CN108292592A - Imprinting apparatus and method - Google Patents

Imprinting apparatus and method Download PDF

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Publication number
CN108292592A
CN108292592A CN201680068257.8A CN201680068257A CN108292592A CN 108292592 A CN108292592 A CN 108292592A CN 201680068257 A CN201680068257 A CN 201680068257A CN 108292592 A CN108292592 A CN 108292592A
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CN
China
Prior art keywords
mould
substrate
plasma treatment
transferred
pine oil
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CN201680068257.8A
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Chinese (zh)
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CN108292592B (en
Inventor
具滋鹏
李眩雨
李南植
丘璜燮
金铉济
郑熙锡
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Ji Jialan Science And Technology Co Ltd
GigaLane Co Ltd
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Ji Jialan Science And Technology Co Ltd
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Filing date
Publication date
Priority claimed from KR1020160166099A external-priority patent/KR20170067665A/en
Application filed by Ji Jialan Science And Technology Co Ltd filed Critical Ji Jialan Science And Technology Co Ltd
Publication of CN108292592A publication Critical patent/CN108292592A/en
Application granted granted Critical
Publication of CN108292592B publication Critical patent/CN108292592B/en
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/02Manufacture or treatment of semiconductor devices or of parts thereof
    • H01L21/027Making masks on semiconductor bodies for further photolithographic processing not provided for in group H01L21/18 or H01L21/34
    • H01L21/0271Making masks on semiconductor bodies for further photolithographic processing not provided for in group H01L21/18 or H01L21/34 comprising organic layers
    • H01L21/0273Making masks on semiconductor bodies for further photolithographic processing not provided for in group H01L21/18 or H01L21/34 comprising organic layers characterised by the treatment of photoresist layers
    • H01L21/0274Photolithographic processes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C45/00Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
    • B29C45/17Component parts, details or accessories; Auxiliary operations
    • B29C45/26Moulds
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C45/00Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
    • B29C45/17Component parts, details or accessories; Auxiliary operations
    • B29C45/26Moulds
    • B29C45/263Moulds with mould wall parts provided with fine grooves or impressions, e.g. for record discs
    • B29C45/2632Stampers; Mountings thereof
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C45/00Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
    • B29C45/17Component parts, details or accessories; Auxiliary operations
    • B29C45/26Moulds
    • B29C45/263Moulds with mould wall parts provided with fine grooves or impressions, e.g. for record discs
    • B29C45/2642Heating or cooling means therefor
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C59/00Surface shaping of articles, e.g. embossing; Apparatus therefor
    • B29C59/02Surface shaping of articles, e.g. embossing; Apparatus therefor by mechanical means, e.g. pressing
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C59/00Surface shaping of articles, e.g. embossing; Apparatus therefor
    • B29C59/02Surface shaping of articles, e.g. embossing; Apparatus therefor by mechanical means, e.g. pressing
    • B29C59/026Surface shaping of articles, e.g. embossing; Apparatus therefor by mechanical means, e.g. pressing of layered or coated substantially flat surfaces
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C59/00Surface shaping of articles, e.g. embossing; Apparatus therefor
    • B29C59/14Surface shaping of articles, e.g. embossing; Apparatus therefor by plasma treatment
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C65/00Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C66/00General aspects of processes or apparatus for joining preformed parts
    • B29C66/80General aspects of machine operations or constructions and parts thereof
    • B29C66/83General aspects of machine operations or constructions and parts thereof characterised by the movement of the joining or pressing tools
    • B29C66/832Reciprocating joining or pressing tools
    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03FPHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
    • G03F7/00Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03FPHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
    • G03F7/00Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
    • G03F7/0002Lithographic processes using patterning methods other than those involving the exposure to radiation, e.g. by stamping
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/02Manufacture or treatment of semiconductor devices or of parts thereof
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/02Manufacture or treatment of semiconductor devices or of parts thereof
    • H01L21/02104Forming layers
    • H01L21/02107Forming insulating materials on a substrate
    • H01L21/02296Forming insulating materials on a substrate characterised by the treatment performed before or after the formation of the layer
    • H01L21/02299Forming insulating materials on a substrate characterised by the treatment performed before or after the formation of the layer pre-treatment
    • H01L21/02312Forming insulating materials on a substrate characterised by the treatment performed before or after the formation of the layer pre-treatment treatment by exposure to a gas or vapour
    • H01L21/02315Forming insulating materials on a substrate characterised by the treatment performed before or after the formation of the layer pre-treatment treatment by exposure to a gas or vapour treatment by exposure to a plasma
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/02Manufacture or treatment of semiconductor devices or of parts thereof
    • H01L21/027Making masks on semiconductor bodies for further photolithographic processing not provided for in group H01L21/18 or H01L21/34
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/02Manufacture or treatment of semiconductor devices or of parts thereof
    • H01L21/04Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer
    • H01L21/50Assembly of semiconductor devices using processes or apparatus not provided for in a single one of the subgroups H01L21/06 - H01L21/326, e.g. sealing of a cap to a base of a container
    • H01L21/56Encapsulations, e.g. encapsulation layers, coatings
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/02Manufacture or treatment of semiconductor devices or of parts thereof
    • H01L21/04Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer
    • H01L21/50Assembly of semiconductor devices using processes or apparatus not provided for in a single one of the subgroups H01L21/06 - H01L21/326, e.g. sealing of a cap to a base of a container
    • H01L21/56Encapsulations, e.g. encapsulation layers, coatings
    • H01L21/565Moulds
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/67Apparatus specially adapted for handling semiconductor or electric solid state devices during manufacture or treatment thereof; Apparatus specially adapted for handling wafers during manufacture or treatment of semiconductor or electric solid state devices or components ; Apparatus not specifically provided for elsewhere
    • H01L21/677Apparatus specially adapted for handling semiconductor or electric solid state devices during manufacture or treatment thereof; Apparatus specially adapted for handling wafers during manufacture or treatment of semiconductor or electric solid state devices or components ; Apparatus not specifically provided for elsewhere for conveying, e.g. between different workstations
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/67Apparatus specially adapted for handling semiconductor or electric solid state devices during manufacture or treatment thereof; Apparatus specially adapted for handling wafers during manufacture or treatment of semiconductor or electric solid state devices or components ; Apparatus not specifically provided for elsewhere
    • H01L21/677Apparatus specially adapted for handling semiconductor or electric solid state devices during manufacture or treatment thereof; Apparatus specially adapted for handling wafers during manufacture or treatment of semiconductor or electric solid state devices or components ; Apparatus not specifically provided for elsewhere for conveying, e.g. between different workstations
    • H01L21/67703Apparatus specially adapted for handling semiconductor or electric solid state devices during manufacture or treatment thereof; Apparatus specially adapted for handling wafers during manufacture or treatment of semiconductor or electric solid state devices or components ; Apparatus not specifically provided for elsewhere for conveying, e.g. between different workstations between different workstations
    • H01L21/67715Changing the direction of the conveying path
    • HELECTRICITY
    • H05ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05HPLASMA TECHNIQUE; PRODUCTION OF ACCELERATED ELECTRICALLY-CHARGED PARTICLES OR OF NEUTRONS; PRODUCTION OR ACCELERATION OF NEUTRAL MOLECULAR OR ATOMIC BEAMS
    • H05H1/00Generating plasma; Handling plasma
    • H05H1/24Generating plasma
    • H05H1/46Generating plasma using applied electromagnetic fields, e.g. high frequency or microwave energy

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  • Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Manufacturing & Machinery (AREA)
  • General Physics & Mathematics (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Computer Hardware Design (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • Power Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Plasma & Fusion (AREA)
  • Electromagnetism (AREA)
  • Spectroscopy & Molecular Physics (AREA)
  • Shaping Of Tube Ends By Bending Or Straightening (AREA)

Abstract

Invention describes a kind of imprinting apparatus and methods.The present invention imprinting apparatus include:Surface modification portion, the surface to forming figuratum mould carry out plasma treatment;Engaging portion, in a manner of enabling the pattern for the mould for having carried out plasma treatment to be stamped in substrate, in conjunction with the mould and the substrate;And separation unit, detach the mould being combined and the substrate.

Description

Imprinting apparatus and method
Technical field
The present invention relates to a kind of to be coated on the resin of substrate surface to transfer imprinting apparatus and the side of pattern with mould pressurization Method.
Background technology
Nano-imprint lithography engineering is a kind of not only economical but also can effectively make nanostructure (nano- Structure technology) is spin coating (spin-coating) or spot printing (dispensing) tree on base material (substrate) Fat, and will be formed and figuratum be molded to resin surface to transfer the technology of (transfer) pattern.
Nano-imprint lithography engineering can substantially be divided into heated type (thermal-type) and ultraviolet light radiation modality.
Heated type engineering is referred to as thermal transfer (Hot Embossing) or thermal imprint lithography (Thermal Imprint Lithography), be it is a kind of so that mould is contacted with the base material for being formed with macromolecule layer after, heating and to macromolecule layer provide flowing Property, and apply pressure the method for producing desired pattern on macromolecule layer.This heated type engineering exists because of thermal deformation And the problem of being difficult to carry out Multilayer aligned, and due to needing higher pressure to imprint the larger resin of viscosity, thus deposit In the frangible problem of pattern.
It is to improve the nano-imprint lithography engineering of ultraviolet light radiation modality developed the problem of this heated type engineering A method of the ultraviolet light using low viscosity photocurable resin and for hardening it, since work can be executed with Room-temperature low-pressure Journey, thus suitable for carrying out multiple stratification and mass production.
In the nano-imprint lithography engineering of previous ultraviolet light radiation modality, if first coating UV cured use on substrate It after resin, is pressed using mould, then hardening resin will be filled up between the pattern of mould.At this point, since viscosity is low, even if lower It can be also easy with resin between the pattern for filling up mould under pressure.Later, if being felt to resin by transparent mould by UV light sources Light, then resin be hardened.Later, if taking mould, remnant layer will be remained between pattern, is ashed by oxygen and removes the remnant layer To complete engineering.
In the engineering of above-mentioned previous ultraviolet light radiation modality, also self-assembled monolayer can be coated on the surface of mould Improve release property, but there are problems that the required coating processing time is longer, productivity of product declines.
In addition, in the case where carrying out other coating processing to mould, there are price competitiveness declines, and be additionally formed Coat can be sticky in the separation of substrate and mould so that the shortcomings that mould is difficult to reuse.
Further, it since the re-usability of mould declines, needs only to transfer mould to a direction, thus productivity declines, and Resin application process etc. carries out leading to not carry out in other place or equipment successional engineering, thus exist need compared with More working spaces, and the problem of need the more activity duration.
It is served only for promoting the understanding of the background to the present invention as the item illustrated by above-mentioned background technology, should not be understood as Approval belongs to the known prior art of general technical staff to this field.
Existing technical literature
Patent document 1:KR 10-2012-0127731(2012.11.23)
Invention content
Technical problem
The purpose of the present invention is to provide a kind of imprinting apparatus and method for improving release property and capable of reusing mould.
Technical solution
For reach this purpose the present invention imprinting apparatus include:Surface modification portion, to forming figuratum mould Surface carry out plasma treatment;Engaging portion so that the pattern for having carried out the mould of plasma treatment can be stamped in The mode of substrate, in conjunction with the mould and the substrate;And separation unit, detach the mould being combined and the substrate.
The imprinting apparatus is characterized in that the plasma is to including one in air, argon gas, oxygen and nitrogen A above gas applies RF and generates.
The imprinting apparatus is characterized in that, further includes transferred unit, transfers the mould, the transferred unit will be at described point From part from the mould be transferred to surface modification portion, be reused described so that plasma treatment can be carried out to the mould Mould.
The imprinting apparatus further includes control unit, combination to the mould and the substrate or detaches number and counts Number, and the transferred unit is controlled according to set number, the mould is changed to new mould.
The imprinting apparatus further includes control unit, check the separate section from mould surface state, according to institute It states surface state and controls the transferred unit and the mould is changed to new mould.
The imprinting apparatus is characterized in that, between surface modification portion, engaging portion and the spaced regulation of separation unit Transfer direction away from and along the mould is arranged in order.
The imprinting apparatus is characterized in that, between the engaging portion, surface modification portion and the spaced regulation of separation unit Transfer direction away from and along the mould is arranged in order.
The mould includes spaced regulation spacing and is set to the first mould in the transferred unit and the second mould, the table Face modification portion includes being respectively separated regulation spacing across the engaging portion and the first surface modification portion being arranged and second surface change Property portion, the separation unit include across the engaging portion and the surface modification moiety not Jian Ge regulation spacing and be arranged first Separation unit and the second separation unit, the transferred unit will be detached in any of described first, second separation unit described first Or second mould be transferred to any of described first, second surface modification portion.
The imprinting apparatus further includes painting part, and the substrate top is coated with resin.
The painting part includes:Spin coating portion, on the substrate portion's applying liquid resin;And drying section, drying The resin.
The engaging portion includes:Chamber maintains low vacuum state, can prevent foreign matter from flowing into;And hardening portion, Make the hardening of resin on the substrate.
The imprinting apparatus is characterized in that the transferred unit includes:PET film;First roller supplies the one of the PET film It holds in conjunction with and winds;And second roller, for the PET film the other end in conjunction with and wind and provided with first roller interval Spacing and configure, the mould is formed on the PET film.
The imprinting apparatus includes:Surface modification portion, the surface to forming figuratum mould carry out plasma treatment;With And work department, the stamping is pressed on the substrate, so that the pattern for having carried out the mould of plasma treatment can be rushed It is pressed on substrate, and from mould described in the substrate pine oil.
A kind of method for stamping, including:The mistake that plasma treatment is carried out to be modified to the surface for forming figuratum mould Journey;The pattern die of the mould of plasma treatment will have been carried out in the process of substrate;And it is loose from the substrate being stamped Release the process of the mould.
The method for stamping is characterized in that, executes the process of the plasma treatment, can reuse through the pine The mould for the process released.
The method for stamping further includes that set punching press or pine oil will be performed in the mould of the process through the pine oil Several moulds is changed to the process of new mould.
A kind of method for stamping, which is characterized in that including:Carry out plasma treatment with to formed the surface of figuratum mould into The modified process of row;The mould is transferred to a direction and the pattern die of the mould that will carry out plasma treatment is in substrate Process;The mould is transferred to a direction and from the process of mould described in the substrate pine oil being stamped;Institute is transferred to other direction It states mould and carries out plasma treatment with to the process being modified by the surface of the mould of pine oil;The mould is transferred to a direction And the pattern die of the mould of plasma treatment will be carried out in the process of new substrate;And transfer the mould to a direction And from the process of mould described in the new substrate pine oil being stamped, each process is carried out repeatedly and continuously.
A kind of method for stamping, which is characterized in that including:Carry out plasma treatment with to formed the surface of figuratum mould into The modified process of row;The mould is transferred to other direction and the pattern die of the mould that will carry out plasma treatment is in substrate Process;The mould is transferred to a direction and from the process of mould described in the substrate pine oil being stamped;It is transferred to other direction The mould and to by the mould of pine oil surface carry out plasma treatment process;Transfer the mould to other direction and will be into Gone plasma treatment the mould pattern die in the process of new substrate;And to a direction transfer the mould and from quilt The process of mould, each process described in the new substrate pine oil of punching press are carried out repeatedly and continuously.
A kind of method for stamping, using forming the figuratum more than two substrates of first, second die stamping, the coining side Method is characterized in that, carries out plasma treatment so that the surface to first mould is modified and first stamping is pressed on the One substrate, and after plasma treatment is modified with the surface to second mould, rushed from the first substrate pine oil While first mould of pressure, second stamping for having carried out plasma treatment is pressed on second substrate.
The method for stamping is characterised by comprising:Plasma treatment is carried out with the surface to first mould to change The process of property;First mould is transferred to a direction and will carry out the pattern die of first mould of plasma treatment in The process of one substrate;First, second mould is transferred to a direction and carries out plasma treatment with the surface to second mould The process being modified;First, second mould is transferred to a direction and from the first mould described in the substrate pine oil being stamped While, the pattern die of second mould of plasma treatment will have been carried out in the process of second substrate;It is moved to other direction It send first, second mould and carries out plasma treatment with to the process being modified by the surface of first mould of pine oil; And transfer first, second mould to other direction and the pattern die of first mould that plasma treatment will have been carried out in While third substrate, from the process of the second mould described in the second substrate pine oil being stamped, each process is anti- It continuously carries out again.
The method for stamping is characterized in that the plasma is to including one in air, argon gas, oxygen and nitrogen A above gas applies RF and generates.
A kind of imprinting apparatus, which is characterized in that including:Engaging portion, so that the pattern energy for the mould being surface-treated It is enough stamped in substrate;Separation unit detaches the mode of the mould and the substrate that are combined, in conjunction with the mould and the base Plate;And transferred unit, transfer the mould, the transferred unit by the separate section from the mould be transferred to the combination Portion and reuse the mould.
A kind of method for stamping, which is characterized in that including:By the pattern die for the mould being surface-treated in the mistake of substrate Journey;The mould is transferred to a direction and from the process of mould described in the substrate pine oil being stamped;Described in other direction transfer Mould and by the pattern die for the mould being surface-treated in the process of new substrate;And transfer the mould to a direction And from the process of mould described in the new substrate pine oil being stamped, each process is carried out repeatedly and continuously.
The effect of invention
In accordance with the invention it is possible to realize following multi-effect.
First, improve the release property of mould.
Second, have the advantages that engineering time and expense can be shortened.
Third has the advantages that mould can be reused.
Description of the drawings
Fig. 1 is the figure for the imprinting apparatus for showing the embodiment of the present invention 1;
Fig. 2 is the figure for the method for stamping for showing the embodiment of the present invention 1;
Fig. 3 is the figure for the method for stamping for showing the embodiment of the present invention 1;
Fig. 4 is the figure for the method for stamping for showing the embodiment of the present invention 1;
Fig. 5 is the figure for the imprinting apparatus for showing the embodiment of the present invention 2;And
Fig. 6 is the figure for the method for stamping for showing the embodiment of the present invention 2.
Symbol description
The engaging portions 10-, 12- pressing parts, 14- hardening portion, 16- chambers, the surfaces 20- modification portion, 22- first surfaces are modified Portion, 24- second surface modifications portion, 30- separation units, the first separation units of 32-, the second separation units of 34-, 40- transferred unit, 50- coatings Portion, 52- spin coatings portion, 54- drying sections, the first moulds of M1-, the second moulds of M2-, B1- first substrates, B2- second substrates, B3- third bases Plate, B- substrates, R1, R2- a pair of rolls.
Specific implementation mode
The purpose of the present invention, some specific advantages and new feature will be from the relevant following detailed descriptions of attached drawing and in fact It applies in example and becomes more apparent upon.It should be noted that in this specification, it is right when the inscape to each figure adds reference marks It makes it have and is identically numbered as possible in identical inscape, if even if being shown in other figures.In addition, first, second etc. Term can be used in a variety of inscapes of explanation, but these inscapes should not be limited to these terms.These terms are only used Make the purpose of one inscape and another inscape of differentiation.In addition, during illustrating the present invention, when being judged as to phase Pass known technology illustrates it is possible that when unnecessarily the gist of the invention being made not know, description is omitted.
The embodiment of the present invention is illustrated with reference to the accompanying drawings.
As illustrated in Fig. 1 to Fig. 6, imprinting apparatus of the invention include surface modification portion 20, engaging portion 10, separation unit 30 with And transferred unit 40.
The present invention imprinting apparatus and method be the surfaces mould M are modified to improve the release property of mould M and substrate B, and Reciprocal transfer mould M, so as to reuse the technology of mould M.
Mould M is functionally divided into master mold (Master mold) and backed stamper (replica mold) and distinguishes, and can be with According to there are many material sections, such as Si moulds, Ni moulds, Resin moulds etc..
In the present invention, mould M can be formed on PET film, and according to the intention of designer, above-mentioned mould M could be formed with a variety of Pattern can also make selected from multiple material.
Transferred unit 40 plays the function that above-mentioned mould M is transferred to positive direction or reverse direction.The case where mould M is formed in PET film Under, above-mentioned transferred unit 40 can be designed as include a pair of rolls R1, R2 structure, the both ends of PET film are being individually fixed in one In the state of two pairs of rollers R1, R2, if by a pair of rolls R1, R2 side direction (hereinafter, claim " positive direction ") or side from right to left from left to right Direction (hereinafter, claiming " reverse direction ") rotation, then the mould M for being formed in PET film are also moved to positive direction or reverse direction, can be carried out Reciprocal transfer.
At this point, the mould M detached in separation unit 30 can be transferred to surface modification portion 20 by transferred unit 40, can carry out etc. Ion processing and reuse.
This transferred unit 40 can be replaced by various mechanisms such as conveyer belt or mechanical arms.
Surface modification portion 20 is modified and improves the release property of mould M to forming the surfaces figuratum mould M, plays big The function of carrying out plasma treatment under air pressure to the surfaces mould M, preferably to including air (Air) or argon gas (Ar), oxygen (O2), nitrogen Gas (N2) any of gas apply RF (radio frequency, Radio Frequency) to form plasma, and to the surfaces mould M into Row is modified.
When carrying out plasma treatment, if more than 80 DEG C, mould M can melt or be bent, thus preferably in 80 DEG C or less low temperature Lower carry out plasma treatment.
In addition, to improve the modified effect on the surfaces mould M, preferably applied between the RF antennas and RF power supply of atmos plasma Add plasma adaptation (Matcher) to make load impedance and source impedance match.
Engaging portion 10 includes pressing part 12, and punching press has carried out the mould M of plasma treatment, so that pattern can be needed on Substrate B.
Separation unit 30 plays after pattern is needed on substrate, from the function of substrate pine oil mould M.
In this way, in order to combine, splitting die M and substrate B, although engaging portion 10 and separation unit 30 can be separately provided, It can introduce while play the work department (not shown) of punching press and pine oil function.
For example, if work department (not shown) by opening/closing control by that can carry out length elongation and the piston of diminution Bar or even mechanical arm are constituted, then mould M will with being acted come stamping substrate downwards by work department (not shown), and with It works and is detached from from substrate upward.
In addition, work department (not shown) can also be embodied in the structure that can be moved using transferred unit 40, that is, when When positioned at chamber 16, decline mould M under opening (ON) state and suppress substrate B to carry out punching course, and is detached when being located at When portion 30, restore to original position to detach with substrate B from closing (OFF) state to carry out pine oil process.
On the other hand, imprinting apparatus of the invention further includes control unit (not shown).
In order to reuse mould M, control unit controls transferred unit so that existing mould to be changed to new mould.Specifically, control Portion to the combination of mould M and substrate or can also detach number and be counted and be changed to mould M according to set number new Mould.Mould M is changed to according to surface state by new mould in the mould M surface state that separation unit 30 detaches alternatively, can also check.
[embodiment 1]
In the imprinting apparatus of the embodiment of the present invention, as illustrated in fig. 1, surface modification portion 20, engaging portion 10 and point From portion 30 can spaced regulation spacing and set gradually along positive direction, as shown in Fig. 2, engaging portion 10, face modification portion 20 with And separation unit 30 can also spaced regulation spacing and the positive direction along mould M is set gradually.
In addition, as illustrated in fig. 3, the position in the surface modification portion 20 and separation unit 30 that can also make Fig. 1 it is displaced from one another and Setting.
The position in this surface modification portion 20, engaging portion 10 and separation unit 30 can carry out more according to the intention of designer Kind deformation setting.
On the other hand, imprinting apparatus of the invention further includes painting part 50.
Substrate B is periodically provided to engaging portion 10, painting part 50 uses resin coated base after painting part 50 is coated The tops plate B, and according to the present invention, have the advantages that the successional engineering for being coated to pattern and transferring from substrate B can be carried out.
Painting part 50 includes spin coating portion 52 and drying section 54, and spin coating portion 52 plays rotary plate and resin is made to pass through centrifugal force It is uniformly coated in the function on substrate B, drying section 54 plays drying and is uniformly coated in the work(of the resin on substrate B Energy.
In this way, if resin is uniformly coated in substrate B and drying, substrate B is transferred to engaging portion 10.
Other than pressing part 12, engaging portion 10 may include:Chamber 16 maintains low vacuum state, different can prevent Logistics enters;And hardening portion 14, make the hardening of resin on substrate B.
The method for stamping of the present invention is illustrated with reference to the accompanying drawings.
It is illustrated as shown in Figure 1, Figure 2, it rotates first substrate B1 in the spin coating portion 52 of painting part 50 and resin is made to pass through centrifugal force It is uniformly coated on substrate B, and dries the resin being uniformly coated in drying section 54.
In the state that resin is coated and dries, first substrate B1 is provided to the low vacuum chamber 16 of engaging portion 10.
On the other hand, atmospheric plasma processes are carried out to mould M by surface modification portion 20 with mould M, at plasma The mould M for managing and having carried out surface modification will be pressed with being transferred to positive direction on low vacuum chamber 16, and with passing through The action in portion 12 processed makes mould M and substrate B be needed on the punching course of substrate B in conjunction with and into exercising the pattern of mould M.
The mould M and substrate B combined in chamber 16 is moved to positive direction again with the action of transferred unit 40, mould M and substrate B Separation unit 30 will be located at the state being combined, and make mould M and substrate B separation in separation unit 30.
Later, plasma is carried out to the surfaces mould M again from upper side direction to the left (hereinafter, claiming " reverse direction ") transfer mould M Processing, and again to positive direction transfer mould M and so that mould M patterns is stamped after new substrate B, to positive direction transfer mould M and it is loose New substrate is released, this process is carried out repeatedly and continuously.
On the other hand, the embodiment of the method for stamping of the present invention is illustrated with reference to Fig. 3.
As illustrated in fig. 3, method for stamping of the invention is carried out with following process:It is carried out to forming the surfaces figuratum mould M Plasma treatment, and mould M is transferred by M pattern dies after substrate B to reverse direction, transfer mould M and pine oil substrate to positive direction B。
Later, the process for carrying out plasma treatment is executed, the mould M of the process through pine oil can be reused.
Specifically, transfer mould M to reverse direction and plasma treatment is carried out to the surfaces mould M again, and again to reverse direction Mould M is transferred by mould M pattern dies after new substrate B, mould M is transferred and the new substrate of pine oil to positive direction.
Repeatedly and continuity carry out above-mentioned each process so as to shorten engineering time, and improve productivity.
It is also possible to include that will perform set punching press or pine oil number in the mould of the process through pine oil Mould be changed to the process of new mould.Specifically, more to change the mold, transferred unit 40 is acted so as to be adjacent to the new of existing mould Mould come the position of existing mould.
On the other hand, Fig. 4 is the another embodiment of the method for stamping of the present invention.According to an above-mentioned embodiment (with reference to Fig. 2) Apparatus structure, this method for stamping is different only in sequence of movement, thus to be replaced to the explanation of an above-mentioned embodiment.
[embodiment 2]
Hereinafter, during illustrating embodiment 2, for convenience, saying to structure same as Example 1 will be omitted It is bright.
As illustrated in fig. 5, in the imprinting apparatus of another embodiment of the present invention, mould M include spaced regulation spacing and It is set to the first mould M1 and the second mould M2 of the setting in transferred unit 40, surface modification portion 20 includes between the difference of engaging portion 10 Every the first surface modification portion 22 and second surface modification portion 24 that regulation spacing is arranged, separation unit 30 includes across engaging portion 10 The first separation unit 32 and the second separation unit 34 for being respectively separated regulation spacing with surface modification portion 20 and being arranged.In addition, transferred unit The first or second mould M1 or M2 that are detached in the first, second separation unit 32, any of 34 are transferred to the first, second table by 40 Face modification portion 22, any of 24.
Specifically, side direction (hereinafter, claiming " positive direction ") is fixedly installed the second separation unit 34, the second table from left to right Face modification portion 24, engaging portion 10, first surface modification portion 22 and the first separation unit 32.
Transferred unit 40 moves back and forth on this fixed line to positive direction or reverse direction, and first is provided in transferred unit 40 Mould M1 and the second mould M2.
First mould M1 and the second mould M2 carries out surface modification in first surface modification portion 22, second surface modification portion 24, and Respectively after engaging portion 10 is combined with substrate B, detached respectively from substrate B in the first separation unit 32 and the second separation unit 34, substrate B After painting part 50 is coated, it is periodically provided to engaging portion 10.
Fig. 5 and Fig. 6 illustrates another embodiment of the method for stamping of the present invention with reference to the accompanying drawings.
Another embodiment of the present invention is to utilize to form the more than two bases of figuratum first, second mould M1, M2 punching press The method for stamping of plate, is technically characterized in that, is carried out at the same time the process to first, second mould M1, M2 punching press respectively and pine oil Process.Thereby, it is possible to improve productivity.
That is, plasma treatment is carried out to be modified to the first surfaces mould M1, and punching press is in first substrate B1, and carry out etc. After ion processing is to be modified the second surfaces mould M2, from the first mould M1 that first substrate B1 pine oils are stamped while, will The second mould M2 punching presses of plasma treatment have been carried out in second substrate B2.
The method for stamping of the imprinting apparatus using Fig. 5 is specifically described below as process.
First substrate B1 is rotated so that resin is uniformly coated by centrifugal force in base in the spin coating portion 52 of painting part 50 On plate B, and the resin being uniformly coated is dried in drying section 54.
In the state that resin is coated and dries, first substrate B1 is provided to the low vacuum chamber 16 of engaging portion 10.
On the other hand, first mould M1 is carried out at atmos plasma by second surface modification portion 24 with the first mould M1 Reason, the first mould M1 that is plasma treated and having carried out surface modification will be located at low vacuum chamber with being transferred to positive direction On 16, and as the action by pressing part 12 makes the first mould M1 and first substrate B1 combine, into the pattern for exercising the first mould M1 It is needed on the punching course of first substrate B1.
At this point, the second mould M2 for being spaced regulation spacing on identical PET film with the first mould M1 and being arranged will be located at second In separation unit 34, and the second separation unit 34 is not acted separately, but maintains wait state.
The the first mould M1 and first substrate B1 combined in chamber 16 is moved to positive direction again with the action of transferred unit 40.
If the first mould M1 and first substrate B1 is moved to first surface modification portion 22, the second mould M2 with the state being combined Second surface modification portion 24 will be located at.
At this point, first surface modification portion 22 does not work separately, the only work of second surface modification portion 24 comes to the second mould M2 Surface carries out plasma treatment and is modified.
If the second surfaces mould M2 are modified, task transfers the second mould M2, the state being combined to transferred unit 40 again First mould M1 and first substrate B1, the first mould M1 and first substrate B1 will be located at the first separation unit 32 with the state being combined, the Two mould M2 are transferred to engaging portion 10.
Later, the first mould M1 is made to be detached with first substrate B1 in the first separation unit 32.
While carrying out the separation process of the first mould M1 and first substrate B1, the second mould M2 is applied in painting part 50 It covers processing and is combined in the 16 waiting second substrate B2 in inside of chamber, to make the pattern of the second mould M2 be needed on the second base Plate B2.
After the separation of first mould M1 and first substrate B1 and the cohesive process of the second mould M2 and second substrate B2, move Sending portion 40 to transfer the first mould M1, the second mould M2 of the state being combined and second substrate B2, the first mould M1 to reverse direction will be located at First surface modification portion 22, the second mould M2 and second substrate B2 will be located at second surface modification portion 24 with the state being combined.
At this point, first surface modification portion 22 is to open ON states, and plasma treatment is carried out to the first surfaces mould M1.Into In a period of the row process, second surface modification portion 24 is to close (OFF) state, is not acted separately.
If the plasma treatment on the first surfaces mould M1 terminates, transferred unit 40 is carried out to reverse direction again, in the first mould M1 While positioned at 16 inside of chamber of engaging portion 10, the second mould M2 and second substrate B2 will be located at the second separation unit 34.
Later, the first mould M1 is combined in the 16 waiting third substrate B3 in inside of chamber, and is solved in the second separation unit 34 Except the bonding state of the second mould M2 and second substrate B2.
On the other hand, the imprinting apparatus of another embodiment of the present invention is technically characterized in that, although to improve release property Using the physics mode of such as plasma treatment, but be surface-treated using the chemical mode formed by such as coat Mould.
The imprinting apparatus of above-mentioned specific descriptions includes:Engaging portion, to make by having carried out surface in a manner of physically or chemically The pattern of the mould of processing can be stamped in the mode of substrate, in conjunction with mould and substrate;Separation unit detaches the mould and base being combined Plate;And transferred unit, transfer mould.In addition, transferred unit be configured to by separate section from mould be transferred to engaging portion and make again Use mould.
Method for stamping using this imprinting apparatus includes:The mould that will be surface-treated by physically or chemically mode Pattern die in the process of substrate;To direction transfer mould from the process for the substrate pine oil mould being stamped;To other direction Transfer mould and by the pattern die for the mould being surface-treated in the process of new substrate;And to a direction transfer mould and from The process of mould described in the new substrate pine oil being stamped.In addition, this each process is carried out repeatedly and continuously.
It, can be based on the embodiment of the present invention to upper although being illustrated centered on the embodiment of the present invention above It states number or configuration of the inscape of surface modification portion, engaging portion, separation unit etc. etc. and carries out various deformation, it is clear that Ground, this variation are also fallen into the interest field of the present invention.

Claims (23)

1. a kind of imprinting apparatus, which is characterized in that including:
Surface modification portion carries out plasma treatment to forming figuratum mould surface;
Engaging portion, in a manner of enabling the pattern for the mould for having carried out plasma treatment to be stamped in substrate, in conjunction with institute State mould and the substrate;And
Separation unit detaches the mould being combined and the substrate.
2. imprinting apparatus according to claim 1, which is characterized in that
The plasma is generated to applying RF including the more than one gas in air, argon gas, oxygen and nitrogen.
3. imprinting apparatus according to claim 1, which is characterized in that
Further include transferred unit, transfer the mould,
The transferred unit by the separate section from the mould be transferred to surface modification portion, with can to the mould into Row plasma treatment and reuse the mould.
4. imprinting apparatus according to claim 3, which is characterized in that
Further include control unit, combination to the mould and the substrate or detach number and count, and according to set Number controls the transferred unit and the mould is changed to new mould.
5. imprinting apparatus according to claim 3, which is characterized in that
Further include control unit, check the separate section from mould surface state, according to the surface state control described in The mould is changed to new mould by transferred unit.
6. imprinting apparatus according to claim 3, which is characterized in that
Surface modification portion, engaging portion and the spaced regulation spacing of separation unit and arranged successively along the transfer direction of the mould Row.
7. imprinting apparatus according to claim 3, which is characterized in that
The engaging portion, surface modification portion and the spaced regulation spacing of separation unit and arranged successively along the transfer direction of the mould Row.
8. imprinting apparatus according to claim 3, which is characterized in that
The mould includes spaced regulation spacing and is set to the first mould in the transferred unit and the second mould,
Surface modification portion include be respectively separated regulation spacing across the engaging portion and the first surface modification portion that is arranged and Second surface modification portion,
The separation unit include across the engaging portion and the surface modification moiety not Jian Ge regulation spacing and be arranged first Separation unit and the second separation unit,
The first or second mould detached in any of described first, second separation unit is transferred to institute by the transferred unit State any of first, second surface modification portion.
9. imprinting apparatus according to claim 3, which is characterized in that
Further include painting part, the substrate top is coated with resin.
10. imprinting apparatus according to claim 9, which is characterized in that
The painting part includes:
Spin coating portion, on the substrate portion's applying liquid resin;And
Drying section dries the resin.
11. imprinting apparatus according to claim 3, which is characterized in that
The engaging portion includes:
Chamber maintains low vacuum state, can prevent foreign matter from flowing into;And
Hardening portion makes the hardening of resin on the substrate.
12. imprinting apparatus according to claim 11, which is characterized in that
The transferred unit includes:
PET film;
First roller, for the PET film one end in conjunction with and wind;And
Second roller, for the PET film the other end in conjunction with and wind and with first roller interval regulation spacing and configure,
The mould is formed on the PET film.
13. a kind of imprinting apparatus, which is characterized in that including:
Surface modification portion carries out plasma treatment to forming figuratum mould surface;And
Work department will be described in a manner of so that the pattern for the mould for having carried out plasma treatment is stamped in substrate Stamping is pressed on the substrate, and from mould described in the substrate pine oil.
14. a kind of method for stamping, which is characterized in that including:
The process that plasma treatment is carried out to be modified to the surface for forming figuratum mould;
The pattern die of the mould of plasma treatment will have been carried out in the process of substrate;And
From the process of mould described in the substrate pine oil being stamped.
15. method for stamping according to claim 14, which is characterized in that
The process for executing the plasma treatment, the mould of the process through the pine oil can be reused.
16. method for stamping according to claim 14, which is characterized in that
Further include will be performed in the mould of the process through the pine oil set punching press or pine oil number mould be changed to it is new The process of mould.
17. a kind of method for stamping, which is characterized in that including:
The process that plasma treatment is carried out to be modified to the surface for forming figuratum mould;
The mould is transferred to a direction and the pattern die of the mould that will carry out plasma treatment is in the process of substrate;
The mould is transferred to a direction and from the process of mould described in the substrate pine oil being stamped;
The mould is transferred to other direction and carries out plasma treatment with to the mistake being modified by the surface of the mould of pine oil Journey;
The mould is transferred to a direction and the pattern die of the mould that will carry out plasma treatment is in the process of new substrate; And
Transfer the mould to a direction and from the process of mould described in the new substrate pine oil being stamped,
Each process is carried out repeatedly and continuously.
18. a kind of method for stamping, which is characterized in that including:
The process that plasma treatment is carried out to be modified to the surface for forming figuratum mould;
The mould is transferred to other direction and the pattern die of the mould that will carry out plasma treatment is in the process of substrate;
The mould is transferred to a direction and from the process of mould described in the substrate pine oil being stamped;
To other direction transfer the mould and to being carried out the process of plasma treatment by the surface of the mould of pine oil;
The mould is transferred to other direction and the pattern die of the mould that will carry out plasma treatment is in the mistake of new substrate Journey;And
Transfer the mould to a direction and from the process of mould described in the new substrate pine oil being stamped,
Each process is carried out repeatedly and continuously.
19. a kind of method for stamping, using forming the figuratum more than two substrates of first, second die stamping, the coining side Method is characterized in that,
Plasma treatment is carried out to be modified with the surface to first mould and first stamping is pressed on first substrate, and It carries out after plasma treatment is modified with the surface to second mould, described the to be stamped from the first substrate pine oil While one mould, second stamping for having carried out plasma treatment is pressed on second substrate.
20. method for stamping according to claim 19, which is characterized in that including:
Carry out the process that plasma treatment is modified with the surface to first mould;
First mould is transferred to a direction and the pattern die of first mould that will carry out plasma treatment is in the first base The process of plate;
First, second mould is transferred to a direction and carries out what plasma treatment was modified with the surface to second mould Process;
Transfer first, second mould to a direction and from described in the substrate pine oil being stamped while the first mould, will be into Gone plasma treatment second mould pattern die in the process of second substrate;
First, second mould is transferred to other direction and carries out plasma treatment with to by the surface of first mould of pine oil The process being modified;And
Transfer first, second mould to other direction and the pattern die of first mould that plasma treatment will have been carried out in While third substrate, from the process of the second mould described in the second substrate pine oil being stamped,
Each process is carried out repeatedly and continuously.
21. the method for stamping according to any one of claim 14 to 20, which is characterized in that
The plasma is generated to applying RF including the more than one gas in air, argon gas, oxygen and nitrogen.
22. a kind of imprinting apparatus, which is characterized in that including:
Engaging portion, in a manner of so that the pattern for the mould being surface-treated is stamped in substrate, in conjunction with the mould and The substrate;
Separation unit detaches the mould being combined and the substrate;And
Transferred unit transfers the mould,
The transferred unit by the separate section from the mould be transferred to the engaging portion and reuse the mould.
23. a kind of method for stamping, which is characterized in that including:
By the pattern die for the mould being surface-treated in the process of substrate;
The mould is transferred to a direction and from the process of mould described in the substrate pine oil being stamped;
The mould is transferred to other direction and by the pattern die for the mould being surface-treated in the process of new substrate; And
Transfer the mould to a direction and from the process of mould described in the new substrate pine oil being stamped,
Each process is carried out repeatedly and continuously.
CN201680068257.8A 2015-12-08 2016-12-08 Imprint apparatus and method Active CN108292592B (en)

Applications Claiming Priority (7)

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KR10-2015-0174408 2015-12-08
KR20150174408 2015-12-08
KR10-2015-0174416 2015-12-08
KR20150174416 2015-12-08
KR10-2016-0166099 2016-12-07
KR1020160166099A KR20170067665A (en) 2015-12-08 2016-12-07 Apparatus and method for imprinting
PCT/KR2016/014375 WO2017099492A1 (en) 2015-12-08 2016-12-08 Imprint device and method

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JP2004148494A (en) * 2002-10-24 2004-05-27 Hewlett-Packard Development Co Lp Hardening nano-imprinting stamp
JP2008179034A (en) * 2007-01-24 2008-08-07 Toppan Printing Co Ltd Imprint mold, imprint mold manufacturing method, and surface reforming device
JP2011146447A (en) * 2010-01-12 2011-07-28 Canon Inc Imprint apparatus and article manufacturing method
CN104094379A (en) * 2012-02-07 2014-10-08 佳能株式会社 Imprint apparatus and method of manufacturing article
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