CN108246317A - A kind of recyclable ferroselenium composite nano materials and its application in rhodamine B degradation waste water - Google Patents

A kind of recyclable ferroselenium composite nano materials and its application in rhodamine B degradation waste water Download PDF

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Publication number
CN108246317A
CN108246317A CN201810025239.2A CN201810025239A CN108246317A CN 108246317 A CN108246317 A CN 108246317A CN 201810025239 A CN201810025239 A CN 201810025239A CN 108246317 A CN108246317 A CN 108246317A
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Prior art keywords
ferroselenium
composite nano
nano materials
solution
rhodamine
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CN201810025239.2A
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Inventor
龚安华
孙岳玲
陆陈杰
吴家宝
邱雨程
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Yangzhou Polytechnic Institute
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Yangzhou Polytechnic Institute
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/02Sulfur, selenium or tellurium; Compounds thereof
    • B01J27/057Selenium or tellurium; Compounds thereof
    • B01J27/0573Selenium; Compounds thereof
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/0013Colloids
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/002Catalysts characterised by their physical properties
    • B01J35/0033Electric or magnetic properties
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/02Solids
    • B01J35/023Catalysts characterised by dimensions, e.g. grain size
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/72Treatment of water, waste water, or sewage by oxidation
    • C02F1/722Oxidation by peroxides
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/72Treatment of water, waste water, or sewage by oxidation
    • C02F1/725Treatment of water, waste water, or sewage by oxidation by catalytic oxidation
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2101/00Nature of the contaminant
    • C02F2101/30Organic compounds
    • C02F2101/308Dyes; Colorants; Fluorescent agents
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2101/00Nature of the contaminant
    • C02F2101/30Organic compounds
    • C02F2101/34Organic compounds containing oxygen
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2101/00Nature of the contaminant
    • C02F2101/30Organic compounds
    • C02F2101/38Organic compounds containing nitrogen

Abstract

The present invention relates to a kind of recyclable ferroselenium composite nano materials and its applications in rhodamine B degradation waste water, the ferroselenium composite nano materials of the present invention, it can be used as Fenton catalyst to be used for rhodamine B degradation, after the material circulation uses 5 times, it is catalyzed to the degradation rate of RhB still greater than 90%.

Description

It a kind of recyclable ferroselenium composite nano materials and its gives up in rhodamine B degradation Application in water
Technical field
The invention belongs to field of nanometer material technology, and in particular to a kind of recyclable ferroselenium composite nano materials and its Application in rhodamine B degradation waste water.
Background technology
Rhodamine B (Rhodamine B, RhB) is a kind of artificial synthesized organic dyestuff, industry (as weaving, printing and dyeing, Process hides etc.) in be widely used, produce the higher industrial wastewater of the content of a large amount of rhodamine Bs.RhB is a kind of carcinogen, It such as cannot effectively remove, it will threaten the physical and mental health of the mankind.It is generally removed in waste water using Fenton oxidation method at present Rhodamine B, Fenton oxidation method is using Fe2+And H2O2OH is generated, it, being capable of Quick Oxidation since OH oxidabilities are strong A variety of organic matters for being difficult to aoxidize in sewage, but traditional Fenton oxidation technology is that Fe need to be added in system2+And H2O2, Because of the Fe in system2+It is not easily recycled, it is impossible to reuse and effluent color dilution is higher, be restricted its application, therefore, compel to be essential It develops one kind to be easily recycled, green, the efficient Fenton catalyst that can be recycled.
Invention content
The present invention provides a kind of ferroselenium composite nano materials (i.e. the nano ferriferrous oxide of selenium doping), it is characterised in that institute The preparation method for stating ferroselenium composite nano materials includes the following steps:
(1) it is soluble in water by divalent iron salt, polyvinylpyrrolidone, 80-90 DEG C is heated to, obtains solution A;
(2) selenium powder is added in hydrazine hydrate, heating stirring to selenium powder is completely dissolved to obtain solution B;
(3) after in the solution A for obtaining the solution B addition step (1) that step (2) obtains, alkali metal hydroxide is added in Solution is kept for 80-90 DEG C, after being stirred to react 3-5h, is centrifuged, is washed, is dry that dark brown precipitation, as described ferroselenium are answered Close nano material (i.e. the nano ferriferrous oxide of selenium doping).
The preferred FeSO of divalent iron salt described in step (1)4·7H2O、FeSO4、FeCl2、Fe(NO3)2In one kind or several Kind;Divalent iron salt:Polyvinylpyrrolidone:The mass ratio of water is 1:0.1-0.2:15-20;
Containing 10-15mg selenium in a concentration of every milliliter of hydrazine hydrate of selenium in step (2) solution B, i.e., per 10-15 mg selenium powders Use 1mL hydrazine hydrates;
Alkali metal hydroxide preferred NaOH, KOH, LiOH, CsOH, alkali hydroxide soln described in step (3) A concentration of 4-5mol/L, the dosage of alkali hydroxide soln is 5-10 times of divalent iron salt quality;The dosage of solution B is Every gram of divalent iron salt uses 1mL solution Bs;The grain size of the ferroselenium composite nano materials is 50-100nm.
Another embodiment of the present invention provides the preparation method of the nano ferriferrous oxide of above-mentioned selenium doping, and feature exists In including the following steps:
(1) it is soluble in water by divalent iron salt, polyvinylpyrrolidone, 80-90 DEG C is heated to, obtains solution A;
(2) selenium powder is added in hydrazine hydrate, heating stirring to selenium powder is completely dissolved to obtain solution B;
(3) after in the solution A for obtaining the solution B addition step (1) that step (2) obtains, alkali metal hydroxide is added in Solution is kept for 80-90 DEG C, after being stirred to react 3-5h, is centrifuged, is washed, is dry that dark brown precipitation, as described selenium adulterate Nano ferriferrous oxide.
The preferred FeSO of divalent iron salt described in step (1)4·7H2O、FeSO4、FeCl2、Fe(NO3)2In one kind or several Kind;Divalent iron salt:Polyvinylpyrrolidone:The mass ratio of water is 1:0.1-0.2:15-20;
Containing 10-15mg selenium in a concentration of every milliliter of hydrazine hydrate of selenium in step (2) solution B, i.e., per 10-15 mg selenium powders Use 1mL hydrazine hydrates;
Alkali metal hydroxide preferred NaOH, KOH, LiOH, CsOH, alkali hydroxide soln described in step (3) A concentration of 4-5mol/L, the dosage of alkali hydroxide soln is 5-10 times of divalent iron salt quality;The dosage of solution B is Every gram of divalent iron salt uses 1mL solution Bs;The grain size of the nano ferriferrous oxide of the selenium doping is 50-100nm.
Another embodiment of the present invention provides (the i.e. oxidation of nanometer four three of selenium doping of above-mentioned ferroselenium composite nano materials Iron) application as Fenton catalyst.Above-mentioned ferroselenium composite nano materials (i.e. the nano ferriferrous oxide of selenium doping) can follow Ring uses 5 times.
The method that another embodiment of the present invention provides rhodamine B in a kind of degrading waste water, it is characterised in that including such as Lower step:Above-mentioned ferroselenium composite nano materials and peroxide are added in into waste water.The dosage of ferroselenium composite nano materials is every Waste water is risen using 0.6-3.6g ferroseleniums composite nano materials, it is preferable to use 1.8g ferroselenium composite nano materials;Peroxide is preferred Hydrogen peroxide, the dosage of hydrogen peroxide use 1.5-4.0g hydrogen peroxide, it is preferable to use 3.0g hydrogen peroxide for every liter of waste water.Ferroselenium of the present invention In composite nano materials degrading waste water the preferred pH of rhodamine B be 1.0-5.0, further preferably 5.0.
Hydrogen peroxide of the present invention be commercially available common hydrogen peroxide, content of hydrogen peroxide 30%.
Compared with prior art, the advantage of the invention is that:(1) the invention discloses a kind of novel ferroselenium composite Nanos Material (i.e. the nano ferriferrous oxide of selenium doping), being used as Fenton catalyst, the material has for rhodamine B degradation After recycling 5 times, it is catalyzed to the degradation rate of RhB still greater than 90%;(2) above-mentioned ferroselenium composite Nano provided by the invention Material is in catalysis efficiency and recycles on number better than (such as the Chinese patent Shen of other ferriferrous oxide materials in the prior art Please number:201610080860.X, 201611144384.X, the records such as 201610310844.5 ferriferrous oxide material).
Description of the drawings
The SEM figures of Fig. 1 products A
The XRD diagram of Fig. 2 products A
Influence of Fig. 3 product A usage amounts to rhodamine B degradation rate
Influence of Fig. 4 hydrogen peroxide usage amount to rhodamine B degradation rate
Influences of Fig. 5 pH to rhodamine B degradation efficiency
Fig. 6 reaction temperatures influence the degradation rate of rhodamine B
Product A-D, Fe-G-3, Fe under Fig. 7 optimum experimental conditions3O4Nanocages are to the degradation rate of rhodamine B
Fig. 8 products A, which recycles 5 degradation rates to rhodamine B, to be changed
Specific embodiment
For the ease of a further understanding of the present invention, examples provided below has done more detailed description to it.But It is that these embodiments only are not used for limiting the scope of the present invention or implementation principle, reality of the invention for being better understood from inventing The mode of applying is not limited to the following contents.
Embodiment 1
(1) by FeSO4·7H2O (10g), polyvinylpyrrolidone (1g), are dissolved in water (150g), are heated to 80-90 DEG C, Obtain solution A;
(2) selenium powder (100mg) is added in hydrazine hydrate (10mL), heating stirring to selenium powder is completely dissolved to obtain solution B;
(3) after in the solution A for obtaining the solution B addition step (1) that step (2) obtains, the NaOH for adding in 4 mol/L is molten Liquid (100g) is kept for 80-90 DEG C, after being stirred to react 3h, is centrifuged, is washed, is dry that dark brown precipitates 2.6g, as described Ferroselenium composite nano materials (abbreviation product A).
Embodiment 2
(1) by FeCl2(10g), polyvinylpyrrolidone (2g), is dissolved in water (200g), is heated to 80-90 DEG C, obtain molten Liquid A;
(2) selenium powder (150mg) is added in hydrazine hydrate (10mL), heating stirring to selenium powder is completely dissolved to obtain solution B;
(3) after in the solution A for obtaining the solution B addition step (1) that step (2) obtains, the KOH for adding in 5 mol/L is molten Liquid (50g) is kept for 80-90 DEG C, after being stirred to react 5h, is centrifuged, is washed, is dry that dark brown precipitates 5.8g, as described Ferroselenium composite nano materials (abbreviation product B).
Embodiment 3
(1) by FeSO4·7H2O (10g), polyvinylpyrrolidone (1g), are dissolved in water (150g), are heated to 80-90 DEG C, Obtain solution A;
(2) selenium powder (50mg) is added in hydrazine hydrate (10mL), heating stirring to selenium powder is completely dissolved to obtain solution B;
(3) after in the solution A for obtaining the solution B addition step (1) that step (2) obtains, the NaOH for adding in 4 mol/L is molten Liquid (100g) is kept for 80-90 DEG C, after being stirred to react 3h, is centrifuged, is washed, is dry that dark brown precipitates 2.4g, abbreviation product C。
Embodiment 4
(1) by FeSO4·7H2O (10g), polyvinylpyrrolidone (1g), are dissolved in water (150g), are heated to 80-90 DEG C, Add in the NaOH solution (100g) of 4mol/L, kept for 80-90 DEG C, after being stirred to react 3h, centrifuge, washing, dry black Precipitate 2.5g, abbreviation product D.
5 rhodamine B degradation experiment of embodiment
(1) dosage of ferroselenium composite nano materials of the present invention, hydrogen peroxide, the influence of pH, temperature to degradation rate
Experimental method:Rhodamine B solution (10mg/L) 100mL is moved into the conical flask of 250mL, with hydrochloric acid conditioning solution Acidity is separately added into test sample and suitable hydrogen peroxide, is vibrated on shaking table, takes supernatant liquor at regular intervals, measures Remain rhodamine B concentration.
1. investigate the usage amount of ferroselenium composite nano materials of the present invention
Experiment condition:Hydrogen peroxide usage amount be 2.5g/L, pH 5.0,30 DEG C, reaction time 15min of reaction temperature, selenium The usage amount of iron composite nano materials (product A) is respectively 0.6g/L, 1.2g/L, 1.8g/L, 2.4g/L, 3.0g/L, 3.6g/ L。
The degradation rate (Fig. 3) of rhodamine B.
2. investigate the usage amount of hydrogen peroxide
Experiment condition:The usage amount of product A is 1.8g/L, pH 5.0, and 30 DEG C, reaction time 15min of reaction temperature is double Oxygen water usage amount is respectively 1.5g/L, 2.0g/L, 2.5g/L, 3.0g/L, 3.5g/L, 4.0 g/L.
The degradation rate (Fig. 4) of rhodamine B.
3. investigate pH
Experiment condition:The usage amount of product A be 1.8g/L, hydrogen peroxide usage amount be 3.0g/L, 30 DEG C of reaction temperature, instead 15min between seasonable adjusts pH value 1 to 9, the degradation rate (Fig. 5) of rhodamine B.
4. investigate reaction temperature
The usage amount of product A be 1.8g/L, hydrogen peroxide usage amount be 3.0g/L, pH 5.0, reaction time 15min, instead It is 20 DEG C, 30 DEG C, 40 DEG C, 50 DEG C to answer temperature, influence (Fig. 6) of the temperature to degradation efficiency.
(2) under the optimum experimental condition obtained in (1):Test sample usage amount is 1.8g/L, and hydrogen peroxide usage amount is 3.0g/L, pH 5.0,30 DEG C of reaction temperature under conditions of reaction time 15min, take 6 parts of rhodamine B solution (10mg/ respectively L) 100mL is moved into the conical flask of 250mL, with hydrochloric acid conditioning solution pH 5.0, is separately added into appropriate product A-D, Fe-G-3 and (is pressed According to Chinese Patent Application No.:201610080860.X it is prepared by embodiment 1), Fe3O4Nanocages are (according to Chinese Patent Application No.: It is prepared by 201611144384.X embodiments 1) and suitable hydrogen peroxide, it is vibrated on shaking table, takes upper strata clear at regular intervals Liquid measures residual rhodamine B concentration (Fig. 7).
(3) the recycling performance of ferroselenium composite nano materials of the present invention
Under optimum experimental condition, the recycling performance of test product A is carried out after the completion of catalysis reaction with magnet every time Recycling carries out 5 experiments (Fig. 8) altogether at identical conditions.As seen from the figure, after 5 uses, product A is catalyzed to sieve The degradation rate of red bright B drops to 91% from 96%, illustrates it with preferable stability and recycles performance, is much better than Fe-G-3 And Fe3O4Nanocages.

Claims (7)

1. a kind of ferroselenium composite nano materials, it is characterised in that the preparation method of the ferroselenium composite nano materials includes following step Suddenly:
(1) it is soluble in water by divalent iron salt, polyvinylpyrrolidone, 80-90 DEG C is heated to, obtains solution A;
(2) selenium powder is added in hydrazine hydrate, heating stirring to selenium powder is completely dissolved to obtain solution B;
(3) after in the solution A for obtaining the solution B addition step (1) that step (2) obtains, alkali hydroxide soln is added in, It is kept for 80-90 DEG C, after being stirred to react 3-5h, centrifuges, washs, is dry that dark brown precipitates, as described ferroselenium is compound to be received Rice material.
2. ferroselenium composite nano materials described in claim 1, it is characterised in that the divalent iron salt described in step (1) is preferred FeSO4·7H2O、FeSO4、FeCl2、Fe(NO3)2One or more of;Divalent iron salt:Polyvinylpyrrolidone:The quality of water Than being 1:0.1-0.2:15-20.
3. claim 1-2 any one of them ferroselenium composite nano materials, it is characterised in that selenium is dense in step (2) solution B It spends to contain 10-15mg selenium in every milliliter of hydrazine hydrate.
4. claim 1-3 any one of them ferroselenium composite nano materials, it is characterised in that alkali metal hydrogen described in step (3) Oxide preferred NaOH, KOH, LiOH, CsOH, a concentration of 4-5mol/L of alkali hydroxide soln, alkali metal hydroxide The dosage of object solution is 5-10 times of divalent iron salt quality;The dosage of solution B uses 1mL solution Bs for every gram of divalent iron salt.
5. claim 1-4 any one of them ferroselenium composite nano materials, it is characterised in that the ferroselenium composite nano materials Grain size be 50-100nm.
6. application of the claim 1-5 any one of them ferroselenium composite nano materials as Fenton catalyst.
7. the preparation method of claim 1-5 any one of them ferroselenium composite nano materials.
CN201810025239.2A 2018-01-10 2018-01-10 A kind of recyclable ferroselenium composite nano materials and its application in rhodamine B degradation waste water Pending CN108246317A (en)

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Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104190434A (en) * 2014-08-22 2014-12-10 哈尔滨工业大学 Preparation of Fe3O4-MnO2 composite catalyst and method for removing organic dye in printing and dyeing wastewater by using Fe3O4-MnO2 composite catalyst
CN106045151A (en) * 2016-07-08 2016-10-26 常州大学 Method for degrading rhodamine B through nanometer Fe3O4/H2O2 synergistically
CN106571248A (en) * 2016-10-26 2017-04-19 信阳师范学院 Preparation method for electrode material of Se-doped ZnO-SnO2 supercapacitor taking foamed nickel as substrate

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104190434A (en) * 2014-08-22 2014-12-10 哈尔滨工业大学 Preparation of Fe3O4-MnO2 composite catalyst and method for removing organic dye in printing and dyeing wastewater by using Fe3O4-MnO2 composite catalyst
CN106045151A (en) * 2016-07-08 2016-10-26 常州大学 Method for degrading rhodamine B through nanometer Fe3O4/H2O2 synergistically
CN106571248A (en) * 2016-10-26 2017-04-19 信阳师范学院 Preparation method for electrode material of Se-doped ZnO-SnO2 supercapacitor taking foamed nickel as substrate

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
龚安华 等: ""纳米四氧化三铁的制备及其催化氧化过氧化氢降解罗丹明B废水的研究"", 《染整技术》 *

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