CN108323582A - A kind of high stability plant blend oil and preparation method thereof rich in DHA - Google Patents
A kind of high stability plant blend oil and preparation method thereof rich in DHA Download PDFInfo
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- CN108323582A CN108323582A CN201810055620.3A CN201810055620A CN108323582A CN 108323582 A CN108323582 A CN 108323582A CN 201810055620 A CN201810055620 A CN 201810055620A CN 108323582 A CN108323582 A CN 108323582A
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- dha
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- seed
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Classifications
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- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23D—EDIBLE OILS OR FATS, e.g. MARGARINES, SHORTENINGS, COOKING OILS
- A23D9/00—Other edible oils or fats, e.g. shortenings, cooking oils
- A23D9/007—Other edible oils or fats, e.g. shortenings, cooking oils characterised by ingredients other than fatty acid triglycerides
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23D—EDIBLE OILS OR FATS, e.g. MARGARINES, SHORTENINGS, COOKING OILS
- A23D9/00—Other edible oils or fats, e.g. shortenings, cooking oils
- A23D9/02—Other edible oils or fats, e.g. shortenings, cooking oils characterised by the production or working-up
- A23D9/04—Working-up
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11B—PRODUCING, e.g. BY PRESSING RAW MATERIALS OR BY EXTRACTION FROM WASTE MATERIALS, REFINING OR PRESERVING FATS, FATTY SUBSTANCES, e.g. LANOLIN, FATTY OILS OR WAXES; ESSENTIAL OILS; PERFUMES
- C11B1/00—Production of fats or fatty oils from raw materials
- C11B1/10—Production of fats or fatty oils from raw materials by extracting
- C11B1/104—Production of fats or fatty oils from raw materials by extracting using super critical gases or vapours
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11B—PRODUCING, e.g. BY PRESSING RAW MATERIALS OR BY EXTRACTION FROM WASTE MATERIALS, REFINING OR PRESERVING FATS, FATTY SUBSTANCES, e.g. LANOLIN, FATTY OILS OR WAXES; ESSENTIAL OILS; PERFUMES
- C11B3/00—Refining fats or fatty oils
- C11B3/12—Refining fats or fatty oils by distillation
Abstract
The invention discloses a kind of high stability plant blend oil and preparation method thereof rich in DHA, the plant blend oil includes the raw material of following weight percent:DHA 0.5~1.2%, strange Asia seed 20~30%, grape pip 20~30%, kardiseed 10~20%, peony seeds 10~20%, tea seed 10~20% and seabuckthorn seeds 10~20%.The plant blend oil of the present invention is not easy to be aoxidized, and stability is high, greatly meets the needs of market.
Description
Technical field
The present invention relates to a kind of edible blend oils, and in particular to a kind of high stability plant blend oil rich in DHA and its
Preparation method.
Background technology
DHA (docosahexaenoic acid) is a kind of to be distributed in the long-chain omega-fatty acid of human body everywhere.More particularly, it goes back
It is brain and the main composition fat of eyes and the important component of heart.The data constantly accumulated shows DHA in life
Safeguard that health plays very important role in each stage.
Human body maintains the normal function of various tissues, it is necessary to assure there are sufficient various aliphatic acid, it can if lacking them
Cause a series of symptoms, including growth retardation, the skin abnormality scales of skin that peel off, dysnoesia etc..DHA is as a kind of required fat
The effects that acid, enhancing memory is with thinking ability, raising intelligence, is more notable.Population epidemiology is the study found that DHA contains in vivo
Measure that the Psychological Endurance of high people is relatively strong, mental development index is also high.
With scientific and technical personnel to DHA's the study found that due to its active character make its exposure in air quickly occur from
Dynamic oxidation is rotten, or even generates fishlike smell, to influence product mouthfeel and nutritive value.To solve the problems, such as this, conventional oil is added
The common antioxidant such as fat, vitamin E or vitamin C or anti-oxidant auxiliary agent, still, antioxidant effect is general, moreover,
Want the ready-mixed oil of raw material based on DHA and common plant grease, it is with single nutrient component, Fatty acids composition is unreasonable, it is more difficult to by people
Body fully absorbs, and effect is not obvious in terms of intelligence development.
Invention content
In view of the above technical problems, the present invention provides a kind of rich in the high stability plant blend oil of DHA and its preparation
Method.
Technical solution is used by the present invention solves the technical problem:A kind of high stability plant reconciliation rich in DHA
Oil includes the raw material of following weight percent:DHA0.5~1.2%, strange Asia seed 20~30%, grape pip 20~30% are red
Flower seed 10~20%, peony seeds 10~20%, tea seed 10~20% and seabuckthorn seeds 10~20%.
The present invention solves another technical solution used by the technical problem:A kind of high stability plant rich in DHA
The preparation method of ready-mixed oil, includes the following steps:
First, according to weight ratio by the strange sub- seed 20~30%, grape pip 20~30%, kardiseed 10~20%,
It is added to multistage point after peony seeds 10~20%, tea seed 10~20% and the drying of seabuckthorn seeds 10~20%, mixing and crushing
From supercritical CO2In the extraction kettle of extraction equipment, extractant condition, 40~50 DEG C of extraction temperature, extracting pressure 32- are adjusted
40MPa, 2.5~5.0h of extraction time enter the decompression separation for carrying out carbon dioxide and grease in separating still, adjust after the completion of extraction
The process conditions of separating still are saved, 40~60 DEG C of I temperature of separating still, I 10~18MPa of pressure of separating still obtain plant from separating still I
Ready-mixed oil crude oil;
Then plant blend oil crude oil is refined:The plant blend oil crude oil of extraction gained is added to molecule
It distills in sample jar, adjusts molecular distillation technological parameter, 3~7Pa of vacuum degree, 110~130 DEG C of vapo(u)rizing temperature, knifing rotating speed 120
~240rmin-1, 40~60mLmin of charging rate-1And 30~40 DEG C of condensation temperature, carry out refining treatment, refining process
After the completion, the DHA that the plant blend oil after refining mixes the weight ratio is collected, the high stability for being rich in DHA is both obtained
Plant blend oil.
Compared with prior art, there is following good effect:The high stability plant blend oil rich in DHA of the present invention,
By adding the higher strange sub- seed oil of inoxidizability, grape seed oil, safflower seed oil, peony seed oil, camellia seed oil and Seabuckthorm Seed Oil,
Effective protection DHA is not oxidized, avoids generating bad eating mouth feel and fishlike smell;Wherein, strange sub- seed oil is rich in flavonoids antioxygen
Compound, such as chlorogenic acid, caffeic acid, myricetin not only itself have and remove free radical, prevent unsaturated fatty acid peroxidating
The effects that, more can preferably it be acted on ω -3 Coordinated Plays of DHA.In addition, grape seed oil, safflower seed oil, peony seed oil, oil tea
Seed oil and Seabuckthorm Seed Oil, not only be rich in various nutritional ingredients (vitamin E, phytosterol, minerals etc.), but also rich in oleic acid,
The unsaturated fatty acids such as linoleic acid plus linolenic acid, have greatly enriched the nutritive value of the plant blend oil of the present invention, and collocation is more closed
Reason, it is easier to it is fully absorbed by human body, it is better in terms of intelligence development.
With reference to embodiment, the invention will be further described.
Specific implementation mode
Embodiment 1
The high stability plant blend oil rich in DHA of embodiment 1, includes the raw material of following weight:DHA0.5kg, very
Sub- seed 29.5kg, grape pip 20kg, kardiseed 20kg;Peony seeds 10kg, tea seed 10kg and seabuckthorn seeds 10kg.
The high stability plant blend oil rich in DHA of embodiment 1, is prepared by the following method:
First, strange sub- seed 29.5kg, grape pip 20kg, kardiseed 20kg;Peony seeds 10kg, tea seed 10kg, Yi Jisha
Spine seed 10kg is dry, mix and is added to multi-stage separation supercritical CO after crushing2In the extraction kettle of extraction equipment, extraction work is adjusted
Skill condition, 50 DEG C, extracting pressure 32MPa, extraction time 5.0h of extraction temperature enter after the completion of extraction and carry out dioxy in separating still
The decompression separation for changing carbon and grease, adjusts the process conditions of separating still, and I temperature 60 C of separating still, I pressure 10MPa of separating still divide
30 DEG C from II temperature of kettle, II pressure 8MPa of separating still, III pressure 5MPa of 35 DEG C of III temperature of separating still and separating still, from separating still I
In plant blend oil crude oil;
Then plant blend oil crude oil is refined:The plant blend oil crude oil of extraction gained is added to molecule
It distills in sample jar, adjusts molecular distillation technological parameter, vacuum degree 7Pa, 110 DEG C of vapo(u)rizing temperature, knifing rotating speed 240rmin-1、
Charging rate 40mLmin-1And 40 DEG C of condensation temperature, refining treatment is carried out, after the completion of refining process, collects the plant after refining
The DHA of ready-mixed oil mixing 0.5kg had both obtained the high stability plant blend oil for being rich in DHA.
Above-mentioned includes three separating stills:Separating still I, separating still II and separating still III, the CO under supercriticality2And mixing
Object, which enters, carries out decompression separation, isolated plant blend oil crude oil and the CO with impurity in separating still I2, from separating still I
It obtains the plant blend oil crude oil to be refined, obtains product, and carry the CO of impurity2Sequentially enter separating still II and separation
The separation that carbon dioxide and grease impurities are carried out in kettle III obtains the high CO of purity2Recycling.Three separating stills constitute
The operation principle of multi-stage separation technology, the multi-stage separation is identical in the following example.
The DHA of embodiment 1 selects the DHA (sterling) of Guangdong Runke Bioengineering Co., Ltd..The DHA of embodiment 2-6
Select the DHA (sterling) of Guangdong Runke Bioengineering Co., Ltd..
Embodiment 2
The high stability plant blend oil rich in DHA of embodiment 2, includes the raw material of following weight:DHA1.2kg, very
Sub- seed 20kg, grape pip 23.8kg, kardiseed 10kg;Peony seeds 15kg, tea seed 20kg and seabuckthorn seeds 10kg.
The high stability plant blend oil rich in DHA of embodiment 2, is prepared by the following method:
First, strange sub- seed 20kg, grape pip 23.8kg, kardiseed 10kg;Peony seeds 15kg, tea seed 20kg, Yi Jisha
Spine seed 10kg is dry, mix and is added to multi-stage separation supercritical CO after crushing2In the extraction kettle of extraction equipment, extraction work is adjusted
Skill condition, 40 DEG C, extracting pressure 40MPa, extraction time 2.5h of extraction temperature enter after the completion of extraction and carry out dioxy in separating still
The decompression separation for changing carbon and grease, adjusts the process conditions of separating still, and 40 DEG C of I temperature of separating still, I pressure 18MPa of separating still divide
40 DEG C from II temperature of kettle, II pressure 5MPa of separating still, III pressure 8MPa of 40 DEG C of III temperature of separating still and separating still, from separating still I
In plant blend oil crude oil;
Then plant blend oil crude oil is refined:The plant blend oil crude oil of extraction gained is added to molecule
It distills in sample jar, adjusts molecular distillation technological parameter, vacuum degree 3Pa, 130 DEG C of vapo(u)rizing temperature, knifing rotating speed 120rmin-1、
Charging rate 60mLmin-1And 30 DEG C of condensation temperature, refining treatment is carried out, after the completion of refining process, collects the plant after refining
The DHA of ready-mixed oil mixing 1.2kg had both obtained the high stability plant blend oil for being rich in DHA.
Embodiment 3
The high stability plant blend oil rich in DHA of embodiment 3, includes the raw material of following weight:DHA1kg, it is strange sub-
Seed 30kg, grape pip 22kg, kardiseed 15kg;Peony seeds 12kg, tea seed 10kg and seabuckthorn seeds 10kg.
The high stability plant blend oil rich in DHA of embodiment 3, is prepared by the following method:
First, strange sub- seed 30kg, grape pip 22kg, kardiseed 15kg;Peony seeds 12kg, tea seed 10kg and sea-buckthorn
Seed 10kg is dry, mix and is added to multi-stage separation supercritical CO after crushing2In the extraction kettle of extraction equipment, extraction process is adjusted
Condition, 50 DEG C, extracting pressure 35MPa, extraction time 4.0h of extraction temperature enter after the completion of extraction and carry out titanium dioxide in separating still
The decompression separation of carbon and grease adjusts the process conditions of separating still, I temperature 60 C of separating still, I pressure 15MPa of separating still, separation
25 DEG C of II temperature of kettle, III pressure 7MPa of II pressure 6MPa of separating still, 38 DEG C of III temperature of separating still and separating still, from separating still I
Obtain plant blend oil crude oil;
Then plant blend oil crude oil is refined:The plant blend oil crude oil of extraction gained is added to molecule
It distills in sample jar, adjusts molecular distillation technological parameter, vacuum degree 5Pa, 120 DEG C of vapo(u)rizing temperature, knifing rotating speed 200rmin-1、
Charging rate 50mLmin-1And 30 DEG C of condensation temperature, refining treatment is carried out, after the completion of refining process, collects the plant after refining
The DHA of ready-mixed oil mixing 1kg had both obtained the high stability plant blend oil for being rich in DHA.
Embodiment 4
The high stability plant blend oil rich in DHA of embodiment 4, includes the raw material of following weight:DHA0.8kg, very
Sub- seed 20kg, grape pip 30kg, kardiseed 11.2kg;Peony seeds 10kg, tea seed 14kg and seabuckthorn seeds 14kg.
The high stability plant blend oil rich in DHA of embodiment 4, is prepared by the following method:
First, strange sub- seed 20kg, grape pip 30kg, kardiseed 11.2kg;Peony seeds 10kg, tea seed 14kg, Yi Jisha
Spine seed 14kg is dry, mix and is added to multi-stage separation supercritical CO after crushing2In the extraction kettle of extraction equipment, extraction work is adjusted
Skill condition, 40 DEG C, extracting pressure 32MPa, extraction time 3.0h of extraction temperature enter after the completion of extraction and carry out dioxy in separating still
The decompression separation for changing carbon and grease, adjusts the process conditions of separating still, and I temperature 50 C of separating still, I pressure 10MPa of separating still divide
28 DEG C from II temperature of kettle, II pressure 8MPa of separating still, III pressure 6MPa of 40 DEG C of III temperature of separating still and separating still, from separating still I
In plant blend oil crude oil;
Then plant blend oil crude oil is refined:The plant blend oil crude oil of extraction gained is added to molecule
It distills in sample jar, adjusts molecular distillation technological parameter, vacuum degree 5Pa, 120 DEG C of vapo(u)rizing temperature, knifing rotating speed 180rmin-1、
Charging rate 50mLmin-1And 40 DEG C of condensation temperature, refining treatment is carried out, after the completion of refining process, collects the plant after refining
The DHA of ready-mixed oil mixing 0.8kg had both obtained the high stability plant blend oil for being rich in DHA.
Embodiment 5
The high stability plant blend oil rich in DHA of embodiment 5, includes the raw material of following weight:DHA1kg, it is strange sub-
Seed 21kg, grape pip 28kg, kardiseed 10kg;Peony seeds 20kg, tea seed 10kg and seabuckthorn seeds 10kg.
The high stability plant blend oil rich in DHA of embodiment 5, preparation method are same as Example 1.
Embodiment 6
The high stability plant blend oil rich in DHA of embodiment 6, includes the raw material of following weight:DHA1kg, it is strange sub-
Seed 20kg, grape pip 23kg, kardiseed 10kg;Peony seeds 16kg, tea seed 10kg and seabuckthorn seeds 20kg.
The high stability plant blend oil rich in DHA of embodiment 6, preparation method are same as Example 3.
Its main fatty acid composition and content are detected according to internal standard method described in GB 5009.168-2016, as a result such as 1 institute of table
Show.
The aliphatic acid composition and content (%) of ready-mixed oils of the 1 embodiment 1-6 of table rich in DHA
Aliphatic acid | Saturated fatty acid | Unsaturated fatty acid | Oleic acid | Linoleic acid | Leukotrienes | DHA |
Embodiment 1 | 12.36 | 87.64 | 33.56 | 28.51 | 16.32 | 1.2 |
Embodiment 2 | 11.65 | 88.35 | 28.65 | 25.43 | 17.96 | 1.2 |
Embodiment 3 | 14.52 | 85.48 | 30.69 | 26.75 | 20.33 | 1.0 |
Embodiment 4 | 9.86 | 90.14 | 36.95 | 23.68 | 18.67 | 0.8 |
Embodiment 5 | 10.74 | 89.26 | 31.56 | 22.66 | 15.42 | 1.0 |
Embodiment 6 | 9.41 | 90.59 | 34.88 | 24.59 | 18.53 | 1.0 |
As it can be seen from table 1 the DHA content in ready-mixed oil obtained by embodiment 1-6 is up to 1% or so, and unsaturated fat
For acid content up to 90%, wherein oleic acid and linoleic acid content is higher, can effectively supplement needed by human body aliphatic acid.
Peroxide value is detected according to GB 5009.227-2016, acid value is detected according to GB 5009.229-2016.
The physical and chemical index of ready-mixed oils of the 2 embodiment 1-6 of table rich in DHA
Physical and chemical index | Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 | Embodiment 5 | Embodiment 6 |
Peroxide value (mmol/kg) | 1.52 | 1.21 | 1.89 | 1.54 | 1.33 | 1.55 |
Acid value (mg/g) | 0.76 | 0.68 | 0.59 | 0.55 | 0.64 | 0.71 |
As shown in Table 2, after supercritical carbon dioxide extracting and molecular distillation, the peroxide value of gained ready-mixed oil and
Acid value fabulous can meet ready-mixed oil national standard, illustrate that the preparation process of ready-mixed oil of the present invention is scientific and reasonable.
According to method described in GB/T 21121-2007, embodiment is measured using 679 type oxidimetry instrument of Rancimat
Induction time of the ready-mixed oil at 120 DEG C obtained by 1-6, is tested using constant temperature (25 DEG C) accelerated oxidation, public by A rrhenius
Formula predicts that the results are shown in Table 3 to gained ready-mixed oil shelf life.
The oxidation stability testing result of 3 ready-mixed oils of the embodiment 1-6 containing DHA of table
Stability | Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 | Embodiment 5 | Embodiment 6 |
Induction period (h) | 8.51 | 7.86 | 8.62 | 8.15 | 9.03 | 7.56 |
Shelf life (d) | 185 | 205 | 182 | 201 | 196 | 188 |
3 experimental result of table shows that induction period of the ready-mixed oil at 120 DEG C obtained by embodiment 1-6 is all higher than 10 hours, shows
The oxidation stability of ready-mixed oil of the present invention is preferable;The present invention is protected from light storage at 25 DEG C, the shelf-life was up to 180 days or more.
The invention is not limited in the above embodiments, if not departing from the present invention to the various changes or modifications of the present invention
Spirit and scope, if these modification and variations belong within the scope of the claim and equivalent technologies of the present invention, then this hair
It is bright to be also intended to include these modification and variations.
Claims (3)
1. a kind of high stability plant blend oil rich in DHA, it is characterised in that:Include the raw material of following weight percent:
DHA 0.5~1.2%, strange Asia seed 20~30%, grape pip 20~30%, kardiseed 10~20%, peony seeds 10~20%, oil
Tea seed 10~20% and seabuckthorn seeds 10~20%.
2. being rich in the high stability plant blend oil of DHA as described in claim 1, which is characterized in that include the following steps:
First, according to weight ratio by the strange sub- seed 20~30%, grape pip 20~30%, kardiseed 10~20%, tree peony
It is super it to be added to multi-stage separation after seed 10~20%, tea seed 10~20% and the drying of seabuckthorn seeds 10~20%, mixing and crushing
Critical CO2In the extraction kettle of extraction equipment, adjusting extractant condition, 40~50 DEG C, extracting pressure 32-40MPa of extraction temperature,
2.5~5.0h of extraction time enters the decompression separation for carrying out carbon dioxide and grease in separating still, adjusts separation after the completion of extraction
The process conditions of kettle, 40~60 DEG C of I temperature of separating still, I 10~18MPa of pressure of separating still obtain plant blend oil from separating still I
Crude oil;Then plant blend oil crude oil is refined:The plant blend oil crude oil of extraction gained is added to molecule to steam
It evaporates in sample jar, adjusting molecular distillation technological parameter, 3~7Pa of vacuum degree, 110~130 DEG C of vapo(u)rizing temperature, knifing rotating speed 120~
240r·min-1, 40~60mLmin of charging rate-1And 30~40 DEG C of condensation temperature, refining treatment is carried out, refining process is complete
Cheng Hou, collects the DHA that the plant blend oil after refining mixes the weight ratio, has both obtained the high stability rich in DHA and has planted
Object ready-mixed oil.
3. a kind of preparation method of the high stability plant blend oil rich in DHA, which is characterized in that include the following steps:First,
Raw material are weighed according to following weight percent:DHA 0.5~1.2%, strange Asia seed 20~30%, grape pip 20~30% are red
Flower seed 10~20%;Peony seeds 10~20%, tea seed 10~20% and seabuckthorn seeds 10~20%;The strange sub- seed, grape
It is added to multi-stage separation supercritical CO after seed, kardiseed, peony seeds, tea seed and seabuckthorn seeds mixing, dry and crushing2Extraction is set
In standby extraction kettle, adjusting extractant condition, 40~50 DEG C, extracting pressure 32-40MPa of extraction temperature, extraction time 2.5~
5.0h enters the decompression separation for carrying out carbon dioxide and grease in separating still, adjusts the process conditions of separating still after the completion of extraction,
40~60 DEG C of I temperature of separating still, I 10~18MPa of pressure of separating still obtain plant blend oil crude oil from separating still I;
Then plant blend oil crude oil is refined:The plant blend oil crude oil of extraction gained is added to molecular distillation
In sample jar, adjusting molecular distillation technological parameter, 3~7Pa of vacuum degree, 110~130 DEG C of vapo(u)rizing temperature, knifing rotating speed 120~
240r·min-1, 40~60mLmin of charging rate-1And 30~40 DEG C of condensation temperature, refining treatment is carried out, refining process is complete
Cheng Hou collects the plant blend oil after refining and mixes the DHA, both obtained the high stability plant blend oil for being rich in DHA.
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CN101884351A (en) * | 2010-07-13 | 2010-11-17 | 山东金丰粮油集团有限公司 | Safflower seed nutritional blend oil |
CN103385314A (en) * | 2013-07-29 | 2013-11-13 | 山东三星玉米产业科技有限公司 | Flavor health-care blending oil and preparation method thereof |
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CN104886269A (en) * | 2014-03-06 | 2015-09-09 | 洛阳春魁农业开发有限公司 | Female special dietary peony seed nutritional blend oil |
CN104938653A (en) * | 2015-06-24 | 2015-09-30 | 洛阳国花坊牡丹生物科技有限公司 | Preparation method of peony seed oil and safflower seed oil blended cooking oil |
CN105941666A (en) * | 2016-05-13 | 2016-09-21 | 王永妍 | Peony seed oil with health-care efficacy and preparation method thereof |
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2018
- 2018-01-19 CN CN201810055620.3A patent/CN108323582A/en active Pending
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Publication number | Priority date | Publication date | Assignee | Title |
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CN101884351A (en) * | 2010-07-13 | 2010-11-17 | 山东金丰粮油集团有限公司 | Safflower seed nutritional blend oil |
CN103385314A (en) * | 2013-07-29 | 2013-11-13 | 山东三星玉米产业科技有限公司 | Flavor health-care blending oil and preparation method thereof |
CN104509599A (en) * | 2013-09-29 | 2015-04-15 | 中粮营养健康研究院有限公司 | Edible oil blending method for reinforcing n-3 polyunsaturated fatty acids, and apparatus thereof |
CN104886269A (en) * | 2014-03-06 | 2015-09-09 | 洛阳春魁农业开发有限公司 | Female special dietary peony seed nutritional blend oil |
CN104938653A (en) * | 2015-06-24 | 2015-09-30 | 洛阳国花坊牡丹生物科技有限公司 | Preparation method of peony seed oil and safflower seed oil blended cooking oil |
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Application publication date: 20180727 |