CN108218307A - A kind of ocean engineering marine sand concrete - Google Patents

A kind of ocean engineering marine sand concrete Download PDF

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Publication number
CN108218307A
CN108218307A CN201611193144.9A CN201611193144A CN108218307A CN 108218307 A CN108218307 A CN 108218307A CN 201611193144 A CN201611193144 A CN 201611193144A CN 108218307 A CN108218307 A CN 108218307A
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CN
China
Prior art keywords
concrete
sea sand
sand
particle
marine
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201611193144.9A
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Chinese (zh)
Inventor
张崇凤
赵岩
张志伟
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Dalian University of Technology
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Dalian University of Technology
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Filing date
Publication date
Application filed by Dalian University of Technology filed Critical Dalian University of Technology
Priority to CN201611193144.9A priority Critical patent/CN108218307A/en
Publication of CN108218307A publication Critical patent/CN108218307A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B20/00Use of materials as fillers for mortars, concrete or artificial stone according to more than one of groups C04B14/00 - C04B18/00 and characterised by shape or grain distribution; Treatment of materials according to more than one of the groups C04B14/00 - C04B18/00 specially adapted to enhance their filling properties in mortars, concrete or artificial stone; Expanding or defibrillating materials
    • C04B20/02Treatment
    • C04B20/04Heat treatment
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/20Resistance against chemical, physical or biological attack
    • C04B2111/24Sea water resistance

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Curing Cements, Concrete, And Artificial Stone (AREA)

Abstract

The present invention relates to a kind of ocean engineering marine sand concretes, belong to building material field.Sea sand used in the concrete is pre-processed as follows:It is dry after sea sand is cleaned, it is stood after 1~6h will be handled at sea sand and rubber powder mixing and ball milling, with 150~200 DEG C;Then crushed, it is levigate, obtain the particle that average grain diameter is less than 100 microns;Gained particle is mixed with EPS particles;The mixture of gained is subjected to ball milling, 2~12h of Ball-milling Time obtains clinker sea sand.The marine sand concrete is the concrete of chloride-penetration resistance using sea sand as raw material, while overcomes the problem of sea sand chlorine ion concentration itself is high so that architectural engineering can gather materials on the spot, cost-effective.

Description

A kind of ocean engineering marine sand concrete
Technical field
The present invention relates to a kind of ocean engineering marine sand concretes, belong to building material field.
Background technology
Marine sand concrete is that sea sand pours the concrete that materials mix with other buildings.When using sea sand preparation reinforcing bar During concrete, chloride ion content should be not more than 0.06% (with the percentage of dry sand) in sea sand.The exceeded one side of chlorion has It damages in concrete in itself, it is enabled to generate microcrack;When chlorion is accumulated to a certain concentration, the passivating film of reinforcing bar will be destroyed, drawn Play steel bar corrosion;More than 10% the suitable muscle of protective layer can be caused to crack when corrosion ratio reaches, protective layer stripping, peeled off, reinforcing bar Anti-seismic performance substantially reduces.
Concrete used in ocean engineering is maritime concrete.Country does not define maritime concrete.It is generally believed that through Concrete used in being subjected to the structure that the spray splashes, all belongs to maritime concrete.Maritime concrete is high workability, high-durability Concrete.For harbour, bridge, seawater disengaging the equal concrete steel building such as reinforced concrete pipiline, a large amount of chlorine from After son is penetrated into concrete, meeting corrosion reinforcing bar leads to the damage of building, safety that is heavy then destroying building, reducing it makes Use the service life.Therefore, chloride-penetration resistance effect is one of very important technical indicator of maritime concrete.
Under normal circumstances, sea sand is not particularly suited for the raw material of maritime concrete, mainly since the chlorion in sea sand contains Amount is inherently high;But since sea sand is taken from marine environment, it such as can be used for the construction of ocean engineering, then can gather materials on the spot, subtract Few a large amount of landed costs.
Invention content
The object of the present invention is to provide ocean engineering marine sand concrete, which, using sea sand as raw material, is anti- The concrete of chloride permeability, while overcome the problem of sea sand chlorine ion concentration itself is high so that architectural engineering can take on the spot Material, it is cost-effective.
A kind of ocean engineering marine sand concrete, sea sand used in the concrete are pre-processed as follows:
It is dry after sea sand is cleaned, after 1~6h is handled at sea sand and rubber powder mixing and ball milling, with 150~200 DEG C It stands;Then crushed, it is levigate, obtain the particle that average grain diameter is less than 100 microns;Gained particle is mixed with EPS particles; The mixture of gained is subjected to ball milling, 2~12h of Ball-milling Time obtains clinker sea sand.
Further, the marine sand concrete is made of following components:Cement 50~60%, clinker sea sand 10~15%, Clay 20~30%, nano kaoline particle 1~3%, water-reducing agent 1~3%, the ratio of mud are 0.35~0.6.
Further, the grain size of the EPS particles is 20~200 microns.
Further, the concrete is prepared as follows:Nano kaoline particle is subjected to ultrasonic disperse in water 15~30min;By cement 50~60%, clinker sea sand 10~15%, clay 20~30%, after water-reducing agent 1~3% is mixed with water It stirs evenly to be placed in mold and be conserved, 0.5~6h of curing time obtains preforming slurry;By preforming slurry and nanometer The outstanding mixed liquid mixing of kaolin particle, then conserved, conserve 7~28d.
Beneficial effects of the present invention are:Ocean engineering marine sand concrete provided by the invention, sea used in the concrete Sand is pre-processed as follows:It is dry after sea sand is cleaned, by sea sand and rubber powder mixing and ball milling, with 150~200 It is stood after handling 1~6h at DEG C;Then crushed, it is levigate, obtain the particle that average grain diameter is less than 100 microns;By gained Grain is mixed with EPS particles;The mixture of gained is subjected to ball milling, 2~12h of Ball-milling Time obtains clinker sea sand.The marine sand concrete Using sea sand as raw material, it is the concrete of chloride-penetration resistance, while overcomes the problem of sea sand chlorine ion concentration itself is high so that Architectural engineering can gather materials on the spot, cost-effective.
Specific embodiment
Following non-limiting examples can make those of ordinary skill in the art be more fully understood the present invention, but not with Any mode limits the present invention.
Test method described in following embodiments is conventional method unless otherwise specified;The reagent and material, such as Without specified otherwise, commercially obtain.
Embodiment 1
A kind of ocean engineering marine sand concrete, sea sand used in the concrete are pre-processed as follows:It will be extra large It is dry after sand washing is net, it is stood after 2h will be handled at sea sand and rubber powder mixing and ball milling, with 180 DEG C;It is then crushed, is ground Carefully, the particle that average grain diameter is less than 100 microns is obtained;Gained particle is mixed with EPS particles, the grain size of the EPS particles is 50~80 microns;The mixture of gained is subjected to ball milling, Ball-milling Time 6h obtains clinker sea sand.
Nano kaoline particle is subjected to ultrasonic disperse 15min in water;By cement 55%, clinker sea sand 15%, clay 25%, water-reducing agent 3% is stirred evenly to be placed in mold after mixing with water and be conserved, the ratio of mud 0.51, curing time 1.5h obtain preforming slurry;Preforming slurry with the outstanding mixed liquid of nano kaoline particle (2%) is mixed, then conserved, is supported Protect 14d.
Embodiment 2
A kind of ocean engineering marine sand concrete, sea sand used in the concrete are pre-processed as follows:It will be extra large It is dry after sand washing is net, it is stood after 2h will be handled at sea sand and rubber powder mixing and ball milling, with 180 DEG C;It is then crushed, is ground Carefully, the particle that average grain diameter is less than 100 microns is obtained;Gained particle is mixed with EPS particles, the grain size of the EPS particles is 50~80 microns;The mixture of gained is subjected to ball milling, Ball-milling Time 6h obtains clinker sea sand.
Nano kaoline particle is subjected to ultrasonic disperse 15min in water;By cement 60%, clinker sea sand 15%, clay 20%, water-reducing agent 2% is stirred evenly to be placed in mold after mixing with water and be conserved, the ratio of mud 0.59, curing time 2h, Obtain preforming slurry;Preforming slurry with the outstanding mixed liquid of nano kaoline particle (3%) is mixed, then conserved, is conserved 14d。

Claims (4)

1. a kind of ocean engineering marine sand concrete, it is characterised in that:Sea sand used in the concrete carries out pre- as follows Processing:
It is dry after sea sand is cleaned, it is stood after 1~6h will be handled at sea sand and rubber powder mixing and ball milling, with 150~200 DEG C; Then crushed, it is levigate, obtain the particle that average grain diameter is less than 100 microns;Gained particle is mixed with EPS particles;By institute The mixture obtained carries out ball milling, and 2~12h of Ball-milling Time obtains clinker sea sand.
2. marine sand concrete according to claim 1, it is characterised in that:The marine sand concrete is made of following components: Cement 50~60%, clinker sea sand 10~15%, clay 20~30%, nano kaoline particle 1~3%, water-reducing agent 1~3%, The ratio of mud is 0.35~0.6.
3. marine sand concrete according to claim 1, it is characterised in that:The grain size of the EPS particles is micro- for 20~200 Rice.
4. marine sand concrete according to claim 1, it is characterised in that:The concrete is prepared as follows:
Nano kaoline particle is subjected to 15~30min of ultrasonic disperse in water;By cement 50~60%, clinker sea sand 10~ 15%, clay 20~30%, water-reducing agent 1~3% is stirred evenly to be placed in mold after mixing with water and be conserved, curing time 0.5~6h obtains preforming slurry;Preforming slurry with the outstanding mixed liquid of nano kaoline particle is mixed, then conserved, is conserved 7~28d.
CN201611193144.9A 2016-12-21 2016-12-21 A kind of ocean engineering marine sand concrete Pending CN108218307A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201611193144.9A CN108218307A (en) 2016-12-21 2016-12-21 A kind of ocean engineering marine sand concrete

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201611193144.9A CN108218307A (en) 2016-12-21 2016-12-21 A kind of ocean engineering marine sand concrete

Publications (1)

Publication Number Publication Date
CN108218307A true CN108218307A (en) 2018-06-29

Family

ID=62656028

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201611193144.9A Pending CN108218307A (en) 2016-12-21 2016-12-21 A kind of ocean engineering marine sand concrete

Country Status (1)

Country Link
CN (1) CN108218307A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110642579A (en) * 2019-11-14 2020-01-03 广西云燕特种水泥建材有限公司 Marine sulphoaluminate cement for rapid construction and preparation method thereof
CN110698142A (en) * 2019-11-14 2020-01-17 广西云燕特种水泥建材有限公司 Antifouling corrosion-resistant marine cement and preparation method thereof

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110642579A (en) * 2019-11-14 2020-01-03 广西云燕特种水泥建材有限公司 Marine sulphoaluminate cement for rapid construction and preparation method thereof
CN110698142A (en) * 2019-11-14 2020-01-17 广西云燕特种水泥建材有限公司 Antifouling corrosion-resistant marine cement and preparation method thereof

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Application publication date: 20180629