The method of talcum concentrate is separated from complicated formula Talc Ore raw material
Technical field:
The method that the present invention relates to a kind of to recycle talcum concentrate from talc ore raw material, it is especially a kind of sliding from complicated formula
The method of talcum concentrate is separated in stone ore raw material.
Background technique:
Talc Ore is the nonmetallic minerals that a kind of aqueous magnesium silicate mineral are main component.The principal component of talcum is Mg3
(Si4O10) (H2O)2, layer close structure silicate mineral.It is the good nonmetal mineral resource in China.Currently, explored
Nearly 300,000,000 tons of talcum Resource management.The talcum ore resources in China are distributed mainly on Liaoning, Shandong, Guangxi, Jiangxi and Qinghai etc.
5 provinces and cities account for 95% or more of national talcum mineral resources content.The main component of talcum mineral is talcum, is associated with mineral water chestnut
Magnesium mine, dolomite, serpentine etc..
Talc Ore is very important a kind of nonmetal mineral resource, is widely used in ceramics, papermaking, coating, modeling
Material etc., consumption figure accounts for 80% or more of Talc Ore resources consumption amount, these are all the rough consumption of talcum.And for
Talcum concentrate is mainly applied to high-end consumption market, such as cosmetics, medicine and food processing field;But in cosmetics, doctor
Although medicine and food processing field are small to the consumption amount of Talc Ore, such as talcum concentrate material higher to the quality requirements of Talc Ore,
And its extraction is also higher, extraction process is also more complex.
Such as " a method of separate miscellaneous stone from Talc Ore " that Chinese patent notification number is CN104138852A, will slide
Stone ore is broken into 1-2 centimetres of small nugget, crosses the vibrating screen of 14 mesh, and -14 mesh powder mines are collected, and the particle mineral aggregate of 14 mesh is defeated
It send into storage bin, is carried out dehydrating to hair mine, the mining color selector of hair is sorted, while the voltage for controlling color selector is
200-220V, the mineral aggregate and miscellaneous stone that separate collection is handled well.But the processing method of above-mentioned talcum mineral, first is that it is only capable of
Preparation sub-elects low-quality Talc Ore;On the other hand, relatively simple to the constituent requirement of Talc Ore raw material, in other words
The simple talcum ore resources of ingredient.Can use above-mentioned simple method for separating, the low-quality talcum mineral products prepared,
Its talcum mineral products sub-elected cannot meet the use of high-end raw material.And have the shortcomings that the rate of recovery is low, to cause to having
Limit the waste of resource.
The Talc Ore of formula complicated for one it is existing it is common be to be mentioned with barren rock using either carrying out simple talcum
It takes, but these barren rocks are in addition to minority is for other than filling out hole, paving the way, majority not to be comprehensively utilized.The accumulation having now found that
Just there are tens million of tons, in these above-mentioned Talc Ores, production-grade is not achieved, always as abandoned mine, barren rock processing, waste money
Source not only influences the exploitation of other high-quality mineral reserve, but also occupies mountainous region, and bring serious harm to surrounding enviroment, to periphery
The security of the lives and property of the people constitutes a threat to.
Therefore, there is an urgent need to develop recycle talcum in a kind of economic, efficiently, environmentally friendly Talc Ore raw material stone from complicated formula
The new method of concentrate.
Summary of the invention:
The present invention provides a kind of method that talcum concentrate is separated from complicated formula Talc Ore raw material, with complicated formula talc ore
For raw material through broken, removal of impurities, screening, then through washup, sorting, slurry, classification etc. is smash, talcum concentrate product, economic skill are prepared into
Benefit is evident for art, and three-protection design is small, and talcum concentrate product yield is high.
The present invention discloses a kind of method that talcum concentrate is separated from complicated formula Talc Ore raw material, with complicated formula talc ore
For raw material, through broken, removal of impurities, sieve comprising following method and step:
1) it is crushed, cleans, the complicated formula talc ore raw material is cleaned through broken, sorting, is the small of partial size 0.5-1cm
Ore powder agglomates is talcum ore grinding material,
2) by talcum ore grinding material with water feeding into washing storage device, and dispersion activator is added in washup, sorting,
It is stirred continuously condition and carries out washed with impurities processing, sub-elect thick talcum mineral aggregate,
3) slurry, classification are smash, slurry is made in thick talcum mineral aggregate, and flocculant is added and smash slurry processing, with grader into
The processing of row gradient fractionation, obtains sub-material in Talc Ore;
4) screening, frosted, carry out sorting screening process for sub-material in Talc Ore, sorted screening process is recycled to again
Frosted processing, sorted screening process is concentrate material at the beginning of Talc Ore again after frosted handles and is recycled to grader classification again;
5) concentrate material at the beginning of Talc Ore is prepared into talcum concentrate through magnetic separation by magnetic separation, talcum concentrate processed.
The complexity formula talc ore raw material is talcum enstatite, black talc, Talc Ore containing troilite and the miscellaneous mine of talcum
It is any two or more.
The sorting is the sorting of distant bed or spiral separating or is distant bed sorting and the mixing of spiral separating sorting.
Preferably, the dispersion activator for being 2) the step addition is the mixing of phosphoric acid class sodium salt or Organic Sodium Salt or both;
The phosphoric acid class sodium salt is sodium tripolyphosphate or calgon;Control dispersion activator additive amount is the quality of talcum ore grinding material
0.01-0.1%;The Organic Sodium Salt is dodecyl sodium sulfate.
It preferably, is that 3) flocculant described in step is polyacrylic acid and its sodium salt or polyacrylic acid and its sodium salt and polyethanol
Mixing.
5) magnetic separation high intensity magnetic separation including a weak magnetic beneficiation and twice.
It further, is that the processing step of the separation by shaking table is: feed trough flushing water, bed surface forms inclined-plane pellicular water
Stream, solid waste particle enter the bed surface of shake, and particle is isolated layering by density, and the particle of different densities or granularity is longitudinal along bed surface
And transverse movement, the fan-shaped distribution on bed surface of different densities particle, thick and light particle are top layer, followed by thin and light
Third particle is thick and weight particle, the bottom is thin and weight particle, and sorting is completed.
It further, be the spiral separating include spiral chute, the processing step of the spiral chute are as follows: pan feeding,
Slurry dispenser, spiral chute, weight solid waste sink to the lower layer of liquid stream, and light solid waste floats on the upper layer of liquid stream, light solid
Waste is concentrated on upper layer to the outer rim of slot, and weight solid waste is concentrated in lower layer to the inner edge of slot, cross of light, the weight solid waste along slot
To evenly distributed from outer rim to inner edge, light, weight solid waste passes through the discharge of respective drainage conduit respectively, sorting is completed.
Preferably, the polyacrylic acid and its sodium salt and the mixed mass ratio of polyethanol are 1:1-2.
Process of the invention is simple, and beneficiation cost is low, solves and extracts Talc Ore using complicated formula Talc Ore raw material
The problem of product, generally will make rejected ore to complicated formula Talc Ore originally and abandon use, and be generally used for roadbed and use, but its
It is only that small part uses, a large amount of complexity formula Talc Ore is discarded to be stacked, and brings serious harm to surrounding enviroment, and to periphery people
The security of the lives and property of the people masses constitutes a threat to problem, realizes to extract from complicated formula Talc Ore raw material and isolates talcum concentrate,
Turn waste into wealth, be conducive to environmental protection, there is big economic and social benefit.
Specific embodiment: With reference to embodiment to further detailed description of the invention.Mass parts or matter
Amount ratio.
Embodiment of the present invention is the complicated formula Talc Ore raw material, and preferred complexity formula talc ore raw material is that talcum is stupid
Any one two or more i.e. the mixing above of fiery pyroxene, black talc, Talc Ore containing troilite and the miscellaneous mine of talcum.Including as follows
Method,
1) it is crushed, cleans, any one or a few by complicated formula talc ore raw material described above is removed through broken, sorting
It is miscellaneous, removal of impurities stone etc. is mainly removed, material talc mine is broken into the small ore powder agglomates of partial size 0.5-1cm, is talcum ore grinding material,
2) washup, sorting, by talcum ore grinding material with water feeding into washing storage device, i.e. the washing storage of talcum ore grinding material
In batch can body, and dispersion activator is added, the dispersion activator is the mixing of phosphoric acid class sodium salt or Organic Sodium Salt or both, can
Using sodium tripolyphosphate and dodecyl sodium sulfate by the mixing for the mass ratio for respectively accounting for 50%;The amount that control dispersion activator is added
For the 0.01-0.1% of talcum ore grinding material quality, while controlling and carrying out washed with impurities processing in the condition that is being stirred continuously, and control point
The washed with impurities processing time dissipated under activator existence condition is 5-8 hours, sub-elects thick talcum mineral aggregate,
3) slurry, classification are smash, slurry is made in thick talcum mineral aggregate, and flocculant is added and carries out smashing slurry processing, the flocculant
For the mixing of polyacrylic acid and its sodium salt or polyacrylic acid and its sodium salt and polyethanol, the additional amount of the flocculant is thick talcum
The 0.01-0. 1% of mineral aggregate quality, it is 3-5 hours that the slurry processing time is smash in control, while control is carried out at gradient fractionation with grader
Reason, obtains sub-material in Talc Ore;
4) screening, frosted, carry out sorting screening process for sub-material in Talc Ore, sorted screening process is recycled to again
Frosted processing, sorted screening process is concentrate material at the beginning of Talc Ore again after frosted handles and is recycled to grader classification again;
It preferably, is that grinding aid is added in the frosted treatment process, the grinding aid is sodium sulphate or Sodium Polyacrylate
Or both mixing, meter is added by existing grinding aid in the amount of addition;
5) magnetic separation, talcum concentrate processed, by concentrate material at the beginning of Talc Ore through magnetic separation, the magnetic separation is that concentrate material at the beginning of Talc Ore is first
A low intensity magnetic separation is carried out, is then prepared into talcum concentrate after continuous magnetic separator processing twice again.
Sorting of the present invention can be preferably with separation by shaking table, the processing step of the specific separation by shaking table
Carry out as follows: i.e. feed trough flushing water, bed surface form inclined-plane sheet flow, and solid waste particle enters the bed surface of shake,
Particle is isolated layering by density, and the particle of different densities or granularity is moved along bed surface vertical and horizontal, and different densities particle is in bed
Fan-shaped distribution on face, thick and light particle are top layer, third followed by thin and light particle is thick and weight particle,
The bottom is thin and weight particle, and sorting is completed;
The magnetic separator be it is preferable to use high-gradient magnetic separation, can be as by concentrate material high gradient magnetic separator at the beginning of Talc Ore
Smash slurry, the flocculant that is added that the step of removal of impurities is poly- is the mixed of polyacrylic acid and its sodium salt or polyacrylic acid and its sodium salt and polyethanol
It closes., it is preferred to use the mixing of Sodium Polyacrylate and polyethanol, and the mass ratio for controlling its Sodium Polyacrylate and polyethanol is 5:5
Ratio mixing;Flocculant addition is the first concentrate material of Talc Ore that control is 0.01-0. 1%;Talcum concentrate is prepared.?
During high-gradient magnetic separation, magnetic pole surfaces magnetic field strength H≤1700A/m of the high gradient magnetic separator is controlled.
During high-gradient magnetic separation of the present invention, the magnetic pole surfaces magnetic field strength H of the high gradient magnetic separator is controlled
≤1700A/m。
Embodiment 1
Certain several ton of complicated formula Talc Ore raw material is taken, predominantly Talc Ore containing troilite, main chemical compositions are as follows
(wt%): SiO252.47 Al2O33.46 K2O, 0.16, Na2O 0.14, CaO 0.01, MgO 20.69, Fe2O31.19
Remaining is other compound compositions;Raw material whiteness is 50.1;Surplus is other substances.Above-mentioned complicated formula Talc Ore raw material is passed through
It after jaw crushing crusher machine, is classified through spiral classifier and the processing that cleans, removes iron mineral in magnetic iron ore, grasped into washup
Make, talcum ore grinding material is made;The mixing of dispersion activator sodium tripolyphosphate and dodecyl sodium sulfate is added to talcum ore grinding material,
The ratio that the mass ratio of both control is 5:5 mixes, and the amount that control dispersion activator is added is the 0.05% of talcum ore grinding material, into
Thick talcum mineral aggregate is made in row sorting operation;Slurry, progressive operation are smash, slurry is made in thick talcum mineral aggregate, to the slurry of thick talcum mineral aggregate
The mixing of flocculant polyacrylic acid and polyacrylic acid sodium salt is added in material, control polyacrylic acid additional amount is flocculant addition
40-45%, and the additional amount of flocculant is the 0.06% of thick talcum mineral aggregate quality, is then divided with grader such as spiral classifier
Grade processing, control smash slurry processing the time be 5 hours, be made Talc Ore in sub-material.Sub-material in Talc Ore is subjected to separating sieve again
Point processing is directly entered lower step magnetic separation work for sub-material is satisfactory in the Talc Ore after sorted screening process for the first time
The low intensity magnetic separation of sequence walks, and sub-material is recycled to frosted processing in the most Talc Ore through primary sorting screening process, is grinding
Grinding aid is added in sand treatment process, the grinding aid is the mixing of sodium sulphate or Sodium Polyacrylate or both, the amount of addition
Meter is added by existing grinding aid;Handled through frosted and be recycled to the 3 of upper step again) the grader classification smash slurry, be classified the stage of step
Sorted screening process is Talc Ore just concentrate material again afterwards;The undeclared place of grader classification processing, can be used existing
The grader of technology or classification processing technique classification processing;Talc Ore just concentrate material is made.The magnetic separation of last 5) step, by obtained cunning
The first concentrate material talcum concentrate product of stone ore.It is that concentrate material at the beginning of Talc Ore is first subjected to a low intensity magnetic separation, then again through continuous two
After secondary magnetic separator processing, that is, it is prepared into talcum concentrate.The talcum concentrate being prepared into reaches 65.3 through testing product whiteness.It is sliding
The whiteness of stone concentrate product is largely increased.
Embodiment 2
It is following except it is stated that in addition to, remaining undeclared place is identical as embodiment 1 and above-mentioned specific embodiment.
1) it is crushed, removal of impurities raw material, complicated formula talc ore raw material is the mixed of any ratio of talcum enstatite and black talc
It closes;
2) washup, sorting, by talcum ore grinding material with water feeding into washing storage device, and it is six that dispersion activator, which is added,
Sodium metaphosphate and dodecyl sodium sulfate are the mixing of the ratio of 4:6 in mass ratio, and additional amount is the 0.08% of talcum ore grinding material,
Washed with impurities processing is carried out in the condition that is stirred continuously, sub-elects thick talcum mineral aggregate,
4) screening, frosted, carry out sorting screening process for sub-material in Talc Ore, sorted screening process is recycled to again
Frosted processing, sorted screening process is concentrate material at the beginning of Talc Ore again after frosted handles and is recycled to grader classification again;Frosted
Grinding aid polypropylene sodium or sodium sulphate are added when processing, 40-60g is added in frosted raw material per ton in the amount control of addition;
And the prior art is difficult to recycle from complicated formula Talc Ore raw material and isolates such as above-mentioned talcum concentrate of the invention
Product shows that it can be widely applied to cosmetics, medicine and other fields through relevant enterprise application, greatly improves complicated formula Talc Ore and mentions
Take production efficiency.