CN108329504A - A kind of antiultraviolet wave transparent coating and preparation method thereof based on polylactic acid tablet - Google Patents
A kind of antiultraviolet wave transparent coating and preparation method thereof based on polylactic acid tablet Download PDFInfo
- Publication number
- CN108329504A CN108329504A CN201810229506.8A CN201810229506A CN108329504A CN 108329504 A CN108329504 A CN 108329504A CN 201810229506 A CN201810229506 A CN 201810229506A CN 108329504 A CN108329504 A CN 108329504A
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- Prior art keywords
- polylactic acid
- acid tablet
- antiultraviolet
- wave transparent
- transparent coating
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- 239000004626 polylactic acid Substances 0.000 title claims abstract description 42
- 229920000747 poly(lactic acid) Polymers 0.000 title claims abstract description 40
- 239000011248 coating agent Substances 0.000 title claims abstract description 36
- 238000000576 coating method Methods 0.000 title claims abstract description 36
- 238000002360 preparation method Methods 0.000 title claims abstract description 11
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims abstract description 19
- 239000003085 diluting agent Substances 0.000 claims abstract description 16
- 229920002379 silicone rubber Polymers 0.000 claims abstract description 14
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 11
- 239000003822 epoxy resin Substances 0.000 claims abstract description 11
- 229920000647 polyepoxide Polymers 0.000 claims abstract description 11
- 238000000034 method Methods 0.000 claims abstract description 6
- 230000004224 protection Effects 0.000 claims abstract description 6
- 238000005507 spraying Methods 0.000 claims abstract description 3
- 239000000203 mixture Substances 0.000 claims description 19
- 239000011259 mixed solution Substances 0.000 claims description 16
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical group CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 12
- 239000011247 coating layer Substances 0.000 claims description 8
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 claims description 6
- 229920005573 silicon-containing polymer Polymers 0.000 claims description 6
- 239000007921 spray Substances 0.000 claims description 6
- 230000006750 UV protection Effects 0.000 claims description 5
- 230000002269 spontaneous effect Effects 0.000 claims description 5
- 230000008859 change Effects 0.000 claims description 3
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 2
- 229910052760 oxygen Inorganic materials 0.000 claims description 2
- 239000001301 oxygen Substances 0.000 claims description 2
- 230000005540 biological transmission Effects 0.000 abstract description 8
- 230000008901 benefit Effects 0.000 abstract description 5
- 239000000463 material Substances 0.000 description 8
- 239000002131 composite material Substances 0.000 description 7
- 230000000694 effects Effects 0.000 description 7
- 239000010410 layer Substances 0.000 description 5
- 238000002156 mixing Methods 0.000 description 5
- 230000005855 radiation Effects 0.000 description 5
- 239000011787 zinc oxide Substances 0.000 description 5
- 239000002245 particle Substances 0.000 description 4
- 238000009775 high-speed stirring Methods 0.000 description 3
- 230000001681 protective effect Effects 0.000 description 3
- 238000011160 research Methods 0.000 description 3
- 230000002745 absorbent Effects 0.000 description 2
- 239000002250 absorbent Substances 0.000 description 2
- 239000006096 absorbing agent Substances 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000005286 illumination Methods 0.000 description 2
- 239000006193 liquid solution Substances 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 239000000758 substrate Substances 0.000 description 2
- 239000012780 transparent material Substances 0.000 description 2
- 239000006097 ultraviolet radiation absorber Substances 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 238000004364 calculation method Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 238000005457 optimization Methods 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
- 238000002834 transmittance Methods 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
- C08J7/04—Coating
- C08J7/0427—Coating with only one layer of a composition containing a polymer binder
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D183/00—Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers
- C09D183/04—Polysiloxanes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/32—Radiation-absorbing paints
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2367/00—Characterised by the use of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Derivatives of such polymers
- C08J2367/04—Polyesters derived from hydroxy carboxylic acids, e.g. lactones
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2463/00—Characterised by the use of epoxy resins; Derivatives of epoxy resins
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2483/00—Characterised by the use of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen, or carbon only; Derivatives of such polymers
- C08J2483/04—Polysiloxanes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2296—Oxides; Hydroxides of metals of zinc
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Medicinal Preparation (AREA)
- Paints Or Removers (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
Abstract
The present invention discloses a kind of antiultraviolet wave transparent coating and preparation method thereof based on polylactic acid tablet, and the coating is prepared by polylactic acid tablet, Zinc oxide powder, silicon rubber, epoxy resin, curing agent and diluent.The nano-zinc oxide powder and silicon rubber by volume 1：2 are mixed and stirred for uniformly, and the epoxy resin, curing agent and diluent mass ratio are 10:1:10, by the coating spraying of preparation to polylactic acid tablet, 8h or more is dried under natural conditions.The advantage of the invention is that can be achieved at the same time antiultraviolet and high wave transmission rate, intensity is high, and simple for process, easy to operate, can be applied to the fields such as plasma discharge protection.
Description
Technical field
The present invention relates to field of compound material and plasma discharge to protect field, and Gao Wei can be met simultaneously by being related to one kind
The coating of wave transmissivity and anti-ultraviolet function, more particularly to a kind of antiultraviolet wave transparent coating based on polylactic acid tablet and its
Preparation method.
Background technology
The development of plasma technique has direct shadow to high-technology industry development and the transformation of many traditional industries
It rings, in absorbing property, many fields such as material surface modifying and flowing control are widely used.Currently, researcher couple
A large amount of theoretical, emulation and experimental study have been carried out by the complex flowfield for being covered in body surface that plasma generates.And for
The ultraviolet light of the plasma of discharge mode, especially dielectric barrier discharge pattern and glow discharge mode, generation can be to research
Personnel health causes damages.Therefore it needs to take certain safeguard procedures shielding ultraviolet rays when carrying out pilot plasma research
Influence.
The harm that ultraviolet radiation is brought in order to prevent, many ultra-violet absorbers are used to prepare antiultraviolet material,
Object is protected for being coated in outer surface.But many ultra-violet absorbers can not only shielding ultraviolet rays, Er Qiehui
The transmission performance of microwave is influenced, the research of this plasma absorbing property is a disaster.
Based on the above issues, need to prepare one kind can either ultraviolet radiation preventing, and it is new with excellent wave transmission rate
Composite material.
Invention content
In view of this, the purpose of the present invention is to provide a kind of antiultraviolet wave transparent coating based on polylactic acid tablet and its
Antiultraviolet and high wave transmission rate can be achieved at the same time in preparation method, can be applied to plasma discharge protection field.
To achieve the goals above, the technical solution adopted by the present invention is：
A kind of antiultraviolet wave transparent coating based on polylactic acid tablet, it is characterised in that：The coating by polylactic acid tablet,
Zinc oxide powder, silicon rubber, epoxy resin, curing agent and diluent are prepared.
Preferably, the Zinc oxide powder is nano-zinc oxide powder.
Preferably, the diluent is acetone or dimethyl silicone polymer.
The invention also discloses a kind of methods preparing the above-mentioned antiultraviolet wave transparent coating based on polylactic acid tablet, specifically
Steps are as follows：
(1) by the nano-zinc oxide powder and the silicon rubber by volume 1：2 are mixed, evenly dispersed to prepare
Mixture；
(2) by the epoxy resin, the curing agent and the diluent in mass ratio 10:1:The standby mixing of 10 assignment systems is molten
Mixture described in upper step is dissolved in mixed solution by liquid, and mixed solution is 90 with mixture quality ratio:10, high-speed stirred is mixed
Zoarium system；
(3) mixed system is sprayed on polylactic acid tablet using spray gun, 0.1~0.2mm of coating layer thickness is to get anti-
Ultraviolet light wave transparent coating.
Preferably, by the coating spraying to polylactic acid tablet made from step (3), spontaneous curing 8h or more.
Preferably, the Zinc oxide powder is nano-zinc oxide powder.
Preferably, the diluent is acetone or dimethyl silicone polymer.
Preferably, the coating can be applicable to plasma discharge protection field.
The invention has the characteristics that and excellent effect：
(1) ultraviolet radiation protective effect is good：Using nano-zinc oxide powder as ultra-violet absorber, zinc oxide is the present invention
The principle of a kind of physical absorbent, shielding ultraviolet rays is absorption and scatters, and the function of scatters ultraviolet and material particle size size
Correlation, nanometer particle can scatter ultraviolet light to all directions, reduce the uitraviolet intensity of direction of illumination, therefore nanoscale oxygen
Change zinc protectiving ultraviolet effect has apparent advantage compared with general size；
(2) wave transmission effect is excellent：Electromagnetic wave transparent material is typically to obtain energy by the dielectric constant and dissipation factor of adjusting material
Enough meet the composite material of requirement.Currently, the wave transmission rate of domestic advanced electromagnetic wave transparent material is between 90%~99%.The present invention
A kind of composite material of double-layer structure is collectively constituted using poly-lactic acid material, and with coating, by the dielectric for optimizing double-layer structure
Constant reduces the decaying for causing microwave irradiation coated tape because of the dielectric loss of zinc oxide, obtains higher wave transparent performance；
(3) composite material strength is high：Due to the use of polylactic acid tablet as substrate, the thickness of polylactic acid can be adjusted, is made
Composite material keeps higher intensity；
(4) preparation process of the invention is simple, easy to operate, can obtain preparing effect well under field conditions (factors).
Description of the drawings
By referring to the drawings to the description of the embodiment of the present invention, the above and other purposes of the present invention, feature and
Advantage will be apparent from, in the accompanying drawings：
Fig. 1 is the transmittance graph figure of the embodiment of the present invention.
Specific implementation mode
A kind of antiultraviolet wave transparent coating based on polylactic acid tablet, the coating by polylactic acid tablet, Zinc oxide powder,
Silicon rubber, epoxy resin, curing agent and diluent are prepared.
By the present invention in that using polylactic acid tablet as substrate, the thickness of polylactic acid can be adjusted, composite material is made to keep
Higher intensity, poly-lactic acid material and the coating of use collectively constitute a kind of composite material of double-layer structure.
For the present invention using nano-zinc oxide powder as ultra-violet absorber, zinc oxide is a kind of physical absorbent, shielding
The principle of ultraviolet light is to absorb and scatter, and the function of scatters ultraviolet is related to material particle size size, and nanometer particle can incite somebody to action
Ultraviolet light is scattered to all directions, reduces the uitraviolet intensity of direction of illumination, therefore Nano-class zinc oxide protectiving ultraviolet effect
There is apparent advantage compared with general size.
Matrix of the present invention using silicon rubber as coating, by adjusting the volume ratio of Zinc oxide powder and silicon rubber, optimization
The dielectric constant of double-layer structure reduces the decaying for causing microwave irradiation coated tape because of the dielectric loss of zinc oxide, obtains more
High wave transparent performance.
The present invention is using acetone or dimethyl silicone polymer as diluent, acetone or dimethyl silicone polymer with readily soluble
In the organic solvents such as silicon rubber the advantages of.
The invention also discloses the method for preparing the antiultraviolet wave transparent coating described above based on polylactic acid tablet, tools
Steps are as follows for body：
(1) by the nano-zinc oxide powder and the silicon rubber by volume 1：2 are mixed, evenly dispersed to prepare
Mixture；
(2) by the epoxy resin, the curing agent and the diluent in mass ratio 10:1:The standby mixing of 10 assignment systems is molten
Mixture described in upper step is dissolved in mixed solution by liquid, and mixed solution is 90 with mixture quality ratio:10, high-speed stirred is mixed
Zoarium system；
(3) mixed system is sprayed on polylactic acid tablet using spray gun, 0.1~0.2mm of coating layer thickness, it is naturally solid
Change 8h or more to get antiultraviolet wave transparent coating.
The preparation process of the present invention is simple, easy to operate, can obtain preparing effect well under field conditions (factors).
Present invention is described for several embodiments exemplified below, but the present invention is not restricted to these embodiments.
The following examples are only intended to that the present invention will be described in detail, do not limit the protection domain of invention in any way.
(1) embodiment 1
The first step：By nano-zinc oxide powder and silicon rubber by volume 1：2 are mixed, evenly dispersed to prepare mixing
Object；
Second step：By epoxy resin described in claim 1, curing agent and diluent in mass ratio 10:1:10 assignment systems
Mixture described in upper step is dissolved in mixed solution by standby mixed solution, and mixed solution is 90 with mixture quality ratio:10, high-speed stirring
It mixes to obtain mixed system；
Third walks：Mixed system is sprayed on polylactic acid tablet using spray gun, spontaneous curing 8h or more is to get UV resistance
The thickness of line wave transparent coating, coating layer thickness 0.1mm, polylactic acid tablet is 1mm.
(2) embodiment 2
The first step：By nano-zinc oxide powder and silicon rubber by volume 1：2 are mixed, evenly dispersed to prepare mixing
Object；
Second step：By epoxy resin described in claim 1, curing agent and diluent in mass ratio 10:1:10 assignment systems
Mixture described in upper step is dissolved in mixed solution by standby mixed solution, and mixed solution is 90 with mixture quality ratio:10, high-speed stirring
It mixes to obtain mixed system；
Third walks：Mixed system is sprayed on polylactic acid tablet using spray gun, spontaneous curing 8h or more is to get UV resistance
The thickness of line wave transparent coating, coating layer thickness 0.15mm, polylactic acid tablet is 1mm.
(3) embodiment 3
The first step：By nano-zinc oxide powder and silicon rubber by volume 1：2 are mixed, evenly dispersed to prepare mixing
Object；
Second step：By epoxy resin described in claim 1, curing agent and diluent in mass ratio 10:1:10 assignment systems
Mixture described in upper step is dissolved in mixed solution by standby mixed solution, and mixed solution is 90 with mixture quality ratio:10, high-speed stirring
It mixes to obtain mixed system；
Third walks：Mixed system is sprayed on polylactic acid tablet using spray gun, spontaneous curing 8h or more is to get UV resistance
The thickness of line wave transparent coating, coating layer thickness 0.2mm, polylactic acid tablet is 1mm.
Further, experimental analysis is carried out to the ultraviolet radiation protective effect of Examples 1 to 3 and transmissivity, the present invention is imitated
Fruit illustrates：
As shown in Figure 1, the transmissivity minimum of Examples 1 to 3 more than 90% or more, has fine wave transmission effect：It is real
It applies in example 1, mass ratio shared by nano zine oxide mixture is 10%, coating layer thickness 0.1mm, polylactic acid slab-thickness 1mm, transmission
Rate is in 2~18GHz frequency ranges more than 95%；In embodiment 2, mass ratio shared by nano zine oxide mixture is 10%, is applied
Layer thickness 0.15mm, polylactic acid slab-thickness 1mm, transmissivity is in 2~18GHz frequency ranges more than 94%；In embodiment 3,
Mass ratio shared by nano zine oxide mixture is 10%, coating layer thickness 0.2mm, polylactic acid slab-thickness 1mm, transmissivity 2~
More than 92% in 18GHz frequency ranges.At the same time, by testing survey calculation, the ultraviolet protection of Examples 1 to 3 is obtained
Coefficient can be maintained between 45≤UPF≤50, i.e., ultraviolet radiation protective effect is good.
The foregoing is merely the preferred embodiment of the present invention, are not intended to restrict the invention, for those skilled in the art
For, the present invention can have various modifications and changes.It is all within spirit and principles of the present invention made by any modification, equivalent
Replace, improve etc., it should all be included in the protection scope of the present invention.
Claims (8)
1. a kind of antiultraviolet wave transparent coating based on polylactic acid tablet, it is characterised in that：The coating is by polylactic acid tablet, oxygen
Change zinc powder, silicon rubber, epoxy resin, curing agent and diluent to be prepared.
2. a kind of antiultraviolet wave transparent coating based on polylactic acid tablet according to claim 1, it is characterised in that：It is described
Zinc oxide powder is nano-zinc oxide powder.
3. a kind of antiultraviolet wave transparent coating based on polylactic acid tablet according to claim 1, it is characterised in that：It is described
Diluent is acetone or dimethyl silicone polymer.
4. a kind of method preparing the antiultraviolet wave transparent coating based on polylactic acid tablet described in claim 1, it is characterised in that：
It is as follows：
(1) by the Zinc oxide powder and the silicon rubber by volume 1：2 are mixed, evenly dispersed to prepare mixture；
(2) by the epoxy resin, the curing agent and the diluent in mass ratio 10:1:10 assignment systems for mixed solution,
Mixture described in upper step is dissolved in mixed solution, mixed solution is 90 with mixture quality ratio:10, high-speed stirred obtains mixture
System；
(3) mixed system is sprayed on polylactic acid tablet using spray gun, 0.1~0.2mm of coating layer thickness is to get UV resistance
Line wave transparent coating.
5. a kind of preparation method of antiultraviolet wave transparent coating based on polylactic acid tablet according to claim 4, special
Sign is：By on the coating spraying to polylactic acid tablet made from step (3), spontaneous curing 8h or more.
6. a kind of preparation method of antiultraviolet wave transparent coating based on polylactic acid tablet according to claim 4, special
Sign is：The Zinc oxide powder is nano-zinc oxide powder.
7. a kind of preparation method of antiultraviolet wave transparent coating based on polylactic acid tablet according to claim 4, special
Sign is：The diluent is acetone or dimethyl silicone polymer.
8. the antiultraviolet wave transparent coating based on polylactic acid tablet described in any one of claims 1 to 3, it is characterised in that：
The coating can be applicable to plasma discharge protection field.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810229506.8A CN108329504B (en) | 2018-03-20 | 2018-03-20 | Anti-ultraviolet wave-transmitting coating based on polylactic acid flat plate and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810229506.8A CN108329504B (en) | 2018-03-20 | 2018-03-20 | Anti-ultraviolet wave-transmitting coating based on polylactic acid flat plate and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN108329504A true CN108329504A (en) | 2018-07-27 |
| CN108329504B CN108329504B (en) | 2021-03-30 |
Family
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810229506.8A Expired - Fee Related CN108329504B (en) | 2018-03-20 | 2018-03-20 | Anti-ultraviolet wave-transmitting coating based on polylactic acid flat plate and preparation method thereof |
Country Status (1)
| Country | Link |
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| CN (1) | CN108329504B (en) |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20070154721A1 (en) * | 2005-12-30 | 2007-07-05 | Industrial Technology Research Institute | Heat transfer fluids with heteroatom-containing carbon nanocapsules |
| US20100221557A1 (en) * | 2009-03-02 | 2010-09-02 | Shin-Etsu Chemical Co., Ltd. | Uv-shielding silicone coating composition and coated article |
| CN104004466A (en) * | 2014-05-23 | 2014-08-27 | 东莞轩朗实业有限公司 | Reflecting film and preparation method thereof |
| CN105368116A (en) * | 2015-11-10 | 2016-03-02 | 张家港康得新光电材料有限公司 | Anti-ultraviolet material, anti-ultraviolet film and preparation method of film |
-
2018
- 2018-03-20 CN CN201810229506.8A patent/CN108329504B/en not_active Expired - Fee Related
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20070154721A1 (en) * | 2005-12-30 | 2007-07-05 | Industrial Technology Research Institute | Heat transfer fluids with heteroatom-containing carbon nanocapsules |
| US20100221557A1 (en) * | 2009-03-02 | 2010-09-02 | Shin-Etsu Chemical Co., Ltd. | Uv-shielding silicone coating composition and coated article |
| CN104004466A (en) * | 2014-05-23 | 2014-08-27 | 东莞轩朗实业有限公司 | Reflecting film and preparation method thereof |
| CN105368116A (en) * | 2015-11-10 | 2016-03-02 | 张家港康得新光电材料有限公司 | Anti-ultraviolet material, anti-ultraviolet film and preparation method of film |
Non-Patent Citations (5)
| Title |
|---|
| YING HE ET AL.: ""Novel epoxy-silicone thermolytic transparent packaging adhesives chemical modified by ZnO nanowires for HB LEDs"", 《JOURNAL OF NANOPARTICLE RESEARCH》 * |
| YUPING SUN ET AL.: ""Preparation and Properties of Transparent Zinc Oxide/Silicone Nanocomposites for the Packaging of High-Power Light-Emitting Diodes"", 《JOURNAL OF APPLIED POLYMER SCIENCE》 * |
| 汪多仁: "《绿色化工助剂》", 31 January 2006, 科学技术文献出版社 * |
| 邵明望: "《微波化学与工程》", 30 June 1999, 安徽大学出版社 * |
| 郑天亮: "《现代涂料与涂装工程》", 30 June 2003, 北京航空航天大学出版社 * |
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| CN108329504B (en) | 2021-03-30 |
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