CN108306080A - Lighting apparatus - Google Patents

Lighting apparatus Download PDF

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Publication number
CN108306080A
CN108306080A CN201711406528.9A CN201711406528A CN108306080A CN 108306080 A CN108306080 A CN 108306080A CN 201711406528 A CN201711406528 A CN 201711406528A CN 108306080 A CN108306080 A CN 108306080A
Authority
CN
China
Prior art keywords
lighting apparatus
cell reaction
reaction slot
circuit board
metal
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201711406528.9A
Other languages
Chinese (zh)
Inventor
胡广来
汪云华
和晓才
靳喜
缪森艳
徐俊毅
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Yunnan Aluminium Co Ltd
Original Assignee
Yunnan Aluminium Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Yunnan Aluminium Co Ltd filed Critical Yunnan Aluminium Co Ltd
Priority to CN201711406528.9A priority Critical patent/CN108306080A/en
Publication of CN108306080A publication Critical patent/CN108306080A/en
Pending legal-status Critical Current

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Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M12/00Hybrid cells; Manufacture thereof
    • H01M12/04Hybrid cells; Manufacture thereof composed of a half-cell of the fuel-cell type and of a half-cell of the primary-cell type
    • H01M12/06Hybrid cells; Manufacture thereof composed of a half-cell of the fuel-cell type and of a half-cell of the primary-cell type with one metallic and one gaseous electrode
    • H01M12/065Hybrid cells; Manufacture thereof composed of a half-cell of the fuel-cell type and of a half-cell of the primary-cell type with one metallic and one gaseous electrode with plate-like electrodes or stacks of plate-like electrodes
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F21LIGHTING
    • F21LLIGHTING DEVICES OR SYSTEMS THEREOF, BEING PORTABLE OR SPECIALLY ADAPTED FOR TRANSPORTATION
    • F21L4/00Electric lighting devices with self-contained electric batteries or cells
    • F21L4/08Electric lighting devices with self-contained electric batteries or cells characterised by means for in situ recharging of the batteries or cells
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F21LIGHTING
    • F21VFUNCTIONAL FEATURES OR DETAILS OF LIGHTING DEVICES OR SYSTEMS THEREOF; STRUCTURAL COMBINATIONS OF LIGHTING DEVICES WITH OTHER ARTICLES, NOT OTHERWISE PROVIDED FOR
    • F21V23/00Arrangement of electric circuit elements in or on lighting devices
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F21LIGHTING
    • F21VFUNCTIONAL FEATURES OR DETAILS OF LIGHTING DEVICES OR SYSTEMS THEREOF; STRUCTURAL COMBINATIONS OF LIGHTING DEVICES WITH OTHER ARTICLES, NOT OTHERWISE PROVIDED FOR
    • F21V23/00Arrangement of electric circuit elements in or on lighting devices
    • F21V23/06Arrangement of electric circuit elements in or on lighting devices the elements being coupling devices, e.g. connectors
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/10Primary casings; Jackets or wrappings
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/10Primary casings; Jackets or wrappings
    • H01M50/147Lids or covers
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/10Primary casings; Jackets or wrappings
    • H01M50/172Arrangements of electric connectors penetrating the casing
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/10Primary casings; Jackets or wrappings
    • H01M50/183Sealing members
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/50Current conducting connections for cells or batteries
    • H01M50/543Terminals
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/50Current conducting connections for cells or batteries
    • H01M50/571Methods or arrangements for affording protection against corrosion; Selection of materials therefor
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/60Arrangements or processes for filling or topping-up with liquids; Arrangements or processes for draining liquids from casings
    • H01M50/609Arrangements or processes for filling with liquid, e.g. electrolytes
    • H01M50/627Filling ports
    • H01M50/636Closing or sealing filling ports, e.g. using lids
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/60Arrangements or processes for filling or topping-up with liquids; Arrangements or processes for draining liquids from casings
    • H01M50/691Arrangements or processes for draining liquids from casings; Cleaning battery or cell casings
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01RELECTRICALLY-CONDUCTIVE CONNECTIONS; STRUCTURAL ASSOCIATIONS OF A PLURALITY OF MUTUALLY-INSULATED ELECTRICAL CONNECTING ELEMENTS; COUPLING DEVICES; CURRENT COLLECTORS
    • H01R12/00Structural associations of a plurality of mutually-insulated electrical connecting elements, specially adapted for printed circuits, e.g. printed circuit boards [PCB], flat or ribbon cables, or like generally planar structures, e.g. terminal strips, terminal blocks; Coupling devices specially adapted for printed circuits, flat or ribbon cables, or like generally planar structures; Terminals specially adapted for contact with, or insertion into, printed circuits, flat or ribbon cables, or like generally planar structures
    • H01R12/50Fixed connections
    • H01R12/51Fixed connections for rigid printed circuits or like structures
    • H01R12/55Fixed connections for rigid printed circuits or like structures characterised by the terminals
    • H01R12/57Fixed connections for rigid printed circuits or like structures characterised by the terminals surface mounting terminals
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01RELECTRICALLY-CONDUCTIVE CONNECTIONS; STRUCTURAL ASSOCIATIONS OF A PLURALITY OF MUTUALLY-INSULATED ELECTRICAL CONNECTING ELEMENTS; COUPLING DEVICES; CURRENT COLLECTORS
    • H01R4/00Electrically-conductive connections between two or more conductive members in direct contact, i.e. touching one another; Means for effecting or maintaining such contact; Electrically-conductive connections having two or more spaced connecting locations for conductors and using contact members penetrating insulation
    • H01R4/28Clamped connections, spring connections
    • H01R4/48Clamped connections, spring connections utilising a spring, clip, or other resilient member
    • H01R4/4809Clamped connections, spring connections utilising a spring, clip, or other resilient member using a leaf spring to bias the conductor toward the busbar
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M2220/00Batteries for particular applications
    • H01M2220/30Batteries in portable systems, e.g. mobile phone, laptop
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • General Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Hybrid Cells (AREA)

Abstract

The invention discloses a kind of lighting apparatus, including:Lighting device, circuit board assemblies and metal fuel battery.Circuit board assemblies are connected with lighting device, metal fuel battery is connected with circuit board assemblies, metal fuel battery includes cell reaction slot, metal electrode, air electrode and electrolyte, the top of cell reaction slot has cover board, metal electrode is equipped with the conduct piece for being suitable for being connected with circuit board assemblies, and conduct piece is located at side of the cover board far from cell reaction slot.Lighting apparatus according to the present invention, when lighting apparatus works, it can prevent the gas generated in electrolyte and the course of work in lighting apparatus from causing to corrode to above-mentioned conduct piece, thereby may be ensured that the stability of lighting apparatus work, extend the service life of lighting apparatus.

Description

Lighting apparatus
Technical field
The present invention relates to lighting technical fields, more particularly, to a kind of lighting apparatus.
Background technology
Lighting apparatus has been indispensable part in daily life, and the lighting apparatus generally used in life at present is exactly One kind in small-sized lightings, this lighting apparatus be widely used in night trip, burst have a power failure, outlying easy power-shortage area or Take an excursion in an open country etc..Common lighting apparatus is made of lead-acid battery, lithium ion battery mostly currently on the market, some can be attached to too The function that can generate electricity of sun, but such battery is relative to metal fuel battery, with it is lower than energy, pollute environment, self-discharge rate it is high, The shortcomings of cycle life is short cannot meet the market demand.
Using the lighting apparatus of metal fuel battery, the short feature of lead-acid battery pollution environment, cycle life can overcome the disadvantages that, more Mend that lithium ion battery is of high cost, energy density problem.However, the lighting apparatus using metal fuel battery in the related technology, It is not reasonable due to its structure setting, lead to lighting apparatus in use, the metal electrode in metal fuel battery with The part of circuit board assemblies conduction is easy to be corroded and influence use and the service life of lighting apparatus.Therefore, have much room for improvement.
Invention content
The present invention is directed at least solve one of the technical problems existing in the prior art.For this purpose, the present invention proposes a kind of photograph Bright equipment, the lighting apparatus is easy to use and service life is long.
Lighting apparatus according to the ... of the embodiment of the present invention, including:Lighting device;Circuit board assemblies, the circuit board assemblies with The lighting device is connected;Metal fuel battery, the metal fuel battery are connected with the circuit board assemblies, the metal combustion Material battery includes cell reaction slot, metal electrode, air electrode and electrolyte, and the top of the cell reaction slot has cover board, The metal electrode is equipped with the conduct piece for being suitable for being connected with the circuit board assemblies, and it is separate that the conduct piece is located at the cover board The side of the cell reaction slot.
Lighting apparatus according to the ... of the embodiment of the present invention, by the way that cover board is arranged at the top of cell reaction slot, by circuit board Component is spaced with cell reaction slot, while by being arranged metal electrode and circuit connecting section (i.e. conduct piece) in cover board Side far from cell reaction slot can prevent the gas generated in the lighting apparatus course of work thus when lighting apparatus works Body causes to corrode to above-mentioned conduct piece, thereby may be ensured that the stability of lighting apparatus work, and extend lighting apparatus uses the longevity Life.
According to some embodiments of the present invention, the conduct piece is integrally formed with the metal electrode.
According to some embodiments of the present invention, the lighting apparatus includes:Connector for installing the metal electrode, The metal fuel battery is located at the lower section of the circuit board assemblies, and the connector is located on the metal electrode, the company The periphery wall of fitting has the first mounting surface, and first mounting surface from bottom to top and is inclined outwardly extension, shape on the cover board At the mounting hole having suitable for installing the connector, the internal perisporium of the mounting hole has the coordinated with first mounting surface Two mounting surfaces, second mounting surface from bottom to top and are inclined outwardly extension.
Optionally, the connector is the moulding being moulded on the metal electrode.
Optionally, sealing element is equipped between first mounting surface and second mounting surface.
According to some embodiments of the present invention, the conduct piece is connected with the circuit board assemblies by metal buckle, institute It states metal buckle to be located on the circuit board assemblies, the metal buckle includes:It buckles ontology and is respectively provided at the buckle The first shrapnel and the second shrapnel of ontology opposite end, the conduct piece are fastened on first shrapnel and the second shrapnel institute In the space of restriction, and the conduct piece is contacted with first shrapnel, second shrapnel.
According to some embodiments of the present invention, one end of the lighting device rotationally connects with the metal fuel battery It connects, and the other end of the lighting device is connect with the metal fuel battery by breaking buckle.
According to some embodiments of the present invention, the side wall of the cell reaction slot is equipped with filtering port, and the filtering port is adjacent The bottom setting of the nearly cell reaction slot, the filtering port upper cover are equipped with spiral cover.
Further, the lighting apparatus includes:Partition board, the partition board are located in the cell reaction slot with by the electricity Pond reactive tank is separated into two sub- reactive tanks spaced apart from each other, and the metal electrode and institute are equipped in each sub- reactive tank State air electrode.
Further, the filtering port is located at the intersection of the side wall and the partition board of the cell reaction slot, it is described every Position corresponding with the filtering port is equipped with notch on plate, and the notch is suitable for two sub- reactive tanks of connection, the notch Place is equipped with sealing sprue to separate two sub- reactive tanks by the sealing sprue when the lighting apparatus works.
According to some embodiments of the present invention, the side wall of the cell reaction slot is equipped with gas vent, and the gas vent is adjacent The top setting of the nearly cell reaction slot.
Optionally, the cross section of the cell reaction slot is rectangular, and the side wall of the cell reaction slot is equipped with filtering port, The gas vent is located at the filtering port on the same side wall of the cell reaction slot.
Optionally, the top of the cell reaction slot is equipped with the lug upwardly extended, and the gas vent is formed in described convex On ear.
Optionally, the cross section of the gas vent gradually increases on direction from inside to outside.
The additional aspect and advantage of the present invention will be set forth in part in the description, and will partly become from the following description Obviously, or practice through the invention is recognized.
Description of the drawings
The above-mentioned and/or additional aspect and advantage of the present invention will become in the description from combination following accompanying drawings to embodiment Obviously and it is readily appreciated that, wherein:
Fig. 1 is the schematic diagram of lighting apparatus according to the ... of the embodiment of the present invention;
Fig. 2 is the three-dimensional structure diagram of lighting apparatus according to an embodiment of the invention;
Fig. 3 is the enlarged drawing at A in Fig. 2;
Fig. 4 is the enlarged drawing at B in Fig. 2;
Fig. 5 is the three-dimensional structure diagram of another angle of lighting apparatus according to an embodiment of the invention;
Fig. 6 is the enlarged drawing at C in Fig. 5;
Fig. 7 is the explosive view of lighting apparatus according to an embodiment of the invention;
Fig. 8 is that the lighting device of lighting apparatus according to an embodiment of the invention rotates signal around metal fuel battery Figure;
Fig. 9 is the part-structure schematic diagram of lighting apparatus according to an embodiment of the invention;
Figure 10 is the enlarged drawing at D in Fig. 9;
Figure 11 is the part-structure exploded view of lighting apparatus according to an embodiment of the invention;
Figure 12 is the part-structure schematic diagram of lighting apparatus according to an embodiment of the invention;
Figure 13 is the part-structure exploded view of lighting apparatus according to an embodiment of the invention.
Reference numeral:
Lighting apparatus 100;
Lighting device 1;Even light shield 11;Reflector 12;Protective cover 13;
Circuit board assemblies 2;Substrate 21;Mounting portion 211;Circuit board 22;Middle cover 23;Pivotal axis 231;
Break button 3;First clamping portion 31;Second clamping portion 32;Handle 4;
Metal fuel battery 5;Cell reaction slot 51;Groove body 51a;Ventilating cover 51b;Sub- reactive tank 511;Filtering port 512;Rotation Lid 513;Partition board 514;Notch 5141;Seal sprue 5142;Lug 515;Gas vent 5151;Pivoting hole 516;Metal electrode 52; Conduct piece 521;Connector 53;First mounting surface 531;Air electrode 54;Cover board 55;Mounting hole 551;Second mounting surface 5511; Sealing element 56;
Metal buckle 6;Buckle ontology 61;First shrapnel 62;Second shrapnel 63.
Specific implementation mode
The embodiment of the present invention is described below in detail, examples of the embodiments are shown in the accompanying drawings, wherein from beginning to end Same or similar label indicates same or similar element or element with the same or similar functions.Below with reference to attached The embodiment of figure description is exemplary, and is only used for explaining the present invention, and is not considered as limiting the invention.
In the description of the present invention, it is to be understood that, term "center", " longitudinal direction ", " transverse direction ", " length ", " width ", " thickness ", "upper", "lower", "front", "rear", "left", "right", "vertical", "horizontal", "top", "bottom" "inner", "outside", " up time The orientation or positional relationship of the instructions such as needle ", " counterclockwise ", " axial direction ", " radial direction ", " circumferential direction " be orientation based on ... shown in the drawings or Position relationship is merely for convenience of description of the present invention and simplification of the description, and does not indicate or imply the indicated device or element must There must be specific orientation, with specific azimuth configuration and operation, therefore be not considered as limiting the invention.In addition, limit There is the feature of " first ", " second " to can explicitly or implicitly include one or more this feature surely.The present invention's In description, unless otherwise indicated, the meaning of " plurality " is two or more.
In the description of the present invention, it should be noted that unless otherwise clearly defined and limited, term " installation ", " phase Even ", " connection " shall be understood in a broad sense, for example, it may be being fixedly connected, may be a detachable connection, or be integrally connected;It can Can also be electrical connection to be mechanical connection;It can be directly connected, can also indirectly connected through an intermediary, Ke Yishi Connection inside two elements.For the ordinary skill in the art, above-mentioned term can be understood at this with concrete condition Concrete meaning in invention.
Lighting apparatus 100 according to the ... of the embodiment of the present invention is described below with reference to Fig. 1-Figure 13.
As shown in Fig. 1-Figure 13, lighting apparatus 100 according to the ... of the embodiment of the present invention, including:Lighting device 1, circuit board group Part 2 and metal fuel battery 5.
Specifically, circuit board assemblies 2 are connected with lighting device 1, can lead between circuit board assemblies 2 and lighting device 1 Cross conducting wire connection.Metal fuel battery 5 is connected with circuit board assemblies 2, can be between metal fuel battery 5 and circuit board assemblies 2 It is connected by terminal.Lighting device 1, circuit board assemblies 2 and metal fuel battery 5 can successively be set on direction from top to bottom It sets, i.e., metal fuel battery 5 is located at bottom, circuit board assemblies 2 are located at top and the lighting device 1 of metal fuel battery 5 In the top of circuit board assemblies 2.Wherein, metal fuel battery 5 is to convert chemical energy to electric energy, and metal fuel battery 5 is to shine Bright device 1 provides electric energy, load of the lighting device 1 as metal fuel battery 5, and lighting device 1 can convert electrical energy into light It can be for illumination.
Metal fuel battery 5 includes that cell reaction slot 51, metal electrode 52, air electrode 54 and electrolyte, electrolyte are filled out It fills in cell reaction slot 51, electrolyte can be brine or seawater.It is anti-that metal electrode 52 and air electrode 54 are each provided at battery It answers in slot 51 and with the electrolyte contacts in cell reaction slot 51, metal electrode 52 and air electrode 54 is and circuit board assemblies 2 are connected, and metal electrode 52 and air electrode 54 are connected in series with.It is corresponding with air electrode 54 on the side wall of cell reaction slot 51 Position is equipped with air hole, and air hole can be in that lattice-like is arranged, and can be played to air electrode 54 by the air hole of setting Protective effect.Wherein, air electrode 54 can be suppressed by waterproof layer, conductive layer, waterproof layer, Catalytic Layer, make air The above-mentioned various pieces of air electrode 54 can be used glue sticking when electrode 54, be then sealed at gap with silica gel.
There is cover board 55, circuit board assemblies 2 to be located at the top of cover board 55 at the top of cell reaction slot 51, and cover board 55 is for sealing The top of lid cell reaction slot 51 is cell reaction slot 51 and circuit board assemblies 2 to be spaced.Optionally, cover board 55 can be with electricity The groove body 51a of pond reactive tank 51 is integrally formed.For example, the groove body 51a of cell reaction slot 51 can be by injection molding side with cover board 55 Formula is integrally formed.
(conduct piece 521 can conduct equipped with the conduct piece 521 for being suitable for being connected with circuit board assemblies 2 for metal electrode 52 One of above-mentioned terminal), conduct piece 521 is located at side of the cover board 55 far from cell reaction slot 51.Pass through the cover board of setting as a result, 55, and the conduct piece of metal electrode 52 521 is arranged in side of the cover board 55 far from cell reaction slot 51, it also can be by metal The conduct piece 521 of electrode 52 is kept apart with cell reaction slot 51, and the gas generated when preventing lighting apparatus 100 from working is led to above-mentioned Electric part 521 causes to corrode and influence normal use and the service life of lighting apparatus 100 so that metal electrode 52 and circuit board assemblies 2 Between keep good electrical contact, thereby may be ensured that the stability that lighting apparatus 100 works, and lighting apparatus can be extended 100 service life.
Optionally, conduct piece 521 is integrally formed with metal electrode 52.For example, the top of metal electrode 52 can extend A part is used as above-mentioned conduct piece 521, and conduct piece 521 is also aluminum metal at this time.Leading for metal electrode 52 is not only simplified as a result, Electric structure, while also simplifying the installation procedure of metal electrode 52.
The operation principle of the brief description lighting apparatus 100.
Electrolyte is added into cell reaction slot 51, after metal fuel battery 5 is triggered, metal electrode 52 and air electricity Pole 54 constitutes primary battery in cell reaction slot 51, and with air electrode 54 under electrolyte effect electrochemistry occurs for metal electrode 52 Reaction, to power for lighting device 1.Wherein, the energy of metal electrode 52 itself is higher, lighter weight, to improve illumination The portability of equipment 100, and saline solution is also easier to obtain, and especially when needing high-energy spare, user need to only prepare enough metal Electrode 52 and salt, you can energy supply is obtained for a long time, it is simple in structure easy to improve the cruising ability of lighting apparatus 100 It realizes.Optionally, metal electrode can be aluminum metal electrode or magnesium metal electrode etc..
Specifically, the chemical energy contained in metal directly can be changed into electric energy by metal fuel battery 5.For example, golden Belong to aluminium theory and can reach 8100Wh/kg than energy, actually also can reach 350Wh/kg than energy after battery is made, be lithium-ion electric More than twice of pond (150Wh/kg), and environmental pollution is not present, fuel storage is extremely safe, and cost is very cheap, recharges Only need to change metal fuel and electrolyte.For example, when it is desired to be used, aluminium sheet can be put into cell reaction slot 51 as gold Belong to electrode 52, brine or seawater as electrolyte, startup power supply switch, you can for illuminating.When not in use, power supply is closed to open It closes, the electrolyte in cell reaction slot 51 can be poured out, and clean cell reaction slot 51, had simple and convenient, energy saving, lossless The advantage of consumption.
Lighting apparatus 100 according to the ... of the embodiment of the present invention will by the way that cover board 55 is arranged at the top of cell reaction slot 51 Circuit board assemblies 2 are spaced with cell reaction slot 51, while by by metal electrode 52 and circuit connecting section (i.e. conduct piece 521) it is arranged in side of the cover board 55 far from cell reaction slot 51, thus when lighting apparatus 100 works, can prevents illumination from setting The gas generated in standby 100 courses of work causes to corrode to above-mentioned conduct piece 521, thereby may be ensured that lighting apparatus 100 works Stability, extend lighting apparatus 100 service life.
According to some embodiments of the present invention, with reference to Fig. 2, Fig. 4-Fig. 6 and Fig. 8, one end of lighting device 1 and metal fuel Battery 5 is rotatably coupled, and the other end of lighting device 1 is clamped with metal fuel battery 5 by breaking button 3.Thus, it is possible to side Just lighting apparatus 100 is mounted and dismounted, the operation and maintenance of lighting apparatus 100 is facilitated.
According to some embodiments of the present invention, with reference to Fig. 7 and Figure 11, lighting apparatus 100 includes:For installing metal electrode 52 connector 53, metal fuel battery 5 are located at the lower section of circuit board assemblies 2, and connector 53 is located on metal electrode 52, connection The periphery wall of part 53 has the first mounting surface 531, and ("outside" refers to far from even to the first mounting surface 531 from bottom to top and outward The center position of fitting 53, the plane where the direction are horizontal plane) extension is tilted, it is formed on cover board 55 suitable for installation connection The mounting hole 551 of part 53, the internal perisporium of mounting hole 551 have the second mounting surface 5511 coordinated with the first mounting surface 531, and second ("outside" refers to the center position far from mounting hole 551, the plane where the direction to mounting surface 5511 from bottom to top and outward For horizontal plane) tilt extension.Metal electrode 52 easily can be carried out by installation fixation by the connector of setting 53 as a result,. It is simple and reliable in the replacement using process metal electrode 52 and electrolyte of lighting apparatus 100 meanwhile by above-mentioned setting.
It is understood that being matched by the first mounting surface 531 of connector 53 and the second mounting surface 5511 of mounting hole 551 It closes, and the first mounting surface 531 and the second mounting surface 5511 tilt under and extend upwardly and outwardly, mounting hole 551 is interior at this time Peripheral wall has the component lifted upwards to connector 53, since metal electrode 52 is connected with connector 53, it is possible thereby to by metal Electrode 52 is fixed on cover board 55.
Optionally, connector 53 can be the moulding being moulded on metal electrode 52.Facilitate as a result, connector 53 with The connection of metal electrode 52.Certainly, other modes can also be used to be attached between connector 53 and metal electrode 52.Example Such as, connecting hole can be set on connector 53, and the conduct piece 521 of metal electrode 52 can extend up through the connecting hole, lead to The interference fit crossed between conduct piece 521 and connecting hole is metal electrode 52 to be connected with connector 53;Alternatively, can also use Conduct piece 521 is pasted onto in connecting hole by viscose glue, to which metal electrode 52 can also be connected with connector 53.
Optionally, referring to Fig.1 1, the first mounting surface 531 of connector 53 and the second mounting surface 5511 of mounting hole 551 it Between be equipped with sealing element 56.Thus, it is possible to further prevent the gas that lighting apparatus 100 generates during the work time from leaking to lid The top of plate 55, so as to preferably make the conduct piece 521 of metal electrode 52 keep good electricity to connect with circuit board assemblies 2 It touches.
According to some embodiments of the present invention, with reference to Fig. 7, Fig. 9 and Figure 10, conduct piece 521 passes through gold with circuit board assemblies 2 Belong to buckle 6 to be connected, metal buckle 6 is located on circuit board assemblies 2.Metal buckle 6 includes:It buckles ontology 61 and is respectively provided at card The first shrapnel 62 and the second shrapnel 63 of 61 opposite end of ontology are detained, conduct piece 521 is fastened on the first shrapnel 62 and the second shrapnel In space defined by 63, and conduct piece 521 is contacted with the first shrapnel 62, the second shrapnel 63.As a result, by conduct piece 521 with Metal electrode 52 and circuit board assemblies 2 may be implemented in the close contact of the first shrapnel 62 and the second shrapnel 63 of metal buckle 6 Electrical connection, while the conduct piece 521 of metal electrode 52 need to be only inserted into 63 institute of the first shrapnel 62 and the second shrapnel of metal buckle 6 Electrical connection can be conveniently realized in the space of restriction, and facilitates the dismounting of metal electrode 52.
According to some embodiments of the present invention, with reference to Fig. 2, Fig. 5, Fig. 7, Fig. 9, Figure 11-Figure 13, the side of cell reaction slot 51 Wall is equipped with filtering port 512, and the bottom of 512 adjacent cells reactive tank 51 of filtering port is arranged, and 512 upper cover of filtering port is equipped with spiral cover 513.As a result, by the way that filtering port 512 is arranged on the side wall of cell reaction slot 51, electrolyte is facilitated by filtering port 512 It adds and pours out, and the bottom of 512 adjacent cells reactive tank 51 of filtering port is arranged, it is convenient to be observed by the filtering port 512 Whether remain electrolyte on the bottom wall of cell reaction slot 51 and whether remains the reaction residues that do not clean out.
For example, when using lighting apparatus 100 or in the insufficient electrolyte of lighting apparatus 100, it can be by lighting apparatus 100 filtering port 512 is placed upward, opens spiral cover 513, electrolyte is poured into filtering port 512, and the electrolyte poured into flows into electricity In pond reactive tank 51, after enough electrolyte is added, spiral cover 513 is screwed on, and lighting apparatus 100 is used by normal place. When without using lighting apparatus 100, spiral cover 513 is opened, the electrolyte in cell reaction slot 51 is poured out, and clean cell reaction Slot 51 can observe whether cell reaction slot 51 cleans up, in cleaning completion during cleaning by filtering port 512 After screw on spiral cover 513.
Further, 2 and Figure 13, lighting apparatus 100 include referring to Fig.1:Partition board 514, partition board 514 are located at cell reaction slot Cell reaction slot 51 is separated into two sub- reactive tanks 511 spaced apart from each other in 51, gold is equipped in every sub- reactive tank 511 Belong to electrode 52 and air electrode 54.Can cell reaction slot 51 be easily separated into two by the partition board of setting 514 as a result, Sub- reactive tank 511, every sub- reactive tank 511 are equivalent to a batteries, and two sub- reactive tanks 511 are connected with circuit board assemblies 2, Two sub- reactive tanks 511 can connect.
Further, filtering port 512 is located at the intersection of the side wall and partition board 514 of cell reaction slot 51, on partition board 514 with 512 corresponding position of filtering port is equipped with notch 5141, and notch 5141 is suitable for two sub- reactive tanks 511 of connection, is set at notch 5141 There is sealing sprue 5142 to separate two sub- reactive tanks 511 by sealing sprue 5142 when lighting apparatus 100 works.By This, two sub- cell reaction slots 51 can share a filtering port 512, can be conveniently realized simultaneously by the filtering port 512 It is added or is poured out electrolyte to two sub- reactive tanks 511, the structure of lighting apparatus 100 is simplified and facilitates lighting apparatus 100 use.
Specifically, when adding or pouring out electrolyte, sealing sprue 5142 can be removed from notch 5141, thus When pouring into electrolyte to filtering port 512, electrolyte can be separately flowed into two sub- reactive tanks 511 by the notch 5141; When needing to pour out electrolyte, the electrolyte in two sub- reactive tanks 511 can flow to filtering port by the notch 5141 512, so as to which the electrolyte in two sub- reactive tanks 511 is discharged simultaneously by a filtering port 512.
Optionally, above-mentioned notch 5141 can be arc-shaped, and the part that sealing sprue 5142 coordinates with notch 5141 can be in It is spherical, it is possible thereby to play good sealing function.
It in other embodiments of the invention, can also be by the way that multiple partition boards 514 be arranged to separate cell reaction slot 51 At three or three or more sub- reactive tanks 511.Certainly, above-mentioned partition board 514 can not also be set in cell reaction slot 51, this When cell reaction slot 51 in setting a pair of metal electrodes 52 and air electrode 54.
According to some embodiments of the present invention, with reference to Fig. 2, Fig. 3 and Figure 11, the side wall of cell reaction slot 51 is equipped with exhaust Hole 5151, the top setting of 5151 adjacent cells reactive tank 51 of gas vent.Gas vent 5151 is located at cell reaction slot 51 as a result, Higher position, be less prone to the phenomenon of leakage.
Optionally, with reference to Fig. 2, Fig. 3 and Figure 11, the cross section of cell reaction slot 51 can be rectangular, cell reaction slot 51 Side wall be equipped with filtering port 512, gas vent 5151 and filtering port 512 are located on the same side wall of cell reaction slot 51.As a result, Facilitate and electrolyte is added into cell reaction slot 51 or pours out 51 electrolyte inside of cell reaction slot, prevents in the operating process There is leakage.For example, when gas vent 5151 is located at filtering port 512 on the same side wall of cell reaction slot 51, gas vent 5151 The top of the side wall can be located at, be thus conducive to the gas that cell reaction slot 51 generates and pass through 5151 row of the gas vent in time Go out.It is understood that when gas vent 5151 is arranged in the vertex of cell reaction slot 51, cell reaction slot 51 with the top Gas near the adjacent two side walls in angle can rapidly be discharged from the gas vent 5151.
Optionally, with reference to Fig. 2, Fig. 3 and Figure 11, the top of cell reaction slot 51 is equipped with the lug 515 upwardly extended, exhaust Hole 5151 is formed on lug 515.Thus, it is possible to easily gas vent 5151 is arranged in higher position, it can be preferably Avoid the occurrence of the phenomenon of leakage.For example, the lug 515 can extend upwardly to the comparable position of the height of circuit board assemblies 2, this is convex Ear 515 can be formed to have the hollow structure of accommodating chamber, the bottom-open of the lug 515 and with the inside of cell reaction slot 51 Connection, the gas thus generated in cell reaction slot 51 can be discharged by the gas vent 5151 on the lug 515.
Optionally, with reference to Fig. 3, the cross section of gas vent 5151 gradually increases on direction from inside to outside, such as is vented Hole 5151 can be in horn-like.Thus, it is possible to so that by the gas vent 5151 be discharged gas rapid cooling, the row of avoiding the occurrence of Temperature is excessively high and hot at stomata 5151.
Lighting apparatus 100 according to an embodiment of the invention is described in detail referring to Fig. 2-Figure 13.In the present embodiment In, lighting apparatus 100 can be lantern.
With reference to Fig. 2-Figure 13, in the present embodiment, lighting apparatus 100 include above-mentioned lighting device 1, circuit board assemblies 2, Metal fuel battery 5, lighting device 1, circuit board assemblies 2 and metal fuel battery 5 are set gradually from top to bottom, circuit board assemblies 2 outside mask is equipped with middle cover 23, and lighting apparatus 100 further includes handle 4, and handle 4 is rotatably arranged on middle cover 23.Wherein, it shines Bright device 1 includes luminescent device (such as lamp bead), even light shield 11, reflector 12 and protective cover 13, and even light shield 11 is located at luminous Device is outer with light is evenly dispersed, and protective cover 13 is located at outside even light shield 11, and protective cover 13 is transparent, and protective cover 13 can be with It plays a protective role, while for extraneous illumination, reflector 12 is located at the lower end in protective cover 13 and positioned at luminescent device, instead Light shield 12 is used to adjust the angle of light, to make light send out.
Metal fuel battery 5 includes above-mentioned cell reaction slot 51, metal electrode 52, air electrode 54 and electrolyte, electricity Pond reactive tank 51 may include groove body 51a and be located at the ventilating cover 51b of the opposite sides of groove body 51a, is formed on ventilating cover 51b The groove body 51a of lattice-like ground air hole, cell reaction slot 51 is insulation shell.Aforementioned barriers 514 are set in cell reaction slot 51 To be divided into two sub- reactive tanks 511,514 setting direction of partition board and ventilating cover 51b are substantially parallel.Every sub- reactive tank Above-mentioned metal electrode 52 and air electrode 54 are respectively provided in 511, each air electrode 54 is arranged adjacent to ventilating cover 51b, metal The part that the top of electrode 52 is extended as above-mentioned conduct piece 521, i.e., metal electrode 52 and 521 one of conduct piece at Type, conduct piece 521 are mounted on by above-mentioned connector 53 on the cover board 55 of cell reaction slot 51, and connector 53 is to be moulded in gold Belong to the moulding on electrode 52, metal electrode 52 is connected by above-mentioned metal buckle 6 with circuit board assemblies 2, metal electrode 52 It is spaced with the bottom wall of cell reaction slot 51, is thus conducive to deslagging and facilitates the assembly of metal electrode 52.
Circuit board assemblies 2 include the circuit board 22 of substrate 21 and setting on the base plate (21, and substrate 21 is equipped with for installing There is installation cavity, metal buckle 6 to be contained in the installation cavity for the mounting portion 211 of fixed metal buckle 6, mounting portion 211, while can Metal buckle 6 to be securely fixed on mounting portion 211 by fasteners such as screws.
Wherein, lighting device 1, circuit board assemblies 2 and middle cover 23 can connect into an entirety, and opposite the two of middle cover 23 End is respectively set pivotal axis 231 and breaks the first clamping portion 31 of button 3, the opposite end difference of the groove body 51a of cell reaction slot 51 The second clamping portion 32 that pivoting hole 516 breaks button 3 with this is set, the pivot on the pivotal axis 231 and groove body 51a on middle cover 23 is passed through Button is broken in the cooperation in hole 516 and the first clamping portion 31 on middle cover 23 with what the second clamping portion 32 on groove body 51a collectively formed 3 structures so that the assembling and use of lighting apparatus 100 have larger advantage, while conducive to the maintenance of lighting apparatus 100.Example Such as, when needing replacing metal electrode 52, can by it is above-mentioned break button 3 open, and rotate lighting device 1, circuit board assemblies 2 and The entirety that middle cover 23 is constituted, the conduct piece 521 of metal electrode 52 is removed from metal buckle 6, then by metal electrode 52 and connector 53 take out out of cell reaction slot 51, then by the new installation of metal electrode 52 for being molded with connector 53 to battery In reactive tank 51, the entirety that rotation lighting device 1, circuit board assemblies 2 and middle cover 23 are constituted will break button after rotateing in place 3 the first clamping portion 31 is connected on the second clamping portion 32 for breaking button 3, so as to complete the replacement of metal electrode 52, user Just.
One side wall of cell reaction slot 51 is equipped with above-mentioned filtering port 512, and filtering port 512 is located at cell reaction slot 51 The intersection of side wall and partition board 514, partition board 514 are equipped with above-mentioned notch 5141 and seal the sealing sprue of the notch 5141 5142.The side wall opposite with the filtering port 512 of cell reaction slot 51 is equipped with false filtering port, ensures the symmetry of appearance.Institute It states and is covered with above-mentioned spiral cover 513 at " false filtering port ", it is consistent with filtering port 512 from the appearance, but side wall herein does not have trepanning.
The cross section of cell reaction slot 51 is rectangular, and the top of cell reaction slot 51 is equipped with above-mentioned lug 515 and the lug 515 are located near the apex angle of cell reaction slot 51, and gas vent 5151 is located on the lug 515, and gas vent 5151 is two and is in It is horn-like.Gas vent 5151 and above-mentioned filtering port 512 are located on the same side wall of cell reaction slot 51, thus facilitate add or Electrolyte is poured out, prevents from adding or pour out electrolyte and the phenomenon of leakage occurs.
Lighting apparatus 100 in the embodiment of the present invention has the output power of 0-4W, output power and metal electrode 52 Soak time has relationship, and in a certain range, output power increases with the increase of soak time, when the substance that reaction generates When excessive, increase that output power can be at any time and become smaller, while prompting user that should replace electrolyte (general electrolysis every time Liquid usage time is no more than 6.5h).
In the description of this specification, reference term " one embodiment ", " some embodiments ", " illustrative examples ", The description of " example ", " specific example " or " some examples " etc. means specific features described in conjunction with this embodiment or example, knot Structure, material or feature are included at least one embodiment or example of the invention.In the present specification, to above-mentioned term Schematic representation may not refer to the same embodiment or example.Moreover, specific features, structure, material or the spy of description Point can be combined in any suitable manner in any one or more of the embodiments or examples.
Although an embodiment of the present invention has been shown and described, it will be understood by those skilled in the art that:Not In the case of being detached from the principle of the present invention and objective a variety of change, modification, replacement and modification can be carried out to these embodiments, this The range of invention is limited by claim and its equivalent.

Claims (14)

1. a kind of lighting apparatus, which is characterized in that including:
Lighting device;
Circuit board assemblies, the circuit board assemblies are connected with the lighting device;
Metal fuel battery, the metal fuel battery are connected with the circuit board assemblies, and the metal fuel battery includes electricity The top of pond reactive tank, metal electrode, air electrode and electrolyte, the cell reaction slot has cover board, the metal electrode It is equipped with the conduct piece for being suitable for being connected with the circuit board assemblies, the conduct piece is located at the cover board far from the cell reaction The side of slot.
2. lighting apparatus according to claim 1, which is characterized in that the conduct piece and the metal electrode one at Type.
3. lighting apparatus according to claim 1, which is characterized in that including:Connection for installing the metal electrode Part, the metal fuel battery are located at the lower section of the circuit board assemblies, and the connector is located on the metal electrode, described The periphery wall of connector has the first mounting surface, and first mounting surface from bottom to top and is inclined outwardly extension, on the cover board It is formed with the mounting hole suitable for installing the connector, the internal perisporium of the mounting hole has to be coordinated with first mounting surface Second mounting surface, second mounting surface from bottom to top and are inclined outwardly extension.
4. lighting apparatus according to claim 3, which is characterized in that the connector is to be moulded on the metal electrode Moulding.
5. lighting apparatus according to claim 3, which is characterized in that first mounting surface and second mounting surface it Between be equipped with sealing element.
6. lighting apparatus according to claim 1, which is characterized in that the conduct piece passes through gold with the circuit board assemblies Belong to buckle to be connected, the metal buckle is located on the circuit board assemblies, and the metal buckle includes:Buckle ontology and difference It is located at the first shrapnel and the second shrapnel of the buckle ontology opposite end, the conduct piece is fastened on first shrapnel and institute It states in space defined by the second shrapnel, and the conduct piece is contacted with first shrapnel, second shrapnel.
7. lighting apparatus according to claim 1, which is characterized in that one end of the lighting device and the metal fuel Battery is rotatably coupled, and the other end of the lighting device is connect with the metal fuel battery by breaking buckle.
8. according to the lighting apparatus described in any one of claim 1-7, which is characterized in that on the side wall of the cell reaction slot Equipped with filtering port, the filtering port is arranged adjacent to the bottom of the cell reaction slot, and the filtering port upper cover is equipped with spiral cover.
9. lighting apparatus according to claim 8, which is characterized in that including:Partition board, it is anti-that the partition board is located at the battery It answers in slot so that the cell reaction slot is separated into two sub- reactive tanks spaced apart from each other, is equipped in each sub- reactive tank The metal electrode and the air electrode.
10. lighting apparatus according to claim 9, which is characterized in that the filtering port is located at the cell reaction slot The intersection of side wall and the partition board, position corresponding with the filtering port is equipped with notch on the partition board, and the notch is suitable for Two sub- reactive tanks are connected to, the indentation, there is equipped with sealing sprue to pass through the sealing when the lighting apparatus works Sprue separates two sub- reactive tanks.
11. according to the lighting apparatus described in any one of claim 1-7, which is characterized in that the side wall of the cell reaction slot It is equipped with gas vent, the gas vent is arranged adjacent to the top of the cell reaction slot.
12. lighting apparatus according to claim 11, which is characterized in that the cross section of the cell reaction slot is rectangular, The side wall of the cell reaction slot is equipped with filtering port, and the gas vent is located at the same of the cell reaction slot with the filtering port In one side wall.
13. lighting apparatus according to claim 11, which is characterized in that the top of the cell reaction slot is equipped with prolongs upwards The lug stretched, the gas vent are formed on the lug.
14. lighting apparatus according to claim 11, which is characterized in that the cross section of the gas vent is from inside to outside Gradually increase on direction.
CN201711406528.9A 2017-12-22 2017-12-22 Lighting apparatus Pending CN108306080A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201711406528.9A CN108306080A (en) 2017-12-22 2017-12-22 Lighting apparatus

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Application Number Priority Date Filing Date Title
CN201711406528.9A CN108306080A (en) 2017-12-22 2017-12-22 Lighting apparatus

Publications (1)

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CN108306080A true CN108306080A (en) 2018-07-20

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Country Link
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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101715609A (en) * 2007-06-26 2010-05-26 科尔曼公司 Electrical appliance that utilizes multiple power sources
CN202042547U (en) * 2011-04-20 2011-11-16 西安蝶能电子科技有限公司 Illuminating terminal of rechargeable battery
CN202074266U (en) * 2011-04-06 2011-12-14 骐宏科技有限公司 Lighting equipment
CN104051769A (en) * 2014-06-16 2014-09-17 弗尔赛(上海)能源科技有限公司 Portable fuel cell power supply equipment
CN104676424A (en) * 2015-01-27 2015-06-03 华南理工大学 LED lighting system based on passive direct methanol fuel cells
CN204885371U (en) * 2015-07-31 2015-12-16 光钰科技(临沂)有限公司 Displaceable metal air fuel cell and series connection module and lighting device thereof
JP2016072018A (en) * 2014-09-29 2016-05-09 株式会社エムグロー Electrical lighting device
JP2017021987A (en) * 2015-07-10 2017-01-26 株式会社エムグロー Lamp device
CN206656181U (en) * 2017-04-01 2017-11-21 东莞市蓝极能源有限公司 A kind of salt solution generating light

Patent Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101715609A (en) * 2007-06-26 2010-05-26 科尔曼公司 Electrical appliance that utilizes multiple power sources
CN202074266U (en) * 2011-04-06 2011-12-14 骐宏科技有限公司 Lighting equipment
CN202042547U (en) * 2011-04-20 2011-11-16 西安蝶能电子科技有限公司 Illuminating terminal of rechargeable battery
CN104051769A (en) * 2014-06-16 2014-09-17 弗尔赛(上海)能源科技有限公司 Portable fuel cell power supply equipment
JP2016072018A (en) * 2014-09-29 2016-05-09 株式会社エムグロー Electrical lighting device
CN104676424A (en) * 2015-01-27 2015-06-03 华南理工大学 LED lighting system based on passive direct methanol fuel cells
JP2017021987A (en) * 2015-07-10 2017-01-26 株式会社エムグロー Lamp device
CN204885371U (en) * 2015-07-31 2015-12-16 光钰科技(临沂)有限公司 Displaceable metal air fuel cell and series connection module and lighting device thereof
CN206656181U (en) * 2017-04-01 2017-11-21 东莞市蓝极能源有限公司 A kind of salt solution generating light

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