CN108328863A - A kind of modularization integrated technology process suitable for flax degumming wastewater treatment - Google Patents

A kind of modularization integrated technology process suitable for flax degumming wastewater treatment Download PDF

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CN108328863A
CN108328863A CN201810148624.6A CN201810148624A CN108328863A CN 108328863 A CN108328863 A CN 108328863A CN 201810148624 A CN201810148624 A CN 201810148624A CN 108328863 A CN108328863 A CN 108328863A
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reactor
outlet
tank
water
module
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CN108328863B (en
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于鹏飞
何亚婷
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Hunan Fenghui Linen Industry Co.,Ltd.
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Shenyang Jianzhu University
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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F9/00Multistage treatment of water, waste water or sewage
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/001Processes for the treatment of water whereby the filtration technique is of importance
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/24Treatment of water, waste water, or sewage by flotation
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F2001/007Processes including a sedimentation step
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2103/00Nature of the water, waste water, sewage or sludge to be treated
    • C02F2103/30Nature of the water, waste water, sewage or sludge to be treated from the textile industry
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2209/00Controlling or monitoring parameters in water treatment
    • C02F2209/001Upstream control, i.e. monitoring for predictive control
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2209/00Controlling or monitoring parameters in water treatment
    • C02F2209/08Chemical Oxygen Demand [COD]; Biological Oxygen Demand [BOD]
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00Biological treatment of water, waste water, or sewage
    • C02F3/30Aerobic and anaerobic processes

Abstract

The present invention relates to a kind of modularization integrated technology process suitable for flax degumming wastewater treatment, carry out that technique is integrated and Parametric designing for high concentration flax degumming waste water, technique is made of 3 level-one preprocessing module, secondary biochemical module and three-level advanced treating module modules, the mobile coarse rack basket of level-one preprocessing module setting, balancing tank and flotation tank, remove oil removal and regulating pondage water quality;Anaerobic Contact reactor, anoxic reacter and aerobic reaction member is arranged in secondary biochemical module, remove major pollutants in waste water, there are two reactors for aerobic reaction unit, respectively fixed biofilm-activated sludge process reactor and biological fluidized-bed reactor, according to different influent quality conditions, selection operation different reactor.Radial-flow sedimentation tank and SPR sewage purification devices is arranged in three-level advanced treating module, removes SS and disinfection.Present invention process have the characteristics that it is simple and direct, flexible, efficient, intelligent, can ensure waste water disposal facility economy, effectively, stablize operation.

Description

A kind of modularization integrated technology process suitable for flax degumming wastewater treatment
Technical field
The present invention relates to a kind of high concentrated organic wastewater integrated approach technologies, more particularly to a kind of useless suitable for flax degumming The modularization integrated technique of water process, the high concentration wastewater treatment generated in process of production for flax spinning industry enterprise are asked Topic, carries out that technique is integrated and Parametric designing, realizes technical module, intelligence, integrated.
Background technology
Textile industry be Chinese national economy conventional column industry and important people's livelihood industry and China international competing Industry with the obvious advantage in striving in flourish the market, expands outlet, receives employment, increases farmers' income, promotes Urbanization Progress Etc. play an important role, but textile industry waste discharge amount is big simultaneously, and concentration of organic wastewater is high, is that China's weight is dirty Contaminate one of industry.
Chinese bast-fibre textile process industry is broadly divided into ramie textile according to fiber and technology features, flax is spun It knits.Also contain the non-cellulose components such as hemicellulose, pectin substance, lignin in fiber crops other than containing cellulose, these are non- Cellulose components are referred to as colloid, and colloidal substance can be obtained spinnability fiber in removal fiber crops, this process is known as degumming.Bast fibre spinning It is mainly degumming waste water to knit waste water, and non-cellulose components are generally 25%-the 35% of fiber weight in flaxen fiber, therefore degumming is useless Water pollutant content is higher.
Major pollutants are that lignin and its intermediates, hemicellulose and its degradation are intermediate in flax degumming waste water Product, tannin, pectin, resin acid etc., flax degumming Wastewater Pollutant leading indicator are shown in Table 1.
1 flax degumming Wastewater Pollutant leading indicator of table
The good Anaerobic treatment technique for the treatment of process generally use aerobic biological treatment process of flax degumming waste water combines Form, obtained preferable treatment effect, but there is also following problems:
(1) using traditional anaerobic technique, such as when upflow anaerobic sludge blanket process (UASB), due to the SS of flax degumming waste water It is worth larger, therefore the granule sludge culture of anaerobic device is more difficult, and system start-up time is longer, substantially increases the economy of enterprise Burden;
(2) traditional activated sludge process is used, such as when SBR techniques, since flax degumming waste water dissolved organic matter contains Amount is high, F/M high, causes aerobic stage that the high viscosity expansion of sludge occurs, influences sedimentation effect, causes water outlet SS values not up to standard;
(3) traditional biomembrane process is used, such as when contact oxidation technology, since flax degumming waste water SS values occupy height not Under, cause filler to be easy to block, water distribution, aeration are not easy uniformly, dead angle locally occur, influence treatment effect;
(4) flax degumming waste water can cause waste water index to vary widely because of the difference of degumming tech, even Using the textile company of same technique, as the constituent of Various Seasonal difference flax raw material is different and leads to waste water Ingredient is different, and waste water index can vary widely, and processing system is caused to face larger load variations, and effluent index is unstable;
(5) flax degumming wastewater discharge is big, and reuse water demand is big, but at present technology depth, the degree of automation, set Standby quality etc. is horizontal relatively low, greatly hinders the development of flax textile industry.
Invention content
In order to solve the above technical problems, the present invention provides a kind of modularizations suitable for flax degumming wastewater treatment to integrate work The problem of process, the high concentration wastewater treatment generated in process of production for linen textile enterprise, carry out technique it is integrated with Parametric designing realizes technical module, intelligence, integrated.
Specific technical solution is as follows:
Flax degumming waste water integrated technology method according to the present invention is made of 3 modules, and it is pre- to be respectively designated as level-one Processing module, secondary biochemical module and three-level advanced treating module.
The level-one preprocessing module includes mobile coarse rack basket, balancing tank and flotation tank.
The movable type coarse rack basket, is the larger floating material and suspended matter that water pump assembly may be blocked for removing, with Ensure subsequent processing facility energy normal operation.In the present invention, mobile coarse rack basket is mounted on balancing tank water inlet end, is removable Dynamic formula, including coarse rack basket and hand-rail type lifting device.When dirt is more in coarse rack basket, by hand-rail type lifting device, Grid is promoted to operable height, artificial scarfing cinder.It is 5-10mm to design coarse rack grizzly bar gap.
The balancing tank is used for regulating water quality water, to ensure that follow-up water processing establishment water inlet is stablized relatively.It adjusts The Cistern Design residence time is for 24 hours.
The flotation tank is the micro-bubble for forming high degree of dispersion in water, utilizes hydrophobic group in bubble adhesion waste water Solid or liquid particles, formed apparent density float to the water surface less than the flco of water, be then stripped off, to realize solid-liquid or The process of person's Liquid liquid Separation.In the present invention, flotation tank uses flat flow type air-float pool, including reaction tank, contact chamber, air supporting point From room, dreg collecting slot etc., wherein reaction tank designs the residence time as 10min, and it is 0.02m/s, contact that contact chamber, which designs upflow velocity, The residence time is designed as 2min in room, and air flotation zone separation chamber surface loading is 8-10m3/ (m2h), and flotation tank designs the residence time For 15-25min.
The secondary biochemical module includes Anaerobic Contact reactor, anoxic reacter and aerobic reaction member, wherein aerobic There are two reactors, respectively fixed biofilm-activated sludge process (IFAS) reactor and biological fluidized bed reaction for reaction member Device.
Mudpan is arranged in digester water outlet in the Anaerobic Contact reactor, also referred to as anaerobic activated sludge method, The anaerobic organism sludge reflux of precipitation entered in digester, the sludge retention time in digester is improved with this.Using this Reactor can keep sludge concentration in digester higher by sludge reflux, impact resistance ability enhancing, especially with this Reactor can directly handle the feed liquid that suspended solids content is higher or particle is larger, and blockage problem is not present, is particularly adapted to The higher flax degumming waste water of suspension content.Anaerobic Contact reactor design volumetric loading of the present invention is 5-8kgCOD/m3 d。
For the anoxic reacter refers to opposite anaerobic and aerobic environment, by dissolved oxygen control 0.2-0.5mg/l it Between biochemical system, main to play denitrification removal nitrate nitrogen, while removing part BOD, also having hydrolysis to improve can The effect of biochemical.The present invention is 2-4h, mixed liquid recycle ratio 100% the design anoxic reacter design residence time.
Fixed biofilm-activated sludge process (IFAS) reactor is the activated Sludge System for including fixed membrane carrier, While the characteristics of active sludge and biofilm.It is to increase solid film, microorganism in traditional active sludge system It can be attached on fixed membrane carrier and grow, to increase available biomass, the present invention uses plastic three-dimensional ripple packing, design MLSS is 4000-5000mg/L.
The biological fluidized-bed reactor refers to improve the treatment effeciency of biofilm, with sand (or anthracite, activated carbon Deng) make filler and as biofilm carrier, the bottom-up casting bed that flows through of waste water makes carrier layer be in flow regime, in unit Between increase biomembrane with waste water contact area and fully oxygen supply, and using filler fluidized state strengthen biological wastewater treatment process Structures.In the present invention, design MLSS be 5000-8000mg/L, floating stuffing grain size be 10mm, expansion rate 100%, BOD loading is 8.5-12kgBOD5/m3d.
The three-level advanced treating module includes radial-flow sedimentation tank and SPR sewage purification devices.
The radial-flow sedimentation tank, effect are mud-water separations, make mixed liquor it is clear disappear, sludge condensation and the sludge reflux by separation To biological treatment section.In the present invention, sedimentation basin design surface load is 0.8-1.0m3/ (m2h).
The SPR sewage purification devices are so that the pollutant of dissolved state is precipitated under true solution state using chemical method, Form the micelle with solid phase interface or small suspended particulate;Select efficient and economic adsorbent by organic pollution, color Degree etc. is separated from sewage;Then various micelles and suspended particulate in sewage are condensed into greatly using microphysics absorption method The closely knit flco of block;The fluid mechanics principles such as eddy flow and filtering hydraulics are relied on again, it is net in the SPR high-turbidity sewages of designed, designed Changing in device makes flco and water quick separating;After clear water is filtered by the fine and close suspension mud layer self formed in tank body, reach Reuse is realized in the level of tertiary treatment, water outlet.Design water outlet SS values are 3mg/L, select activated carbon as adsorbent, select polymerization Aluminium chloride selects polyacrylamide as flocculation aid, selects liquid chlorine as disinfectant as coagulant.
Flax degumming waste water integrated technology method according to the present invention is made of 3 modules, and it is pre- to be respectively designated as level-one Processing module, secondary biochemical module, three-level advanced treating module.When actual motion, on-line monitoring system is set, by former to coming The water quality information of water is collected, is analyzed, and result is exported to automatic control system, is sent out from automatic control system to submodule unit Signal, to control the automatic operating of integrated artistic.
The level-one preprocessing module includes mobile coarse rack basket, balancing tank and flotation tank, the thick lattice of movable type Grid basket connects flax degumming waste water inlet, and outlet connects the balancing tank import;The balancing tank outlet connects the gas Floating pond import;The flotation tank outlet connects the secondary biochemical module inlet;
The secondary biochemical module includes Anaerobic Contact reactor, anoxic reacter and aerobic reaction member, the anaerobism Contact reactor connects the level-one preprocessing module outlet, and outlet connects the anoxic reacter;The anoxic reacter goes out Mouth connects the aerobic reaction unit inlet, and the aerobic reaction unit outlet connects the three-level advanced treating module inlet;
Further, aerobic reaction unit includes that fixed biofilm-activated sludge process (IFAS) reactor and biology flow Fluidized bed reactor, the biological fluidized-bed reactor import connect aerobic reaction member import, the outlet connection fixed biology Film-activated sludge process (IFAS) Reactor inlet, fixed biofilm-activated sludge process (IFAS) reactor outlet connection Aerobic reaction unit exports;
Further, electromagnetic switch is connected before the biological fluidized-bed reactor import, the electromagnetic switch is by computer Keying is automatically controlled, the electromagnetic switch import connects the biological fluidized-bed reactor import, and the electromagnetic switch outlet connects Connect the biological fluidized-bed reactor outlet;
The three-level advanced treating module includes radial-flow sedimentation tank and SPR sewage purification devices, the radial-flow sedimentation tank import The secondary biochemical treatment module outlet is connected, outlet connects the SPR sewage purification devices import;The SPR sewage purification devices Outlet is connected to water treatment system general export.
The present invention is that one kind being suitable for flax degumming waste water integrated technology process, is to use above system, including following step Suddenly:
Step 1 starts operation level-one preprocessing module, flax degumming waste water is introduced into total sewage disposal system, waste water Mobile coarse rack basket is first passed around, the larger substance in waste water is removed;
Step 2 starts balancing tank, regulating water quality water;
Step 3 starts flotation tank, removes the suspended matter in water removal;
Step 4 starts Anaerobic Contact reactor, removes the pollutant in water removal;
Step 5 starts anoxic reacter, removes the pollutant in water removal;
Step 6, the COD value of on-line monitoring analysis anaerobic unit water outlet, works as COD>1000mg/L enters step seven, otherwise Enter step eight;
Step 7 starts biological fluidized-bed reactor, removes the pollutant in water removal;
Step 8 starts fixed type biological film-activated sludge reactor, removes the pollutant in water removal;
Step 9 starts radial-flow sedimentation tank, precipitation spoil disposal is carried out to waste water;
Step 10 starts SPR sewage purification devices, processing is filtered to waste water.
This method have the advantage that:
(1) treatment process used is current state-of-the-art treatment process, especially aerobic unit using two reactions Device ensures to save cost to the maximum extent while effluent quality by automatically controlling conversion process;
(2) anaerobic technique used in the present invention can quickly start for Anaerobic Contact reactor, and especially suitable for The flax degumming waste water larger into aqueous suspension, it is more difficult to solve traditional anaerobic technique granule sludge culture, system start-up time Longer problem;
(3) fixed type biological film-activated sludge reactor that modified activated sludge process is used in the present invention, increases The sludge concentration of traditional activated sludge process, can be effectively prevented from flax degumming waste water causes conventional activated sludge process to generate high stick The case where property sludge bulking;
(4) the biological fluidized-bed reactor technique used in the present invention increases internal flow velocity, can effectively avoid flax degumming Waste water causes the generation of common biomembrane process filler stopping state;
(5) the SPR techniques used in the present invention can remove COD, SS and disinfection simultaneously, and stable water outlet, water quality refer to Mark is good, and water outlet can reach recycle water standard, increase reuse water, while reducing enterprise's production cost;
(6) the process combination degree of modularity is high, and it is integrated equipment to be conducive to technical transform, saves space;Process combination skill Art is advanced, stably reaching standard.
Description of the drawings
Fig. 1 is present invention process route map.
Specific implementation mode
The present invention is described in detail below in conjunction with the accompanying drawings, but protection scope of the present invention is not limited by attached drawing.
Fig. 1 is present invention process route map, as shown, on-line monitoring system is arranged in water inlet end, by carrying out raw water Water quality information collect, analysis, result is exported to automatic control system, from automatic control system to a module or submodule list Member sends out signal, to control the automatic operating of integrated artistic.
Sewage is introduced into level-one preprocessing module, includes altogether 3 units, is mobile coarse rack basket, balancing tank respectively And flotation tank, series operation, wherein coarse rack grizzly bar gap are 5-10mm;The residence time is designed as 24 hours in balancing tank;Reaction The residence time is designed as 10min in pond, and it is 0.02m/s that contact chamber, which designs upflow velocity, and the contact chamber design residence time is 2min, gas Floating region separation chamber surface loading is 8-10m3/(m2H), the flotation tank design residence time is 15-25min.
Secondary biochemical module includes altogether 3 units, is Anaerobic Contact reactor, anoxic reacter and aerobic reaction respectively Unit, there are two reactors, respectively fixed biofilm-activated sludge process (IFAS) reactor and biology for aerobic reaction unit Fluidized-bed reactor.Wherein, Anaerobic Contact reactor design volumetric loading is 5-8kgCOD/m3·d;Design anoxic reacter The design residence time is 2-4h, mixed liquid recycle ratio 100%;Fixed biofilm-activated sludge process (IFAS) reactor design MLSS is 4000-5000mg/L;It is 5000-8000mg/L that biological fluidized-bed reactor, which designs MLSS, and floating stuffing grain size is 10mm, expansion rate 100%, BOD loading are 8.5-12kgBOD5/m3·d。
Three-level advanced treating module includes altogether 3 units, is radial-flow sedimentation tank and SPR sewage purification devices respectively.Wherein, Sedimentation basin design surface load is 0.8-1.0m3/(m2·h).SPR sewage purification devices design water outlet SS values are 3mg/L, select and live Property charcoal as adsorbent, select aluminium polychloride as coagulant, select polyacrylamide as flocculation aid, select liquid chlorine as Disinfectant.

Claims (6)

1. a kind of modularization integrated technology process suitable for flax degumming wastewater treatment, it is characterised in that:Integrated technique is by one Grade preprocessing module, secondary biochemical module and three-level advanced treating module composition, the level-one preprocessing module setting are mobile Coarse rack basket, balancing tank and flotation tank;Secondary biochemical module setting Anaerobic Contact reactor, anoxic reacter and aerobic Reaction member, there are two reactor, respectively fixed biofilm-activated sludge process reactors and biology to flow for aerobic reaction unit Fluidized bed reactor;The three-level advanced treating module setting radial-flow sedimentation tank and SPR sewage purification devices.
2. the modularization integrated technology process according to claim 1 suitable for flax degumming wastewater treatment, feature exists In:
The level-one preprocessing module includes mobile coarse rack basket, balancing tank and flotation tank, the movable type coarse rack basket Flax degumming waste water inlet is connected, outlet connects the balancing tank import;The balancing tank outlet connects the flotation tank Import;The flotation tank outlet connects the secondary biochemical module inlet;
The secondary biochemical module includes Anaerobic Contact reactor, anoxic reacter and aerobic reaction member, the Anaerobic Contact Reactor connects the level-one preprocessing module outlet, and outlet connects the anoxic reacter;The anoxic reacter outlet connects The aerobic reaction unit inlet is connect, the aerobic reaction unit outlet connects the three-level advanced treating module inlet;It is aerobic Reaction member includes fixed biofilm-activated sludge process (IFAS) reactor and biological fluidized-bed reactor, the biology stream Fluidized bed reactor import connects aerobic reaction member import, and it is anti-that outlet connects the fixed biofilm-activated sludge process (IFAS) Device import, fixed biofilm-activated sludge process (IFAS) reactor outlet is answered to connect aerobic reaction member outlet;It is described Electromagnetic switch is connected before biological fluidized-bed reactor import, the electromagnetic switch is automatically controlled by a computer keying, the electromagnetism It switchs import and connects the biological fluidized-bed reactor import, the electromagnetic switch outlet connects the biological fluidized-bed reactor Outlet;
The three-level advanced treating module includes radial-flow sedimentation tank and SPR sewage purification devices, the radial-flow sedimentation tank import connection The secondary biochemical treatment module outlet, outlet connect the SPR sewage purification devices import;The SPR sewage purification devices outlet It is connected to water treatment system general export.
3. a kind of modularization integrated technology process suitable for flax degumming wastewater treatment according to claim 1, feature It is, using above system, includes the following steps:
Step 1 starts operation level-one preprocessing module, flax degumming waste water is introduced into total sewage disposal system, waste water is first By mobile coarse rack basket, the larger substance in waste water is removed;
Step 2 starts balancing tank, regulating water quality water;
Step 3 starts flotation tank, removes the suspended matter in water removal;
Step 4 starts Anaerobic Contact reactor, removes the pollutant in water removal;
Step 5 starts anoxic reacter, removes the pollutant in water removal;
Step 6, the COD value of on-line monitoring analysis anaerobic unit water outlet, works as COD>1000mg/L enters step seven, otherwise enters Step 8;
Step 7 starts biological fluidized-bed reactor, removes the pollutant in water removal;
Step 8 starts fixed type biological film-activated sludge reactor, removes the pollutant in water removal;
Step 9 starts radial-flow sedimentation tank, precipitation spoil disposal is carried out to waste water;
Step 10 starts SPR sewage purification devices, is filtered and disinfects to waste water.
4. a kind of modularization integrated technology process suitable for flax degumming wastewater treatment according to claim 1, feature It is:The movable type coarse rack basket design coarse rack grizzly bar gap is 5-10mm;The balancing tank design residence time is 24h;The flotation tank reaction tank design residence time is 10min, and it is 0.02m/s that contact chamber, which designs upflow velocity, and contact chamber is set The meter residence time is 2min, and air flotation zone separation chamber surface loading is 8-10m3/(m2H), the flotation tank design residence time is 15—25min。
5. a kind of modularization integrated technology process suitable for flax degumming wastewater treatment according to claim 1, feature It is:The Anaerobic Contact reactor design volumetric loading is 5-8kgCOD/m3·d;When the anoxic reacter design stops Between be 2-4h, mixed liquid recycle ratio 100%;Fixed biofilm-activated sludge process (IFAS) reactor design MLSS is 4000—5000mg/L;The biological fluidized-bed reactor design MLSS is 5000-8000mg/L, and floating stuffing grain size is 10mm, expansion rate 100%, BOD loading are 8.5-12kgBOD5/m3·d。
6. a kind of modularization integrated technology process suitable for flax degumming wastewater treatment according to claim 1, feature It is:The radial-flow sedimentation tank design surface load is 0.8-1.0m3/(m2·h);The SPR sewage purification devices design water outlet SS values are 3mg/L, and activated carbon is selected to be used as adsorbent, selection aluminium polychloride as coagulant, select polyacrylamide as Flocculation aid selects liquid chlorine as disinfectant.
CN201810148624.6A 2018-02-13 2018-02-13 Modularized integrated process method suitable for treating flax degumming wastewater Active CN108328863B (en)

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CN113526799A (en) * 2021-08-03 2021-10-22 中国热带农业科学院 Method for treating wastewater generated after degumming and cooking of pineapple leaf fibers

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111410362A (en) * 2020-03-27 2020-07-14 普洱普蓝环境咨询有限公司 Method for treating coffee primary processing wastewater
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CN113526799A (en) * 2021-08-03 2021-10-22 中国热带农业科学院 Method for treating wastewater generated after degumming and cooking of pineapple leaf fibers

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