CN108298533A - A method of preparing graphene oxide solution - Google Patents
A method of preparing graphene oxide solution Download PDFInfo
- Publication number
- CN108298533A CN108298533A CN201810344209.8A CN201810344209A CN108298533A CN 108298533 A CN108298533 A CN 108298533A CN 201810344209 A CN201810344209 A CN 201810344209A CN 108298533 A CN108298533 A CN 108298533A
- Authority
- CN
- China
- Prior art keywords
- water
- graphene oxide
- added
- slowly added
- stirring
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2204/00—Structure or properties of graphene
- C01B2204/20—Graphene characterized by its properties
- C01B2204/22—Electronic properties
Landscapes
- Carbon And Carbon Compounds (AREA)
- Battery Electrode And Active Subsutance (AREA)
Abstract
A method of graphene oxide solution is prepared, including：Step 1:At room temperature, the salpeter solution of the concentrated sulfuric acid of 70mL98wt% and 5ml25wt% are mixed, is then slowly added to 3.0g graphite powders while stirring, is added followed by 1.5g sodium nitrate and 1.1g niter cakes；Step 2:This mixture is moved into cooling in ice bath, under violent stirring, is slowly added into 9.0g potassium permanganate and 1g potassium nitrate.
Description
Technical field
The present invention relates to a kind of methods preparing graphene oxide solution.
Background technology
The method flow in the prior art for preparing graphene oxide solution is complicated, low precision, not environmentally.
Invention content
A method of graphene oxide solution is prepared, including：
Step 1:At room temperature, the salpeter solution of the concentrated sulfuric acid of 70mL98wt% and 5ml25wt% are mixed, is then delayed while stirring
It is slow that 3.0g graphite powders are added, it is added followed by 1.5g sodium nitrate and 1.1g niter cakes；
Step 2:This mixture is moved into cooling in ice bath, under violent stirring, is slowly added into 9.0g potassium permanganate and 1g
Potassium nitrate;
Step 3:After charging, reaction system is transferred in 40 °C of water-baths, constant temperature stirring is reacted 30 minutes;
Step 4:150mL deionized waters are slowly added to, and water-bath is warming up to 90 °C, are reacted 15 minutes;
Step 5:500mL water is added, the hydrogen peroxide of 15mL30wt% is slowly added to;
Step 6:The mixture of gained filter and washed with the dilute hydrochloric acid of 250mL3.5wt% to remove metal ion,
It is washed with 200mL deionized waters again to remove the acid of remaining;
Step 7:It is diluted in input deionized water after solid filter cake is dried in air, graphite oxide is obtained by being ultrasonically treated
Alkene dispersion liquid;
Step 8:This dispersion liquid is fitted into and is dialysed in bag filter to remove the acid and metal ion of remaining, is changed daily primary
Water is dialysed seven days;
Step 9:Graphene oxide dispersion after dialysis is taken out and is centrifuged under the conditions of 4000 rpms, discards lower layer not
The graphite powder of oxidation or non-complete oxidation collects upper solution.
The graphene oxide solution of the present invention can be applied to field of cell preparation.
Inventive point is：1）Complete reaction process；2）Material used；3）Concrete component.
Specific implementation mode
Embodiment 1
A method of graphene oxide solution is prepared, including：
Step 1:At room temperature, the salpeter solution of the concentrated sulfuric acid of 70mL98wt% and 5ml25wt% are mixed, is then delayed while stirring
It is slow that 3.0g graphite powders are added, it is added followed by 1.5g sodium nitrate and 1.1g niter cakes；
Step 2:This mixture is moved into cooling in ice bath, under violent stirring, is slowly added into 9.0g potassium permanganate and 1g
Potassium nitrate;
Step 3:After charging, reaction system is transferred in 40 °C of water-baths, constant temperature stirring is reacted 30 minutes;
Step 4:150mL deionized waters are slowly added to, and water-bath is warming up to 90 °C, are reacted 15 minutes;
Step 5:500mL water is added, the hydrogen peroxide of 15mL30wt% is slowly added to;
Step 6:The mixture of gained filter and washed with the dilute hydrochloric acid of 250mL3.5wt% to remove metal ion,
It is washed with 200mL deionized waters again to remove the acid of remaining;
Step 7:It is diluted in input deionized water after solid filter cake is dried in air, graphite oxide is obtained by being ultrasonically treated
Alkene dispersion liquid;
Step 8:This dispersion liquid is fitted into and is dialysed in bag filter to remove the acid and metal ion of remaining, is changed daily primary
Water is dialysed seven days;
Step 9:Graphene oxide dispersion after dialysis is taken out and is centrifuged under the conditions of 4000 rpms, discards lower layer not
The graphite powder of oxidation or non-complete oxidation collects upper solution.
The graphene oxide solution of the present invention can be applied to field of cell preparation.
Embodiment 2
A method of graphene oxide solution is prepared, including：
Step 1:At room temperature, the salpeter solution of the concentrated sulfuric acid of 70mL98wt% and 5ml25wt% are mixed, is then delayed while stirring
It is slow that 3.0g graphite powders are added, it is added followed by 1.5g sodium nitrate and 1.2g niter cakes；
Step 2:This mixture is moved into cooling in ice bath, under violent stirring, is slowly added into 9.0g potassium permanganate and 1g
Potassium nitrate;
Step 3:After charging, reaction system is transferred in 40 °C of water-baths, constant temperature stirring is reacted 30 minutes;
Step 4:150mL deionized waters are slowly added to, and water-bath is warming up to 90 °C, are reacted 15 minutes;
Step 5:500mL water is added, the hydrogen peroxide of 15mL30wt% is slowly added to;
Step 6:The mixture of gained filter and washed with the dilute hydrochloric acid of 250mL3.5wt% to remove metal ion,
It is washed with 200mL deionized waters again to remove the acid of remaining;
Step 7:It is diluted in input deionized water after solid filter cake is dried in air, graphite oxide is obtained by being ultrasonically treated
Alkene dispersion liquid;
Step 8:This dispersion liquid is fitted into and is dialysed in bag filter to remove the acid and metal ion of remaining, is changed daily primary
Water is dialysed seven days;
Step 9:Graphene oxide dispersion after dialysis is taken out and is centrifuged under the conditions of 4000 rpms, discards lower layer not
The graphite powder of oxidation or non-complete oxidation collects upper solution.
The graphene oxide solution of the present invention can be applied to field of cell preparation.
Embodiment 3
A method of graphene oxide solution is prepared, including：
Step 1:At room temperature, the salpeter solution of the concentrated sulfuric acid of 70mL98wt% and 5ml25wt% are mixed, is then delayed while stirring
It is slow that 3.0g graphite powders are added, it is added followed by 1.5g sodium nitrate and 1.3g niter cakes；
Step 2:This mixture is moved into cooling in ice bath, under violent stirring, is slowly added into 9.0g potassium permanganate and 1g
Potassium nitrate;
Step 3:After charging, reaction system is transferred in 40 °C of water-baths, constant temperature stirring is reacted 30 minutes;
Step 4:150mL deionized waters are slowly added to, and water-bath is warming up to 90 °C, are reacted 15 minutes;
Step 5:500mL water is added, the hydrogen peroxide of 15mL30wt% is slowly added to;
Step 6:The mixture of gained filter and washed with the dilute hydrochloric acid of 250mL3.5wt% to remove metal ion,
It is washed with 200mL deionized waters again to remove the acid of remaining;
Step 7:It is diluted in input deionized water after solid filter cake is dried in air, graphite oxide is obtained by being ultrasonically treated
Alkene dispersion liquid;
Step 8:This dispersion liquid is fitted into and is dialysed in bag filter to remove the acid and metal ion of remaining, is changed daily primary
Water is dialysed seven days;
Step 9:Graphene oxide dispersion after dialysis is taken out and is centrifuged under the conditions of 4000 rpms, discards lower layer not
The graphite powder of oxidation or non-complete oxidation collects upper solution.
The graphene oxide solution of the present invention can be applied to field of cell preparation.
Embodiment 4
A method of graphene oxide solution is prepared, including：
Step 1:At room temperature, the salpeter solution of the concentrated sulfuric acid of 70mL98wt% and 5ml25wt% are mixed, is then delayed while stirring
It is slow that 3.0g graphite powders are added, it is added followed by 1.5g sodium nitrate and 1.4g niter cakes；
Step 2:This mixture is moved into cooling in ice bath, under violent stirring, is slowly added into 9.0g potassium permanganate and 1g
Potassium nitrate;
Step 3:After charging, reaction system is transferred in 40 °C of water-baths, constant temperature stirring is reacted 30 minutes;
Step 4:150mL deionized waters are slowly added to, and water-bath is warming up to 90 °C, are reacted 15 minutes;
Step 5:500mL water is added, the hydrogen peroxide of 15mL30wt% is slowly added to;
Step 6:The mixture of gained filter and washed with the dilute hydrochloric acid of 250mL3.5wt% to remove metal ion,
It is washed with 200mL deionized waters again to remove the acid of remaining;
Step 7:It is diluted in input deionized water after solid filter cake is dried in air, graphite oxide is obtained by being ultrasonically treated
Alkene dispersion liquid;
Step 8:This dispersion liquid is fitted into and is dialysed in bag filter to remove the acid and metal ion of remaining, is changed daily primary
Water is dialysed seven days;
Step 9:Graphene oxide dispersion after dialysis is taken out and is centrifuged under the conditions of 4000 rpms, discards lower layer not
The graphite powder of oxidation or non-complete oxidation collects upper solution.
The graphene oxide solution of the present invention can be applied to field of cell preparation.
Embodiment 5
A method of graphene oxide solution is prepared, including：
Step 1:At room temperature, the salpeter solution of the concentrated sulfuric acid of 70mL98wt% and 5ml25wt% are mixed, is then delayed while stirring
It is slow that 3.0g graphite powders are added, it is added followed by 1.5g sodium nitrate and 1.5g niter cakes；
Step 2:This mixture is moved into cooling in ice bath, under violent stirring, is slowly added into 9.0g potassium permanganate and 1g
Potassium nitrate;
Step 3:After charging, reaction system is transferred in 40 °C of water-baths, constant temperature stirring is reacted 30 minutes;
Step 4:150mL deionized waters are slowly added to, and water-bath is warming up to 90 °C, are reacted 15 minutes;
Step 5:500mL water is added, the hydrogen peroxide of 15mL30wt% is slowly added to;
Step 6:The mixture of gained filter and washed with the dilute hydrochloric acid of 250mL3.5wt% to remove metal ion,
It is washed with 200mL deionized waters again to remove the acid of remaining;
Step 7:It is diluted in input deionized water after solid filter cake is dried in air, graphite oxide is obtained by being ultrasonically treated
Alkene dispersion liquid;
Step 8:This dispersion liquid is fitted into and is dialysed in bag filter to remove the acid and metal ion of remaining, is changed daily primary
Water is dialysed seven days;
Step 9:Graphene oxide dispersion after dialysis is taken out and is centrifuged under the conditions of 4000 rpms, discards lower layer not
The graphite powder of oxidation or non-complete oxidation collects upper solution.
Embodiment 6
A method of graphene oxide solution is prepared, including：
Step 1:At room temperature, the salpeter solution of the concentrated sulfuric acid of 70mL98wt% and 5ml25wt% are mixed, is then delayed while stirring
It is slow that 3.0g graphite powders are added, it is added followed by 1.5g sodium nitrate and 1.6g niter cakes；
Step 2:This mixture is moved into cooling in ice bath, under violent stirring, is slowly added into 9.0g potassium permanganate and 1g
Potassium nitrate;
Step 3:After charging, reaction system is transferred in 40 °C of water-baths, constant temperature stirring is reacted 30 minutes;
Step 4:150mL deionized waters are slowly added to, and water-bath is warming up to 90 °C, are reacted 15 minutes;
Step 5:500mL water is added, the hydrogen peroxide of 15mL30wt% is slowly added to;
Step 6:The mixture of gained filter and washed with the dilute hydrochloric acid of 250mL3.5wt% to remove metal ion,
It is washed with 200mL deionized waters again to remove the acid of remaining;
Step 7:It is diluted in input deionized water after solid filter cake is dried in air, graphite oxide is obtained by being ultrasonically treated
Alkene dispersion liquid;
Step 8:This dispersion liquid is fitted into and is dialysed in bag filter to remove the acid and metal ion of remaining, is changed daily primary
Water is dialysed seven days;
Step 9:Graphene oxide dispersion after dialysis is taken out and is centrifuged under the conditions of 4000 rpms, discards lower layer not
The graphite powder of oxidation or non-complete oxidation collects upper solution.
The graphene oxide solution of the present invention can be applied to field of cell preparation.
Embodiment 7
A method of graphene oxide solution is prepared, including：
Step 1:At room temperature, the salpeter solution of the concentrated sulfuric acid of 70mL98wt% and 5ml25wt% are mixed, is then delayed while stirring
It is slow that 3.0g graphite powders are added, it is added followed by 1.5g sodium nitrate and 1.7g niter cakes；
Step 2:This mixture is moved into cooling in ice bath, under violent stirring, is slowly added into 9.0g potassium permanganate and 1g
Potassium nitrate;
Step 3:After charging, reaction system is transferred in 40 °C of water-baths, constant temperature stirring is reacted 30 minutes;
Step 4:150mL deionized waters are slowly added to, and water-bath is warming up to 90 °C, are reacted 15 minutes;
Step 5:500mL water is added, the hydrogen peroxide of 15mL30wt% is slowly added to;
Step 6:The mixture of gained filter and washed with the dilute hydrochloric acid of 250mL3.5wt% to remove metal ion,
It is washed with 200mL deionized waters again to remove the acid of remaining;
Step 7:It is diluted in input deionized water after solid filter cake is dried in air, graphite oxide is obtained by being ultrasonically treated
Alkene dispersion liquid;
Step 8:This dispersion liquid is fitted into and is dialysed in bag filter to remove the acid and metal ion of remaining, is changed daily primary
Water is dialysed seven days;
Step 9:Graphene oxide dispersion after dialysis is taken out and is centrifuged under the conditions of 4000 rpms, discards lower layer not
The graphite powder of oxidation or non-complete oxidation collects upper solution.
The graphene oxide solution of the present invention can be applied to field of cell preparation.
Embodiment 8
A method of graphene oxide solution is prepared, including：
Step 1:At room temperature, the salpeter solution of the concentrated sulfuric acid of 70mL98wt% and 5ml25wt% are mixed, is then delayed while stirring
It is slow that 3.0g graphite powders are added, it is added followed by 1.5g sodium nitrate and 1.8g niter cakes；
Step 2:This mixture is moved into cooling in ice bath, under violent stirring, is slowly added into 9.0g potassium permanganate and 1g
Potassium nitrate;
Step 3:After charging, reaction system is transferred in 40 °C of water-baths, constant temperature stirring is reacted 30 minutes;
Step 4:150mL deionized waters are slowly added to, and water-bath is warming up to 90 °C, are reacted 15 minutes;
Step 5:500mL water is added, the hydrogen peroxide of 15mL30wt% is slowly added to;
Step 6:The mixture of gained filter and washed with the dilute hydrochloric acid of 250mL3.5wt% to remove metal ion,
It is washed with 200mL deionized waters again to remove the acid of remaining;
Step 7:It is diluted in input deionized water after solid filter cake is dried in air, graphite oxide is obtained by being ultrasonically treated
Alkene dispersion liquid;
Step 8:This dispersion liquid is fitted into and is dialysed in bag filter to remove the acid and metal ion of remaining, is changed daily primary
Water is dialysed seven days;
Step 9:Graphene oxide dispersion after dialysis is taken out and is centrifuged under the conditions of 4000 rpms, discards lower layer not
The graphite powder of oxidation or non-complete oxidation collects upper solution.
The graphene oxide solution of the present invention can be applied to field of cell preparation.
Embodiment 9
A method of graphene oxide solution is prepared, including：
Step 1:At room temperature, the salpeter solution of the concentrated sulfuric acid of 70mL98wt% and 5ml25wt% are mixed, is then delayed while stirring
It is slow that 3.0g graphite powders are added, it is added followed by 1.5g sodium nitrate and 1.9g niter cakes；
Step 2:This mixture is moved into cooling in ice bath, under violent stirring, is slowly added into 9.0g potassium permanganate and 1g
Potassium nitrate;
Step 3:After charging, reaction system is transferred in 40 °C of water-baths, constant temperature stirring is reacted 30 minutes;
Step 4:150mL deionized waters are slowly added to, and water-bath is warming up to 90 °C, are reacted 15 minutes;
Step 5:500mL water is added, the hydrogen peroxide of 15mL30wt% is slowly added to;
Step 6:The mixture of gained filter and washed with the dilute hydrochloric acid of 250mL3.5wt% to remove metal ion,
It is washed with 200mL deionized waters again to remove the acid of remaining;
Step 7:It is diluted in input deionized water after solid filter cake is dried in air, graphite oxide is obtained by being ultrasonically treated
Alkene dispersion liquid;
Step 8:This dispersion liquid is fitted into and is dialysed in bag filter to remove the acid and metal ion of remaining, is changed daily primary
Water is dialysed seven days;
Step 9:Graphene oxide dispersion after dialysis is taken out and is centrifuged under the conditions of 4000 rpms, discards lower layer not
The graphite powder of oxidation or non-complete oxidation collects upper solution.
The graphene oxide solution of the present invention can be applied to field of cell preparation.
Embodiment 10
A method of graphene oxide solution is prepared, including：
Step 1:At room temperature, the salpeter solution of the concentrated sulfuric acid of 70mL98wt% and 5ml25wt% are mixed, is then delayed while stirring
It is slow that 3.0g graphite powders are added, it is added followed by 1.5g sodium nitrate and 2g niter cakes；
Step 2:This mixture is moved into cooling in ice bath, under violent stirring, is slowly added into 9.0g potassium permanganate and 1g
Potassium nitrate;
Step 3:After charging, reaction system is transferred in 40 °C of water-baths, constant temperature stirring is reacted 30 minutes;
Step 4:150mL deionized waters are slowly added to, and water-bath is warming up to 90 °C, are reacted 15 minutes;
Step 5:500mL water is added, the hydrogen peroxide of 15mL30wt% is slowly added to;
Step 6:The mixture of gained filter and washed with the dilute hydrochloric acid of 250mL3.5wt% to remove metal ion,
It is washed with 200mL deionized waters again to remove the acid of remaining;
Step 7:It is diluted in input deionized water after solid filter cake is dried in air, graphite oxide is obtained by being ultrasonically treated
Alkene dispersion liquid;
Step 8:This dispersion liquid is fitted into and is dialysed in bag filter to remove the acid and metal ion of remaining, is changed daily primary
Water is dialysed seven days;
Step 9:Graphene oxide dispersion after dialysis is taken out and is centrifuged under the conditions of 4000 rpms, discards lower layer not
The graphite powder of oxidation or non-complete oxidation collects upper solution.
The graphene oxide solution of the present invention can be applied to field of cell preparation.
Claims (2)
1. a kind of method preparing graphene oxide solution, including：
Step 1:At room temperature, the salpeter solution of the concentrated sulfuric acid of 70mL98wt% and 5ml25wt% are mixed, is then delayed while stirring
It is slow that 3.0g graphite powders are added, it is added followed by 1.5g sodium nitrate and 1.1g niter cakes；
Step 2:This mixture is moved into cooling in ice bath, under violent stirring, is slowly added into 9.0g potassium permanganate and 1g
Potassium nitrate;
Step 3:After charging, reaction system is transferred in 40 °C of water-baths, constant temperature stirring is reacted 30 minutes;
Step 4:150mL deionized waters are slowly added to, and water-bath is warming up to 90 °C, are reacted 15 minutes;
Step 5:500mL water is added, the hydrogen peroxide of 15mL30wt% is slowly added to;
Step 6:The mixture of gained filter and washed with the dilute hydrochloric acid of 250mL3.5wt% to remove metal ion,
It is washed with 200mL deionized waters again to remove the acid of remaining;
Step 7:It is diluted in input deionized water after solid filter cake is dried in air, graphite oxide is obtained by being ultrasonically treated
Alkene dispersion liquid;
Step 8:This dispersion liquid is fitted into and is dialysed in bag filter to remove the acid and metal ion of remaining, is changed daily primary
Water is dialysed seven days;
Step 9:Graphene oxide dispersion after dialysis is taken out and is centrifuged under the conditions of 4000 rpms, discards lower layer not
The graphite powder of oxidation or non-complete oxidation collects upper solution.
2. the graphene oxide solution of the present invention can be applied to field of cell preparation.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810344209.8A CN108298533A (en) | 2018-04-17 | 2018-04-17 | A method of preparing graphene oxide solution |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810344209.8A CN108298533A (en) | 2018-04-17 | 2018-04-17 | A method of preparing graphene oxide solution |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN108298533A true CN108298533A (en) | 2018-07-20 |
Family
ID=62848481
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810344209.8A Withdrawn CN108298533A (en) | 2018-04-17 | 2018-04-17 | A method of preparing graphene oxide solution |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN108298533A (en) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109052383A (en) * | 2018-09-05 | 2018-12-21 | 七台河宝泰隆石墨烯新材料有限公司 | A kind of technique of electroosmose process separation graphene oxide |
| CN109112692A (en) * | 2018-10-22 | 2019-01-01 | 苏州高研纺织科技有限公司 | A kind of the radar invisible attached Metal Yarns of graphene plating and preparation method |
| CN109938038A (en) * | 2019-03-28 | 2019-06-28 | 新冶高科技集团有限公司 | A kind of biology graphene oxide antimicrobial fluid and preparation method thereof |
| CN113800806A (en) * | 2021-11-01 | 2021-12-17 | 湖南先锋建材有限公司 | Concrete water reducing agent and production method thereof |
| WO2022022050A1 (en) * | 2020-07-27 | 2022-02-03 | 中国港湾工程有限责任公司 | Material for wave wall |
| CN115924899A (en) * | 2022-11-19 | 2023-04-07 | 河北麦森钛白粉有限公司 | Preparation method of lithium iron phosphate/graphene oxide composite material |
-
2018
- 2018-04-17 CN CN201810344209.8A patent/CN108298533A/en not_active Withdrawn
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109052383A (en) * | 2018-09-05 | 2018-12-21 | 七台河宝泰隆石墨烯新材料有限公司 | A kind of technique of electroosmose process separation graphene oxide |
| CN109112692A (en) * | 2018-10-22 | 2019-01-01 | 苏州高研纺织科技有限公司 | A kind of the radar invisible attached Metal Yarns of graphene plating and preparation method |
| CN109938038A (en) * | 2019-03-28 | 2019-06-28 | 新冶高科技集团有限公司 | A kind of biology graphene oxide antimicrobial fluid and preparation method thereof |
| CN109938038B (en) * | 2019-03-28 | 2021-06-11 | 新冶高科技集团有限公司 | Graphene oxide antibacterial liquid for biology and preparation method thereof |
| WO2022022050A1 (en) * | 2020-07-27 | 2022-02-03 | 中国港湾工程有限责任公司 | Material for wave wall |
| CN113800806A (en) * | 2021-11-01 | 2021-12-17 | 湖南先锋建材有限公司 | Concrete water reducing agent and production method thereof |
| CN115924899A (en) * | 2022-11-19 | 2023-04-07 | 河北麦森钛白粉有限公司 | Preparation method of lithium iron phosphate/graphene oxide composite material |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN108298533A (en) | A method of preparing graphene oxide solution | |
| CN105838895B (en) | A kind of method that lithium and manganese are extracted from Mn-rich slag containing lithium | |
| RU2648807C2 (en) | Method for hydrometallurgical recovery of lithium, nickel and cobalt from lithium transition metal oxide-containing fraction of used galvanic cells | |
| RU2638481C2 (en) | Method of hydrometallurgical invasion of lithium from fraction of galvanic batteries containing lithium and iron phosphate | |
| CN104386679A (en) | Method for preparing graphene oxide and graphene | |
| CN109485031A (en) | A kind of nitrogen-doped graphene and preparation method thereof | |
| CN108585027B (en) | Method for preparing two-dimensional metal oxide and carbon composite material in large scale | |
| CN106587035A (en) | Eco-friendly safe reducing agent-based graphene and its preparation and application | |
| WO2020054917A1 (en) | Method for producing lithium compound | |
| CN105776189A (en) | Method for preparing high-purity small oxidized graphene | |
| CN105502374A (en) | Preparation method for small graphene | |
| WO2019237452A1 (en) | Method for preparing two-dimensional sheet-shaped cu-mof material | |
| WO2011120273A1 (en) | Method for preparing manganese sulfate monohydrate | |
| CN104340967A (en) | High stability graphite purification method | |
| CN108545730A (en) | It is a kind of to prepare semiconductor sulfonated graphene method | |
| CN108063295B (en) | Method for extracting lithium from slag generated by pyrogenic recovery of lithium battery | |
| CN108328608A (en) | A method of preparing aviation reduced graphene dispersion liquid | |
| CN107706394B (en) | MoO (MoO)2/Mo4O11Mixed-phase nano electrode material and preparation method thereof | |
| CN108502852A (en) | A kind of method that selenium in copper anode mud is recycled in microwave sulfating roasting | |
| WO2019144475A1 (en) | Method for preparing high-valence iron salt | |
| CN115626620B (en) | Preparation method of manganese phosphate | |
| CN116986566A (en) | Preparation method and application of ferric iron synthesized nano ferric iron phosphate and lithium iron phosphate | |
| JP2024052508A (en) | Vanadium electrolyte and its manufacturing method and application | |
| JP2015534610A (en) | Method for recovering lithium by lithium metallurgical process from lithium manganese oxide-containing part of used galvanic cell | |
| CN104340966A (en) | Method for purifying graphite |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| WW01 | Invention patent application withdrawn after publication |
Application publication date: 20180720 |
|
| WW01 | Invention patent application withdrawn after publication |