CN108246064A - A kind of comprehensive purifying method for the exhaust gas containing VOCs that sewage farm loss goes out - Google Patents

A kind of comprehensive purifying method for the exhaust gas containing VOCs that sewage farm loss goes out Download PDF

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Publication number
CN108246064A
CN108246064A CN201611242114.2A CN201611242114A CN108246064A CN 108246064 A CN108246064 A CN 108246064A CN 201611242114 A CN201611242114 A CN 201611242114A CN 108246064 A CN108246064 A CN 108246064A
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exhaust gas
vocs
sewage farm
gas containing
goes out
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梁凯
向修传
许谦
崔亚军
曲晨
姜媛
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China National Petroleum Corp
China Petroleum Engineering and Construction Corp
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China National Petroleum Corp
China Petroleum Engineering and Construction Corp
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    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/46Removing components of defined structure
    • B01D53/72Organic compounds not provided for in groups B01D53/48 - B01D53/70, e.g. hydrocarbons
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/02Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
    • B01D53/04Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/02Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
    • B01D53/04Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
    • B01D53/0407Constructional details of adsorbing systems
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/46Removing components of defined structure
    • B01D53/48Sulfur compounds
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/74General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/77Liquid phase processes
    • B01D53/78Liquid phase processes with gas-liquid contact
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/74General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/84Biological processes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2251/00Reactants
    • B01D2251/20Reductants
    • B01D2251/206Ammonium compounds
    • B01D2251/2062Ammonia
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2251/00Reactants
    • B01D2251/30Alkali metal compounds
    • B01D2251/304Alkali metal compounds of sodium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2251/00Reactants
    • B01D2251/30Alkali metal compounds
    • B01D2251/306Alkali metal compounds of potassium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2253/00Adsorbents used in seperation treatment of gases and vapours
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2259/00Type of treatment
    • B01D2259/40Further details for adsorption processes and devices
    • B01D2259/40083Regeneration of adsorbents in processes other than pressure or temperature swing adsorption
    • B01D2259/40088Regeneration of adsorbents in processes other than pressure or temperature swing adsorption by heating
    • B01D2259/4009Regeneration of adsorbents in processes other than pressure or temperature swing adsorption by heating using hot gas
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A50/00TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
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Abstract

The invention discloses a kind of comprehensive purifying methods for the exhaust gas containing VOCs that sewage farm loss goes out, and belong to the field of purification of VOCs exhaust gas.The processing method includes the following steps:The exhaust gas containing VOCs of sewage farm loss is pressed into high concentration VOCs exhaust gas and low concentration VOCs exhaust gas categorised collections;The high concentration VOCs exhaust gas initially enters absorption tower and carries out wet desulphurization, then enters back into adsorption bed and carries out adsorption cleaning, the clean gas after being adsorbed;Clean gas after the absorption is mixed, and pass through biological bed and handled with the low concentration VOCs exhaust gas.The embodiment of the present invention can pass through the VOCs exhaust gas of treated sewage Treatment stations middle and high concentration and low concentration respectively, realize the comprehensive treatment to the structures of sewage farm loss exhaust gas containing VOCs, purification discharge gas can meet related request of the national environmental protection regulation to sewage treatment plant of oil refining enterprise waste gas emission standard, have the advantages that purification efficiency is high, investment is small, operating cost is low.

Description

A kind of comprehensive purifying method for the exhaust gas containing VOCs that sewage farm loss goes out
Technical field
The present invention relates to the field of purification of VOCs exhaust gas, exhaust gas containing VOCs that more particularly to a kind of sewage farm loss goes out Comprehensive purifying method.
Background technology
Oil refining, each structures of Treatment of Sewage Reservoir of Chemical Plant Treatment stations loss can contain foul waste gas, this kind of sewage disposal into air Volatile organic matter (Volatile Organic Compounds, english abbreviation containing higher concentration in the exhaust gas of field loss VOCs), each pollutant such as hydrogen sulfide, mercaptan, thioether.Such exhaust gas not only results in the decline of regional air quality, Er Qieqi In it is certain into branch stimulation human body respiratory system, hematological system and nervous systems, this kind of exhaust gas of Long Term Contact can be to people Body health causes serious threat.Therefore this kind of exhaust gas is administered.
The fluctuation of concentration of exhaust emission containing VOCs generated due to sewage farm is larger and the exhaust gas of each structures loss Middle VOCs concentration differences are larger, and suitable can be limited to the treatment technology of the VOCs exhaust gas of high concentration and low concentration simultaneously.It is existing Have in technology, processing exhaust gas treatment method containing VOCs mainly have burning method, Production by Catalytic Combustion Process, condensation method, absorption process, absorption method, Bioanalysis etc., but these methods are respectively provided with certain specific aim, can not well to sewage farm generate containing VOCs into Row is administered.
Patent document CN101062463A discloses a kind of comprehensive purifying method of foul waste gas.Sewage farm aeration tank The low concentration VOCs foul waste gas of structures loss is waited to be handled first using washing-absorbing process, purified gas that treated Body qualified discharge;Using being catalyzed combustion tail gas desorption and regeneration adsorbent, the structures such as desorption and regeneration exhaust gas and oil separator, floation tank The higher concentration VOCs exhaust gas mixing of loss is using desulfurization and total hydrocarbon concentration homogenizing-catalytic combustion technology processing.The technique can be with To sewage farm each structures loss exhaust gas containing VOCs carry out comprehensive purifying, in exhaust gas pollutant (malodor components and Volatile organic components) purification efficiency is high, but the invention flow is complicated, the larger and process operation temperatures are invested compared with high safety Property is poor.
Patent document CN1393283A discloses a kind of purification method of exhaust gas containing combustible components.This method is using pre- place (desulfurization, homogenizing or dedusting)-catalytic combustion process is managed, higher combustible components concentration waste gas purification will be contained, this method is to useless Pollutant (malodor components and volatile organic components) purification efficiency in gas is high, but the technique is only suitable for processing containing more highly concentrated The exhaust gas of combustible components is spent, when handling low concentration VOCs exhaust gas, operating cost is larger.
Patent document CN101347708A discloses a kind of processing method of sulphur-containing exhaust air with fetor escaped from storage tank.The invention is adopted Sulphur-containing exhaust air with fetor escaped from storage tank is purified with the technique of pretreatment (desulfurization)-absorption.This method is to the net of sulfur-containing foul waste gas It is higher to change efficiency, but when invention is applied to sewage farm dissipating stinking sulfur-containing exhaust gas, due to low concentration VOCs exhaust gas volumes Flow is larger, it will the amount of adsorbent, which greatly increases, used in making causes one-time investment larger.Further, since resolution gas returns It returns to adsorption tower to continue to concentrate, is likely to result in accumulation of the constituent part in adsorption tower.
Patent document CN200710031286.X discloses a kind of processing method of foul waste gas.Invention use absorption- Low concentration, atm number, different foul gas pollutants are carried out deodorization purification by bioremediation.This method is adapted to low dense The deodorization purified treatment of exhaust gas is spent, but when this method is applied to the high concentration VOCs exhaust gas of sewage farm loss, to exhaust gas In TREATMENT OF VOCs effect it is limited.
Patent document CN102039078A discloses a kind of processing method of multi-component stink exhaust gas, (is inhaled using pretreatment Receive)-microbial method combined treatment process purifies the exhaust gas containing multi-component stink, and which equally has biological law technology On deficiency.
Invention content
In order to solve the technical issues of above-mentioned, the present invention provides a kind of the comprehensive of the exhaust gas containing VOCs that sewage farm loss goes out Close purification method, which is capable of the VOCs exhaust gas of the loss of treated sewage Treatment stations goes out respectively high concentration and low concentration, There is purification efficiency is high, investment is small, operating cost is low etc..
Specifically, including following technical solution:
A kind of comprehensive purifying method for the exhaust gas containing VOCs that sewage farm loss goes out, the treating method comprises following step Suddenly:
The exhaust gas containing VOCs of sewage farm loss is pressed into high concentration VOCs exhaust gas and low concentration VOCs exhaust gas categorised collections;
The high concentration VOCs exhaust gas initially enters absorption tower and carries out wet desulphurization, then enters back into adsorption bed and is inhaled Attached purification, the clean gas after being adsorbed;
Clean gas after the absorption is mixed, and pass through at biological bed with the low concentration VOCs exhaust gas Reason.
Further, after the absorption of the adsorption bed reaches saturation, using water vapour in the adsorption bed Adsorbent desorbed to obtain mixed vapour;The mixed vapour after desorption enters condenser heat exchange cooling, forms condensation Liquid and fixed gas, and the fixed gas is mixed, and lead to clean gas, the low concentration VOCs exhaust gas after the absorption The biological bed is crossed to be handled.
Further, the condensate liquid enters layering slot layering, obtains organic solvent not soluble in water, described not soluble in water Organic solvent be discharged into sewage disposal field control tank or oil separator.
Preferably, the adsorption bed includes the first absorption casing and the second absorption casing, and first absorption casing The handover operation that can be adsorbed and desorbed with second absorption casing.
Preferably, the processing of the biological bed include zinc cation, bio-trickling and biofiltration any one or The combination of two kinds of biological treatment sections.
Preferably, the desulfurization absorbing liquid for carrying out wet desulphurization is provided in the absorption tower;The desulfurization absorbing liquid For alkaline solution, the alkaline solution is sodium hydroxide (NaOH) aqueous solution, potassium hydroxide (KOH) aqueous solution, sodium carbonate (Na2CO3) aqueous solution, potassium carbonate (K2CO3) aqueous solution or ammonium hydroxide.
Preferably, the adsorbent on the adsorption bed (2) is active carbon particle and/or activated carbon fibre.
Preferably, the high concentration VOCs source exhaust gas collect in sewage farm, oil removal and Treatment of Sludge structures, It is adjusted between tank, oil separator, floation tank, slop tank, sludge concentration tank, the dehydration of three mud including sewage;The low concentration VOCs exhaust gas From sewage farm biochemical treatment structures, including biochemistry pool, aeration tank, a heavy pond.
Preferably, in the high concentration VOCs exhaust gas mean concentration of VOCs in 300~6000mg/m3, the low concentration The mean concentration of VOCs is not more than 200mg/m in VOCs exhaust gas3
Preferably, it is 100-200 DEG C for the temperature of the water vapour of desorption.
The advantageous effect of technical solution provided in an embodiment of the present invention:Provide that a kind of sewage farm loss goes out contains The comprehensive purifying method of VOCs exhaust gas, the foul waste gas containing VOCs particularly suitable for the loss of oil refining enterprise sewage farm it is net Change.Specifically, the categorised collection of exhaust gas containing VOCs of Wastewater Treatment Field in Refinery loss is obtained first high concentration VOCs exhaust gas and High concentration VOCs exhaust gas is carried out wet desulphurization, then carries out adsorption cleaning, the clean gas after absorption by low concentration VOCs exhaust gas It is mixed with low concentration VOCs exhaust gas, and passes through malodor components and VOCs groups in Biochemical method technique advanced treating exhaust gas Point.The embodiment of the present invention can be realized by the VOCs exhaust gas of treated sewage Treatment stations middle and high concentration and low concentration respectively to dirt The comprehensive treatment of the structures for the exhaust gas containing VOCs that Large Water Treatment Field loss goes out, purification discharge gas can meet national environmental protection regulation pair The related request of sewage treatment plant of oil refining enterprise waste gas emission standard, it is excellent to have that purification efficiency is high, investment is small, operating cost is low Point.
Description of the drawings
To describe the technical solutions in the embodiments of the present invention more clearly, make required in being described below to embodiment Attached drawing is briefly described, it should be apparent that, the accompanying drawings in the following description is only some embodiments of the present invention, for For those of ordinary skill in the art, without creative efforts, other are can also be obtained according to these attached drawings Attached drawing.
Fig. 1 is the work of the exhaust gas of VOCs containing high concentration that a kind of treated sewage Treatment stations loss provided in an embodiment of the present invention goes out Skill flow diagram;
Fig. 2 is the work of the exhaust gas of VOCs containing low concentration that a kind of treated sewage Treatment stations loss provided in an embodiment of the present invention goes out Skill flow diagram.
Reference numeral in figure represents respectively:
1st, absorption tower;
2nd, adsorption bed;21st, the first absorption casing;22nd, the second absorption casing;
3rd, biological bed;
4th, condenser;
5th, it is layered slot;
6th, air-introduced machine.
Specific embodiment
To make technical scheme of the present invention and advantage clearer, embodiment of the present invention is made below in conjunction with attached drawing into One step it is described in detail.Unless otherwise defined, all technical terms used in the embodiment of the present invention are respectively provided with and art technology The normally understood identical meaning of personnel.
The embodiment of the present invention provides a kind of comprehensive purifying method of the exhaust gas containing VOCs that sewage farm loss goes out, the processing Method includes the following steps:
The exhaust gas containing VOCs of sewage farm loss is pressed into high concentration VOCs exhaust gas and low concentration VOCs exhaust gas categorised collections;
High concentration VOCs exhaust gas initially enters absorption tower 1 and carries out wet desulphurization, then enters back into adsorption bed 2 and is adsorbed Purification, the clean gas after being adsorbed;
Clean gas after absorption is mixed, and carried out in processing exhaust gas by biological bed 3 with low concentration VOCs exhaust gas Malodor components and VOCs components.
The embodiment of the present invention uses Biochemical method technique to the processing of low concentration VOCs exhaust gas, to high concentration VOCs exhaust gas Processing use wet desulphurization-absorption-Biochemical method technique.Before being processed, first to sewage farm loss The categorised collection of exhaust gas containing VOCs (high concentration VOCs exhaust gas and low concentration VOCs exhaust gas) can specifically come according to the source difference of exhaust gas Categorised collection is carried out to it, for example, high concentration VOCs exhaust gas is mainly derived from sewage farm collection, oil removal and Treatment of Sludge Structures, including between sewage adjusting tank (pond), oil separator, floation tank, slop tank, sludge concentration tank, the dehydration of three mud etc., ventilation is secondary Number preferably selects 1 time.Low concentration VOCs exhaust gas is mainly derived from sewage farm biochemical treatment structures, including biochemistry pool (A/O Pond), aeration tank, a heavy pond etc., rate of ventilation preferably selects 4 times (aeration tank calculates tolerance according to aeration quantity).Wherein, high concentration The mean concentration of VOCs is in 300~6000mg/m in VOCs exhaust gas3, the mean concentration of VOCs is not in low concentration VOCs exhaust gas More than 200mg/m3.When low VOCs concentration structures rate of ventilation selection 4 times, (it is more than 300mg/ when VOCs concentration is still higher m3), can suitably mend fresh air reduces VOCs concentration, and exhaust gas concentration is allow to purify qualified discharge by the degradation of biology.
The work of the comprehensive purifying method for the exhaust gas containing VOCs that sewage farm loss provided in an embodiment of the present invention goes out is former It manages and is:As depicted in figs. 1 and 2, high concentration VOCs exhaust gas is subjected to wet desulphurization, removes organic sulfur, inorganic sulfur etc. in exhaust gas Sulfide, wet desulphurization use desulfurization absorbing liquid.High concentration VOCs exhaust gas after pretreatment (after wet desulphurization) enters suction Attached bed 2 using the volatile organic matter in the adsorbent removing exhaust gas in adsorption bed 2, carries out adsorption cleaning, after absorption Clean gas is mixed with low concentration VOCs exhaust gas, by the malodor components in Biochemical method technique advanced treating exhaust gas and VOCs components.The embodiment of the present invention can be real by the VOCs exhaust gas of treated sewage Treatment stations middle and high concentration and low concentration respectively The comprehensive treatment of the structures of the exhaust gas containing VOCs now gone out to sewage farm loss, purification discharge gas can meet national environmental protection Regulation has purification efficiency height, invests small, operating cost to the related request of sewage treatment plant of oil refining enterprise waste gas emission standard The advantages of low, the purification of the foul waste gas containing VOCs particularly suitable for the loss of oil refining enterprise sewage farm.
In the processing method of the exhaust gas containing VOCs gone out in above-mentioned sewage farm loss, in order to reuse absorption Bed 2, the processing method further include:After the absorption of adsorption bed 2 reaches saturation, using water vapour in adsorption bed 2 Adsorbent desorbed to obtain mixed vapour;Mixed vapour after desorption enters the heat exchange cooling of condenser 4, cold with condenser 4 But mixed vapour (cooling medium selects recirculated water or frost water), the steam formed after condensate liquid and desorption passes through condenser 4 Fixed gas afterwards.Further, then by fixed gas with clean gas, the low concentration VOCs exhaust gas after absorption it mixes, and pass through life Object bed 3 carries out malodor components and VOCs components in processing exhaust gas.It so on the one hand can be to being directly entered biological bed 3 Low concentration VOCs exhaust gas play a diluting effect, low concentration VOCs exhaust gas is made to be more advantageous to dropping by Biochemical method technique Solution, fixed gas of the steam after condenser 4 after on the other hand desorbing are mixed into Biochemical method technique advanced treating, and The non-adsorption bed 2 that is sent to continues to concentrate, in this way can be to avoid the accumulation of constituent part.
It is layered in addition, condensate liquid is made to enter layering slot 5, forms organic solvent not soluble in water, this not soluble in water is had Solvent is directly discharged into the structures such as sewage disposal field control tank or oil separator.Further, the desorption of adsorption bed 2 is finished Afterwards, air can also be used or purify wind, non-purification wind blows steam remaining when being desorbed on the adsorbent in adsorption bed 2 Go out, preferably to carry out adsorption cleaning again.
In the processing method of the exhaust gas containing VOCs gone out in above-mentioned sewage farm loss, in order in adsorption bed 2 In be carried out at the same time absorption and desorption operations, to improve exhaust treatment efficiency, can set adsorption bed 2 include at least two adsorption boxes Body, in a kind of possible embodiment, setting adsorption bed 2 includes the first absorption casing 21 and the second absorption casing 22, absorption When, the high concentration VOCs exhaust gas after pretreatment (after wet desulphurization) is made to be inhaled into the first absorption casing 21 by control valve Attached purification run, using the volatile organic matter in the adsorbent removing exhaust gas in the first absorption casing 21, when the first adsorption box After adsorbent adsorption saturation in body 21, switch valve makes pretreated high concentration VOCs exhaust gas enter the second absorption casing 22 Adsorption cleaning operation is carried out, while (thermal desorption regeneration) is desorbed to the first absorption casing 21.Wherein, water vapour heat can be used Regeneration is desorbed, that is, is passed through supersaturation water steam and the first absorption casing 21 is heated, the VOCs for making to adsorb is by stripping It releases, and adsorption bed 2 is left together with water vapour formation mixed vapour, into condenser 4.
And after adsorbent adsorption saturation in the second absorption casing 22, changeable valve carries out the second absorption casing 22 Desorption, and the first absorption casing 21 is made to carry out adsorption cleaning operation, the first absorption casing 21 and the second absorption casing 22 are handed over successively For the handover operation for being adsorbed and being desorbed, to save material, and exhaust treatment efficiency is improved.
In the processing method of the exhaust gas containing VOCs gone out in above-mentioned sewage farm loss, the processing of biological bed 3 can adopt It, specifically can root with the combination of any one or two kinds of biological treatment sections of zinc cation, bio-trickling and biofiltration It is determined according to the parameters such as VOCs concentration, composition in exhaust gas.Independent filler (plastics, pottery may be selected in biologic packing material used in biological bed 3 Porcelain or metal), or mixed fillers.Biological bacterium solution in biological bed 3 can should simultaneously degrade the stench in exhaust gas Component and VOCs components, for the bacterial activity temperature at 15~45 DEG C, suitable pH value is 4~10.After exhaust gas, desorption after cleaning Fixed gas of the steam after condenser 4 be mixed into biological bed 3 with low concentration VOCs exhaust gas, pass through biological bed 3 Residence time is generally 10s~120s, preferably 20s~60s, specifically can be true according to the parameters such as VOCs concentration, composition in exhaust gas It is fixed.
It is wet for carrying out in absorption tower 1 in the processing method of the exhaust gas containing VOCs gone out in above-mentioned sewage farm loss The desulfurization absorbing liquid of method desulfurization is alkaline absorbent, can generally use sodium hydroxide (NaOH) aqueous solution, potassium hydroxide (KOH) Aqueous solution, sodium carbonate (Na2CO3) aqueous solution, potassium carbonate (K2CO3) aqueous solution or ammonium hydroxide etc., concentration is generally 1%~30% (wt), pH value general control is not less than 7.2, and alkaline absorbent can be recycled during operation, when pH value is down to 7.2~7.5, PH is adjusted by discharging any waste liquor or the fresh lye of supplement.Alkali cleaning temperature is normally controlled in 20~50 DEG C, alkaline absorbent Typical concentrations are the sodium hydroxide solution of 10%~15% (wt).
It is used to carry out in the processing method of the exhaust gas containing VOCs gone out in above-mentioned sewage farm loss, in adsorption bed 2 The adsorbent of adsorption cleaning is any one or two kinds of mixtures with arbitrary proportion in active carbon particle, activated carbon fibre. Further, exhaust gas is generally 500~10000h by the volume space velocity of adsorption bed-1, preferably 1000~8000h-1
In the processing method of the exhaust gas containing VOCs gone out in above-mentioned sewage farm loss, for the temperature of the water vapour of desorption Degree temperature range is generally 100-250 DEG C, preferably 100-200 DEG C.
The scheme and effect of method are further illustrated the present invention with reference to embodiment:
The present embodiment is contained using wet desulphurization-absorption-Liang Duan Biochemical methods oil refining enterprise sewage farm loss VOCs exhaust gas.High concentration VOCs source exhaust gas is in sewage farm collection, oil removal and Treatment of Sludge structures, including sewage tune Between section tank (pond), oil separator, floation tank, slop tank, sludge concentration tank, the dehydration of three mud etc., exhaust gas flow 5000Nm3/ h, contains H2S 100mg/m3Left and right, non-methane total hydrocarbons 2500mg/m3Left and right.Low concentration VOCs derives from sewage farm biochemical treatment structure Object is built, including biochemistry pool (A/O ponds), aeration tank, a heavy pond etc., exhaust gas flow 20000Nm3/ h, containing H2S 40mg/m3Left and right, Non-methane total hydrocarbons 150mg/m3Left and right.
High concentration VOCs exhaust gas initially enters the H in absorption tower removing exhaust gas2S, desulfurization absorbing liquid are sodium hydroxide (NaOH) aqueous solution, a concentration of 15% (wt), pH value control are not less than 7.5, and alkaline absorbent recycles during operation, works as pH When value is down to 7.5, pH is adjusted by discharging any waste liquor or the fresh lye of supplement.Alkali liquid temperature is controlled at 30 DEG C.
High VOCs concentration waste gas after removing sulfide enters adsorption bed, and adsorbent selects commercially available common active carbon fibre Dimension, specific surface area 1300m2/ g, hole hold 0.8ml/g, average pore size 2.0nm.Total volume air speed is 1200h-1, absorption 12h is again It is raw.All kinds of organic components in high VOCs concentration waste gas are fully adsorbed by adsorbent.
Steam after low VOCs concentration waste gas and purified high VOCs concentration waste gas and desorption by it is condensed not Solidifying gas is mixed into biological treatment.Biological treatment uses two sections of biological law technologies of bio-trickling-biofiltration.Two The bacterium solution of commercially available can degrade malodor components and VOCs components is sprayed in section bioanalysis.Wherein bio-trickling section is filled out using biology Expect the plastic filler for polyhedron empty ball, residence time 30s;Biofiltration section is organic and nothing using commercially available biologic packing material Machine compounded mix, residence time 30s.Two sections of bioanalysis bacterium solution temperature are 30 DEG C.
The exhaust gas containing VOCs that sewage farm loss goes out is after above-mentioned process, exit gas non-methane total hydrocarbons concentration Less than 70mg/m3, concentration of hydrogen sulfide examines and do not measure substantially.Purification discharge gas can meet national environmental protection regulation to oil refining enterprise's dirt The related request of Large Water Treatment Field waste gas emission standard.
The above is for only for ease of it will be understood by those skilled in the art that technical scheme of the present invention, not limiting The present invention.All within the spirits and principles of the present invention, any modification, equivalent replacement, improvement and so on should be included in this Within the protection domain of invention.

Claims (10)

1. a kind of comprehensive purifying method for the exhaust gas containing VOCs that sewage farm loss goes out, it is characterised in that:The processing method Include the following steps:
The exhaust gas containing VOCs of sewage farm loss is pressed into high concentration VOCs exhaust gas and low concentration VOCs exhaust gas categorised collections;
The high concentration VOCs exhaust gas initially enters absorption tower (1) and carries out wet desulphurization, then enters back into adsorption bed (2) progress Adsorption cleaning, the clean gas after being adsorbed;
Clean gas after the absorption with the low concentration VOCs exhaust gas is mixed, and passes through biological bed (3) and is handled.
2. the comprehensive purifying method for the exhaust gas containing VOCs that sewage farm loss according to claim 1 goes out, feature exist In,
After the absorption of the adsorption bed (2) reaches saturation, using water vapour to the adsorbent in the adsorption bed (2) It is desorbed to obtain mixed vapour;The mixed vapour after desorption enters condenser (4) heat exchange cooling, forms condensate liquid and not Solidifying gas;
And the fixed gas with clean gas, the low concentration VOCs exhaust gas after the absorption is mixed, and is passed through described Biological bed (3) is handled.
3. the comprehensive purifying method for the exhaust gas containing VOCs that sewage farm loss according to claim 2 goes out, feature exist In the condensate liquid enters layering slot (5) and is layered, and obtains organic solvent not soluble in water.
4. the comprehensive purifying method for the exhaust gas containing VOCs that sewage farm loss according to claim 2 goes out, feature exist In the adsorption bed (2) includes the first absorption casing (21) and the second absorption casing (22), and first absorption casing (21) and second absorption casing (22) handover operation that can be adsorbed and desorbed.
5. according to the comprehensive purifying method for the exhaust gas containing VOCs that claim 1-4 any one of them sewage farm loss goes out, It is characterized in that, it is described biology bed (3) processing include zinc cation, bio-trickling and biofiltration any one or two The combination of kind biological treatment section.
6. according to the comprehensive purifying method for the exhaust gas containing VOCs that claim 1-4 any one of them sewage farm loss goes out, It is characterized in that, the desulfurization absorbing liquid for carrying out wet desulphurization is provided in the absorption tower (1);
The desulfurization absorbing liquid is alkaline solution, and the alkaline solution is sodium hydroxide (NaOH) aqueous solution, potassium hydroxide (KOH) Aqueous solution, sodium carbonate (Na2CO3) aqueous solution, potassium carbonate (K2CO3) aqueous solution or ammonium hydroxide.
7. according to the comprehensive purifying method for the exhaust gas containing VOCs that claim 2-4 any one of them sewage farm loss goes out, It is characterized in that, the adsorbent on the adsorption bed (2) is active carbon particle and/or activated carbon fibre.
8. according to the comprehensive purifying method for the exhaust gas containing VOCs that claim 1-4 any one of them sewage farm loss goes out, It is characterized in that, the high concentration VOCs source exhaust gas is collected in sewage farm, oil removal and Treatment of Sludge structures, including Sewage is adjusted between tank, oil separator, floation tank, slop tank, sludge concentration tank, the dehydration of three mud;The low concentration VOCs source exhaust gas In sewage farm biochemical treatment structures, including biochemistry pool, aeration tank, a heavy pond.
9. according to the comprehensive purifying method for the exhaust gas containing VOCs that claim 1-4 any one of them sewage farm loss goes out, It is characterized in that, the mean concentration of VOCs is in 300~6000mg/m in the high concentration VOCs exhaust gas3, the low concentration VOCs The mean concentration of VOCs is not more than 200mg/m in exhaust gas3
10. according to the comprehensive purifying method for the exhaust gas containing VOCs that claim 2-4 any one of them sewage farm loss goes out, It is characterized in that, the temperature for the water vapour of desorption is 100-200 DEG C.
CN201611242114.2A 2016-12-29 2016-12-29 A kind of comprehensive purifying method for the exhaust gas containing VOCs that sewage farm loss goes out Pending CN108246064A (en)

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CN111282433A (en) * 2020-03-25 2020-06-16 杭州楚环科技股份有限公司 VOCs waste gas treatment method and VOCs waste gas treatment system
CN114917715A (en) * 2022-05-19 2022-08-19 合肥国风先进基础材料科技有限公司 Method for recovering DMAc solvent in waste gas of polyimide film production line
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Application publication date: 20180706