CN108276845B - Environment-friendly oil painting shaping paste - Google Patents
Environment-friendly oil painting shaping paste Download PDFInfo
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- CN108276845B CN108276845B CN201810144248.3A CN201810144248A CN108276845B CN 108276845 B CN108276845 B CN 108276845B CN 201810144248 A CN201810144248 A CN 201810144248A CN 108276845 B CN108276845 B CN 108276845B
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D131/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid, or of a haloformic acid; Coating compositions based on derivatives of such polymers
- C09D131/02—Homopolymers or copolymers of esters of monocarboxylic acids
- C09D131/04—Homopolymers or copolymers of vinyl acetate
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/06—Artists' paints
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
- C08K2003/265—Calcium, strontium or barium carbonate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Abstract
The invention discloses an environment-friendly oil painting shaping paste which is characterized by comprising the following components in parts by weight: the invention discloses an environment-friendly oil painting shaping paste, which is an opaque shaping paste.
Description
Technical Field
The present invention belongs to the field of fine chemical engineering, and is one kind of three-dimensional forming paste material for replacing pigment in the early stage production of oil painting and ornament.
Background
The invention relates to a shaping paste, which is an artistic creation material with low cost and excellent performance produced by using common chemical raw materials under the condition of a normal production process. The performance of the shaping paste simultaneously meets the following conditions:
A. the adhesive force is strong, and the adhesive can be firmly attached to the used interface without falling off.
B. The plasticity is good (the plasticity of professional inner finger materials is not chemically known, the surface of the paste is touched by fingers or a drawing knife in a general condition and is slowly pulled up, and the paste moves along with gestures and stands for more than 10mm without deformation and falling tip.
C. The fluidity is good, which means that the ointment can form smooth, mellow and smooth lines under the condition of adding water for dilution. When the lines are attached to other interfaces, the dry film is not shrunk and deformed. When the roller is used for construction, fluff of the roller can be naturally recovered without adhesion.
D. The shaping paste can slide with the tool during use, and when the movement is stopped, the paste can be kept to be smooth without tail dragging, and the surface texture of the dry film is smooth and fine.
E. Good toughness, which means that the dry film of the paste has certain elasticity. A glue film with the width of 10mm and the thickness of more than 5mm and any length is molded by paste, after the glue film is completely dried, a round bar with the diameter of 5-10mm is wound around the glue film without cracks, and the glue film is not broken by manual pressing.
F. The synchronous drying performance is good, which means that the paste is almost dried inside, outside, above and below at the same time in use, and no obvious skinning phenomenon is formed on the surface.
The inventor's prior application 201210389772.X discloses a direct molding paste which achieves this goal with the following scheme based on the above requirements.
①, using elastic colloid as base material (vinyl acetate-ethylene copolymer emulsion, acrylic acid emulsion), 705 emulsion produced by Sichuan vinylon factory, 8101 emulsion of Guangdong Yinyang resin Co., Ltd., 8518 emulsion:
②, taking dibutyl phthalate and chlorinated paraffin as plasticizer and smoothing agent, preferably dibutyl phthalate produced by zilu petrochemical industry and 52-degree chlorinated paraffin produced by Henan;
③, aromatic hydrocarbon solvent is used as thickening and lubricating agent, preferably toluene produced by the famous petrochemical industry;
④, cellulose is used as thickening and toughening agent, preferably 1000Pa.s viscosity of sodium carboxymethyl cellulose or liquid thickening agent;
⑤, controlling the cost by white latex, preferably 25-30% white latex;
⑥, selecting proper dispersant and defoamer according to the requirement;
⑦, the filler is selected from anatase titanium dioxide, lithopone, 800-1200 mesh light calcium carbonate and 300-400 mesh heavy calcium carbonate.
The invention aims to creatively upgrade and reform the plastic material on the basis of the prior invention according to the market requirement, so that the plastic effect is better; and under the condition of good ventilation, the general shaping paste is dried completely within 12-24 hours when coated with one centimeter, and industrial operation is not utilized. In addition, the use amount of toluene is greatly reduced, and the method is more environment-friendly.
Disclosure of Invention
Aiming at the defects in the prior art, the invention provides the environment-friendly oil painting shaping paste which has the advantages of better plasticity effect and the like.
The purpose of the invention can be realized by the following technical scheme:
the environment-friendly oil painting shaping paste is characterized in that: the molding paste is non-transparent molding paste, and the non-transparent molding paste is prepared from the following raw materials in parts by weight:
emulsion 100-130kg
Under the stirring state of a high-speed dispersion machine, the following raw materials are sequentially added into the emulsion and stirred for about 5 minutes,
mixing, ultrasonically dispersing for 5min, adding trehalose powder 1kg into the mixture, heating to 80 deg.C, maintaining for 20min, cooling to 5 deg.C, maintaining for 30min, recovering to room temperature, sequentially adding the following materials,
stirring the mixed raw materials for 40-60 minutes, and cooling for later use;
or the nontransparent shaping paste consists of the following raw materials in parts by weight:
80-100kg of emulsion
Under the stirring state of a high-speed dispersion machine, the following raw materials are sequentially added into the emulsion and stirred for about 5 minutes,
mixing, ultrasonically dispersing for 5min, adding trehalose powder 1kg into the mixture, heating to 80 deg.C, maintaining for 20min, cooling to 5 deg.C, maintaining for 30min, recovering to room temperature, sequentially adding the following materials,
stirring the mixed raw materials for 40-60 minutes, and cooling for later use;
the emulsion is YS-8101 emulsion or VAE 705 emulsion;
as a preference, the first and second liquid crystal compositions are,
the mesh number of the light calcium carbonate is 800-1200 meshes;
the mesh number of the double-flying powder is 300-400 meshes.
The chlorinated paraffin is 52-degree chlorinated paraffin produced in Henan.
The liquid thickener is replaced by 1.5-3kg of carboxymethyl cellulose.
The liquid thickener was replaced by sodium carboxymethylcellulose with a viscosity of 800-1000 Pa.s.
The preparation method of the cross-linked sweet potato starch comprises the following steps: under the condition that the weight of the sweet potato starch is 20 parts, the adding amount of 8% sodium hydroxide solution is 16 parts by weight, the adding amount of epichlorohydrin is 2 parts by weight, the reaction time is 5 hours, and the reaction temperature is controlled at 45 ℃.
The inventor unexpectedly finds that the plasticity of the shaping paste can be obviously improved and the drying time can be obviously shortened by comprehensively applying ultrasonic dispersion, trehalose powder and cross-linked sweet potato starch at a specific stage and controlling the temperature, and in addition, the use amount of toluene is greatly reduced, so that the shaping paste is more environment-friendly.
The invention also provides an environment-friendly oil painting shaping paste, which is characterized in that: the shaping paste is transparent and is composed of the following raw materials by weight: transparent shaping paste:
or
Or
Or
The invention has the advantages that:
(1) greatly reduces the using amount of toluene and is more environment-friendly.
(2) The plasticity of the shaping paste can be obviously improved and the drying time can be obviously shortened by comprehensively using ultrasonic dispersion, trehalose powder and cross-linked sweet potato starch at a specific stage and controlling the temperature.
Detailed Description
Example 1:
the environment-friendly oil painting shaping paste is characterized in that: the molding paste is non-transparent molding paste, and the non-transparent molding paste is prepared from the following raw materials in parts by weight:
emulsion 100kg
Under the stirring state of a high-speed dispersion machine, the following raw materials are sequentially added into the emulsion and stirred for about 5 minutes,
mixing, ultrasonically dispersing for 5min, adding trehalose powder 1kg into the mixture, heating to 80 deg.C, maintaining for 20min, cooling to 5 deg.C, maintaining for 30min, recovering to room temperature, sequentially adding the following materials,
stirring the mixed raw materials for 40 minutes, and cooling for later use;
the emulsion is VAE 705 emulsion;
the mesh number of the light calcium carbonate is 800-1200 meshes;
the mesh number of the double-flying powder is 300-400 meshes.
The chlorinated paraffin is 52-degree chlorinated paraffin produced in Henan.
The liquid thickener is replaced by 1.5-3kg of carboxymethyl cellulose.
The liquid thickener was replaced by sodium carboxymethylcellulose with a viscosity of 800-1000 Pa.s.
The preparation method of the cross-linked sweet potato starch comprises the following steps: under the condition that the weight of the sweet potato starch is 20 parts, the adding amount of 8% sodium hydroxide solution is 16 parts by weight, the adding amount of epichlorohydrin is 2 parts by weight, the reaction time is 5 hours, and the reaction temperature is controlled at 45 ℃.
As a comparison, when the shaping paste of the prior application 201210389772.X is coated with a thickness of one centimeter, the shaping paste is dried completely within 12 to 24 hours, the shaping paste is touched with fingers or a drawing knife to be slowly pulled up, and the shaping paste is upright along with the movement of gestures and does not deform and tip over 10 to 13 mm.
Results of this example: when the paste is coated to a thickness of one centimeter, the paste is dried completely in 8 hours, the paste is touched by fingers or a drawing knife and is slowly pulled up, and the paste is upright and does not deform and fall down over 17mm along with the movement of gestures.
Example 2:
the environment-friendly oil painting shaping paste is characterized in that: the molding paste is non-transparent molding paste, and the non-transparent molding paste is prepared from the following raw materials in parts by weight:
130kg of emulsion
Under the stirring state of a high-speed dispersion machine, the following raw materials are sequentially added into the emulsion and stirred for about 5 minutes,
mixing, ultrasonically dispersing for 5min, adding trehalose powder 1kg into the mixture, heating to 80 deg.C, maintaining for 20min, cooling to 5 deg.C, maintaining for 30min, recovering to room temperature, sequentially adding the following materials,
stirring the mixed raw materials for 60 minutes, and cooling for later use;
the emulsion is VAE 705 emulsion;
the mesh number of the light calcium carbonate is 800-1200 meshes;
the mesh number of the double-flying powder is 300-400 meshes.
The chlorinated paraffin is 52-degree chlorinated paraffin produced in Henan.
The liquid thickener is replaced by 1.5-3kg of carboxymethyl cellulose.
The liquid thickener was replaced by sodium carboxymethylcellulose with a viscosity of 800-1000 Pa.s.
The preparation method of the cross-linked sweet potato starch comprises the following steps: under the condition that the weight of the sweet potato starch is 20 parts, the adding amount of 8% sodium hydroxide solution is 16 parts by weight, the adding amount of epichlorohydrin is 2 parts by weight, the reaction time is 5 hours, and the reaction temperature is controlled at 45 ℃.
As a comparison, when the shaping paste of the prior application 201210389772.X is coated with a thickness of one centimeter, the shaping paste is dried completely within 12 to 24 hours, the shaping paste is touched with fingers or a drawing knife to be slowly pulled up, and the shaping paste is upright along with the movement of gestures and does not deform and tip over 10 to 13 mm.
Results of this example: when the paste is coated to a thickness of one centimeter, the paste is dried completely in 9 hours, the paste is touched by fingers or a drawing knife and is slowly pulled up, and the paste is upright and does not deform and tip over 16mm along with the movement of gestures.
Example 3:
the environment-friendly oil painting shaping paste is characterized in that: the molding paste is non-transparent molding paste, and the non-transparent molding paste is prepared from the following raw materials in parts by weight:
120kg of emulsion
Under the stirring state of a high-speed dispersion machine, the following raw materials are sequentially added into the emulsion and stirred for about 5 minutes,
mixing, ultrasonically dispersing for 5min, adding trehalose powder 1kg into the mixture, heating to 80 deg.C, maintaining for 20min, cooling to 5 deg.C, maintaining for 30min, recovering to room temperature, sequentially adding the following materials,
stirring the mixed raw materials for 50 minutes, and cooling for later use;
the emulsion is VAE 705 emulsion;
the mesh number of the light calcium carbonate is 800-1200 meshes;
the mesh number of the double-flying powder is 300-400 meshes.
The chlorinated paraffin is 52-degree chlorinated paraffin produced in Henan.
The liquid thickener is replaced by 1.5-3kg of carboxymethyl cellulose.
The liquid thickener was replaced by sodium carboxymethylcellulose with a viscosity of 800-1000 Pa.s.
The preparation method of the cross-linked sweet potato starch comprises the following steps: under the condition that the weight of the sweet potato starch is 20 parts, the adding amount of 8% sodium hydroxide solution is 16 parts by weight, the adding amount of epichlorohydrin is 2 parts by weight, the reaction time is 5 hours, and the reaction temperature is controlled at 45 ℃.
As a comparison, when the shaping paste of the prior application 201210389772.X is coated with a thickness of one centimeter, the shaping paste is dried completely within 12 to 24 hours, the shaping paste is touched with fingers or a drawing knife to be slowly pulled up, and the shaping paste is upright along with the movement of gestures and does not deform and tip over 10 to 13 mm.
Results of this example: when the paste is coated to a thickness of one centimeter, the paste is dried completely in 4 hours, the paste is touched by fingers or a drawing knife and is slowly pulled up, and the paste is upright for more than 20mm along with the movement of gestures and is not deformed and does not tip.
Example 4:
the environment-friendly oil painting shaping paste is characterized in that: the molding paste is non-transparent molding paste, and the non-transparent molding paste is prepared from the following raw materials in parts by weight:
95kg of emulsion
Under the stirring state of a high-speed dispersion machine, the following raw materials are sequentially added into the emulsion and stirred for about 5 minutes,
mixing, ultrasonically dispersing for 5min, adding trehalose powder 1kg into the mixture, heating to 80 deg.C, maintaining for 20min, cooling to 5 deg.C, maintaining for 30min, recovering to room temperature, sequentially adding the following materials,
stirring the mixed raw materials for 45 minutes, and cooling for later use;
the emulsion is YS-8101 emulsion;
the mesh number of the light calcium carbonate is 800-1200 meshes;
the mesh number of the double-flying powder is 300-400 meshes.
The chlorinated paraffin is 52-degree chlorinated paraffin produced in Henan.
The liquid thickener is replaced by 1.5-3kg of carboxymethyl cellulose.
The liquid thickener was replaced by sodium carboxymethylcellulose with a viscosity of 800-1000 Pa.s.
The preparation method of the cross-linked sweet potato starch comprises the following steps: under the condition that the weight of the sweet potato starch is 20 parts, the adding amount of 8% sodium hydroxide solution is 16 parts by weight, the adding amount of epichlorohydrin is 2 parts by weight, the reaction time is 5 hours, and the reaction temperature is controlled at 45 ℃.
As a comparison, when the shaping paste of the prior application 201210389772.X is coated with a thickness of one centimeter, the shaping paste is dried completely within 12 to 24 hours, the shaping paste is touched with fingers or a drawing knife to be slowly pulled up, and the shaping paste is upright along with the movement of gestures and does not deform and tip over 10 to 13 mm.
Results of this example: when the paste is coated to a thickness of one centimeter, the paste is dried completely in 7 hours, the paste is touched by fingers or a drawing knife and is slowly pulled up, and the paste is upright and does not deform and tip over 12mm along with the movement of gestures.
Example 5:
the environment-friendly oil painting shaping paste is characterized in that: the molding paste is non-transparent molding paste, and the non-transparent molding paste is prepared from the following raw materials in parts by weight:
emulsion 93kg
Under the stirring state of a high-speed dispersion machine, the following raw materials are sequentially added into the emulsion and stirred for about 5 minutes,
mixing, ultrasonically dispersing for 5min, adding trehalose powder 1kg into the mixture, heating to 80 deg.C, maintaining for 20min, cooling to 5 deg.C, maintaining for 30min, recovering to room temperature, sequentially adding the following materials,
stirring the mixed raw materials for 60 minutes, and cooling for later use;
the emulsion is YS-8101 emulsion;
the mesh number of the light calcium carbonate is 800-1200 meshes;
the mesh number of the double-flying powder is 300-400 meshes.
The chlorinated paraffin is 52-degree chlorinated paraffin produced in Henan.
The liquid thickener is replaced by 1.5-3kg of carboxymethyl cellulose.
The liquid thickener was replaced by sodium carboxymethylcellulose with a viscosity of 800-1000 Pa.s.
The preparation method of the cross-linked sweet potato starch comprises the following steps: under the condition that the weight of the sweet potato starch is 20 parts, the adding amount of 8% sodium hydroxide solution is 16 parts by weight, the adding amount of epichlorohydrin is 2 parts by weight, the reaction time is 5 hours, and the reaction temperature is controlled at 45 ℃.
As a comparison, when the shaping paste of the prior application 201210389772.X is coated with a thickness of one centimeter, the shaping paste is dried completely within 12 to 24 hours, the shaping paste is touched with fingers or a drawing knife to be slowly pulled up, and the shaping paste is upright along with the movement of gestures and does not deform and tip over 10 to 13 mm.
Results of this example: when the paste is coated to a thickness of one centimeter, the paste is dried completely in 8 hours, the paste is touched by fingers or a drawing knife and is slowly pulled up, and the paste is upright along with the movement of gestures and does not deform and tip.
The inventor unexpectedly finds that the plasticity of the shaping paste can be obviously improved and the drying time can be obviously shortened by comprehensively applying ultrasonic dispersion, trehalose powder and cross-linked sweet potato starch at a specific stage and controlling the temperature, in addition, the using amount of toluene is greatly reduced, the shaping paste is more environment-friendly, the factors are very important, the effect is seriously influenced by the absence of any factor, the using amount of toluene cannot be reduced, and the quick-drying time of less than 10 hours can be achieved.
The above description is only for the preferred embodiment of the present invention, but the scope of the present invention is not limited thereto, and any person skilled in the art should be considered to be within the technical scope of the present invention, and the technical solutions and the inventive concepts thereof according to the present invention should be equivalent or changed within the scope of the present invention.
Claims (3)
1. A production method of environment-friendly oil painting shaping paste is characterized by comprising the following steps: the molding paste is non-transparent molding paste, and the non-transparent molding paste is prepared from the following raw materials in parts by weight:
emulsion 100-130kg
Under the stirring state of a high-speed dispersion machine, the following raw materials are sequentially added into the emulsion and stirred for about 5 minutes,
mixing, ultrasonically dispersing for 5min, adding trehalose powder 1kg into the mixture, heating to 80 deg.C, maintaining for 20min, cooling to 5 deg.C, maintaining for 30min, recovering to room temperature, sequentially adding the following materials,
stirring the mixed raw materials for 40-60 minutes, and cooling for later use;
or the nontransparent shaping paste consists of the following raw materials in parts by weight:
80-100kg of emulsion
Under the stirring state of a high-speed dispersion machine, the following raw materials are sequentially added into the emulsion and stirred for about 5 minutes,
mixing, ultrasonically dispersing for 5min, adding trehalose powder 1kg into the mixture, heating to 80 deg.C, maintaining for 20min, cooling to 5 deg.C, maintaining for 30min, recovering to room temperature, sequentially adding the following materials,
stirring the mixed raw materials for 40-60 minutes, and cooling for later use;
the emulsion is YS-8101 emulsion or VAE 705 emulsion;
the mesh number of the light calcium carbonate is 800-1200 meshes;
the mesh number of the double-flying powder is 300-400 meshes;
the chlorinated paraffin is 52-degree chlorinated paraffin produced in Henan province
The preparation method of the cross-linked sweet potato starch comprises the following steps: under the condition that the weight of the sweet potato starch is 20 parts, the adding amount of 8% sodium hydroxide solution is 16 parts by weight, the adding amount of epichlorohydrin is 2 parts by weight, the reaction time is 5 hours, and the reaction temperature is controlled at 45 ℃.
2. The method for producing the environment-friendly oil painting shaping paste of claim 1, which is characterized by comprising the following steps:
the liquid thickener is replaced by 1.5-3kg of carboxymethyl cellulose.
3. The method for producing the environment-friendly oil painting shaping paste of claim 1, which is characterized by comprising the following steps:
the liquid thickener was replaced by sodium carboxymethylcellulose with a viscosity of 800-1000 Pa.s.
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| CN101070039A (en) * | 2006-05-08 | 2007-11-14 | 郑仕清 | Five-colour handicraft decoration, spray-drawing and oil-painting cloth and making technology |
| CN101376754A (en) * | 2007-08-28 | 2009-03-04 | 刘真林 | Stereo painting and calligraphy colouring matter formula |
| CN102627888A (en) * | 2011-02-03 | 2012-08-08 | 精工爱普生株式会社 | Ink composition and printed matter |
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| CN108276845A (en) | 2018-07-13 |
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