzyme system deoxidier is to pH, salt content, temperature and other factors
Variation is all very sensitive, and the participation of water is also needed in reaction, enzyme system deoxidier is fixed on polypropylene or polyethylene film, can remove
Wherein oxygen.
Antifoaming agent, also referred to as defomaing agent are that surface tension is reduced in food processing process, and foam is inhibited to generate or eliminate
Generate the food additives of foam.Common antifoaming agent has the fatty acid ester compounded object of silicone emulsion, higher alcohols, polyoxyethylene polyoxy
Propylene pentaerythrite ether, polyoxyethylene polyoxy propyl alcohol amidogen ether, polypropylene glycerol aether and polyoxyethylene polyoxypropylene glycerin ether gather
7 kinds of dimethyl siloxane etc..
Optionally, the mildew resistant paint for crops, by weight score meter, including following components：Matrix resin 40
~60 parts by weight, 50~70 parts by weight of solvent, 0.5~1.5 parts by weight of modified rosin and its derivative, 2~12 weight of mould inhibitor
Part, 0.5~1.8 parts by weight of deoxidier, 0.3~0.7 parts by weight of antifoaming agent.
Optionally, the mildew resistant paint for crops, by weight score meter, including following components：Matrix resin 50
Parts by weight, 60 parts by weight of solvent, 1 parts by weight of modified rosin and its derivative, 10 parts by weight of mould inhibitor, 1.5 parts by weight of deoxidier,
0.5 parts by weight of antifoaming agent.
Optionally, the mould inhibitor includes sodium para-aminosalicylate and D-araboascorbic acid sodium, sodium para-aminosalicylate and
The weight ratio of D-araboascorbic acid sodium is 1：2~4；
Optionally, the mould inhibitor further includes xanthoxlin, Chinese herbal medicine extract and catechin, the xanthoxlin, Chinese herbal medicine
The weight ratio of extract and catechin is 2~3:1:0.5~0.75.
Mould inhibitor is the medicament that can prevent microorganism from causing food mouldy, sodium para-aminosalicylate and D-araboascorbic acid sodium
For antioxidant fresh-keeping agent important in food service industry, the color and luster of food, natural flavor can be kept to extend the shelf life, and without any poison
Side effect is mainly used for meat products, fruit, vegetables, can, jam, beer, carbonated drink, fruit tea, fruit juice, Portugal in the food industry
Grape wine etc..Xanthoxlin, Chinese herbal medicine extract and catechin are assisted class mould inhibitor, prevent fungus growth.
Optionally, the solvent is water.Solvent can be such that active principle evenly spreads on matrix resin.
Optionally, the mildew resistant paint for crops, preparation method includes the following steps：
Step 1：Matrix resin is put into reaction kettle, stirring solvent is added；
Step 2：After mould inhibitor is added into deoxidier, it is dissolved in water, obtains mixture；
Step 3：While the mixture is added dropwise into the reaction kettle, first stage stirring is carried out；
Step 4：After dripping the mixture, antifoaming agent is added, carries out second stage stirring, obtains the mould proof painting
Material.
By above technical scheme, present applicant proposes a kind of mildew resistant paints for crops, using fine and close high-barrier
Resin, by oxygen and water resistance every the moisture in preservation crops achievees the effect that anti-mildew fresh-keeping, is added in mildew resistant paint de-
Oxygen agent, removal wherein oxygen, prevents crops from going mouldy in respiratory, further extends the shelf-life of crops.
Embodiment 1
A kind of mildew resistant paint for crops, by weight score meter, including following components：30 parts by weight of matrix resin,
40 parts by weight of solvent, 0.2 parts by weight of modified rosin and its derivative, 0.2 parts by weight of mould inhibitor, 0.3 parts by weight of deoxidier, defoaming
0.2 parts by weight of agent；Wherein, the matrix resin includes polyvinylidene chloride and polyvinyl alcohol, polyvinylidene chloride and polyethylene
The weight ratio of alcohol is 1:2.The mould inhibitor includes sodium para-aminosalicylate and D-araboascorbic acid sodium, PAS
The weight ratio of sodium and D-araboascorbic acid sodium is 1：2~4；The mould inhibitor further includes xanthoxlin, Chinese herbal medicine extract and
The weight ratio of catechin, the xanthoxlin, Chinese herbal medicine extract and catechin is 2~3:1:0.5~0.75.The solvent
For water.
The preparation method of the mildew resistant paint for crops includes the following steps：
Step 1：Matrix resin is put into reaction kettle, be added 5~15min of stirring solvent, rotating speed be 100~300 turns/
min；
Step 2：After mould inhibitor is added into deoxidier, it is dissolved in water, obtains mixture；
Step 3：While the mixture is added dropwise into the reaction kettle, first stage stirring, rotating speed 800 are carried out
~1000 turns/min, the time of titration is 1~2h；
Step 4：After dripping the mixture, antifoaming agent is added, carries out second stage and stirs 1~2h, obtains described anti-
Mould coating.
Embodiment 2
A kind of mildew resistant paint for crops, by weight score meter, including following components：70 parts by weight of matrix resin,
80 parts by weight of solvent, 2 parts by weight of modified rosin and its derivative, 15 parts by weight of mould inhibitor, 2 parts by weight of deoxidier, 1 weight of antifoaming agent
Measure part；Wherein, the matrix resin includes polyvinylidene chloride and polyvinyl alcohol, the weight of polyvinylidene chloride and polyvinyl alcohol
Part ratio is 1:2.The mould inhibitor includes sodium para-aminosalicylate and D-araboascorbic acid sodium, and sodium para-aminosalicylate and D- are different
The weight ratio of sodium ascorbate is 1：2~4；The mould inhibitor further includes xanthoxlin, Chinese herbal medicine extract and catechin, institute
The weight ratio for stating xanthoxlin, Chinese herbal medicine extract and catechin is 2~3:1:0.5~0.75.The solvent is water.
The preparation method of the mildew resistant paint for crops includes the following steps：
Step 1：Matrix resin is put into reaction kettle, be added 5~15min of stirring solvent, rotating speed be 100~300 turns/
min；
Step 2：After mould inhibitor is added into deoxidier, it is dissolved in water, obtains mixture；
Step 3：While the mixture is added dropwise into the reaction kettle, first stage stirring, rotating speed 800 are carried out
~1000 turns/min, the time of titration is 1~2h；
Step 4：After dripping the mixture, antifoaming agent is added, carries out second stage and stirs 1~2h, obtains described anti-
Mould coating.
Embodiment 3
A kind of mildew resistant paint for crops, by weight score meter, including following components：50 parts by weight of matrix resin,
60 parts by weight of solvent, 1 parts by weight of modified rosin and its derivative, 10 parts by weight of mould inhibitor, 1.5 parts by weight of deoxidier, antifoaming agent
0.5 parts by weight；Wherein, the matrix resin includes polyvinylidene chloride and polyvinyl alcohol, polyvinylidene chloride and polyvinyl alcohol
Weight ratio be 1:2.The mould inhibitor includes sodium para-aminosalicylate and D-araboascorbic acid sodium, sodium para-aminosalicylate
Weight ratio with D-araboascorbic acid sodium is 1：2~4；The mould inhibitor further includes xanthoxlin, Chinese herbal medicine extract and youngster
The weight ratio of theine, the xanthoxlin, Chinese herbal medicine extract and catechin is 2~3:1:0.5~0.75.The solvent is
Water.
The preparation method of the mildew resistant paint for crops includes the following steps：
Step 1：Matrix resin is put into reaction kettle, be added 5~15min of stirring solvent, rotating speed be 100~300 turns/
min；
Step 2：After mould inhibitor is added into deoxidier, it is dissolved in water, obtains mixture；
Step 3：While the mixture is added dropwise into the reaction kettle, first stage stirring, rotating speed 800 are carried out
~1000 turns/min, the time of titration is 1~2h；
Step 4：After dripping the mixture, antifoaming agent is added, carries out second stage and stirs 1~2h, obtains described anti-
Mould coating.
Embodiment 4
Fungicidal properties contrast test：The obtained mildew resistant paints of embodiment 1-3 are applied in the packaging of vegetables, with normal packet
The mould quantity of the vegetables of dress and packless vegetables is compared.
Test method：The vegetables in packaging will be placed on to take out at interval of a period of time, be placed in water and clean, use liquid-transfering gun
The solution for taking out certain volume is placed on nutrients, then with the quantity of mould in micro- sem observation solution, is compared using mould proof
Packaging, ordinary packing and the quantity without the mould of vegetables in packaging of coating.
Found by comparison, the result measured after 10 days is to have a less mould on packless vegetables, ordinary packing and
Using the vegetables in the packaging of mildew resistant paint without mould.
The result measured after 30 days is to have a large amount of mould on packless vegetables, and the vegetables in ordinary packing have a small amount of mould
Bacterium, the vegetables in the packaging for the mildew resistant paint that Application Example 1-3 is obtained are without mould.
The result measured after 120 days be without packaging and ordinary packing in vegetables on have a large amount of moulds, Application Example 1-3
There is a small amount of mould in the packaging of obtained mildew resistant paint.
To sum up, the fungistatic effect of the packaging for the mildew resistant paint that Application Example 1-3 is obtained is better than ordinary packing and Wu Bao
Fill the fungistatic effect to vegetables.
By above technical scheme, present applicant proposes a kind of mildew resistant paints for crops, by weight score meter, including
Following components：30~70 parts by weight of matrix resin, 40~80 parts by weight of solvent, 0.2~2 weight of modified rosin and its derivative
Part, 0.2~15 parts by weight of mould inhibitor, 0.3~2 parts by weight of deoxidier, 0.2~1 parts by weight of antifoaming agent；Wherein, the main body tree
Fat includes polyvinylidene chloride and polyvinyl alcohol, and the weight ratio of polyvinylidene chloride and polyvinyl alcohol is 1:2.The mould proof painting
Material using fine and close high-barrier resin, by oxygen and water resistance every, preserve the moisture in crops, achieve the effect that anti-mildew fresh-keeping,
Deoxidier is added in mildew resistant paint, removal wherein oxygen prevents crops from going mouldy in respiratory, further extends
The shelf-life of crops.
The above is only the specific implementation mode of the application, is made skilled artisans appreciate that or realizing this Shen
Please.Various modifications to these embodiments will be apparent to one skilled in the art, as defined herein
General Principle can in other embodiments be realized in the case where not departing from spirit herein or range.Therefore, the application
It is not intended to be limited to the embodiments shown herein, and is to fit to and the principles and novel features disclosed herein phase one
The widest range caused.
It should be understood that the application is not limited to the content being described above, and its model can not departed from
It encloses and carry out various modifications and change.Scope of the present application is only limited by the accompanying claims.
Claims (7)
1. a kind of mildew resistant paint for crops, which is characterized in that score meter by weight, including following components：Matrix resin
30~70 parts by weight, 40~80 parts by weight of solvent, 0.2~2 parts by weight of modified rosin and its derivative, 0.2~15 weight of mould inhibitor
Measure part, 0.3~2 parts by weight of deoxidier, 0.2~1 parts by weight of antifoaming agent；
Wherein, the matrix resin includes polyvinylidene chloride and polyvinyl alcohol, the weight of polyvinylidene chloride and polyvinyl alcohol
Part ratio is 1:2.
2. the mildew resistant paint according to claim 1 for crops, which is characterized in that score meter by weight, including with
Lower component：40~60 parts by weight of matrix resin, 50~70 parts by weight of solvent, 0.5~1.5 weight of modified rosin and its derivative
Part, 2~12 parts by weight of mould inhibitor, 0.5~1.8 parts by weight of deoxidier, 0.3~0.7 parts by weight of antifoaming agent.
3. the mildew resistant paint according to claim 1 for crops, which is characterized in that score meter by weight, including with
Lower component：50 parts by weight of matrix resin, 60 parts by weight of solvent, 1 parts by weight of modified rosin and its derivative, 10 weight of mould inhibitor
Part, 1.5 parts by weight of deoxidier, 0.5 parts by weight of antifoaming agent.
4. being used for the mildew resistant paint of crops according to claim 1-3 any one of them, which is characterized in that the mould inhibitor packet
Include sodium para-aminosalicylate and D-araboascorbic acid sodium, the weight ratio of sodium para-aminosalicylate and D-araboascorbic acid sodium is
1：2~4.
5. the mildew resistant paint according to claim 4 for crops, which is characterized in that the mould inhibitor further includes Chinese prickly ash
The weight ratio of element, Chinese herbal medicine extract and catechin, the xanthoxlin, Chinese herbal medicine extract and catechin is 2~3:1:
0.5~0.75.
6. being used for the mildew resistant paint of crops according to claim 1-3 any one of them, which is characterized in that the solvent is
Water.
7. being used for the mildew resistant paint of crops according to claim 1-3 any one of them, which is characterized in that preparation method packet
Include following steps：
Step 1：Matrix resin is put into reaction kettle, stirring solvent is added；
Step 2：After mould inhibitor is added into deoxidier, it is dissolved in water, obtains mixture；
Step 3：While the mixture is added dropwise into the reaction kettle, first stage stirring is carried out；
Step 4：After dripping the mixture, antifoaming agent is added, carries out second stage stirring, obtains the mildew resistant paint.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810157247.2A CN108329773A (en) | 2018-02-24 | 2018-02-24 | A kind of mildew resistant paint for crops |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810157247.2A CN108329773A (en) | 2018-02-24 | 2018-02-24 | A kind of mildew resistant paint for crops |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN108329773A true CN108329773A (en) | 2018-07-27 |
Family
ID=62929774
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810157247.2A Pending CN108329773A (en) | 2018-02-24 | 2018-02-24 | A kind of mildew resistant paint for crops |
Country Status (1)
| Country | Link |
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| CN (1) | CN108329773A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111568641A (en) * | 2020-05-28 | 2020-08-25 | 刘子琛 | Novel eye patch heating material and preparation process thereof |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106634517A (en) * | 2016-12-29 | 2017-05-10 | 常德市金润新材料科技有限公司无锡新材料研究院 | Mildew-proof fresh-keeping paint and preparation method and application thereof |
-
2018
- 2018-02-24 CN CN201810157247.2A patent/CN108329773A/en active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106634517A (en) * | 2016-12-29 | 2017-05-10 | 常德市金润新材料科技有限公司无锡新材料研究院 | Mildew-proof fresh-keeping paint and preparation method and application thereof |
Non-Patent Citations (3)
| Title |
|---|
| 朱明德: "《商业园艺》", 31 May 2002, 中国农业出版社 * |
| 李喜宏等: "《果蔬薄膜保鲜技术》", 30 September 2003, 天津科学技术出版社 * |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111568641A (en) * | 2020-05-28 | 2020-08-25 | 刘子琛 | Novel eye patch heating material and preparation process thereof |
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Application publication date: 20180727 |