CN108328937A - A method of using nano powder processing glass, metal, ceramic surface - Google Patents
A method of using nano powder processing glass, metal, ceramic surface Download PDFInfo
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- CN108328937A CN108328937A CN201810158459.2A CN201810158459A CN108328937A CN 108328937 A CN108328937 A CN 108328937A CN 201810158459 A CN201810158459 A CN 201810158459A CN 108328937 A CN108328937 A CN 108328937A
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/006—Surface treatment of glass, not in the form of fibres or filaments, by coating with materials of composite character
- C03C17/008—Surface treatment of glass, not in the form of fibres or filaments, by coating with materials of composite character comprising a mixture of materials covered by two or more of the groups C03C17/02, C03C17/06, C03C17/22 and C03C17/28
- C03C17/009—Mixtures of organic and inorganic materials, e.g. ormosils and ormocers
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/006—Surface treatment of glass, not in the form of fibres or filaments, by coating with materials of composite character
- C03C17/007—Surface treatment of glass, not in the form of fibres or filaments, by coating with materials of composite character containing a dispersed phase, e.g. particles, fibres or flakes, in a continuous phase
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/06—Surface treatment of glass, not in the form of fibres or filaments, by coating with metals
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/22—Surface treatment of glass, not in the form of fibres or filaments, by coating with other inorganic material
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/22—Surface treatment of glass, not in the form of fibres or filaments, by coating with other inorganic material
- C03C17/225—Nitrides
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/22—Surface treatment of glass, not in the form of fibres or filaments, by coating with other inorganic material
- C03C17/23—Oxides
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
- C03C17/36—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
- C03C17/36—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
- C03C17/3602—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer
- C03C17/3605—Coatings of the type glass/metal/inorganic compound
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
- C03C17/36—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
- C03C17/3602—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer
- C03C17/3644—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer the metal being silver
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/50—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
- C04B41/85—Coating or impregnation with inorganic materials
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C24/00—Coating starting from inorganic powder
- C23C24/08—Coating starting from inorganic powder by application of heat or pressure and heat
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2217/00—Coatings on glass
- C03C2217/20—Materials for coating a single layer on glass
- C03C2217/21—Oxides
- C03C2217/212—TiO2
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2217/00—Coatings on glass
- C03C2217/20—Materials for coating a single layer on glass
- C03C2217/21—Oxides
- C03C2217/213—SiO2
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2217/00—Coatings on glass
- C03C2217/40—Coatings comprising at least one inhomogeneous layer
- C03C2217/43—Coatings comprising at least one inhomogeneous layer consisting of a dispersed phase in a continuous phase
- C03C2217/44—Coatings comprising at least one inhomogeneous layer consisting of a dispersed phase in a continuous phase characterized by the composition of the continuous phase
- C03C2217/445—Organic continuous phases
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2217/00—Coatings on glass
- C03C2217/40—Coatings comprising at least one inhomogeneous layer
- C03C2217/43—Coatings comprising at least one inhomogeneous layer consisting of a dispersed phase in a continuous phase
- C03C2217/46—Coatings comprising at least one inhomogeneous layer consisting of a dispersed phase in a continuous phase characterized by the dispersed phase
- C03C2217/47—Coatings comprising at least one inhomogeneous layer consisting of a dispersed phase in a continuous phase characterized by the dispersed phase consisting of a specific material
- C03C2217/475—Inorganic materials
- C03C2217/477—Titanium oxide
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2217/00—Coatings on glass
- C03C2217/70—Properties of coatings
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2218/00—Methods for coating glass
- C03C2218/10—Deposition methods
- C03C2218/11—Deposition methods from solutions or suspensions
- C03C2218/111—Deposition methods from solutions or suspensions by dipping, immersion
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- Chemical Kinetics & Catalysis (AREA)
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- Geochemistry & Mineralogy (AREA)
- Life Sciences & Earth Sciences (AREA)
- Inorganic Chemistry (AREA)
- Ceramic Engineering (AREA)
- Structural Engineering (AREA)
- Composite Materials (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Dispersion Chemistry (AREA)
- Other Surface Treatments For Metallic Materials (AREA)
Abstract
The present invention relates to technical field of material surface treatment, relate generally to a kind of nano powder for being 0.1 50% using nano powder processing glass, the method on metal and ceramic surface, including weight ratio, the deionized water that weight ratio is 50 99.9% and 0 20% organic solvent.Nano powder and deionized water are mixed evenly, it pours into the clean pressure vessel equipped with clean product, sealing pressing heats, pressure-maintaining and heat-preservation 1 200 hours, nano powder is set to be adhered to product surface, and to spreading inside article substrate under pressure and temperature effect, inside disperse product, and with article substrate metallurgical binding, make product surface that there is hydrophobicity, hydrophily, wearability and other effects.Technical scheme of the present invention makes more wear-resisting metal product, corrosion-resistant, high temperature resistant, self-lubricating, more resistant to the extension of face crack, improves the anti-fatigue performance of product.
Description
Technical field
The present invention relates to technical field of material surface treatment, relate generally to it is a kind of using nano powder processing glass, metal and
The method on ceramic surface.
Background technology
The surface modification treatment for carrying out the performances such as super hydrophilic, super-hydrophobic to glass at present, is by nano-ceramic powder mostly
It is added in coating or organic solvent, is applied to or is sprayed on glass surface and generate super hydrophilic, super-hydrophobic and other effects, this method scrubbing resistance
Property it is poor, against weather is poor, 2 to 5 months just fail.Metal surface properties modification processing mostly uses plasma spraying, plating, electricity greatly
Weldering, physical vaccum deposite, chemical vacuum plated film, fused salt note ooze, the techniques such as laser cladding, exists mostly and basis material binding force
Difference, easily peel off, depth of penetration is insufficient, part is yielding, wearability is bad, product life is not high, efficiency is low, equipment investment is big and
The shortcomings of complex process.
Invention content
Present invention offer one kind is simple for process, various nano-ceramic powders is made to be effectively injected in metallic matrix, with product base
Body metallurgical binding, be not easy to peel off, binding force is strong, part is unlikely to deform, is efficient, manufactured product is more wear-resisting, corrosion-resistant etc.,
The nano ceramics ingredient oozed by adjusting note and corresponding technique, can be made into the product of various properties, different to meet
Demand.
Various nano-ceramic powders, nano metal powder, nano nonmetal powder are passed through into special warfare implantation glass, gold
Inside belonging to and being ceramic, various properties are generated.
Technical scheme of the present invention is specific as follows：
A method of using nano powder processing glass, metal and ceramic surface, it is raw materials used include nano powder, go
Ionized water and/or organic solvent, weight ratio are：
Nano powder 0.1-50%
Deionized water 50-99.9%
Organic solvent 0-20%；
Specific steps include：
Step 1, nano powder is added in deionized water or organic solution, stirs evenly, obtains nano powder solution；
Step 2, it would be desirable to the product surface degreasing being surface-treated, and be washed with deionized water only, it is put into clean
In pressure vessel；
Step 3, the nano powder solution being stirred in step 1 is added in the pressure vessel, nano powder solution addition
Product, which can be covered all, to be advisable, and product surface is made to be come into full contact with nano powder solution；
Step 4, the pressure vessel is sealed, pressurized, heated, and heat-insulation pressure keeping 1-200 hours, is made in pressure and temperature
Under, nano powder is to spreading inside article substrate, inside disperse product, and with article substrate metallurgical binding.
Further, when handling surface of metal product using nano powder, raw materials used includes nano powder, deionized water
And/or organic solvent, weight ratio are：
Nano powder 0.1-50%
Deionized water 48-97.9%
Organic solvent 2-20%；
Specific steps include：
Step 1, nano powder is added in deionized water or organic solution, stirs evenly, obtains nano powder solution；
Step 2, it would be desirable to the product surface degreasing being surface-treated, and be washed with deionized water only, it is put into clean
In pressure vessel；
Step 3, the nano powder solution being stirred in step 1 is added in the pressure vessel, nano powder solution addition
Product, which can be covered all, to be advisable, and product surface is made to be come into full contact with nano powder solution；
Step 4, the pressure vessel is sealed, pressurized, heated, and heat-insulation pressure keeping 1-200 hours, is made in pressure and temperature
Under, nano powder is to spreading inside article substrate, inside disperse product, and with article substrate metallurgical binding.
Further, the chemical composition of the nano powder be oxide, nitride, carbide, metal or it is nonmetallic in
One or more.
Further, one kind or several in the metallic aluminium, vanadium, chromium, niobium, titanium, zirconium, molybdenum, tungsten, nickel, cobalt or rare earth metal
Kind；
It is described nonmetallic for one or more of boron, carbon, silicon, phosphorus, sulphur；
The oxide is one or more of titanium dioxide, silica, tin oxide, zinc oxide, alundum (Al2O3)；
The nitride is one or more of silicon nitride, boron nitride, titanium nitride, vanadium nitride, aluminium nitride, zirconium nitride；
The carbide is one or more of silicon carbide, titanium carbide, boron carbide, vanadium carbide.
Further, the organic solvent is one or more of organic silicone oil or silicone emulsion.
Further, in step 4, it is forced into 0.5Mpa-400Mpa；Temperature is controlled at 50 DEG C -800 DEG C.
Further, the metal product is aluminum products, copper product, magnesium product or steel part.
Further, including nano powder, deionized water or organic solvent, weight ratio are：
Nano powder 0.1-15%
Deionized water 65-79.9%
Organic solvent 0-20%
Specific steps include：
Step 1, nano powder is added in deionized water or organic solution, stirs evenly, obtains nano powder solution；
Step 2, it would be desirable to the product surface degreasing being surface-treated, and be washed with deionized water only, it is put into clean
In pressure vessel；
Step 3, the nano powder solution being stirred in step 1 is added in the pressure vessel, nano powder solution addition
Product can be covered all by, which, is advisable, and product surface is made to be come into full contact with nano powder solution；
Step 4, the pressure vessel is sealed, pressurized, heated, and heat-insulation pressure keeping 1-200 hours, is made in pressure and temperature
Under, nano powder is to spreading inside article substrate, inside disperse product, and with article substrate metallurgical binding.
Further, including nano powder, deionized water or organic solvent, weight ratio are：
Nano powder 40.1-50%
Deionized water 30-39.9%
Organic solvent 0-20%
Specific steps include：
Step 1, nano powder is added in deionized water or organic solution, stirs evenly, obtains nano powder solution；
Step 2, it would be desirable to the product surface degreasing being surface-treated, and be washed with deionized water only, it is put into clean
In pressure vessel；
Step 3, the nano powder solution being stirred in step 1 is added in the pressure vessel, nano powder solution addition
Product can be covered all by, which, is advisable, and product surface is made to be come into full contact with nano powder solution；
Step 4, the pressure vessel is sealed, pressurized, heated, and heat-insulation pressure keeping 1-200 hours, is made in pressure and temperature
Under, nano powder is to spreading inside article substrate, inside disperse product, and with article substrate metallurgical binding.
Further, including nano powder, deionized water or organic solvent, weight ratio are：
Nano powder 25%
Deionized water 65%
Organic solvent 10%；
Specific steps include：
Step 1, nano powder is added in deionized water or organic solution, stirs evenly, obtains nano powder solution；
Step 2, it would be desirable to the product surface degreasing being surface-treated, and be washed with deionized water only, it is put into clean
In pressure vessel；
Step 3, the nano powder solution being stirred in step 1 is added in the pressure vessel, nano powder solution addition
Product can be covered all by, which, is advisable, and product surface is made to be come into full contact with nano powder solution；
Step 4, the pressure vessel is sealed, pressurized, heated, and heat-insulation pressure keeping 1-200 hours, is made in pressure and temperature
Under, nano powder is to spreading inside article substrate, inside disperse product, and with article substrate metallurgical binding.
Beneficial effects of the present invention are：The present invention under certain temperature and pressure, makes the nanometer for being adhered to product surface
Material granule obtains higher kinetic energy, to article substrate inside spread, the products such as disperse and glass, ceramics and metal the inside, and
With the matrix metallurgical binding of glass, ceramics and metal, make the products such as glass, ceramics, metal that there are the spies such as super hydrophilic, super-hydrophobic
Property, so that metallic crystal is divided into more tiny crystal grain, and strengthen crystal grain, increase plane of crystal dislocation density, makes metal product
More wear-resisting, corrosion-resistant, high temperature resistant, self-lubricating improve anti-fatigue performance more resistant to the extension of face crack.Organic solution is selected
It is not aoxidized under metallic high temperature with that can place and nitrogen-atoms, carbon atom etc. can be provided under high temperature, improve the hardness of metal surface, into
One step improves the wear-resisting and corrosion resistance of metal product.
Specific implementation mode
In order to make the technical problems, technical solutions and beneficial effects solved by the present invention be more clearly understood, below in conjunction with
Embodiment, the present invention will be described in further detail.It should be appreciated that specific embodiment described herein is only used to explain
The present invention is not intended to limit the present invention.
Embodiment 1 modifying glass article surface using a kind of in following methods
Method 1
Nanometer titanium dioxide titanium valve 1%
Deionized water and/or organic solvent 99%
Specific steps include：
Step 1, nanometer titanium dioxide titanium valve is added in deionized water or organic solution, stirs evenly, obtains nano-silica
Change titanium valve solution；
Step 2, it would be desirable to the glass article surface degreasing being surface-treated, and be washed with deionized water only, it is put into dry
In net pressure vessel；
Step 3, the nanometer titanium dioxide titanium valve solution being stirred in step 1 is added in the pressure vessel, nano-silica
Changing titanium valve solution addition and wanting that product can be covered all is advisable；
Step 4, the pressure vessel is sealed, is forced into 35Mpa, heat to 139 DEG C, and heat-insulation pressure keeping 48 is small
When, so that nano powder is adhered to product surface, and to spreading inside article substrate under pressure and temperature effect, in disperse product
Face, and with article substrate metallurgical binding, so that glass article surface is generated super hydrophilic effect.
Method 2
Nanometer titanium dioxide titanium valve 3%
Deionized water 97%；
Specific steps include：
Step 1, deionized water is added in nanometer titanium dioxide titanium valve, stirs evenly, obtains nanometer titanium dioxide titanium valve solution；
Step 2, it would be desirable to the glass article surface degreasing being surface-treated, and be washed with deionized water only, it is put into dry
In net pressure vessel；
Step 3, the nanometer titanium dioxide titanium valve solution being stirred in step 1 is added in the pressure vessel, nano-silica
Changing titanium valve solution addition and wanting that product can be covered all is advisable；
Step 4, the pressure vessel is sealed, is forced into 32Mpa, heat to 139 DEG C, and heat-insulation pressure keeping 40 is small
When, so that nano powder is adhered to product surface, and to spreading inside article substrate under pressure and temperature effect, in disperse product
Face, and with article substrate metallurgical binding, so that glass article surface is generated super hydrophilic effect.If glass article surface is silver-plated, side adds
Heat is warming up to 80 DEG C, and pressurize 40 hours, glass article surface generates super hydrophilic effect.
Method 3
Nano-silica powder 1%
Deionized water 99%；
Specific steps include：
Step 1, deionized water is added in nano-silica powder, stirred evenly, obtain nano-silica powder solution；
Step 2, it would be desirable to the glass article surface degreasing being surface-treated, and be washed with deionized water only, it is put into dry
In net pressure vessel；
Step 3, the nano-silica powder solution being stirred in step 1 is added in the pressure vessel, nano-silica
SiClx powder solution addition, which wants that product can be covered all, to be advisable；
Step 4, the pressure vessel is sealed, is forced into 36Mpa, heat to 136 DEG C, and heat-insulation pressure keeping 48 is small
When, so that nano powder is adhered to product surface, and to spreading inside article substrate under pressure and temperature effect, in disperse product
Face, and with article substrate metallurgical binding, so that glass article surface is generated super hydrophilic effect.
Embodiment 2 modifying steel part surface using a kind of in following scheme
Method 1
Specific steps include：
Step 1, deionized water is added in nanometer alchlor powder, stirs evenly, obtains a nanometer alchlor powder solution；
Step 2, it would be desirable to the steel part surface degreasing being surface-treated, and be washed with deionized water only, it is put into clean
Pressure vessel in；
Step 3, the nanometer alchlor powder solution being stirred in step 1 is added in the pressure vessel, three oxygen of nanometer
Changing aluminum powder solution addition and wanting that product can be covered all is advisable；
Step 4, the pressure vessel is sealed, is forced into 80Mpa, heat to 500 DEG C, and heat-insulation pressure keeping 48 is small
When, so that nano powder is adhered to product surface, and to spreading inside article substrate under pressure and temperature effect, in disperse product
Face, and with article substrate metallurgical binding, the wear-resisting property of steel part improves 3 times or more.
Method 2
Specific steps include：
Step 1, deionized water is added in nanometer alchlor powder, organic silicone oil and silicone emulsion, stirs evenly, is received
Rice alchlor powder solution；
Step 2, it would be desirable to the steel part surface degreasing being surface-treated, and be washed with deionized water only, it is put into clean
Pressure vessel in；
Step 3, the nanometer alchlor powder solution being stirred in step 1 is added in the pressure vessel, three oxygen of nanometer
Changing aluminum powder solution addition and wanting that product can be covered all is advisable；
Step 4, the pressure vessel is sealed, is forced into 90Mpa, heat to 530 DEG C, and heat-insulation pressure keeping 40 is small
When, so that nano powder is adhered to product surface, and to spreading inside article substrate under pressure and temperature effect, in disperse product
Face, and with article substrate metallurgical binding, the wear-resisting property of steel part improves 3 times or more.
Method 3
Specific steps include：
Step 1, deionized water is added in nano silicon nitride powders, organic silicone oil and silicone emulsion, stirs evenly, obtains nanometer
Silicon nitride powder solution；
Step 2, it would be desirable to the steel part surface degreasing being surface-treated, and be washed with deionized water only, it is put into clean
Pressure vessel in；
Step 3, the nano silicon nitride powders solution being stirred in step 1 is added in the pressure vessel, nano-silicon nitride
Powder solution addition, which wants that product can be covered all, to be advisable；
Step 4, the pressure vessel is sealed, is forced into 100Mpa, heat to 530 DEG C, and heat-insulation pressure keeping 40 is small
When, so that nano powder is adhered to product surface, and to spreading inside article substrate under pressure and temperature effect, in disperse product
Face, and with article substrate metallurgical binding, the wear-resisting property of steel part improves 3 times or more.
Method 4
Specific steps include：
Step 1, deionized water, stirring is added in nano boron carbide powder, nano carborundum powder, organic silicone oil and silicone emulsion
Uniformly, the solution containing nano boron carbide powder and nano carborundum powder is obtained；
Step 2, it would be desirable to the steel part surface degreasing being surface-treated, and be washed with deionized water only, it is put into clean
Pressure vessel in；
Step 3, it will be stirred in step 1 and the pressure be added containing nano boron carbide powder and the solution of nano carborundum powder
In force container, the solution addition containing nano boron carbide powder and nano carborundum powder, which wants that product can be covered all, to be advisable；
Step 4, the pressure vessel is sealed, is forced into 150Mpa, heat to 600 DEG C, and heat-insulation pressure keeping 40 is small
When, so that nano powder is adhered to product surface, and to spreading inside article substrate under pressure and temperature effect, in disperse product
Face, and with article substrate metallurgical binding, the wear-resisting property of steel part improves 5 times or more.
Method 5
Specific steps include：
Step 1, deionized water is added in nano tungsten carbide, organic silicone oil and silicone emulsion, stirs evenly, obtains nanometer
Tungsten carbide powder solution；
Step 2, it would be desirable to the steel part surface degreasing being surface-treated, and be washed with deionized water only, it is put into clean
Pressure vessel in；
Step 3, the nano tungsten carbide solution being stirred in step 1 is added in the pressure vessel, nanometer tungsten carbide
Powder solution addition, which wants that product can be covered all, to be advisable；
Step 4, the pressure vessel is sealed, is forced into 200Mpa, heat to 580 DEG C, and heat-insulation pressure keeping 36 is small
When, so that nano powder is adhered to product surface, and to spreading inside article substrate under pressure and temperature effect, in disperse product
Face, and with article substrate metallurgical binding, the wear-resisting property of steel part improves 3 times or more.
Method 6：
Nano-aluminium oxide powder 3%
TF-1 salt agent 95%；
Specific steps include：
Step 1, nano-aluminium oxide powder is added in TF-1 salt agent, stirs evenly, obtains nano-aluminium oxide powder
Solution；
Step 2, it would be desirable to the steel part surface degreasing being surface-treated, and be washed with deionized water only, it is put into clean
Pressure vessel in；
Step 3, the nano-aluminium oxide powder solution being stirred in step 1 is added in the pressure vessel, nanometer three
Al 2 O powder solution addition, which wants that product can be covered all, to be advisable；
Step 4, the pressure vessel is sealed, is forced into 120Mpa, heat to 530 DEG C, and heat-insulation pressure keeping 40 is small
When, so that nano powder is adhered to product surface, and to spreading inside article substrate under pressure and temperature effect, in disperse product
Face, and with article substrate metallurgical binding, the wear-resisting property of steel part improves 3 times or more.
Embodiment 3 modifying copper product surface using a kind of in following scheme
Method 1：
Specific steps include：
Step 1, deionized water is added in nano tungsten carbide, organic silicone oil and silicone emulsion, stirs evenly, obtains nanometer
Tungsten carbide powder solution；
Step 2, it would be desirable to the copper product surface degreasing being surface-treated, and be washed with deionized water only, it is put into clean
Pressure vessel in；
Step 3, the nano tungsten carbide solution being stirred in step 1 is added in the pressure vessel, nanometer tungsten carbide
Powder solution addition, which wants that product can be covered all, to be advisable；
Step 4, the pressure vessel is sealed, is forced into 60Mpa, heat to 500 DEG C, and heat-insulation pressure keeping 24 is small
When, so that nano powder is adhered to product surface, and to spreading inside article substrate under pressure and temperature effect, in disperse product
Face, and with article substrate metallurgical binding, improve the wear-resisting property and electric erosion resistance of copper product.
Method 2：
Specific steps include：
Step 1, deionized water, stirring is added in nano tungsten carbide, nano carborundum powder, organic silicone oil and silicone emulsion
Uniformly, it obtains containing nano tungsten carbide and nano carborundum powder solution；
Step 2, it would be desirable to the copper product surface degreasing being surface-treated, and be washed with deionized water only, it is put into clean
Pressure vessel in；
Step 3, it will be stirred in step 1 and the pressure be added containing nano tungsten carbide and nano carborundum powder solution
In container, containing nano tungsten carbide and nano carborundum powder solution addition wanting that product can be covered all is advisable；
Step 4, the pressure vessel is sealed, is forced into 65Mpa, heat to 520 DEG C, and heat-insulation pressure keeping 30 is small
When, so that nano powder is adhered to product surface, and to spreading inside article substrate under pressure and temperature effect, in disperse product
Face, and with article substrate metallurgical binding, improve the wear-resisting property and electric erosion resistance of copper product.
Embodiment 4 modifying aluminum products surface using a kind of in following scheme
Method 1：
Nano-aluminium oxide powder 3%
Deionized water 97%；
Specific steps include：
Step 1, deionized water is added in nano-aluminium oxide powder, stirs evenly, it is molten obtains nano-aluminium oxide powder
Liquid；
Step 2, it would be desirable to the aluminum products surface degreasing being surface-treated, and be washed with deionized water only, it is put into clean
Pressure vessel in；
Step 3, the nano-aluminium oxide powder solution being stirred in step 1 is added in the pressure vessel, nanometer three
Al 2 O powder solution addition, which wants that product can be covered all, to be advisable；
Step 4, the pressure vessel is sealed, is forced into 50Mpa, heat to 400 DEG C, and heat-insulation pressure keeping 24 is small
When, so that nano powder is adhered to product surface, and to spreading inside article substrate under pressure and temperature effect, in disperse product
Face, and with article substrate metallurgical binding, improve the wear-resisting property of aluminum products.
Method 2
Nano silicon nitride titanium valve 2%
Nano aluminum nitride powder 1%
Deionized water 97%；
Specific steps include：
Step 1, deionized water is added in nano silicon nitride titanium valve and nano aluminum nitride powder, stirs evenly, obtains containing nanometer
Nitrogenize the solution of titanium valve and nano aluminum nitride powder；
Step 2, it would be desirable to the aluminum products surface degreasing being surface-treated, and be washed with deionized water only, it is put into clean
Pressure vessel in；
Step 3, it will be stirred in step 1 and the pressure be added containing nano silicon nitride titanium valve and the solution of nano aluminum nitride powder
In force container, the solution addition containing nano silicon nitride titanium valve and nano aluminum nitride powder, which wants that product can be covered all, to be advisable；
Step 4, the pressure vessel is sealed, is forced into 60Mpa, heat to 380 DEG C, and heat-insulation pressure keeping 20 is small
When, so that nano powder is adhered to product surface, and to spreading inside article substrate under pressure and temperature effect, in disperse product
Face, and with article substrate metallurgical binding, improve the wear-resisting property of aluminum products.
The above is only a specific embodiment of the present invention, is not intended to limit the invention, therefore, as long as with this
All any modification, equivalent and improvement etc., should all be included in the protection scope of the present invention made by description of the invention appearance.
Claims (10)
1. a kind of using nano powder processing glass, metal and the method on ceramic surface, which is characterized in that raw materials used to include
Nano powder, deionized water and/or organic solvent, weight ratio are：
Nano powder 0.1-50%
Deionized water 50-99.9%
Organic solvent 0-20%；
Specific steps include：
Step 1, nano powder is added in deionized water and organic solution in proportion, is stirred evenly, obtain nano powder solution；
Step 2, it would be desirable to the product surface degreasing being surface-treated, and be washed with deionized water only, it is put into clean pressure
In container；
Step 3, the nano powder solution being stirred in step 1 is added in the pressure vessel, nano powder solution addition can be complete
Product is lived in all standing to be advisable, and product surface is made to be come into full contact with nano powder solution；
Step 4, the pressure vessel is sealed, pressurized, heated, and heat-insulation pressure keeping 1-200 hours, under pressure and temperature effect,
Nano powder is to spreading inside article substrate, inside disperse product, and with article substrate metallurgical binding.
2. according to claim 1 existed using nano powder processing glass, metal and the method on ceramic surface, feature
In when handling surface of metal product using nano powder, raw materials used includes nano powder, deionized water and/or organic solvent, weight
Measuring ratio is：
Nano powder 0.1-50%
Deionized water 48-97.9%
Organic solvent 2-20%；
Specific steps include：
Step 1, nano powder is added in deionized water and organic solution, is stirred evenly, obtain nano powder solution；
Step 2, it would be desirable to the product surface degreasing being surface-treated, and be washed with deionized water only, it is put into clean pressure
In container；
Step 3, the nano powder solution being stirred in step 1 is added in the pressure vessel, nano powder solution addition can be complete
Product is lived in all standing to be advisable, and product surface is made to be come into full contact with nano powder solution；
Step 4, the pressure vessel is sealed, pressurized, heated, and heat-insulation pressure keeping 1-200 hours, under pressure and temperature effect,
Nano powder is to spreading inside article substrate, inside disperse product, and with article substrate metallurgical binding.
3. according to claim 1 existed using nano powder processing glass, metal and the method on ceramic surface, feature
In the chemical composition of, the nano powder be oxide, nitride, carbide, metal or one or more of nonmetallic.
4. it is according to claims 1 to 3 using nano powder processing glass, metal and the method on ceramic surface, it is special
Sign is that the metal is one or more of aluminium, vanadium, chromium, niobium, titanium, zirconium, molybdenum, tungsten, nickel, cobalt or rare earth metal；
It is described nonmetallic for one or more of boron, carbon, silicon, phosphorus, sulphur；
The oxide is one or more of titanium dioxide, silica, tin oxide, zinc oxide, alundum (Al2O3)；
The nitride is one or more of silicon nitride, boron nitride, titanium nitride, vanadium nitride, aluminium nitride, zirconium nitride；
The carbide is one or more of silicon carbide, titanium carbide, boron carbide, vanadium carbide.
5. according to claim 1 existed using nano powder processing glass, metal and the method on ceramic surface, feature
In the organic solvent is one or more of organic silicone oil or silicone emulsion.
6. according to claim 1 existed using nano powder processing glass, metal and the method on ceramic surface, feature
In in step 4, being forced into 0.5Mpa-400Mpa；Temperature is controlled at 50 DEG C -800 DEG C.
7. according to claim 1 existed using nano powder processing glass, metal and the method on ceramic surface, feature
In the metal product is aluminum products, copper product, magnesium product or steel part.
8. according to claim 1 existed using nano powder processing glass, metal and the method on ceramic surface, feature
In, including nano powder, deionized water or organic solvent, weight ratio be：
Nano powder 0.1-15%
Deionized water 65-79.9%
Organic solvent 0-20%
Specific steps include：
Step 1, nano powder is added in deionized water or organic solution, stirs evenly, obtains nano powder solution；
Step 2, it would be desirable to the product surface degreasing being surface-treated, and be washed with deionized water only, it is put into clean pressure
In container；
Step 3, the nano powder solution being stirred in step 1 is added in the pressure vessel, nano powder solution addition wants energy
Covering all product is advisable, and product surface is made to be come into full contact with nano powder solution；
Step 4, the pressure vessel is sealed, pressurized, heated, and heat-insulation pressure keeping 1-200 hours, under pressure and temperature effect,
Nano powder is to spreading inside article substrate, inside disperse product, and with article substrate metallurgical binding.
9. according to claim 1 existed using nano powder processing glass, metal and the method on ceramic surface, feature
In, including nano powder, deionized water or organic solvent, weight ratio be：
Nano powder 40.1-50%
Deionized water 30-39.9%
Organic solvent 0-20%
Specific steps include：
Step 1, nano powder is added in deionized water or organic solution, stirs evenly, obtains nano powder solution；
Step 2, it would be desirable to the product surface degreasing being surface-treated, and be washed with deionized water only, it is put into clean pressure
In container；
Step 3, the nano powder solution being stirred in step 1 is added in the pressure vessel, nano powder solution addition wants energy
Covering all product is advisable, and product surface is made to be come into full contact with nano powder solution；
Step 4, the pressure vessel is sealed, pressurized, heated, and heat-insulation pressure keeping 1-200 hours, under pressure and temperature effect,
Nano powder is to spreading inside article substrate, inside disperse product, and with article substrate metallurgical binding.
10. according to claim 1 using nano powder processing glass, metal and the method on ceramic surface, feature
It is, including nano powder, deionized water or organic solvent, weight ratio are：
Nano powder 25%
Deionized water 65%
Organic solvent 10%；
Specific steps include：
Step 1, nano powder is added in deionized water or organic solution, stirs evenly, obtains nano powder solution；
Step 2, it would be desirable to the product surface degreasing being surface-treated, and be washed with deionized water only, it is put into clean pressure
In container；
Step 3, the nano powder solution being stirred in step 1 is added in the pressure vessel, nano powder solution addition wants energy
Covering all product is advisable, and product surface is made to be come into full contact with nano powder solution；
Step 4, the pressure vessel is sealed, pressurized, heated, and heat-insulation pressure keeping 1-200 hours, under pressure and temperature effect,
Nano powder is to spreading inside article substrate, inside disperse product, and with article substrate metallurgical binding.
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Application publication date: 20180727 |