CN108250907A - A kind of dumb light solvent-free epoxy self-leveling coating and preparation method thereof - Google Patents
A kind of dumb light solvent-free epoxy self-leveling coating and preparation method thereof Download PDFInfo
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- CN108250907A CN108250907A CN201810074095.XA CN201810074095A CN108250907A CN 108250907 A CN108250907 A CN 108250907A CN 201810074095 A CN201810074095 A CN 201810074095A CN 108250907 A CN108250907 A CN 108250907A
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- Prior art keywords
- dumb light
- epoxy
- light solvent
- agent
- leveling coating
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
- C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
- C08G59/40—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
- C08G59/44—Amides
- C08G59/46—Amides together with other curing agents
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
- C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
- C08G59/40—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
- C08G59/50—Amines
- C08G59/5026—Amines cycloaliphatic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
- C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
- C08G59/40—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
- C08G59/50—Amines
- C08G59/56—Amines together with other curing agents
- C08G59/60—Amines together with other curing agents with amides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Paints Or Removers (AREA)
Abstract
The present invention relates to the present invention relates to technical field of coatings, a kind of dumb light solvent-free epoxy self-leveling coating and preparation method thereof is specifically disclosed.The coating includes two kinds of components of epoxy component and curing agent, wherein the epoxy component is by weight percentage, including following components:Epoxy resin:37 45%, reactive diluent:8 12%, antifoaming agent:0.2 0.3%, coalescents:5 5.1%, substrate wetting agents:0.5 0.6%, filler:40 48%, thickener:1 1.2%, levelling agent:0.2 0.3%;The curing agent by weight percentage, including following components:Polyamide:50 70%, modified aliphatic cyclic amine:30 50%.Coating gloss prepared by the present invention is less than 40, fully meets in the use in place (such as the occasions such as hospital) that glossiness is low, gloss is soft, and VOC content is low, small to the harm of environment and human body.
Description
Technical field
The present invention relates to technical field of coatings more particularly to a kind of dumb light solvent-free epoxy self-leveling coating and its preparation sides
Method.
Background technology
Raising and the constant growth of productivity with industrial technology, the requirement for clean production environment is increasingly
Its terrace of high request is corrosion-resistant, clean and wear-resisting, and room air dustiness is low.But existing non-solvent epoxy terrace product light
Ze Dutaigao (universal 60 degree of angle gloss is more than 90), this product is used in needing the place (example that glossiness is low, gloss is soft
Such as hospital's occasion) it is and improper, while in organic solvent be inflammable and explosive so in transportational process and storing process
There is sizable security risk, it is mishandling to cause fire and explosion.In addition to this it can be distributed in coating process a large amount of
VOC damages human body, and pollutes environment, causes atmosphere pollution.As the enhancing of people's environmental consciousness and country are right
The support energetically of environmental protection cause, so it is extremely urgent to develop new dumb light solvent-free epoxy self-leveling.
Invention content
Too high for existing epoxide terrace product glossiness and the problems such as distribute a large amount of VOC, the present invention provides a kind of mute
Light solvent-free epoxy self-leveling coating.
Further, the present invention also provides a kind of preparation methods of dumb light solvent-free epoxy self-leveling coating.
To achieve the above object of the invention, the embodiment of the present invention employs following technical solution:
A kind of dumb light solvent-free epoxy self-leveling coating, the coating include two kinds of components of epoxy component and curing agent,
In
The epoxy component by weight percentage, including following components:Epoxy resin:37-45%, reactive diluent:
8-12%, antifoaming agent:0.2-0.3%, coalescents:5-5.1%, substrate wetting agents:0.5-0.6%, filler:40-48% increases
Thick dose:1-1.2%, levelling agent:0.2-0.3%;
The curing agent by weight percentage, including following components:Polyamide:50-70%, modified aliphatic cyclic amine:30-
50%.
Relative to the prior art, this glossiness of dumb light solvent-free epoxy self-leveling coating provided by the invention is complete less than 40
Full up foot is in the use in place (such as the occasions such as hospital) that glossiness is low, gloss is soft, and VOC content is low, to environment and people
The harm of body is small.
The present invention selects polyamide and modified aliphatic cyclic amine to mix as curing agent, due to the molecule of phenyl ring in modified aliphatic cyclic amine
Steric hindrance is larger, the amino limitation of activity being connected with phenyl ring so that its reactivity reduces, therefore uses polyamide and modified alicyclic ring
Amine mixing prevents the reaction of active hydrogen, so that the film transparency reduces, reduces the glossiness of paint film as curing agent.
Further, the present invention also provides the preparation methods of the dumb light solvent-free epoxy self-leveling coating.The preparation side
Method, including at least following steps:
Each component is weighed according to above-mentioned raw material proportioning;
By the epoxy resin, reactive diluent, antifoaming agent, coalescents, substrate wetting agents, filler, thickener, levelling
Agent, mill base carry out mixing treatment, and grinding obtains epoxy component;
Polyamide, modified aliphatic cyclic amine are subjected to mixing treatment and obtain curing agent.
Relative to the prior art, the preparation method of dumb light solvent-free epoxy self-leveling coating provided by the invention is simple, holds
It is easy to control.
Specific embodiment
In order to make the purpose , technical scheme and advantage of the present invention be clearer, with reference to embodiments, to the present invention
It is further elaborated.It should be appreciated that the specific embodiments described herein are merely illustrative of the present invention, it is not used to
Limit the present invention.
The embodiment of the present invention provides a kind of dumb light solvent-free epoxy self-leveling coating, and the coating is including epoxy component and admittedly
Two kinds of components of agent, wherein
The epoxy component by weight percentage, including following components:Epoxy resin:37-45%, reactive diluent:
8-12%, antifoaming agent:0.2-0.3%, coalescents:5-5.1%, substrate wetting agents:0.5-0.6%, filler:40-48% increases
Thick dose:1-1.2%, levelling agent:0.2-0.3%;
The curing agent by weight percentage, including following components:Polyamide:50-70%, modified aliphatic cyclic amine:30-
50%.
The present invention selects polyamide and modified aliphatic cyclic amine to mix as curing agent, due to the molecule of phenyl ring in modified aliphatic cyclic amine
Steric hindrance is larger, the amino limitation of activity being connected with phenyl ring so that its reactivity reduces, therefore uses polyamide and modified alicyclic ring
Amine mixing prevents the reaction of active hydrogen, so that the film transparency reduces, reduces the glossiness of paint film as curing agent.
Preferably, the active hydrogen equivalent weight of the modified aliphatic cyclic amine is 90-100.
Active hydrogen equivalent weight refers to:The a great deal of (gram/a great deal of) of modified " amine " of aliphatic cyclic amine containing an active hydrogen, i.e. amine
Average molecular weight divided by contained active hydrogen quantity obtained by value.
Preferably, the epoxy resin is bisphenol A type epoxy resin.If epoxy resin is the epoxy of E-51,828 and 128
Resin.
Height containing polarized makes it to concrete etc. without the hydroxyl and ehter bond of facile hydrolysis in bisphenol A type epoxy resin molecule
A variety of base materials have good adhesive force.Cubical contraction when terrace cures is low, and chemical resistance is good.And bisphenol type epoxy tree
The structure that fat is arranged alternately for rigid phenyl ring and flexible ehter bond, assigns the preferable mechanical performance of terrace.
Preferably, the levelling agent is acrylic acid levelling agent.
Preferably, the antifoaming agent is organic silicon defoamer, such as modest 6800 antifoaming agent of moral.
Volatilization is not contained in above-mentioned coating component (including modified aliphatic cyclic amine, stating epoxy resin, levelling agent and antifoaming agent etc.)
Property solvent, surface have exhibiting high surface active material, in process of production easily generate bubble, therefore select organosilicon disappear
Infusion.
Preferably, the coalescents are diisobutyl adipate, glutaric acid diisobutyl ester and succinic acid diisobutyl ester
Mixture, the Coasol produced such as Chemoxy companies of Britain.
Coalescents have the advantages of coefficient of dispersion is small, low volatility high furtherance film.
Preferably, the epoxy component further includes mill base.
Preferably, the mass ratio of the epoxy component and curing agent is 3.5-4.2:1.
The present invention under the premise of the dumb light solvent-free epoxy self-leveling coating is provided, still further provide the dumb light without
The preparation method of solvent epoxy self-leveling coating.
In any embodiment, which includes at least following steps:
Each component is weighed according to above-mentioned raw material proportioning;
By the epoxy resin, reactive diluent, antifoaming agent, coalescents, substrate wetting agents, filler, thickener, levelling
Agent, mill base carry out mixing treatment, and grinding obtains epoxy component;
Polyamide, modified aliphatic cyclic amine are subjected to mixing treatment and obtain curing agent.
The preparation method of above-mentioned dumb light solvent-free epoxy self-leveling coating is simple, and process is easy to control.
Explanation is further explained to above-mentioned preparation method below:
Preferably, the epoxy resin, levelling agent, reactive diluent, antifoaming agent, substrate wetting agents are added to reactor
In, 10-15min is mixed under the rotating speed of 300-500rpm, then filler, mill base are added in reactor, with 600-
8-10min is mixed under the rotating speed of 800rpm, coalescents, thickener are added in reactor, in turning for 1000-1200rpm
The lower dispersion 15-20min of speed, is ground to fineness≤25um, obtains epoxy component.
It for 300-500rpm stirring at low speed is mainly that system viscosity is larger to select mixing speed first, and stirring at low speed is not easy
Bubble is stirred into system, and high-speed stirred is readily incorporated bubble, when viscosity is big, bubble is not easy to be precipitated, and can influence film forming
Energy;
The mixing speed of dispersion is 600-800rpm moderate-speed mixers, mainly contains film forming matter, rate influences very much body soon
It is performance, so system is made to reach uniform effect with moderate-speed mixer rate;
Mixing speed is selected as 800-1000rpm, batch mixing helps to disperse when stirring high-speed.
The application method of the dumb light solvent-free epoxy self-leveling coating is:By the epoxy component prepared and curing agent by
It is 3.5-4.2 according to mass ratio:1 carries out batch mixing, and application is carried out after stirring evenly.
It is provided in an embodiment of the present invention in order to better illustrate, it is illustrated below by embodiment is further.
Embodiment 1
The present embodiment provides a kind of dumb light solvent-free epoxy self-leveling coating, the coating includes epoxy component and curing agent
Two kinds of components, the epoxy component and curing agent are 4 according to mass ratio:1, wherein
The epoxy component by weight percentage, including following components:Epoxy resin:37%, reactive diluent:8%,
Antifoaming agent:0.2%, coalescents:5%, substrate wetting agents:0.5%, filler:40%, thickener:1%, levelling agent:0.2%;
The curing agent by weight percentage, including following components:Polyamide:60%, modified aliphatic cyclic amine:40%.
The preparation method of above-mentioned dumb light solvent-free epoxy self-leveling coating includes the following steps:
The epoxy resin, levelling agent, reactive diluent, antifoaming agent, substrate wetting agents will be added in reactor,
10-15min is mixed under the rotating speed of 300-500rpm, then filler, mill base are added in reactor, with turning for 600-800rpm
The lower mixing 8-10min of speed, coalescents, thickener are added in reactor, disperse 15- under the rotating speed of 1000-1200rpm
20min is ground to fineness≤25um, obtains epoxy component;
Polyamide, modified aliphatic cyclic amine are subjected to mixing treatment and obtain curing agent.
The application method of the dumb light solvent-free epoxy self-leveling coating is:By the epoxy component prepared and curing agent ratio
Example carry out batch mixing, carries out application after stirring evenly.
Embodiment 2
The present embodiment provides a kind of dumb light solvent-free epoxy self-leveling coating, the coating includes epoxy component and curing agent
Two kinds of components, the epoxy component and curing agent are 4 according to mass ratio:1, wherein
The epoxy component by weight percentage, including following components:Epoxy resin:45%, reactive diluent:8%,
Antifoaming agent:0.2%, coalescents:5%, substrate wetting agents:0.6%, filler:40%, thickener:1%, levelling agent:0.2%;
The curing agent by weight percentage, including following components:Polyamide:70%, modified aliphatic cyclic amine:30%.
The preparation method of above-mentioned dumb light solvent-free epoxy self-leveling coating as described in Example 1, is not repeating.
Embodiment 3
The present embodiment provides a kind of dumb light solvent-free epoxy self-leveling coating, the coating includes epoxy component and curing agent
Two kinds of components, the epoxy component and curing agent are 4 according to mass ratio:1, wherein
The epoxy component by weight percentage, including following components:Epoxy resin:37%, reactive diluent:8%,
Antifoaming agent:0.3%, coalescents:5.1%, substrate wetting agents:0.5%, filler:48%, thickener:1.2%, levelling agent:
0.2%;
The curing agent by weight percentage, including following components:Polyamide:50%, modified aliphatic cyclic amine:50%.
The preparation method of above-mentioned dumb light solvent-free epoxy self-leveling coating as described in Example 1, is not repeating.
In order to better illustrate the characteristic of dumb light solvent-free epoxy self-leveling coating provided in an embodiment of the present invention, below will
Dumb light solvent-free epoxy self-leveling coating prepared by embodiment 1,2,3 carries out performance detection, and testing result is as shown in table 1 below.
1 performance test results of table
As can be seen from Table 1, dumb light solvent-free epoxy self-leveling coating provided by the invention, glossiness are complete less than 40
Full up foot is in the use in place (such as the occasions such as hospital) that glossiness is low, gloss is soft, and VOC content is low, to environment and people
The harm of body is small.
The foregoing is merely illustrative of the preferred embodiments of the present invention, is not intended to limit the invention, all essences in the present invention
Any modification, equivalent replacement or improvement made within refreshing and principle etc., should all be included in the protection scope of the present invention.
Claims (10)
1. a kind of dumb light solvent-free epoxy self-leveling coating, it is characterised in that:The coating includes epoxy component and curing agent two
Kind component, wherein
The epoxy component by weight percentage, including following components:Epoxy resin:37-45%, reactive diluent:8-
12%, antifoaming agent:0.2-0.3%, coalescents:5-5.1%, substrate wetting agents:0.5-0.6%, filler:40-48%, thickening
Agent:1-1.2%, levelling agent:0.2-0.3%;
The curing agent by weight percentage, including following components:Polyamide:50-70%, modified aliphatic cyclic amine:30-50%.
2. dumb light solvent-free epoxy self-leveling coating as described in claim 1, it is characterised in that:The work of the modified aliphatic cyclic amine
It is 90-100 to sprinkle hydrogen equivalent.
3. dumb light solvent-free epoxy self-leveling coating as described in claim 1, it is characterised in that:The epoxy resin is bis-phenol
A type epoxy resin.
4. dumb light solvent-free epoxy self-leveling coating as described in claim 1, it is characterised in that:The levelling agent is acrylic acid
Levelling agent.
5. dumb light solvent-free epoxy self-leveling coating as described in claim 1, it is characterised in that:The antifoaming agent is organosilicon
Antifoaming agent.
6. dumb light solvent-free epoxy self-leveling coating as described in claim 1, it is characterised in that:The coalescents for oneself two
The mixture of sour diisobutyl ester, glutaric acid diisobutyl ester and succinic acid diisobutyl ester.
7. such as claim 1-6 any one of them dumb light solvent-free epoxy self-leveling coating, it is characterised in that:The epoxy group
Divide and further include mill base.
8. such as claim 1-6 any one of them dumb light solvent-free epoxy self-leveling coating, it is characterised in that:The epoxy group
It is 3.5-4.2 to divide with the mass ratio of curing agent:1.
9. a kind of preparation method of dumb light solvent-free epoxy self-leveling coating, it is characterised in that:Including at least following steps:
Each component is weighed according to such as claim 1~8 any one of them raw material proportioning;
By the epoxy resin, reactive diluent, antifoaming agent, coalescents, substrate wetting agents, filler, thickener, levelling agent,
Mill base carries out mixing treatment, and grinding obtains epoxy component;
Polyamide, modified aliphatic cyclic amine are subjected to mixing treatment and obtain curing agent.
10. the preparation method of dumb light solvent-free epoxy self-leveling coating as claimed in claim 9, it is characterised in that:By described in
Epoxy resin, levelling agent, reactive diluent, antifoaming agent, substrate wetting agents are added in reactor, in the rotating speed of 300-500rpm
Filler, mill base, are then added in reactor by lower mixing 10-15min, to mix 8-10min under the rotating speed of 600-800rpm,
Coalescents, thickener are added in reactor, disperses 15-20min under the rotating speed of 1000-1200rpm, is ground to fineness
≤ 25um, obtains epoxy component.
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Cited By (2)
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CN111363448A (en) * | 2020-04-17 | 2020-07-03 | 绵阳惠利环氧工程有限公司 | Solvent-free antistatic matte epoxy floor compound |
CN116042055A (en) * | 2023-03-02 | 2023-05-02 | 石家庄市长安育才建材有限公司 | Quick-drying epoxy floor coating and preparation method thereof |
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