CN108285678A - A kind of organic and inorganic tertiary colour material of environment-friendly type and production technology - Google Patents
A kind of organic and inorganic tertiary colour material of environment-friendly type and production technology Download PDFInfo
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- CN108285678A CN108285678A CN201810108769.3A CN201810108769A CN108285678A CN 108285678 A CN108285678 A CN 108285678A CN 201810108769 A CN201810108769 A CN 201810108769A CN 108285678 A CN108285678 A CN 108285678A
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- Prior art keywords
- organic
- inorganic
- pigment
- environment
- tertiary colour
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
- C09C1/36—Compounds of titanium
- C09C1/3607—Titanium dioxide
- C09C1/3669—Treatment with low-molecular organic compounds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
- C09C1/0081—Composite particulate pigments or fillers, i.e. containing at least two solid phases, except those consisting of coated particles of one compound
- C09C1/0084—Composite particulate pigments or fillers, i.e. containing at least two solid phases, except those consisting of coated particles of one compound containing titanium dioxide
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C3/00—Treatment in general of inorganic materials, other than fibrous fillers, to enhance their pigmenting or filling properties
- C09C3/006—Combinations of treatments provided for in groups C09C3/04 - C09C3/12
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C3/00—Treatment in general of inorganic materials, other than fibrous fillers, to enhance their pigmenting or filling properties
- C09C3/04—Physical treatment, e.g. grinding, treatment with ultrasonic vibrations
- C09C3/041—Grinding
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C3/00—Treatment in general of inorganic materials, other than fibrous fillers, to enhance their pigmenting or filling properties
- C09C3/08—Treatment with low-molecular-weight non-polymer organic compounds
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Composite Materials (AREA)
- Pigments, Carbon Blacks, Or Wood Stains (AREA)
Abstract
The present invention relates to fine chemicals production fields, disclose a kind of organic and inorganic tertiary colour material of environment-friendly type and production technology, pass through formulas optimized design, organic pigment and inorganic pigment are surface-treated, it is ground into nano level ultramicron in shearing grinding device, by the method for its surface physical reaction, makes quantitative charge on these ultra micro pigment particles bands, assigns some special applications functions, make it suitable for the application in the high-tech products such as electronics, computer；Tertiary colour material by rational design, by multiple performance Indexs measure, property indices are identical with reference substance or are better than reference substance, to substitute the maturation process technology of lead chromate pigments.
Description
Technical field
The present invention relates to fine chemicals production field, the organic and inorganic tertiary colour material of especially a kind of environment-friendly type and production
Technique.
Background technology
According to Chinese coating association statistics in 2015, more than 30 family of existing lead chromate pigments manufacturing enterprise of China, distribution
In national 14 provinces, municipalities and autonomous regions, annual capacity total amount is 86,000 ton, 69,000 ton of total output.Each enterprise be generally used as
Under technological process, produce lead chromate pigments：
It is prepared by plumbi nitras that -- -- filtration washing -- drying and crushing -- colorant match is packed for pigment synthesis；
Producing capital equipment is：
Ba Erdun stoves, reaction kettle, filter press, drying machine, pulverizer, mixing machine etc..
Often produce one ton of lead chromate pigments, 300 degree of electricity consumption, with 33 tons of water, using steam coal consumption equal quantity be 0.23 ton, give birth to
Producing the wastewater flow rate discharged in the process is：30 tons or so/ton product.According to the difference of kind, the weight contained in lead chromate pigments
The ratio of metallic lead and chromium is different, and statistical data is shown, in average lead chromate pigments per ton, leaded weight is about 600
Kilogram or so/ton product, the weight containing 6 valence chromium is not less than 100 kgs/tonne products.
Due to the old backwardness of production technology, so, in process of production, environmental pollution is big, energy consumption is big, resource is unrestrained
Fei great, labor intensity are big, under the promotion of this " four big " resultant force, have produced a lead chromate pigments product, and this product
Itself, and leaded secondary pollution also is caused to natural environment in addition to endangering human health containing chromium.
Invention content
The purpose of the present invention is to provide a kind of organic and inorganic tertiary colour material of environment-friendly type and production technologies, pass through organic face
Material and inorganic pigment are surface-treated, and organic pigment particle and inorganic pigment granules is made to merge into an organic whole, the composite pigment of formation,
Have organic pigment and all whole excellent properties of inorganic pigment, bright in color light, tinting strength, tinting power is high, and oil absorption is low, covering power
By force, good dispersion, resistance to migration is splendid, and has excellent weather-proof and heat resistance.
To realize above-mentioned technical purpose and the technique effect, that the invention discloses a kind of environment-friendly types is organic and inorganic multiple
Color material is closed, the formula of tertiary colour material includes inorganic pigment, organic pigment and surfactant, and inorganic pigment is titanium dioxide or oxygen
Change or mixtures thereof one kind in iron pigment, organic pigment is permanent yellow or everbright fast yellow, and surfactant is lived for non-ionic surface
Property agent or anion surfactant, the weight ratio of inorganic pigment and organic pigment is 1:10-10:1, the dosage of surfactant
For the 2wt%-10wt% of whole finished products.
Wherein, nonionic surfactant is fatty alcohol polyethenoxy ether class, aliphatic acid polyethenoxy in surfactant
One kind in esters or polyalcohols.
Wherein, anion surfactant is fatty acid salt or sulfonate in surfactant.
The invention also discloses a kind of organic and inorganic tertiary colour material production technology of environment-friendly type, production technology is using above-mentioned multiple
Prepared by the formula for closing color material, production craft step is as follows：
It weighs：It is accurate to weigh inorganic pigment, organic pigment, surfactant, it puts into high energy shear milling machine；
It is pulverized and mixed：Start high energy shear milling machine, be stirred 1 minute, shuts down 3 minutes, can discharge for 5 times repeatedly.
Wherein, the operating parameter of high energy shear milling machine is 2000-20000 revs/min of rotating speed, and temperature of charge is 30- in machine
60°C。
The invention has the advantages that：
1. the present invention is surface-treated by formulas optimized design by organic pigment and inorganic pigment, dress is crushed in shearing
Nano level ultramicron is ground into setting, by the method for its surface physical reaction, it is fixed on these ultra micro pigment particles bands to make
Amount charge assigns some special applications functions, makes it suitable for the application in the high-tech products such as electronics, computer.
2. by the tertiary colour material rationally designed, by multiple performance Indexs measure, property indices and control condition
Together or it is better than reference substance, to substitute the maturation process technology of lead chromate pigments.
Specific implementation mode
In order to make the purpose , technical scheme and advantage of the present invention be clearer, with reference to embodiments, to the present invention
It is further elaborated.
Embodiment 1
The invention discloses a kind of organic and inorganic tertiary colour material of environment-friendly type and production technologies, and the formula of tertiary colour material includes nothing
Machine pigment, organic pigment and surfactant, inorganic pigment are or mixtures thereof one kind in titanium dioxide or iron oxide pigment, are had
Machine pigment is permanent yellow or everbright fast yellow, and surfactant is nonionic surfactant or anion surfactant, inorganic face
The weight ratio of material and organic pigment is 1:10-10:1, the dosage of surfactant is the 2wt%-10wt% of whole finished products.
Wherein, nonionic surfactant is fatty alcohol polyethenoxy ether class, aliphatic acid polyethenoxy in surfactant
One kind in esters or polyalcohols, anion surfactant are fatty acid salt, sulfonate.
The production craft step of tertiary colour material is as follows：
It weighs：It is accurate to weigh inorganic pigment, organic pigment, surfactant, it puts into high energy shear milling machine；
It is pulverized and mixed：Start high energy shear milling machine, be stirred 1 minute, shuts down 3 minutes, can discharge for 5 times repeatedly.
Wherein, the operating parameter of high energy shear milling machine is 2000-20000 revs/min of rotating speed, and temperature of charge is 30- in machine
60°C。
Embodiment 2
The invention discloses a kind of organic and inorganic tertiary colour material of environment-friendly type and production technologies, and wherein inorganic pigment is titanium dioxide
800g, organic pigment permanent yellow 200g, surfactant are Arlacel-80 30g, and production technology is same as Example 1.
Embodiment 3
The invention discloses a kind of organic and inorganic tertiary colour material of environment-friendly type and production technologies, and wherein inorganic pigment is titanium dioxide
600g, organic pigment everbright fast yellow 400g, surfactant are Arlacel-80 30g, and production technology is same as Example 1.
Embodiment 4
The invention discloses a kind of organic and inorganic tertiary colour material of environment-friendly type and production technologies, and wherein inorganic pigment is titanium dioxide
800g, organic pigment permanent yellow 200g, surfactant are Tween-80 30g, and production technology is same as Example 1.
Embodiment 5
The invention discloses a kind of organic and inorganic tertiary colour material of environment-friendly type and production technologies, and wherein inorganic pigment is titanium dioxide
800g, organic pigment permanent yellow 200g, surfactant are turkey red oil 30g, and production technology is same as Example 1.
Embodiment 6
The invention discloses a kind of organic and inorganic tertiary colour material of environment-friendly type and production technologies, and wherein inorganic pigment is titanium dioxide
800g, iron oxide red 50g, organic pigment everbright fast yellow 150g, surfactant are Arlacel-80 30g, production technology and implementation
Example 1 is identical.
Embodiment 7
The invention discloses a kind of organic and inorganic tertiary colour material of environment-friendly type and production technologies, and wherein inorganic pigment is titanium dioxide
700g, iron oxide yellow 50g, organic pigment everbright fast yellow 200g, surfactant are Arlacel-80 30g, production technology and implementation
Example 1 is identical.
Embodiment 8
The present embodiment using embodiment 2 product as experimental subjects, to its coloured light, tinting strength, tinting power, covering power, oil absorption, heat-resisting, resistance to
Light, acidproof, alkaline-resisting, dispersed, resistance to migration, wherein coloured light, tinting strength, tinting power binomial are detected using criterion keying method, and when detection makes
Standard control sample is commercially available lead chromate pigments product.The method and steps of detection is all issued according to country or industry
The detection method standard of cloth executes, and details are not described herein again.
The key technical indexes of 1 tertiary colour material of table
| Index name | It judges | Standard method | Remarks |
| Coloured light | It is micro- -- it is close | It is compareed with standard specimen | |
| Tinting strength, tinting power | ≧ 95% | It is compareed with standard specimen | |
| Covering power | ≦55 | g/㎡ | |
| Oil absorption | ≦18 | ml/g | |
| It is heat-resisting | 240℃ | HG/T3853-2006 | |
| It is fast light | 7 grades | 1-8 grades | |
| It is acidproof | 5 grades | 1-5 grades | |
| It is alkaline-resisting | 5 grades | 1-5 grades | |
| Dispersibility | It is good | GB/T9287-1988 | |
| Resistance to migration | 5 | 1-5 grades | EN14469-3 |
By detecting comparison it can be found that by taking 2 product of embodiment as an example, product is all equivalent in every technical performance or is better than phase
The lead chromate pigments kind answered.
The foregoing is only a preferred embodiment of the present invention, but scope of protection of the present invention is not limited thereto,
Any one skilled in the art in the technical scope disclosed by the present invention, the change or replacement that can be readily occurred in,
It should be covered by the protection scope of the present invention.
Claims (5)
1. a kind of organic and inorganic tertiary colour material of environment-friendly type, which is characterized in that the formula of the tertiary colour material includes inorganic face
Material, organic pigment and surfactant, the inorganic pigment are or mixtures thereof one kind in titanium dioxide or iron oxide pigment,
The organic pigment is permanent yellow or everbright fast yellow, and the surfactant is nonionic surfactant or anionic surface
The weight ratio of activating agent, the inorganic pigment and organic pigment is 1:10-10:1, the dosage of the surfactant is complete
The 2wt%-10wt% of portion's finished product.
2. a kind of organic and inorganic tertiary colour material of environment-friendly type as described in claim 1, it is characterised in that：The surface-active
Nonionic surfactant is one in fatty alcohol polyethenoxy ether class, polyoxyethylene carboxylate class or polyalcohols in agent
Kind.
3. a kind of organic and inorganic tertiary colour material of environment-friendly type as claimed in claim 1 or 2, it is characterised in that：It lives on the surface
Property agent in anion surfactant be fatty acid salt or sulfonate.
4. a kind of organic and inorganic tertiary colour material production technology of environment-friendly type, it is characterised in that：The production technology is wanted using right
The formula of any one of 1-3 tertiary colour materials is asked to be prepared, production craft step is as follows：
It weighs：It is accurate to weigh inorganic pigment, organic pigment, surfactant, it puts into high energy shear milling machine；
It is pulverized and mixed：Start high energy shear milling machine, be stirred 1 minute, shuts down 3 minutes, can discharge for 5 times repeatedly.
5. a kind of organic and inorganic tertiary colour material production technology of environment-friendly type as claimed in claim 4, it is characterised in that：Described
The operating parameter of high energy shear milling machine is 2000-20000 revs/min of rotating speed, and temperature of charge is 30-60 °C in machine.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810108769.3A CN108285678A (en) | 2018-02-05 | 2018-02-05 | A kind of organic and inorganic tertiary colour material of environment-friendly type and production technology |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810108769.3A CN108285678A (en) | 2018-02-05 | 2018-02-05 | A kind of organic and inorganic tertiary colour material of environment-friendly type and production technology |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN108285678A true CN108285678A (en) | 2018-07-17 |
Family
ID=62836390
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810108769.3A Pending CN108285678A (en) | 2018-02-05 | 2018-02-05 | A kind of organic and inorganic tertiary colour material of environment-friendly type and production technology |
Country Status (1)
| Country | Link |
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| CN (1) | CN108285678A (en) |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1849374A (en) * | 2003-09-12 | 2006-10-18 | 科莱恩产品（德国）有限公司 | Pigment compositions consisting of organic and inorganic pigments |
| CN102483472A (en) * | 2009-09-30 | 2012-05-30 | 富士胶片株式会社 | Black curable composition for wafer level lens and wafer level lens |
| CN104356861A (en) * | 2014-11-10 | 2015-02-18 | 兴化市兴成铜业有限公司 | Composition for inner laminated insulating film of screening can and screening can inner laminating method |
-
2018
- 2018-02-05 CN CN201810108769.3A patent/CN108285678A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1849374A (en) * | 2003-09-12 | 2006-10-18 | 科莱恩产品（德国）有限公司 | Pigment compositions consisting of organic and inorganic pigments |
| CN102483472A (en) * | 2009-09-30 | 2012-05-30 | 富士胶片株式会社 | Black curable composition for wafer level lens and wafer level lens |
| CN104356861A (en) * | 2014-11-10 | 2015-02-18 | 兴化市兴成铜业有限公司 | Composition for inner laminated insulating film of screening can and screening can inner laminating method |
Non-Patent Citations (1)
| Title |
|---|
| 林学军: "无机一有机复合颜料的制备及性能研究", 《内蒙古大学硕士学位论文》 * |
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Application publication date: 20180717 |