CN108209897A - A kind of portable medical assistance system of wearable product - Google Patents

A kind of portable medical assistance system of wearable product Download PDF

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Publication number
CN108209897A
CN108209897A CN201810090434.3A CN201810090434A CN108209897A CN 108209897 A CN108209897 A CN 108209897A CN 201810090434 A CN201810090434 A CN 201810090434A CN 108209897 A CN108209897 A CN 108209897A
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China
Prior art keywords
layer
graphene
heart rate
added
pressure sensitive
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CN201810090434.3A
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Chinese (zh)
Inventor
周琳
陈林瑞
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Sichuan Dongding Lizhi Information Technology Co Ltd
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Sichuan Dongding Lizhi Information Technology Co Ltd
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Priority to CN201810090434.3A priority Critical patent/CN108209897A/en
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    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61BDIAGNOSIS; SURGERY; IDENTIFICATION
    • A61B5/00Measuring for diagnostic purposes; Identification of persons
    • A61B5/02Detecting, measuring or recording pulse, heart rate, blood pressure or blood flow; Combined pulse/heart-rate/blood pressure determination; Evaluating a cardiovascular condition not otherwise provided for, e.g. using combinations of techniques provided for in this group with electrocardiography or electroauscultation; Heart catheters for measuring blood pressure
    • A61B5/024Detecting, measuring or recording pulse rate or heart rate
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61BDIAGNOSIS; SURGERY; IDENTIFICATION
    • A61B5/00Measuring for diagnostic purposes; Identification of persons
    • A61B5/68Arrangements of detecting, measuring or recording means, e.g. sensors, in relation to patient
    • A61B5/6801Arrangements of detecting, measuring or recording means, e.g. sensors, in relation to patient specially adapted to be attached to or worn on the body surface
    • A61B5/6802Sensor mounted on worn items
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61BDIAGNOSIS; SURGERY; IDENTIFICATION
    • A61B5/00Measuring for diagnostic purposes; Identification of persons
    • A61B5/74Details of notification to user or communication with user or patient ; user input means
    • A61B5/746Alarms related to a physiological condition, e.g. details of setting alarm thresholds or avoiding false alarms

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  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Biomedical Technology (AREA)
  • Heart & Thoracic Surgery (AREA)
  • Veterinary Medicine (AREA)
  • Biophysics (AREA)
  • Pathology (AREA)
  • Engineering & Computer Science (AREA)
  • Public Health (AREA)
  • Physics & Mathematics (AREA)
  • Medical Informatics (AREA)
  • Molecular Biology (AREA)
  • Surgery (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Cardiology (AREA)
  • Physiology (AREA)
  • Measuring Pulse, Heart Rate, Blood Pressure Or Blood Flow (AREA)

Abstract

The present invention overcome traditional heart rate sensor particularly graphene sensing heart rate system the defects of, provide it is a kind of have that range ability is big, the portable medical assistance system towards wearable product of high sensitivity.The assistance system includes graphene sensing heart rate system.The sensor-based system has the advantages that flexibility is high, and manufacture craft is simple, and production scale is big, at low cost.Graphene heart rate sensor proposed in this paper has outstanding sensitivity and larger working range, can have the good linearity in the range of compared with low pressure and higher pressure.

Description

A kind of portable medical assistance system of wearable product
Technical field
The invention belongs to sensor fields, and in particular to a kind of portable medical assistance system of wearable product.
Background technology
Flexible mechanics device received the extensive concern of academia and industrial circle in recent years.Compared to conventional rigid substrate device Part, flexible mechanics device greatly improve the deformability of device on the basis of performance is not sacrificed, so as to adapt to Increasingly complex application scenarios are especially suitable for wearable application.Graphene is to be stripped out from graphite, be made of carbon atom Only one layer of atomic thickness two dimensional crystal.It is it is found that the first by individual layer atomic building material.Graphene Although very thin, but very tough material, meanwhile, it has good elasticity again, and stretch range can reach own dimensions 20%.Grapheme material has had benefited from the characteristics such as its unique electricity, mechanics, has been widely used in since 2004 are found In flexible mechanics device, graphene mechanics device has very high sensitivity.However, there is system in existing graphene mechanics sensor Standby complex process, shortcomings and the problem such as repeatability is poor with consistency, yields is low.Traditional pressure sensor cannot be real simultaneously Existing highly sensitive and big working range, cause its application it is limited.There is an urgent need to develop novel pressure sensor, in spirit Sensitivity and two aspect of working range make a breakthrough simultaneously.
At present there are many pressure sensor using graphene, 2012, A.D.Smith et al. completely proposed suspension The structure of graphene pressure sensor, as shown in Figure 1, and in the pressure sensor, due to silica and silicon carbide substrate Property can not show a candle to the inwardness of graphene, this can generate limitation to the structure of sensor with function.And by film thickness shadow It rings, it typically is thousands of times of single-layer graphene thickness, transducer sensitivity is also impacted, and low-pressure field does not apply to.
O.K.Kwon et al. proposes modified deflocculated graphite alkene pressure sensor, as shown in the figure, this pressure sensor A top plate with cylindrical supporting leg is increased, the pressure acted on graphene film by supporting leg transmission will become rapidly Greatly.This follow-on pressure sensor can be used for low pressure to detect environment, and sensitivity is high, and the low pressure range linearity is fine, But the drawback is that the high pressure range linearity is poor, and structure size is more than general deflocculated graphite alkene pressure sensor.
J.Ma et al. has studied a kind of optical fiber graphene pressure sensor, is by vitreous silica capillary to single-mode optics Fine end applies air pressure postcapillary in inside and is tapered, then melts capillary and form air cavity.Graphene film covers On cylindrical cavity, external pressure variation can be not only detected, and sealing function can be played to cavity.This pressure passes Sensor is compact-sized, and mechanical strength is good.But shortcoming is that operating pressure is relatively low, and pressure-sensitivity is not high, gas in sealing cavity Have minor leakage.
Invention content
In view of above analysis, it is a primary object of the present invention to provide a kind of big, face of high sensitivity with range ability To the portable medical assistance system of wearable product.The assistance system includes graphene sensing heart rate system.The sensor-based system has Have flexibility high, manufacture craft is simple, and production scale is big, it is at low cost the advantages that.Graphene sensing heart rate utensil proposed in this paper There are outstanding sensitivity and larger working range, there can be the good linearity in the range of compared with low pressure and higher pressure.
The purpose of the present invention is what is be achieved through the following technical solutions.
A kind of portable medical assistance system of wearable product, including graphene sensing heart rate system, data transmission system And alarm system.
Further, the graphene sensing heart rate system includes multilayered structure, is from top to bottom substrate layer successively, pressure-sensitive Material layer, basal layer.
Further, the first pressure sensitivity electrode layer is additionally provided in the substrate layer and layer of pressure sensitive, described pressure-sensitive The second pressure sensitivity electrode layer is additionally provided in material layer and basal layer.
Further, the layer of pressure sensitive is made of graphene.
Further, the pressure sensitivity electrode layer is metal conductive oxide layer.
Further, the substrate layer and basal layer are the poroid tissue layer of elasticity.
Further, the specific forming step of the layer of pressure sensitive is:By beaker as in cold water, the dense sulphur of 23ml is added in Acid, controlled at 0 DEG C;It is added with stirring the solid mixture of 1g graphite powders and 0.5g sodium nitrate;Add in 3g Gao Meng by several times again Sour potassium, controlling reaction temperature are no more than 20 DEG C;Potassium permanganate removes water-bath after adding, and is then heated to 35 DEG C or so, continues to stir 30min is mixed, is slow added into deionized water, is heated at high temperature 90 degree, reacts 15min, warm water is diluted to 140ml, and adds in suitable Measuring 30% hydrogen peroxide makes solution become glassy yellow, weighs said products 0.05g and is added in the NaOH solution of 100mL pH=11; Ultrasound 90min prepares dispersion liquid under 150W, removes unstripped graphite oxide at high speed;To graphene oxide dispersion Middle addition 0.1mL hydrazine hydrates, react 2h at 90 DEG C, obtain graphene dispersing solution, the dispersion liquid is deposited to pore and filters dress It puts, using the method for vacuum suction filter, obtains grapheme material layer, then obtained graphene layer is dried up, obtain required thickness Graphene layer.
Technical scheme of the present invention has the following advantages:
Graphene heart rate sensor proposed in this paper has outstanding sensitivity and larger working range, compared with low pressure and There can be the good linearity in the range of higher pressure.Show that heart rate sensor of the invention is in pressure limit through actual measurement 20kPa has significant performance when hypersensitivity is 17.2kPa-1 (0Pa-2kPa).
Description of the drawings
Fig. 1 is the portable medical assistance system structure diagram of the wearable product of the present invention;
Fig. 2 is the structure chart of the graphene sensing heart rate system described in the embodiment of the present invention 1.
Wherein 1 is substrate layer, and 2 be the first pressure sensitivity electrode layer, and 3 be layer of pressure sensitive, and 4 be the second pressure sensitivity electrode layer, and 5 be base Bottom.
Specific embodiment
Embodiment one
Referring to Fig. 1, the portable medical assistance system 100 of a kind of wearable product for the present invention, including graphene heart rate Sensor-based system 200, data transmission system 300 and alarm system 400.The detection of graphene sensing heart rate system 200 wearing The heart rate of the user of wearable product, and pass through data transmission system 300 and be transferred to far-end server, server is according to preset The threshold value of user individual is compared, and warning information is sent out to alarm system 400 when more than secure threshold range, by alarming System 400 is alarmed in a manner of sound and light and vibration (or thrin) to user.
As shown in Fig. 2, the graphene sensing heart rate system includes multilayered structure, it is from top to bottom substrate layer, pressure successively Quick material layer, basal layer.
The first pressure sensitivity electrode layer is additionally provided in the substrate layer and layer of pressure sensitive, in the layer of pressure sensitive and base The second pressure sensitivity electrode layer is additionally provided in bottom.
The layer of pressure sensitive is made of graphene.
The pressure sensitivity electrode layer is made of high-molecular organic material.
The substrate layer and basal layer are the poroid tissue layer of elasticity.
The specific forming step of the layer of pressure sensitive is:By beaker as the 23ml concentrated sulfuric acids in cold water, are added in, control is warm Spend is 0 DEG C;It is added with stirring the solid mixture of 1g graphite powders and 0.5g sodium nitrate;Add in 3g potassium permanganate, control by several times again Reaction temperature is no more than 20 DEG C;Potassium permanganate removes water-bath after adding, and is then heated to 35 DEG C or so, continues to stir 30min, then Deionized water is slowly added to, is heated at high temperature 90 degree, reacts 15min, warm water is diluted to 140ml, and adds in appropriate 30% dioxygen Water makes solution become glassy yellow, weighs said products 0.05g and is added in the NaOH solution of 100mL pH=11;Surpass under 150W Sound 90min prepares dispersion liquid, removes unstripped graphite oxide at high speed;It is added in into graphene oxide dispersion 0.1mL hydrazine hydrates react 2h at 90 DEG C, obtain graphene dispersing solution, the dispersion liquid is deposited to pore filter device, profit With the method for vacuum suction filter, grapheme material layer is obtained, then obtained graphene layer is dried up, obtain the graphene of required thickness Layer material.
The first, second pressure sensitivity electrode layer is vertically arranged to be interdigital, setting in this way, when being acted on by pressure, The variation of variation and graphene layer resistance between measuring electrode can go out acted on pressure size with composite measurement, and And if carrying out coordinate calibration to electrode layer in advance, specific pressure position can also be measured, the pressure-sensing can be increased The scope of application of system.
Embodiment two
Identical with embodiment one, the graphene sensing heart rate system of embodiment two is also multilayered structure.The sensing heart rate system System is from top to bottom substrate layer, the first layer of pressure sensitive, pressure sensitivity electrode layer, the second layer of pressure sensitive, basal layer successively.
First layer of pressure sensitive and the second layer of pressure sensitive are made of graphene.
The pressure sensitivity electrode layer is high-molecular organic material.
The substrate layer and basal layer are the poroid tissue layer of elasticity.
The specific forming step of the graphene is:By beaker as in cold water, the 23ml concentrated sulfuric acids are added in, controlled at 0℃;It is added with stirring the solid mixture of 1g graphite powders and 0.5g sodium nitrate;Add in 3g potassium permanganate, control reaction by several times again Temperature is no more than 20 DEG C;Potassium permanganate removes water-bath after adding, and is then heated to 35 DEG C or so, continues to stir 30min, then slowly Deionized water is added in, is heated at high temperature 90 degree, reaction 15min, warm water is diluted to 140ml, and adds in appropriate 30% hydrogen peroxide and make Solution becomes glassy yellow, weighs said products 0.05g and is added in the NaOH solution of 100mL pH=11;It is ultrasonic under 150W 90min prepares dispersion liquid, removes unstripped graphite oxide at high speed;0.1mL is added in into graphene oxide dispersion Hydrazine hydrate reacts 2h at 90 DEG C, obtains graphene dispersing solution, the dispersion liquid is deposited to pore filter device, using true The method of suction filter obtains grapheme material layer, then obtained graphene layer is dried up, and obtains the graphene layer material of required thickness Material.
The foregoing is merely illustrative of the preferred embodiments of the present invention, is not intended to limit the invention, all essences in the present invention All any modification, equivalent and improvement made within refreshing and principle etc., should all be included in the protection scope of the present invention.

Claims (8)

1. a kind of portable medical assistance system of wearable product, which is characterized in that including graphene sensing heart rate system, data Transmission system and alarm system.
2. the portable medical assistance system of wearable product according to claim 1, it is characterised in that the graphene heart Rate sensor-based system includes multilayered structure, is from top to bottom substrate layer, layer of pressure sensitive, basal layer successively.
3. graphene sensing heart rate system as claimed in claim 2, wherein also being set in the substrate layer and layer of pressure sensitive The first pressure sensitivity electrode layer is equipped with, the second pressure sensitivity electrode layer is additionally provided in the layer of pressure sensitive and basal layer.
4. graphene sensing heart rate system as claimed in claim 3, wherein the layer of pressure sensitive is made of graphene.
5. graphene sensing heart rate system as claimed in claim 4, wherein the pressure sensitivity electrode layer is metal conductive oxide Layer.
6. graphene sensing heart rate system as claimed in claim 5 is knitted wherein the substrate layer and basal layer are that elasticity is poroid Nitride layer.
7. graphene sensing heart rate system as claimed in claim 6, wherein the specific forming step of the layer of pressure sensitive is: By beaker as in cold water, the 23ml concentrated sulfuric acids are added in, controlled at 0 DEG C;It is added with stirring 1g graphite powders and 0.5g sodium nitrate Solid mixture;Add in 3g potassium permanganate by several times again, controlling reaction temperature is no more than 20 DEG C;Potassium permanganate removes water after adding Bath, is then heated to 35 DEG C or so, continues to stir 30min, is slow added into deionized water, is heated at high temperature 90 degree, reaction 15min, warm water are diluted to 140ml, and adding in appropriate 30% hydrogen peroxide makes solution become glassy yellow, weighs said products 0.05g It is added in the NaOH solution of 100mL pH=11;Ultrasound 90min prepares dispersion liquid under 150W, removes do not shell at high speed From graphite oxide;0.1mL hydrazine hydrates are added in into graphene oxide dispersion, 2h is reacted at 90 DEG C, obtains graphene dispersion Liquid deposits the dispersion liquid to pore filter device, using the method for vacuum suction filter, obtains grapheme material layer, then will Obtained graphene layer drying, obtains the graphene layer of required thickness.
8. a kind of portable medical assistance system of the wearable product with graphene sensing heart rate system, the graphene heart rate Sensor-based system is multilayered structure, which is from top to bottom substrate layer, the first layer of pressure sensitive, pressure sensitivity electrode successively Layer, the second layer of pressure sensitive, basal layer, first layer of pressure sensitive and the second layer of pressure sensitive are made of graphene, institute Pressure sensitivity electrode layer is stated as high-molecular organic material, the substrate layer and basal layer are the poroid tissue layer of elasticity, the graphene Specifically forming step is:By beaker as in cold water, the 23ml concentrated sulfuric acids are added in, controlled at 0 DEG C;It is added with stirring 1g graphite The solid mixture of powder and 0.5g sodium nitrate;Add in 3g potassium permanganate by several times again, controlling reaction temperature is no more than 20 DEG C;Permanganic acid Potassium removes water-bath after adding, and is then heated to 35 DEG C or so, continues to stir 30min, is slow added into deionized water, is heated at high temperature To 90 degree, 15min is reacted, warm water is diluted to 140ml, and adding in appropriate 30% hydrogen peroxide makes solution become glassy yellow, weighs Product 0.05g is stated to be added in the NaOH solution of 100mL pH=11;Ultrasound 90min prepares dispersion liquid under 150W, turns in height Speed is lower to remove unstripped graphite oxide;0.1mL hydrazine hydrates are added in into graphene oxide dispersion, 2h is reacted at 90 DEG C, obtains To graphene dispersing solution, the dispersion liquid is deposited to pore filter device, using the method for vacuum suction filter, obtains graphene Material layer, then obtained graphene layer is dried up, obtain the graphene layer material of required thickness.
CN201810090434.3A 2018-01-30 2018-01-30 A kind of portable medical assistance system of wearable product Pending CN108209897A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN116584897A (en) * 2023-05-19 2023-08-15 深圳市鑫坪实业有限公司 Portable health real-time alarm and system

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Publication number Priority date Publication date Assignee Title
CN1551037A (en) * 2003-05-20 2004-12-01 祥群科技股份有限公司 Sliding type fingerprint sensor module assembly and its sensing method
CN102520035A (en) * 2011-11-04 2012-06-27 上海大学 Preparation method for copper oxide-graphene nano-complex modification electrode, and application of modification electrode in glucose detection
CN102674327A (en) * 2012-05-17 2012-09-19 哈尔滨工业大学 Environment-friendly method for preparing water-soluble grapheme at normal temperature
CN102980917A (en) * 2011-09-06 2013-03-20 英飞凌科技股份有限公司 Sensor device and method
CN106073710A (en) * 2016-06-06 2016-11-09 宁波力芯科信息科技有限公司 Intelligent worn device and the control method of Intelligent worn device
CN106482628A (en) * 2016-09-20 2017-03-08 清华大学 A kind of large deformation flexible strain transducer and preparation method thereof

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1551037A (en) * 2003-05-20 2004-12-01 祥群科技股份有限公司 Sliding type fingerprint sensor module assembly and its sensing method
CN102980917A (en) * 2011-09-06 2013-03-20 英飞凌科技股份有限公司 Sensor device and method
CN102520035A (en) * 2011-11-04 2012-06-27 上海大学 Preparation method for copper oxide-graphene nano-complex modification electrode, and application of modification electrode in glucose detection
CN102674327A (en) * 2012-05-17 2012-09-19 哈尔滨工业大学 Environment-friendly method for preparing water-soluble grapheme at normal temperature
CN106073710A (en) * 2016-06-06 2016-11-09 宁波力芯科信息科技有限公司 Intelligent worn device and the control method of Intelligent worn device
CN106482628A (en) * 2016-09-20 2017-03-08 清华大学 A kind of large deformation flexible strain transducer and preparation method thereof

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN116584897A (en) * 2023-05-19 2023-08-15 深圳市鑫坪实业有限公司 Portable health real-time alarm and system

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Application publication date: 20180629