CN108300020A - A kind of electric-heating coatings - Google Patents

A kind of electric-heating coatings Download PDF

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Publication number
CN108300020A
CN108300020A CN201610456534.4A CN201610456534A CN108300020A CN 108300020 A CN108300020 A CN 108300020A CN 201610456534 A CN201610456534 A CN 201610456534A CN 108300020 A CN108300020 A CN 108300020A
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CN
China
Prior art keywords
parts
electric
heating
heating coatings
film forming
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610456534.4A
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Chinese (zh)
Inventor
王庆华
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Tianjin Dongta Coating Co Ltd
Original Assignee
Tianjin Dongta Coating Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Tianjin Dongta Coating Co Ltd filed Critical Tianjin Dongta Coating Co Ltd
Priority to CN201610456534.4A priority Critical patent/CN108300020A/en
Publication of CN108300020A publication Critical patent/CN108300020A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/02Elements
    • C08K3/08Metals
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K9/00Use of pretreated ingredients
    • C08K9/10Encapsulated ingredients
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D163/00Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D175/00Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
    • C09D175/04Polyurethanes
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/02Elements
    • C08K3/08Metals
    • C08K2003/085Copper
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/02Elements
    • C08K3/08Metals
    • C08K2003/0862Nickel

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Paints Or Removers (AREA)

Abstract

The invention discloses a kind of electric-heating coatings, it is related to can be used for the coating of the indoor and outdoor heating service of building, it is coated on indoor wall, at the sentry post on desk, outdoor, heating service can be realized in voltage safe to use, by the control of resistivity, meet different heating requirements, 5 DEG C~20 DEG C of performance higher than environment temperature can be reached, for this purpose, the present invention also provides the processing methods of electric-heating coatings.It is to be achieved by following technical proposals:It includes following weight parts material:40 parts ~ 60 parts of film forming matter, 15 parts ~ 30 parts of color stuffing, 1 part ~ 2 parts of auxiliary agent, 20 parts ~ 30 parts of solvent, above-mentioned substance is put into ball mill in proportion, is adequately mixed, is ground, and the coating of 30 μm ~ 60 μm of fineness range, as electric-heating coatings is made.

Description

A kind of electric-heating coatings
Technical field
The present invention relates to the coating that the present invention relates to the indoor and outdoor heating service that can be used for building, can be made into Electric heating table, electric heater and industrial middle low-temperature bake electric furnace, specially electric-heating coatings.
Background technology
Several electric-heating coatings patents are disclosed currently on the market(Publication number CN1068582, CN1112592), they are mainly using carbon dust and graphite as filler, the problem is that the resistance of these electric-heating coatings is all at tens ohm or more, if further increasing conductive filler content resistance, then the adhesive force of coating is deteriorated, and heating efficiency is relatively low in actual use, needs higher voltage(Higher than 36 volt-amperes full voltages), it is unfavorable for practical application.
Invention content
Regarding to the issue above, the present invention provides a kind of electric-heating coatings, it is coated on indoor wall, at the sentry post on desk, outdoor, heating service can be realized in voltage safe to use, by the control of resistivity, meet different heating requirements, 5 DEG C~20 DEG C of performance higher than environment temperature can be reached, for this purpose, the present invention also provides the processing methods of electric-heating coatings.
Its technical solution is such:It includes following weight parts material:40 parts ~ 60 parts of film forming matter, 15 parts ~ 30 parts of color stuffing, 1 part ~ 2 parts of auxiliary agent, 20 parts ~ 30 parts of solvent, above-mentioned substance is put into ball mill in proportion, is adequately mixed, is ground, and the coating of 30 μm ~ 60 μm of fineness range is made.
The film forming matter is acrylic resin, epoxy resin or polyurethane resin;
The color stuffing is 10%~30% silver medal containing weight percentage including 5 parts~15 parts Ni powder, 10 parts~20 parts silver-coated copper powders;
The auxiliary agent includes adhesion promoter Silok629, and content accounts for film forming matter 0.5%~1% and dispersant Efka4010, and content accounts for pigment 0.5%~1%;
It is described that different solvents, including polystyrene, toluene, butyl acetate, cyclohexanone etc. are selected according to different film forming matters;
The corresponding diluent of the acrylic resin include following volumes than material:Butyl acetate 20:Dimethylbenzene 60:Cyclohexanone 20;
The corresponding diluent of the epoxy resin include following volumes than material :Butyl acetate 40:Butanone 40:Cyclohexanone 20;
The corresponding diluent of the polyurethane resin include following volumes than material:Butyl acetate 25:Dimethylbenzene 60:Cyclohexanone 15.
Select wicker copper as conductive filler, it improves the electric conductivity of copper powder, reduces the cost of silver powder, and solves the problems, such as that copper powder is oxidized easily, therefore coating can be made to reach lower resistivity(Electrical resistivity range:M~1 0.1 × 10-4 Ω × 10-4 Ω m), and suitable for engineering production.Prepared electric-heating coatings ensure that coating can be coated in different substrates, while crossing the preferred of adjuvant system and solving the problems, such as coating adhesion well by different film forming matters.Since conductivity is relatively low and can adjust, different resistance can be reached by the adjustment of different length and widths, thickness.Such as in 20cm × 30cm, thickness 0.15mm Coating resistance can reach 1~5 Ω, therefore in safe voltage(36 volts)There is down good heating effect.
Specific implementation mode
Embodiment 1
The present invention includes following weight parts material:40 parts of film forming matter, 22.5 parts of color stuffing, 1 part of auxiliary agent, 25 parts of solvent, above-mentioned substance is put into ball mill in proportion, is adequately mixed, is ground, and the coating of 45 μm of fineness range is made.Film forming matter is acrylic resin, epoxy resin or polyurethane resin;Color stuffing includes 5 parts of Ni powder, 20 parts of silver-coated copper powders, wherein being 20% silver medal containing weight percentage;Auxiliary agent includes adhesion promoter Silok629, and content accounts for film forming matter 0.75% and dispersant Efka4010, and content accounts for pigment 0.75%;The corresponding diluent of acrylic resin include following volumes than material:Butyl acetate 20:Dimethylbenzene 60:Cyclohexanone 20;The corresponding diluent of epoxy resin include following volumes than material:Butyl acetate 40:Butanone 40:Cyclohexanone 20;The corresponding diluent of polyurethane resin include following volumes than material:Butyl acetate 25:Dimethylbenzene 60:Cyclohexanone 15.
Embodiment 2
The present invention includes following weight parts material:60 parts of film forming matter, 30 parts of color stuffing, 2 parts of auxiliary agent, 30 parts of solvent, above-mentioned substance is put into ball mill in proportion, is adequately mixed, is ground, and the coating of 30 μm of fineness range is made.
Film forming matter is acrylic resin, epoxy resin or polyurethane resin;Color stuffing includes 15 parts of Ni powder, 10 parts of silver-coated copper powders, wherein being 30% silver medal containing weight percentage;Auxiliary agent includes adhesion promoter Silok629, and content accounts for film forming matter 1% and dispersant Efka4010, and content accounts for pigment 0. 5%;The corresponding diluent of acrylic resin include following volumes than material:Butyl acetate 20:Dimethylbenzene 60:Cyclohexanone 20;The corresponding diluent of epoxy resin include following volumes than material:Butyl acetate 40:Butanone 40:Cyclohexanone 20;The corresponding diluent of polyurethane resin include following volumes than material:Butyl acetate 25:Dimethylbenzene 60:Cyclohexanone 15.
Embodiment 3
The present invention includes following weight parts material:50 parts of film forming matter, 15 parts of color stuffing, 1.5 parts of auxiliary agent, 20 parts of solvent, above-mentioned substance is put into ball mill in proportion, is adequately mixed, is ground, and the coating of 60 μm of fineness range is made.
Film forming matter is acrylic resin, epoxy resin or polyurethane resin;Color stuffing includes 10 parts of Ni powder, 15 parts of silver-coated copper powders, wherein being 10% silver medal containing weight percentage;Auxiliary agent includes adhesion promoter Silok629, and content accounts for film forming matter 0.5% and dispersant Efka4010, and content accounts for pigment 1%;The corresponding diluent of acrylic resin include following volumes than material:Butyl acetate 20:Dimethylbenzene 60:Cyclohexanone 20;The corresponding diluent of epoxy resin include following volumes than material:Butyl acetate 40:Butanone 40:Cyclohexanone 20;The corresponding diluent of polyurethane resin include following volumes than material:Butyl acetate 25:Dimethylbenzene 60:Cyclohexanone 15.
What is finally illustrated is, the above examples are only used to illustrate the technical scheme of the present invention and are not limiting, although being described the invention in detail with reference to preferred embodiment, it will be understood by those of ordinary skill in the art that, technical scheme of the present invention can be modified or replaced equivalently, without departing from the objective and range of technical solution of the present invention, it is intended to be within the scope of the claims of the invention.

Claims (7)

1. a kind of electric-heating coatings, it is characterised in that:It includes following weight parts material :40 parts ~ 60 parts of film forming matter, 15 parts ~ 30 parts of color stuffing, 1 part ~ 2 parts of auxiliary agent, 20 parts ~ 30 parts of solvent, above-mentioned substance is put into ball mill in proportion, is adequately mixed, is ground, and the coating of 30 μm ~ 60 μm of fineness range is made.
2. electric-heating coatings according to claim 1, it is characterised in that:The film forming matter is acrylic resin, epoxy resin or polyurethane resin.
3. according to the electric-heating coatings of claim 1 or 2, it is characterised in that:The color stuffing is 10%~30% silver medal containing weight percentage including 5 parts~15 parts Ni powder, 10 parts~20 parts silver-coated copper powders.
4. according to the electric-heating coatings of claim 1 or 2, it is characterised in that:The auxiliary agent includes adhesion promoter Silok629, and content accounts for film forming matter 0.5%~1% and dispersant Efka4010, and content accounts for pigment 0.5%~1%.
5. according to the electric-heating coatings of claim 1 or 2, it is characterised in that:The corresponding diluent of the acrylic resin include following volumes than material:Butyl acetate 20:Dimethylbenzene 60:Cyclohexanone 20.
6. according to the electric-heating coatings of claim 1 or 2, it is characterised in that:The corresponding diluent of the epoxy resin include following volumes than material :Butyl acetate 40:Butanone 40:Cyclohexanone 20.
7. according to the electric-heating coatings of claim 1 or 2, it is characterised in that:The corresponding diluent of the polyurethane resin include following volumes than material:Butyl acetate 25:Dimethylbenzene 60:Cyclohexanone 15.
CN201610456534.4A 2016-06-23 2016-06-23 A kind of electric-heating coatings Pending CN108300020A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610456534.4A CN108300020A (en) 2016-06-23 2016-06-23 A kind of electric-heating coatings

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610456534.4A CN108300020A (en) 2016-06-23 2016-06-23 A kind of electric-heating coatings

Publications (1)

Publication Number Publication Date
CN108300020A true CN108300020A (en) 2018-07-20

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Family Applications (1)

Application Number Title Priority Date Filing Date
CN201610456534.4A Pending CN108300020A (en) 2016-06-23 2016-06-23 A kind of electric-heating coatings

Country Status (1)

Country Link
CN (1) CN108300020A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110551435A (en) * 2019-07-26 2019-12-10 罗苗苗 preparation method of composite carbon-based electric heating coating

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110551435A (en) * 2019-07-26 2019-12-10 罗苗苗 preparation method of composite carbon-based electric heating coating

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Application publication date: 20180720

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