CN108219842A - Amide waxe is modified micronizing Fischer-Tropsch wax and its preparation method and application - Google Patents
Amide waxe is modified micronizing Fischer-Tropsch wax and its preparation method and application Download PDFInfo
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- CN108219842A CN108219842A CN201810091757.4A CN201810091757A CN108219842A CN 108219842 A CN108219842 A CN 108219842A CN 201810091757 A CN201810091757 A CN 201810091757A CN 108219842 A CN108219842 A CN 108219842A
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- China
- Prior art keywords
- fischer
- tropsch wax
- amide waxe
- modified
- micronizing
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G73/00—Recovery or refining of mineral waxes, e.g. montan wax
- C10G73/38—Chemical modification of petroleum
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
- Lubricants (AREA)
- Paints Or Removers (AREA)
Abstract
The invention belongs to coating, technical field of ink, and in particular to a kind of amide waxe is modified micronizing Fischer-Tropsch wax and its preparation method and application.This method includes the following steps：1) Fischer-Tropsch wax is crushed to 250~350 mesh；Amide waxe is crushed to 150~250 mesh；2) by Fischer-Tropsch wax and amide waxe 1:1~3:1 uniformly mixing；3) Fischer-Tropsch wax mixed and amide waxe are sent in cryogenic freezing pulverizer and crushed, obtained amide waxe and be modified micronizing Fischer-Tropsch wax.The technical solution that this method is provided is simple and reliable, at low cost, convenient for industrial production.Micronizing Fischer-Tropsch wax favorable dispersibility in ink or paint is modified by the amide waxe that the present invention obtains, the feel of lacquer painting can be increased.
Description
Technical field
The invention belongs to coating, technical field of ink, and in particular to a kind of amide waxe is modified micronizing Fischer-Tropsch wax and its system
Preparation Method and application.
Background technology
Fischer-Tropsch wax is methylene based polyalcohol, is hydrocarbon-based synthesis gas or the alkane of natural gas synthesis.Fischer-Tropsch wax can be applied
Into plastic processing, such as injection squeezes out and is granulated industry.Fischer-Tropsch wax is in Masterbatch and modified plastics production process, mixed
Contribute to the dispersion of filler and outstanding slipping during material.The external lubricant of PVC is may be used as, low-viscosity can improve the production of product
Speed contributes to the dispersion of color stuffing especially to have in the extrusion of high viscosity systems in batch mixing and preferably appoints, compares common PE
Wax additive amount lacks 40-50%, and can significantly improve product surface gloss.When using heavy colour, the Fischer-Tropsch wax of fusing can have
Effect ground wetting dyestuff, reduces and squeezes out viscosity.When in ink, the wear-resisting of application material can be improved with particle sprills use
Property, wrinkle resistance.It applies in coating, corrugation effect can be played, striped and water wave corrugation can be formed in micronised state use
Effect.Powder coating resin is being added in, is playing Fischer-Tropsch cunning in extrusion, screw torque can be reduced, energy consumption is being reduced and improves
Production efficiency.Fischer-Tropsch wax is preferable synthetic wax used in EVA based melt adhesives.If it cannot effectively improve the product of Fischer-Tropsch wax
Matter certainly will influence whether the application in industries such as printing ink paint, plastic processing, adhesives.
Invention content
To solve the deficiencies in the prior art, the present invention provides a kind of amide waxes to be modified micronizing Fischer-Tropsch wax and its preparation side
Method and application.Amide waxe provided by the present invention is modified micronizing Fischer-Tropsch wax has dispersibility well in paint, ink.
A kind of amide waxe is modified the preparation method of micronizing Fischer-Tropsch wax, includes the following steps：
1) Fischer-Tropsch wax is crushed to 250~350 mesh；Amide waxe is crushed to 150~250 mesh；
2) by Fischer-Tropsch wax and amide waxe by weight 1:1~3:1 uniformly mixing；
3) Fischer-Tropsch wax mixed and amide waxe are sent in cryogenic freezing pulverizer and crushed, it is micro- to obtain amide waxe modification
Dusting Fischer-Tropsch wax.
Pass through above-mentioned technical proposal can be prepared the amide waxe in paint, ink with dispersibility well and be modified
It is micronized Fischer-Tropsch wax.
Preferably, in step 1), Fischer-Tropsch wax is crushed to 280~320 mesh.
Preferably, in step 1), amide waxe is crushed to 180~220 mesh.
It it is -100 DEG C~-50 DEG C by the operating temperature of cryogenic freezing pulverizer specifically, in step 3).
Specifically, in step 3), the Fischer-Tropsch wax mixed and amide waxe are sent in cryogenic freezing pulverizer and are crushed to
1000~2000 mesh obtain amide waxe and are modified micronizing Fischer-Tropsch wax.
The present invention also provides the amides that the preparation method that micronizing Fischer-Tropsch wax is modified according to above-mentioned amide waxe is prepared
Wax is modified micronizing Fischer-Tropsch wax.
Amide waxe provided by the present invention is modified micronizing Fischer-Tropsch wax has dispersibility well in paint, ink.
Specifically, particle size is 1000~2000 mesh.
The present invention also provides the application that above-mentioned amide waxe is modified micronizing Fischer-Tropsch wax, applied in ink or paint.
It can be that auxiliary agent is added in paint or ink that amide waxe provided by the present invention, which is modified micronizing Fischer-Tropsch wax, increase paint
The feel in face.
Generally, the technical solution that this method is provided is simple and reliable, at low cost, convenient for industrial production.Obtained amide
Wax is modified micronizing Fischer-Tropsch wax favorable dispersibility in ink or paint, can increase the feel of lacquer painting.
Specific embodiment
The principles and features of the present invention are described below, and illustrated embodiment is served only for explaining the present invention, is not intended to
Limit the scope of the present invention.
Embodiment 1
Amide waxe is modified the preparation method of micronizing Fischer-Tropsch wax, includes the following steps：
1) Fischer-Tropsch wax is crushed to 300 mesh；Amide waxe is crushed to 200 mesh；
2) by Fischer-Tropsch wax and amide waxe by weight 2:1 uniformly mixing；
3) Fischer-Tropsch wax mixed and amide waxe are sent in cryogenic freezing pulverizer and are crushed to 2000 mesh, cryogenic freezing
The operating temperature of pulverizer is -75 DEG C, obtains amide waxe and is modified micronizing Fischer-Tropsch wax.
Weight ratio is according to 5:Amide waxe is modified micronizing Fischer-Tropsch wax by 100 to be added in ink, is stirred 8 minutes, blender
1000 revs/min of rotating speed, amide waxe are modified micronizing Fischer-Tropsch wax and are uniformly dispersed, aggregate-free.
Embodiment 2
Amide waxe is modified the preparation method of micronizing Fischer-Tropsch wax, includes the following steps：
1) Fischer-Tropsch wax is crushed to 350 mesh；Amide waxe is crushed to 150 mesh；
2) by Fischer-Tropsch wax and amide waxe by weight 3:1 uniformly mixing；
3) Fischer-Tropsch wax mixed and amide waxe are sent in cryogenic freezing pulverizer and are crushed to 2000 mesh, cryogenic freezing
The operating temperature of pulverizer is -100 DEG C, obtains amide waxe and is modified micronizing Fischer-Tropsch wax.
Weight ratio is according to 5:Amide waxe is modified micronizing Fischer-Tropsch wax by 100 to be added in ink, is stirred 10 minutes, blender
1000 revs/min of rotating speed, amide waxe are modified micronizing Fischer-Tropsch wax and are uniformly dispersed, aggregate-free.
Embodiment 3
Amide waxe is modified the preparation method of micronizing Fischer-Tropsch wax, includes the following steps：
1) Fischer-Tropsch wax is crushed to 250 mesh；Amide waxe is crushed to 250 mesh；
2) by Fischer-Tropsch wax and amide waxe by weight 1:1 uniformly mixing；
3) Fischer-Tropsch wax mixed and amide waxe are sent in cryogenic freezing pulverizer and are crushed to 1000 mesh, cryogenic freezing
The operating temperature of pulverizer is -50 DEG C, obtains amide waxe and is modified micronizing Fischer-Tropsch wax.
Weight ratio is according to 5:Amide waxe is modified micronizing Fischer-Tropsch wax by 100 to be added in paint, is stirred 10 minutes, blender
1000 revs/min of rotating speed, amide waxe are modified micronizing Fischer-Tropsch wax and are uniformly dispersed, aggregate-free.
Comparative example 1
Amide waxe is modified the preparation method of micronizing Fischer-Tropsch wax, includes the following steps：
1) Fischer-Tropsch wax is crushed to 300 mesh；
2) Fischer-Tropsch wax mixed and amide waxe are sent in cryogenic freezing pulverizer and are crushed to 2000 mesh, cryogenic freezing
The operating temperature of pulverizer is -75 DEG C, obtains amide waxe and is modified micronizing Fischer-Tropsch wax.
Weight ratio is according to 5:Amide waxe is modified micronizing Fischer-Tropsch wax by 100 to be added in ink, is stirred 15 minutes, blender
1500 revs/min of rotating speed, amide waxe modification micronizing Fischer-Tropsch wax dispersion times is uneven, there is apparent aggregation.
Comparative example 2
Amide waxe is modified the preparation method of micronizing Fischer-Tropsch wax, includes the following steps：
1) Fischer-Tropsch wax is crushed to 300 mesh；Amide waxe is crushed to 200 mesh；
2) by Fischer-Tropsch wax and amide waxe by weight 4:1 uniformly mixing；
3) Fischer-Tropsch wax mixed and amide waxe are sent in cryogenic freezing pulverizer and are crushed to 2000 mesh, cryogenic freezing
The operating temperature of pulverizer is -75 DEG C, obtains amide waxe and is modified micronizing Fischer-Tropsch wax.
Weight ratio is according to 5:Amide waxe is modified micronizing Fischer-Tropsch wax by 100 to be added in paint, is stirred 10 minutes, blender
1000 revs/min of rotating speed, amide waxe are modified the dispersion of micronizing Fischer-Tropsch wax not exclusively, there is a small amount of aggregation residual.
By the way that embodiment and comparative example is carried out comparison as can be seen that being modified by adding amide waxe to Fischer-Tropsch wax,
Amide waxe can be significantly improved and be modified dispersibility of the micronizing Fischer-Tropsch wax in paint and ink.Modified micronizing Fischer-Tropsch wax exists
Under the shorter time and slower rotating speed, you can be uniformly dispersed, so as to improve production efficiency.
The foregoing is merely presently preferred embodiments of the present invention, is not intended to limit the invention, it is all the present invention spirit and
Within principle, any modification, equivalent replacement, improvement and so on should all be included in the protection scope of the present invention.
Claims (8)
1. a kind of amide waxe is modified the preparation method of micronizing Fischer-Tropsch wax, which is characterized in that includes the following steps：
1) Fischer-Tropsch wax is crushed to 250~350 mesh；Amide waxe is crushed to 150~250 mesh；
2) by Fischer-Tropsch wax and amide waxe by weight 1:1~3:1 uniformly mixing；
3) Fischer-Tropsch wax mixed and amide waxe are sent in cryogenic freezing pulverizer and crushed, obtained amide waxe and be modified micronizing
Fischer-Tropsch wax.
2. amide waxe according to claim 1 is modified the preparation method of micronizing Fischer-Tropsch wax, which is characterized in that step 1)
In, Fischer-Tropsch wax is crushed to 280~320 mesh.
3. amide waxe according to claim 1 is modified the preparation method of micronizing Fischer-Tropsch wax, which is characterized in that step 1)
In, amide waxe is crushed to 180~220 mesh.
4. amide waxe according to claim 1 is modified the preparation method of micronizing Fischer-Tropsch wax, it is characterised in that：Step 3)
In, the operating temperature of cryogenic freezing pulverizer is -100 DEG C~-50 DEG C.
5. amide waxe according to any one of claims 1 to 4 is modified the preparation method of micronizing Fischer-Tropsch wax, it is characterised in that：
In step 3), the Fischer-Tropsch wax mixed and amide waxe are sent in cryogenic freezing pulverizer and are crushed to 1000~2000 mesh, obtained
Micronizing Fischer-Tropsch wax is modified to amide waxe.
6. the preparation method that a kind of amide waxe according to any one of claims 1 to 5 is modified micronizing Fischer-Tropsch wax is prepared
Amide waxe be modified micronizing Fischer-Tropsch wax.
7. amide waxe according to claim 6 is modified micronizing Fischer-Tropsch wax, it is characterised in that：Its grain size is 1000~2000
Mesh.
8. the amide waxe described in a kind of according to claim 6 or 7 is modified the application of micronizing Fischer-Tropsch wax, it is characterised in that：As
Modifying agent is applied in ink or paint.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810091757.4A CN108219842A (en) | 2018-01-30 | 2018-01-30 | Amide waxe is modified micronizing Fischer-Tropsch wax and its preparation method and application |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810091757.4A CN108219842A (en) | 2018-01-30 | 2018-01-30 | Amide waxe is modified micronizing Fischer-Tropsch wax and its preparation method and application |
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| CN108219842A true CN108219842A (en) | 2018-06-29 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201810091757.4A Pending CN108219842A (en) | 2018-01-30 | 2018-01-30 | Amide waxe is modified micronizing Fischer-Tropsch wax and its preparation method and application |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111205889A (en) * | 2018-11-21 | 2020-05-29 | 内蒙古伊泰煤基新材料研究院有限公司 | Wax for high-temperature printing ink and preparation method thereof |
| CN116376597A (en) * | 2023-03-29 | 2023-07-04 | 国家能源集团宁夏煤业有限责任公司 | Amide wax and preparation method thereof |
Citations (5)
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|---|---|---|---|---|
| CN101108984A (en) * | 2006-07-17 | 2008-01-23 | 上海通世科技有限公司 | Method of manufacturing spherical micro mist wax |
| CN101921506A (en) * | 2009-06-10 | 2010-12-22 | 施乐公司 | Have the solid or the phase change ink that improve performance |
| CN102649845A (en) * | 2011-02-28 | 2012-08-29 | 南京天诗实验微粉有限公司 | Preparation method of polymer wax ultrafine powder |
| CN103748182A (en) * | 2011-08-20 | 2014-04-23 | 科莱恩金融(Bvi)有限公司 | Printing ink systems |
| CN105440779A (en) * | 2015-12-30 | 2016-03-30 | 茂名阪田油墨有限公司 | Friction-resistant matt varnish and preparation method thereof |
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2018
- 2018-01-30 CN CN201810091757.4A patent/CN108219842A/en active Pending
Patent Citations (5)
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|---|---|---|---|---|
| CN101108984A (en) * | 2006-07-17 | 2008-01-23 | 上海通世科技有限公司 | Method of manufacturing spherical micro mist wax |
| CN101921506A (en) * | 2009-06-10 | 2010-12-22 | 施乐公司 | Have the solid or the phase change ink that improve performance |
| CN102649845A (en) * | 2011-02-28 | 2012-08-29 | 南京天诗实验微粉有限公司 | Preparation method of polymer wax ultrafine powder |
| CN103748182A (en) * | 2011-08-20 | 2014-04-23 | 科莱恩金融(Bvi)有限公司 | Printing ink systems |
| CN105440779A (en) * | 2015-12-30 | 2016-03-30 | 茂名阪田油墨有限公司 | Friction-resistant matt varnish and preparation method thereof |
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| 常城等: "微粉蜡在油墨中的应用", 《化工纵横》 * |
| 韩仲琦等: "《粉体技术词典》", 31 March 1999, 武汉工业大学出版社 * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111205889A (en) * | 2018-11-21 | 2020-05-29 | 内蒙古伊泰煤基新材料研究院有限公司 | Wax for high-temperature printing ink and preparation method thereof |
| CN116376597A (en) * | 2023-03-29 | 2023-07-04 | 国家能源集团宁夏煤业有限责任公司 | Amide wax and preparation method thereof |
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Application publication date: 20180629 |
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