CN108329584A - A kind of thermocouple temperature sensor encapsulating housing - Google Patents

A kind of thermocouple temperature sensor encapsulating housing Download PDF

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Publication number
CN108329584A
CN108329584A CN201711433180.2A CN201711433180A CN108329584A CN 108329584 A CN108329584 A CN 108329584A CN 201711433180 A CN201711433180 A CN 201711433180A CN 108329584 A CN108329584 A CN 108329584A
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parts
flaxen fiber
toughening
temperature sensor
thermocouple temperature
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CN201711433180.2A
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Chinese (zh)
Inventor
高凤谊
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Anhui Ruixin Automation Instrument Co Ltd
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Anhui Ruixin Automation Instrument Co Ltd
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Priority to CN201711433180.2A priority Critical patent/CN108329584A/en
Publication of CN108329584A publication Critical patent/CN108329584A/en
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10Homopolymers or copolymers of propene
    • C08L23/12Polypropene
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M10/00Physical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. ultrasonic, corona discharge, irradiation, electric currents, or magnetic fields; Physical treatment combined with treatment with chemical compounds or elements
    • D06M10/001Treatment with visible light, infrared or ultraviolet, X-rays
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/77Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof
    • D06M11/79Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof with silicon dioxide, silicic acids or their salts
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/50Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with organometallic compounds; with organic compounds containing boron, silicon, selenium or tellurium atoms
    • D06M13/51Compounds with at least one carbon-metal or carbon-boron, carbon-silicon, carbon-selenium, or carbon-tellurium bond
    • D06M13/513Compounds with at least one carbon-metal or carbon-boron, carbon-silicon, carbon-selenium, or carbon-tellurium bond with at least one carbon-silicon bond
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2237Oxides; Hydroxides of metals of titanium
    • C08K2003/2241Titanium dioxide
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2296Oxides; Hydroxides of metals of zinc
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/011Nanostructured additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/08Stabilised against heat, light or radiation or oxydation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00Applications
    • C08L2203/20Applications use in electrical or conductive gadgets
    • C08L2203/206Applications use in electrical or conductive gadgets use in coating or encapsulating of electronic parts
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/08Polymer mixtures characterised by other features containing additives to improve the compatibility between two polymers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/14Polymer mixtures characterised by other features containing polymeric additives characterised by shape
    • C08L2205/16Fibres; Fibrils
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/02Natural fibres, other than mineral fibres
    • D06M2101/04Vegetal fibres
    • D06M2101/06Vegetal fibres cellulosic

Abstract

The invention discloses a kind of thermocouple temperature sensor encapsulating housing, raw material includes by weight:80 90 parts of major ingredient, 12 parts of cumyl peroxide, 0.2 0.9 parts of zinc oxide, 35 42 parts of toughening flaxen fiber, 20 30 parts of medical stone powder, 8 17 parts of melmac, 2 10 parts of nano-titanium dioxide, 28 parts of polyacrylonitrile-based carbon fibre, 24 parts of compatilizer, 12 parts of lubricant, 12 parts of Masterbatch, 13 parts of dispersant, 12 parts of antioxidant, 12 parts of ultraviolet light absorbent.Toughening flaxen fiber is prepared using following technique:Flaxen fiber, talcum powder, dispersant, water are mixed, regulation system pH value is 6.4 6.8, and heating stirring is added silane coupling agent KH 550 and stirs, and ultraviolet irradiation processing is filtered, and washing is dried to obtain toughening flaxen fiber.Not only mechanical property is good by the present invention, high-low temperature resistant, and tearing-resistant performance is excellent.

Description

A kind of thermocouple temperature sensor encapsulating housing
Technical field
The present invention relates to temperature sensor technology field more particularly to a kind of thermocouple temperature sensor encapsulating housings.
Background technology
Temperature sensor is divided into contact and contactless two major classes by measurement method, according to sensor internal element material It is divided into thermal resistance and thermocouple two major classes.Currently, in aviation field field of pyrometry, it is widely used most for thermoelectricity Even, the internal enclosing structure of thermocouple temperature sensor is one of its key technology, on the one hand rational encapsulating material can carry On the other hand the reliability of high product can improve response time, the measurement accuracy of sensor.Existing encapsulating material is generally adopted It is prepared, is existed intolerant to hot and cold alternation with plastic material, the technical issues of crack easily occurs in encapsulating housing, cannot meet control system It is required that.
Invention content
Technical problems based on background technology, the present invention propose a kind of thermocouple temperature sensor encapsulating shell Body, not only mechanical property is good, high-low temperature resistant, and tearing-resistant performance is excellent, while water resistance is extremely excellent.
A kind of thermocouple temperature sensor encapsulating housing proposed by the present invention, raw material include by weight:Major ingredient 80- 90 parts, 1-2 parts of cumyl peroxide, 0.2-0.9 parts of zinc oxide, 35-42 parts of toughening flaxen fiber, 20-30 parts of medical stone powder, three 8-17 parts of cymel, 2-10 parts of nano-titanium dioxide, 2-8 parts of polyacrylonitrile-based carbon fibre, 2-4 parts of compatilizer, lubricant 1-2 parts, 1-2 parts of Masterbatch, 1-3 parts of dispersant, 1-2 parts of antioxidant, 1-2 parts of ultraviolet light absorbent.
Preferably, toughening flaxen fiber is prepared using following technique:Flaxen fiber, talcum powder, dispersant, water are mixed, adjusted System pH is 6.4-6.8, heating stirring, and silane resin acceptor kh-550 stirring is added, and ultraviolet irradiation processing is filtered, washed, does It is dry to obtain toughening flaxen fiber.
Preferably, in the preparation process of toughening flaxen fiber, regulation system pH value is 6.4-6.8, is warming up to 80-90 DEG C of stirring 10-15min。
Preferably, in the preparation process of toughening flaxen fiber, ultraviolet irradiation processing time is 5-12min, ultraviolet irradiation wavelength For 240-260nm, irradiation distance 100-120mm.
Preferably, in the preparation process of toughening flaxen fiber, flaxen fiber, talcum powder, dispersant, water, silane coupling agent KH- 550 weight ratio is 30-40:5-10:1-2:80-120:0.2-0.6.
Preferably, major ingredient includes by weight:40-60 parts of polypropylene, 15-25 parts of polyarylsulfone (PAS), acrylonitrile-butadiene-benzene 10-20 parts of ethylene copolymer.
Preferably, compatilizer includes by weight:1-2 parts of phthalic anhydride, 1-2 parts of butyl titanate.
Using polypropylene, polyarylsulfone (PAS), acrylonitrile-butadiene-styrene copolymer, as major ingredient, peroxidating is added in the present invention Diisopropylbenzene (DIPB) cures, and making the present invention, not only mechanical property is good, high-low temperature resistant, and tearing-resistant performance is excellent, using O-phthalic Acid anhydrides and butyl titanate cooperation, improve toughening flaxen fiber, medical stone powder, melmac, nano-titanium dioxide, polypropylene The compatibility of itrile group carbon fiber and major ingredient, shock resistance further enhances after solidification, and tearing-resistant performance is excellent.
In the toughening flaxen fiber of the present invention, flaxen fiber and talcum powder are fully dispersed under the action of dispersant, by irradiation The active group of flaxen fiber can be combined with group in the lamella of talcum powder in the form of covalent bond after processing, on the one hand be had fabulous Toughening effect can still keep fabulous tearing-resistant performance even if being subjected to hot and cold alternation, it is mutual on the other hand to form layer structure Connection, water resistance are extremely excellent;Toughening flaxen fiber under the cooperation of phthalic anhydride and butyl titanate, with polypropylene, Polyarylsulfone (PAS), the bond strength of acrylonitrile-butadiene-styrene copolymer are high, and filling effect is good, can lower the additive amount of major ingredient, Cost input is reduced, heat-resistant stability is good, and the present invention impregnates in the water of use -40~100 DEG C, impregnates 400h and does not lose Effect.
Specific implementation mode
In the following, technical scheme of the present invention is described in detail by specific embodiment.
Embodiment 1
A kind of thermocouple temperature sensor encapsulating housing, raw material include:Major ingredient 80g, cumyl peroxide 2g, oxygen Change zinc 0.2g, toughening flaxen fiber 42g, medical stone powder 20g, melmac 17g, nano-titanium dioxide 2g, polyacrylonitrile-radical Carbon fiber 8g, compatilizer 2g, lubricant 2g, Masterbatch 1g, dispersant 3g, antioxidant 1g, ultraviolet light absorbent 2g.
Major ingredient includes:Polypropylene 40g, polyarylsulfone (PAS) 25g, acrylonitrile-butadiene-styrene copolymer 10g.Compatilizer packet It includes:Phthalic anhydride 2g, butyl titanate 1g.
Toughening flaxen fiber is prepared using following technique:40g flaxen fibers, 5g talcum powder, 2g dispersants, 80g water are mixed, adjusted Section system pH is 6.4-6.8, is warming up to 90 DEG C of stirring 10min, and 0.6g silane resin acceptor kh-550s are added and stir 10min, purple External irradiation handles 12min, and ultraviolet irradiation wavelength is 240-260nm, irradiation distance 100mm, and filtering, deionized water is washed, dry It is dry to obtain toughening flaxen fiber.
Embodiment 2
A kind of thermocouple temperature sensor encapsulating housing, raw material include:Major ingredient 90g, cumyl peroxide 1g, oxygen Change zinc 0.9g, toughening flaxen fiber 35g, medical stone powder 30g, melmac 8g, nano-titanium dioxide 10g, polyacrylonitrile-radical Carbon fiber 2g, compatilizer 4g, lubricant 1g, Masterbatch 2g, dispersant 1g, antioxidant 2g, ultraviolet light absorbent 1g.
Major ingredient includes:Polypropylene 60g, polyarylsulfone (PAS) 15g, acrylonitrile-butadiene-styrene copolymer 20g.Compatilizer packet It includes:Phthalic anhydride 1g, butyl titanate 2g.
Toughening flaxen fiber is prepared using following technique:30g flaxen fibers, 10g talcum powder, 1g dispersants, 120g water are mixed, Regulation system pH value is 6.4-6.8, is warming up to 80 DEG C of stirring 15min, 0.2g silane resin acceptor kh-550s are added and stir 20min, Ultraviolet irradiation handles 5min, and ultraviolet irradiation wavelength is 240-260nm, irradiation distance 120mm, and filtering, deionized water is washed, dry It is dry to obtain toughening flaxen fiber.
Embodiment 3
A kind of thermocouple temperature sensor encapsulating housing, raw material include:Major ingredient 82g, cumyl peroxide 1.8g, Zinc oxide 0.4g, toughening flaxen fiber 40g, medical stone powder 22g, melmac 15g, nano-titanium dioxide 4g, polyacrylonitrile Base carbon fibre 6g, compatilizer 2.5g, lubricant 1.8g, Masterbatch 1.3g, dispersant 2.5g, antioxidant 1.2g, ultraviolet light are inhaled Receive agent 1.7g.
Major ingredient includes:Polypropylene 45g, polyarylsulfone (PAS) 22g, acrylonitrile-butadiene-styrene copolymer 12g.Compatilizer packet It includes:Phthalic anhydride 1.8g, butyl titanate 1.3g.
Toughening flaxen fiber is prepared using following technique:37g flaxen fibers, 6g talcum powder, 1.8g dispersants, 90g water are mixed, Regulation system pH value is 6.4-6.8, is warming up to 88 DEG C of stirring 12min, 0.5g silane resin acceptor kh-550s are added and stir 12min, Ultraviolet irradiation handles 10min, and ultraviolet irradiation wavelength is 240-260nm, irradiation distance 105mm, is filtered, deionized water washing, It is dried to obtain toughening flaxen fiber.
Embodiment 4
A kind of thermocouple temperature sensor encapsulating housing, raw material include:Major ingredient 88g, cumyl peroxide 1.2g, Zinc oxide 0.8g, toughening flaxen fiber 38g, medical stone powder 28g, melmac 10g, nano-titanium dioxide 8g, polyacrylonitrile Base carbon fibre 4g, compatilizer 3.5g, lubricant 1.2g, Masterbatch 1.7g, dispersant 1.5g, antioxidant 1.8g, ultraviolet light are inhaled Receive agent 1.3g.
Major ingredient includes:Polypropylene 55g, polyarylsulfone (PAS) 18g, acrylonitrile-butadiene-styrene copolymer 18g.Compatilizer packet It includes:Phthalic anhydride 1.2g, butyl titanate 1.7g.
Toughening flaxen fiber is prepared using following technique:33g flaxen fibers, 8g talcum powder, 1.2g dispersants, 110g water are mixed It closes, regulation system pH value is 6.4-6.8, is warming up to 82 DEG C of stirring 14min, the stirring of 0.3g silane resin acceptor kh-550s is added 18min, ultraviolet irradiation handle 6min, and ultraviolet irradiation wavelength is 240-260nm, irradiation distance 110mm, filtering, deionized water Washing, is dried to obtain toughening flaxen fiber.
The foregoing is only a preferred embodiment of the present invention, but scope of protection of the present invention is not limited thereto, Any one skilled in the art in the technical scope disclosed by the present invention, according to the technique and scheme of the present invention and its Inventive concept is subject to equivalent substitution or change, should be covered by the protection scope of the present invention.

Claims (7)

1. a kind of thermocouple temperature sensor encapsulating housing, which is characterized in that its raw material includes by weight:Major ingredient 80-90 Part, 1-2 parts of cumyl peroxide, 0.2-0.9 parts of zinc oxide, 35-42 parts of toughening flaxen fiber, 20-30 parts of medical stone powder, trimerization 8-17 parts of melamine resin, 2-10 parts of nano-titanium dioxide, 2-8 parts of polyacrylonitrile-based carbon fibre, 2-4 parts of compatilizer, lubricant 1-2 Part, 1-2 parts of Masterbatch, 1-3 parts of dispersant, 1-2 parts of antioxidant, 1-2 parts of ultraviolet light absorbent.
2. thermocouple temperature sensor encapsulating housing according to claim 1, which is characterized in that toughening flaxen fiber is using such as It is prepared by lower technique:Flaxen fiber, talcum powder, dispersant, water are mixed, regulation system pH value is 6.4-6.8, and heating stirring is added Silane resin acceptor kh-550 stirs, ultraviolet irradiation processing, filters, and washing is dried to obtain toughening flaxen fiber.
3. thermocouple temperature sensor encapsulating housing according to claim 2, which is characterized in that the preparation of toughening flaxen fiber In technique, regulation system pH value is 6.4-6.8, is warming up to 80-90 DEG C of stirring 10-15min.
4. according to thermocouple temperature sensor encapsulating housing described in Claims 2 or 3, which is characterized in that toughening flaxen fiber In preparation process, ultraviolet irradiation processing time is 5-12min, and ultraviolet irradiation wavelength is 240-260nm, irradiation distance 100- 120mm。
5. according to any one of the claim 2-4 thermocouple temperature sensor encapsulating housings, which is characterized in that toughening fiber crops are fine In the preparation process of dimension, flaxen fiber, talcum powder, dispersant, water, silane resin acceptor kh-550 weight ratio be 30-40:5-10: 1-2:80-120:0.2-0.6.
6. according to any one of the claim 1-5 thermocouple temperature sensor encapsulating housings, which is characterized in that major ingredient is by weight Measuring part includes:40-60 parts of polypropylene, 15-25 parts of polyarylsulfone (PAS), 10-20 parts of acrylonitrile-butadiene-styrene copolymer.
7. according to any one of the claim 1-6 thermocouple temperature sensor encapsulating housings, which is characterized in that compatilizer is pressed Parts by weight include:1-2 parts of phthalic anhydride, 1-2 parts of butyl titanate.
CN201711433180.2A 2017-12-26 2017-12-26 A kind of thermocouple temperature sensor encapsulating housing Withdrawn CN108329584A (en)

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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20120059100A1 (en) * 2010-09-07 2012-03-08 Xiamen Runner Industrial Corporatio Imitation metal engineering plastic composite material and preparation method of the same
CN104292620A (en) * 2014-09-24 2015-01-21 铜陵市新泰电容电器有限责任公司 Novel high-hardness plastic shell composition for capacitor
CN106117790A (en) * 2016-07-07 2016-11-16 蚌埠海明压铸机有限公司 A kind of high temperature resistant aging resistance modified plastic particles
CN107216549A (en) * 2017-06-01 2017-09-29 合肥尚强电气科技有限公司 A kind of antistatic weather-resistance flame-retardant electric instrument shell of high intensity and preparation method thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20120059100A1 (en) * 2010-09-07 2012-03-08 Xiamen Runner Industrial Corporatio Imitation metal engineering plastic composite material and preparation method of the same
CN104292620A (en) * 2014-09-24 2015-01-21 铜陵市新泰电容电器有限责任公司 Novel high-hardness plastic shell composition for capacitor
CN106117790A (en) * 2016-07-07 2016-11-16 蚌埠海明压铸机有限公司 A kind of high temperature resistant aging resistance modified plastic particles
CN107216549A (en) * 2017-06-01 2017-09-29 合肥尚强电气科技有限公司 A kind of antistatic weather-resistance flame-retardant electric instrument shell of high intensity and preparation method thereof

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Application publication date: 20180727