CN108308802A - With the necklace and preparation method thereof for improving insomnia function - Google Patents
With the necklace and preparation method thereof for improving insomnia function Download PDFInfo
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- CN108308802A CN108308802A CN201810126174.0A CN201810126174A CN108308802A CN 108308802 A CN108308802 A CN 108308802A CN 201810126174 A CN201810126174 A CN 201810126174A CN 108308802 A CN108308802 A CN 108308802A
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- 208000013738 Sleep Initiation and Maintenance disease Diseases 0.000 title claims abstract description 49
- 206010022437 insomnia Diseases 0.000 title claims abstract description 49
- 238000002360 preparation method Methods 0.000 title claims abstract description 36
- 229910000851 Alloy steel Inorganic materials 0.000 claims abstract description 5
- 238000004381 surface treatment Methods 0.000 claims abstract description 3
- 239000000843 powder Substances 0.000 claims description 115
- 239000006247 magnetic powder Substances 0.000 claims description 59
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 49
- 238000002156 mixing Methods 0.000 claims description 48
- 239000002002 slurry Substances 0.000 claims description 46
- 238000005245 sintering Methods 0.000 claims description 41
- SZVJSHCCFOBDDC-UHFFFAOYSA-N ferrosoferric oxide Chemical compound O=[Fe]O[Fe]O[Fe]=O SZVJSHCCFOBDDC-UHFFFAOYSA-N 0.000 claims description 39
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 38
- 239000000654 additive Substances 0.000 claims description 38
- 230000000996 additive effect Effects 0.000 claims description 38
- 229910001004 magnetic alloy Inorganic materials 0.000 claims description 34
- 239000000956 alloy Substances 0.000 claims description 33
- 229910045601 alloy Inorganic materials 0.000 claims description 33
- 239000000203 mixture Substances 0.000 claims description 31
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 claims description 30
- 229910000570 Cupronickel Inorganic materials 0.000 claims description 30
- 238000012216 screening Methods 0.000 claims description 24
- 229910052751 metal Inorganic materials 0.000 claims description 23
- 239000002184 metal Substances 0.000 claims description 23
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 23
- 229910052742 iron Inorganic materials 0.000 claims description 22
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 20
- 239000010949 copper Substances 0.000 claims description 20
- 229910052802 copper Inorganic materials 0.000 claims description 20
- 229910052759 nickel Inorganic materials 0.000 claims description 19
- 229940056319 ferrosoferric oxide Drugs 0.000 claims description 18
- 239000011159 matrix material Substances 0.000 claims description 17
- 229910000777 cunife Inorganic materials 0.000 claims description 15
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 14
- GOECOOJIPSGIIV-UHFFFAOYSA-N copper iron nickel Chemical compound [Fe].[Ni].[Cu] GOECOOJIPSGIIV-UHFFFAOYSA-N 0.000 claims description 14
- 239000012298 atmosphere Substances 0.000 claims description 12
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 12
- 239000008367 deionised water Substances 0.000 claims description 12
- 229910021641 deionized water Inorganic materials 0.000 claims description 12
- 239000003595 mist Substances 0.000 claims description 12
- IJGRMHOSHXDMSA-UHFFFAOYSA-N nitrogen Substances N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 12
- 229910052757 nitrogen Inorganic materials 0.000 claims description 12
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 claims description 12
- 230000001681 protective effect Effects 0.000 claims description 12
- 238000001238 wet grinding Methods 0.000 claims description 12
- 239000011324 bead Substances 0.000 claims description 11
- 239000000919 ceramic Substances 0.000 claims description 11
- 238000012545 processing Methods 0.000 claims description 11
- 239000004576 sand Substances 0.000 claims description 11
- NLZUEZXRPGMBCV-UHFFFAOYSA-N Butylhydroxytoluene Chemical compound CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 NLZUEZXRPGMBCV-UHFFFAOYSA-N 0.000 claims description 10
- 239000002994 raw material Substances 0.000 claims description 10
- 238000005422 blasting Methods 0.000 claims description 9
- 235000010354 butylated hydroxytoluene Nutrition 0.000 claims description 9
- 239000010941 cobalt Substances 0.000 claims description 8
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- ZHDZZQCPMPRKFO-UHFFFAOYSA-N [Fe].[Ni].[Cu].[Co] Chemical compound [Fe].[Ni].[Cu].[Co] ZHDZZQCPMPRKFO-UHFFFAOYSA-N 0.000 claims 1
- 230000005291 magnetic effect Effects 0.000 abstract description 37
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- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 abstract description 7
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- 208000030208 low-grade fever Diseases 0.000 abstract 1
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 52
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 30
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- 238000004458 analytical method Methods 0.000 description 17
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- TZBAVQKIEKDGFH-UHFFFAOYSA-N n-[2-(diethylamino)ethyl]-1-benzothiophene-2-carboxamide;hydrochloride Chemical compound [Cl-].C1=CC=C2SC(C(=O)NCC[NH+](CC)CC)=CC2=C1 TZBAVQKIEKDGFH-UHFFFAOYSA-N 0.000 description 8
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 7
- -1 phenthazine Chemical compound 0.000 description 7
- 238000005488 sandblasting Methods 0.000 description 7
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- 239000010935 stainless steel Substances 0.000 description 7
- 201000010099 disease Diseases 0.000 description 6
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 6
- 229910052737 gold Inorganic materials 0.000 description 6
- 239000010931 gold Substances 0.000 description 6
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 5
- 238000001467 acupuncture Methods 0.000 description 5
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 5
- 239000003350 kerosene Substances 0.000 description 5
- 239000001301 oxygen Substances 0.000 description 5
- 229910052760 oxygen Inorganic materials 0.000 description 5
- 238000003756 stirring Methods 0.000 description 5
- 239000003814 drug Substances 0.000 description 4
- 230000005389 magnetism Effects 0.000 description 4
- 238000011160 research Methods 0.000 description 4
- 239000010963 304 stainless steel Substances 0.000 description 3
- VSAWBBYYMBQKIK-UHFFFAOYSA-N 4-[[3,5-bis[(3,5-ditert-butyl-4-hydroxyphenyl)methyl]-2,4,6-trimethylphenyl]methyl]-2,6-ditert-butylphenol Chemical compound CC1=C(CC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)C(C)=C(CC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)C(C)=C1CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 VSAWBBYYMBQKIK-UHFFFAOYSA-N 0.000 description 3
- 229910000589 SAE 304 stainless steel Inorganic materials 0.000 description 3
- 238000004873 anchoring Methods 0.000 description 3
- 208000002173 dizziness Diseases 0.000 description 3
- 238000010998 test method Methods 0.000 description 3
- CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 2
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- 208000006820 Arthralgia Diseases 0.000 description 1
- 206010012289 Dementia Diseases 0.000 description 1
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 1
- 206010020772 Hypertension Diseases 0.000 description 1
- 206010028980 Neoplasm Diseases 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- 235000008331 Pinus X rigitaeda Nutrition 0.000 description 1
- 235000011613 Pinus brutia Nutrition 0.000 description 1
- 241000018646 Pinus brutia Species 0.000 description 1
- 229920001030 Polyethylene Glycol 4000 Polymers 0.000 description 1
- 238000007792 addition Methods 0.000 description 1
- 230000001754 anti-pyretic effect Effects 0.000 description 1
- 239000002221 antipyretic Substances 0.000 description 1
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- 239000006210 lotion Substances 0.000 description 1
- 238000004020 luminiscence type Methods 0.000 description 1
- 230000004199 lung function Effects 0.000 description 1
- 239000000395 magnesium oxide Substances 0.000 description 1
- 230000005426 magnetic field effect Effects 0.000 description 1
- 238000002653 magnetic therapy Methods 0.000 description 1
- 239000002398 materia medica Substances 0.000 description 1
- 239000013528 metallic particle Substances 0.000 description 1
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- 239000002048 multi walled nanotube Substances 0.000 description 1
- 210000003205 muscle Anatomy 0.000 description 1
- 239000010956 nickel silver Substances 0.000 description 1
- MOFOBJHOKRNACT-UHFFFAOYSA-N nickel silver Chemical compound [Ni].[Ag] MOFOBJHOKRNACT-UHFFFAOYSA-N 0.000 description 1
- 231100000862 numbness Toxicity 0.000 description 1
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Classifications
-
- A—HUMAN NECESSITIES
- A44—HABERDASHERY; JEWELLERY
- A44C—PERSONAL ADORNMENTS, e.g. JEWELLERY; COINS
- A44C11/00—Watch chains; Ornamental chains
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61N—ELECTROTHERAPY; MAGNETOTHERAPY; RADIATION THERAPY; ULTRASOUND THERAPY
- A61N2/00—Magnetotherapy
- A61N2/004—Magnetotherapy specially adapted for a specific therapy
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61N—ELECTROTHERAPY; MAGNETOTHERAPY; RADIATION THERAPY; ULTRASOUND THERAPY
- A61N2/00—Magnetotherapy
- A61N2/06—Magnetotherapy using magnetic fields produced by permanent magnets
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C9/00—Alloys based on copper
- C22C9/06—Alloys based on copper with nickel or cobalt as the next major constituent
Landscapes
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Biomedical Technology (AREA)
- Nuclear Medicine, Radiotherapy & Molecular Imaging (AREA)
- Radiology & Medical Imaging (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Chemical & Material Sciences (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Powder Metallurgy (AREA)
- Adornments (AREA)
Abstract
The invention discloses a kind of necklace and preparation method thereof for having and improving insomnia function, the preparation method with the necklace for improving insomnia function includes carrying out surface treatment step to steel alloy necklace.The present invention's has the necklace for improving insomnia function, can generate a large amount of quantum, realizes the health-care efficacy to human body, by magnetic fields, generates low-grade fever effect, can improve cerebral insufficiency, headache, insomnia；It relieves fatigue, improve the tingle distending pain of cervical vertebra；Resist radiation；Adjust blood glucose, blood fat, blood pressure；Beauty；Lifter motion function；Improve inferior health, pressure of releiving；Microcirculation is got through, Parkinson is adjusted.
Description
Technical field
The invention belongs to health treatment fields, and in particular to a kind of to have the necklace for improving insomnia function and its preparation side
Method.
Background technology
Human survival on earth, all the time all by earth magnetic field effect with influence, earth magnetism is the same as empty gas and water, sun
Light is equally that the mankind depend on for existence one of indispensable element.People can be correspondingly formed human body itself under magnetic fields
Magnetic field, the human body heart, lung, brain, muscle and nerve etc. have different degrees of micro- magnetic field.Applying a magnetic field acts on human body diseases and controls
The method for the treatment of probably already exists at all times magnetotherapy, this method, and Ancient Times in China cures the disease with regard to useful loadstone, the note of diseases prevention
It carries, its principle is magnet to be acted on human acupoint to adjust meridian point, such as Shen Nongshi《Sheng Nong's herbal classic》With regard to note
It carries：" magnetite cures mainly solid numbness, rheumatism, oncotic arthralgia of limbs "；The famous physician's Li Shizhen (1518-1593 A.D.) of the Ming Dynasty is written at him《Compendium of Materia Medica》In
Magnetite is classified as one of external used medicine, and records the function of magnetic therapy " dispersing wind and cold, gets round by bribery and subsides a swelling bitterly at strong moral integrity ".Modern age, such as
Biological magnetic medicine this frontier science are produced in the first time world magnetic biomedicine meeting held in 1961, it is biology
A new disciplines being combined with magnetics refer to the subject with Modern Physics means research biological magnetic field phenomenon and its application,
The connecting each other of research biological phenomena and changing of magnetism or magnetic field, the rule that interacts and its application.
In recent years, daily necessities of the magnetic treatment health care necklace as a kind of health care and decoration, is increasingly closed by consumer
It notes and likes.Magnetic necklace is more common magnetotherapy appliance, it not only has certain health-care effect, but also beautiful, has dress
Adorn function.Magnetic health necklace can be sent out the magnetic line of force by its top permanent magnet and adjust nerve and can promote body physiological function just
Normalizing, to reach treatment disease effect.Magnetic field is uniform-distribution on necklace, and since necklace is worn on neck so that
Magnetic health necklace has an impact human body by skin on close contact neck.People neck and near, there is traditional Chinese medicine
The human acupoints such as upper described big vertebra, wind pond, Tiantu, Renying, Taotao, Jianjing, Dingchuan, sleeping, and Chinese medicine medical research is found,
There are substantial connection, health-care effect of the magnetic health necklace to human body in acupuncture point on human body with certain internal organs functions or systemic physiological function
It is played by influencing acupuncture point：As Anmian point can be promoted sleep, alleviation dizziness of having a headache, dizziness, the heart by magnetic fields
Throb with fear, demented effect；The magnetic line of force acts on wind pond acupuncture point, can play to people have dispelling wind is antipyretic, cure mainly headache, dizziness, high blood
The effect of the diseases such as pressure；Point cv 22 is had facilitaing lung regulating the qi flowing in the channels function, mainly curing bronchial asthma, bronchitis disease by magnetic line of force effect
Deng；Big vertebra and Taotao acupuncture point can have been made one cephalocathartic by the magnetic line of force effect of necklace and allay excitement and calm；Dingchuan acupuncture point is by necklace
Upper magnetic fields have the diseases such as improvement lung functions and treatment bronchitis, bronchial asthma；Simultaneously under magnetic fields, it can increase
The life cycle for adding each cell, achievees the effect that beautifying face and moistering lotion.It promotes blood circulation, changes in addition, magnetic field can also play
Kind microcirculating state and other effects.
Currently, magnetic treatment health care necklace has two in the market：First, the processing of magnetic treatment health care necklace is crude, necklace
On magnetic field intensity deviate from optimum magnetic field；Second is that the magnetic fields range of magnetic treatment health care necklace is smaller, health-care effect is not achieved.
Invention content
In view of the above-mentioned deficiencies in the prior art, the present invention provides with the necklace and its system for improving insomnia function
Preparation Method.
A kind of preparation method with the necklace for improving insomnia function, includes the following steps：Surface is carried out to necklace matrix
The material of processing, the preferably described necklace matrix is steel alloy.
The steel alloy is one in 304 stainless steels, 316 stainless steels, 316L stainless steels, 301 stainless steels, 302 stainless steels
Kind.
The preparation method for having the necklace for improving insomnia function, surface treatment include the following steps：
I, oil removing grease removal, it is dry；
II, carries out blasting treatment using blast media to necklace matrix surface, then magnetic powder is sprayed on necklace matrix.
The blast media is one or more in white fused alumina, bead, ceramic sand
The magnetic powder is one kind in white magnetic powder, ferroso-ferric oxide, cunife magnet alloy, cupro-nickel iron Co permanent magnetic alloy powder
Or it is a variety of.
Preferably, the blast media be white fused alumina, bead, ceramic sand mixture, wherein white fused alumina, bead,
The mass ratio of ceramic sand is (1-6):(1-6):(1-6).
Preferably, the magnetic powder is the mixture of white magnetic powder, ferroso-ferric oxide, cunife magnet alloy powder, wherein white magnetic
Powder, ferroso-ferric oxide, cunife magnet alloy powder mass ratio be (1-6):(1-6):(1-6).
It is highly preferred that the magnetic powder is the mixture of white magnetic powder, ferroso-ferric oxide, cupro-nickel iron Co permanent magnetic alloy powder, wherein
White magnetic powder, ferroso-ferric oxide, cupro-nickel iron Co permanent magnetic alloy powder mass ratio be (1-6):(1-6):(1-6).
The copper-nickel iron permanent-magnet alloy is prepared by the raw material of following weight parts：40-80 parts of copper, 13-40 parts of nickel, iron 5-
8 parts, 0.2-1.5 parts of additive.
The copper-nickel iron Co permanent magnetic alloy is prepared by the raw material of following weight parts：40-80 parts of copper, 13-40 parts of nickel, iron
5-8 parts, 3-7 parts of cobalt, 0.2-1.5 parts of additive.
The preparation method of the copper-nickel iron permanent-magnet alloy is：
I, weighs each raw material component according to parts by weight, and raw metal is mixed to get mixed metal powder；Mixing gold is added
Belong to the deionized water of powder quality 25%-50%, gained mixture is placed in ball-grinding machine, with 150-230r/min wet-millings 8-
After 12h, slurry A is obtained；
Additive is added into above-mentioned slurry A in II, then places into wet mixing 2-6h in ball mill, gained slurry B；
III, carries out mist projection granulating processing to above-mentioned slurry B, and the rotating speed of atomizer is 6000-8000r/min, inlet temperature
220-260 DEG C, 80-100 DEG C of outlet temperature, feeding revolution speed is 600-1000r/min, obtains prilling powder after screening；
The above-mentioned prilling powders of IV, are placed in Fast Sintering in sintering furnace after ungrease treatment, feed rate 3-8kg/h,
Sintering temperature is 1000-1400 DEG C, and sintering time 0.1s-5s, protective atmosphere is nitrogen, finally obtains cupro-nickel after screening
Iron permanent-magnet alloy or cupro-nickel iron Co permanent magnetic alloy powder.
The production method of the copper-nickel iron Co permanent magnetic alloy powder is：
I, weighs each raw material component according to parts by weight, and raw metal is mixed to get mixed metal powder；Mixing gold is added
Belong to the deionized water of powder quality 25%-50%, gained mixture is placed in ball-grinding machine, with 150-230r/min wet-millings 8-
After 12h, slurry is obtained；
II, carries out mist projection granulating processing to above-mentioned slurry, and the rotating speed of atomizer is 6000-8000r/min, inlet temperature
220-260 DEG C, 80-100 DEG C of outlet temperature, feeding revolution speed is 600-1000r/min, obtains prilling powder after screening；
The above-mentioned prilling powders of III, are placed in Fast Sintering in sintering furnace after ungrease treatment, feed rate 3-8kg/h,
Sintering temperature is 1000-1400 DEG C, and sintering time 0.1s-5s, protective atmosphere is nitrogen, finally obtains cupro-nickel after screening
Iron permanent-magnet alloy or cupro-nickel iron Co permanent magnetic alloy powder.
Preferably, the preparation method of the copper-nickel iron Co permanent magnetic alloy powder is：
I, weighs each raw material component according to parts by weight, and raw metal is mixed to get mixed metal powder；Mixing gold is added
Belong to the deionized water of powder quality 25%-50%, gained mixture is placed in ball-grinding machine, with 150-230r/min wet-millings 8-
After 12h, slurry A is obtained；
Additive is added into above-mentioned slurry A in II, then places into wet mixing 2-6h in ball mill, gained slurry B；
III, carries out mist projection granulating processing to above-mentioned slurry B, and the rotating speed of atomizer is 6000-8000r/min, inlet temperature
220-260 DEG C, 80-100 DEG C of outlet temperature, feeding revolution speed is 600-1000r/min, obtains prilling powder after screening；
The above-mentioned prilling powders of IV, are placed in Fast Sintering in sintering furnace after ungrease treatment, feed rate 3-8kg/h,
Sintering temperature is 1000-1400 DEG C, and sintering time 0.1s-5s, protective atmosphere is nitrogen, finally obtains cupro-nickel after screening
Iron permanent-magnet alloy or cupro-nickel iron Co permanent magnetic alloy powder.
The additive presses (60-80) by adhesive and antioxidant:The mass ratio of (0.5-1) mixes.
The binder is one or more in polyethylene glycol, polymethyl methacrylate, polyvinylpyrrolidone.
The antioxidant be phenthazine, 2,6 di tert butyl 4 methyl phenol, 1,3,5- trimethyls -2,4,6- three (3,
5- di-tert-butyl-4-hydroxyl benzyls) it is one or more in benzene.
Preferably, the antioxidant be phenthazine, 2,6- di-tert-butyl-4-methy phenols, 1,3,5- trimethyls -2,4,
The mixture of 6- tri- (3,5- di-tert-butyl-4-hydroxyl benzyl) benzene, the phenthazine, 2,6- di-t-butyl -4- methylbenzenes
Phenol, 1,3,5- trimethyls -2,4,6- three (3,5- di-tert-butyl-4-hydroxyl benzyls) benzene mass ratio be (1-6):(1-6):(1-
6)。
Quantum dot is the substance with crystal structure, and size is only several nanometers, and by about hundreds of to few thousand atoms
Composition.Since the size of quantum dot is extremely small, thus it will produce quantum confined effect.Quantum confined effect refers to, when object
Size reach nano-scale or it is following when, then the band gap of the object can become larger.Therefore, when than the band gap have more high energy
When the light of the wavelength of amount is incident in quantum dot, quantum dot can absorb the energy of the light, be activated and make to the energy level of quantum dot
Be in excitation state, then emit the light of specific wavelength, the energy level of last quantum dot drops to ground state.Transmitting light wavelength take rhymed formula in
Energy corresponding with the band gap.In general, the particle of quantum dot is smaller, then the wavelength for emitting light is shorter, and the grain of quantum dot
Son is bigger, then the wavelength for emitting light is longer.These are the unique electricity distinguished with existing semi-conducting material and optical
Matter.Therefore, the characteristics of luminescence of desired quantum dot is realized by controlling quantum dot size and composition etc..Quantum dot of the present invention
Can have near-infrared fluorescent/photoacoustic imaging and photo-thermal/optical dynamic therapy function simultaneously, show good photothermal conversion energy
Power, and generation singlet oxygen can be induced, realize that photo-thermal/light power synergistic treatment to tumour, quantum dot are prepared conveniently, no
It is related to that toxic element, crystal structure are perfect, can ensures stability and the safety of material.
By adopting the above-described technical solution, the present invention has the advantages that compared with prior art：The present invention adopts
With the magnetic powder processing steel alloy necklace surface of rational proportion, gained has the necklace for improving insomnia function, the distribution of surface magnetic powder
More uniformly, close, this magnetic necklace is worn over neck, by magnetic fields, improves microcirculation, achievees the effect that health care.The present invention
It can improve cerebral insufficiency, headache, insomnia with the necklace for improving insomnia function；It relieves fatigue, improve the tingle distending pain of cervical vertebra；
Resist radiation；Adjust blood glucose, blood fat, blood pressure；Beauty；Lifter motion function；Improve inferior health, pressure of releiving；Microcirculation is got through,
Adjust Parkinson.
Specific implementation mode
The foregoing invention content of the present invention is described in further detail With reference to embodiment, in the present invention
If not refering in particular to, all devices and raw material is commercially available or the industry is common, the method in following embodiments, such as nothing
It illustrates, is this field conventional method.
Each raw material and equipment introduction in embodiment：
Necklace matrix, the 304 stainless steels routinely necklace preparation process provided by Rui Hui stainless steels Co., Ltd of Foshan City
Processing obtains.
White fused alumina, grain size are 80 mesh, and model GC is purchased from big two factory of ridge grinding wheel of Yancheng City.
Bead, grain size are 220 mesh, and model GB 60# are purchased from Changzhou Pei Yuan abrasive materials Co., Ltd.
Ceramic sand, grain size are 120 mesh, and model GB205 is purchased from Dongguan City great river grinding-material Co., Ltd.
White magnetic powder, a kind of silvery white powder are synthesized with aluminium oxide or magnesia by black particle, model HK-3, grain
400 mesh of diameter is purchased from Taizhou Peng Bo gauge checks Instrument Ltd..
Ferroso-ferric oxide, No. CAS：12227-89-3,200 mesh of grain size are purchased from Lingshou County Jian Hui mineral products processings factory.
Copper, 200 mesh of grain size, model XJ-Cu01 are purchased from Anhui Xin Jiatong industry Co., Ltd.
Nickel, 300 mesh of grain size, model FND-2 are purchased from Nangong City Zhong Zhou alloy materials Co., Ltd.
Cobalt, 300 mesh of grain size, the trade mark：Co92AA is purchased from Nangong City Plain alloy material Co., Ltd.
Macrogol 4000, No. CAS：25322-68-3, model PEG-4000, molecular weight 3600-4400 are purchased from river
The Hai'an Su Sheng petrochemical plant.
Phenthazine, No. CAS：92-84-2, technical grade are purchased from ten thousand abundant industrial chemicals Co., Ltd of Henan.
2,6- di-tert-butyl-4-methy phenols, No. CAS：It is limited to open magnificent chemical industry purchased from Guangzhou for 128-37-0, technical grade
Company.
1,3,5- trimethyl -2,4,6- tri- (3,5- di-tert-butyl-4-hydroxyl benzyl) benzene, No. CAS：1709-70-2, model
For antioxidant 330, it is purchased from Shanghai Ju Qi plastic cement Technology Co., Ltd..
The model SYH-5 of powder mixer, purchased from Changzhou times at drying equipment Engineering Co., Ltd.
Abrasive blast equipment is the manual sand-blasting machine of GY-9060A types, is purchased from Guang Yao abrasive blast equipments Science and Technology Ltd. of Shenzhen.
Spraying equipment is JP5000 type supersonic flame systems, is purchased from Praxair companies of the U.S..
Ball mill is QM-2SP60 type vertical-type planetary formula ball mills, is purchased from Shanghai sage section experimental instruments and equipment limited.
Spray drying device is LPG200-2000 type centrifugal spray dryers, limited purchased from Hangzhou Qianjiang drying equipment
Company.
Analysis sieve model WZ-300, is purchased from Xinxiang Wanda Machinery Co., Ltd..
Degreasing equipment is FPJ-430 type debinding furnaces, is purchased from Hefei Fei Sheluo heat energy technologies Co., Ltd.
Sintering furnace is ZGLL1400-60-VT type vertical tubular furnaces, purchased from Shanghai celestial being as instrument and meter Co., Ltd.
Embodiment 1
The preparation method for having the necklace for improving insomnia function, includes the following steps：
The sodium hydroxide alkali wash water of 5wt% is heated to 70 DEG C by I, and sodium hydroxide alkali wash water then is added in necklace matrix
In, 4min is impregnated, then clean substrate surface with acetone, then with alcohol wipe, is dried up；
It is 1 that mass ratio is added into powder mixer by II,:1:1 white fused alumina, bead, ceramic sand, at 30 DEG C with
The rotating speed of 30r/min stirs 2.5h, and gained blast media carries out blasting treatment to stainless steel substrate, spray gun pressure 0.6MPa,
Sandblasting angle is 45 °, nozzle distance 100mm, blast time 30s, then using magnetic powder as dusty spray, to necklace base material table
Face carries out spray treatment, spray distance 380mm, oxygen flow 15L/h, kerosene oil flow 23L/h, and powder feeding rate 76g/min works as spray
It applies when thickness is 0.5mm and stops, obtaining with the necklace for improving insomnia function.
The magnetic powder is the mixture of white magnetic powder, ferroso-ferric oxide, cupro-nickel iron Co permanent magnetic alloy powder, the white magnetic powder, four
The mass ratio 1 of Fe 3 O, cupro-nickel iron Co permanent magnetic alloy powder:1:1.
The production method of the copper-nickel iron Co permanent magnetic alloy powder is：
I, presses 50:40:5:5:1 mass ratio weighs copper, nickel, iron, cobalt and additive, by copper, nickel, iron, cobalt metal powder
Mixing, obtains mixed metal powder；The deionized water of mixed metal powder quality 40% is added, mixing is placed on ball mill, then
Be put into the YG8 sintered carbide balls of a diameter of 20mm, at 25 DEG C with 200r/min wet-millings 8h after, obtain slurry A；
Additive is added into above-mentioned slurry A in II, is placed in ball mill, places into the YG8 hard alloy of a diameter of 20mm
Ball obtains slurry B with 200r/min wet mixing 3h at 25 DEG C；
Above-mentioned slurry B is placed in spray drying device and carries out mist projection granulating by III, and the rotating speed of atomizer is 6000r/min,
220 DEG C of inlet temperature, 100 DEG C of outlet temperature, feeding revolution speed are 840r/min, and the screening through analysis sieve obtains 80 purposes and makes
Grain powder；
Above-mentioned prilling powder is placed in 600 DEG C of degreasing equipment by IV, and degreasing 6h is subsequently placed into sintering furnace and quickly burns
Knot, feed rate 6kg/h, sintering temperature are 1400 DEG C, and sintering time 3s, protective atmosphere is nitrogen, are most sieved afterwards through analysis
Screening, obtain the cupro-nickel iron Co permanent magnetic alloy powder of 180 mesh.
The preparation method of the additive is：By Macrogol 4000, phenthazine, 2,6 di tert butyl 4 methyl phenol,
1,3,5- trimethyls -2,4,6- three (3,5- di-tert-butyl-4-hydroxyl benzyls) benzene presses 75:0.2:0.2:0.2 mass ratio mixing,
It is subsequently added into solvent acetone, the mass volume ratio for obtaining mixture B, the mixture B and acetone is 1：7 (g/ml), at 50 DEG C
Under with 1000r/min mixing 2h, evaporate acetone at 85 DEG C, when solution in it is powdered when stop, obtaining the additive.
Embodiment 2
The preparation method for having the necklace for improving insomnia function, includes the following steps：
The sodium hydroxide alkali wash water of 5wt% is heated to 70 DEG C by I, and sodium hydroxide alkali wash water then is added in necklace matrix
In, 4min is impregnated, then clean substrate surface with acetone, then with alcohol wipe, is dried up；
It is 1 that mass ratio is added into powder mixer by II,:1 white fused alumina, bead are turned at 30 DEG C with 30r/min
Speed stirring 2.5h, gained blast media carry out blasting treatment, spray gun pressure 0.6MPa to stainless steel substrate, and sandblasting angle is
45 °, nozzle distance 100mm, blast time 30s, then using magnetic powder as dusty spray, necklace substrate surface is sprayed
Processing, spray distance 380mm, oxygen flow 15L/h, kerosene oil flow 23L/h, powder feeding rate 76g/min, when coating thickness is
Stop when 0.5mm, obtains with the necklace for improving insomnia function.
The magnetic powder is the mixture of white magnetic powder, ferroso-ferric oxide, cupro-nickel iron Co permanent magnetic alloy powder, the white magnetic powder, four
The mass ratio 1 of Fe 3 O, cupro-nickel iron Co permanent magnetic alloy powder:1:1.
The production method of the copper-nickel iron Co permanent magnetic alloy powder is：
I, presses 50:40:5:5:1 mass ratio weighs copper, nickel, iron, cobalt and additive, by copper, nickel, iron, cobalt metal powder
Mixing, obtains mixed metal powder；The deionized water of mixed metal powder quality 40% is added, mixing is placed on ball mill, then
Be put into the YG8 sintered carbide balls of a diameter of 20mm, at 25 DEG C with 200r/min wet-millings 8h after, obtain slurry A；
The additive of slurry A mass 0.5% is added into above-mentioned slurry A by II, is placed in ball mill, places into a diameter of
The YG8 sintered carbide balls of 20mm obtain slurry B with 200r/min wet mixing 3h at 25 DEG C；
Above-mentioned slurry B is placed in spray drying device and carries out mist projection granulating by III, and the rotating speed of atomizer is 6000r/min,
220 DEG C of inlet temperature, 100 DEG C of outlet temperature, feeding revolution speed are 840r/min, and the screening through analysis sieve obtains 80 purposes and makes
Grain powder；
Above-mentioned prilling powder is placed in 600 DEG C of degreasing equipment by IV, and degreasing 6h is subsequently placed into sintering furnace and quickly burns
Knot, feed rate 6kg/h, sintering temperature are 1400 DEG C, and sintering time 3s, protective atmosphere is nitrogen, are most sieved afterwards through analysis
Screening, obtain the cupro-nickel iron Co permanent magnetic alloy powder of 180 mesh.
The preparation method of the additive is：By Macrogol 4000, phenthazine, 2,6 di tert butyl 4 methyl phenol,
1,3,5- trimethyls -2,4,6- three (3,5- di-tert-butyl-4-hydroxyl benzyls) benzene presses 75:0.2:0.2:0.2 mass ratio mixing,
It is subsequently added into solvent acetone, the mass volume ratio for obtaining mixture B, the mixture B and acetone is 1：7 (g/ml), at 50 DEG C
Under with 1000r/min mixing 2h, evaporate acetone at 85 DEG C, when solution in it is powdered when stop, obtaining the additive.
Embodiment 3
The preparation method for having the necklace for improving insomnia function, includes the following steps：
The sodium hydroxide alkali wash water of 5wt% is heated to 70 DEG C by I, and sodium hydroxide alkali wash water then is added in necklace matrix
In, 4min is impregnated, then clean substrate surface with acetone, then with alcohol wipe, is dried up；
It is 1 that mass ratio is added into powder mixer by II,:1 bead, ceramic sand are turned at 30 DEG C with 30r/min
Speed stirring 2.5h, gained blast media carry out blasting treatment, spray gun pressure 0.6MPa to stainless steel substrate, and sandblasting angle is
45 °, nozzle distance 100mm, blast time 30s, then using magnetic powder as dusty spray, necklace substrate surface is sprayed
Processing, spray distance 380mm, oxygen flow 15L/h, kerosene oil flow 23L/h, powder feeding rate 76g/min, when coating thickness is
Stop when 0.5mm, obtains with the necklace for improving insomnia function.
The magnetic powder is the mixture of white magnetic powder, ferroso-ferric oxide, cupro-nickel iron Co permanent magnetic alloy powder, the white magnetic powder, four
The mass ratio 1 of Fe 3 O, cupro-nickel iron Co permanent magnetic alloy powder:1:1.
The production method of the copper-nickel iron Co permanent magnetic alloy powder is：
I, presses 50:40:5:5:1 mass ratio weighs copper, nickel, iron, cobalt and additive, by copper, nickel, iron, cobalt metal powder
Mixing, obtains mixed metal powder；The deionized water of mixed metal powder quality 40% is added, mixing is placed on ball mill, then
Be put into the YG8 sintered carbide balls of a diameter of 20mm, at 25 DEG C with 200r/min wet-millings 8h after, obtain slurry A；
Additive is added into above-mentioned slurry A in II, is placed in ball mill, places into the YG8 hard alloy of a diameter of 20mm
Ball obtains slurry B with 200r/min wet mixing 3h at 25 DEG C；
Above-mentioned slurry B is placed in spray drying device and carries out mist projection granulating by III, and the rotating speed of atomizer is 6000r/min,
220 DEG C of inlet temperature, 100 DEG C of outlet temperature, feeding revolution speed are 840r/min, and the screening through analysis sieve obtains 80 purposes and makes
Grain powder；
Above-mentioned prilling powder is placed in 600 DEG C of degreasing equipment by IV, and degreasing 6h is subsequently placed into sintering furnace and quickly burns
Knot, feed rate 6kg/h, sintering temperature are 1400 DEG C, and sintering time 3s, protective atmosphere is nitrogen, are most sieved afterwards through analysis
Screening, obtain the cupro-nickel iron Co permanent magnetic alloy powder of 180 mesh.
The preparation method of the additive is：By Macrogol 4000, phenthazine, 2,6 di tert butyl 4 methyl phenol,
1,3,5- trimethyls -2,4,6- three (3,5- di-tert-butyl-4-hydroxyl benzyls) benzene presses 75:0.2:0.2:0.2 mass ratio mixing,
It is subsequently added into solvent acetone, the mass volume ratio for obtaining mixture B, the mixture B and acetone is 1：7 (g/ml), at 50 DEG C
Under with 1000r/min mixing 2h, evaporate acetone at 85 DEG C, when solution in it is powdered when stop, obtaining the additive.
Embodiment 4
The preparation method for having the necklace for improving insomnia function, includes the following steps：
The sodium hydroxide alkali wash water of 5wt% is heated to 70 DEG C by I, and sodium hydroxide alkali wash water then is added in necklace matrix
In, 4min is impregnated, then clean substrate surface with acetone, then with alcohol wipe, is dried up；
It is 1 that mass ratio is added into powder mixer by II,:1 white fused alumina, ceramic sand are turned at 30 DEG C with 30r/min
Speed stirring 2.5h, gained blast media carry out blasting treatment, spray gun pressure 0.6MPa to stainless steel substrate, and sandblasting angle is
45 °, nozzle distance 100mm, blast time 30s, then using magnetic powder as dusty spray, necklace substrate surface is sprayed
Processing, spray distance 380mm, oxygen flow 15L/h, kerosene oil flow 23L/h, powder feeding rate 76g/min, when coating thickness is
Stop when 0.5mm, obtains with the necklace for improving insomnia function.
The magnetic powder is the mixture of white magnetic powder, ferroso-ferric oxide, cupro-nickel iron Co permanent magnetic alloy powder, the white magnetic powder, four
The mass ratio 1 of Fe 3 O, cupro-nickel iron Co permanent magnetic alloy powder:1:1.
The production method of the copper-nickel iron Co permanent magnetic alloy powder is：
I, presses 50:40:5:5:1 mass ratio weighs copper, nickel, iron, cobalt and additive, by copper, nickel, iron, cobalt metal powder
Mixing, obtains mixed metal powder；The deionized water of mixed metal powder quality 40% is added, mixing is placed on ball mill, then
Be put into the YG8 sintered carbide balls of a diameter of 20mm, at 25 DEG C with 200r/min wet-millings 8h after, obtain slurry A；
Additive is added into above-mentioned slurry A in II, is placed in ball mill, places into the YG8 hard alloy of a diameter of 20mm
Ball obtains slurry B with 200r/min wet mixing 3h at 25 DEG C；
Above-mentioned slurry B is placed in spray drying device and carries out mist projection granulating by III, and the rotating speed of atomizer is 6000r/min,
220 DEG C of inlet temperature, 100 DEG C of outlet temperature, feeding revolution speed are 840r/min, and the screening through analysis sieve obtains 80 purposes and makes
Grain powder；
Above-mentioned prilling powder is placed in 600 DEG C of degreasing equipment by IV, and degreasing 6h is subsequently placed into sintering furnace and quickly burns
Knot, feed rate 6kg/h, sintering temperature are 1400 DEG C, and sintering time 3s, protective atmosphere is nitrogen, are most sieved afterwards through analysis
Screening, obtain the cupro-nickel iron Co permanent magnetic alloy powder of 180 mesh.
The preparation method of the additive is：By Macrogol 4000, phenthazine, 2,6 di tert butyl 4 methyl phenol,
1,3,5- trimethyls -2,4,6- three (3,5- di-tert-butyl-4-hydroxyl benzyls) benzene presses 75:0.2:0.2:0.2 mass ratio mixing,
It is subsequently added into solvent acetone, the mass volume ratio for obtaining mixture B, the mixture B and acetone is 1：7 (g/ml), at 50 DEG C
Under with 1000r/min mixing 2h, evaporate acetone at 85 DEG C, when solution in it is powdered when stop, obtaining the additive.
Embodiment 5
It is substantially the same manner as Example 1, it differs only in：The magnetic powder is the mixing of white magnetic powder, ferroferric oxide magnetic powder
Object, the white magnetic powder, ferroso-ferric oxide mass ratio 1:1.
Embodiment 6
It is substantially the same manner as Example 1, it differs only in：The magnetic powder is ferroso-ferric oxide, cunife magnet alloy powder
Mixture, the ferroso-ferric oxide, cunife magnet alloy powder mass ratio 1:1.
The production method of the copper-nickel iron permanent magnet alloy powder is：
Copper, nickel, iron and additive are pressed 50 by I,:40:5:Copper, nickel, iron are mixed to get mixing gold by 1 mass ratio mixing
Belong to powder；The deionized water of mixed metal powder quality 40% is added, mixing is placed on ball mill, places into a diameter of 20mm's
YG8 sintered carbide balls, at 25 DEG C with 200r/min wet-millings 8h after, obtain slurry A；
Additive is added into above-mentioned slurry A in II, is placed in ball mill, places into the YG8 hard alloy of a diameter of 20mm
Ball obtains slurry B with 200r/min wet mixing 3h at 25 DEG C；
Above-mentioned slurry B is placed in spray drying device and carries out mist projection granulating by III, and the rotating speed of atomizer is 6000r/min,
220 DEG C of inlet temperature, 100 DEG C of outlet temperature, feeding revolution speed are 840r/min, and the screening through analysis sieve obtains 80 purposes and makes
Grain powder；
Above-mentioned prilling powder is placed in 600 DEG C of degreasing equipment by IV, and degreasing 6h is subsequently placed into sintering furnace and quickly burns
Knot, feed rate 6kg/h, sintering temperature are 1400 DEG C, and sintering time 3s, protective atmosphere is nitrogen, are most sieved afterwards through analysis
Screening, obtain the cunife magnet alloy powder of 180 mesh.
The preparation method of the additive is：By Macrogol 4000, phenthazine, 2,6 di tert butyl 4 methyl phenol,
1,3,5- trimethyls -2,4,6- three (3,5- di-tert-butyl-4-hydroxyl benzyls) benzene presses 75:0.2:0.2:0.2 mass ratio mixing,
It is subsequently added into solvent acetone, the mass volume ratio for obtaining mixture B, the mixture B and acetone is 1：7 (g/ml), at 50 DEG C
Under with 1000r/min mixing 2h, evaporate acetone at 85 DEG C, when solution in it is powdered when stop, obtaining the additive.
Embodiment 7
It is substantially the same manner as Example 1, it differs only in：The magnetic powder be white magnetic powder, cunife magnet alloy powder it is mixed
Close object, the white magnetic powder, cunife magnet alloy powder mass ratio 1:1.
The production method of the copper-nickel iron permanent magnet alloy powder is：
Copper, nickel, iron and additive are pressed 50 by I,:40:5:Copper, nickel, iron are mixed to get mixing gold by 1 mass ratio mixing
Belong to powder；The deionized water of mixed metal powder quality 40% is added, mixing is placed on ball mill, places into a diameter of 20mm's
YG8 sintered carbide balls, at 25 DEG C with 200r/min wet-millings 8h after, obtain slurry A；
Additive is added into above-mentioned slurry A in II, is placed in ball mill, places into the YG8 hard alloy of a diameter of 20mm
Ball obtains slurry B with 200r/min wet mixing 3h at 25 DEG C；
Above-mentioned slurry B is placed in spray drying device and carries out mist projection granulating by III, and the rotating speed of atomizer is 6000r/min,
220 DEG C of inlet temperature, 100 DEG C of outlet temperature, feeding revolution speed are 840r/min, and the screening through analysis sieve obtains 80 purposes and makes
Grain powder；
Above-mentioned prilling powder is placed in 600 DEG C of degreasing equipment by IV, and degreasing 6h is subsequently placed into sintering furnace and quickly burns
Knot, feed rate 6kg/h, sintering temperature are 1400 DEG C, and sintering time 3s, protective atmosphere is nitrogen, are most sieved afterwards through analysis
Screening, obtain the cunife magnet alloy powder of 180 mesh.
The preparation method of the additive is：By Macrogol 4000, phenthazine, 2,6 di tert butyl 4 methyl phenol,
1,3,5- trimethyls -2,4,6- three (3,5- di-tert-butyl-4-hydroxyl benzyls) benzene presses 75:0.2:0.2:0.2 mass ratio mixing,
It is subsequently added into solvent acetone, the mass volume ratio for obtaining mixture B, the mixture B and acetone is 1：7 (g/ml), at 50 DEG C
Under with 1000r/min mixing 2h, evaporate acetone at 85 DEG C, when solution in it is powdered when stop, obtaining the additive.
Embodiment 8
It is substantially the same manner as Example 1, it differs only in：The magnetic powder is white magnetic powder, ferroso-ferric oxide, cupro-nickel iron permanent magnetism
The mixture of alloyed powder, the white magnetic powder, ferroso-ferric oxide, cunife magnet alloy powder mass ratio 1:1:1.
The production method of the copper-nickel iron permanent magnet alloy powder is：
Copper, nickel, iron and additive are pressed 50 by I,:40:5:Copper, nickel, iron are mixed to get mixing gold by 1 mass ratio mixing
Belong to powder；The deionized water of mixed metal powder quality 40% is added, mixing is placed on ball mill, places into a diameter of 20mm's
YG8 sintered carbide balls, at 25 DEG C with 200r/min wet-millings 8h after, obtain slurry A；
Additive is added into above-mentioned slurry A in II, is placed in ball mill, places into the YG8 hard alloy of a diameter of 20mm
Ball obtains slurry B with 200r/min wet mixing 3h at 25 DEG C；
Above-mentioned slurry B is placed in spray drying device and carries out mist projection granulating by III, and the rotating speed of atomizer is 6000r/min,
220 DEG C of inlet temperature, 100 DEG C of outlet temperature, feeding revolution speed are 840r/min, and the screening through analysis sieve obtains 80 purposes and makes
Grain powder；
Above-mentioned prilling powder is placed in 600 DEG C of degreasing equipment by IV, and degreasing 6h is subsequently placed into sintering furnace and quickly burns
Knot, feed rate 6kg/h, sintering temperature are 1400 DEG C, and sintering time 3s, protective atmosphere is nitrogen, are most sieved afterwards through analysis
Screening, obtain the cunife magnet alloy powder of 180 mesh.
The preparation method of the additive is：By Macrogol 4000, phenthazine, 2,6 di tert butyl 4 methyl phenol,
1,3,5- trimethyls -2,4,6- three (3,5- di-tert-butyl-4-hydroxyl benzyls) benzene presses 75:0.2:0.2:0.2 mass ratio mixing,
It is subsequently added into solvent acetone, the mass volume ratio for obtaining mixture B, the mixture B and acetone is 1：7 (g/ml), at 50 DEG C
Under with 1000r/min mixing 2h, evaporate acetone at 85 DEG C, when solution in it is powdered when stop, obtaining the additive.
Embodiment 9
The preparation method for having the necklace for improving insomnia function, includes the following steps：
The sodium hydroxide alkali wash water of 5wt% is heated to 70 DEG C by I, and sodium hydroxide alkali wash water then is added in necklace matrix
In, 4min is impregnated, then clean substrate surface with acetone, then with alcohol wipe, is dried up；
It is 1 that mass ratio is added into powder mixer by II,:1:1 white fused alumina, bead, ceramic sand, at 30 DEG C with
The rotating speed of 30r/min stirs 2.5h, and gained blast media carries out blasting treatment to stainless steel substrate, spray gun pressure 0.6MPa,
Sandblasting angle is 45 °, nozzle distance 100mm, blast time 30s, then using magnetic powder as dusty spray, to necklace base material table
Face carries out spray treatment, spray distance 380mm, oxygen flow 15L/h, kerosene oil flow 23L/h, and powder feeding rate 76g/min works as spray
It applies when thickness is 0.5mm and stops, obtaining with the necklace for improving insomnia function.
The magnetic powder is the mixture of white magnetic powder, ferroso-ferric oxide, cupro-nickel iron Co permanent magnetic alloy powder, the white magnetic powder, four
The mass ratio 1 of Fe 3 O, cupro-nickel iron Co permanent magnetic alloy powder:1:1.
The production method of the copper-nickel iron Co permanent magnetic alloy powder is：
Copper, nickel, iron, cobalt metal powder are pressed 50 by I,:40:5:5 mass ratio mixing, obtains mixed metal powder；It is added
The deionized water of mixed metal powder quality 40%, mixing are placed on ball mill, place into the YG8 hard alloy of a diameter of 20mm
Ball, at 25 DEG C with 200r/min wet-millings 8h after, obtain slurry；
Above-mentioned slurry is placed in spray drying device and carries out mist projection granulating by II, and the rotating speed of atomizer is 6000r/min,
220 DEG C of inlet temperature, 100 DEG C of outlet temperature, feeding revolution speed are 840r/min, and the screening through analysis sieve obtains 80 purposes and makes
Grain powder；
Above-mentioned prilling powder is placed in 600 DEG C of degreasing equipment by III, and degreasing 6h is subsequently placed into sintering furnace and quickly burns
Knot, feed rate 6kg/h, sintering temperature are 1400 DEG C, and sintering time 3s, protective atmosphere is nitrogen, are most sieved afterwards through analysis
Screening, obtain the cupro-nickel iron Co permanent magnetic alloy powder of 180 mesh.
Test case 1
Bond strength is tested：Using 304 stainless steels that specification is φ 25mm × 7mm as bar sample, using of the invention real
Applying a 1-9, there is the sandblasting for the necklace for improving insomnia function to carry out blasting treatment, then spray work using moderate supersonic speed of the present invention
Skill sprays the magnetic powder in corresponding embodiment, coating thickness 0.5mm, then according to HB5476《Hot-spraying coating bonding strength test
Method》Specified in method, using universal tensile machine (model WDW-10-1000, be purchased from the limited public affairs of the fast detection device of Ningbo moral
Department) to the bond strength of magnetic powder coating is measured on bar sample after spraying, test temperature is 25 DEG C, tensile speed 2mm/
min。
Table 1：Anchoring strength of coating test result table
| Product | Bond strength/MPa |
| Embodiment 1 | 68.5 |
| Embodiment 2 | 56.0 |
| Embodiment 3 | 56.7 |
| Embodiment 4 | 55.6 |
| Embodiment 5 | 64.4 |
| Embodiment 6 | 64.0 |
| Embodiment 7 | 63.6 |
| Embodiment 8 | 65.7 |
| Embodiment 9 | 62.4 |
Blasting treatment can be such that the mechanical performance of matrix surface is improved, and increase the adhesive force between matrix and coating,
The bond strength for enhancing coating, extends the durability of film, is also beneficial to the levelling and decoration of coating.Data in comparison sheet 1,
It can be seen that in embodiment 1 at using 304 stainless steel surface of blast media pair combined by white fused alumina, bead, ceramic sand
Reason, sprays obtained sample after magnetic powder, anchoring strength of coating be higher than and using white fused alumina in embodiment 2-4, bead,
Anchoring strength of coating on the obtained sample of blast media of the arbitrary two kinds of combinations of ceramic sand.
Test case 2
Magnetic parameter is tested：According to emitting beautiful journal of writings《Prepared by microwave method forms controllable Cu1-xNix/MWCNTs composite woods
Material and its magnetic property》The test method of 1.2 sections has to improve and lose in 304 stainless steel specimen surfaces spraying embodiment of the present invention 1-9
The magnetic powder of the item of dormancy function, spraying process be the embodiment of the present invention in supersonic spray coating technique, coating thickness 0.5mm, then
Stainless steel curved beam after spraying and the magnetic parameter of blank group are measured, blank group is not spray the stainless steel curved beam of magnetic powder,
304 stainless steel specimen size sizes are 20mm × 20mm × 4mm.
Table 2：Magnetic parameter result table
| Product | Coercivity/kAm-1 |
| Embodiment 1 | 58.2 |
| Embodiment 2 | 55.2 |
| Embodiment 3 | 56.0 |
| Embodiment 4 | 54.9 |
| Embodiment 5 | 46.6 |
| Embodiment 6 | 45.9 |
| Embodiment 7 | 46.3 |
| Embodiment 8 | 50.5 |
| Embodiment 9 | 53.5 |
| Blank group | 0 |
Coercivity refers to the characterisitic parameter index that magnetic material resists that opposing magnetic field makes it demagnetize, the bigger table of coercivity
Show that the magnetism of magnetic material is less susceptible to disappear.There is in comparison sheet 1 in embodiment 5-8 the necklace and sky for improving insomnia function
The data organized in vain are it is found that embodiment 8 is sprayed using the magnetic powder combined by white magnetic powder, ferroso-ferric oxide, cunife magnet alloy powder
Necklace matrix, coercivity, which is greater than, has the necklace for improving insomnia function (using by white magnetic powder, four oxidations three in embodiment 5-7
The magnetic powder of the arbitrary two kinds of combinations of iron, cunife magnet alloy powder) and blank group；And in the magnetic powder used in embodiment 1, by
Cupro-nickel iron Co permanent magnetic alloy powder substitute cunife magnet alloy powder, relative in embodiment 8 have improve insomnia function necklace,
Further improve the coercivity size with the necklace for improving insomnia function.
Test case 3
Apparent density is tested：Using the Master's thesis of Jin Dongxu《Preparation with core/shell structure copper/nickel silver powder and its resistance to
High-temperature behavior research》In 5.3 section test methods to used in embodiment 1-9 and comparative example 1 magnetic powder carry out pine fill it is close
Degree test.
Table 3：Apparent density tests table
| Product | Apparent density/gm-3 |
| Embodiment 1 | 3.6 |
| Embodiment 2 | 3.3 |
| Embodiment 3 | 3.4 |
| Embodiment 4 | 3.3 |
| Embodiment 5 | 3.0 |
| Embodiment 6 | 2.9 |
| Embodiment 7 | 3.0 |
| Embodiment 8 | 3.2 |
| Embodiment 9 | 2.4 |
Apparent density represents the filling physical property of powder, and apparent density shows more greatly the degree that body of powder gap can be filled
Smaller, powder flowbility is also better, and polyethylene glycol 400 can lead to as a kind of additive in the preparation of alloy magnetic powder
It is spheric granules to cross its adhesive effect metallic particles is made mutually to bond reunion, and can prevent the sedimentation of subparticle in slurry and coagulate
It is poly-, the final performance for improving metal powder.Data in comparison sheet 3, it can be seen that the system of cupro-nickel iron Co permanent magnetic alloy powder in embodiment 1
Standby to use the additive that polyethylene glycol 400 is formed as primary raw material, the apparent density of final mixing gained magnetic powder is apparent
More than embodiment 9.
Test case 4
Health care curative effect is tested：Selection has the volunteer of insomnia or hypertension, and the age, men and women was fifty-fifty between 35-70 Sui, altogether
400 people of volunteer is collected, is randomly divided into 20 groups, insomnia and each 10 groups of hyperglycemia measure changed using having in embodiment 1-9 respectively
The necklace of kind insomnia function and the improvement insomnia effect and blood glucose value of blank group, blank group are to be not used to have to improve insomnia work(
The necklace of energy.
Improve insomnia measure of merit：It no longer has a sleepless night after removing the present invention, is effective；The present invention is worn without insomnia, is taken
It remains to have a sleepless night after the lower present invention, is effective；It is constant to wear symptom of the present invention, is invalid.
Blood sugar test：It is right respectively using blood glucose monitoring system (BKM13-1 types step on medical limited liability company purchased from Nanjing shellfish)
Hyperglycemia volunteer is tested before using the present invention and using the blood glucose value after 5 months.
Application method：The present invention is worn on front to test using effect, volunteer is in addition to using the present invention
Outside, unused other methods are treated, while before the test begins, should be informed volunteer's major function of the present invention and may be sent out
Raw uncomfortable, concrete outcome is shown in Table 4.
Table 4：Health care curative effect test result table
From the data in table 4, it can be seen that can using the data of the necklace and blank group in embodiment 1 with improvement insomnia function
Know, effective and effective improvement insomnia is respectively 13,5, and blood glucose value reduces 1.80mmol/L, therefore the present invention has
The necklace for improving insomnia function has the health-care effect for improving insomnia and reducing blood glucose.
The above described is only a preferred embodiment of the present invention, limitation in any form not is done to the present invention, therefore
The equivalent or simple change that all principles according to described in inventional idea of the present invention are done, is included in the protection domain of patent of the present invention
It is interior；Those skilled in the art can make various modifications or additions to the described embodiments
Or substitute by a similar method, without departing from structure of the invention or beyond the scope defined by this claim,
It is within the scope of protection of the invention.
Claims (10)
1. a kind of preparation method with the necklace for improving insomnia function, which is characterized in that include the following steps：To necklace matrix
It is surface-treated；The material of the necklace matrix is steel alloy.
2. the preparation method with the necklace for improving insomnia function described in claim 1, which is characterized in that the surface treatment
Step is：
I, oil removing grease removal, it is dry；
II, carries out blasting treatment using blast media to necklace matrix surface, then magnetic powder is sprayed on necklace matrix.
3. having the preparation method for the necklace for improving insomnia function as claimed in claim 2, which is characterized in that the blast media
It is one or more in white fused alumina, bead, ceramic sand.
4. having the preparation method for the necklace for improving insomnia function as claimed in claim 2, which is characterized in that the magnetic powder is white
It is one or more in magnetic powder, ferroso-ferric oxide, cunife magnet alloy, cupro-nickel iron Co permanent magnetic alloy powder.
5. having the preparation method for the necklace for improving insomnia function as claimed in claim 4, which is characterized in that the copper-nickel iron cobalt
Permanent-magnet alloy is prepared by the raw material of following weight parts：40-80 parts of copper, 13-40 parts of nickel, 5-8 parts of iron, 3-7 parts of cobalt, additive
0.2-1.5 parts.
6. having the preparation method for the necklace for improving insomnia function as claimed in claim 5, which is characterized in that the copper-nickel iron is forever
The preparation method of magnetic alloy or cupro-nickel iron Co permanent magnetic alloy powder is：
I, weighs each raw material component according to parts by weight, and raw metal is mixed to get mixed metal powder；Mixed metal powder is added
The deionized water of last quality 25%-50%, gained mixture are placed in ball-grinding machine, after 150-230r/min wet-millings 8-12h,
Obtain slurry A；
Additive is added into above-mentioned slurry A in II, places into wet mixing 2-6h in ball mill, gained slurry B；
III, carries out mist projection granulating processing to above-mentioned slurry B, and the rotating speed of atomizer is 6000-8000r/min, inlet temperature 220-
260 DEG C, 80-100 DEG C of outlet temperature, feeding revolution speed is 600-1000r/min, obtains prilling powder after screening；
The above-mentioned prilling powders of IV, are placed in Fast Sintering in sintering furnace, feed rate 3-8kg/h, sintering after ungrease treatment
Temperature is 1000-1400 DEG C, and sintering time 0.1s-5s, protective atmosphere is nitrogen, finally obtains cupro-nickel iron cobalt after screening
Permanent magnet alloy powder.
7. as claimed in claim 6 have improve insomnia function necklace preparation method, which is characterized in that the additive by
Adhesive and antioxidant (60-80) in mass ratio:(0.5-1) is mixed.
8. having the preparation method for the necklace for improving insomnia function as claimed in claim 7, which is characterized in that the binder is
It is one or more in polyethylene glycol, polymethyl methacrylate, polyvinylpyrrolidone.
9. having the preparation method for the necklace for improving insomnia function as claimed in claim 7, which is characterized in that the antioxidant
For phenthazine, the 2,6 di tert butyl 4 methyl phenol, (3,5- di-t-butyl -4- hydroxyl benzyls of 1,3,5- trimethyls -2,4,6- three
Base) it is one or more in benzene.
10. a kind of with the necklace for improving insomnia function, which is characterized in that there is improvement using any in claim 2-9
The preparation method of the necklace for function of having a sleepless night is prepared.
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| CN201810126174.0A CN108308802B (en) | 2018-02-08 | 2018-02-08 | Necklace with function of improving insomnia and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810126174.0A CN108308802B (en) | 2018-02-08 | 2018-02-08 | Necklace with function of improving insomnia and preparation method thereof |
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| CN108308802A true CN108308802A (en) | 2018-07-24 |
| CN108308802B CN108308802B (en) | 2019-12-31 |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112690544A (en) * | 2020-12-30 | 2021-04-23 | 广州美术学院 | Necklace capable of relieving fatigue and preparation method thereof |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN202456794U (en) * | 2012-02-29 | 2012-10-03 | 王斐芬 | Negative ion health-care necklace |
| CN202566626U (en) * | 2012-03-09 | 2012-12-05 | 张志伟 | Rope-free and buckle-free magnetic health care pearl necklace |
| CN105559278A (en) * | 2016-02-25 | 2016-05-11 | 罗福仲 | Buddha bead with health care and noctilucence functions |
| CN107068316A (en) * | 2017-04-14 | 2017-08-18 | 河北工业大学 | Cupro-nickel permendur strip and preparation method thereof |
| CN206729375U (en) * | 2017-04-07 | 2017-12-12 | 中山市华睿雅生物科技有限公司 | Health-care ornament |
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2018
- 2018-02-08 CN CN201810126174.0A patent/CN108308802B/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN202456794U (en) * | 2012-02-29 | 2012-10-03 | 王斐芬 | Negative ion health-care necklace |
| CN202566626U (en) * | 2012-03-09 | 2012-12-05 | 张志伟 | Rope-free and buckle-free magnetic health care pearl necklace |
| CN105559278A (en) * | 2016-02-25 | 2016-05-11 | 罗福仲 | Buddha bead with health care and noctilucence functions |
| CN206729375U (en) * | 2017-04-07 | 2017-12-12 | 中山市华睿雅生物科技有限公司 | Health-care ornament |
| CN107068316A (en) * | 2017-04-14 | 2017-08-18 | 河北工业大学 | Cupro-nickel permendur strip and preparation method thereof |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112690544A (en) * | 2020-12-30 | 2021-04-23 | 广州美术学院 | Necklace capable of relieving fatigue and preparation method thereof |
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| CN108308802B (en) | 2019-12-31 |
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Effective date of registration: 20240122 Address after: No. 30-2 Binhe North Road, Niushan Street, Donghai County, Lianyungang City, Jiangsu Province, 222300 Patentee after: Jiangsu Dejia Health Industry Technology Co.,Ltd. Country or region after: China Address before: 432200, Room 1, 1st Floor, Building 15, Bingjinglan Xinyuan, Huancheng Yougang Village, Huangpi District, Wuhan City, Hubei Province Patentee before: Hubei juejiang Technology Co.,Ltd. Country or region before: China |