CN108315747A - A kind of composite stainless steel cleaning agent - Google Patents

A kind of composite stainless steel cleaning agent Download PDF

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Publication number
CN108315747A
CN108315747A CN201810360136.1A CN201810360136A CN108315747A CN 108315747 A CN108315747 A CN 108315747A CN 201810360136 A CN201810360136 A CN 201810360136A CN 108315747 A CN108315747 A CN 108315747A
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parts
stainless steel
cleaning agent
composite stainless
carbomer
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万玉梅
朱冬梅
张烨
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    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23GCLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
    • C23G1/00Cleaning or pickling metallic material with solutions or molten salts
    • C23G1/24Cleaning or pickling metallic material with solutions or molten salts with neutral solutions

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
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Abstract

The invention discloses a kind of composite stainless steel cleaning agents, belong to stainless steel surface cleaning material field.The present invention counts in parts by weight, by 10~20 parts of dopamine solutions, 10~20 parts of bacillus subtilis bacterium solutions, 5~8 parts of carbomers, 8~10 parts of property-modifying additives, 8~10 parts of aniline, 2~3 parts of urea, 10~20 parts of polyvinyl alcohol liquid, 3~5 parts of malic acid, 3~5 parts of phosphatide, 3~5 parts of plants essential oils, 20~30 parts of water are placed in batch mixer, under the conditions of rotating speed is 300~500r/min, 40~60min is stirred to get composite stainless steel cleaning agent.Composite stainless steel cleaning agent provided by the invention has excellent cleaning performance, and has long-effective protection and corrosion inhibition.

Description

A kind of composite stainless steel cleaning agent
Technical field
The invention discloses a kind of composite stainless steel cleaning agents, belong to stainless steel surface cleaning material field.
Background technology
To in the chemical cleaning construction of heating equipment, stainless steel plate type heat exchanger is main cleaning equipment before heat supply in winter One of.Because plate heat exchanger has, heat exchange efficiency is high, floor space is small, and service life length, convenient disassembly, operational safety can Lean on, price it is low, the features such as malleable heat exchange area or path combination, easy cleaning, be widely used in central heating and enterprise change In hot device systems.Cleaning for plate heat exchanger can carry out on-line chemical cleaning;Can also loosening pressed bolt, Plate beam is unclamped, lower sheet space is unloaded and carries out mechanical cleaning or chemical cleaning.The plate of plate heat exchanger generally uses 304 or 316 Ovshinskies Body stainless steel.And austenitic stainless steel is that the high-alloy steel of the alloying elements such as chromium, nickel, molybdenum is added using iron as matrix, surface has One layer of fine and close chromium oxide passivation film is not easy to be corroded under general condition.Meanwhile austenitic stainless steel is because of bright in appearance, anti-corruption Erosion and excellent machining property, are also widely used for the manufacture of other industrial equipments.
In the chemical cleaning of stainless steel equipment, forbid the cleaning agent using chloride ion-containing.This is because chlorion is rotten Corrosion ion, it can be preferentially adsorbed on passivating film, oxygen atom is supplanted, and then combine and generate with the cation in passivating film Soluble chloride is generated small etch pit on base metal, and can be formed the erosion of bigger using these small etch pits as activated centre Hole, and then cause metal spot corrosion, crevice corrosion and stress corrosion, so the passive state of stainless steel is played directly in the presence of chlorion Broken ring effect, can be caused when serious equipment perforation, scrap.With being widely used for stainless steel equipment, various stainless steel cleanings Agent is developed and is applied in succession.The particular/special requirement of austenitic steel equipment material, existing to grind in constructing for chemical cleaning The person of studying carefully is compounded sulfamic acid and nitric acid by debita spissitudo, while a certain amount of high-efficient corrosion inhibitor and bleeding agent is added, and is matched New type stainless steel. corrosion resistance cleaning agent is made.But traditional stainless steel cleaner is there is also the bad problem of cleaning performance at present, also needs pair It is studied.
Invention content
The present invention solves the technical problem of:For the bad problem of traditional stainless steel cleaner cleaning performance, carry A kind of composite stainless steel cleaning agent is supplied.
In order to solve the above-mentioned technical problem, the technical solution adopted in the present invention is:
A kind of composite stainless steel cleaning agent, is made of the raw material of following parts by weight:
10~20 parts of dopamine solution
10~20 parts of bacillus subtilis bacterium solution
5~8 parts of carbomer
8~10 parts of property-modifying additive
8~10 parts of aniline
2~3 parts of urea
10~20 parts of polyvinyl alcohol liquid
Phosphatidase 3~5 part
3~5 parts of plants essential oil
20~30 parts of water
The process for preparation of the stainless steel cleaner is:Each raw material is weighed by raw material composition, by dopamine solution, bacillus subtilis Bacterium bacterium solution, carbomer, property-modifying additive, aniline, urea, polyvinyl alcohol liquid, malic acid, phosphatide, plants essential oil and water stirring are mixed It closes to get composite stainless steel cleaning agent.
The bacillus subtilis bacterium solution is made of the raw material of following parts by weight:10~20 parts of bacillus subtilises, 8 ~10 parts of glycerine, 8~10 parts of glucose solutions, 20~30 parts of deionized waters.
The carbomer is any one in carbomer 734P, carbomer 740P or carbomer 710P.
The preparation process of the property-modifying additive is:It will(N- amidino groups)Dodecylacrylamide and polyethylene glycol phosphate In mass ratio 2:1~4:1 mixing, and the paracide and polyethylene glycol phosphorus of 0.2~0.4 times of polyethylene glycol phosphate quality is added The ferrocene that 0.12~0.18 times of acid esters quality, constant temperature are stirred to react, and are discharged to get property-modifying additive.
The preparation process of the polyvinyl alcohol liquid is:By polyvinyl alcohol and water in mass ratio 1:50~1:100 mixing, stand After swelling, heating stirring mixes to get polyvinyl alcohol liquid.
The phosphatide is cholinphospholipide, sphingomylin, any one in serinephosphatide or glycerophosphatide.
The plants essential oil is Rosemary Oil, Lavender, feverfew essential oil, in camellia essential oil or Schisandra chinensis essential oil Any one.
The beneficial effects of the invention are as follows:
The present invention first, is produced in bacillus subtilis metabolic process in use by adding bacillus subtilis bacterium solution Raw lipase, can effectively decompose the greasy dirt of steel surface, to enhance the cleaning performance of cleaning agent, secondly, bacillus subtilis Organic acid is generated in bacterium metabolic process, organic acid can be reacted with iron oxide, on the one hand, the iron rust of steel surface is can remove, it is another Aspect, organic acid are reacted with iron oxide, generate iron ion, iron ion can promote polyvinyl alcohol coordination cross-linked, in steel surface shape At protective film, steel is effectively prevent to be aoxidized again, meanwhile, organic acid can be with iron oxide exothermic heat of reaction so that system temperature liter Height improves the activity of enzyme, to further promote the cleaning performance of cleaning agent, again, in bacillus subtilis metabolic process Laccase is generated, aniline can shift electronics to laccase, form aniline free radical, and aniline free radical can cause aniline polymerization, form three Network is tieed up, the interspersed crosslinking of three-dimensional network of the three-dimensional network of formation and polyvinyl alcohol crosslinked formation further enhances protective film Intensity, to play long-effective protection and corrosion inhibition.
Specific implementation mode
It counts in parts by weight, by 10~20 parts of bacillus subtilises, 8~10 parts of glycerine, 8~10 parts of mass fractions are 0.3 ~0.5% glucose solution, 20~30 parts of deionized waters are placed in single-necked flask, and single-necked flask is placed in digital display and is tested the speed perseverance It it is 28~32 DEG C in temperature, under the conditions of rotating speed is 300~500r/min, constant temperature stirs 30~50min in warm magnetic stirring apparatus Afterwards to get bacillus subtilis bacterium solution;It will(N- amidino groups)Dodecylacrylamide and polyethylene glycol phosphate in mass ratio 2:1 ~4:1 is placed in No. 1 beaker, and be added into No. 1 beaker 0.2~0.4 times of polyethylene glycol phosphate quality paracide and The ferrocene of 0.12~0.18 times of polyethylene glycol phosphate quality is stirred 30 under the conditions of rotating speed is 300~500r/min ~50min is to get property-modifying additive;By polyvinyl alcohol and water in mass ratio 1:50~1:100 are added in No. 2 beakers, use glass After stick is stirred 20~30min, after standing 3~4h of swelling, then No. 2 beakers is moved into digital display and are tested the speed constant temperature blender with magnetic force In, it is 90~95 DEG C in temperature, under the conditions of rotating speed is 300~500r/min, heating stirring dissolves 30~50min, then to No. 2 Beaker be added polyvinyl alcohol 0.4~0.5 times of mass fraction of quality be 3~5% sodium periodate solution, in temperature be 90~95 DEG C, Under the conditions of rotating speed is 300~500r/min, continues heating stirring and mix 40~60min to get modified polyvinylalcohol liquid;By weight Number meter, by 10~20 parts of dopamine solutions, 10~20 parts of bacillus subtilis bacterium solutions, 5~8 parts of carbomers, 8~10 parts of modifications Additive, 8~10 parts of aniline, 2~3 parts of urea, 10~20 parts of polyvinyl alcohol liquid, 3~5 parts of phosphatide, 3~5 parts of plants essential oils, 20 ~30 parts of water are placed in batch mixer, in rotating speed be 300~500r/min under the conditions of, be stirred 40~60min to get it is compound not Become rusty steel cleaning agent.The carbomer is any one in carbomer 734P, carbomer 740P or carbomer 710P.The phosphatide For cholinphospholipide, sphingomylin, any one in serinephosphatide or glycerophosphatide.The plants essential oil is rosemary essence Any one in oil, Lavender, feverfew essential oil, camellia essential oil or Schisandra chinensis essential oil.
Example 1
It counts in parts by weight, by 20 parts of bacillus subtilises, 10 parts of glycerine, the glucose solution that 10 parts of mass fractions are 0.5%, 30 parts of deionized waters are placed in single-necked flask, and single-necked flask is placed in digital display and is tested the speed in constant temperature blender with magnetic force, are in temperature 32 DEG C, under the conditions of rotating speed is 500r/min, to get bacillus subtilis bacterium solution after constant temperature stirring 50min;It will(N- amidino groups)12 Alkyl acrylamide and polyethylene glycol phosphate in mass ratio 4:1 is placed in No. 1 beaker, and poly- second two is added into No. 1 beaker The ferrocene of 0.18 times of the paracide and polyethylene glycol phosphate quality of 0.4 times of alcohol phosphate quality, in rotating speed be 500r/ Under the conditions of min, 50min is stirred to get property-modifying additive;By polyvinyl alcohol and water in mass ratio 1:100 are added No. 2 beakers In, after being stirred 30min with glass bar, after standing swelling 4h, then No. 2 beakers is moved into digital display and are tested the speed constant temperature blender with magnetic force In, it is 95 DEG C in temperature, under the conditions of rotating speed is 500r/min, heating stirring dissolves 50min, and poly- second is added then to No. 2 beakers 0.5 times of mass fraction of enol quality be 5% sodium periodate solution, in temperature be 95 DEG C, rotating speed be 500r/min under the conditions of, after Continuous heating stirring mixes 60min to get modified polyvinylalcohol liquid;It counts in parts by weight, by 20 parts of dopamine solutions, 20 portions of withered grass Bacillus bacterium solution, 8 parts of carbomers, 10 parts of property-modifying additives, 10 parts of aniline, 3 parts of urea, 20 parts of polyvinyl alcohol liquid, 5 parts of phosphorus Fat, 5 parts of plants essential oils, 30 parts of water are placed in batch mixer, under the conditions of rotating speed is 500r/min, are stirred 60min to get multiple Close stainless steel cleaner.The carbomer is carbomer 734P.The phosphatide is cholinphospholipide.The plants essential oil is rosemary Essential oil.
Example 2
It will(N- amidino groups)Dodecylacrylamide and polyethylene glycol phosphate in mass ratio 4:1 is placed in No. 1 beaker, and to 1 The paracide of 0.4 times of polyethylene glycol phosphate quality and two cyclopentadienyls of 0.18 times of polyethylene glycol phosphate quality are added in number beaker Iron is stirred 50min to get property-modifying additive under the conditions of rotating speed is 500r/min;In mass ratio by polyvinyl alcohol and water 1:100 are added in No. 2 beakers, after being stirred 30min with glass bar, after standing swelling 4h, then No. 2 beakers are moved to digital display and are surveyed It is 95 DEG C in temperature in fast constant temperature blender with magnetic force, under the conditions of rotating speed is 500r/min, heating stirring dissolves 50min, then to The sodium periodate solution that polyvinyl alcohol 0.5 times of mass fraction of quality is 5% is added in No. 2 beakers, is 95 DEG C in temperature, rotating speed is Under the conditions of 500r/min, continues heating stirring and mix 60min to get modified polyvinylalcohol liquid;It counts in parts by weight, it will be more than 20 parts Bar amine aqueous solution, 8 parts of carbomers, 10 parts of property-modifying additives, 10 parts of aniline, 3 parts of urea, 20 parts of polyvinyl alcohol liquid, 5 parts of phosphatide, 5 parts Plants essential oil, 30 parts of water are placed in batch mixer, under the conditions of rotating speed is 500r/min, are stirred 60min to get compound stainless Steel cleaning agent.The carbomer is carbomer 734P.The phosphatide is cholinphospholipide.The plants essential oil is Rosemary Oil.
Example 3
It counts in parts by weight, by 20 parts of bacillus subtilises, 10 parts of glycerine, the glucose solution that 10 parts of mass fractions are 0.5%, 30 parts of deionized waters are placed in single-necked flask, and single-necked flask is placed in digital display and is tested the speed in constant temperature blender with magnetic force, are in temperature 32 DEG C, under the conditions of rotating speed is 500r/min, to get bacillus subtilis bacterium solution after constant temperature stirring 50min;It will(N- amidino groups)12 Alkyl acrylamide and polyethylene glycol phosphate in mass ratio 4:1 is placed in No. 1 beaker, and poly- second two is added into No. 1 beaker The ferrocene of 0.18 times of the paracide and polyethylene glycol phosphate quality of 0.4 times of alcohol phosphate quality, in rotating speed be 500r/ Under the conditions of min, 50min is stirred to get property-modifying additive;By polyvinyl alcohol and water in mass ratio 1:100 are added No. 2 beakers In, after being stirred 30min with glass bar, after standing swelling 4h, then No. 2 beakers is moved into digital display and are tested the speed constant temperature blender with magnetic force In, it is 95 DEG C in temperature, under the conditions of rotating speed is 500r/min, heating stirring dissolves 50min, and poly- second is added then to No. 2 beakers 0.5 times of mass fraction of enol quality be 5% sodium periodate solution, in temperature be 95 DEG C, rotating speed be 500r/min under the conditions of, after Continuous heating stirring mixes 60min to get modified polyvinylalcohol liquid;It counts in parts by weight, by 20 parts of dopamine solutions, 20 portions of withered grass Bacillus bacterium solution, 10 parts of property-modifying additives, 10 parts of aniline, 3 parts of urea, 20 parts of polyvinyl alcohol liquid, 5 parts of phosphatide, 5 parts of plant essences Oil, 30 parts of water are placed in batch mixer, under the conditions of rotating speed is 500r/min, is stirred 60min and is cleaned to get composite stainless steel Agent.The phosphatide is cholinphospholipide.The plants essential oil is Rosemary Oil.
Example 4
It counts in parts by weight, by 20 parts of bacillus subtilises, 10 parts of glycerine, the glucose solution that 10 parts of mass fractions are 0.5%, 30 parts of deionized waters are placed in single-necked flask, and single-necked flask is placed in digital display and is tested the speed in constant temperature blender with magnetic force, are in temperature 32 DEG C, under the conditions of rotating speed is 500r/min, to get bacillus subtilis bacterium solution after constant temperature stirring 50min;It will(N- amidino groups)12 Alkyl acrylamide and polyethylene glycol phosphate in mass ratio 4:1 is placed in No. 1 beaker, and poly- second two is added into No. 1 beaker The ferrocene of 0.18 times of the paracide and polyethylene glycol phosphate quality of 0.4 times of alcohol phosphate quality, in rotating speed be 500r/ Under the conditions of min, 50min is stirred to get property-modifying additive;By polyvinyl alcohol and water in mass ratio 1:100 are added No. 2 beakers In, after being stirred 30min with glass bar, after standing swelling 4h, then No. 2 beakers is moved into digital display and are tested the speed constant temperature blender with magnetic force In, it is 95 DEG C in temperature, under the conditions of rotating speed is 500r/min, heating stirring dissolves 50min, and poly- second is added then to No. 2 beakers 0.5 times of mass fraction of enol quality be 5% sodium periodate solution, in temperature be 95 DEG C, rotating speed be 500r/min under the conditions of, after Continuous heating stirring mixes 60min to get modified polyvinylalcohol liquid;It counts in parts by weight, by 20 parts of dopamine solutions, 20 portions of withered grass Bacillus bacterium solution, 8 parts of carbomers, 10 parts of aniline, 3 parts of urea, 20 parts of polyvinyl alcohol liquid, 5 parts of phosphatide, 5 parts of plants essential oils, 30 Part water is placed in batch mixer, under the conditions of rotating speed is 500r/min, is stirred 60min to get composite stainless steel cleaning agent.Institute It is carbomer 734P to state carbomer.The phosphatide is cholinphospholipide.The plants essential oil is Rosemary Oil.
Example 5
It counts in parts by weight, by 20 parts of bacillus subtilises, 10 parts of glycerine, the glucose solution that 10 parts of mass fractions are 0.5%, 30 parts of deionized waters are placed in single-necked flask, and single-necked flask is placed in digital display and is tested the speed in constant temperature blender with magnetic force, are in temperature 32 DEG C, under the conditions of rotating speed is 500r/min, to get bacillus subtilis bacterium solution after constant temperature stirring 50min;It will(N- amidino groups)12 Alkyl acrylamide and polyethylene glycol phosphate in mass ratio 4:1 is placed in No. 1 beaker, and poly- second two is added into No. 1 beaker The ferrocene of 0.18 times of the paracide and polyethylene glycol phosphate quality of 0.4 times of alcohol phosphate quality, in rotating speed be 500r/ Under the conditions of min, 50min is stirred to get property-modifying additive;It counts in parts by weight, by 20 parts of dopamine solutions, 20 portions of withered grass Bacillus bacterium solution, 8 parts of carbomers, 10 parts of property-modifying additives, 10 parts of aniline, 3 parts of urea, 5 parts of phosphatide, 5 parts of plants essential oils, 30 Part water is placed in batch mixer, under the conditions of rotating speed is 500r/min, is stirred 60min to get composite stainless steel cleaning agent.Institute It is carbomer 734P to state carbomer.The phosphatide is cholinphospholipide.The plants essential oil is Rosemary Oil.
Example 6
It counts in parts by weight, by 20 parts of bacillus subtilises, 10 parts of glycerine, the glucose solution that 10 parts of mass fractions are 0.5%, 30 parts of deionized waters are placed in single-necked flask, and single-necked flask is placed in digital display and is tested the speed in constant temperature blender with magnetic force, are in temperature 32 DEG C, under the conditions of rotating speed is 500r/min, to get bacillus subtilis bacterium solution after constant temperature stirring 50min;It will(N- amidino groups)12 Alkyl acrylamide and polyethylene glycol phosphate in mass ratio 4:1 is placed in No. 1 beaker, and poly- second two is added into No. 1 beaker The ferrocene of 0.18 times of the paracide and polyethylene glycol phosphate quality of 0.4 times of alcohol phosphate quality, in rotating speed be 500r/ Under the conditions of min, 50min is stirred to get property-modifying additive;By polyvinyl alcohol and water in mass ratio 1:100 are added No. 2 beakers In, after being stirred 30min with glass bar, after standing swelling 4h, then No. 2 beakers is moved into digital display and are tested the speed constant temperature blender with magnetic force In, it is 95 DEG C in temperature, under the conditions of rotating speed is 500r/min, heating stirring dissolves 50min, and poly- second is added then to No. 2 beakers 0.5 times of mass fraction of enol quality be 5% sodium periodate solution, in temperature be 95 DEG C, rotating speed be 500r/min under the conditions of, after Continuous heating stirring mixes 60min to get modified polyvinylalcohol liquid;It counts in parts by weight, by 20 parts of dopamine solutions, 20 portions of withered grass Bacillus bacterium solution, 8 parts of carbomers, 10 parts of property-modifying additives, 10 parts of aniline, 3 parts of urea, 20 parts of polyvinyl alcohol liquid, 5 portions of plants Essential oil, 30 parts of water are placed in batch mixer, and under the conditions of rotating speed is 500r/min, it is clear to get composite stainless steel to be stirred 60min Lotion.The carbomer is carbomer 734P.The plants essential oil is Rosemary Oil.
Comparative example:The stainless steel cleaner of Shanghai Chemical Co., Ltd. production.
1 to 6 gained stainless steel cleaner of example and comparative example product are subjected to performance detection, specific detection method is as follows:
The evaluation of cleaning performance:The method observed by the naked eye evaluates the cleaning situation of stainless steel surface.It is clear to observe stainless steel Wash the brightness of rear surface.
Corrosion mitigating effect is evaluated:Experiment evaluates corrosion inhibition rate using weight-loss method.Corrosion inhibition rate is calculated as follows:
Ƞ=(V-V’)/V×100%
Specific testing result is as shown in table 1:
Table 1:Performance detection table
Detection content Example 1 Example 2 Example 3 Example 4 Example 5 Example 6 Comparative example
Corrosion inhibition rate/% 93.2 88.0 85.4 87.1 86.3 87.6 82.5
The stainless steel brightness cleaned using 1 gained cleaning agent of example is best, the stainless steel brightness of comparative example product cleaning It is worst.
By testing result it is found that present invention gained composite stainless steel cleaning agent has excellent cleaning performance, and have long-acting Protection and corrosion inhibition.

Claims (7)

1. a kind of composite stainless steel cleaning agent, it is characterised in that:It is made of the raw material of following parts by weight:
10~20 parts of dopamine solution
10~20 parts of bacillus subtilis bacterium solution
5~8 parts of carbomer
8~10 parts of property-modifying additive
8~10 parts of aniline
2~3 parts of urea
10~20 parts of polyvinyl alcohol liquid
Phosphatidase 3~5 part
3~5 parts of plants essential oil
20~30 parts of water
The process for preparation of the stainless steel cleaner is:Each raw material is weighed by raw material composition, by dopamine solution, bacillus subtilis Bacterium bacterium solution, carbomer, property-modifying additive, aniline, urea, polyvinyl alcohol liquid, malic acid, phosphatide, plants essential oil and water stirring are mixed It closes to get composite stainless steel cleaning agent.
2. a kind of composite stainless steel cleaning agent according to claim 1, it is characterised in that:The bacillus subtilis bacterium solution is It is made of the raw material of following parts by weight:10~20 parts of bacillus subtilises, 8~10 parts of glycerine, 8~10 parts of glucose solutions, 20~30 parts of deionized waters.
3. a kind of composite stainless steel cleaning agent according to claim 1, it is characterised in that:The carbomer is carbomer Any one in 734P, carbomer 740P or carbomer 710P.
4. a kind of composite stainless steel cleaning agent according to claim 1, it is characterised in that:The preparation of the property-modifying additive Cheng Wei:It will(N- amidino groups)Dodecylacrylamide and polyethylene glycol phosphate in mass ratio 2:1~4:1 mixing, and be added poly- The ferrocene of 0.12~0.18 times of the paracide and polyethylene glycol phosphate quality of 0.2~0.4 times of ethylene glycol phosphate quality, Constant temperature is stirred to react, and is discharged to get property-modifying additive.
5. a kind of composite stainless steel cleaning agent according to claim 1, it is characterised in that:The preparation of the polyvinyl alcohol liquid Cheng Wei:By polyvinyl alcohol and water in mass ratio 1:50~1:100 mixing, after standing swelling, heating stirring mixes to get polyethylene Alcohol liquid.
6. a kind of composite stainless steel cleaning agent according to claim 1, it is characterised in that:The phosphatide is cholinphospholipide, second Any one in hydramine phosphatide, serinephosphatide or glycerophosphatide.
7. a kind of composite stainless steel cleaning agent according to claim 1, it is characterised in that:The plants essential oil is rosemary essence Any one in oil, Lavender, feverfew essential oil, camellia essential oil or Schisandra chinensis essential oil.
CN201810360136.1A 2018-04-20 2018-04-20 A kind of composite stainless steel cleaning agent Pending CN108315747A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109042638A (en) * 2018-08-08 2018-12-21 长沙昱旻信息科技有限公司 A kind of controlled release bacillus subtilis microbial agent

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102808191A (en) * 2012-06-08 2012-12-05 上海凯谷化工科技有限公司 Biological decarburizing cleaning agent
CN103865855A (en) * 2014-03-25 2014-06-18 南京工业大学 Bacillus subtilis strain and applications thereof
CN107841750A (en) * 2017-11-07 2018-03-27 常州禾吉纺织品有限公司 A kind of anti-rust metal detergent

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102808191A (en) * 2012-06-08 2012-12-05 上海凯谷化工科技有限公司 Biological decarburizing cleaning agent
CN103865855A (en) * 2014-03-25 2014-06-18 南京工业大学 Bacillus subtilis strain and applications thereof
CN107841750A (en) * 2017-11-07 2018-03-27 常州禾吉纺织品有限公司 A kind of anti-rust metal detergent

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109042638A (en) * 2018-08-08 2018-12-21 长沙昱旻信息科技有限公司 A kind of controlled release bacillus subtilis microbial agent

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Application publication date: 20180724