CN108251074A - A kind of 89 degree of phase-changing energy storage materials - Google Patents
A kind of 89 degree of phase-changing energy storage materials Download PDFInfo
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- CN108251074A CN108251074A CN201810203419.5A CN201810203419A CN108251074A CN 108251074 A CN108251074 A CN 108251074A CN 201810203419 A CN201810203419 A CN 201810203419A CN 108251074 A CN108251074 A CN 108251074A
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- 238000004146 energy storage Methods 0.000 title claims abstract description 74
- 239000011232 storage material Substances 0.000 title claims abstract description 62
- 239000000463 material Substances 0.000 claims abstract description 32
- 230000007797 corrosion Effects 0.000 claims abstract description 25
- 238000005260 corrosion Methods 0.000 claims abstract description 25
- MFUVDXOKPBAHMC-UHFFFAOYSA-N magnesium;dinitrate;hexahydrate Chemical compound O.O.O.O.O.O.[Mg+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O MFUVDXOKPBAHMC-UHFFFAOYSA-N 0.000 claims abstract description 24
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 17
- 239000010439 graphite Substances 0.000 claims abstract description 17
- 229910002804 graphite Inorganic materials 0.000 claims abstract description 17
- 239000004094 surface-active agent Substances 0.000 claims abstract description 16
- 239000003086 colorant Substances 0.000 claims abstract description 8
- 239000002562 thickening agent Substances 0.000 claims abstract description 8
- 238000005338 heat storage Methods 0.000 claims abstract description 6
- 230000009466 transformation Effects 0.000 claims abstract description 6
- 239000007788 liquid Substances 0.000 claims description 38
- 238000000034 method Methods 0.000 claims description 18
- 229910001220 stainless steel Inorganic materials 0.000 claims description 18
- 239000010935 stainless steel Substances 0.000 claims description 18
- 239000006185 dispersion Substances 0.000 claims description 15
- 239000001768 carboxy methyl cellulose Substances 0.000 claims description 12
- 238000007789 sealing Methods 0.000 claims description 12
- 238000003756 stirring Methods 0.000 claims description 12
- 230000008569 process Effects 0.000 claims description 11
- 238000005485 electric heating Methods 0.000 claims description 10
- 238000010298 pulverizing process Methods 0.000 claims description 10
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical group CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 8
- 150000001412 amines Chemical class 0.000 claims description 6
- 229910052751 metal Inorganic materials 0.000 claims description 6
- 239000002184 metal Substances 0.000 claims description 6
- 235000005979 Citrus limon Nutrition 0.000 claims description 5
- 244000131522 Citrus pyriformis Species 0.000 claims description 5
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 5
- 238000003860 storage Methods 0.000 claims description 5
- 229920002134 Carboxymethyl cellulose Polymers 0.000 claims description 4
- 235000010948 carboxy methyl cellulose Nutrition 0.000 claims description 4
- 239000008112 carboxymethyl-cellulose Substances 0.000 claims description 4
- 239000003760 tallow Substances 0.000 claims description 4
- 235000009328 Amaranthus caudatus Nutrition 0.000 claims description 3
- 240000001592 Amaranthus caudatus Species 0.000 claims description 3
- 235000000177 Indigofera tinctoria Nutrition 0.000 claims description 3
- REYJJPSVUYRZGE-UHFFFAOYSA-N Octadecylamine Chemical compound CCCCCCCCCCCCCCCCCCN REYJJPSVUYRZGE-UHFFFAOYSA-N 0.000 claims description 3
- 235000012735 amaranth Nutrition 0.000 claims description 3
- 239000004178 amaranth Substances 0.000 claims description 3
- 239000003795 chemical substances by application Substances 0.000 claims description 3
- 238000001816 cooling Methods 0.000 claims description 3
- IINNWAYUJNWZRM-UHFFFAOYSA-L erythrosin B Chemical compound [Na+].[Na+].[O-]C(=O)C1=CC=CC=C1C1=C2C=C(I)C(=O)C(I)=C2OC2=C(I)C([O-])=C(I)C=C21 IINNWAYUJNWZRM-UHFFFAOYSA-L 0.000 claims description 3
- 235000012732 erythrosine Nutrition 0.000 claims description 3
- 239000004174 erythrosine Substances 0.000 claims description 3
- 229940011411 erythrosine Drugs 0.000 claims description 3
- 235000019441 ethanol Nutrition 0.000 claims description 3
- 229940097275 indigo Drugs 0.000 claims description 3
- COHYTHOBJLSHDF-UHFFFAOYSA-N indigo powder Natural products N1C2=CC=CC=C2C(=O)C1=C1C(=O)C2=CC=CC=C2N1 COHYTHOBJLSHDF-UHFFFAOYSA-N 0.000 claims description 3
- JAJWGJBVLPIOOH-IZYKLYLVSA-M sodium taurocholate Chemical compound [Na+].C([C@H]1C[C@H]2O)[C@H](O)CC[C@]1(C)[C@@H]1[C@@H]2[C@@H]2CC[C@H]([C@@H](CCC(=O)NCCS([O-])(=O)=O)C)[C@@]2(C)[C@@H](O)C1 JAJWGJBVLPIOOH-IZYKLYLVSA-M 0.000 claims description 3
- LUEWUZLMQUOBSB-FSKGGBMCSA-N (2s,3s,4s,5s,6r)-2-[(2r,3s,4r,5r,6s)-6-[(2r,3s,4r,5s,6s)-4,5-dihydroxy-2-(hydroxymethyl)-6-[(2r,4r,5s,6r)-4,5,6-trihydroxy-2-(hydroxymethyl)oxan-3-yl]oxyoxan-3-yl]oxy-4,5-dihydroxy-2-(hydroxymethyl)oxan-3-yl]oxy-6-(hydroxymethyl)oxane-3,4,5-triol Chemical compound O[C@H]1[C@@H](O)[C@H](O)[C@@H](CO)O[C@H]1O[C@@H]1[C@@H](CO)O[C@@H](O[C@@H]2[C@H](O[C@@H](OC3[C@H](O[C@@H](O)[C@@H](O)[C@H]3O)CO)[C@@H](O)[C@H]2O)CO)[C@H](O)[C@H]1O LUEWUZLMQUOBSB-FSKGGBMCSA-N 0.000 claims description 2
- SGHZXLIDFTYFHQ-UHFFFAOYSA-L Brilliant Blue Chemical compound [Na+].[Na+].C=1C=C(C(=C2C=CC(C=C2)=[N+](CC)CC=2C=C(C=CC=2)S([O-])(=O)=O)C=2C(=CC=CC=2)S([O-])(=O)=O)C=CC=1N(CC)CC1=CC=CC(S([O-])(=O)=O)=C1 SGHZXLIDFTYFHQ-UHFFFAOYSA-L 0.000 claims description 2
- LZZYPRNAOMGNLH-UHFFFAOYSA-M Cetrimonium bromide Chemical compound [Br-].CCCCCCCCCCCCCCCC[N+](C)(C)C LZZYPRNAOMGNLH-UHFFFAOYSA-M 0.000 claims description 2
- 229920002581 Glucomannan Polymers 0.000 claims description 2
- 239000004354 Hydroxyethyl cellulose Substances 0.000 claims description 2
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 claims description 2
- 229920002752 Konjac Polymers 0.000 claims description 2
- SWXVUIWOUIDPGS-UHFFFAOYSA-N diacetone alcohol Natural products CC(=O)CC(C)(C)O SWXVUIWOUIDPGS-UHFFFAOYSA-N 0.000 claims description 2
- 229940046240 glucomannan Drugs 0.000 claims description 2
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 claims description 2
- SNRUBQQJIBEYMU-UHFFFAOYSA-N Dodecane Natural products CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 claims 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims 1
- 241001446187 Kermes Species 0.000 claims 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims 1
- 238000004040 coloring Methods 0.000 claims 1
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 claims 1
- 230000036571 hydration Effects 0.000 claims 1
- 238000006703 hydration reaction Methods 0.000 claims 1
- CXORMDKZEUMQHX-UHFFFAOYSA-N kermesic acid Chemical compound O=C1C2=C(O)C(O)=CC(O)=C2C(=O)C2=C1C=C(O)C(C(O)=O)=C2C CXORMDKZEUMQHX-UHFFFAOYSA-N 0.000 claims 1
- 229910052749 magnesium Inorganic materials 0.000 claims 1
- 239000011777 magnesium Substances 0.000 claims 1
- FGIUAXJPYTZDNR-UHFFFAOYSA-N potassium nitrate Chemical compound [K+].[O-][N+]([O-])=O FGIUAXJPYTZDNR-UHFFFAOYSA-N 0.000 claims 1
- 239000011734 sodium Substances 0.000 claims 1
- 229910052708 sodium Inorganic materials 0.000 claims 1
- 235000015424 sodium Nutrition 0.000 claims 1
- MZSDGDXXBZSFTG-UHFFFAOYSA-M sodium;benzenesulfonate Chemical compound [Na+].[O-]S(=O)(=O)C1=CC=CC=C1 MZSDGDXXBZSFTG-UHFFFAOYSA-M 0.000 claims 1
- 238000000844 transformation Methods 0.000 claims 1
- 238000009833 condensation Methods 0.000 abstract description 7
- 230000005494 condensation Effects 0.000 abstract description 7
- 238000010438 heat treatment Methods 0.000 abstract description 5
- 238000002360 preparation method Methods 0.000 abstract description 4
- 230000000052 comparative effect Effects 0.000 description 9
- 230000007704 transition Effects 0.000 description 9
- FJLUATLTXUNBOT-UHFFFAOYSA-N 1-Hexadecylamine Chemical compound CCCCCCCCCCCCCCCCN FJLUATLTXUNBOT-UHFFFAOYSA-N 0.000 description 8
- DPXJVFZANSGRMM-UHFFFAOYSA-N acetic acid;2,3,4,5,6-pentahydroxyhexanal;sodium Chemical group [Na].CC(O)=O.OCC(O)C(O)C(O)C(O)C=O DPXJVFZANSGRMM-UHFFFAOYSA-N 0.000 description 8
- 235000019812 sodium carboxymethyl cellulose Nutrition 0.000 description 8
- 229920001027 sodium carboxymethylcellulose Polymers 0.000 description 8
- 238000012545 processing Methods 0.000 description 6
- 150000003839 salts Chemical class 0.000 description 6
- 230000008859 change Effects 0.000 description 5
- 238000009825 accumulation Methods 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- 239000012782 phase change material Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 238000004781 supercooling Methods 0.000 description 3
- 241000220317 Rosa Species 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 230000002209 hydrophobic effect Effects 0.000 description 2
- YIXJRHPUWRPCBB-UHFFFAOYSA-N magnesium nitrate Chemical compound [Mg+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O YIXJRHPUWRPCBB-UHFFFAOYSA-N 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- 239000010963 304 stainless steel Substances 0.000 description 1
- 241001312219 Amorphophallus konjac Species 0.000 description 1
- 235000001206 Amorphophallus rivieri Nutrition 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- 241000370738 Chlorion Species 0.000 description 1
- AFCARXCZXQIEQB-UHFFFAOYSA-N N-[3-oxo-3-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)propyl]-2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carboxamide Chemical compound O=C(CCNC(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F)N1CC2=C(CC1)NN=N2 AFCARXCZXQIEQB-UHFFFAOYSA-N 0.000 description 1
- 229910000589 SAE 304 stainless steel Inorganic materials 0.000 description 1
- 238000005054 agglomeration Methods 0.000 description 1
- 125000003277 amino group Chemical group 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 230000001351 cycling effect Effects 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000000280 densification Methods 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 238000007499 fusion processing Methods 0.000 description 1
- 150000004676 glycans Chemical class 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 230000005764 inhibitory process Effects 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 230000013011 mating Effects 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 229910021645 metal ion Inorganic materials 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 239000002667 nucleating agent Substances 0.000 description 1
- 230000006911 nucleation Effects 0.000 description 1
- 238000010899 nucleation Methods 0.000 description 1
- 238000005191 phase separation Methods 0.000 description 1
- 230000010287 polarization Effects 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 239000012756 surface treatment agent Substances 0.000 description 1
- 230000004083 survival effect Effects 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K5/00—Heat-transfer, heat-exchange or heat-storage materials, e.g. refrigerants; Materials for the production of heat or cold by chemical reactions other than by combustion
- C09K5/02—Materials undergoing a change of physical state when used
- C09K5/06—Materials undergoing a change of physical state when used the change of state being from liquid to solid or vice versa
- C09K5/063—Materials absorbing or liberating heat during crystallisation; Heat storage materials
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F28—HEAT EXCHANGE IN GENERAL
- F28D—HEAT-EXCHANGE APPARATUS, NOT PROVIDED FOR IN ANOTHER SUBCLASS, IN WHICH THE HEAT-EXCHANGE MEDIA DO NOT COME INTO DIRECT CONTACT
- F28D20/00—Heat storage plants or apparatus in general; Regenerative heat-exchange apparatus not covered by groups F28D17/00 or F28D19/00
- F28D20/02—Heat storage plants or apparatus in general; Regenerative heat-exchange apparatus not covered by groups F28D17/00 or F28D19/00 using latent heat
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/14—Thermal energy storage
Abstract
The present invention relates to the technical fields of energy storage material, and in particular to a kind of 89 degree of phase-changing energy storage materials and preparation method and application.The material is made of the component of following parts by weight：100 parts of magnesium nitrate hexahydrate, 0.5~5 part of graphite, 0.5~10 part of thickener, 0.1~2 part of corrosion inhibiter, 0.1~2 part of surfactant, 0.1~1 part of colorant.The phase-changing energy storage material can solve the problems, such as material easily in the condensation of heat conduction pipe surface, corrosivity is strong, poor thermal conductivity, easy to leak are dangerous.The material phase transformation temperature is matched with heating network operating temperature, can apply to the Latent Heat Storage Exchanger in co-generation unit.
Description
Technical field
The present invention relates to the technical field of energy storage material, more specifically to a kind of 89 degree of phase-changing energy storage materials and its
Preparation method and application.
Background technology
The energy is the basis of human survival and development, and wherein electric energy and thermal energy are even more the energy shape that human society utilizes extensively
One of formula.At present, co-generation unit externally can not only export electric energy but also export thermal energy, can ensure exhausting and life simultaneously
The demand of electricity consumption heat in production.But due to being usually staggered with heat and peak of power consumption, when the heat of co-generation unit produces
When going out to be more than real-time heat demand, it is necessary to carry out energy storage to reduce the waste of the energy.The development of energy storage technology is be unable to do without efficiently
The exploitation of energy storage material, energy storage material can be divided into two major class.The first kind is chemical heat-accumulating material, utilizes reaction or heat of solution
Heat is stored, although storage density is bigger, heat storage capacity is limited, and pollutes environment.Second class is physics energy storage material,
It is divided into sensible heat formula and phase-change type.Wherein phase-change type is to be absorbed during material phase transformation or release heat, so as to fulfill heat
Storage and release, this material are thus referred to as phase-changing energy storage material PCM (phase change materials).
Phase-changing energy storage material has the property that：When temperature raising reaches phase transition temperature, the physics shape of phase-changing energy storage material
State changes, and the temperature of phase-changing energy storage material itself almost remains unchanged before phase transformation completion, during this, great Liang Xiang
Heating is absorbed or released out.So as in the phase transformation stage, produce a wider temperature platform, this platform goes out
It is existing so that we can obtain a metastable constant temperature time.The energy storage density of phase-change accumulation energy is high, and heat mainly divides
Cloth is near phase transition temperature, therefore practical utilize is easier.Phase-changing energy storage material possesses numerous value volume and range of product.It is general and
Phase-changing energy storage material, according to the difference of phase-changing energy storage material phase transition temperature, can be divided into low-temperature phase-change energy-storing material (15- by speech
90 DEG C), medium temperature phase-changing energy storage material (90-550 DEG C) and high-temperature phase-change energy storage material (550 DEG C of ＞)；According to chemical composition not
Together, phase-changing energy storage material is divided into organic and Inorganic phase change energy storage material.
Specifically, inorganic molten salt is as Inorganic phase change energy storage material, it is notable the advantages of be：1. since inorganic salts are
Ionic crystal body, for solid-state or liquid, thermal conductivity is good, when being converted into liquid, due to a large amount of free ions
Presence, thermal conductivity is more preferable, and (heat conduction of substance is similar with conductivity principle, is both needed to carry out reality by the vibration of lattice and the movement of electronics
It is existing)；It is easy to get 2. type is various, widely distributed, cheap；3. since polarization stronger between partial moisture and metal ion is made
It is destroyed in fusion process, needs to absorb larger heat, latent heat of phase change is big.Inorganic molten salt phase-changing energy storage material due to
Latent heat of phase change is larger in its phase transition process, phase transition temperature is constant, can store a large amount of heat, while can realize temperature control, always by
To the concern of researcher.
In recent years, it has been developed that a variety of inorganic molten salt phase-changing energy storage materials, and apply to numerous areas such as heat
Energy storage is carried out in cogeneration system.Specifically, the phase-change energy storage device in existing co-generation unit includes an energy-storage box, storage
Phase-changing energy storage material can be placed, and heat pipe is passed through energy-storage box from inlet extension, and is arranged in energy-storage box inside turn in case,
It is drawn again from exit from energy-storage box.Hot Bottomhole pressure heat-conducting medium.For example, the high temperature heat conducting medium from co-generation unit
Heat exchange occurs along the phase-changing energy storage material that heat pipe is flowed into from inlet in energy-storage box, with energy-storage box, discharges heat, Ran Houcong
It flows out in exit.
But the existing inorganic molten salt phase-changing energy storage material used still has following defect：First, inorganic-phase variable stores up
Energy material degree of supercooling is big, is also easy to produce phase separation；Second is that phase-changing energy storage material easily heat conduction pipe surface condense, influence from heat pipe to
The heat transfer of energy-storage box；Third, phase-changing energy storage material is strong to thermal conductive pipe corrosivity, and need to add in the nucleation containing chlorion
Agent easily corrodes the stainless steel as heat pipe；In addition, also there is easily leakage, phase transition temperature and confession in phase-changing energy storage material
The required ideal temperature of heat has the problem of certain temperature difference, and these problems are all urgently to be resolved hurrily and improve.
Invention content
The shortcomings that in order to overcome the prior art and deficiency, present invention aims at provide a kind of 89 degree of phase-changing energy storage materials and
Preparation method and application.The phase-changing energy storage material can solve material easily in the condensation of heat conduction pipe surface, corrosivity is strong, thermal conductivity
Difference, the technical issues of easy to leak is dangerous.The phase-changing energy storage material phase transition temperature is matched with heating network operating temperature, can apply to heat
Latent Heat Storage Exchanger in cogeneration system.
Purpose to realize the present invention, the present invention use following technical scheme：
A kind of 89 degree of phase-changing energy storage materials, the material are made of the component of following parts by weight：Magnesium nitrate hexahydrate 100
Part, 0.5~5 part of graphite, 0.5~10 part of thickener, 0.1~2 part of corrosion inhibiter, 0.1~2 part of surfactant, colorant 0.1~
1 part.
Preferably, the thickener is sodium carboxymethylcellulose, carboxymethyl cellulose, hydroxyethyl cellulose, Amorphophallus rivieri glucomannan
At least one of glycan.
Preferably, the corrosion inhibiter is at least one of tallow amine, cetylamine, octadecylamine.
Preferably, the surfactant is neopelex, in sodium taurocholate, cetyl trimethylammonium bromide
At least one.
Preferably, the colorant is amaranth, famille rose, erythrosine, newly red, lemon yellow, sunset yellow, indigo, brilliant blue
At least one of.
Further, it is preferable that the parts by weight of the graphite are 1~2.5 part.
Further, it is preferable that the parts by weight of the thickener are 2~5 parts.
Further, it is preferable that the parts by weight of the corrosion inhibiter are 0.5~1 part.
Further, it is preferable that the parts by weight of the surfactant are 0.5~1 part.
Further, it is preferable that the parts by weight of the colorant are 0.5 part.
Further to realize the object of the invention, it is preferable that the weight ratio of corrosion inhibiter and surfactant is 1 in the material
∶1。
The present invention also provides a kind of preparation methods of 89 degree of phase-changing energy storage materials, include the following steps：
(1) stainless steel sealing container will be put into after magnesium nitrate hexahydrate pulverization process, be placed in KDM types control-temperature electric heating set and adds
Then heat adds in corrosion inhibiter while stirring to 90~95 DEG C, until being melt into molten liquid completely；
(2) surfactant is added in molten liquid, ultrasonic disperse handles 30~40min, obtains dispersion liquid；
(3) graphite, thickener and colorant are added in dispersion liquid, postcooling is mixed evenly to get phase-change accumulation energy
Material.
Further, the present invention also provides a kind of application method of 89 degree of phase-changing energy storage materials, include the following steps：
(1) 89 degree of phase-changing energy storage materials are prepared according to the above method, it is spare；
(2) stainless steel pipe inner wall is handled with metal conditioner, removes the dirt on pipe inner wall, the metal watch
Surface treatment agent is acetone or ethyl alcohol；
(3) conduit, which is placed in heat source, is maintained under 90~95 DEG C of temperature condition, and 89 degree of phase-changing energy storage materials are added
Heat is injected in conduit, sealing recession is except heat source, cooling while hot to molten condition.
Further, the present invention also provides the applications of 89 degree of phase-changing energy storage materials, specifically, 89 degree of phase-change accumulation energies
Material is applied to the Latent Heat Storage Exchanger in co-generation unit.
Relative to the prior art, the invention has the advantages that：
(1) 89 degree of phase-changing energy storage materials of the invention select six water and magnesium nitrate as matrix phase-change material, phase alternating temperature
Degree is near 89 DEG C, within the temperature change section in co-generation unit application environment, is particularly suitable for applications in phase transformation storage
Energy heat exchanger, phase transition temperature are matched with heating network operating temperature；By adding in graphite, can not have to add in corrosivity it is strong contain chlorine
Nucleating agent while increasing material thermal conductivity and keeps original phase-change thermal storage performance.
(2) tallow amine, cetylamine and octadecylamine etc. are referred to as the amine of " film amine ", belong to adsorbed film type corrosion inhibiter.
As organic inhibitor, they have the amino group of polar hydrophilic base, can be adsorbed on metal surface, form one layer of densification
Hydrophobic film, protect metal surface not by aqueous corrosion.Adding in surfactant then can further help corrosion inhibiter to be formed well
Inhibition hydrophobic film.
(3) since corrosion inhibiter is in stainless steel pipe surface formation protective film, and then phase-changing energy storage material is inhibited in stainless steel
The phenomenon that pipe surface condenses, improves the conducting power of heat inside and outside pipeline, and cold cycling stability is good, convenient for long-term extensive
It uses.
(4) since surfactant acts as dispersant to material is added to, the graphite surface in material can be made to be easy to moisten
It is wet, so as to which graphite be made easily to be distributed in medium, further improve the capacity of heat transmission of material.
(5) it adds in colorant to colour phase-changing energy storage material, can find, improve in time when being leaked convenient for material
Safety during materials'use.
Specific embodiment
To more fully understand the present invention, the present invention is further elaborated with reference to embodiment, but embodiment not structure
Into limiting the scope of the invention.
In following embodiment, comparative example, the corrosivity of use common 304 stainless steel test materials in the market makes
The stainless steel sheet specimens of 50mm × 20mm × 2 through acetone and alcohol washes, are embedded to after weighing in fuse salt, in Muffle furnace
500 ± 1 DEG C are kept for 10 days, and taking-up is cleaned with acetone, the quality after corrosion are weighed after removing corrosion product, using Shimadzu
SHIMADZU electronic balances are weighed.
In following embodiment, comparative example, the degree of supercooling of material is measured using ZDR-21 type binary channels moisture recorder.
In following embodiment, comparative example, the thermal conductivity factor of material is measured using DRL-II type heat flow methods conductometer.
In following embodiment, comparative example, the phase transition temperature and latent heat of material are measured using HCT-4 type microcomputers differential thermal balance,
Heating rate be 10 DEG C/min, 25~600 DEG C of temperature range.
Embodiment 1
The magnesium nitrate hexahydrate of 100 parts by weight is weighed, stainless steel sealing container is put into after pulverization process, is placed in KDM types
92 DEG C are heated in control-temperature electric heating set, the cetylamine of 0.1 parts by weight is then added in while stirring, until being melt into melting completely
Liquid, adds in the neopelex of 0.1 parts by weight in molten liquid, and ultrasonic disperse processing 30min obtains dispersion liquid；
The famille rose of the graphite of 0.5 parts by weight, the sodium carboxymethylcellulose of 1 parts by weight and 0.5 parts by weight is sequentially added in dispersion liquid, is filled
Divide and postcooling is mixed evenly to get phase-changing energy storage material.
Embodiment 2
The magnesium nitrate hexahydrate of 100 parts by weight is weighed, stainless steel sealing container is put into after pulverization process, is placed in KDM types
93 DEG C are heated in control-temperature electric heating set, the cetylamine of 0.5 parts by weight is then added in while stirring, until being melt into melting completely
Liquid, adds in the neopelex of 0.5 parts by weight in molten liquid, and ultrasonic disperse processing 35min obtains dispersion liquid；
The lemon yellow of the graphite of 1 parts by weight, the sodium carboxymethylcellulose of 2 parts by weight and 0.5 parts by weight is sequentially added in dispersion liquid, fully
Postcooling is mixed evenly to get phase-changing energy storage material.
Embodiment 3
The magnesium nitrate hexahydrate of 100 parts by weight is weighed, stainless steel sealing container is put into after pulverization process, is placed in KDM types
93 DEG C are heated in control-temperature electric heating set, then adds in the cetylamine of 1 parts by weight while stirring, until it is melt into molten liquid completely,
The neopelex of 1 parts by weight is added in molten liquid, ultrasonic disperse processing 35min obtains dispersion liquid；In dispersion liquid
In sequentially add the lemon yellow of the graphite of 2.5 parts by weight, the sodium carboxymethylcellulose of 5 parts by weight and 0.5 parts by weight, be sufficiently mixed
Postcooling is stirred evenly to get phase-changing energy storage material.
Embodiment 4
The magnesium nitrate hexahydrate of 100 parts by weight is weighed, stainless steel sealing container is put into after pulverization process, is placed in KDM types
92 DEG C are heated in control-temperature electric heating set, then adds in the cetylamine of 2 parts by weight while stirring, until it is melt into molten liquid completely,
The neopelex of 2 parts by weight is added in molten liquid, ultrasonic disperse processing 40min obtains dispersion liquid；In dispersion liquid
In sequentially add the sunset yellow of the graphite of 5 parts by weight, the sodium carboxymethylcellulose of 10 parts by weight and 0.5 parts by weight, be sufficiently mixed
Postcooling is stirred evenly to get phase-changing energy storage material.
Embodiment 5
The magnesium nitrate hexahydrate of 100 parts by weight is weighed, stainless steel sealing container is put into after pulverization process, is placed in KDM types
93 DEG C are heated in control-temperature electric heating set, then adds in the tallow amine of 1 parts by weight while stirring, until it is melt into molten liquid completely,
The sodium taurocholate of 1 parts by weight is added in molten liquid, ultrasonic disperse processing 35min obtains dispersion liquid；It is sequentially added in dispersion liquid
The amaranth of the graphite of 2.5 parts by weight, the carboxymethyl cellulose of 5 parts by weight and 0.5 parts by weight, be sufficiently mixed stir evenly it is rear cold
But to get phase-changing energy storage material.
Embodiment 6
The magnesium nitrate hexahydrate of 100 parts by weight is weighed, stainless steel sealing container is put into after pulverization process, is placed in KDM types
92 DEG C are heated in control-temperature electric heating set, then adds in the cetylamine of 1 parts by weight while stirring, until it is melt into molten liquid completely,
The neopelex of 0.5 parts by weight is added in molten liquid, ultrasonic disperse processing 35min obtains dispersion liquid；Disperseing
The indigo of the graphite of 2.5 parts by weight, the sodium carboxymethylcellulose of 5 parts by weight and 0.5 parts by weight is sequentially added in liquid, is sufficiently mixed
Postcooling is stirred evenly to get phase-changing energy storage material.
Comparative example 1
The magnesium nitrate hexahydrate of 100 parts by weight is weighed, stainless steel sealing container is put into after pulverization process, is placed in KDM types
Be heated to 93 DEG C in control-temperature electric heating set, until be melt into molten liquid completely, sequentially added in molten liquid 2.5 parts by weight graphite, 5
The erythrosine of the sodium carboxymethylcellulose of parts by weight and 0.5 parts by weight is sufficiently mixed and stirs evenly postcooling to get phase-change accumulation energy
Material.
Comparative example 2
The magnesium nitrate hexahydrate of 100 parts by weight is weighed, stainless steel sealing container is put into after pulverization process, is placed in KDM types
93 DEG C are heated in control-temperature electric heating set, the cetylamine of 1 parts by weight is then added in while stirring, until being melt into molten liquid completely；
The lemon yellow of the graphite of 2.5 parts by weight, the sodium carboxymethylcellulose of 5 parts by weight and 0.5 parts by weight is sequentially added in molten liquid,
It is sufficiently mixed and stirs evenly postcooling to get phase-changing energy storage material.
The test result of embodiment 1-6 and comparative example 1-2 see the table below：
* it cools down at room temperature, observes the condensation situation of material on cooling initial stage chamber wall, wherein a large amount of significantly condensations are designated as 2,
The a small amount of condensation in part is designated as 1, and no condensation is designated as 0.
It can be seen that compared with comparative example 1 from the test result in table, it is real due to adding in corrosion inhibiter and surfactant
The corrosion rate for applying material in a 1-6 is remarkably decreased, and the corrosion resistance of material is improved, material on stainless steel wall not
Easily condensation, and the thermal conductivity of material and degree of supercooling are also improved；Compared with comparative example 2 only individually adds corrosion inhibiter, implement
Corrosion inhibiter and surfactant mating reaction in example 1-6, can obtain preferably corrosion-resistant and surface anti-agglomeration effect；From reality
It applies in the test result of example 2 and 3 as can be seen that using special ratios and the corrosion inhibiter and surfactant of dosage so as to produce
Synergistic enhancing effect, the corrosion resistance of material and is greatly improved in the performance for being not easy to condense on stainless steel wall, obtains
Unexpected technique effect.
It should be pointed out that the related technical personnel of this research field are not it should be recognized that departing from the skill of the invention provided
In the case of art feature and range, increase, the replacement made to technical characteristic all belong to the scope of protection of the present invention.
Claims (10)
1. a kind of 89 degree of phase-changing energy storage materials, which is characterized in that the material is made of the component of following parts by weight：Six hydration nitre
Sour 100 parts of magnesium, 0.5~5 part of graphite, 0.5~10 part of thickener, 0.1~2 part of corrosion inhibiter, 0.1~2 part of surfactant, coloring
0.1~1 part of agent.
2. 89 degree of phase-changing energy storage materials according to claim 1, which is characterized in that the thickener is carboxymethyl cellulose
At least one of sodium, carboxymethyl cellulose, hydroxyethyl cellulose, konjaku glucomannan.
3. 89 degree of phase-changing energy storage materials according to claim 1, which is characterized in that the corrosion inhibiter is tallow amine, 16
At least one of alkanamine, octadecylamine.
4. 89 degree of phase-changing energy storage materials according to claim 1, which is characterized in that the surfactant is dodecyl
At least one of benzene sulfonic acid sodium salt, sodium taurocholate, cetyl trimethylammonium bromide.
5. 89 degree of phase-changing energy storage materials according to claim 1, which is characterized in that the colorant is amaranth, kermes
At least one of red, erythrosine, newly red, lemon yellow, sunset yellow, indigo, brilliant blue.
6. 89 degree of phase-changing energy storage materials according to claim 1, which is characterized in that the parts by weight of the corrosion inhibiter are 0.5
~1 part, the parts by weight of the surfactant are 0.5~1 part.
7. 89 degree of phase-changing energy storage materials according to claim 1, which is characterized in that the weight of corrosion inhibiter and surfactant
Than being 1: 1.
A kind of 8. method for preparing 89 degree of phase-changing energy storage materials according to claims 1 to 7, which is characterized in that including with
Lower step：
(1) stainless steel sealing container will be put into after magnesium nitrate hexahydrate pulverization process, be placed in KDM types control-temperature electric heating set and be heated to
90~95 DEG C, corrosion inhibiter is then added in while stirring, until being melt into molten liquid completely；
(2) surfactant is added in molten liquid, ultrasonic disperse handles 30~40min, obtains dispersion liquid；
(3) graphite, thickener and colorant are added in dispersion liquid, postcooling is mixed evenly to get phase-changing energy storage material.
9. a kind of application method of 89 degree of phase-changing energy storage materials, which is characterized in that include the following steps：
(1) 89 degree of phase-changing energy storage materials are prepared according to the method in claim 8, it is spare；
(2) stainless steel pipe inner wall is handled with metal conditioner, the dirt on pipe inner wall is removed, at the metal surface
It is acetone or ethyl alcohol to manage agent；
(3) conduit, which is placed in heat source, is maintained under 90~95 DEG C of temperature condition, and 89 degree of phase-changing energy storage materials are heated to
Molten condition is injected in conduit while hot, and sealing recession is except heat source, cooling.
10. the application of 89 degree of phase-changing energy storage materials according to claims 1 to 7, which is characterized in that 89 degree of phase transformations storage
Energy material is applied to the Latent Heat Storage Exchanger in co-generation unit.
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