CN108219265A - A kind of lamp package insulating materials - Google Patents

A kind of lamp package insulating materials Download PDF

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Publication number
CN108219265A
CN108219265A CN201611145790.8A CN201611145790A CN108219265A CN 108219265 A CN108219265 A CN 108219265A CN 201611145790 A CN201611145790 A CN 201611145790A CN 108219265 A CN108219265 A CN 108219265A
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CN
China
Prior art keywords
parts
insulating materials
lamp package
package insulating
gypsum
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Application number
CN201611145790.8A
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Chinese (zh)
Inventor
王永飞
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Suzhou Zhirui Photoelectric Material Technology Co Ltd
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Suzhou Zhirui Photoelectric Material Technology Co Ltd
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Priority to CN201611145790.8A priority Critical patent/CN108219265A/en
Publication of CN108219265A publication Critical patent/CN108219265A/en
Withdrawn legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10Homopolymers or copolymers of propene
    • C08L23/12Polypropene
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L33/00Semiconductor devices having potential barriers specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L33/48Semiconductor devices having potential barriers specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof characterised by the semiconductor body packages
    • H01L33/52Encapsulations
    • H01L33/56Materials, e.g. epoxy or silicone resin
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00Applications
    • C08L2203/20Applications use in electrical or conductive gadgets
    • C08L2203/206Applications use in electrical or conductive gadgets use in coating or encapsulating of electronic parts
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Manufacturing & Machinery (AREA)
  • Computer Hardware Design (AREA)
  • Power Engineering (AREA)
  • Organic Insulating Materials (AREA)
  • Inorganic Insulating Materials (AREA)

Abstract

The invention belongs to insulating materials technical fields, specifically disclose a kind of lamp package insulating materials.The raw materials by weight portion proportioning of the lamp package insulating materials is as follows:PP100 parts;90 parts of EVA50;25 45 parts of acrylic rubber;15 55 parts of paraffin oil;1 40 80 parts of butylene;25 parts of PC5;15 parts of phthalate ester;0.5 2.5 parts of anti-oxidant DLTP;48 parts of gypsum;Antioxidant CA is 0.3 0.7 parts;6 10 parts of antimony oxide.Obtained 10 30MPa of product tensile strength, elongation 400 600%;Product high temperature resistant, 130 170 DEG C of heat resisting temperature;350 550kV/mm of pulse breakdown voltage, exchange are electrically insulated and wear 40 60kV/mm of voltage;Shore hardness 1000 1200A, it is of low cost, it is easy to operate, there is high dielectric strength and insulating properties, can produce extensively and constantly instead of current material.

Description

A kind of lamp package insulating materials
Technical field
The invention belongs to insulating materials technical field more particularly to a kind of lamp package insulating materials.
Background technology
Insulating materials is the material for the current-carrying part of different potentials to be isolated, and conductivity is about in 10-100 west/rice Below.By standard GB/T/T2900.5-2013 regulations, the definition of insulating materials is:" it is used for that device is made electrically to insulate Material ", that is, can prevent electric current by material.Such as in motor, the insulating materials around conductor is isolated by turn-to-turn And keep apart with the stator core of ground connection, to ensure the safe operation of motor.
There are many insulating materials type, can divide gas, liquid, solid three categories.Common gas insulating material has air, nitrogen Gas, sulfur hexafluoride etc..Liquid insulating material mainly has mineral insulating oil, synthetic insulating oil(Silicone oil, detergent alkylate, poly- isobutyl Alkene, isopropyl biphenyl, diarylethane etc.)Two classes.Solid insulating material can be divided to organic and inorganic two class.Organic solid insulation material Material include insulated paint, insulating cement, insulating paper, non-conductive fibre product, plastics, rubber, varnished cloth paint pipe and insulation impregnating fibre, Electrician's film, composite article and adhesive tape, electrician's laminated product etc..Inoganic solids insulating materials mainly has mica, glass, pottery Porcelain and its product.In contrast, solid insulating material is numerous in variety, also mostly important.
Requirement of the different electrical equipments to insulating material properties emphasizes particularly on different fields.High pressure electrical device such as high-voltage motor, height The insulating materials of voltage cable etc. requires have high breakdown strength and low dielectric loss.Low-voltage electrical apparatus is then with mechanical strength, disconnected Elongation, temperature classification etc. are split as major requirement.
The macro property of insulating materials such as electrical property, hot property, mechanical property, chemical-resistant resistance, weatherability variation, corrosion resistant The performances and its chemical composition, molecular structure etc. such as erosion have substantial connection.Inoganic solids insulating materials is mainly by silicon, boron and more Kind metal oxide composition based on ionic structure, is mainly characterized in that heat resistance height, and operating temperature is generally higher than 180 DEG C, surely It is qualitative good, resistance to weathering, chemical resistance and the ageing properties under electric field action are good for a long time;But brittleness is high, resistance to punching Hit intensity is low, high pressure and tensile strength is low;Craftsmanship is poor.Organic material is generally polymer, and heat resistance is usually less than nothing Machine material.Material its heat resistance containing the elements such as aromatic ring, heterocycle and silicon, titanium, fluorine is then higher than general line chain high molecular material.
An important factor for influencing insulating materials dielectric properties is the power of molecular polarity and the content of polar compound.Polarity material The dielectric constant of material, dielectric loss are above non-polar material, and easily adsorbing contaminant ion increases conductance and reduces its Jie Electrical property.Therefore it is noted that cleaning, prevents from polluting in insulating materials manufacturing process.Capacitor electricity consumption medium requirements have high dielectric Constant is to improve its ratio characteristic.
Artificial synthesized insulating materials is rapidly developed since the thirties, mainly there is acetal resin, neoprene, polychlorostyrene Ethylene, butadiene-styrene rubber, polyamide, melamine, polyethylene and it has excellent performance referred to as polytetrafluoroethylene (PTFE) of King etc..These The appearance of synthetic material has played significant role to electrotechniical development.If acetal enameled wire is for motor, make its operating temperature It is improved with reliability, and the volume and weight of motor substantially reduces.Glass fibre and its braid over braid succeed in developing and organosilicon The synthesis of resin increases H grades of this temperature classifications for motor insulation again.And with the popularity of humanized concept and novel harmony The composition of society, design that a kind of intensity is high, hardness is high, elongation at break is high and the lamp package insulating materials of good insulating and its Preparation method is very important.
Invention content
The technical issues of solution:
The purpose of the present invention is to provide a kind of lamp package insulating materials, solve existing insulating materials intensity is low, elongation is low, The technical issues of hardness is low.
Technical solution:
A kind of lamp package insulating materials, the raw materials by weight portion proportioning of the lamp package insulating materials are as follows:PP100 Part;EVA50-90 parts;25-45 parts of acrylic rubber;15-55 parts of paraffin oil;40-80 parts of 1- butylene;PC5-25 parts;Phthalate ester 1-5 parts;0.5-2.5 parts of anti-oxidant DLTP;4-8 parts of gypsum;Antioxidant CA is 0.3-0.7 parts;6-10 parts of antimony oxide.
As a preferred technical solution of the present invention:The raw materials by weight portion proportioning of the lamp package insulating materials It is as follows:PP100 parts;EVA60-80 parts;30-40 parts of acrylic rubber;25-45 parts of paraffin oil;50-70 parts of 1- butylene;PC10- 20 parts;2-4 parts of phthalate ester;1-2 parts of anti-oxidant DLTP;5-7 parts of gypsum;Antioxidant CA is 0.4-0.6 parts;Antimony oxide 7-9 Part.
As a preferred technical solution of the present invention:The raw materials by weight portion proportioning of the lamp package insulating materials It is as follows:PP100 parts;EVA60 parts;30 parts of acrylic rubber;25 parts of paraffin oil;50 parts of 1- butylene;PC10 parts;2 parts of phthalate ester; 1 part of anti-oxidant DLTP;5 parts of gypsum;Antioxidant CA is 0.4 part;7 parts of antimony oxide.
As a preferred technical solution of the present invention:The raw materials by weight portion proportioning of the lamp package insulating materials It is as follows:PP100 parts;EVA80 parts;40 parts of acrylic rubber;45 parts of paraffin oil;70 parts of 1- butylene;PC20 parts;4 parts of phthalate ester; 2 parts of anti-oxidant DLTP;7 parts of gypsum;Antioxidant CA is 0.6 part;9 parts of antimony oxide.
As a preferred technical solution of the present invention:The raw materials by weight portion proportioning of the lamp package insulating materials It is as follows:PP100 parts;EVA70 parts;35 parts of acrylic rubber;35 parts of paraffin oil;60 parts of 1- butylene;PC15 parts;3 parts of phthalate ester; 1.5 parts of anti-oxidant DLTP;6 parts of gypsum;Antioxidant CA is 0.5 part;8 parts of antimony oxide.
Advantageous effect:
A kind of lamp package insulating materials of the present invention compared with prior art, has following technology using above technical scheme Effect:1st, product tensile strength 10-30MPa, elongation 400-600%;2nd, product high temperature resistant, 130-170 DEG C of heat resisting temperature;3、 Pulse breakdown voltage 350-550kV/mm, exchange are electrically insulated and wear voltage 40-60kV/mm;4th, shore hardness 1000- 1200A, it is of low cost, it is easy to operate, there is high dielectric strength and insulating properties, can produce extensively and constantly replace existing material Material.
Specific embodiment
Embodiment 1:
PP100 parts are weighed according to parts by weight proportioning;EVA50 parts;25 parts of acrylic rubber;15 parts of paraffin oil;1- butylene 40 Part;PC5 parts;1 part of phthalate ester;0.5 part of anti-oxidant DLTP;4 parts of gypsum;Antioxidant CA is 0.3 part;6 parts of antimony oxide.
Raw material input blender is mixed, 50 DEG C, mixing velocity 300r/min is warming up to, mixes 1h.
Put into double screw extruder after mixing, 170 DEG C of feeding section temperature, 200 DEG C of body temperature, 205 DEG C, 210 DEG C, 215 DEG C, 220 DEG C, 230 DEG C of head temperature, 235 DEG C, 235 DEG C, 240 DEG C, 245 DEG C, screw speed 35r/min, feed intake rotating speed 30 r/min。
Product tensile strength 10MPa, elongation 400%;Product high temperature resistant, 130 DEG C of heat resisting temperature;Pulse insulation breakdown electricity 350kV/mm is pressed, exchange is electrically insulated and wears voltage 40kV/mm;Shore hardness 1000A, it is of low cost, it is easy to operate, there is Gao Jie Electric strength and insulating properties can produce and constantly replace current material extensively.
Embodiment 2:
PP100 parts are weighed according to parts by weight proportioning;EVA90 parts;45 parts of acrylic rubber;55 parts of paraffin oil;1- butylene 80 Part;PC25 parts;5 parts of phthalate ester;2.5 parts of anti-oxidant DLTP;8 parts of gypsum;Antioxidant CA is 0.7 part;10 parts of antimony oxide.
Raw material input blender is mixed, 90 DEG C, mixing velocity 500r/min is warming up to, mixes 3h.
Put into double screw extruder after mixing, 190 DEG C of feeding section temperature, 210 DEG C of body temperature, 215 DEG C, 220 DEG C, 225 DEG C, 230 DEG C, 240 DEG C of head temperature, 245 DEG C, 245 DEG C, 250 DEG C, 255 DEG C, screw speed 45r/min, feed intake rotating speed 40 r/min。
Product tensile strength 15MPa, elongation 450%;Product high temperature resistant, 140 DEG C of heat resisting temperature;Pulse insulation breakdown electricity 400kV/mm is pressed, exchange is electrically insulated and wears voltage 45kV/mm;Shore hardness 1050A, it is of low cost, it is easy to operate, there is Gao Jie Electric strength and insulating properties can produce and constantly replace current material extensively.
Embodiment 3:
PP100 parts are weighed according to parts by weight proportioning;EVA60 parts;30 parts of acrylic rubber;25 parts of paraffin oil;1- butylene 50 Part;PC10 parts;2 parts of phthalate ester;1 part of anti-oxidant DLTP;5 parts of gypsum;Antioxidant CA is 0.4 part;7 parts of antimony oxide.
Raw material input blender is mixed, 50 DEG C, mixing velocity 300r/min is warming up to, mixes 1h.
Put into double screw extruder after mixing, 170 DEG C of feeding section temperature, 200 DEG C of body temperature, 205 DEG C, 210 DEG C, 215 DEG C, 220 DEG C, 230 DEG C of head temperature, 235 DEG C, 235 DEG C, 240 DEG C, 245 DEG C, screw speed 35r/min, feed intake rotating speed 30r/min。
Product tensile strength 20MPa, elongation 500%;Product high temperature resistant, 150 DEG C of heat resisting temperature;Pulse insulation breakdown electricity 450kV/mm is pressed, exchange is electrically insulated and wears voltage 50kV/mm;Shore hardness 1100A, it is of low cost, it is easy to operate, there is Gao Jie Electric strength and insulating properties can produce and constantly replace current material extensively.
Embodiment 4:
PP100 parts are weighed according to parts by weight proportioning;EVA80 parts;40 parts of acrylic rubber;45 parts of paraffin oil;1- butylene 70 Part;PC20 parts;4 parts of phthalate ester;2 parts of anti-oxidant DLTP;7 parts of gypsum;Antioxidant CA is 0.6 part;9 parts of antimony oxide.
Raw material input blender is mixed, 90 DEG C, mixing velocity 500r/min is warming up to, mixes 3h.
Put into double screw extruder after mixing, 190 DEG C of feeding section temperature, 210 DEG C of body temperature, 215 DEG C, 220 DEG C, 225 DEG C, 230 DEG C, 240 DEG C of head temperature, 245 DEG C, 245 DEG C, 250 DEG C, 255 DEG C, screw speed 45r/min, feed intake rotating speed 40 r/min。
Product tensile strength 25MPa, elongation 550%;Product high temperature resistant, 160 DEG C of heat resisting temperature;Pulse insulation breakdown electricity 500kV/mm is pressed, exchange is electrically insulated and wears voltage 55kV/mm;Shore hardness 1150A, it is of low cost, it is easy to operate, there is Gao Jie Electric strength and insulating properties can produce and constantly replace current material extensively.
Embodiment 5:
PP100 parts are weighed according to parts by weight proportioning;EVA70 parts;35 parts of acrylic rubber;35 parts of paraffin oil;1- butylene 60 Part;PC15 parts;3 parts of phthalate ester;1.5 parts of anti-oxidant DLTP;6 parts of gypsum;Antioxidant CA is 0.5 part;8 parts of antimony oxide.
Raw material input blender is mixed, 70 DEG C, mixing velocity 400r/min is warming up to, mixes 2h.
Put into double screw extruder after mixing, 180 DEG C of feeding section temperature, 205 DEG C of body temperature, 210 DEG C, 215 DEG C, 220 DEG C, 225 DEG C, 235 DEG C of head temperature, 240 DEG C, 240 DEG C, 245 DEG C, 250 DEG C, screw speed 40r/min, feed intake rotating speed 35 r/min。
Product tensile strength 30MPa, elongation 600%;Product high temperature resistant, 170 DEG C of heat resisting temperature;Pulse insulation breakdown electricity 550kV/mm is pressed, exchange is electrically insulated and wears voltage 60kV/mm;Shore hardness 1200A, it is of low cost, it is easy to operate, there is Gao Jie Electric strength and insulating properties can produce and constantly replace current material extensively.
Composition all components in above example can be commercially available.
The above embodiments are merely intended to illustrate the present invention rather than to limit it, therefore with the present invention's Any change in the comparable meaning and scope of claims, should be construed as being included in the scope of the claims.

Claims (5)

1. a kind of lamp package insulating materials, it is characterised in that:The raw materials by weight portion of the lamp package insulating materials is matched Than as follows:PP100 parts;EVA50-90 parts;25-45 parts of acrylic rubber;15-55 parts of paraffin oil;40-80 parts of 1- butylene; PC5-25 parts;1-5 parts of phthalate ester;0.5-2.5 parts of anti-oxidant DLTP;4-8 parts of gypsum;Antioxidant CA is 0.3-0.7 parts;Three oxidations Two 6-10 parts of antimony.
2. a kind of lamp package insulating materials according to claim 1, it is characterised in that:The lamp package insulating materials Raw materials by weight portion proportioning is as follows:PP100 parts;EVA60-80 parts;30-40 parts of acrylic rubber;25-45 parts of paraffin oil; 50-70 parts of 1- butylene;PC10-20 parts;2-4 parts of phthalate ester;1-2 parts of anti-oxidant DLTP;5-7 parts of gypsum;Antioxidant CA is 0.4- 0.6 part;7-9 parts of antimony oxide.
3. a kind of lamp package insulating materials according to claim 1, it is characterised in that:The lamp package insulating materials Raw materials by weight portion proportioning it is as follows:PP100 parts;EVA60 parts;30 parts of acrylic rubber;25 parts of paraffin oil;1- butylene 50 Part;PC10 parts;2 parts of phthalate ester;1 part of anti-oxidant DLTP;5 parts of gypsum;Antioxidant CA is 0.4 part;7 parts of antimony oxide.
4. a kind of lamp package insulating materials according to claim 1, it is characterised in that:The lamp package insulating materials Raw materials by weight portion proportioning it is as follows:PP100 parts;EVA80 parts;40 parts of acrylic rubber;45 parts of paraffin oil;1- butylene 70 Part;PC20 parts;4 parts of phthalate ester;2 parts of anti-oxidant DLTP;7 parts of gypsum;Antioxidant CA is 0.6 part;9 parts of antimony oxide.
5. a kind of lamp package insulating materials according to claim 1, it is characterised in that:The lamp package insulating materials Raw materials by weight portion proportioning it is as follows:PP100 parts;EVA70 parts;35 parts of acrylic rubber;35 parts of paraffin oil;1- butylene 60 Part;PC15 parts;3 parts of phthalate ester;1.5 parts of anti-oxidant DLTP;6 parts of gypsum;Antioxidant CA is 0.5 part;8 parts of antimony oxide.
CN201611145790.8A 2016-12-13 2016-12-13 A kind of lamp package insulating materials Withdrawn CN108219265A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201611145790.8A CN108219265A (en) 2016-12-13 2016-12-13 A kind of lamp package insulating materials

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Application Number Priority Date Filing Date Title
CN201611145790.8A CN108219265A (en) 2016-12-13 2016-12-13 A kind of lamp package insulating materials

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108892939A (en) * 2018-07-16 2018-11-27 广州极慧技术服务有限公司 Insulating composite material and preparation method thereof is worn in a kind of resistance

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104231436A (en) * 2014-09-24 2014-12-24 日照市遨游车件有限公司 Low-temperature-resistant polypropylene composite material for rear shell of automobile lamp and preparation method of low-temperature-resistant polypropylene composite material

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104231436A (en) * 2014-09-24 2014-12-24 日照市遨游车件有限公司 Low-temperature-resistant polypropylene composite material for rear shell of automobile lamp and preparation method of low-temperature-resistant polypropylene composite material

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
君轩: "溶解度参数", 《世界橡胶工业》 *
宋波: "《塑料改性技术》", 13 October 2016, 中国纺织出版社 *

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108892939A (en) * 2018-07-16 2018-11-27 广州极慧技术服务有限公司 Insulating composite material and preparation method thereof is worn in a kind of resistance

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Application publication date: 20180629