CN108219618B - A kind of preparation method of high resist sagging type acrylic coating - Google Patents
A kind of preparation method of high resist sagging type acrylic coating Download PDFInfo
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- CN108219618B CN108219618B CN201810102720.7A CN201810102720A CN108219618B CN 108219618 B CN108219618 B CN 108219618B CN 201810102720 A CN201810102720 A CN 201810102720A CN 108219618 B CN108219618 B CN 108219618B
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- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 title claims abstract description 83
- 238000000576 coating method Methods 0.000 title claims abstract description 70
- 239000011248 coating agent Substances 0.000 title claims abstract description 68
- 238000007665 sagging Methods 0.000 title claims abstract description 54
- 238000002360 preparation method Methods 0.000 title claims abstract description 30
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 36
- 239000000839 emulsion Substances 0.000 claims abstract description 30
- 239000000463 material Substances 0.000 claims abstract description 28
- 239000003795 chemical substances by application Substances 0.000 claims description 56
- 238000003756 stirring Methods 0.000 claims description 45
- 239000000203 mixture Substances 0.000 claims description 35
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 34
- 239000003999 initiator Substances 0.000 claims description 29
- 239000000178 monomer Substances 0.000 claims description 29
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 claims description 27
- 239000000843 powder Substances 0.000 claims description 25
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 24
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 20
- 238000006243 chemical reaction Methods 0.000 claims description 20
- -1 Lauryl Alcohol ester Chemical class 0.000 claims description 18
- 108010020346 Polyglutamic Acid Proteins 0.000 claims description 15
- 229920002643 polyglutamic acid Polymers 0.000 claims description 15
- 238000010992 reflux Methods 0.000 claims description 15
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 14
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 12
- OMIGHNLMNHATMP-UHFFFAOYSA-N 2-hydroxyethyl prop-2-enoate Chemical compound OCCOC(=O)C=C OMIGHNLMNHATMP-UHFFFAOYSA-N 0.000 claims description 11
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 claims description 11
- 230000035935 pregnancy Effects 0.000 claims description 11
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 claims description 10
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims description 10
- YGCOKJWKWLYHTG-UHFFFAOYSA-N [[4,6-bis[bis(hydroxymethyl)amino]-1,3,5-triazin-2-yl]-(hydroxymethyl)amino]methanol Chemical compound OCN(CO)C1=NC(N(CO)CO)=NC(N(CO)CO)=N1 YGCOKJWKWLYHTG-UHFFFAOYSA-N 0.000 claims description 10
- 229910000019 calcium carbonate Inorganic materials 0.000 claims description 10
- 239000003595 mist Substances 0.000 claims description 10
- 238000002156 mixing Methods 0.000 claims description 10
- OZAIFHULBGXAKX-UHFFFAOYSA-N 2-(2-cyanopropan-2-yldiazenyl)-2-methylpropanenitrile Chemical compound N#CC(C)(C)N=NC(C)(C)C#N OZAIFHULBGXAKX-UHFFFAOYSA-N 0.000 claims description 9
- 230000015572 biosynthetic process Effects 0.000 claims description 9
- 238000009413 insulation Methods 0.000 claims description 9
- 238000012986 modification Methods 0.000 claims description 9
- 230000004048 modification Effects 0.000 claims description 9
- 239000002904 solvent Substances 0.000 claims description 9
- 238000003786 synthesis reaction Methods 0.000 claims description 9
- DGVVWUTYPXICAM-UHFFFAOYSA-N β‐Mercaptoethanol Chemical compound OCCS DGVVWUTYPXICAM-UHFFFAOYSA-N 0.000 claims description 9
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 8
- 230000032050 esterification Effects 0.000 claims description 8
- 238000005886 esterification reaction Methods 0.000 claims description 8
- 150000002148 esters Chemical class 0.000 claims description 8
- 239000006210 lotion Substances 0.000 claims description 8
- 238000011084 recovery Methods 0.000 claims description 8
- 238000007789 sealing Methods 0.000 claims description 8
- 239000007787 solid Substances 0.000 claims description 8
- 230000002269 spontaneous effect Effects 0.000 claims description 8
- 239000004359 castor oil Substances 0.000 claims description 6
- 235000019438 castor oil Nutrition 0.000 claims description 6
- 239000008367 deionised water Substances 0.000 claims description 6
- 229910021641 deionized water Inorganic materials 0.000 claims description 6
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 claims description 6
- 239000006185 dispersion Substances 0.000 claims description 5
- 239000000243 solution Substances 0.000 claims description 5
- 229960000935 dehydrated alcohol Drugs 0.000 claims description 4
- 229960004756 ethanol Drugs 0.000 claims description 4
- 235000019441 ethanol Nutrition 0.000 claims description 4
- 239000002994 raw material Substances 0.000 claims description 4
- 238000004064 recycling Methods 0.000 claims description 4
- 239000012047 saturated solution Substances 0.000 claims description 4
- 230000008859 change Effects 0.000 claims description 3
- 229920000058 polyacrylate Polymers 0.000 claims description 2
- 238000012546 transfer Methods 0.000 claims 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims 1
- 239000002253 acid Substances 0.000 claims 1
- 239000004411 aluminium Substances 0.000 claims 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims 1
- 229910052782 aluminium Inorganic materials 0.000 claims 1
- 229910052791 calcium Inorganic materials 0.000 claims 1
- 239000011575 calcium Substances 0.000 claims 1
- 229910052799 carbon Inorganic materials 0.000 claims 1
- 230000008014 freezing Effects 0.000 claims 1
- 238000007710 freezing Methods 0.000 claims 1
- 150000002576 ketones Chemical class 0.000 claims 1
- 150000004702 methyl esters Chemical class 0.000 claims 1
- 239000002105 nanoparticle Substances 0.000 claims 1
- 239000003973 paint Substances 0.000 abstract description 6
- 239000003085 diluting agent Substances 0.000 abstract description 4
- 238000009825 accumulation Methods 0.000 abstract description 3
- 230000005484 gravity Effects 0.000 abstract description 3
- 238000005507 spraying Methods 0.000 abstract description 3
- 239000003960 organic solvent Substances 0.000 abstract description 2
- 238000006116 polymerization reaction Methods 0.000 description 8
- 238000004090 dissolution Methods 0.000 description 7
- 238000000034 method Methods 0.000 description 7
- 229960001777 castor oil Drugs 0.000 description 4
- 229920005989 resin Polymers 0.000 description 4
- 239000011347 resin Substances 0.000 description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 3
- KTWOOEGAPBSYNW-UHFFFAOYSA-N ferrocene Chemical compound [Fe+2].C=1C=C[CH-]C=1.C=1C=C[CH-]C=1 KTWOOEGAPBSYNW-UHFFFAOYSA-N 0.000 description 3
- 229910021485 fumed silica Inorganic materials 0.000 description 3
- 229920000141 poly(maleic anhydride) Polymers 0.000 description 3
- 230000008569 process Effects 0.000 description 3
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
- 235000004443 Ricinus communis Nutrition 0.000 description 2
- 240000000528 Ricinus communis Species 0.000 description 2
- 239000002390 adhesive tape Substances 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- GYZLOYUZLJXAJU-UHFFFAOYSA-N diglycidyl ether Chemical compound C1OC1COCC1CO1 GYZLOYUZLJXAJU-UHFFFAOYSA-N 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 230000007062 hydrolysis Effects 0.000 description 2
- 238000006460 hydrolysis reaction Methods 0.000 description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- 239000011159 matrix material Substances 0.000 description 2
- 239000002808 molecular sieve Substances 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 238000000518 rheometry Methods 0.000 description 2
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 239000013008 thixotropic agent Substances 0.000 description 2
- 230000009974 thixotropic effect Effects 0.000 description 2
- CTRPRMNBTVRDFH-UHFFFAOYSA-N 2-n-methyl-1,3,5-triazine-2,4,6-triamine Chemical compound CNC1=NC(N)=NC(N)=N1 CTRPRMNBTVRDFH-UHFFFAOYSA-N 0.000 description 1
- 239000004925 Acrylic resin Substances 0.000 description 1
- 229920000178 Acrylic resin Polymers 0.000 description 1
- 150000008065 acid anhydrides Chemical class 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- DIZPMCHEQGEION-UHFFFAOYSA-H aluminium sulfate (anhydrous) Chemical compound [Al+3].[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O DIZPMCHEQGEION-UHFFFAOYSA-H 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 239000005028 tinplate Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
- C09D133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
- C09D133/062—Copolymers with monomers not covered by C09D133/06
- C09D133/066—Copolymers with monomers not covered by C09D133/06 containing -OH groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/38—Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/04—Acids; Metal salts or ammonium salts thereof
- C08F220/06—Acrylic acid; Methacrylic acid; Metal salts or ammonium salts thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/14—Methyl esters, e.g. methyl (meth)acrylate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
- C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/02—Homopolymers or copolymers of acids; Metal or ammonium salts thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
- C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
- C08F220/1804—C4-(meth)acrylate, e.g. butyl (meth)acrylate, isobutyl (meth)acrylate or tert-butyl (meth)acrylate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
- C08K2003/265—Calcium, strontium or barium carbonate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Polymerisation Methods In General (AREA)
Abstract
The invention discloses a kind of preparation methods of high resist sagging type acrylic coating, are related to technical field of coatings, comprising the following steps: (1) aqueous acrylic emulsion synthesizes, the preparation of (2) auxiliary material, the preparation of (3) acrylic coating.The present invention makes coating using water as diluent by the preparation of aqueous acrylic emulsion, avoids the problem that using organic solvent as volatile pollution environment existing for diluent；Made acrylic coating is on the basis of mechanical property satisfies the use demand while having excellent resist sagging performance, it can effectively avoid Conventional acrylic coating after spray coating since gravity generates flowing accumulation downwards to the appearance current mark of " shedding tears " occur, and then improve the presentation quality of paint film.
Description
Technical field:
The present invention relates to technical field of coatings, and in particular to a kind of preparation method of high resist sagging type acrylic coating.
Background technique:
In paint field, acrylic resin has many excellent performances, and with the development of technology, to acrylic acid
Higher requirements are also raised for the service performance of coating, especially the thixotropic property of coating.Good thixotropic property makes paint film i.e.
Make in the case where thicker, sagging phenomenon will not occur.
Sagging phenomenon is a kind of defect frequently encountered in coating application.When coating passes through spraying or the coating of other techniques
When on to the surface being disposed vertically, due to gravity, thicker coating wet film or the excessively dilute coating wet film of viscosity can be to
Lower generation flowing accumulation, and there is the appearance current mark of " shedding tears ", seriously affect the appearance of paint film.
Currently, the common method for improving paint thixotropy includes: that thixotropic agent is added in coating by (1).Thixotropic agent due to
The reasons such as performance, side effect, additive amount is limited, very limited for the change of Rheological Property of Coating, so that made coating is anti-
Sagging performance is poor.(2) rheology control agent is synthesized in the presence of matrix resin, is finally mixed to form thixotroping resin.Rheology
It is physical mixed between controlling agent and matrix resin, the dispersion in resin needs to realize by physical agitation, is unable to get
More stable uniform product, and thixotropy is still poor, causes resist sagging performance poor.
Summary of the invention:
Technical problem to be solved by the present invention lies in one kind is provided, operation is simple, the feature of environmental protection is strong and product usability
The preparation method of high resist sagging type acrylic coating that can be excellent.
The following technical solution is employed for the technical problems to be solved by the invention to realize:
A kind of preparation method of high resist sagging type acrylic coating, comprising the following steps:
(1) aqueous acrylic emulsion synthesizes: acetone being added into initiator, stirring is completely dissolved initiator, adds
Chain-transferring agent and the monomer mixed, are heated to reflux state insulation reaction, after reaction drop gained mixture under stirring
Then temperature is added in triethylamine and stirs to 30-40 DEG C, deionized water is added after the completion of to be neutralized and stirs aquation, and distills back
Acetone solvent is received to get aqueous acrylic emulsion；
(2) prepared by auxiliary material: by nanometer calcium carbonate, ultra-fine polytetrafluorethylepowder powder, Lauryl Alcohol ester, anti-sagging agent, polymerization
Aluminum sulfate, the mixing of hexamethylolmelamine pregnancy ether are to get auxiliary material；
(3) prepared by acrylic coating: aqueous acrylic emulsion and auxiliary material being added into water, contains the quality of gained mixture
Water reaches 30-40%, stirs evenly, and is transferred to sealing and standing 12h in 5-10 DEG C of environment, and spontaneous recovery to room temperature is sufficiently stirred
It mixes to get acrylic coating.
The initiator is selected from one of azodiisobutyronitrile, azobisisoheptonitrile.
The initiator amount accounts for the 4.5-5% of monomer gross mass.
The monomer is made of methyl methacrylate, butyl acrylate, acrylic acid, hydroxy-ethyl acrylate.
The methyl methacrylate, butyl acrylate, acrylic acid, hydroxy-ethyl acrylate molar ratio be 1:1:1:0.5-
1。
The chain-transferring agent selects beta -mercaptoethanol.
The dosage of the chain-transferring agent is that every synthesis 1mol acrylate polymer needs 1mol chain-transferring agent.
The nanometer calcium carbonate, ultra-fine polytetrafluorethylepowder powder, Lauryl Alcohol ester, anti-sagging agent, polyaluminium sulfate, six hydroxyls
Methyl melamine pregnancy ether and the ratio of monomer gross mass are 10-15:5-10:3-8:3-8:1-5:1-5:50-80.
The anti-sagging agent is selected from one of rilanit special, fumed silica.
The anti-sagging agent is made of the raw material of following parts by weight: 20-40 parts of rilanit special, polyglutamic acid 10-
15 parts, 5-10 parts of 4A molecular screen primary powder, 100-200 parts of dehydrated alcohol.
The preparation method of the anti-sagging agent includes the following steps:
(1) esterification modification: polyglutamic acid being dissolved in 20-25 DEG C of deionized water, polyglutamic acid saturated solution be made,
And 5% dilute sulfuric acid is added dropwise and adjusts solution ph to 4.5-5, rilanit special is added, it is anti-to be heated to reflux state insulated and stirred
It answers, lotion is made in the reduced pressure of gained mixture after esterification, made lotion is sent into after cooled to room temperature
In freeze drier, micro mist is made through micronizer to get modified hydrogenated castor oil in dry obtained solid；
(2) carrier helps dispersion: the modified hydrogenated castor oil of made polyglutamic acid being added to absolute ethanol, and is heated to
50-55 DEG C of insulated and stirred 5-10min, adds 4A molecular screen primary powder, continues to be heated to reflux state insulated and stirred 0.5-1h, institute
It obtains mixture and recycling ethyl alcohol is concentrated under reduced pressure, condensate residue, which is sent into 55-60 DEG C of baking oven, to be dried to constant weight, and obtained solid warp is super
Micro mist is made to get anti-sagging agent in atomizer.
The polyglutamic acid selects water process grade polyglutamic acid.
By polyglutamic acid to the esterification modification of rilanit special, easy shape when solving rilanit special applied to coating
The problem of at gel, improves dispersibility of the rilanit special in coating；And helping peptizaiton and further promote by carrier
It is dispersed in rilanit special in coating, the comixing compatibility of anti-sagging agent and coating raw material is improved, to make resist sagging
Agent gives full play to its resist sagging performance.
The 4A molecular screen primary powder passes through modification, method of modifying are as follows: three hydroxyl first are added into 4A molecular screen primary powder
Base propane triglycidyl ether and ferrocene are heated to 120-125 DEG C of insulated and stirred 0.5-1h, add hydrolyzed polymaleic anhydride
Acid anhydride continues insulated and stirred 0.5-1h, gained mixture cooled to room temperature, most afterwards through micronizer at 120-125 DEG C
Micro mist is made to get modified 4A molecular sieve.
The 4A molecular screen primary powder, trihydroxymethylpropanyltri diglycidyl ether, ferrocene, hydrolysis of polymaleic anhydride quality
Than for 15-25:5-10:0.05-0.5:1-5.
4A molecular screen primary powder significantly increases its comixing compatibility with coating raw material after above-mentioned modification, to promote
It is dispersed in rilanit special in coating, to give full play to its sag resistance energy.
Thixotroping value: referring at room temperature, the ratio of the viscosity number under viscosity number and 50rpm under revolving speed 5rpm.
The beneficial effects of the present invention are: the preparation method of acrylic coating of the present invention has, operation is simple, ring
The strong feature of guarantor property, is made coating using water as diluent, avoids being made using organic solvent by the preparation of aqueous acrylic emulsion
For existing for diluent the problem of volatile pollution environment；Made acrylic coating is on the basis that mechanical property satisfies the use demand
Above while there is excellent resist sagging performance, can effectively avoid Conventional acrylic coating after spray coating since gravity produces downwards
Raw flowing accumulation improves the presentation quality of paint film to the appearance current mark of " shedding tears " occur.
Specific embodiment:
In order to be easy to understand the technical means, the creative features, the aims and the efficiencies achieved by the present invention, tie below
Specific embodiment is closed, the present invention is further explained.
Embodiment 1
The preparation of coating:
(1) aqueous acrylic emulsion synthesizes: acetone being added into initiator azodiisobutyronitrile, stirring keeps initiator complete
Dissolution, adds the monomer that chain-transferring agent beta -mercaptoethanol and 80kg are mixed, reflux state insulation reaction is heated under stirring,
Gained mixture is cooled to 30-40 DEG C after reaction, is then added in triethylamine and stirs, is added and goes after the completion of to be neutralized
Ionized water stirs aquation, and is distilled to recover acetone solvent to get aqueous acrylic emulsion；
(2) prepared by auxiliary material: by 15kg nanometer calcium carbonate, the ultra-fine polytetrafluorethylepowder powder of 8kg, 5kg Lauryl Alcohol ester, 5kg
Anti-sagging agent rilanit special, 3kg polyaluminium sulfate, the mixing of 2kg hexamethylolmelamine pregnancy ether are to get auxiliary material；
(3) prepared by acrylic coating: aqueous acrylic emulsion and auxiliary material being added into water, contains the quality of gained mixture
Water reaches 30-40%, stirs evenly, and is transferred to sealing and standing 12h in 5-10 DEG C of environment, and spontaneous recovery to room temperature is sufficiently stirred
It mixes to get acrylic coating.
Wherein, initiator amount accounts for the 5% of monomer gross mass, and monomer is 1:1:1:0.7 methyl methacrylate by molar ratio
Ester, butyl acrylate, acrylic acid, hydroxy-ethyl acrylate composition, the dosage of chain-transferring agent are every synthesis 1mol acrylic ester polymerization
Object needs 1mol chain-transferring agent.
Embodiment 2
The preparation of coating:
(1) aqueous acrylic emulsion synthesizes: acetone being added into initiator azodiisobutyronitrile, stirring keeps initiator complete
Dissolution, adds the monomer that chain-transferring agent beta -mercaptoethanol and 80kg are mixed, reflux state insulation reaction is heated under stirring,
Gained mixture is cooled to 30-40 DEG C after reaction, is then added in triethylamine and stirs, is added and goes after the completion of to be neutralized
Ionized water stirs aquation, and is distilled to recover acetone solvent to get aqueous acrylic emulsion；
(2) prepared by auxiliary material: by 15kg nanometer calcium carbonate, the ultra-fine polytetrafluorethylepowder powder of 8kg, 5kg Lauryl Alcohol ester, 5kg
Anti-sagging agent fumed silica, 3kg polyaluminium sulfate, the mixing of 2kg hexamethylolmelamine pregnancy ether are to get auxiliary material；
(3) prepared by acrylic coating: aqueous acrylic emulsion and auxiliary material being added into water, contains the quality of gained mixture
Water reaches 30-40%, stirs evenly, and is transferred to sealing and standing 12h in 5-10 DEG C of environment, and spontaneous recovery to room temperature is sufficiently stirred
It mixes to get acrylic coating.
Wherein, initiator amount accounts for the 5% of monomer gross mass, and monomer is 1:1:1:0.7 methyl methacrylate by molar ratio
Ester, butyl acrylate, acrylic acid, hydroxy-ethyl acrylate composition, the dosage of chain-transferring agent are every synthesis 1mol acrylic ester polymerization
Object needs 1mol chain-transferring agent.
Embodiment 3
The preparation of coating:
(1) aqueous acrylic emulsion synthesizes: acetone being added into initiator azodiisobutyronitrile, stirring keeps initiator complete
Dissolution, adds the monomer that chain-transferring agent beta -mercaptoethanol and 80kg are mixed, reflux state insulation reaction is heated under stirring,
Gained mixture is cooled to 30-40 DEG C after reaction, is then added in triethylamine and stirs, is added and goes after the completion of to be neutralized
Ionized water stirs aquation, and is distilled to recover acetone solvent to get aqueous acrylic emulsion；
(2) prepared by auxiliary material: by 15kg nanometer calcium carbonate, the ultra-fine polytetrafluorethylepowder powder of 8kg, 5kg Lauryl Alcohol ester, 5kg
Anti-sagging agent, 3kg polyaluminium sulfate, the mixing of 2kg hexamethylolmelamine pregnancy ether are to get auxiliary material；
(3) prepared by acrylic coating: aqueous acrylic emulsion and auxiliary material being added into water, contains the quality of gained mixture
Water reaches 30-40%, stirs evenly, and is transferred to sealing and standing 12h in 5-10 DEG C of environment, and spontaneous recovery to room temperature is sufficiently stirred
It mixes to get acrylic coating.
Wherein, initiator amount accounts for the 5% of monomer gross mass, and monomer is 1:1:1:0.7 methyl methacrylate by molar ratio
Ester, butyl acrylate, acrylic acid, hydroxy-ethyl acrylate composition, the dosage of chain-transferring agent are every synthesis 1mol acrylic ester polymerization
Object needs 1mol chain-transferring agent.
The preparation of anti-sagging agent:
(1) esterification modification: 15g water process grade polyglutamic acid is dissolved in 20-25 DEG C of deionized water, more polyglutamics is made
Sour saturated solution, and 5% dilute sulfuric acid is added dropwise and adjusts solution ph to 4.5-5,40g rilanit special is added, is heated to flowing back
State insulated and stirred is reacted, and lotion is made in the reduced pressure of gained mixture after esterification, made lotion is through naturally cold
But in feeding freeze drier, micro mist is made through micronizer to get modified hydrogenated castor-oil plant in dry obtained solid after room temperature
Oil；
(2) carrier helps dispersion: the modified hydrogenated castor oil of made polyglutamic acid being added in 200g dehydrated alcohol, and is heated
To 50-55 DEG C of insulated and stirred 10min, 8g 4A molecular screen primary powder is added, continues to be heated to reflux state insulated and stirred 1h, institute
It obtains mixture and recycling ethyl alcohol is concentrated under reduced pressure, condensate residue, which is sent into 55-60 DEG C of baking oven, to be dried to constant weight, and obtained solid warp is super
Micro mist is made to get anti-sagging agent in atomizer.
Embodiment 4
The preparation of coating:
(1) aqueous acrylic emulsion synthesizes: acetone being added into initiator azodiisobutyronitrile, stirring keeps initiator complete
Dissolution, adds the monomer that chain-transferring agent beta -mercaptoethanol and 80kg are mixed, reflux state insulation reaction is heated under stirring,
Gained mixture is cooled to 30-40 DEG C after reaction, is then added in triethylamine and stirs, is added and goes after the completion of to be neutralized
Ionized water stirs aquation, and is distilled to recover acetone solvent to get aqueous acrylic emulsion；
(2) prepared by auxiliary material: by 15kg nanometer calcium carbonate, the ultra-fine polytetrafluorethylepowder powder of 8kg, 5kg Lauryl Alcohol ester, 5kg
Anti-sagging agent, 3kg polyaluminium sulfate, the mixing of 2kg hexamethylolmelamine pregnancy ether are to get auxiliary material；
(3) prepared by acrylic coating: aqueous acrylic emulsion and auxiliary material being added into water, contains the quality of gained mixture
Water reaches 30-40%, stirs evenly, and is transferred to sealing and standing 12h in 5-10 DEG C of environment, and spontaneous recovery to room temperature is sufficiently stirred
It mixes to get acrylic coating.
Wherein, initiator amount accounts for the 5% of monomer gross mass, and monomer is 1:1:1:0.7 methyl methacrylate by molar ratio
Ester, butyl acrylate, acrylic acid, hydroxy-ethyl acrylate composition, the dosage of chain-transferring agent are every synthesis 1mol acrylic ester polymerization
Object needs 1mol chain-transferring agent.
The preparation of anti-sagging agent:
(1) esterification modification: 15g water process grade polyglutamic acid is dissolved in 20-25 DEG C of deionized water, more polyglutamics is made
Sour saturated solution, and 5% dilute sulfuric acid is added dropwise and adjusts solution ph to 4.5-5,40g rilanit special is added, is heated to flowing back
State insulated and stirred is reacted, and lotion is made in the reduced pressure of gained mixture after esterification, made lotion is through naturally cold
But in feeding freeze drier, micro mist is made through micronizer to get modified hydrogenated castor-oil plant in dry obtained solid after room temperature
Oil；
(2) carrier helps dispersion: the modified hydrogenated castor oil of made polyglutamic acid being added in 200g dehydrated alcohol, and is heated
To 50-55 DEG C of insulated and stirred 10min, 8g 4A molecular screen primary powder is added, continues to be heated to reflux state insulated and stirred 1h, institute
It obtains mixture and recycling ethyl alcohol is concentrated under reduced pressure, condensate residue, which is sent into 55-60 DEG C of baking oven, to be dried to constant weight, and obtained solid warp is super
Micro mist is made to get anti-sagging agent in atomizer.
The modification of 4A molecular screen primary powder: 8g trihydroxymethylpropanyltri diglycidyl ether is added into 25g 4A molecular screen primary powder
With 0.25g ferrocene, it is heated to 120-125 DEG C of insulated and stirred 1h, adds 3g hydrolysis of polymaleic anhydride, is continued in 120-125
Most micro mist is made to get modified 4A through micronizer afterwards in insulated and stirred 0.5h at DEG C, gained mixture cooled to room temperature
Molecular sieve.
Reference examples 1
The preparation of coating:
(1) aqueous acrylic emulsion synthesizes: acetone being added into initiator azodiisobutyronitrile, stirring keeps initiator complete
Dissolution, adds the monomer that chain-transferring agent beta -mercaptoethanol and 80kg are mixed, reflux state insulation reaction is heated under stirring,
Gained mixture is cooled to 30-40 DEG C after reaction, is then added in triethylamine and stirs, is added and goes after the completion of to be neutralized
Ionized water stirs aquation, and is distilled to recover acetone solvent to get aqueous acrylic emulsion；
(2) prepared by auxiliary material: by 15kg nanometer calcium carbonate, the ultra-fine polytetrafluorethylepowder powder of 8kg, 5kg Lauryl Alcohol ester, 5kg
Anti-sagging agent rilanit special, 3kg polyaluminium sulfate, the mixing of 2kg hexamethylolmelamine pregnancy ether are to get auxiliary material；
(3) prepared by acrylic coating: aqueous acrylic emulsion and auxiliary material being added into water, contains the quality of gained mixture
Water reaches 30-40%, stirs evenly to get acrylic coating.
Wherein, initiator amount accounts for the 5% of monomer gross mass, and monomer is 1:1:1:0.7 methyl methacrylate by molar ratio
Ester, butyl acrylate, acrylic acid, hydroxy-ethyl acrylate composition, the dosage of chain-transferring agent are every synthesis 1mol acrylic ester polymerization
Object needs 1mol chain-transferring agent.
Reference examples 2
The preparation of coating:
(1) aqueous acrylic emulsion synthesizes: acetone being added into initiator azodiisobutyronitrile, stirring keeps initiator complete
Dissolution, adds the monomer that chain-transferring agent beta -mercaptoethanol and 80kg are mixed, reflux state insulation reaction is heated under stirring,
Gained mixture is cooled to 30-40 DEG C after reaction, is then added in triethylamine and stirs, is added and goes after the completion of to be neutralized
Ionized water stirs aquation, and is distilled to recover acetone solvent to get aqueous acrylic emulsion；
(2) prepared by auxiliary material: by 15kg nanometer calcium carbonate, the ultra-fine polytetrafluorethylepowder powder of 8kg, 5kg Lauryl Alcohol ester, 5kg
Anti-sagging agent rilanit special, the mixing of 3kg polyaluminium sulfate are to get auxiliary material；
(3) prepared by acrylic coating: aqueous acrylic emulsion and auxiliary material being added into water, contains the quality of gained mixture
Water reaches 30-40%, stirs evenly, and is transferred to sealing and standing 12h in 5-10 DEG C of environment, and spontaneous recovery to room temperature is sufficiently stirred
It mixes to get acrylic coating.
Wherein, initiator amount accounts for the 5% of monomer gross mass, and monomer is 1:1:1:0.7 methyl methacrylate by molar ratio
Ester, butyl acrylate, acrylic acid, hydroxy-ethyl acrylate composition, the dosage of chain-transferring agent are every synthesis 1mol acrylic ester polymerization
Object needs 1mol chain-transferring agent.
Reference examples 3
The preparation of coating:
(1) aqueous acrylic emulsion synthesizes: acetone being added into initiator azodiisobutyronitrile, stirring keeps initiator complete
Dissolution, adds the monomer that chain-transferring agent beta -mercaptoethanol and 80kg are mixed, reflux state insulation reaction is heated under stirring,
Gained mixture is cooled to 30-40 DEG C after reaction, is then added in triethylamine and stirs, is added and goes after the completion of to be neutralized
Ionized water stirs aquation, and is distilled to recover acetone solvent to get aqueous acrylic emulsion；
(2) prepared by auxiliary material: by 15kg nanometer calcium carbonate, the ultra-fine polytetrafluorethylepowder powder of 8kg, 5kg Lauryl Alcohol ester, 3kg
Polyaluminium sulfate, the mixing of 2kg hexamethylolmelamine pregnancy ether are to get auxiliary material；
(3) prepared by acrylic coating: aqueous acrylic emulsion and auxiliary material being added into water, contains the quality of gained mixture
Water reaches 30-40%, stirs evenly, and is transferred to sealing and standing 12h in 5-10 DEG C of environment, and spontaneous recovery to room temperature is sufficiently stirred
It mixes to get acrylic coating.
Wherein, initiator amount accounts for the 5% of monomer gross mass, and monomer is 1:1:1:0.7 methyl methacrylate by molar ratio
Ester, butyl acrylate, acrylic acid, hydroxy-ethyl acrylate composition, the dosage of chain-transferring agent are every synthesis 1mol acrylic ester polymerization
Object needs 1mol chain-transferring agent.
Embodiment 5
Be utilized respectively embodiment 1-4, reference examples 1-3 prepares acrylic coating, and test the sagging of made acrylic coating
Performance, test result are as shown in table 1.
Test method: one piece of 40mm × 15 × (0.1-0.3) mm tinplate template is divided into 5 with adhesive tape from top to bottom
Then region is sprayed, spray 1 time, 2 times, 3 times, 4 times and 5 times respectively from top to bottom, i.e. film thickness gradually becomes from top to bottom
It is thick.Adhesive tape is torn, vertical state is kept to place surface drying, then enters after baking oven high-temperature baking certain time takes out and observes from which
Region starts slight sagging phenomenon occur, and records the film thickness of this region lower edge, this numerical value is defined as the sagging pole of wet film
Limit film thickness.
The sagging the performance test results of the acrylic coating of the present invention of table 1
As shown in Table 1, self-control anti-sagging agent has better than conventional anti-sagging agent rilanit special and fumed silica
Resist sagging performance makes by oneself and helps the modification of dispersible carrier 4A molecular screen primary powder to can be further improved resist sagging used in anti-sagging agent
Energy；Coating resist sagging performance decline without 5-10 DEG C of sub-cooled processing, is not added with hexamethylolmelamine pregnancy ether
Coating resist sagging performance can also decline.
The above shows and describes the basic principles and main features of the present invention and the advantages of the present invention.The technology of the industry
Personnel are it should be appreciated that the present invention is not limited to the above embodiments, and the above embodiments and description only describe this
The principle of invention, without departing from the spirit and scope of the present invention, various changes and improvements may be made to the invention, these changes
Change and improvement all fall within the protetion scope of the claimed invention.The claimed scope of the invention by appended claims and its
Equivalent thereof.
Claims (8)
1. a kind of preparation method of high resist sagging type acrylic coating, which comprises the following steps:
(1) aqueous acrylic emulsion synthesizes: acetone being added into initiator, stirring is completely dissolved initiator, adds chain and turns
The monomer for moving agent and mixing, is heated to reflux state insulation reaction, is after reaction cooled to gained mixture under stirring
It 30-40 DEG C, is then added in triethylamine and stirs, deionized water is added after the completion of to be neutralized and stirs aquation, and is distilled to recover third
Ketone solvent is to get aqueous acrylic emulsion；
(2) prepared by auxiliary material: by nanometer calcium carbonate, ultra-fine polytetrafluorethylepowder powder, Lauryl Alcohol ester, anti-sagging agent, polyaluminum sulfate
Aluminium, the mixing of hexamethylolmelamine pregnancy ether are to get auxiliary material；
(3) prepared by acrylic coating: aqueous acrylic emulsion and auxiliary material being added into water, makes the mass water content of gained mixture
Reach 30-40%, stir evenly, and be transferred to sealing and standing 12h in 5-10 DEG C of environment, spontaneous recovery to room temperature is sufficiently stirred, i.e.,
Obtain acrylic coating；
The anti-sagging agent is made of the raw material of following parts by weight: 20-40 parts of rilanit special, 10-15 parts of polyglutamic acid,
5-10 parts of 4A molecular screen primary powder, 100-200 parts of dehydrated alcohol, preparation method includes the following steps:
(1) esterification modification: polyglutamic acid is dissolved in 20-25 DEG C of deionized water, polyglutamic acid saturated solution is made, and dripped
Add 5% dilute sulfuric acid to adjust solution ph to 4.5-5, adds rilanit special, be heated to the reaction of reflux state insulated and stirred, ester
Change and lotion is made in the reduced pressure of gained mixture after reaction, it is dry that made lotion is sent into freezing after cooled to room temperature
In dry machine, micro mist is made through micronizer to get modified hydrogenated castor oil in dry obtained solid；
(2) carrier helps dispersion: the modified hydrogenated castor oil of made polyglutamic acid being added to absolute ethanol, and is heated to 50-55
DEG C insulated and stirred 5-10min, adds 4A molecular screen primary powder, continues to be heated to reflux state insulated and stirred 0.5-1h, gained is mixed
It closes object and recycling ethyl alcohol is concentrated under reduced pressure, condensate residue is sent into 55-60 DEG C of baking oven and is dried to constant weight, and obtained solid is through Ultramicro-powder
Micro mist is made to get anti-sagging agent in broken machine.
2. the preparation method of high resist sagging type acrylic coating according to claim 1, it is characterised in that: the initiator
Selected from one of azodiisobutyronitrile, azobisisoheptonitrile.
3. the preparation method of high resist sagging type acrylic coating according to claim 1, it is characterised in that: the initiator
Dosage accounts for the 4.5-5% of monomer gross mass.
4. the preparation method of high resist sagging type acrylic coating according to claim 1, it is characterised in that: the monomer by
Methyl methacrylate, butyl acrylate, acrylic acid, hydroxy-ethyl acrylate composition.
5. the preparation method of high resist sagging type acrylic coating according to claim 4, it is characterised in that: the methyl-prop
E pioic acid methyl ester, butyl acrylate, acrylic acid, hydroxy-ethyl acrylate molar ratio be 1:1:1:0.5-1.
6. the preparation method of high resist sagging type acrylic coating according to claim 1, it is characterised in that: the chain tra nsfer
Beta -mercaptoethanol is selected in agent.
7. the preparation method of high resist sagging type acrylic coating according to claim 1, it is characterised in that: the chain tra nsfer
The dosage of agent is that every synthesis 1mol acrylate polymer needs 1mol chain-transferring agent.
8. the preparation method of high resist sagging type acrylic coating according to claim 1, it is characterised in that: the nano-sized carbon
Sour calcium, ultra-fine polytetrafluorethylepowder powder, Lauryl Alcohol ester, anti-sagging agent, polyaluminium sulfate, hexamethylolmelamine pregnancy ether
Ratio with monomer gross mass is 10-15:5-10:3-8:3-8:1-5:1-5:50-80.
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