CN108244263A - Emulsion compositions, fat or oil composition and their purposes - Google Patents
Emulsion compositions, fat or oil composition and their purposes Download PDFInfo
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- CN108244263A CN108244263A CN201611243635.XA CN201611243635A CN108244263A CN 108244263 A CN108244263 A CN 108244263A CN 201611243635 A CN201611243635 A CN 201611243635A CN 108244263 A CN108244263 A CN 108244263A
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- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23D—EDIBLE OILS OR FATS, e.g. MARGARINES, SHORTENINGS, COOKING OILS
- A23D7/00—Edible oil or fat compositions containing an aqueous phase, e.g. margarines
- A23D7/001—Spread compositions
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- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23D—EDIBLE OILS OR FATS, e.g. MARGARINES, SHORTENINGS, COOKING OILS
- A23D7/00—Edible oil or fat compositions containing an aqueous phase, e.g. margarines
- A23D7/005—Edible oil or fat compositions containing an aqueous phase, e.g. margarines characterised by ingredients other than fatty acid triglycerides
- A23D7/0056—Spread compositions
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23D—EDIBLE OILS OR FATS, e.g. MARGARINES, SHORTENINGS, COOKING OILS
- A23D9/00—Other edible oils or fats, e.g. shortenings, cooking oils
- A23D9/02—Other edible oils or fats, e.g. shortenings, cooking oils characterised by the production or working-up
- A23D9/04—Working-up
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- Oil, Petroleum & Natural Gas (AREA)
- Life Sciences & Earth Sciences (AREA)
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- Food Science & Technology (AREA)
- Polymers & Plastics (AREA)
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Abstract
The present invention provides emulsion compositions, fat or oil composition and their purposes.The emulsion compositions of the present invention, which is characterized in that in terms of total composition, containing 50~65 weight % of water phase, 20~35 weight % of oil phase, 25 DEG C of solid fats content SFC of grease is 20~50 weight % in oil phase.The emulsion compositions of the present invention can improve foaming characteristic and stability.
Description
Technical field
The present invention relates to emulsion compositions, fat or oil composition and their purposes, the purposes particularly in whipped cream.
Background technology
Plant butter cream be using vegetable fat as primary raw material, add in water, protein, emulsifier, thickening stabilizing agent, essence,
The covering with paint and one kind of mounting flower that pigment etc. makes by the strict technologies such as dispensing, emulsification, sterilization, homogeneous, cooling, filling are special
Whipping prods.To the texture of plant butter cream, organoleptic attribute and storage-stable play an important role type, fusing point and the composition of grease
(Knightly, W.H. (1968) .The role of ingredients in the formulation of whipped
Topping.Food Technology, 22,73~86 and Yang Xiaobo, Liu Fan, Wang Xiaoying, Cai Yunsheng, grease, which resists ice cream, to be melted
The influence [J] of property, food industry, 1998,1,7~8).
The quite high fat of hardenability beats bubble product particularly suitable for manufacture, plays product because unsaturated fat has
The shortcomings that bubble property is poor, foam is coarse([English] Ralph Early write, and Zhang Guonong, Lv Bing, Lu Rongrong are translated, dairy products product production technology
(The second edition)[M], Beijing, China Light Industry Press, 2002, l, 218~234 and Wu Hui, Wu Tao, Wu Jianfeng etc., dilute milk
Oil and its application [J], food industry, 2005, (1):19~21).
Patent document CN103315071A, discloses using palm-kernel oil(PKO)And coconut oil(CNO)Non-hydrogenated allotment
Oil base overcomes the characteristics of non-hydrogenated grease stability during plant fresh cream is made is poor, and the amount of rising is low.
Patent document US8603559B2, discloses using PKO, CNO and palm oil(PO)Middle a kind of or its several mixing are sweet
The oil base of three esters, product are stable in processing and freeze/thaw, and the product for beating generation can be used for ice cream, cake mounting
Flower and sandwich decoration.
Patent document US20080038435A1 is disclosed and is made of C12~C14 short chains vegetable oil and long-chain vegetable oil, nothing
Hydrogenation.C12~C14 vegetable oil sources are in PKO, PKO fraction leach-s/tive, CNO, shea butter, babassu oil, murumuru oil(tucum
oil)And its mixture;Long-chain vegetable oil source is in soybean oil, palm oil, canola oil, corn oil, linseed oil, sunflower seeds
Oil and its mixture.The allotment grease consolidates fat characteristic similar to natural milk fat(butterfat), when such product is as mounting flower layer
Conformality is poor.
Patent document JP2015211666A, discloses by medium-chain triglycerides(MCT)It is sweet with long chain fatty acids
Oily three esters can increase product sweetness, reduce sugared dosage to plant butter cream after certain proportion transesterification for beating.
Medium-chain triglycerides(Medium- chain triglycerides, MCT)It typically refers to middle carbon
Chain fatty acid(Medium- chain fatty acid, MCFA, C6~C12)The triglycerides being made of main component.One
As think, typical MCT refer to saturation Trivent OCG or saturation Triglyceride DDD or saturation caprylic-capric acid mixing it is sweet
Oily three esters.Carbochain is then referred to as long-chain fat acid glyceride by the triglyceride that more than 12 aliphatic acid is formed(Long
Chain triglyceride, LCT).
Compared with common vegetable fat, MCT has special nutritive value, can be as the structure ester efficiently digested and assimilated
With the low energy grease of control fatty acid absorption.
Plant fresh cream system is oil hydrosol system, and the degree of stability of system is influenced by more raw material, and system is not
Stabilization can cause it to generate apparent water-oil separating phenomenon etc. during preparing and storing.Variety classes grease is to body in system
The stability of system and whipping also have larger impact using stability.
MCT solidification points are low, are at room temperature liquid oil, there are problems that compatibility with the compounding of high-melting-point grease, beating
Planting the application in butter cream easily can affect greatly product system stability and whipping application performance etc..
Invention content
The present invention carries tristearin using palm kernel oil(PKST)Or hydrogenated palm kernel oil(HPKO), it is sweet with medium-chain fatty acid
Oily three esters(MCT), after being allocated using certain proportion, the problems such as product foaming characteristic is poor, and product foam is coarse is improved, while also solve
Oil/fat composition containing miglyol 812 of having determined applies stability problem in plant butter cream system is beaten, such as the abnormal easy appearance of product defrosting
" soybean residue " state, water-oil separating, cannot beat rise, beat the rate of rising it is poor, beat stability it is poor the problems such as.
The present invention provides emulsion compositions, which is characterized in that in terms of emulsion compositions total amount, contains 50~65 weight of water phase
%, 20~35 weight % of oil phase are measured, 25 DEG C of solid fats content SFC of grease is 20~50 weight % in oil phase.
Emulsion compositions according to the present invention, wherein, the oil phase contains carries stearic or hydrogen selected from palm kernel oil
Change any one of palm-kernel oil and medium-chain triglycerides.
Emulsion compositions according to the present invention, wherein, in terms of emulsion compositions total amount, the content of the water phase is 55
~60 weight %.
Emulsion compositions according to the present invention, wherein, in terms of emulsion compositions total amount, the content of the oil phase is 20
~30 weight %.
Emulsion compositions according to the present invention, wherein, in terms of oil phase total amount, 25 DEG C of grease in the oil phase
Solid fats content is 24~48 weight %.Emulsion compositions according to the present invention, wherein, in terms of oil phase total amount, the oil
25 DEG C of solid fats content of the grease in phase is 25~40 weight %.
Emulsion compositions according to the present invention, wherein, in terms of oil phase total amount, 10 DEG C of grease in the oil phase
Solid fats content is 55~75 weight %.Emulsion compositions according to the present invention, wherein, in terms of oil phase total amount, the oil
10 DEG C of solid fats content of the grease in phase is 58~73 weight %.
Emulsion compositions according to the present invention, wherein, in terms of oil phase total amount, 20 DEG C of grease in the oil phase
Solid fats content is 40~60 weight %.Emulsion compositions according to the present invention, wherein, in terms of oil phase total amount, the oil
20 DEG C of solid fats content of the grease in phase is 42~58 weight %.
Emulsion compositions according to the present invention, wherein, the oil phase contains medium-chain triglycerides and palm fibre
Palmitic acid benevolence oil carries tristearin.
Emulsion compositions according to the present invention, wherein, in terms of oil phase total amount, 30 DEG C of grease in the oil phase
Solid fats content is 0.1~10 weight %.Emulsion compositions according to the present invention, wherein, it is described in terms of oil phase total amount
30 DEG C of solid fats content of the grease in oil phase is 0.2~8 weight %.
Emulsion compositions according to the present invention, wherein, in terms of fatty acid total amount in the oil phase, unrighted acid
Ratio be 5.8~7.1 weight %.Emulsion compositions according to the present invention, wherein, with fatty acid total amount in the oil phase
Meter, the ratio of unrighted acid is 6.0~7.0 weight %.Emulsion compositions according to the present invention, wherein, with the oil
Fatty acid total amount meter in phase, the ratio of unrighted acid is 6.2~6.9 weight %.
Emulsion compositions according to the present invention, wherein, the unrighted acid is selected from C18:1、C18:2 or C18:
At least one of 3n6.Emulsion compositions according to the present invention, wherein, in terms of fatty acid total amount in the oil phase, C18:
1 ratio is 5.0~6.1 weight %.Emulsion compositions according to the present invention, wherein, with fatty acid total amount in the oil phase
Meter, C18:1 ratio is 5.3~5.9 weight %.Emulsion compositions according to the present invention, wherein, with fat in the oil phase
Fat acid total amount meter, C18:2 ratio is 0.75~0.88 weight %.Emulsion compositions according to the present invention, wherein, with institute
State fatty acid total amount meter in oil phase, C18:2 ratio is 0.80~0.85 weight %.Emulsion compositions according to the present invention,
Wherein, in terms of fatty acid total amount in the oil phase, C18:The ratio of 3n6 is 0.09~0.10 weight %.
Emulsion compositions according to the present invention, wherein, in terms of fatty acid total amount in the oil phase, saturated fatty acid
Ratio is 92.9~94.2 weight %.Emulsion compositions according to the present invention, wherein, with fatty acid total amount in the oil phase
Meter, the ratio of saturated fatty acid is 93.0~94.0 weight %.Emulsion compositions according to the present invention, wherein, with the oil
Fatty acid total amount meter in phase, the ratio of saturated fatty acid is 93.1~93.8 weight %.
Emulsion compositions according to the present invention, wherein, the saturated fatty acid is selected from C6:0、C8:0、C10:0、
C12:0、C14:0、C16:0 or C18:At least one of 0.Emulsion compositions according to the present invention, wherein, with the oil
Fatty acid total amount meter in phase, C8:0 ratio is 7.0~14.0 weight %.Emulsion compositions according to the present invention, wherein,
In terms of fatty acid total amount in the oil phase, C8:0 ratio is 8.0~13.0 weight %.Emulsion combination according to the present invention
Object, wherein, in terms of fatty acid total amount in the oil phase, C10:0 ratio is 7.5~14.0 weight %.It is according to the present invention
Emulsion compositions, wherein, in terms of fatty acid total amount in the oil phase, C10:0 ratio is 8.0~13.0 weight %.According to this hair
The bright emulsion compositions, wherein, in terms of fatty acid total amount in the oil phase, C12:0 ratio is 36.0~44.5 weights
Measure %.Emulsion compositions according to the present invention, wherein, in terms of fatty acid total amount in the oil phase, C12:0 ratio is
38.0~43.5 weight %.Emulsion compositions according to the present invention, wherein, in terms of fatty acid total amount in the oil phase, C14:
0 ratio is 17.5~21.5 weight %.Emulsion compositions according to the present invention, wherein, it is total with aliphatic acid in the oil phase
Gauge, C14:0 ratio is 18.5~20.5 weight %.Emulsion compositions according to the present invention, wherein, with the oil phase
Middle fatty acid total amount meter, C16:0 ratio is 8.4~10.0 weight %.Emulsion compositions according to the present invention, wherein, with
Fatty acid total amount meter, C16 in the oil phase:0 ratio is 8.8~9.6 weight %.According to the Emulsion combination described in item of the present invention
Object, wherein, in terms of fatty acid total amount in the oil phase, C18:0 ratio is 2.3~2.7 weight %.It is according to the present invention
Emulsion compositions, wherein, in terms of fatty acid total amount in the oil phase, C18:0 ratio is 2.4~2.6 weight %.
Emulsion compositions according to the present invention, wherein, the oil phase contains medium-chain triglycerides and hydrogen
Change palm-kernel oil.
Emulsion compositions according to the present invention, wherein, in terms of oil phase total amount, 30 DEG C of grease in the oil phase
Solid fats content is 12~24 weight %.Emulsion compositions according to the present invention, wherein, in terms of oil phase total amount, the oil
30 DEG C of solid fats content of the grease in phase is 15~23 weight %.
Emulsion compositions according to the present invention, wherein, in terms of oil phase total amount, 35 DEG C of grease in the oil phase
Solid fats content is 7.5~11.5 weight %.Emulsion compositions according to the present invention, wherein, in terms of oil phase total amount, institute
35 DEG C of solid fats content for stating the grease in oil phase is 8.0~11.0 weight %.
Emulsion compositions according to the present invention, wherein, in terms of oil phase total amount, 40 DEG C of grease in the oil phase
Solid fats content is 3.5~6.0 weight %.Emulsion compositions according to the present invention, wherein, it is described in terms of oil phase total amount
40 DEG C of solid fats content of the grease in oil phase is 3.8~5.8 weight %.
Emulsion compositions according to the present invention, wherein, in terms of fatty acid total amount in the oil phase, unrighted acid
Ratio be 0.30~0.35 weight %.Emulsion compositions according to the present invention, wherein, it is total with aliphatic acid in the oil phase
Gauge, the ratio of unrighted acid is 0.33~0.35 weight %.
Emulsion compositions according to the present invention, wherein, the unrighted acid is selected from C18:1、C18:2 or C18:
At least one of 3n6.Emulsion compositions according to the present invention, wherein, in terms of fatty acid total amount in the oil phase, C18:
1 ratio is 0.01~0.2 weight %.Emulsion compositions according to the present invention, wherein, it is total with aliphatic acid in the oil phase
Gauge, C18:The ratio of 3n6 is 0.25~0.27 weight %.Emulsion compositions according to the present invention, wherein, with the oil
Fatty acid total amount meter in phase, the ratio of saturated fatty acid is 99.64~99.7 weight %.
Emulsion compositions according to the present invention, wherein, the saturated fatty acid is selected from C6:0、C8:0、C10:0、
C12:0、C14:0、C16:0 or C18:At least one of 0.Emulsion compositions according to the present invention, wherein, with the oil
Fatty acid total amount meter in phase, C6:0 ratio is 0.10~0.12 weight %.Emulsion compositions according to the present invention, wherein,
In terms of fatty acid total amount in the oil phase, C8:0 ratio is 8.0~15.0 weight %.Emulsion combination according to the present invention
Object, wherein, in terms of fatty acid total amount in the oil phase, C8:0 ratio is 9.0~13.0 weight %.It is according to the present invention
Emulsion compositions, wherein, in terms of fatty acid total amount in the oil phase, C10:0 ratio is 8.0~14.0 weight %.According to this hair
The bright emulsion compositions, wherein, in terms of fatty acid total amount in the oil phase, C10:0 ratio is 8.5~13.0 weight %.
Emulsion compositions according to the present invention, wherein, in terms of fatty acid total amount in the oil phase, C12:0 ratio for 31.0~
37.5 weight %.Emulsion compositions according to the present invention, wherein, in terms of fatty acid total amount in the oil phase, C12:0 ratio
Example is 32.0~36.5 weight %.Emulsion compositions according to the present invention, wherein, in terms of fatty acid total amount in the oil phase,
C14:0 ratio is 11.5~14.0 weight %.Emulsion compositions according to the present invention, wherein, with fatty in the oil phase
Sour total amount meter, C14:0 ratio is 12.0~13.8 weight %.Emulsion compositions according to the present invention, wherein, with described
Fatty acid total amount meter in oil phase, C16:0 ratio is 8.0~9.5 weight %.Emulsion compositions according to the present invention,
In, in terms of fatty acid total amount in the oil phase, C16:0 ratio is 8.5~9.3 weight %.Lotion group according to the present invention
Object is closed, wherein, in terms of fatty acid total amount in the oil phase, C18:0 ratio is 19.0~22.8 weight %.According to institute of the present invention
The emulsion compositions stated, wherein, in terms of fatty acid total amount in the oil phase, C18:0 ratio is 20.5~22.5 weight %.
Emulsion compositions according to the present invention, wherein, aliphatic acid is originated from the medium-chain triglycerides
Part be carbon atom number be 8~10 linear chain or branch chain, saturation or unrighted acid.
Emulsion compositions according to the present invention, wherein, also comprising sweetener, emulsifier, thickener, essence, moisture
At least one of retention agent or edible salt.
Emulsion compositions according to the present invention, wherein, the sweetener in corn syrup or white granulated sugar extremely
Few one kind;The emulsifier is in Sodium Caseinate, polysorbate60, mono-fatty acid glyceride, diglycerine fatty acid ester or sorbester p18
At least one;At least one of the thickener hydroxypropyl methyl cellulose, xanthans, guar gum or sodium alginate;Institute
Essence is stated as food flavor;The water retention agent is disodium hydrogen phosphate.
Emulsion compositions according to the present invention, wherein, in terms of oil phase total amount, the medium-chain triglycerides
Content be 15~30 weight %, preferably 18~25 weight %.
Emulsion compositions according to the present invention, wherein, it is described to carry tristearin selected from palm kernel oil in terms of oil phase total amount
Or the content of any one of hydrogenated palm kernel oil is 70~85 weight %, preferably 75~82 weight %.
Emulsion compositions according to the present invention, wherein, it is described to be selected from palm kernel oil in terms of emulsion compositions total amount
The content for carrying any one of stearic or hydrogenated palm kernel oil is 14~30 weight %.Emulsion compositions according to the present invention,
Wherein, it is described to carry containing for any one of stearic or hydrogenated palm kernel oil selected from palm kernel oil in terms of emulsion compositions total amount
It measures as 15~25 weight %.Emulsion compositions according to the present invention, wherein, it is described selected from palm fibre in terms of emulsion compositions total amount
The content that palmitic acid benevolence oil carries any one of stearic or hydrogenated palm kernel oil is 17~20 weight %.Breast according to the present invention
Liquid composition, wherein, in terms of emulsion compositions total amount, the content of the medium-chain triglycerides is 3~11 weight %.
Emulsion compositions according to the present invention, wherein, in terms of emulsion compositions total amount, the medium-chain triglycerides
Content is 3.5~10 weight %.Emulsion compositions according to the present invention, wherein, in terms of total composition, the middle carbochain
The content of fatty acid triglycercide is 4~8 weight %.
The present invention is provided to the fat or oil compositions of whipped cream, which is characterized in that 25 DEG C of the fat or oil composition
Solid fats content is 20~50 weight %.Fat or oil composition according to the present invention, wherein, in terms of fat or oil composition total amount,
25 DEG C of solid fats content of the fat or oil composition is 24~48 weight %.Fat or oil composition according to the present invention,
In, in terms of fat or oil composition total amount, 25 DEG C of solid fats content of the fat or oil composition is 25~40 weight %.
Fat or oil composition according to the present invention, wherein, in terms of fat or oil composition total amount, the 10 of the fat or oil composition
DEG C solid fats content be 55~75 weight %.Fat or oil composition according to the present invention, wherein, it is total with fat or oil composition
Gauge, 10 DEG C of solid fats content of the fat or oil composition is 58~73 weight %.
Fat or oil composition according to the present invention, wherein, in terms of fat or oil composition total amount, the 20 of the fat or oil composition
DEG C solid fats content be 40~60 weight %.Fat or oil composition according to the present invention, wherein, it is total with fat or oil composition
Gauge, 20 DEG C of solid fats content of the fat or oil composition is 42~58 weight %.
Fat or oil composition according to the present invention, wherein, in terms of fat or oil composition total amount, the fat or oil composition includes
Any one of stearic or hydrogenated palm kernel oil and medium-chain triglycerides are carried selected from palm kernel oil, wherein, with oil
Oil/fat composition total amount meter, the content of the medium-chain triglycerides is 15~30 weight %.Oil according to the present invention
Oil/fat composition, wherein, in terms of fat or oil composition total amount, the content of the medium-chain triglycerides is 18~25 weight %.
Fat or oil composition according to the present invention, wherein, it is described to be selected from palm kernel oil in terms of fat or oil composition total amount
The content for carrying any one of stearic or hydrogenated palm kernel oil is 70~85 weight %.Fat or oil composition according to the present invention,
Wherein, it is described to carry containing for any one of stearic or hydrogenated palm kernel oil selected from palm kernel oil in terms of fat or oil composition total amount
It measures as 75~82 weight %.
Fat or oil composition according to the present invention, wherein, the fat or oil composition contains medium-chain fatty acid glycerine three
Ester and palm kernel oil carry tristearin.
Fat or oil composition according to the present invention, wherein, in terms of fat or oil composition total amount, the 30 of the fat or oil composition
DEG C solid fats content be 0.1~10 weight %.Fat or oil composition according to the present invention, wherein, it is total with fat or oil composition
Gauge, 30 DEG C of solid fats content of the fat or oil composition is 0.2~8 weight %.
Fat or oil composition according to the present invention, wherein, it is unsaturated in terms of fatty acid total amount in the fat or oil composition
The ratio of aliphatic acid is 5.8~7.1 weight %.Fat or oil composition according to the present invention, wherein, with the fat or oil composition
Middle fatty acid total amount meter, the ratio of unrighted acid is 6.0~7.0 weight %.Fat or oil composition according to the present invention,
Wherein, in terms of fatty acid total amount in the fat or oil composition, the ratio of unrighted acid is 6.2~6.9 weight %.
Fat or oil composition according to the present invention, wherein, the unrighted acid is selected from C18:1、C18:2 or C18:
At least one of 3n6.Fat or oil composition according to the present invention, wherein, with fatty acid total amount in the fat or oil composition
Meter, C18:1 ratio is 5.0~6.1 weight %.Fat or oil composition according to the present invention, wherein, it is combined with the grease
Fatty acid total amount meter in object, C18:1 ratio is 5.3~5.9 weight %.Fat or oil composition according to the present invention, wherein,
In terms of fatty acid total amount in the fat or oil composition, C18:2 ratio is 0.75~0.88 weight %.It is according to the present invention
Fat or oil composition, wherein, in terms of fatty acid total amount in the fat or oil composition, C18:2 ratio is 0.80~0.85 weight %.
Fat or oil composition according to the present invention, wherein, in terms of fatty acid total amount in the fat or oil composition, C18:The ratio of 3n6
For 0.09~0.10 weight %.
Fat or oil composition according to the present invention, wherein, in terms of fatty acid total amount in the fat or oil composition, saturated fat
The ratio of fat acid is 92.9~94.2 weight %.Fat or oil composition according to the present invention, wherein, with the fat or oil composition
Middle fatty acid total amount meter, the ratio of saturated fatty acid is 93.0~94.0 weight %.Fat or oil composition according to the present invention,
Wherein, in terms of fatty acid total amount in the fat or oil composition, the ratio of saturated fatty acid is 93.1~93.8 weight %.
Fat or oil composition according to the present invention, wherein, the saturated fatty acid is selected from C6:0、C8:0、C10:0、
C12:0、C14:0、C16:0 or C18:At least one of 0.Fat or oil composition according to the present invention, wherein, with the oil
Fatty acid total amount meter in oil/fat composition, C8:0 ratio is 7.0~14.0 weight %.Fat or oil composition according to the present invention,
Wherein, in terms of fatty acid total amount in the fat or oil composition, C8:0 ratio is 8.0~13.0 weight %.According to of the present invention
Fat or oil composition, wherein, in terms of fatty acid total amount in the fat or oil composition, C10:0 ratio is 7.5~14.0 weight %.
Fat or oil composition according to the present invention, wherein, in terms of fatty acid total amount in the fat or oil composition, C10:0 ratio is
8.0~13.0 weight %.Fat or oil composition according to the present invention, wherein, with fatty acid total amount in the fat or oil composition
Meter, C12:0 ratio is 36.0~44.5 weight %.Fat or oil composition according to the present invention, wherein, with the grease group
Close fatty acid total amount meter in object, C12:0 ratio is 38.0~43.5 weight %.Fat or oil composition according to the present invention,
In, in terms of fatty acid total amount in the fat or oil composition, C14:0 ratio is 17.5~21.5 weight %.According to of the present invention
Fat or oil composition, wherein, in terms of fatty acid total amount in the fat or oil composition, C14:0 ratio is 18.5~20.5 weights
Measure %.Fat or oil composition according to the present invention, wherein, in terms of fatty acid total amount in the fat or oil composition, C16:0 ratio
Example is 8.4~10.0 weight %.Fat or oil composition according to the present invention, wherein, it is total with aliphatic acid in the fat or oil composition
Gauge, C16:0 ratio is 8.8~9.6 weight %.Fat or oil composition according to the present invention, wherein, with the grease group
Close fatty acid total amount meter in object, C18:0 ratio is 2.3~2.7 weight %.Fat or oil composition according to the present invention,
In, in terms of fatty acid total amount in the fat or oil composition, C18:0 ratio is 2.4~2.6 weight %.
Fat or oil composition according to the present invention, wherein, the fat or oil composition contains medium-chain fatty acid glycerine three
Ester and hydrogenated palm kernel oil.
Fat or oil composition according to the present invention, wherein, in terms of fat or oil composition total amount, the 30 of the fat or oil composition
DEG C solid fats content be 12~24 weight %.Fat or oil composition according to the present invention, wherein, it is total with fat or oil composition
Gauge, 30 DEG C of solid fats content of the grease in the fat or oil composition is 15~23 weight %.
Fat or oil composition according to the present invention, wherein, in terms of fat or oil composition total amount, the 35 of the fat or oil composition
DEG C solid fats content be 7.5~11.5 weight %.Fat or oil composition according to the present invention, wherein, with fat or oil composition
Total amount meter, 35 DEG C of solid fats content of the fat or oil composition is 8.0~11.0 weight %.
Fat or oil composition according to the present invention, wherein, in terms of fat or oil composition total amount, the 40 of the fat or oil composition
DEG C solid fats content be 3.5~6.0 weight %.Fat or oil composition according to the present invention, wherein, with fat or oil composition
Total amount meter, 40 DEG C of solid fats content of the fat or oil composition is 3.8~5.8 weight %.
Fat or oil composition according to the present invention, wherein, it is unsaturated in terms of fatty acid total amount in the fat or oil composition
The ratio of aliphatic acid is 0.30~0.35 weight %.Fat or oil composition according to the present invention, wherein, it is combined with the grease
Fatty acid total amount meter in object, the ratio of unrighted acid is 0.33~0.35 weight %.
Fat or oil composition according to the present invention, wherein, the unrighted acid is selected from C18:1、C18:2 or C18:
At least one of 3n6.Fat or oil composition according to the present invention, wherein, with fatty acid total amount in the fat or oil composition
Meter, C18:1 ratio is 0.01~0.2 weight %.Fat or oil composition according to the present invention, wherein, it is combined with the grease
Fatty acid total amount meter in object, C18:The ratio of 3n6 is 0.25~0.27 weight %.
Fat or oil composition according to the present invention, wherein, in terms of fatty acid total amount in the fat or oil composition, saturated fat
The ratio of fat acid is 99.64~99.7 weight %.
Fat or oil composition according to the present invention, wherein, the saturated fatty acid is selected from C6:0、C8:0、C10:0、
C12:0、C14:0、C16:0 or C18:At least one of 0.Fat or oil composition according to the present invention, wherein, with the oil
Fatty acid total amount meter in oil/fat composition, C6:0 ratio is 0.10~0.12 weight %.Grease combination according to the present invention
Object, wherein, in terms of fatty acid total amount in the fat or oil composition, C8:0 ratio is 8.0~15.0 weight %.According to the present invention
The fat or oil composition, wherein, in terms of fatty acid total amount in the fat or oil composition, C8:0 ratio is 9.0~13.0 weights
Measure %.Fat or oil composition according to the present invention, wherein, in terms of fatty acid total amount in the fat or oil composition, C10:0 ratio
Example is 8.0~14.0 weight %.Fat or oil composition according to the present invention, wherein, it is total with aliphatic acid in the fat or oil composition
Gauge, C10:0 ratio is 8.5~13.0 weight %.Fat or oil composition according to the present invention, wherein, with the grease group
Close fatty acid total amount meter in object, C12:0 ratio is 31.0~37.5 weight %.Fat or oil composition according to the present invention,
In, in terms of fatty acid total amount in the fat or oil composition, C12:0 ratio is 32.0~36.5 weight %.According to of the present invention
Fat or oil composition, wherein, in terms of fatty acid total amount in the fat or oil composition, C14:0 ratio is 11.5~14.0 weights
Measure %.Fat or oil composition according to the present invention, wherein, in terms of fatty acid total amount in the fat or oil composition, C14:0 ratio
Example is 12.0~13.8 weight %.Fat or oil composition according to the present invention, wherein, with aliphatic acid in the fat or oil composition
Total amount meter, C16:0 ratio is 8.0~9.5 weight %.Fat or oil composition according to the present invention, wherein, with the grease
Fatty acid total amount meter in composition, C16:0 ratio is 8.5~9.3 weight %.Fat or oil composition according to the present invention,
In, in terms of fatty acid total amount in the fat or oil composition, C18:0 ratio is 19.0~22.8 weight %.According to of the present invention
Fat or oil composition, wherein, in terms of fatty acid total amount in the fat or oil composition, C18:0 ratio is 20.5~22.5 weights
Measure %.
Fat or oil composition according to the present invention, wherein, aliphatic acid is originated from the medium-chain triglycerides
Part be carbon atom number be 8~10 linear chain or branch chain, saturation or unrighted acid.
The present invention provides the preparation method of emulsion compositions, including preparing water phase step, preparing oil phase step, mixing institute
The step of water phase of preparation and prepared oil phase, beats step at homogenizing step, cooling step.
Preparation method according to the present invention, wherein, in terms of emulsion compositions total amount, containing 50~65 weight % of water phase,
20~35 weight % of oil phase, 25 DEG C of solid fats content SFC of grease is 20~50 weight % in oil phase.
Preparation method according to the present invention, wherein, in terms of oil phase total amount, 10 DEG C of grease in the oil phase consolidate
Body fat content is 55~75 weight %, preferably 58~73 weight %.
Preparation method according to the present invention, wherein, in terms of oil phase total amount, 20 DEG C of grease in the oil phase consolidate
Body fat content is 40~60 weight %, preferably 42~58 weight %.Preparation method according to the present invention, wherein, it is described
It prepares in water phase step, sweetener, salt, hydrophilic emulsifying agent and thickener is added to the water, stirs and heats, obtain water phase.
Preparation method according to the present invention, wherein, it is described to prepare in oil phase step, by medium-chain fatty acid glycerine three
Ester and after palm kernel oil puies forward any one of stearic or hydrogenated palm kernel oil heating stirring, adds in oleophilic emulsifier, obtains
To oil phase.
Preparation method according to the present invention, wherein, the step of water phase and prepared oil phase prepared by the mixing
Gained oil phase is added in gained water phase in rapid, obtains lotion.
Preparation method according to the present invention, wherein, gained lotion is subjected to twice homogenization in the homogenizing step.
Preparation method according to the present invention, wherein, the cooling step includes chilling step and freezing step.
Preparation method according to the present invention, wherein, it is further included between the chilling step and the freezing step
Maturation stage.
Preparation method according to the present invention, wherein, defrosting step is further included after the cooling step.
Preparation method according to the present invention, wherein, the whipping step is carried out after the defrosting step.
The present invention provides cream, it includes emulsion compositions according to the present invention or comprising according to of the present invention
Fat or oil composition or preparation method of the present invention made from emulsion compositions.
The present invention provides food, and it includes emulsion compositions according to the present invention, greases according to the present invention
Composition or cream according to the present invention.
Invention effect
The present invention carries tristearin using palm kernel oil(PKST)Or hydrogenated palm kernel oil(HPKO), with medium-chain fatty acid glycerine three
Ester(MCT), after being allocated using certain proportion, the problems such as product foaming characteristic is poor, and product foam is coarse is improved, while also solve
Oil/fat composition containing miglyol 812 system stability and whipping stability problem in plant butter cream is beaten go out as product defrosting is abnormal
Existing " soybean residue " state, water-oil separating cannot be beaten and rises, beats the problems such as rate of rising is poor, whipping stability is poor.
Description of the drawings
Fig. 1 is the flowchart illustrations of the preparation method of the emulsion compositions of the present invention.
Specific embodiment
The present invention provides emulsion compositions, which is characterized in that in terms of emulsion compositions total amount, contains 50~65 weight of water phase
%, 20~35 weight % of oil phase are measured, 25 DEG C of solid fats content SFC of grease is 20~50 weight % in oil phase.The oil phase contains
There are medium-chain triglycerides(MCT)Tristearin is carried with selected from palm kernel oil(PKST)Or hydrogenated palm kernel oil(HPKO)In
It is any.
It is described to carry stearic or hydrogen selected from palm kernel oil in terms of emulsion compositions total amount in the emulsion compositions of the present invention
The content for changing any one of palm-kernel oil is 14~30 weight %, preferably 15~25 weight %, more preferably 17~20 weights
Measure %.In the specific embodiment of the present invention, in terms of emulsion compositions total amount, the palm kernel oil carries stearic contain
It measures as 18.4 weight %.In the specific embodiment of the present invention, in terms of emulsion compositions total amount, the hydrogenated palm kernel
The content of oil is 18.4 weight %.
In the emulsion compositions of the present invention, in terms of emulsion compositions total amount, the medium-chain triglycerides contain
It measures as 3~11 weight %, preferably 3.5~10 weight %, more preferably 4~8 weight %.In the specific embodiment of the present invention,
In terms of emulsion compositions total amount, the content of the medium-chain triglycerides is 4.6 weight %.
In the emulsion compositions of the present invention, in terms of emulsion compositions total amount, the content of the water phase is 55~60 weight %.
In the specific embodiment of the present invention, in terms of emulsion compositions total amount, the content of the water phase is 57.3 weight %.
In the emulsion compositions of the present invention, in terms of emulsion compositions total amount, the content of the oil phase is 20~30 weight %.
In the specific embodiment of the present invention, in terms of emulsion compositions total amount, the content of the oil phase is 23.0 weight %.
In the emulsion compositions of the present invention, in terms of oil phase total amount, 25 DEG C of hard fat of the grease in the oil phase contains
It measures as 24~48 weight %, preferably 25~40 weight %.It is described in terms of oil phase total amount in the specific embodiment of the present invention
25 DEG C of solid fats content of the grease in oil phase is 25.15 weight %, 29.31 weight %, 38.36 weight %, 38.86 weights
Measure %.
In the emulsion compositions of the present invention, in terms of oil phase total amount, 10 DEG C of hard fat of the grease in the oil phase contains
It measures as 55~75 weight %, preferably 58~73 weight %.It is described in terms of oil phase total amount in the specific embodiment of the present invention
10 DEG C of solid fats content of the grease in oil phase is 59.94 weight %, 61.65 weight %, 71.23 weight %, 72.18 weights
Measure %.
In the emulsion compositions of the present invention, in terms of oil phase total amount, 20 DEG C of hard fat of the grease in the oil phase contains
It measures as 40~60 weight %, preferably 42~58 weight %.It is described in terms of oil phase total amount in the specific embodiment of the present invention
20 DEG C of solid fats content of the grease in oil phase is 43.67 weight %, 44.30 weight %, 55.93 weight %, 57.90 weights
Measure %.
In a preferred embodiment of the invention, in emulsion compositions of the invention, the oil phase contains middle carbochain fat
Acid glycerol three ester and palm kernel oil carry tristearin.
In the emulsion compositions of the present invention, in terms of oil phase total amount, 30 DEG C of hard fat of the grease in the oil phase contains
It measures as 0.1~10 weight %, preferably 0.2~8 weight %.It is described in terms of oil phase total amount in the specific embodiment of the present invention
30 DEG C of solid fats content of the grease in oil phase is 0.33 weight %, 6.24 weight %.
In the emulsion compositions of the present invention, in terms of fatty acid total amount in the oil phase, unrighted acid(USFA)Ratio
Example is 5.8~7.1 weight %, more preferably preferably 6.0~7.0 weight %, 6.2~6.9 weight %.In the specific reality of the present invention
It applies in mode, in terms of fatty acid total amount in the oil phase, in the aliphatic acid composition of the oil phase, the ratio of unrighted acid is
6.32 weight %, 6.81 weight %.
The unrighted acid(USFA)Selected from C18:1、C18:2 or C18:At least one of 3n6.
In the emulsion compositions of the present invention, in terms of fatty acid total amount in the oil phase, C18:1 ratio is 5.0~6.1 weights
Measure %, preferably 5.3~5.9 weight %.In the specific embodiment of the present invention, in terms of fatty acid total amount in the oil phase,
C18:1 ratio is 5.44 weight %, 5.86 weight %.
In the emulsion compositions of the present invention, in terms of fatty acid total amount in the oil phase, C18:2 ratio is 0.75~0.88
Weight %, preferably 0.80~0.85 weight %.In the specific embodiment of the present invention, with fatty acid total amount in the oil phase
Meter, C18:2 ratio is 0.80 weight %, 0.85 weight %.
In the emulsion compositions of the present invention, in terms of fatty acid total amount in the oil phase, C18:The ratio of 3n6 for 0.09~
0.10 weight %.
In the emulsion compositions of the present invention, in terms of fatty acid total amount in the oil phase, the ratio of saturated fatty acid is 92.9
~94.2 weight %, preferably 93.0~94.0 weight %, more preferably 93.1~93.8 weight %.In the specific implementation of the present invention
In mode, in terms of fatty acid total amount in the oil phase, the ratio of saturated fatty acid is 93.19 weight %, 93.78 weight %.
The saturated fatty acid is selected from C6:0、C8:0、C10:0、C12:0、C14:0、C16:0 or C18:At least one in 0
Kind.
In the emulsion compositions of the present invention, in terms of fatty acid total amount in the oil phase, C8:0 ratio is 7.0~14.0 weights
Measure %, preferably 8.0~13.0 weight %.In the specific embodiment of the present invention, in terms of fatty acid total amount in the oil phase,
C8:0 ratio is 8.61 weight %, 12.01 weight %.
In the emulsion compositions of the present invention, in terms of fatty acid total amount in the oil phase, C10:0 ratio is 7.5~14.0
Weight %, preferably 8.0~13.0 weight %.In the specific embodiment of the present invention, in terms of fatty acid total amount in the oil phase,
C10:0 ratio is 8.80 weight %, 12.13 weight %.
In the emulsion compositions of the present invention, in terms of fatty acid total amount in the oil phase, C12:0 ratio is 36.0~44.5
Weight %, preferably 38.0~43.5 weight %.In the specific embodiment of the present invention, with fatty acid total amount in the oil phase
It counts, in the aliphatic acid composition of the oil phase, C12:0 ratio is 39.19 weight %, 43.22 weight %.
In the emulsion compositions of the present invention, in terms of fatty acid total amount in the oil phase, C14:0 ratio is 17.5~21.5
Weight %, preferably 18.5~20.5 weight %.In the specific embodiment of the present invention, with fatty acid total amount in the oil phase
Meter, C14:0 ratio is 18.96 weight %, 20.46 weight %.
In the emulsion compositions of the present invention, in terms of fatty acid total amount in the oil phase, C16:0 ratio is 8.4~10.0
Weight %, preferably 8.8~9.6 weight %.In the specific embodiment of the present invention, in terms of fatty acid total amount in the oil phase,
C16:0 ratio is 8.92 weight %, 9.46 weight %.
In the emulsion compositions of the present invention, in terms of fatty acid total amount in the oil phase, C18:0 ratio is 2.3~2.7 weights
Measure %, preferably 2.4~2.6 weight %.In the specific embodiment of the present invention, in terms of fatty acid total amount in the oil phase,
C18:0 ratio is 2.47 weight %, 2.59 weight %.
In a preferred embodiment of the invention, in emulsion compositions of the invention, the oil phase contains middle carbochain fat
Acid glycerol three ester and hydrogenated palm kernel oil.
In the emulsion compositions of the present invention, in terms of oil phase total amount, 30 DEG C of hard fat of the grease in the oil phase contains
It measures as 12~24 weight %, preferably 15~23 weight %.It is described in terms of oil phase total amount in the specific embodiment of the present invention
30 DEG C of solid fats content of the grease in oil phase is 15.68 weight %, 22.32 weight %.
In the emulsion compositions of the present invention, in terms of oil phase total amount, 35 DEG C of hard fat of the grease in the oil phase contains
It measures as 7.5~11.5 weight %, preferably 8.0~11.0 weight %.In the specific embodiment of the present invention, with oil phase total amount
It counts, 35 DEG C of solid fats content of the grease in the oil phase is 8.39 weight %, 10.70 weight %.
In the emulsion compositions of the present invention, in terms of oil phase total amount, 40 DEG C of hard fat of the grease in the oil phase contains
It measures as 3.5~6.0 weight %, preferably 3.8~5.8 weight %.In the specific embodiment of the present invention, in terms of oil phase total amount,
40 DEG C of solid fats content of the grease in the oil phase is 4.08 weight %, 5.43 weight %.
In the emulsion compositions of the present invention, in terms of fatty acid total amount in the oil phase, unrighted acid(USFA)Ratio
Example is 0.30~0.35 weight %.It is unsaturated in terms of fatty acid total amount in the oil phase in the specific embodiment of the present invention
The ratio of aliphatic acid is 0.33 weight %, 0.35 weight %.
The unrighted acid(USFA)Selected from C18:1、C18:2 or C18:At least one of 3n6.
In the emulsion compositions of the present invention, in terms of fatty acid total amount in the oil phase, C18:1 ratio is 0.08 weight %.
C18 is not preferably contained in the emulsion compositions of the present invention:2.
In the emulsion compositions of the present invention, in terms of fatty acid total amount in the oil phase, C18:The ratio of 3n6 for 0.25~
0.27 weight %.
In the emulsion compositions of the present invention, in terms of fatty acid total amount in the oil phase, the ratio of saturated fatty acid is 99.64
~99.7 weight %.
The saturated fatty acid is selected from C6:0、C8:0、C10:0、C12:0、C14:0、C16:0 or C18:At least one in 0
Kind.
In the emulsion compositions of the present invention, in terms of fatty acid total amount in the oil phase, C6:0 ratio is 0.10~0.12
Weight %.
In the emulsion compositions of the present invention, in terms of fatty acid total amount in the oil phase, C8:0 ratio is 8.0~15.0 weights
Measure %, preferably 9.0~13.0 weight %.In the specific embodiment of the present invention, in terms of fatty acid total amount in the oil phase,
C8:0 ratio is 9.4 weight %, 12.49 weight %.
In the emulsion compositions of the present invention, in terms of fatty acid total amount in the oil phase, C10:0 ratio is 8.0~14.0
Weight %, preferably 8.5~13.0 weight %.In the specific embodiment of the present invention, in terms of fatty acid total amount in the oil phase,
C10:0 ratio is 9.04 weight %, 12.17 weight %.
In the emulsion compositions of the present invention, in terms of fatty acid total amount in the oil phase, C12:0 ratio is 31.0~37.5
Weight %, preferably 32.0~36.5 weight %.In the specific embodiment of the present invention, with fatty acid total amount in the oil phase
Meter, C12:0 ratio is 32.52 weight %, 36.00 weight %.
In the emulsion compositions of the present invention, in terms of fatty acid total amount in the oil phase, C14:0 ratio is 11.5~14.0
Weight %, preferably 12.0~13.8 weight %.In the specific embodiment of the present invention, with fatty acid total amount in the oil phase
Meter, C14:0 ratio is 12.69 weight %, 13.76 weight %.
In the emulsion compositions of the present invention, in terms of fatty acid total amount in the oil phase, C16:0 ratio is 8.0~9.5 weights
Measure %, preferably 8.5~9.3 weight %.In the specific embodiment of the present invention, in terms of fatty acid total amount in the oil phase,
C16:0 ratio is 8.65 weight %, 9.21 weight %.
In the emulsion compositions of the present invention, in terms of fatty acid total amount in the oil phase, C18:0 ratio is 19.0~22.8
Weight %, preferably 20.5~22.5 weight %.In the specific embodiment of the present invention, with fatty acid total amount in the oil phase
Meter, C18:0 ratio is 21.04 weight %, 22.11 weight %.
In the present invention, the medium-chain triglycerides refer to, the part from aliphatic acid is carbon in triglycerides
Atomicity is 6~12(It is preferred that 8~10)Linear chain or branch chain, saturation or unrighted acid.
In the present invention, palm kernel oil carries tristearin(PKST)Typically refer to the solid that palm-kernel oil freezing and crystallizing point puts forward
Part, for palm-kernel oil, fusing point is higher, and iodine value is relatively low, and aliphatic acid saturation degree is higher.
In the present invention, hydrogenated palm kernel oil typically refers to palm-kernel oil(Palm Kernel Oil, PKO)Pass through complete hydrogen
The grease of the obtained high fatty acid saturation degree of chemical industry skill, the iodine value of typical hydrogenated palm kernel oil are generally not more than 4.
In the emulsion compositions of the present invention, also comprising sweetener, emulsifier, thickener, essence, water retention agent or eat
At least one of salt.
The sweetener is selected from least one of corn syrup or white granulated sugar;The emulsifier is selected from Sodium Caseinate, spits
At least one of temperature 60, mono-fatty acid glyceride, diglycerine fatty acid ester or sorbester p18;The thickener is selected from hydroxypropyl first
At least one of base cellulose, xanthans, guar gum or sodium alginate;The essence is food flavor;The water tariff collection
Agent is dipotassium hydrogen phosphate.Hydrophilic emulsifying agent includes Sodium Caseinate in the present invention, and oleophilic emulsifier includes polysorbate60, single glycerin fatty
At least one of acid esters, diglycerine fatty acid ester or sorbester p18.
The emulsion compositions of the present invention can be prepared by the preparation method of following emulsion compositions.
The present invention emulsion compositions preparation method, include prepare water phase step, prepare oil phase step, mix it is made
The step of standby water phase and prepared oil phase, beats step at homogenizing step, cooling step.
Preparation method according to the present invention, wherein, in terms of emulsion compositions total amount, containing 50~65 weight % of water phase,
20~35 weight % of oil phase, 25 DEG C of solid fats content SFC of grease is 20~50 weight % in oil phase.
Preparation method according to the present invention, wherein, in terms of oil phase total amount, 10 DEG C of grease in the oil phase consolidate
Body fat content is 55~75 weight %, preferably 58~73 weight %.
Preparation method according to the present invention, wherein, in terms of oil phase total amount, 20 DEG C of grease in the oil phase consolidate
Body fat content is 40~60 weight %, preferably 42~58 weight %.
In the preparation method of the emulsion compositions of the present invention, in the preparation water phase step, by sweetener, salt, hydrophilic breast
Agent and thickener are added to the water, and stir and heat(Such as 70 DEG C), obtain water phase.
It is described to prepare in oil phase step in the preparation method of the emulsion compositions of the present invention, by medium-chain fatty acid glycerine
Three esters and propose the heating of any one of stearic or hydrogenated palm kernel oil selected from palm kernel oil(Such as 65 DEG C)After stirring, parent is added in
Emulsifier obtains oil phase.
In the preparation method of the emulsion compositions of the present invention, the step of water phase and prepared oil phase prepared by the mixing
Gained oil phase is added in gained water phase in rapid, obtains lotion.According to circumstances require supplementation with the moisture of loss.
In the preparation method of the emulsion compositions of the present invention, sterilisation step is further included.The sterilisation step is, for example, Pasteur
Sterilization(By 80 DEG C of 5~10 min of heating of lotion).
In the preparation method of the emulsion compositions of the present invention, gained lotion is subjected to twice homogenization in the homogenizing step.
Such as 300bar and 500bar twice homogenizations.
In the preparation method of the emulsion compositions of the present invention, the cooling step includes chilling step and freezing step.Institute
State the cold bath for example, by using -10 DEG C in chilling step(LAUDA RE212)It is cooled to 10 DEG C~15 DEG C.The freezing step
In for example place -18 DEG C of temperature below freezen protectives of refrigerator.
In the preparation method of the emulsion compositions of the present invention, further included between the chilling step and the freezing step
Maturation stage.It is cured in 4 DEG C of environment of refrigerator more than 6h for example by lotion in the maturation stage.
In the preparation method of the emulsion compositions of the present invention, defrosting step is further included after the cooling step.It is described
Frozen samples are for example placed 4 DEG C~10 DEG C and thawed more than for 24 hours by defrosting step.
In the preparation method of the emulsion compositions of the present invention, the whipping step is carried out after the defrosting step.Institute
4 DEG C~10 DEG C of sample after whipping step is for example thawed is stated to be beaten (Sridhar Krishnamoorthy AR005 types egg-whisk).
The emulsion compositions of the invention described above, institute can be prepared by the preparation method of the emulsion compositions of the invention described above
State the associated description in the emulsion compositions of associated description reference the invention described above in preparation method.
The present invention also provides the fat or oil compositions for whipped cream, which is characterized in that 25 DEG C of the fat or oil composition
Solid fats content be 20~50 weight %, more preferably preferably 24~48 weight %, 25~40 weight %.The present invention's
In specific embodiment in terms of fat or oil composition total amount, 25 DEG C of solid fats content of the fat or oil composition is 25.15 weights
Measure %, 29.31 weight %, 38.36 weight %, 38.86 weight %.In the fat or oil composition of the present invention, in terms of fat or oil composition total amount,
The fat or oil composition is included carries any one of stearic or hydrogenated palm kernel oil and medium-chain fatty acid selected from palm kernel oil
Triglycerides, wherein, in terms of fat or oil composition total amount, the content of the medium-chain triglycerides is 15~30 weight %,
Preferably 18~25 weight %.In the specific embodiment of the present invention, in terms of fat or oil composition total amount, the middle carbochain fat
The content of acid glycerol three ester is 20 weight %.
It is described to carry stearic or hydrogen selected from palm kernel oil in terms of fat or oil composition total amount in the fat or oil composition of the present invention
The content for changing any one of palm-kernel oil is 70~85 weight %, preferably 75~82 weight %.One in the present invention is specific
In embodiment, in terms of fat or oil composition total amount, it is 80 weight % that the palm kernel oil, which puies forward stearic content,.The present invention's
In another embodiment, in terms of fat or oil composition total amount, the content of the hydrogenated palm kernel oil is 80 weight %.This hair
In bright fat or oil composition, in terms of fat or oil composition total amount, 10 DEG C of solid fats content of the fat or oil composition for 55~
75 weight %, preferably 58~73 weight %.In the specific embodiment of the present invention, in terms of fat or oil composition total amount, the oil
10 DEG C of solid fats content of oil/fat composition is 59.94 weight %, 61.65 weight %, 71.23 weight %, 72.18 weight %.
In the fat or oil composition of the present invention, in terms of fat or oil composition total amount, 20 DEG C of solid fat of the fat or oil composition
Fat content is 40~60 weight %, preferably 42~58 weight %.It is total with fat or oil composition in the specific embodiment of the present invention
Gauge, 20 DEG C of solid fats content of the fat or oil composition is 43.67 weight %, 44.30 weight %, 55.93 weight %,
57.90 weight %.
In a preferred embodiment of the invention, in fat or oil composition of the invention, the fat or oil composition contains middle carbon
Chain fatty acid triglycerides and palm kernel oil carry tristearin.
In the fat or oil composition of the present invention, in terms of fat or oil composition total amount, 30 DEG C of solid fat of the fat or oil composition
Fat content is 0.1~10 weight %, preferably 0.2~8 weight %.In the specific embodiment of the present invention, with fat or oil composition
Total amount meter, 30 DEG C of solid fats content of the fat or oil composition is 0.33 weight %, 6.24 weight %.
In the fat or oil composition of the present invention, in terms of fatty acid total amount in the fat or oil composition, the ratio of unrighted acid
Example is 5.8~7.1 weight %, more preferably preferably 6.0~7.0 weight %, 6.2~6.9 weight %.In the specific reality of the present invention
It applies in mode, in terms of fatty acid total amount in the fat or oil composition, the ratio of unrighted acid is 6.32 weight %, 6.81 weights
Measure %.
The unrighted acid(USFA)Selected from C18:1、C18:2 or C18:At least one of 3n6.
In the fat or oil composition of the present invention, in terms of fatty acid total amount in the fat or oil composition, C18:1 ratio is 5.0
~6.1 weight %, preferably 5.3~5.9 weight %.In the specific embodiment of the present invention, with fat in the fat or oil composition
Fat acid total amount meter, C18:1 ratio is 5.44 weight %, 5.86 weight %.
In the fat or oil composition of the present invention, in terms of fatty acid total amount in the fat or oil composition, C18:2 ratio is 0.75
~0.88 weight %, preferably 0.80~0.85 weight %.In the specific embodiment of the present invention, in the fat or oil composition
Fatty acid total amount meter, C18:2 ratio is 0.80 weight %, 0.85 weight %.
In the fat or oil composition of the present invention, in terms of fatty acid total amount in the fat or oil composition, C18:The ratio of 3n6 is
0.09~0.10 weight %.
In the fat or oil composition of the present invention, in terms of fatty acid total amount in the fat or oil composition, the ratio of saturated fatty acid
For 92.9~94.2 weight %, preferably 93.0~94.0 weight %, more preferably 93.1~93.8 weight %.In the tool of the present invention
In body embodiment, in terms of fatty acid total amount in the fat or oil composition, the ratio of saturated fatty acid is 93.19 weight %,
93.78 weight %.
The saturated fatty acid is selected from C6:0、C8:0、C10:0、C12:0、C14:0、C16:0 or C18:At least one in 0
Kind.
In the fat or oil composition of the present invention, in terms of fatty acid total amount in the fat or oil composition, C8:0 ratio for 7.0~
14.0 weight %, preferably 8.0~13.0 weight %..In the specific embodiment of the present invention, with fat in the fat or oil composition
Fat acid total amount meter, C8:0 ratio is 8.61 weight %, 12.01 weight %.
In the fat or oil composition of the present invention, in terms of fatty acid total amount in the fat or oil composition, C10:0 ratio is 7.5
~14.0 weight %, preferably 8.0~13.0 weight %.In the specific embodiment of the present invention, in the fat or oil composition
Fatty acid total amount meter, C10:0 ratio is 8.80 weight %, 12.13 weight %.
In the fat or oil composition of the present invention, in terms of fatty acid total amount in the fat or oil composition, C12:0 ratio is 36.0
~44.5 weight %, preferably 38.0~43.5 weight %.In the specific embodiment of the present invention, in the fat or oil composition
Fatty acid total amount meter, the oil phase aliphatic acid composition in, C12:0 ratio is 39.19 weight %, 43.22 weight %.
In the fat or oil composition of the present invention, in terms of fatty acid total amount in the fat or oil composition, C14:0 ratio is 17.5
~21.5 weight %, preferably 18.5~20.5 weight %.In the specific embodiment of the present invention, in the fat or oil composition
Fatty acid total amount meter, C14:0 ratio is 18.96 weight %, 20.46 weight %.
In the fat or oil composition of the present invention, in terms of fatty acid total amount in the fat or oil composition, C16:0 ratio is 8.4
~10.0 weight %, preferably 8.8~9.6 weight %.In the specific embodiment of the present invention, with fat in the fat or oil composition
Fat acid total amount meter, C16:0 ratio is 8.92 weight %, 9.46 weight %.
In the fat or oil composition of the present invention, in terms of fatty acid total amount in the fat or oil composition, C18:0 ratio is 2.3
~2.7 weight %, preferably 2.4~2.6 weight %.In the specific embodiment of the present invention, with fat in the fat or oil composition
Fat acid total amount meter, C18:0 ratio is 2.47 weight %, 2.59 weight %.
In a preferred embodiment of the invention, the fat or oil composition contains medium-chain triglycerides and hydrogenation
Palm-kernel oil.
In the fat or oil composition of the present invention, in terms of fat or oil composition total amount, 30 DEG C of solid fat of the fat or oil composition
Fat content is 12~24 weight %, preferably 15~23 weight %.It is total with fat or oil composition in the specific embodiment of the present invention
Gauge, 30 DEG C of solid fats content of the fat or oil composition is 15.68 weight %, 22.32 weight %.
In the fat or oil composition of the present invention, in terms of fat or oil composition total amount, 35 DEG C of solid fat of the fat or oil composition
Fat content is 7.5~11.5 weight %, preferably 8.0~11.0 weight %.In the specific embodiment of the present invention, with grease group
Object total amount meter is closed, 35 DEG C of solid fats content of the fat or oil composition is 8.39 weight %, 10.70 weight %.
In the fat or oil composition of the present invention, in terms of fat or oil composition total amount, 40 DEG C of solid fat of the fat or oil composition
Fat content is 3.5~6.0 weight %, preferably 3.8~5.8 weight %.In the specific embodiment of the present invention, combined with grease
Object total amount meter, 40 DEG C of solid fats content of the fat or oil composition is 4.08 weight %, 5.43 weight %.
In the fat or oil composition of the present invention, in terms of fatty acid total amount in the fat or oil composition, the ratio of unrighted acid
Example is 0.30~0.35 weight %, preferably 0.33~0.35 weight %.
The unrighted acid(USFA)Selected from C18:1、C18:2 or C18:At least one of 3n6.
In the fat or oil composition of the present invention, in terms of fatty acid total amount in the fat or oil composition, C18:1 ratio is 0.08
Weight %.
C18 is not preferably contained in the fat or oil composition of the present invention:2.
In the fat or oil composition of the present invention in terms of fatty acid total amount in the fat or oil composition, C18:The ratio of 3n6 is
0.25~0.27 weight %.
In the fat or oil composition of the present invention, in terms of fatty acid total amount in the fat or oil composition, the ratio of saturated fatty acid
For 99.64~99.7 weight %.
The saturated fatty acid is selected from C6:0、C8:0、C10:0、C12:0、C14:0、C16:0 or C18:At least one in 0
Kind.
In the fat or oil composition of the present invention, in terms of fatty acid total amount in the fat or oil composition, C6:0 ratio is 0.10
~0.12 weight %.
In the fat or oil composition of the present invention, in terms of fatty acid total amount in the fat or oil composition, C8:0 ratio for 8.0~
15.0 weight %, preferably 9.0~13.0 weight %.In the specific embodiment of the present invention, with fat in the fat or oil composition
Fat acid total amount meter, C8:0 ratio is 9.4 weight %, 12.49 weight %.
In the fat or oil composition of the present invention, in terms of fatty acid total amount in the fat or oil composition, C10:0 ratio is 8.0
~14.0 weight %, preferably 8.5~13.0 weight %.In the specific embodiment of the present invention, in the fat or oil composition
Fatty acid total amount meter, C10:0 ratio is 9.04 weight %, 12.17 weight %.
In the fat or oil composition of the present invention, in terms of fatty acid total amount in the fat or oil composition, C12:0 ratio is 31.0
~37.5 weight %, preferably 32.0~36.5 weight %.In the specific embodiment of the present invention, in the fat or oil composition
Fatty acid total amount meter, C12:0 ratio is 32.52 weight %, 36.00 weight %.
In the fat or oil composition of the present invention, in terms of fatty acid total amount in the fat or oil composition, C14:0 ratio is 11.5
~14.0 weight %, preferably 12.0~13.8 weight %.In the specific embodiment of the present invention, in the fat or oil composition
Fatty acid total amount meter, C14:0 ratio is 12.69 weight %, 13.76 weight %.
In the fat or oil composition of the present invention, in terms of fatty acid total amount in the fat or oil composition, C16:0 ratio is 8.0
~9.5 weight %, preferably 8.5~9.3 weight %.In the specific embodiment of the present invention, with fat in the fat or oil composition
Fat acid total amount meter, C16:0 ratio is 8.65 weight %, 9.21 weight %.
In the fat or oil composition of the present invention, in terms of fatty acid total amount in the fat or oil composition, C18:0 ratio is 19.0
~22.8 weight %., preferably 20.5~22.5 weight %.In the specific embodiment of the present invention, with the fat or oil composition
Middle fatty acid total amount meter, C18:0 ratio is 21.04 weight %, 22.11 weight %.
In the fat or oil composition of the present invention, the part from aliphatic acid is carbon original in the medium-chain triglycerides
Subnumber is 6~12(It is preferred that 8~10)Linear chain or branch chain, saturation or unrighted acid.
The present invention also provides cream, the fat or oil compositions of emulsion compositions, the invention described above it includes the invention described above
Or emulsion compositions prepared by the preparation method for the emulsion compositions for passing through the invention described above.
The present invention also provides food, the emulsion compositions it includes the invention described above, the lotion group by the invention described above
Close the emulsion compositions of preparation method preparation, the fat or oil composition of the invention described above or cream of the present invention of object.
One specific embodiment of the preparation method of the emulsion compositions of the present invention is as shown in table 1 below.
Table 1
With reference to specific embodiment, the present invention is further explained.It should be understood that these embodiments are merely to illustrate the present invention
Rather than it limits the scope of the invention.Test method without specific conditions in the following example, usually according to conventional strip
Part or according to the normal condition proposed by manufacturer.Unless otherwise stated, otherwise all percentage, ratio, ratio or number is pressed
Weight meter.
The unit in percent weight in volume in the present invention is well-known to those skilled in the art, such as refer to
The weight of solute in 100 milliliters of solution.
Unless otherwise defined, it anticipates known to all professional and scientific terms used in text and one skilled in the art
Justice is identical.In addition, any method similar or impartial to described content and material all can be applied in the method for the present invention.Wen Zhong
The preferred implement methods and materials are for illustrative purposes only.
Embodiment
Examples 1 to 2 and comparative example 1~7
2 embodiment of table, 1 each Ingredient
Prepare water phase:573g water is weighed in beaker, is heated with stirring to 70 DEG C.By each dispensing for example corn syrup, white granulated sugar,
Sodium Caseinate, hydroxypropyl methyl cellulose, xanthans, guar gum, sodium alginate, dipotassium hydrogen phosphate and edible salt are according to table 1
Percentage is weighed into water.
Prepare oil phase:184g PKST and 46g MCT are weighed in beaker, is heated to 65 DEG C.By each dispensing such as polysorbate60,
Single, diglycerine fatty acid ester and sorbester p18 weigh being added sequentially in oil phase according to the percentage of table 1.Prepared oil phase
Aliphatic acid composition(FAC)(%)Participate in table 3.
Mixing:Oil phase is poured slowly into water phase in whipping process, 1000g is complemented to 65 DEG C of water, obtains emulsion.
Pasteurize:By 65-80 DEG C of 5-15min of heating of lotion.
Homogeneous:Lotion is subjected to 300bar and 500bar twice homogenizations.
Chilling:15 DEG C of < is cooled to using -10 DEG C of cold bath.
Curing:Lotion is cured into 6-8h in 4 DEG C of environment.
Freezing:Sample after curing is placed into -18 DEG C of freezen protectives of refrigerator.
It thaws:Frozen samples are placed 4 DEG C of refrigerator to thaw for 24 hours.
It beats:4-10 DEG C of sample is beaten after defrosting.
Other than the content difference of PKST and MCT, embodiment 2 and comparative example 1~7 carry out similarly to Example 1
It prepares.
Table 3
Note:1. iodine value(IV)Measure with reference to GB/T 5532-2008.
2. the measure of fusing point is with reference to AOCS Cc 3-25-2009.
3. the measure of SFC is with reference to AOCS Cd 16b-93-2009.
4. viscosity measurements use Brookfield DV2T-LV (TC-550AP) viscosity apparatus, rotor:LV 03, rotating speed:100
rpm/min。
5. hardness determination uses TA.XT plus Texture instruments, probe:AB/E 35mm, Pretest Speed:1.50 mm/sec,
Test Speed:2.00 mm/sec, Posttest Speed:2.00 mm/sec, Distance:25.00mm Trigger
Force:20.0g.
6. the measure of overrun plants butter cream with reference to SB/T 10419-2007.
7. freezing phenomenon, defrosting phenomenon and mouthfeel is judged by the sensory evaluation of experimenter.
Table 4
Note:The measure of 1.FAC is with reference to AOCS Ce If-96-2001.
Embodiment 3~4 and comparative example 8~12
5 embodiment of table, 3 each Ingredient
Prepare water phase:573g water is weighed in beaker, is heated with stirring to 70 DEG C.By corn syrup, white granulated sugar, caseinic acid
Sodium, hydroxypropyl methyl cellulose, xanthans, guar gum, sodium alginate, dipotassium hydrogen phosphate and edible salt are added to the water.
Prepare oil phase:184g HPKO and 46g MCT are weighed in beaker, is heated to 65 DEG C.By polysorbate60, list, diglycerol
Aliphatic ester and sorbester p18 are added sequentially in oil phase.The aliphatic acid composition of prepared oil phase(FAC)(%)Participate in table 6.
Mixing:Oil phase is poured slowly into water phase in whipping process, 1000g is complemented to 65 DEG C of water, obtains emulsion.
Pasteurize:By 65-80 DEG C of heating 5-15 min of lotion.
Homogeneous:Lotion is subjected to 300bar and 500bar twice homogenizations.
Chilling:10 DEG C are cooled to using -10 DEG C of cold bath.
Curing:Lotion is cured into 6-8h in 4 DEG C of environment.
Freezing:Sample after curing is placed into -18 DEG C of freezen protectives of refrigerator.
It thaws:Frozen samples are placed 4 DEG C of refrigerator to thaw for 24 hours.
It beats:10 DEG C of sample is beaten after defrosting.
Other than the content difference of PKST and MCT, embodiment 4 and comparative example 8~12 carry out similarly to Example 3
It prepares.
Table 6
Note:1. iodine value(IV)Measure with reference to GB/T 5532-2008.
2. the measure of fusing point is with reference to AOCS Cc 3-25-2009.
3. the measure of SFC is with reference to AOCS Cd 16b-93-2009.
4. viscosity measurements use Brookfield DV2T-LV (TC-550AP) viscosity apparatus, rotor:LV 03, rotating speed:100
rpm/min。
5. hardness determination uses TA.XT plus Texture instruments, probe:AB/E 35mm, Pretest Speed:1.50 mm/sec,
Test Speed:2.00 mm/sec, Posttest Speed:2.00 mm/sec, Distance:25.00mm Trigger
Force:20.0g.
6. the measure of overrun plants butter cream with reference to SB/T 10419-2007.
7. freezing phenomenon, defrosting phenomenon and mouthfeel is judged by the sensory evaluation of experimenter.
Table 7
Note:The measure of 1.FAC is with reference to AOCS Ce If-96-2001.
The foregoing is merely illustrative of the preferred embodiments of the present invention, is not limited to the substantial technological content model of the present invention
It encloses, substantial technological content of the invention is broadly to be defined in the right of application, any technology that other people complete
Entity or method, if with the right of application defined in it is identical, also or a kind of equivalent change, will
It is considered as being covered by among the right.
Claims (10)
1. a kind of emulsion compositions, which is characterized in that in terms of emulsion compositions total amount, contain 50~65 weight % of water phase, oil phase 20
~35 weight %, 25 DEG C of solid fats content SFC of grease is 20~50 weight % in oil phase.
2. emulsion compositions according to claim 1, wherein, the oil phase contains carries stearic or hydrogen selected from palm kernel oil
Change any one of palm-kernel oil and medium-chain triglycerides.
3. emulsion compositions according to claim 1 or 2, wherein, in terms of emulsion compositions total amount, the content of the water phase
For 55~60 weight % and/or, in terms of emulsion compositions total amount, the content of the oil phase for 20~30 weight % and/or, with oil
Phase total amount meter, 25 DEG C of solid fats content of the grease in the oil phase are 24~48 weight %, preferably 25~40 weight %,
And/or in terms of oil phase total amount, 10 DEG C of solid fats content of the grease in the oil phase is 55~75 weight %, preferably 58
~73 weight % and/or, in terms of oil phase total amount, 20 DEG C of solid fats content of the grease in the oil phase is 40~60 weights
Measure %, preferably 42~58 weight %;And/or in terms of oil phase total amount, the contents of the medium-chain triglycerides for 15~
30 weight %, preferably 18~25 weight %;It is described to carry stearic or hydrogenation palm fibre selected from palm kernel oil and/or in terms of oil phase total amount
The content of any one of palmitic acid benevolence oil is 70~85 weight %, preferably 75~82 weight %.
4. the emulsion compositions according to any one in claims 1 to 3, wherein, also comprising sweetener, emulsifier, increasing
Thick dose, essence, at least one of water retention agent or edible salt and/or, the sweetener is selected from corn syrup or white granulated sugar
At least one of;The emulsifier is selected from Sodium Caseinate, polysorbate60, mono-fatty acid glyceride, diglycerine fatty acid ester or department
At least one of disk 60;The thickener in hydroxypropyl methyl cellulose, xanthans, guar gum or sodium alginate extremely
Few one kind;The essence is food flavor;The water retention agent for dipotassium hydrogen phosphate and/or, with emulsion compositions total amount
Meter, the content that any one of stearic or hydrogenated palm kernel oil is carried selected from palm kernel oil is 14~30 weight %, preferably
15~25 weight %, more preferably 17~20 weight % and/or, in terms of emulsion compositions total amount, the medium-chain fatty acid glycerine
The content of three esters is 3~11 weight %, more preferably preferably 3.5~10 weight %, 4~8 weight %.
5. a kind of fat or oil composition for whipped cream, which is characterized in that in terms of fat or oil composition total amount, the grease combination
25 DEG C of solid fats content of object be 20~50 weight %, preferably 24~48 weight %, more preferably 25~40 weight % and/
Or, in terms of fat or oil composition total amount, 10 DEG C of solid fats content of the fat or oil composition is 55~75 weight %, preferably
58~73 weight % and/or, in terms of fat or oil composition total amount, 20 DEG C of solid fats content of the fat or oil composition for 40~
60 weight %, preferably 42~58 weight %.
6. fat or oil composition according to claim 5, wherein, the fat or oil composition is included and is carried firmly selected from palm kernel oil
Any one of fat or hydrogenated palm kernel oil and medium-chain triglycerides, wherein, it is described in terms of fat or oil composition total amount
The content of medium-chain triglycerides be 15~30 weight %, preferably 18~25 weight % and/or, with fat or oil composition
Total amount meter, it is described to put forward the content of any one of stearic or hydrogenated palm kernel oil as 70~85 weight % selected from palm kernel oil, it is excellent
It is selected as 75~82 weight %.
7. a kind of preparation method of emulsion compositions, including preparing water phase step, preparing the prepared water of oil phase step, mixing
The step of phase and prepared oil phase, beats step at homogenizing step, cooling step;Preferably, in terms of emulsion compositions total amount,
Containing 50~65 weight % of water phase, 20~35 weight % of oil phase, 25 DEG C of solid fats content SFC of grease is 20~50 in oil phase
Weight %;Preferably, in terms of oil phase total amount, 10 DEG C of solid fats content of the grease in the oil phase is 55~75 weight %,
Preferably 58~73 weight % and/or, in terms of oil phase total amount, 20 DEG C of solid fats content of the grease in the oil phase is 40
~60 weight %, preferably 42~58 weight %.
8. preparation method according to claim 7, wherein, in the preparation water phase step, by sweetener, salt, hydrophilic breast
Agent and thickener are added to the water, and stir and heat, obtain water phase;And/or it is described prepare in oil phase step, by middle carbochain fat
Fat acid glycerol three ester and after palm kernel oil puies forward any one of stearic or hydrogenated palm kernel oil heating stirring, adds in oleophylic
Emulsifier obtains oil phase;And/or gained oil phase is added in the step of water phase prepared by the mixing and prepared oil phase
Into gained water phase, lotion is obtained.
9. a kind of cream it includes the emulsion compositions described in any one in Claims 1 to 4 or includes claim 5
Fat or oil composition in~6 described in any one or comprising made from the preparation method described in any one in claim 7 ~ 8
Emulsion compositions.
10. a kind of food, it includes described in any one in Claims 1 to 4 emulsion compositions, appoint in claim 5~6
Fat or oil composition described in meaning one or the cream described in claim 9.
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CN102395285A (en) * | 2009-02-17 | 2012-03-28 | 不二制油株式会社 | Oil-in-water emulsions with low oil content |
CN103181417A (en) * | 2011-12-28 | 2013-07-03 | 丰益(上海)生物技术研发中心有限公司 | Grease composition, composite grease composition, product and preparation method thereof |
CN103907695A (en) * | 2014-04-15 | 2014-07-09 | 江南大学 | Method for preparing pre-whipped non-dairy cream without trans-fatty acids |
TW201540189A (en) * | 2014-03-28 | 2015-11-01 | Kaneka Corp | Whipped compound cream |
CN106912625A (en) * | 2015-12-28 | 2017-07-04 | 丰益(上海)生物技术研发中心有限公司 | A kind of water-in-oil type fat or oil composition and preparation method thereof |
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2016
- 2016-12-29 CN CN201611243635.XA patent/CN108244263B/en active Active
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
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CN102395285A (en) * | 2009-02-17 | 2012-03-28 | 不二制油株式会社 | Oil-in-water emulsions with low oil content |
CN103181417A (en) * | 2011-12-28 | 2013-07-03 | 丰益(上海)生物技术研发中心有限公司 | Grease composition, composite grease composition, product and preparation method thereof |
TW201540189A (en) * | 2014-03-28 | 2015-11-01 | Kaneka Corp | Whipped compound cream |
CN103907695A (en) * | 2014-04-15 | 2014-07-09 | 江南大学 | Method for preparing pre-whipped non-dairy cream without trans-fatty acids |
CN106912625A (en) * | 2015-12-28 | 2017-07-04 | 丰益(上海)生物技术研发中心有限公司 | A kind of water-in-oil type fat or oil composition and preparation method thereof |
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