CN108294379A - Ultraviolet-proof mask - Google Patents

Ultraviolet-proof mask Download PDF

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Publication number
CN108294379A
CN108294379A CN201810020143.7A CN201810020143A CN108294379A CN 108294379 A CN108294379 A CN 108294379A CN 201810020143 A CN201810020143 A CN 201810020143A CN 108294379 A CN108294379 A CN 108294379A
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CN
China
Prior art keywords
ultraviolet
light
dyestuff
woven fabrics
proof mask
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Pending
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CN201810020143.7A
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Chinese (zh)
Inventor
江国庆
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Individual
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Individual
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Priority claimed from TW106100882A external-priority patent/TWI617336B/en
Priority claimed from TW106136753A external-priority patent/TW201917239A/en
Application filed by Individual filed Critical Individual
Publication of CN108294379A publication Critical patent/CN108294379A/en
Pending legal-status Critical Current

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    • AHUMAN NECESSITIES
    • A41WEARING APPAREL
    • A41DOUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
    • A41D13/00Professional, industrial or sporting protective garments, e.g. surgeons' gowns or garments protecting against blows or punches
    • A41D13/05Professional, industrial or sporting protective garments, e.g. surgeons' gowns or garments protecting against blows or punches protecting only a particular body part
    • A41D13/11Protective face masks, e.g. for surgical use, or for use in foul atmospheres
    • AHUMAN NECESSITIES
    • A41WEARING APPAREL
    • A41DOUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
    • A41D31/00Materials specially adapted for outerwear
    • AHUMAN NECESSITIES
    • A41WEARING APPAREL
    • A41DOUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
    • A41D2400/00Functions or special features of garments
    • A41D2400/26UV light protection

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Physical Education & Sports Medicine (AREA)
  • Nonwoven Fabrics (AREA)
  • Coloring (AREA)

Abstract

An ultraviolet-proof mask comprises an outer layer, a non-woven fabric body, a light-sensitive material and a light-sensitive material, wherein the non-woven fabric body contains a photochromic dye which can absorb ultraviolet rays; the middle layer is made of materials capable of filtering dust and bacteria; an inner layer configured to be attached to a face, wherein the middle layer is located between the inner layer and the outer layer. The mask of the invention has a surface material which can absorb ultraviolet rays and can absorb the ultraviolet rays to generate appearance change so as to be beneficial to observing the absorption effect.

Description

Ultraviolet-proof mask
Technical field
The present invention relates to a kind of masks, especially with regard to a kind of mask of ultraviolet protection.
Background technology
Mask has a variety of variations, and there are traditional mask three layers or four layers to construct, and the mask of general non-medical level Including outer layer, filter layer and internal layer.Outer layer effect be only cladding filter layer, but this quasi-tradition and can not uvioresistant, Ben Fayin And it is raw here.
Invention content
Traditional uvioresistant dress ornament, cap or umbrella is to be coated with anti-reflecting layer on it, with the ultraviolet of reflective portion Line and reach anti-ultraviolet function.This anti-reflecting layer is easy to damage through hitting, scraping, pull, tear;Whether it has antiultraviolet work( Can also non-availability and know;So market is full of the clothing of uvioresistant amusement, and actually safeguard function is unknown.The mesh of the present invention Be to propose a kind of surface material of mask, especially absorbable ultraviolet light.
It is a further object of the present invention to provide a kind of mask materials, especially can absorb ultraviolet light and generate outward appearance change, Observable assimilation effect.
It is a further object of the present invention to provide a kind of clothes, especially absorbable ultraviolet light, without composite double layer material Expect structure, make to be made simple and required color can be obtained.Prior art is to use double-layer structure based on that can not paint, and is caused Complex process and cost.And this case manufactures plastic pellet in mixing process using Jet forming machine, in batch mixing macromolecule Traditional dyeing material is mixed, it is made to be uniformly distributed in macromolecule ontology, without being dyed using subsequent processing.This and non-excluded processing Dyeing, but have demand that can participate in pigmenting and form Essential colour, it can be in its allochromatic colour of processing dyeing and finishing afterwards.Furthermore, it is possible to carry Temperature is risen close to operating under dissociation temperature.
A kind of mask of absorbable ultraviolet light, wherein for example photic comprising the material doped absorbable ultraviolet light of polymer basis Become dyestuff, made by ratio mixing;By melting the polymer basis material, light-induced variable or thermotropic dyestuff is added to be made fiber It is distributed in polymer basis material, and drawnworking after melting forms, and wherein melting temperature is less than light-induced variable or heat with drawnwork temperature The dissociation temperature of mutagens dyestuff;Mask material reaches ultraviolet light comprising light-induced variable or thermotropic dyestuff in favor of absorbing ultraviolet light Protect effect;It, can be in mixing polymer basis material and light-induced variable or thermotropic if need to wherein adjust basic material basic colors Non- light-induced variable or thermotropic dyestuff are adulterated when dyestuff(This meaning is high molecular dye)In in high molecular basic material.So may be used To avoid being not easy the problem of painting afterwards;And processing temperature is less than light-induced variable or the dissociation temperature of thermotropic dyestuff.It is wherein above-mentioned It melts program or program of drawnworking adds the combination for including stabilization agent, antioxidant, ultraviolet light (UV) absorbent or more.Wherein base Plinth material and photochromic dyes mixed proportion are:One to ten a ten thousandth compares a ten thousandth to one;One than a ten thousandth to one Than 5/10000ths;5 to one/10000th to ten thousand compares one thousandth;One than one thousandth to one to five 1 percent.
Wherein polymer basis material includes polyamide(Polyamide Fiber), polyester(Polyester Fiber)、 Polyacrylonitrile(Polyacrylonitrile Fiber), polyethylene(Polyethylene Fiber), polypropylene (Polypropylene Fiber), polyvinyl alcohol(Polyvinylalcohol Fiber), polyvinyl chloride (Polyvinylchloride Fiber), polytetrafluoroethylene (PTFE)(Polytetrafluoroethylene Fiber), polyacrylonitrile (PAN), nylon, polyethylene terephthalate(PET, terylene), polybutylene terephthalate(PBT), polyurethane(Spandex) Or more arbitrary combination.Above-mentioned basic material can be blended with natural fiber or semisynthetic fibre or synthetic fibers.
A method of making UV absorption fiber, it is characterised in that include:Purchase the basis for making UV absorption fiber Material and purchase light-induced variable or thermotropic dyestuff;With a ratio mixed base material and light-induced variable or thermotropic dyestuff;Melt base Plinth material makes light-induced variable or thermotropic dye distribution in basic material, and wherein melting temperature is less than photochromic dyes dissociation temperature Degree adulterates non-light-induced variable or thermotropic dyestuff in high molecular basic material wherein if basic material basic colors need to be adjusted To reach required color to make master batch;Master batch is moved into spinning machine, and master batch is melted;By the basic material of master batch after fusing Reel off raw silk from cocoons makes raw material yarn have ultraviolet radiation absorption function to make raw material yarn.Wherein above-mentioned melting program addition includes stabilization agent, resists The combination of oxidant, UV absorbents or more;Wherein above-mentioned light-induced variable or thermotropic dye form include microcapsules, liquid, Powder, solution state or master batch.Wherein basic material and the light-induced variable or thermotropic dyestuff mixed proportion are one than number a ten thousandth Compare a ten thousandth to one;One than a ten thousandth to one to ten thousand/five;5 to one/10000th to ten thousand compares one thousandth;One to thousand point One of to one than hundreds of points one.
A method of making UV absorption cloth, it is characterised in that include:Purchase basic material and purchase light-induced variable or Thermotropic dyestuff;Light-induced variable or thermotropic dyestuff are added in the solution of the basic material with a ratio and melted, wherein this is molten It solves temperature and is less than the light-induced variable or thermotropic dyestuff dissociation temperature, if wherein the basic material basic colors need to be adjusted, doping is non- Light-induced variable or thermotropic dyestuff in the high molecular basic material to reach required color;Make the light-induced variable or thermotropic dyestuff It is distributed in the solution of the basic material;It is projected with Jet forming machine and makes basic master batch;The basis master batch is moved and causes spinning machine To make raw material yarn.
The raw material yarn is made into cloth, the cloth is made to have the function of UV absorption.Wherein above-mentioned melting program addition includes peace Determine the combination of agent, antioxidant, UV absorbents or more;Wherein above-mentioned light-induced variable or thermotropic dye form includes micro- glue Capsule, liquid, powder, solution state or master batch.Basic material and the photochromic dyes mixed proportion arrive for one than number a ten thousandth One compares a ten thousandth;One than a ten thousandth to one to ten thousand/five;5 to one/10000th to ten thousand compares one thousandth;One to thousand/ One to one than hundreds of points one.Polymer basis material includes polyamide(Polyamide Fiber), polyester(Polyester Fiber), polyacrylonitrile(Polyacrylonitrile Fiber), polyethylene(Polyethylene Fiber), polypropylene (Polypropylene Fiber), polyvinyl alcohol(Polyvinylalcohol Fiber), polyvinyl chloride (Polyvinylchloride Fiber), polytetrafluoroethylene (PTFE)(Polytetrafluoroethylene Fiber), polyacrylonitrile (PAN), nylon, polyethylene terephthalate(PET, terylene), polybutylene terephthalate(PBT), polyurethane(Spandex) Or more arbitrary combination.Wherein above-mentioned basic material and natural fiber or semisynthetic fibre or synthetic fibers are blended.
A kind of ultra-violet absorption composition:It is basic material with polymer, in being wherein mixed into light-induced variable or thermotropic dye Material handles mixing under less than light-induced variable or thermotropic dissociation temperature, then is fabricated to photochromic composition with molding machine;Its Both middle basic material and light-induced variable or thermotropic dyestuff mixed proportion compare a ten thousandth for one than number a ten thousandth to one;One ratio A ten thousandth is to 5/10000ths to ten thousand;5 to one/10000th to ten thousand compares one thousandth;One than one thousandth to one than hundreds of points it One;One than hundreds of points one to one than tens of points one.If polymer basis material includes polyester, wherein treatment temperature is Celsius 200-250 degree.If polymer basis material includes polypropylene, wherein the treatment temperature is 140-180 degree Celsius.It is wherein above-mentioned Basic material and natural fiber or semisynthetic fibre or synthetic fibers are blended.
A kind of ultraviolet-proof mask, the wherein mask include at least:Outer layer, including non-woven fabrics outer layer, the wherein non-woven fabrics Including photochromic dyes are incorporated in high molecular material;Middle layer, by may filter that the material of dust, bacterium forms;Inner layer is matched It sets for being affixed on face, wherein the middle layer is located between the inner layer and the outer layer.Wherein also include that melting program addition includes The combination of stabilization agent, antioxidant, UV absorbents or more.Wherein the temperature of the melting program is less than the absorbable ultraviolet light dye The dissociation temperature of material.Wherein the basic material of non-woven fabrics and the absorbable ultraviolet dye mixed proportion are one than number a ten thousandth Compare a ten thousandth to one;One than a ten thousandth to one to ten thousand/five;5 to one/10000th to ten thousand compares one thousandth;One to thousand point One of to one than hundreds of points one.Wherein the high molecular material includes polyamide(Polyamide Fiber), polyester (Polyester Fiber), polyacrylonitrile(Polyacrylonitrile Fiber), polyethylene(Polyethylene Fiber), polypropylene(Polypropylene Fiber), polyvinyl alcohol(Polyvinylalcohol Fiber), polyvinyl chloride (Polyvinylchloride Fiber), polytetrafluoroethylene (PTFE)(Polytetrafluoroethylene Fiber), polyacrylonitrile (PAN), nylon, polyethylene terephthalate(PET, terylene), polybutylene terephthalate(PBT), polyurethane(Spandex) Or more arbitrary combination.Wherein above-mentioned high molecular material material and natural fiber or semisynthetic fibre or synthetic fibers are mixed It spins.
A kind of ultraviolet-proof mask, the wherein mask include at least:Outer layer, including antiultraviolet material is sprayed at outer layer base On material, wherein the antiultraviolet material includes light-induced variable dyestuff;Middle layer, by may filter that the material of dust, bacterium forms;In Layer, is configured to be affixed on face, wherein the middle layer is located at the inner layer and the outer interlayer.Wherein the base material includes polyamide (Polyamide Fiber), polyester(Polyester Fiber), polyacrylonitrile(Polyacrylonitrile Fiber), it is poly- Ethylene(Polyethylene Fiber), polypropylene(Polypropylene Fiber), polyvinyl alcohol (Polyvinylalcohol Fiber), polyvinyl chloride(Polyvinylchloride Fiber), polytetrafluoroethylene (PTFE) (Polytetrafluoroethylene Fiber), polyacrylonitrile(PAN), nylon, polyethylene terephthalate(PET is washed Synthetic fibre), polybutylene terephthalate(PBT), polyurethane(Spandex)Or more arbitrary combination.In another embodiment, UV resistance Line mask includes at least:Outer layer, including non-woven fabrics outer layer, the wherein non-woven fabrics, which include absorbable ultraviolet dye, is incorporated in high score In sub- material;Middle layer, by may filter that the material of dust, bacterium forms;Inner layer is configured to be affixed on face, wherein among this Layer is between the inner layer and the outer layer.
Description of the drawings
Fig. 1 is the schematic diagram of the embodiment of the present invention.
Fig. 2 is the schematic diagram of the embodiment of the present invention.
Fig. 3 is the schematic diagram of the embodiment of the present invention.
Fig. 4 is the sectional drawing of the invention through SGS mechanisms examining report.
Primary clustering symbol description:
100 purchase material program;
110 integrating materials programs;
120 reel off raw silk from cocoons program;
130 woven fabric programs;;
200 ultraviolet resistant layers
220 filter layers;
240 inner layers;
300 purchase material program;
310 integrating materials programs;
320 merging solution tank programs;
330 non-woven fabrics programs.
Specific implementation mode
The invention will be further described in the following with reference to the drawings and specific embodiments, so that those skilled in the art can be with It is better understood from the present invention and can be practiced, but illustrated embodiment is not as a limitation of the invention.The present invention can apply In various fibers, an explanation is done below.
Mouth mask with ultraviolet resistance can spray or be coated with uvioresistant on its table cloth and absorb material or light-induced variable dyestuff, and reach To anti-ultraviolet function.If being coated with antiultraviolet observable, it changes, and learns safeguard function, and tradition, which muzzles, has no protection Ultraviolet light function, more leisure opinion observe its protection effect, in fact, traditional mask is without any safeguard function, therefore are unfavorable for face It is maintained after cosmetology.It is maintained after cosmetology, wherein a most important ring is to prevent ultraviolet light from irradiating, therefore the present invention is for beauty Postoperative maintenance is particularly significant, and traditional mask is unable to reach this effect completely.
The present invention will be photochromic(Photo-Chromic)Dyestuff is doped in high molecular polymer, and micro mist may be used Shape, capsule state mix light-induced variable dyestuff with high molecular polymer.Production method can also use coating to be design on fabric surface. Because the present invention be before reeling off raw silk from cocoons doping fusion in fiber, therefore be not easy to be scraped damage, tearing, shock and damage, if but not producing Convenient and cost consideration, then may be used spraying.Light-induced variable dyestuff can absorb sunlight or ultraviolet light and changes structure, generates discoloration It is mixed in medium, such as high molecular polymer.Above-mentioned amalgamation mode include with heat molten polymer or with polymer solution it is molten Light-induced variable dyestuff is made it generally be uniformly distributed therein by solution.In addition in this stage, it is contemplated that dyestuff or color masterbatch is added, Color after reeling off raw silk from cocoons in favor of adjustment.The fabric fibre that can so that dyestuff is uniformly distributed in after whole spin is added in this stage It is interior, rather than so that color stability is promoted just in fiber exterior coloring in spinning.
Fusion generates reversible chemical variation after intrastitial light-induced variable dyestuff is via sunlight or ultraviolet light irradiation and causes Color change.When not irradiated by above-mentioned sunlight or ultraviolet light, script color can be restored.Light-induced variable dyestuff and can with light stabilizer and UV absorbents etc. are selectively doped in assist absorption ultraviolet light in high molecular polymer together.It adds antioxidant and/or UV inhales Receipts agent can be promoted anti-light tired in high molecular polymer.Above-mentioned photochromic material can be spiro-pyrans (spiropyrans), spiral shell Oxazines (spiroxazines), fulgide (fulgide), fulgenimide (fulgimides), chromene (benzopyran), aphthopyrans (naphthopyran), spirobenzopyran (spirobenzopyran), spiral shell aphthopyrans (spironaphthopyran), spiral shell benzoxazine (spirobenzoxazine), spiral shell naphtho- oxazines (spironaphthoxazine) etc., but be not limited with above-mentioned example.
Synthetic fibers(Synthetic Fiber), the monomer molecule raw material obtained by nature, to polymerize in a manner of spinning Form fiber.Such as condensation polymer(Condensation Polymer):(A)Fypro(Polyamide Fiber): Nylon 6(Nylon 6), nylon 6.6(Nylon 6.6), nylon 11(Nylon1);(B)Polyester fiber(Polyester Fiber):PET、PBT、PTT;(C)Addition polymer(Addition Polymer):(1)Polyacrylonitrile fibre (Polyacrylonitrile Fiber):PAN(Or Acrylic Fiber);(2)Polyethylene fibre(Polyethylene Fiber):PE;(3)Polypropylene fibre(Polypropylene Fiber):PP;(4)Vinal (Polyvinylalcohol Fiber):PVA;(5)Polyvinyl chloride fibre(Polyvinylchloride Fiber):PVC; (6)Polytetrafluoroethylene fibre(Polytetrafluoroethylene Fiber):PTFE;(7)Polyurethanes series fiber (Polyurethane Fiber):PU.Carbon fiber, glass fibre etc. then range inorganic synthetic fibers.High function fiber includes Polylactic acid(Poly lactic acid), pbo fiber(p-phenylene-2,6-benzobisoxazole), high-tenacity polyester, Polyamide, polyolefin, contraposition and meta-aromatic polyamide, carbon fiber, high coefficient polyethylene(HMPE), polyphenylene sulfide(PPS), phenol system Polymer fiber, polyether-based ketone(PEEK), P84 etc..If polypropylene fibre need to be used, preferably with grafting shape polypropylene fibre Allow to dye after it is blended with other materials.In addition it is that traditional non-chromotropic dye is added when purchasing basic master batch With chromotropic dye in plastics, in polypropylene, with 140 degree of Celsius temperature to 180 degree processing.
In using synthetic fibers as the basic material and light-induced variable dyestuff in example, purchasing macromolecule or polymer first(If Thermotropic dyestuff is that the caused energy absorption of ultraviolet light is generated discoloration at this time), step 100, if color need to be adjusted, Traditional dyeing need to be purchased(Non- light-induced variable)Dyestuff or color masterbatch.Light-induced variable dyestuff or thermotropic dyestuff may be used or divide discoloration Son is added in polymer or resin material, the basic material before above-mentioned fiber axis and light-induced variable dyestuff can be powdery, Capsule shape, liquid, solution or plastics material master batch.The mixed proportion of light-induced variable dyestuff and polymer is about 0.01% ~ 0.5% weight Measure percentage(w/w);Or 0.5% ~ 0.1% or;0.1%~1.5%.The two is uniformly mixed heating therewith and melts the macromolecule Or the basic material of polymer makes its fusion, heating fusion temperature that need to be less than the dissociation temperature of above-mentioned light-induced variable dyestuff, step 110.For example, the light-induced variable material that can mix aforementioned proportion is formed with high molecular polymer, and melting concn is imitated with discoloration Fruit is related.Based on above-mentioned light-induced variable dyestuff using the selection of powder and processing temperature, without using dispersant.Such as temperature is 150-180 or 180-220 degree.Based on powdery, capsule shape, liquid, solution may be used in embodiment, can when reeling off raw silk from cocoons on the spot, Without being fabricated to master batch, however master batch is conducive to strange land processing and transports convenience.Therefore can first by this it is mixed reel off raw silk from cocoons before material Material, is made into polymer master batch.
The present invention provides a kind of photochromic constituent, is to use that the polymer of fiber can be made as basic material, Yu Qi Middle doping photochromic dyes merge photochromic dyes, wherein processing temperature need to be less than when mixing with heating fusion or solution The dissociation temperature of the photochromic dyes.Possibility need to be by plastics drying and processing before above-mentioned manufacturing process, foundation deal and material, 1 to 5 hour etc., then by high molecular polymer and light-induced variable dyestuff mixed processing, process again later.The two mixed proportion according to According to different purposes, photochromic dyes ratio can be to count a ten thousandth to a ten thousandth;A ten thousandth is to 5/10000ths;Ten thousand/ Five arrive one thousandth;One thousandth to one tens of point of one or hundreds of point of hundreds of points one.To sum up, drying plastics and mixing Light-induced variable material after stirring is allowed to uniformly, is fed in spinning unit.Its basic colors can be influenced for different temperatures and concentration The depth, therefore it can be utilized to control required color with non-chromotropic dye.In addition processing temperature must be less than light-induced variable dyestuff Heating mixes, reels off raw silk from cocoons under dissociation temperature, in favor of making raw material yarn.Therefore it is different photic to coordinate different temperatures must to be adjusted Become material.Light-induced variable material generates thermal change after being irradiated via sunlight or ultraviolet light.When not irradiated by above-mentioned sunlight or ultraviolet light, It can restore script color.Light-induced variable dyestuff absorbs sunlight or ultraviolet light and generates color change, therefore it is ultraviolet except that can absorb Outside line, and fiber bodies color change can be caused, increase fashion statement, also so that uvioresistant see see and add anti-oxidant Agent and/or UV absorbents can be promoted anti-light tired.
Light(Or heat)Master batch can be made by causing chromotropic dye uniformly to be mixed with base polymer or high molecular material.In progress When reeling off raw silk from cocoons, this polymeric base material mixed is dissolved and is reeled off raw silk from cocoons, step 120, whether natural fiber, it is semi-synthetic or The technology of reeling off raw silk from cocoons of synthetic fibers belong to technique it is known that and front and back processing routine of reeling off raw silk from cocoons also fall within to have in this technical field and commonly know The knowledgeable is appreciated that therefore does not repeat.
Completion reels off raw silk from cocoons and obtains raw material yarn after program, can make various clothes 130 with tatting, plain weave or knitting, be known as at this time Embryo cloth.And various other programs are such as dyed, are embossed or pattern making belongs to has ordinary skill can be in this technical field Understand, therefore does not repeat.
It is above-mentioned following methods may be used with the program of polymer fusion to be merged.Such as melt spinning method:It will be photic Become material or off-color material and carry out melt spinning with polymeric base material, or light-induced variable material is dispersed in and can be polymerize with spinning In the resin carrier of object consolute, then it is blended into the polymers such as polyester, nylon, polypropylene and carries out melt spinning.In another implementation In example, solution spinning also can be used by light-induced variable material and to prevent transferring assistant to be directly appended to molten in polymer material solution Then solution carries out spinning and obtains light-induced variable fiber.Compared with melt spinning, the spinning temperature of this method is relatively low, will not go out The problem of now aoxidizing or thermally decompose.In another embodiment, light-induced variable material or off-color material can be dissolved in solvent appropriate, Then it is mixed and made into photochromic material mud with adhesives such as polymer or resin liquids, by fiber or fabric in this slurry liquid Middle carry out coating treatment, so that it may with obtain with discoloration property fiber, such mode be after first reeling off raw silk from cocoons again with photochromic mud Slurry carries out dip dyeing coating.It is core that composite spinning method, which is by photochromic material, and using general fiber as sheath, congruent melting spinning obtains core-skin Composite fibre.
Using solution spinning, as an example, but following manner and basic material can not be limited, only do an embodiment, such as It purchases cellulose acetate, acrylic polymer and solvent and forms spinning material solution, solvent can dissolve cellulose acetate, propylene Nitrile based polymer, such as inorganic acid, inorganic salts.This solvent in affiliated skill field, have ordinary skill it would be appreciated that.It is mixed Stirring is closed, while adulterating photochromic dyes, to make spinning material solution.Using known spinning-nozzle with spinning material solution For raw material, makes the end with fiber kenel and extend silk.Then end is redrawn to extend silk to set several times long.Dry type can also be used to take out Silk method, in affiliated skill field, there is ordinary skill it would be appreciated that, therefore do not repeat.
Do not change original technique using the above method, process will not be increased, before reeling off raw silk from cocoons, by light(Or heat)Mutagens Dyestuff is added in plastics and mixes, and so that it is merged with high molecular polymer, it is made to be uniformly distributed in the polymeric material.It Afterwards, then there is light-induced variable dyestuff to be evenly distributed in fiber by the fiber to reel off raw silk from cocoons, becomes a fiber part.Or it is reeling off raw silk from cocoons Afterwards, it is mixed with mud;Another party's rule is merged in spinning process, is by photochromic dyes as core using composite spinning method, Using general fiber as sheath, congruent melting spinning obtains core-skin composite fiber.Photochromic dyes are preferably doped in resin carrier by this method In as the material that reels off raw silk from cocoons.In other embodiments, the raw materials such as usable polymers such as terylene, polyamide fibre, polyvinyl, polypropylene fibre and natural fibre Dimension, such as cotton, hair, silk, linen blended yarn.
Another embodiment of the present invention then coated UV line absorption material or light-induced variable dyestuff make it generate chemical change and make At color change effect, does not only reach and absorb ultraviolet light effect, but also ultraviolet protection, is seen because of color change See, promotes consumer and trust sense.In addition, recycling PET bottle can also be used as above-mentioned polymer material, reach environmentally friendly effect Fruit.In addition, the processing temperature of this case need to be less than dissociation temperature;And when adulterating macromolecule with ultraviolet radiation absorption dyestuff, color is added Female or conventional plastic dyestuff, makes it be uniformly distributed in polymer basis material.Coating process must make hydrophilic dyestuff attached It on the cloth outer layer of repellency, therefore inventor's hammer away, light-induced variable dyestuff and resin is mixed, such as 1:3-1:8 Weight percent mixes, and adjusts its adhesion coefficient and be less than 20, then can effectively adhere to and not fall off.
Therefore Fig. 2 is please referred to, the schematic cross-section of mask of the present invention is disclosed, may include three layers or four layers or more, this Embodiment is with three layers for example.Outer layer is a ultraviolet resistant layer 200, embodiments thereof can referring to above each implementation, including It uses spraying fabric or is made with chameleon fibre fabric.Middle layer is then filter layer 220, to filter dust, bacterium etc., Inner layer 240 can be that cotton makes, and can also use skin-friendly material, such as ice silk flosssilk wadding material or TPE etc..
A kind of ultraviolet-proof mask, the wherein mask include at least:Outer layer, including antiultraviolet material is sprayed at outer layer base On material, wherein the antiultraviolet material includes ultra-violet absorber;Middle layer, by may filter that the material of dust, bacterium forms;In Layer, is configured to be affixed on face, wherein the middle layer is located at the inner layer and the outer interlayer.Wherein the base material includes polyamide (Polyamide Fiber), polyester(Polyester Fiber), polyacrylonitrile(Polyacrylonitrile Fiber), it is poly- Ethylene(Polyethylene Fiber), polypropylene(Polypropylene Fiber), polyvinyl alcohol (Polyvinylalcohol Fiber), polyvinyl chloride(Polyvinylchloride Fiber), polytetrafluoroethylene (PTFE) (Polytetrafluoroethylene Fiber), polyacrylonitrile(PAN), nylon, polyethylene terephthalate(PET is washed Synthetic fibre), polybutylene terephthalate(PBT), polyurethane(Spandex)Or more arbitrary combination.Wherein above-mentioned base material with it is natural Fiber or semisynthetic fibre or synthetic fibers are blended.
If being limited to the technique board physical limit that reels off raw silk from cocoons, blame unfavorable technique conversion or output, then in another embodiment, on The mask outer layer stated is made of non-woven fabrics, can be saved spraying process, be please referred to Fig.3.The present invention, which removes that dyestuff can be adulterated, melts Together in cloth, and the board physical limit that do not reeled off raw silk from cocoons, thus be not easy to be scraped damage, tearing, shock and damage.Amalgamation mode include with It heats molten polymer or is dissolved light-induced variable dyestuff with polymer solution, it is made generally to be uniformly distributed therein.In addition In this stage, it is contemplated that dyestuff or color masterbatch is added, in favor of adjusting color.Being added in this stage may make dyestuff to be uniformly distributed In in whole cloth, color stability is made to be promoted.The present invention using light-induced variable dyestuff merge in cloth, dyestuff via sunlight Or reversible chemical variation is generated after ultraviolet light irradiation and leads to color change.It, can be extensive when not irradiated by above-mentioned sunlight or ultraviolet light Restore this color.Light-induced variable dyestuff simultaneously can be selectively doped in high molecular polymer together with light stabilizer and UV absorbents etc. Assist absorption ultraviolet light.Addition antioxidant and/or UV absorbents can be promoted anti-light tired in high molecular polymer.It is above-mentioned photic Off-color material can be spiro-pyrans, spirooxazine, fulgide, fulgenimide, chromene, aphthopyrans, spirobenzopyran, Spiral shell aphthopyrans, spiral shell benzoxazine, spiral shell naphtho- oxazines etc. (spiropyrans, spiroxazines, fulgide, fulgimides、benzopyran、naphthopyran、spirobenzopyran、spironaphthopyran、 Spirobenzoxazine or spironaphthoxazine), but be not limited with above-mentioned example.
In an example, the basic material of macromolecule or polymer is purchased first with light-induced variable dyestuff (according to thermotropic Dyestuff is that the energy absorption of ultraviolet light is generated discoloration at this time), referring to step 300, if color need to be adjusted, need to purchase biography System dyeing (non-light-induced variable) dyestuff or color masterbatch.Light-induced variable dyestuff or thermotropic dyestuff may be used or be added to photochromic molecule In polymer or resin material, above-mentioned basic material and light-induced variable dyestuff can be powdery, capsule shape, liquid, solution or Plastics material master batch.The two is uniformly mixed therewith, the macromolecule or the basic material of polymer are melted in heating makes its fusion, The dissociation temperature of above-mentioned light-induced variable dyestuff need to be less than by heating fusion temperature, with reference to step 310.For example, above-mentioned ratio can be mixed The light-induced variable material of example is formed with high molecular polymer, and melting concn is related to color changeable effect.If above-mentioned light-induced variable dyestuff is adopted With the selection of powder and processing temperature, then without using dispersant.Such as Celsius temperature is 150-180 or 180-220 degree.Implement Powdery, capsule shape, liquid, solution state light-induced variable dyestuff may be used in example.
The present invention adulterates photochromic dyes in high molecular polymer, with both heating fusion or solution fusion, wherein mixed Temperature need to be less than the dissociation temperature of photochromic dyes when conjunction.Before above-mentioned manufacturing process may need to by polymer drying and processing, Foundation deal and material, 1 to 5 hour etc., then by high molecular polymer and light-induced variable dyestuff mixed processing, add again later Work.To sum up, drying plastics and mixing light-induced variable material, stirring are allowed to uniform.Its base can be influenced for different temperatures and concentration The depth of this color, therefore it can be utilized to control required color with non-chromotropic dye.Light-induced variable material is via sunlight or ultraviolet Thermal change is generated after line irradiation.When not irradiated by above-mentioned sunlight or ultraviolet light, script color can be restored.Light-induced variable dyestuff absorbs sun Light or ultraviolet light and generate color change, therefore it be in addition to it can absorb ultraviolet light, and can cause fiber bodies color change, Increase fashion statement, also so that seeing of seeing of uvioresistant, and add antioxidant and/or UV absorbents can be promoted it is anti-light tired.
Light (or heat) causes chromotropic dye uniformly to be mixed with base polymer or high molecular material, when follow-up carry out, by this Mixed polymer basic material is placed in the solution tank of non-woven fabrics program, referring to step 320.Non-woven fabrics (non-woven fabric) It is called nonwoven fabric, raw material is handled with tailor's cushion machinery or carding machine, production cloth-like thing is formed or bonded with high pressure.Non-woven fabrics can be Staple fibre or synthetic fibers, raw material often (Polypropylene) containing polypropylene, abbreviation PP.Non-woven fabrics is unlike woven fabric is by longitude and latitude It weaves, non-woven fabrics is made with the difference of engineering method and is varied from, if tailor's cushion method is continuous by thousands of needle thorns Upper and lower acicular hook, therefore, the present invention can shorten technique, not by drawnwork machine physical limit, drawnwork tannin number limited.
Electrospinning processes (Electrospinning may be used in the technique of the present invention;ES), centrifugation spinning process (Force spinning;FS), molten spray spinning process (Solution blow spinning;SBS), EFI spinning process (Electroblowing;EB), compound spinning process (Islands in the sea, Segmented Pie, and side By side including SB and MB), spun-bonded non-woven fabrics technique (Spunbonding;SB), melt spraying non-woven fabrics technique (Meltblowing;MB).Such as United States Patent (USP) US 7931456, denomination of invention Electroblowing web formation It is proposed a kind of EFI spinning process;United States Patent (USP) US 6800226 proposes a kind of spun-bonded non-woven fabrics technique.In general, non-woven fabrics work Skill includes mainly several basic compositions:High voltage power supply, solution tank, nozzle, collector.Above-mentioned polymer, dye mixture solution Heating obtains non-woven fabrics after carrying out non-woven fabrics program, referring to step 330, claims cloth to can be used for various uses, such as uvioresistant at this time Clothing, trousers, cap, umbrella, mask, camp of line etc. and reach absorption ultraviolet light, and reduce ultraviolet light irradiation.Cloth alternative is such as touched Will cloth (Pongee) washs Lun Bu (Polyester), wherein it is more soft to touch will cloth (Pongee) quality.Wash Lun Bu (Polyester) quality is harder, and bottom can add silver color base oil and reinforce hiding brightness.Other can also be used, such as nylon cloth, Oxford Cloth, Se Dingbu, PVC, pearly-lustre cloth, EVA and T/C cottons etc..And various other programs such as dye, be embossed or pattern making belong to In this technical field there is ordinary skill to be appreciated that therefore does not repeat.
It is not that prior art such as is coated with anti-reflecting layer isolation ultraviolet, but is done using light-induced variable dyestuff based on the present invention At fiber absorb ultraviolet light, make its generate chemical change and cause color change effect, do not only reach absorb ultraviolet light effect, But also ultraviolet protection, that is seen because of color change sees, promotes consumer and trusts sense.In addition, recycling can also be used PET bottle reaches environment protecting as above-mentioned polymer material.In addition, the processing temperature of this case need to be less than dissociation temperature;And When adulterating macromolecule with ultraviolet radiation absorption dyestuff, color masterbatch or conventional plastic dyestuff is added, it is made to be uniformly distributed in macromolecule In basic material, rather than using subsequent dyeing in design on fabric surface.
To consider the gas exchange rate of mask, and absorption two factor of ultraviolet light, it is necessary to match dyestuff in right amount, Fig. 4 is warp SGS mechanisms detect, and only about 1 19 Ultraviolet B wave band can penetrate mask, imply that the Ultraviolet B wave band more than eighty per cant It is filtered out by the present invention.
Embodiment described above is only to absolutely prove preferred embodiment that is of the invention and being lifted, protection model of the invention It encloses without being limited thereto.Those skilled in the art on the basis of the present invention made by equivalent substitute or transformation, in the present invention Protection domain within.Protection scope of the present invention is subject to claims.

Claims (10)

1. a kind of ultraviolet-proof mask, which is characterized in that the ultraviolet-proof mask includes at least:
Outer layer, non-woven fabrics are ontology, including light-induced variable dyestuff can absorb ultraviolet light in the non-woven fabrics ontology;
Middle layer, the material by that can filter dust, bacterium form;
Inner layer is configured to be affixed on face, and wherein the middle layer is located between the inner layer and the outer layer.
2. ultraviolet-proof mask according to claim 1, which is characterized in that also include to be added comprising stable in melting program The combination of one or more of many kinds of substance in agent, antioxidant, ultra-violet absorber.
3. ultraviolet-proof mask according to claim 1, which is characterized in that wherein the temperature of the melting program is less than the light The dissociation temperature of mutagens dyestuff.
4. ultraviolet-proof mask according to claim 1,2 or 3, which is characterized in that wherein the material of the non-woven fabrics and should Light-induced variable dyestuff mixed proportion compares a ten thousandth for one than number a ten thousandth to one;One than a ten thousandth to one to ten thousand/five; 5 to one/10000th to ten thousand compares one thousandth;One than one thousandth to one than hundreds of points one.
5. ultraviolet-proof mask according to claim 1,2 or 3, which is characterized in that the material of the wherein non-woven fabrics includes Polyamide, polyester, polyacrylonitrile, polyethylene, polypropylene, polyvinyl alcohol, polyvinyl chloride, polytetrafluoroethylene (PTFE), polyacrylonitrile, Buddhist nun Arbitrary group of one or more of many kinds of substance in dragon, polyethylene terephthalate, polybutylene terephthalate, polyurethane It closes.
6. a kind of ultraviolet-proof mask, which is characterized in that the ultraviolet-proof mask includes at least:
Outer layer, non-woven fabrics are ontology, including antiultraviolet material is sprayed on outer layer, wherein the antiultraviolet material includes photic Become dyestuff;
Middle layer, the material by that can filter dust, bacterium form;
Inner layer is configured to be affixed on face, and wherein the middle layer is located at the inner layer and the outer interlayer.
7. ultraviolet-proof mask according to claim 6, which is characterized in that wherein the non-woven fabrics include polyamide, polyester, Polyacrylonitrile, polyethylene, polypropylene, polyvinyl alcohol, polyvinyl chloride, polytetrafluoroethylene (PTFE), polyacrylonitrile, nylon, poly- terephthaldehyde The arbitrary combination of one or more of many kinds of substance in sour second diester, polybutylene terephthalate, polyurethane.
8. a kind of ultraviolet-proof mask, which is characterized in that wherein the ultraviolet-proof mask includes at least:
Outer layer, non-woven fabrics are ontology, including ultraviolet light material can be absorbed in the non-woven fabrics ontology, wherein this can absorb ultraviolet light Material includes ultra-violet absorber;
Middle layer, the material by that can filter dust, bacterium form;
Inner layer is configured to be affixed on face, and wherein the middle layer is located at the inner layer and the outer interlayer.
9. ultraviolet-proof mask according to claim 8, which is characterized in that wherein the non-woven fabrics include polyamide, polyester, Polyacrylonitrile, polyethylene, polypropylene, polyvinyl alcohol, polyvinyl chloride, polytetrafluoroethylene (PTFE), polyacrylonitrile, nylon, poly- terephthaldehyde The arbitrary combination of one or more of many kinds of substance in sour second diester, polybutylene terephthalate, polyurethane.
10. ultraviolet-proof mask according to claim 8, which is characterized in that wherein above-mentioned non-woven fabrics also includes photic Become dyestuff.
CN201810020143.7A 2017-01-11 2018-01-09 Ultraviolet-proof mask Pending CN108294379A (en)

Applications Claiming Priority (4)

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TW106100882A TWI617336B (en) 2017-01-11 2017-01-11 Anti-uv photochromic mask
TW106100882 2017-01-11
TW106136753 2017-10-25
TW106136753A TW201917239A (en) 2017-10-25 2017-10-25 Non-woven fabric and the method of making the same

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CN109797544A (en) * 2018-12-28 2019-05-24 天长市东安防护用品有限公司 A kind of uvioresistant non-woven fabrics mask and preparation method thereof
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Application publication date: 20180720