CN108214338A - A kind of production technology of interface modification type high-strength environment-friendly heavy duty grinding wheel - Google Patents

A kind of production technology of interface modification type high-strength environment-friendly heavy duty grinding wheel Download PDF

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Publication number
CN108214338A
CN108214338A CN201711370422.8A CN201711370422A CN108214338A CN 108214338 A CN108214338 A CN 108214338A CN 201711370422 A CN201711370422 A CN 201711370422A CN 108214338 A CN108214338 A CN 108214338A
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China
Prior art keywords
grinding wheel
heavy duty
abrasive material
production technology
type high
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CN201711370422.8A
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Chinese (zh)
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CN108214338B (en
Inventor
朱国乔
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Huangshan Anka Heavy Duty Wheel Co Ltd
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Huangshan Anka Heavy Duty Wheel Co Ltd
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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B24GRINDING; POLISHING
    • B24DTOOLS FOR GRINDING, BUFFING OR SHARPENING
    • B24D18/00Manufacture of grinding tools or other grinding devices, e.g. wheels, not otherwise provided for
    • B24D18/0009Manufacture of grinding tools or other grinding devices, e.g. wheels, not otherwise provided for using moulds or presses
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B24GRINDING; POLISHING
    • B24DTOOLS FOR GRINDING, BUFFING OR SHARPENING
    • B24D3/00Physical features of abrasive bodies, or sheets, e.g. abrasive surfaces of special nature; Abrasive bodies or sheets characterised by their constituents
    • B24D3/02Physical features of abrasive bodies, or sheets, e.g. abrasive surfaces of special nature; Abrasive bodies or sheets characterised by their constituents the constituent being used as bonding agent
    • B24D3/20Physical features of abrasive bodies, or sheets, e.g. abrasive surfaces of special nature; Abrasive bodies or sheets characterised by their constituents the constituent being used as bonding agent and being essentially organic
    • B24D3/28Resins or natural or synthetic macromolecular compounds
    • B24D3/285Reaction products obtained from aldehydes or ketones
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B24GRINDING; POLISHING
    • B24DTOOLS FOR GRINDING, BUFFING OR SHARPENING
    • B24D3/00Physical features of abrasive bodies, or sheets, e.g. abrasive surfaces of special nature; Abrasive bodies or sheets characterised by their constituents
    • B24D3/34Physical features of abrasive bodies, or sheets, e.g. abrasive surfaces of special nature; Abrasive bodies or sheets characterised by their constituents characterised by additives enhancing special physical properties, e.g. wear resistance, electric conductivity, self-cleaning properties
    • B24D3/342Physical features of abrasive bodies, or sheets, e.g. abrasive surfaces of special nature; Abrasive bodies or sheets characterised by their constituents characterised by additives enhancing special physical properties, e.g. wear resistance, electric conductivity, self-cleaning properties incorporated in the bonding agent
    • B24D3/344Physical features of abrasive bodies, or sheets, e.g. abrasive surfaces of special nature; Abrasive bodies or sheets characterised by their constituents characterised by additives enhancing special physical properties, e.g. wear resistance, electric conductivity, self-cleaning properties incorporated in the bonding agent the bonding agent being organic

Abstract

The present invention provides a kind of production technology of interface modification type high-strength environment-friendly heavy duty grinding wheel, abrasive material and auxiliary material are subjected to nano modification processing, inorganic agent is nanometer is siliceous and carbonaceous particle.By calcareous, magnesia compound and active carbon particle and the abrasive material of modification, auxiliary material and resin-oatmeal blending.The present invention realize the high intensity of heavy duty grinding wheel, odorlessness, ultralow stomata, high grinding performance outstanding advantage, product is made to catch up with and surpass Japan and the U.S., is reached the international leading level.

Description

A kind of production technology of interface modification type high-strength environment-friendly heavy duty grinding wheel
Technical field
The invention belongs to grinding wheel production fields, and in particular to a kind of life of interface modification type high-strength environment-friendly heavy duty grinding wheel Production. art.
Background technology
At present, the common heavy duty grinding wheel of domestic manufacturer's production is carried out simply using resin, abrasive material and auxiliary material Hot pressing, intensity, grinding performance be not relatively high, and produce during can generate ammonia seriously pollute environment, damage worker's body be good for Health;And since the linear velocity that heavy duty grinding wheel uses reaches 80m/s, and need that the pressure of 10000N is added to carry out in use Grinding, product strength is slightly unqualified, and great safety accident will be caused to occur, and equipment and people can all be caused greatly to hinder Evil.
And enter with the advantage of external product, home products either safety or product are used in cost performance all It is nothing like external product, more than 80% market is all captured by external product, and it is horizontal how to greatly improve domestic heavy duty grinding wheel It has been the key point of domestic manufacturer's final and decisive juncture.
Invention content
The invention mainly solves the technical problem of providing a kind of lifes of interface modification type high-strength environment-friendly heavy duty grinding wheel Production. art, the technology production heavy duty grinding wheel can be effectively improved existing grinding wheel intensity it is low, grinding performance is poor, environment Pollution, the shortcomings of security risk is high.
Abrasive material and auxiliary material are carried out nano modification by a kind of production technology of interface modification type high-strength environment-friendly heavy duty grinding wheel Processing, inorganic agent is nanometer is siliceous and carbonaceous particle.
A kind of production technology of interface modification type high-strength environment-friendly heavy duty grinding wheel, by calcareous or magnesia compound and activity The charcoal particle and abrasive material of modification, auxiliary material and resin-oatmeal are blended.
A kind of production technology of interface modification type high-strength environment-friendly heavy duty grinding wheel, which is characterized in that step is as follows:
(1)Abrasive material and auxiliary material are subjected to nano modification processing, inorganic agent is nanometer is siliceous and carbonaceous particle;
(2)Resin-oatmeal and abrasive material auxiliary material are blended 15 minutes at a high speed, resin-oatmeal is made adequately to be wrapped in abrasive surface, auxiliary material is uniform Be dispersed between resin and abrasive material;
(3)Calcareous or magnesia compound and active carbon particle are poured into and are blended with other powders;
(4)Mixed final powder is poured into high-strength die, by the pressure of 50-80Mpa, 180-200 DEG C of temperature into Row hot pressed sintering, sintering time are 30-40 minutes;
(5)Cryogenic gas or liquid will be sprayed after the product stripping sintered, refine product grains;
(6)Grinding wheel stands 24-36 hours after cooling;
(7)Grinding wheel, which is put into baking oven, after standing carries out secondary curing, and solidification temperature is 180-200 DEG C, and the time is 5-7 hours;
(8)It is finished after curing, balance test;
(9)Product passes through packaging and storage after 2.05 times of rotary safeties (domestic standard is 1.5 times, and international standard is 2.05 times).
Further, the abrasive material is one or more of fused alumina zirconia, Brown Alundum, single alundum.
Further, the auxiliary material is one or more of ice crystal, iron sulfide, calcium sulfate.
Further, nanometer siliceous particles are nanometer aluminium silicate, and carbonaceous particle is nanometer silicon carbide;
Further, modification processing method is as follows:Nanometer aluminium silicate, nanometer silicon carbide are poured into the silane coupled of abrasive material weight 1-3% It is stirred in agent solution, then solution is added in blender and is mixed 15 minutes with abrasive material, auxiliary material;Alumina silicate and two kinds of objects of silicon carbide The ratio of matter is 3:1-5:1, account for the 1-2% of abrasive material weight.
Further, the calcareous compound is one or both of calcium oxide, calcium carbonate, calcium sulfate, calcium chloride, is accounted for The 2-7% of abrasive material weight.
Further, the magnesia compound is one or both of magnesium sulfate, magnesium chloride, magnesia, magnesium carbonate, is accounted for The 2-10% of abrasive material weight.
Further, the 2-5% of the active carbon particle abrasive material weight.
Further, the cryogenic gas is one or both of nitrogen, carbon dioxide, argon gas;The cryogenic liquid is The compound of water or water.
The present invention carries out surface modification using the principle of interface cohesion to abrasive material and auxiliary material, in enhancing abrasive material, auxiliary material and tree It is absorbed while cosmetics interface bond strength and decomposes gas and moisture that resin generates in the curing process.
The technique mainly has three dot characteristics:
1st, high interfacial bonding strength.Nanometer aluminium silicate, nanometer silicon carbide, which are used together, makes abrasive material and resin more secured in combination While improve combination interface heat resistance and inoxidizability.Abrasive material is made to be greatly improved with resin bonding strength using the principle, The tension and impact strength of product can obtain the promotion of 7-12%.
2nd, zero exhaust gas discharges, 0.3% ultralow-porosity.Three kinds of calcareous compound, magnesia compound, active carbon particle materials Material uses adsorbable thermoplastic resin(Such as phenolic aldehyde)The ammonia and moisture discharged in the curing process, predominantly chemical reaction are inhaled It is attached, it is on a small quantity physical absorption.The exhaust gas discharge in production process can be effectively reduced in this way, while reduces the porosity of grinding wheel, Improve wheel strength and abrasion resistance.This technique is than the high 12-23% of grinding performance of conventional heavy duty grinding wheel(Product gas porosity exists Less than 7% heavy duty grinding wheel, 3-4% can be promoted by often reducing by 1% porosity product grinding performance).
3rd, high intensity, odorlessness, ultralow stomata, the protrusion of high grinding performance of the invention for realizing heavy duty grinding wheel is excellent Gesture makes product catch up with and surpass Japan and the U.S., reaches the international leading level.
Specific embodiment
In the following, in conjunction with the embodiments, it is aobvious that the present invention will be further described.
Embodiment 1
Grinding wheel is mixed and made into using following components:Fused alumina zirconia 35kg, Brown Alundum 5kg, phenol-formaldehyde resin powder 6kg, ice crystal 5kg, sulphur Change iron 5kg, nanometer aluminium silicate particle 0.3kg, nano silicon carbide granulate 0.3kg, calcium oxide 1kg, calcium carbonate 1kg, magnesium sulfate 0.5kg, magnesium chloride 0.7kg, active carbon particle 1kg.
Nanometer aluminium silicate particle, nano silicon carbide granulate in 2% silane coupler solution are stirred, then adds in and stirs It mixes in machine and is mixed 15 minutes with fused alumina zirconia, Brown Alundum, ice crystal, iron sulfide;Then phenol-formaldehyde resin powder is added in be blended 15 minutes;It will Calcium oxide, magnesium chloride, active carbon particle are poured into be blended with other powders;Mixed final powder is poured into high-strength die, Hot pressed sintering is carried out by the pressure of 70Mpa, 185 DEG C of temperature, sintering time is 35 minutes;After the product stripping sintered Cryogenic gas or liquid are sprayed, refines product grains;Grinding wheel stands 30 hours after cooling;After standing grinding wheel be put into baking oven into Row secondary curing, solidification temperature are 195 DEG C, and the time is 6 hours;It is finished after curing, balance test;Product passes through 2.05 Packaging and storage after times rotary safety.
Embodiment 2
Grinding wheel is mixed and made into using following components:Fused alumina zirconia 37kg, Brown Alundum 3kg, phenol-formaldehyde resin powder 5.8kg, ice crystal 5kg, Iron sulfide 5kg, nanometer aluminium silicate particle 0.2kg, nano silicon carbide granulate 0.4kg, calcium oxide 1.6kg, calcium carbonate 1.1kg, sulphur Sour magnesium 1.6kg, magnesium chloride 1.4kg, active carbon particle 0.9kg.
Nanometer aluminium silicate particle, nano silicon carbide granulate in 2% silane coupler solution are stirred, then adds in and stirs It mixes in machine and is mixed 15 minutes with fused alumina zirconia, Brown Alundum, ice crystal, iron sulfide;Then phenol-formaldehyde resin powder is added in be blended 15 minutes;It will Calcium oxide, magnesium chloride, active carbon particle are poured into be blended with other powders;Mixed final powder is poured into high-strength die, Hot pressed sintering is carried out by the pressure of 78Mpa, 185 DEG C of temperature, sintering time is 40 minutes;After the product stripping sintered Cryogenic gas or liquid are sprayed, refines product grains;Grinding wheel stands 29 hours after cooling;After standing grinding wheel be put into baking oven into Row secondary curing, solidification temperature are 195 DEG C, and the time is 5.5 hours;It is finished after curing, balance test;Product passes through Packaging and storage after 2.05 times of rotary safeties.
Embodiment 3
Grinding wheel is mixed and made into using following components:Fused alumina zirconia 30kg, Brown Alundum 10kg, phenol-formaldehyde resin powder 6.3kg, ice crystal 4.7kg, iron sulfide 5.6kg, nanometer aluminium silicate particle 0.4kg, nano silicon carbide granulate 0.2kg, calcium oxide 1.2kg, calcium carbonate 0.7kg, magnesium sulfate 1.1kg, magnesium chloride 1.3kg, active carbon particle 1.6kg.
Nanometer aluminium silicate particle, nano silicon carbide granulate in 2% silane coupler solution are stirred, then adds in and stirs It mixes in machine and is mixed 15 minutes with fused alumina zirconia, Brown Alundum, ice crystal, iron sulfide;Then phenol-formaldehyde resin powder is added in be blended 15 minutes;It will Calcium oxide, magnesium chloride, active carbon particle are poured into be blended with other powders;Mixed final powder is poured into high-strength die, Hot pressed sintering is carried out by the pressure of 75Mpa, 180 DEG C of temperature, sintering time is 32 minutes;After the product stripping sintered Cryogenic gas or liquid are sprayed, refines product grains;Grinding wheel stands 33 hours after cooling;After standing grinding wheel be put into baking oven into Row secondary curing, solidification temperature are 190 DEG C, and the time is 6.2 hours;It is finished after curing, balance test;Product passes through Packaging and storage after 2.05 times of rotary safeties.
Embodiment 4
Grinding wheel is mixed and made into using following components:Fused alumina zirconia 33kg, single alundum 7kg, phenol-formaldehyde resin powder 6.1kg, ice crystal 5kg, iron sulfide 5.6kg, nanometer aluminium silicate particle 0.2kg, nano silicon carbide granulate 0.2kg, calcium oxide 1.3kg, calcium carbonate 0.7kg, magnesium sulfate 1kg, magnesium chloride 1.2kg, active carbon particle 1.4kg.
Nanometer aluminium silicate particle, nano silicon carbide granulate in 2% silane coupler solution are stirred, then adds in and stirs It mixes in machine and is mixed 15 minutes with fused alumina zirconia, single alundum, ice crystal, iron sulfide;Then phenol-formaldehyde resin powder is added in be blended 15 minutes; Calcium oxide, magnesium chloride, active carbon particle are poured into and are blended with other powders;Mixed final powder is poured into high-strength die It is interior, hot pressed sintering is carried out by the pressure of 68Mpa, 192 DEG C of temperature, sintering time is 32 minutes;The product sintered is taken off Cryogenic gas or liquid are sprayed after mould, refines product grains;Grinding wheel stands 35 hours after cooling;Grinding wheel is put into baking oven after standing Middle carry out secondary curing, solidification temperature are 200 DEG C, and the time is 6 hours;It is finished after curing, balance test;Product passes through Packaging and storage after 2.05 times of rotary safeties.
Grinding wheel made from above example 1-4 techniques is mounted on the high speed grinding machine of polishing steel billet, and grinding wheel uses linear velocity For 80m/s, operating pressure 10000N.The results are shown in table below for grinding.
Embodiment 1 Embodiment 2 Embodiment 3 Embodiment 4 Domestic plain wheel External advanced grinding wheel
Grinding ratio 68 70 69 71 38-42 65-68
As seen from the above table, grinding wheel performance of the present invention is excellent, and remote super domestic common heavy duty grinding wheel reaches external and first intakes Flat, practical value is big.
All above-mentioned this intellectual properties of primarily implementation, there is no this new products of implementation of setting limitation other forms And/or new method.Those skilled in the art will utilize this important information, the above modification, to realize similar execution feelings Condition.But all modifications or transformation belong to the right of reservation based on new product of the present invention.
The above described is only a preferred embodiment of the present invention, being not that the invention has other forms of limitations, appoint What those skilled in the art changed or be modified as possibly also with the technology contents of the disclosure above equivalent variations etc. Imitate embodiment.But it is every without departing from technical solution of the present invention content, technical spirit according to the present invention is to above example institute Any simple modification, equivalent variations and the remodeling made still fall within the protection domain of technical solution of the present invention.

Claims (10)

1. a kind of production technology of interface modification type high-strength environment-friendly heavy duty grinding wheel, which is characterized in that by abrasive material and auxiliary material into The processing of row nano modification, inorganic agent is nanometer is siliceous and carbonaceous particle.
2. a kind of production technology of interface modification type high-strength environment-friendly heavy duty grinding wheel according to claim 1, feature It is, calcareous, magnesia compound and active carbon particle and the abrasive material of modification, auxiliary material and resin-oatmeal is blended.
3. a kind of production technology of interface modification type high-strength environment-friendly heavy duty grinding wheel, which is characterized in that step is as follows:
(1)Abrasive material and auxiliary material are subjected to nano modification processing, inorganic agent is nanometer is siliceous and carbonaceous particle;
(2)Resin-oatmeal and abrasive material auxiliary material are blended 15 minutes at a high speed, resin-oatmeal is made adequately to be wrapped in abrasive surface, auxiliary material is uniform Be dispersed between resin and abrasive material;
(3)Calcareous, magnesia compound and active carbon particle are poured into and are blended with other powders;
(4)Mixed final powder is poured into high-strength die, by the pressure of 50-80Mpa, 180-200 DEG C of temperature into Row hot pressed sintering, sintering time are 30-40 minutes;
(5)Cryogenic gas or liquid will be sprayed after the product stripping sintered, refine product grains;
(6)Grinding wheel stands 24-36 hours after cooling;
(7)Grinding wheel, which is put into baking oven, after standing carries out secondary curing, and solidification temperature is 180-200 DEG C, and the time is 5-7 hours;
(8)It is finished after curing, balance test;
(9)Product passes through packaging and storage after 2.05 times of rotary safeties.
4. a kind of production technology of interface modification type high-strength environment-friendly heavy duty grinding wheel according to claim 1 or 3, special Sign is that the abrasive material is one or more of fused alumina zirconia, Brown Alundum, single alundum.
5. a kind of production technology of interface modification type high-strength environment-friendly heavy duty grinding wheel according to claim 1 or 3, special Sign is that the auxiliary material is one or more of ice crystal, iron sulfide, calcium sulfate.
6. a kind of production technology of interface modification type high-strength environment-friendly heavy duty grinding wheel according to claim 1 or 3, special Sign is that nanometer siliceous particles are nanometer aluminium silicate, and carbonaceous particle is nanometer silicon carbide.
7. a kind of production technology of interface modification type high-strength environment-friendly heavy duty grinding wheel according to claim 4, feature It is, modification processing method is as follows:Nanometer aluminium silicate, nanometer silicon carbide are poured into the silane coupler solution of abrasive material weight 1-3% Then solution is added in blender and is mixed 15 minutes with abrasive material, auxiliary material by middle stirring;The ratio of two kinds of substances of alumina silicate and silicon carbide Example is 3:1-5:1, account for the 1-2% of abrasive material weight.
8. a kind of production technology of interface modification type high-strength environment-friendly heavy duty grinding wheel according to claim 1 or 3, special Sign is that the calcareous compound is one or both of calcium oxide, calcium carbonate, calcium sulfate, calcium chloride, accounts for abrasive material weight 2-7%.
9. a kind of production technology of interface modification type high-strength environment-friendly heavy duty grinding wheel according to claim 1 or 3, special Sign is that the magnesia compound is one or both of magnesium sulfate, magnesium chloride, magnesia, magnesium carbonate, accounts for abrasive material weight 2-10%.
10. a kind of production technology of interface modification type high-strength environment-friendly heavy duty grinding wheel according to claim 1 or 3, It is characterized in that, the 2-5% of the active carbon particle abrasive material weight.
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