CN108250874A - A kind of anti-corrosion zinc-rich paint - Google Patents
A kind of anti-corrosion zinc-rich paint Download PDFInfo
- Publication number
- CN108250874A CN108250874A CN201611249970.0A CN201611249970A CN108250874A CN 108250874 A CN108250874 A CN 108250874A CN 201611249970 A CN201611249970 A CN 201611249970A CN 108250874 A CN108250874 A CN 108250874A
- Authority
- CN
- China
- Prior art keywords
- zinc
- rich paint
- aminoethyl
- corrosion
- rich
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D143/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing boron, silicon, phosphorus, selenium, tellurium, or a metal; Coating compositions based on derivatives of such polymers
- C09D143/04—Homopolymers or copolymers of monomers containing silicon
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/08—Metals
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
- C08K3/36—Silica
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
- C09D5/10—Anti-corrosive paints containing metal dust
- C09D5/106—Anti-corrosive paints containing metal dust containing Zn
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/08—Metals
- C08K2003/0893—Zinc
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Paints Or Removers (AREA)
Abstract
The present invention relates to a kind of anti-corrosion zinc-rich paint and its preparation processes.The coating includes the components such as potassium silicate, sodium metasilicate, Ludox, 3 aminopropyltriethoxy dimethoxy silicon of N 2 (aminoethyl), dodecanediol amide, silicone acrylic emulsion, zinc powder.The preparation method of the coating is：In dope preparing process, add N 2 (aminoethyl) 3 aminopropyltriethoxy dimethoxysilane coupling agent, improve the compatibility of metal zinc and silicate, enhance the adhesive force of coating, neopelex surfactant is also added simultaneously, improve metal zinc wettability, so as to prepare a kind of composite modified zinc-rich anti-corrosive paint.
Description
Technical field
The present invention relates to a kind of zinc-rich paint, more particularly to a kind of anti-corrosion zinc-rich paint for adding complexing agent and its preparation side
Method belongs to coating manufacture field.
Background technology
The economic loss caused by metal erosion accounts for about the 2%-4% of various countries GDP, the gold scrapped due to corrosion every year in the whole world
Belong to up to hundred million tons or more.Metal erosion can significantly reduce the mechanical properties such as the intensity, plasticity, toughness of metal material, destroy metal structure
The geometry of part increases the abrasion between part, deteriorates the physical properties such as electrical and optical, shortens the service life of equipment, very
To causing the catastrophic failures such as fire, explosion.Steel is similarly faced with corrosion as a kind of most common metal material used
This problem mesh.According to statistics, the steel being directly lost due to corrosion every year accounts for about a quarter of steel annual output.People
Delay the corrosion rate of steel by various modes.
Common coating is coated in steel surface, only prevents steel corrosion in a manner of completely cutting off air, and zinc rich paint
Air can not only be completely cut off, and primary battery protection can be formed, the normal potential of the zinc in zinc rich paint is low compared with steel, corrosive medium
During infiltration, steel forms primary battery with zinc powder, and zinc powder loses electronics as the cathode of primary battery, and steel obtains electronics as anode
And it is protected.After the position having on the film of zinc-rich paint is by mechanical damage, in a certain range of area, anticorrosive current
Also steel exposed portion can be flowed to, then the corrosion product of zinc is deposited upon there and forms layer protecting film.With steel surface
Constantly exposure, zinc-rich film are constantly covered by protective film, and inertia is just presented, but in film by machine in cathodic protection effect again
Tool then starts to bring back to life when damaging and exposing new zinc surface.If expose with sand paper polishing film coated surface or by film scratch new
Zinc face, then potential difference just restore to the original state.In addition, anion binding in the zinc ion and corrosive medium that are dissolved out and formed
Basic zinc salt and zinc-iron double salt, fill up the crack of film, and reach the etch-proof purpose of isolation.Zinc rich paint is divided into organic zinc-rich
Paint and inorganic zinc-rich paint, organic zinc-rich paint are often with epoxy resin, chlorinated rubber, vinylite and polyurethane resin
Film forming binder.But the electric conductivity of the organic binder of organic zinc rich paint is poor.Inorganic zinc-rich paint be divided into for have solvent type and
Aqueous two class.Wherein aqueous inorganic zinc rich paint is by aqueous inorganic silicate（It receives, potassium, lithium）The groups such as resin, zinc powder, auxiliary agent
Into.
Aqueous inorganic zinc-enriched coating has free from extraneous odour, non-ignitable not quick-fried due to its organic solvent-free, free from environmental pollution etc. excellent
Point, but simultaneously because solvent is few, wetability is low, thus adhesive force not as good as corresponding solvent based coating it is good, and zinc powder is added to painting
In material, due to zinc powder with inorganic silicate is more difficult merges, it is low attached power with ground.For this purpose, generally in dope preparing process, add
Add coupling agent, improve the compatibility of metal zinc and silicate, enhance the adhesive force of coating, but this improvement often has
Limit, in preparation process, then adds suitable surfactant, then can play better improvement result.
The present invention is by dope preparing process, except addition N-2- (aminoethyl) -3 aminopropyltriethoxy dimethoxysilane
Coupling agent improves the compatibility of metal zinc and silicate, enhances the adhesive force of coating, while also add dodecyl benzene sulfonic acid
Natrium surfactant improves metal zinc wettability, comprehensive so as to prepare a kind of composite modified zinc-rich anti-corrosive paint
It can will greatly improve.
Invention content
The object of the present invention is to provide a kind of anti-corrosion zinc-rich paint, which includes the raw material of following mass percent：
Potassium silicate 5%-10%；
Sodium metasilicate 5%-10%；
Ludox 20%-40%；
- 3 aminopropyltriethoxy dimethoxysilane 3%-7% of N-2- (aminoethyl)；
Dodecanediol amide 2%-3%；
Silicone acrylic emulsion 20%-30%；
Zinc powder 20%-30%.
The preparation method of above-mentioned zinc-rich paint includes the following steps：
(1) a certain amount of potassium silicate solution and sodium silicate solution are poured into Hybrid Heating in container, temperature is controlled at 50-70 DEG C；
(2) in the case where ceaselessly stirring, the Ludox of metering is slowly added dropwise, is sufficiently mixed it；
(3) -3 aminopropyltriethoxy dimethoxysilanes of N-2- (aminoethyl) and dodecyl centainly measured is added in into container again
Two alkylolamides, high-speed stirred；
(4) stop heating, when temperature is down to room temperature, add in silicone acrylic emulsion；
(5) the zinc powder of a certain amount of 600 mesh is finally added, a kind of the anti-of addition composite modifier can be obtained after persistently stirring evenly
Rotten zinc-rich paint.
The present invention has following advantages and characteristic：
(1) paint preparation process is simple, good operability；
(2) the paint good combination property prepared.
Specific embodiment
Embodiment one：
50g potassium silicate solutions and 50g sodium silicate solutions are poured into respectively in a container and mixed, and is mixed object heating, heating
Temperature is controlled at 50 DEG C or so, is ceaselessly stirred with blender.In whipping process, then 300g Ludox is slowly added dropwise, is added dropwise
After, then -3 aminopropyltriethoxy dimethoxysilanes of N-2- (aminoethyl) of 30g and 20g dodecyls two are added in into container
Alkylolamides, and mixing speed will be improved, stop heating after five minutes, when temperature is down to room temperature, add 250g silicone acrylic emulsions,
The 600 mesh zinc powders of 300g are finally added, a kind of anti-corrosion zinc-rich paint for adding composite modifier can be obtained after persistently stirring evenly.
Embodiment two：
70g potassium silicate solutions and 70g sodium silicate solutions are poured into respectively in a container and mixed, and is mixed object heating, heating
Temperature is controlled at 60 DEG C or so, is ceaselessly stirred with blender.In whipping process, then 300g Ludox is slowly added dropwise, is added dropwise
After, then -3 aminopropyltriethoxy dimethoxysilanes of N-2- (aminoethyl) of 35g and 25g dodecyls two are added in into container
Alkylolamides, and mixing speed will be improved, stop heating after five minutes, when temperature is down to room temperature, add 300g silicone acrylic emulsions,
The 600 mesh zinc powders of 200g are finally added, a kind of anti-corrosion zinc-rich paint for adding composite modifier can be obtained after persistently stirring evenly.
Embodiment three：
100g potassium silicate solutions and 100g sodium silicate solutions are poured into respectively in a container and mixed, and is mixed object heating, is added
Hot temperature control is ceaselessly stirred at 70 DEG C or so with blender.In whipping process, then 200g Ludox is slowly added dropwise, drips
After adding, then -3 aminopropyltriethoxy dimethoxysilanes of N-2- (aminoethyl) of 70g and 30g dodecyls are added in into container
Two alkylolamides, and mixing speed will be improved, stop heating after five minutes, when temperature is down to room temperature, add the third breast of 200g silicon
Liquid finally adds the 600 mesh zinc powders of 300g, and a kind of anti-corrosion zinc-rich for adding composite modifier can be obtained after persistently stirring evenly and is applied
Material.
Claims (2)
1. a kind of anti-corrosion zinc-rich paint, which is characterized in that the coating includes the raw material of following mass percent：
Potassium silicate 5%-10%；
Sodium metasilicate 5%-10%；
Ludox 20%-40%；
- 3 aminopropyltriethoxy dimethoxysilane 3%-7% of N-2- (aminoethyl)；
Dodecanediol amide 2%-3%；
Silicone acrylic emulsion 20%-30%；
Zinc powder 20%-30%.
2. a kind of anti-corrosion zinc-rich paint according to claim 1, which is characterized in that the preparation process of the coating includes as follows
Step：
(1) a certain amount of potassium silicate solution and sodium silicate solution are poured into Hybrid Heating in container, temperature is controlled at 50-70 DEG C；
(2) in the case where ceaselessly stirring, the Ludox of metering is slowly added dropwise, is sufficiently mixed it；
(3) -3 aminopropyltriethoxy dimethoxysilanes of N-2- (aminoethyl) and dodecyl centainly measured is added in into container again
Two alkylolamides, high-speed stirred；
(4) stop heating, when temperature is down to room temperature, add in silicone acrylic emulsion；
(5) the zinc powder of a certain amount of 600 mesh is finally added, a kind of the anti-of addition composite modifier can be obtained after persistently stirring evenly
Rotten zinc-rich paint.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611249970.0A CN108250874A (en) | 2016-12-29 | 2016-12-29 | A kind of anti-corrosion zinc-rich paint |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611249970.0A CN108250874A (en) | 2016-12-29 | 2016-12-29 | A kind of anti-corrosion zinc-rich paint |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN108250874A true CN108250874A (en) | 2018-07-06 |
Family
ID=62721868
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201611249970.0A Pending CN108250874A (en) | 2016-12-29 | 2016-12-29 | A kind of anti-corrosion zinc-rich paint |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN108250874A (en) |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106047005A (en) * | 2016-07-24 | 2016-10-26 | 黄子芳 | Functional coating added with alkyl modifier |
| CN106147480A (en) * | 2016-07-23 | 2016-11-23 | 黄敬来 | A kind of interpolation dodecanediol amide functional paint and preparation method thereof |
-
2016
- 2016-12-29 CN CN201611249970.0A patent/CN108250874A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106147480A (en) * | 2016-07-23 | 2016-11-23 | 黄敬来 | A kind of interpolation dodecanediol amide functional paint and preparation method thereof |
| CN106047005A (en) * | 2016-07-24 | 2016-10-26 | 黄子芳 | Functional coating added with alkyl modifier |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN105038339A (en) | Antirust functional metallic coating doped with vinyl trimethoxy silane | |
| CN105001736A (en) | Coating added with N-2-(aminoethyl)-3-aminopropyl methyl dimethoxyl silane coupling agent | |
| CN104877499A (en) | High-temperature-resistant zinc-rich paint and preparation method thereof | |
| CN105001735A (en) | Functional coating added with gamma-glycidyl ether oxypropyltrimethoxy silane | |
| CN104877488A (en) | Preparation process for water-based zinc rich paint taking potassium metasilicate as base material | |
| CN106519864A (en) | Technique for modifying mixed zinc-rich coating by adding dodecyl alcohol amine | |
| CN104877500A (en) | Lithium silicate-sodium silicate mixed zinc-rich paint and technology thereof | |
| CN105001742A (en) | Metal antirust functional coating doping with vinyltri (2-methoxyethoxy) silane | |
| CN106047005A (en) | Functional coating added with alkyl modifier | |
| CN105086701A (en) | Modified water-based corrosion-resistant coating | |
| CN104927531A (en) | Zinc-rich paint employing lithium silicate and potassium silicate as base materials | |
| CN106118310A (en) | A kind of dual modified functional paint | |
| CN104927532A (en) | Composite silicate zinc-rich paint and preparation technique thereof | |
| CN105017901A (en) | Functional coating added with gamma-aminopropyl triethoxy silane coupling agent | |
| CN105315823A (en) | Method for improving cross-linking stability of zinc-rich functional paint | |
| CN105038472A (en) | 3-trimethoxysilylpropanethiol doped metal rustproof functional coating and preparation process thereof | |
| CN106590269A (en) | Modified mixed zinc-rich coating | |
| CN106752158A (en) | Modified mixing zinc-rich paint and its technique of one kind | |
| CN105017826A (en) | Functional paint with added gama-methacryloxypropyltrimethoxysilane | |
| CN105086708A (en) | Novel modified coating with addition of aluminate trimethyl | |
| CN105086703A (en) | Water-soluble anticorrosive paint | |
| CN104927533A (en) | Water-based zinc rich paint with good film-forming property and preparation method thereof | |
| CN105086700A (en) | Metal antirust functional coating with doped silane coupling agents and method for preparing metal antirust functional coating | |
| CN108250874A (en) | A kind of anti-corrosion zinc-rich paint | |
| CN108610833A (en) | A kind of composite modified anti-corrosion zinc-rich paint of addition surfactant |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20180706 |
|
| WD01 | Invention patent application deemed withdrawn after publication |