CN108238608A - A kind of artificial modification's sodium-ionized bentonite - Google Patents

A kind of artificial modification's sodium-ionized bentonite Download PDF

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Publication number
CN108238608A
CN108238608A CN201810216397.6A CN201810216397A CN108238608A CN 108238608 A CN108238608 A CN 108238608A CN 201810216397 A CN201810216397 A CN 201810216397A CN 108238608 A CN108238608 A CN 108238608A
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CN
China
Prior art keywords
sodium
parts
artificial modification
ionized
ionized bentonite
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CN201810216397.6A
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Chinese (zh)
Inventor
陈丽莎
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Huzhou Informed Technology Service Co Ltd
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Huzhou Informed Technology Service Co Ltd
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Priority to CN201810216397.6A priority Critical patent/CN108238608A/en
Publication of CN108238608A publication Critical patent/CN108238608A/en
Withdrawn legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B33/00Silicon; Compounds thereof
    • C01B33/20Silicates
    • C01B33/36Silicates having base-exchange properties but not having molecular sieve properties
    • C01B33/38Layered base-exchange silicates, e.g. clays, micas or alkali metal silicates of kenyaite or magadiite type
    • C01B33/40Clays

Abstract

The invention discloses a kind of artificial modification's sodium-ionized bentonites, which is characterized in that the raw material including following parts by weight is prepared:75 80 parts of bentonite, 38 parts of sodium salt, 0.5 2 parts of tackifier, 0.5 2.5 parts of synergist, 0.5 3 parts of lubricant, 8 20 parts of organic modifiers.The present invention provides a kind of artificial modification's sodium-ionized bentonite, can improve bentonite and improve bentonitic physical and chemical performance.

Description

A kind of artificial modification's sodium-ionized bentonite
Technical field
The present invention relates to a kind of bentonite more particularly to a kind of artificial modification's sodium-ionized bentonites.
Background technology
With the development of science and technology also higher and higher to bentonitic requirement, China's calcium-base bentonite is resourceful, reserves Greatly, but its poor-performing, quality are unstable, and the physical and chemical performance of sodium bentonite is superior to calcium-base bentonite, but reserves are small, valency Lattice are high, it is therefore desirable to carry out artificial natridization to calcium bentonite, be allowed to be modified as the bentonite of the physical and chemical performance with sodium soil.
Invention content
The object of the present invention is to provide a kind of artificial modification's sodium-ionized bentonites, can improve bentonite and improve swelling The physical and chemical performance of soil.
Technical scheme of the present invention:A kind of artificial modification's sodium-ionized bentonite, which is characterized in that including following parts by weight Raw material be prepared:75-80 parts of bentonite, 3-8 parts of sodium salt, 0.5-2 parts of tackifier, 0.5-2.5 parts of synergist, lubricant 0.5-3 parts, 8-20 parts of organic modifiers.
Aforementioned a kind of artificial modification's sodium-ionized bentonite, which is characterized in that prepared by the raw material including following parts by weight It forms:80 parts of bentonite, 5 parts of sodium salt, 1 part of tackifier, 2 parts of synergist, 2 parts of lubricant, 10 parts of organic modifiers.
Aforementioned a kind of artificial modification's sodium-ionized bentonite, which is characterized in that the sodium salt is sodium carbonate, and sodium metasilicate is fluorinated Sodium, sodium oxalate, sodium acetate, Sodium Polyacrylate, sodium hydroxide, one or more mixtures in sodium cellulosate.
Aforementioned a kind of artificial modification's sodium-ionized bentonite, which is characterized in that the tackifier are magnesia, in magnesium hydroxide One kind.
Aforementioned a kind of artificial modification's sodium-ionized bentonite, which is characterized in that the organic modifiers are with non-ionic surface The surfactant of activating agent, quaternary ammonium alkyl cationic surfactants compounding.
Aforementioned a kind of artificial modification's sodium-ionized bentonite, which is characterized in that the nonionic surfactant is at least fat Fat acid sorbitan ester, alkylol ethylene oxide condensate, alkyl phenol ethylene oxide condensate one kind.
A kind of aforementioned artificial modification's sodium-ionized bentonite, which is characterized in that the alkyl quaternary ammonium salts cation surface activating Agent is at least the alkyl quaternary ammonium salts of the alkyl quaternary ammonium salts of C8-C22, myristyl benzyl dimethyl ammonium salt, double alkyl C8-C18 It is a kind of.
Beneficial effects of the present invention:Sodium modification agent is used as by the combination of a variety of sodium salts, sodium is carried out to bentonite, can had Bentonite is changed to sodium soil by effect, so as to improve with improve bentonitic physical and chemical performance, so as to improve the practicability of product and production Product are worth;By increasing organic synergist, bentonitic expansion character is improved;By increasing inorganic tackifier, improve Bentonitic caking property.
Specific embodiment
The present invention is further illustrated for example below, but is not intended as the foundation limited the present invention.
Embodiment 1:A kind of artificial modification's sodium-ionized bentonite, the raw material including following parts by weight are prepared:Swelling It is 75-80 parts native, 3-8 parts of sodium salt, 0.5-2 parts of tackifier, 0.5-2.5 parts of synergist, 0.5-3 parts of lubricant, organic modifiers 8- 20 parts.
The sodium salt is sodium carbonate, sodium metasilicate, sodium fluoride, sodium oxalate, sodium acetate, Sodium Polyacrylate, sodium hydroxide, fiber One or more mixtures in plain sodium.
The tackifier are magnesia, one kind in magnesium hydroxide.
The organic modifiers are with the table of nonionic surfactant, quaternary ammonium alkyl cationic surfactants compounding Face activating agent.
The nonionic surfactant is at least fatty acid loss water sorbit ester, alkylol ethylene oxide condensate, alkane One kind of base phenolethylene oxide condensation product.
The quaternary ammonium alkyl cationic surfactants are at least the alkyl quaternary ammonium salts of C8-C22, dodecyldimethylamine base Benzyl ammonium salt, double alkyl C8-C18 alkyl quaternary ammonium salts one kind.
Embodiment 2:A kind of artificial modification's sodium-ionized bentonite, the raw material including following parts by weight are prepared:Swelling 80 parts of soil, 5 parts of sodium salt, 1 part of tackifier, 2 parts of synergist, 2 parts of lubricant, 10 parts of organic modifiers.
The sodium salt is sodium carbonate, sodium metasilicate, sodium fluoride, sodium oxalate, sodium acetate, Sodium Polyacrylate, sodium hydroxide, fiber One or more mixtures in plain sodium.
The tackifier are magnesia, one kind in magnesium hydroxide.
The organic modifiers are with the table of nonionic surfactant, quaternary ammonium alkyl cationic surfactants compounding Face activating agent.
The nonionic surfactant is at least fatty acid loss water sorbit ester, alkylol ethylene oxide condensate, alkane One kind of base phenolethylene oxide condensation product.
The quaternary ammonium alkyl cationic surfactants are at least the alkyl quaternary ammonium salts of C8-C22, dodecyldimethylamine base Benzyl ammonium salt, double alkyl C8-C18 alkyl quaternary ammonium salts one kind.

Claims (7)

1. a kind of artificial modification's sodium-ionized bentonite, which is characterized in that the raw material including following parts by weight is prepared:Swelling It is 75-80 parts native, 3-8 parts of sodium salt, 0.5-2 parts of tackifier, 0.5-2.5 parts of synergist, 0.5-3 parts of lubricant, organic modifiers 8- 20 parts.
2. a kind of artificial modification's sodium-ionized bentonite according to claim 1, which is characterized in that including following parts by weight Raw material be prepared:80 parts of bentonite, 5 parts of sodium salt, 1 part of tackifier, 2 parts of synergist, 2 parts of lubricant, organic modifiers 10 Part.
3. a kind of artificial modification's sodium-ionized bentonite according to claim 1 or 2, which is characterized in that the sodium salt is carbonic acid Sodium, sodium metasilicate, sodium fluoride, sodium oxalate, sodium acetate, Sodium Polyacrylate, sodium hydroxide, one or more mixing in sodium cellulosate Object.
4. a kind of artificial modification's sodium-ionized bentonite according to claim 1 or 2, which is characterized in that the tackifier are oxygen Change magnesium, one kind in magnesium hydroxide.
A kind of 5. artificial modification's sodium-ionized bentonite according to claim 1 or 2, which is characterized in that the organic modifiers It is with the surfactant of nonionic surfactant, quaternary ammonium alkyl cationic surfactants compounding.
A kind of 6. artificial modification's sodium-ionized bentonite according to claim 5, which is characterized in that the non-ionic surface active Agent is at least one kind of fatty acid loss water sorbit ester, alkylol ethylene oxide condensate, alkyl phenol ethylene oxide condensate.
7. a kind of artificial modification's sodium-ionized bentonite according to claim 5, which is characterized in that the alkyl quaternary ammonium salts sun from Sub- surfactant is at least the alkane of the alkyl quaternary ammonium salts of C8-C22, myristyl benzyl dimethyl ammonium salt, double alkyl C8-C18 One kind of based quaternary ammonium salt.
CN201810216397.6A 2018-03-16 2018-03-16 A kind of artificial modification's sodium-ionized bentonite Withdrawn CN108238608A (en)

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CN201810216397.6A CN108238608A (en) 2018-03-16 2018-03-16 A kind of artificial modification's sodium-ionized bentonite

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110885594A (en) * 2019-11-29 2020-03-17 芜湖恒杰膨润土科技有限公司 Coating bentonite for building
CN114516769A (en) * 2022-02-21 2022-05-20 烟台浩景农业科技有限公司 Organic and inorganic fertilizer and preparation method thereof

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103896294A (en) * 2014-03-26 2014-07-02 芜湖恒杰膨润土科技有限公司 Artificial sodium bentonite
CN105936510A (en) * 2014-10-14 2016-09-14 王家君 Modification method of organic bentonite

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103896294A (en) * 2014-03-26 2014-07-02 芜湖恒杰膨润土科技有限公司 Artificial sodium bentonite
CN105936510A (en) * 2014-10-14 2016-09-14 王家君 Modification method of organic bentonite

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110885594A (en) * 2019-11-29 2020-03-17 芜湖恒杰膨润土科技有限公司 Coating bentonite for building
CN114516769A (en) * 2022-02-21 2022-05-20 烟台浩景农业科技有限公司 Organic and inorganic fertilizer and preparation method thereof

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Application publication date: 20180703