CN108212101A - A kind of diesel oil adsorption desulfurizing desulfurizing agent - Google Patents
A kind of diesel oil adsorption desulfurizing desulfurizing agent Download PDFInfo
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- CN108212101A CN108212101A CN201810120229.7A CN201810120229A CN108212101A CN 108212101 A CN108212101 A CN 108212101A CN 201810120229 A CN201810120229 A CN 201810120229A CN 108212101 A CN108212101 A CN 108212101A
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- Prior art keywords
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- diesel oil
- desulfurizing
- oil adsorption
- desulfurizing agent
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/20—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising free carbon; comprising carbon obtained by carbonising processes
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/0203—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of metals not provided for in B01J20/04
- B01J20/0225—Compounds of Fe, Ru, Os, Co, Rh, Ir, Ni, Pd, Pt
- B01J20/0229—Compounds of Fe
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/0203—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of metals not provided for in B01J20/04
- B01J20/024—Compounds of Zn, Cd, Hg
- B01J20/0244—Compounds of Zn
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/22—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising organic material
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G25/00—Refining of hydrocarbon oils in the absence of hydrogen, with solid sorbents
- C10G25/003—Specific sorbent material, not covered by C10G25/02 or C10G25/03
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/20—Characteristics of the feedstock or the products
- C10G2300/201—Impurities
- C10G2300/202—Heteroatoms content, i.e. S, N, O, P
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
- C10G2400/04—Diesel oil
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Analytical Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- General Chemical & Material Sciences (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
Abstract
The invention belongs to Diesel fuel desulfurization technologies fields, and in particular to a kind of diesel oil adsorption desulfurizing desulfurizing agent.The diesel oil adsorption desulfurizing desulfurizing agent, including following substance：Frerrous chloride；Ferrous sulfate；Zinc oxide；Triethylene diamine；Ammonium hydroxide；Aminobenzene；Active powdered carbon.Advantage is：A kind of diesel oil adsorption desulfurizing desulfurizing agent low manufacture cost of the present invention can remove sulphur in the case where influencing minimum to the octane number of treated object from diesel oil, and available for the desulfuration purification of a variety of diesel oil, removal efficiency is high, easy to operate.
Description
Technical field
The invention belongs to Diesel fuel desulfurization technologies fields, and in particular to a kind of diesel oil adsorption desulfurizing desulfurizing agent.
Background technology
Sulphur in diesel oil mainly exists in the form of mercaptan, thioether, thiophene and thiophene derivant, accounts for total sulfur content in diesel oil
More than 85%.More and more stringenter to transporting the requirement of fuel sulfur content in environmental legislation, this causes deep from diesel fuel
Desulfurization is spent into a more and more important research topic.
Invention content
In order to compensate for the shortcomings of the prior art, the present invention provides a kind of diesel oil adsorption desulfurizing desulfurizing agents.
The present invention is achieved through the following technical solutions：
A kind of diesel oil adsorption desulfurizing desulfurizing agent, raw material form in mass ratio：9-15 parts of frerrous chloride；Ferrous sulfate
10-18 parts；10-25 parts of zinc oxide；9-15 parts of triethylene diamine；0.5-1.2 parts of ammonium hydroxide；40-50 parts of aminobenzene；Active powdered carbon
50-80 parts.
It is by the method that the present invention is made in above-mentioned each substance：
1) frerrous chloride, ferrous sulfate, zinc oxide, triethylene diamine and active powdered carbon are carried out being mixed to prepare mixing powder by；
2) is by step 1）In mixing powder be mixed with aminobenzene；Ammonium hydroxide is added in later is warming up to the reaction of 45-95 degree
Mixed solvent is made；
3) mixed solvent obtained in step 2) is carried out drawing liquid filtering and drying by, and wherein drying temperature is 110 DEG C, when dry
Between 1-2.5h both.
The beneficial effects of the invention are as follows：A kind of diesel oil adsorption desulfurizing desulfurizing agent low manufacture cost of the present invention, can be to quilt
The octane number of processed material influences to remove sulphur from diesel oil in the case of minimum, available for the desulfuration purification of a variety of diesel oil, removing effect
Rate is high, easy to operate.
Specific embodiment
Specific embodiments of the present invention are given below, are further described for the composition to the present invention.
Embodiment 1
A kind of diesel oil adsorption desulfurizing desulfurizing agent of the present invention, raw material form in mass ratio：9 parts of frerrous chloride；Sulfuric acid is sub-
10 parts of iron；10 parts of zinc oxide；9 parts of triethylene diamine；0.5 part of ammonium hydroxide；40 parts of aminobenzene；Active 50 parts of powdered carbon.
It is by the method that the present invention is made in above-mentioned each substance：
1) carries out 50 parts of 9 parts of frerrous chloride, 10 parts of ferrous sulfate, 10 parts of zinc oxide, 9 parts of triethylene diamine and active powdered carbon
It is mixed to prepare mixing powder；
2) is by step 1）In mixing powder be mixed for 40 parts with aminobenzene；Ammonium hydroxide is added in later is warming up to 45-95 degree
Mixed solvent is made in reaction；
3) mixed solvent obtained in step 2) is carried out drawing liquid filtering and drying by, and wherein drying temperature is 110 DEG C, when dry
Between 1-2.5h both.
Embodiment 2
A kind of diesel oil adsorption desulfurizing desulfurizing agent of the present invention, raw material form in mass ratio：12 parts of frerrous chloride；Sulfuric acid is sub-
15 parts of iron；21 parts of zinc oxide；12 parts of triethylene diamine；1 part of ammonium hydroxide；45 parts of aminobenzene；Active 75 parts of powdered carbon.
It is by the method that the present invention is made in above-mentioned each substance：
1) by 75 parts of 12 parts of frerrous chloride, 15 parts of ferrous sulfate, 21 parts of zinc oxide, 12 parts of triethylene diamine and active powdered carbon into
Row is mixed to prepare mixing powder；
2) is by step 1）In mixing powder be mixed for 45 parts with aminobenzene；Ammonium hydroxide is added in later is warming up to 45-95 degree
Mixed solvent is made in reaction；
3) mixed solvent obtained in step 2) is carried out drawing liquid filtering and drying by, and wherein drying temperature is 110 DEG C, when dry
Between 1-2.5h both.
Embodiment 3
A kind of diesel oil adsorption desulfurizing desulfurizing agent of the present invention, raw material form in mass ratio：15 parts of frerrous chloride；Sulfuric acid is sub-
18 parts of iron；25 parts of zinc oxide；15 parts of triethylene diamine；1.2 parts of ammonium hydroxide；50 parts of aminobenzene；Active 80 parts of powdered carbon.
It is by the method that the present invention is made in above-mentioned each substance：
1) by 80 parts of 15 parts of frerrous chloride, 18 parts of ferrous sulfate, 25 parts of zinc oxide, 15 parts of triethylene diamine and active powdered carbon into
Row is mixed to prepare mixing powder；
2) is by step 1）In mixing powder be mixed for 50 parts with aminobenzene；Ammonium hydroxide is added in later is warming up to 45-95 degree
Mixed solvent is made in reaction；
3) mixed solvent obtained in step 2) is carried out drawing liquid filtering and drying by, and wherein drying temperature is 110 DEG C, when dry
Between 1-2.5h both.
The present invention is not limited to the above-described embodiments, anyone should learn the present invention enlightenment under make with the present invention
With same or similar technical solution, each fall within protection scope of the present invention.
The present invention be not described in detail technology, shape, construction part be known technology.
Claims (4)
- A kind of 1. diesel oil adsorption desulfurizing desulfurizing agent, which is characterized in that 9-15 parts of frerrous chloride；10-18 parts of ferrous sulfate；Oxidation 10-25 parts of zinc；9-15 parts of triethylene diamine；0.5-1.2 parts of ammonium hydroxide；40-50 parts of aminobenzene；Active powdered carbon 50-80 parts.
- 2. a kind of diesel oil adsorption desulfurizing desulfurizing agent according to claim 1, it is characterized in that：Its raw material composition is by matter Amount matches：12 parts of frerrous chloride；15 parts of ferrous sulfate；21 parts of zinc oxide；12 parts of triethylene diamine；1 part of ammonium hydroxide；Aminobenzene 45 Part；Active 75 parts of powdered carbon.
- 3. a kind of diesel oil adsorption desulfurizing desulfurizing agent according to claim 1, it is characterized in that：Its raw material composition is by matter Amount matches：15 parts of frerrous chloride；18 parts of ferrous sulfate；25 parts of zinc oxide；15 parts of triethylene diamine；1.2 parts of ammonium hydroxide；Aminobenzene 50 parts；Active 80 parts of powdered carbon.
- 4. a kind of diesel oil adsorption desulfurizing desulfurizing agent according to claim 1, it is characterized in that：This hair is made in each substance Bright method is：It is by the method that the present invention is made in above-mentioned each substance：1) frerrous chloride, ferrous sulfate, zinc oxide, triethylene diamine and active powdered carbon are carried out being mixed to prepare mixing powder by；2) mixing powder in step 1) is mixed with aminobenzene；Ammonium hydroxide is added in later is warming up to the reaction of 45-95 degree Mixed solvent is made；3) mixed solvent obtained in step 2) is carried out drawing liquid filtering and drying by, and wherein drying temperature is 110 DEG C, when dry Between 1-2.5h both.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810120229.7A CN108212101A (en) | 2018-02-07 | 2018-02-07 | A kind of diesel oil adsorption desulfurizing desulfurizing agent |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810120229.7A CN108212101A (en) | 2018-02-07 | 2018-02-07 | A kind of diesel oil adsorption desulfurizing desulfurizing agent |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN108212101A true CN108212101A (en) | 2018-06-29 |
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ID=62670712
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810120229.7A Pending CN108212101A (en) | 2018-02-07 | 2018-02-07 | A kind of diesel oil adsorption desulfurizing desulfurizing agent |
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| CN (1) | CN108212101A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110484292A (en) * | 2019-07-26 | 2019-11-22 | 天津浩创节能环保设备有限公司 | A kind of efficient diesel fuel desulfurization desulfurizing agent and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1253847A (en) * | 1998-11-13 | 2000-05-24 | 中国石油化工集团公司 | Desulfurizer for refining gas and its preparation method |
| JP2003313570A (en) * | 2002-04-19 | 2003-11-06 | Matsushita Electric Works Ltd | Method for desulfurization of liquefied petroleum gas |
| CN101850237A (en) * | 2009-04-02 | 2010-10-06 | 北京化工大学 | Preparation of diesel oil desulfurizing agents |
-
2018
- 2018-02-07 CN CN201810120229.7A patent/CN108212101A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1253847A (en) * | 1998-11-13 | 2000-05-24 | 中国石油化工集团公司 | Desulfurizer for refining gas and its preparation method |
| JP2003313570A (en) * | 2002-04-19 | 2003-11-06 | Matsushita Electric Works Ltd | Method for desulfurization of liquefied petroleum gas |
| CN101850237A (en) * | 2009-04-02 | 2010-10-06 | 北京化工大学 | Preparation of diesel oil desulfurizing agents |
Non-Patent Citations (1)
| Title |
|---|
| 吴晓东等: "《中国战略性新兴产业.新材料.稀土催化材料》", 30 June 2017, 北京：中国铁道出版社 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110484292A (en) * | 2019-07-26 | 2019-11-22 | 天津浩创节能环保设备有限公司 | A kind of efficient diesel fuel desulfurization desulfurizing agent and preparation method thereof |
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| PB01 | Publication | ||
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| SE01 | Entry into force of request for substantive examination | ||
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Application publication date: 20180629 |