CN108203558A - One-component acrylic ester aquosity coating with anti-corrosion, wear-resisting property - Google Patents
One-component acrylic ester aquosity coating with anti-corrosion, wear-resisting property Download PDFInfo
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- CN108203558A CN108203558A CN201711172781.2A CN201711172781A CN108203558A CN 108203558 A CN108203558 A CN 108203558A CN 201711172781 A CN201711172781 A CN 201711172781A CN 108203558 A CN108203558 A CN 108203558A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/30—Sulfur-, selenium- or tellurium-containing compounds
- C08K2003/3045—Sulfates
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2207/00—Properties characterising the ingredient of the composition
- C08L2207/53—Core-shell polymer
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Abstract
The invention discloses a kind of one-component acrylic ester aquosity coating with anti-corrosion, wear-resisting property, belong to coating preparation field, and the above-mentioned one-component acrylic ester aquosity coating with anti-corrosion, wear-resisting property is made of the ancestral peak of following parts by weight:Special 200 400 parts of acrylic acid ester emulsion, 1 10 parts of propylene glycol, 20 40 parts of titanium dioxide, 10 20 parts of blanc fixe, 20 50 parts of coalescents, 5 10 parts of dispersant, 15 parts of antifoaming agent, 0.1 1 parts of wetting agent, 0.1 1 parts of fungicide, 0.5 2 parts of multifunctional assistant, 0.1 1 parts of thickener, 0.1 1 parts of levelling agent, 0.1 1 parts of acrylic thickener.Water resistance, corrosion resistance and the wearability of the present invention is good, drying time is fast, good permeability, film not bubbling, do not fall off, can be used in 200C to 950C environment, available for the industrial antisepsis such as floor coatings, metal anti-corrosive paint, marine paint field.
Description
Technical field
The present invention relates to a kind of acrylate paint, more particularly to a kind of one-component propylene with anti-corrosion, wear-resisting property
Acid esters water paint.
Background technology
As economy develops rapidly, the industrial coating in China obtains fast development, and floor coatings are with it with excellent object
Manage mechanical performance, electrical insulation capability, the performances such as resistant to chemical etching obtain everybody attention and extensive use, and dosage is year by year not
It is disconnected to increase.But domestic floor coatings about 80% are solvent based coatings at present, organic solvent content is answered, and is being produced and was being used
Organic solvent is evaporate into air in journey, causes the more serious wasting of resources and environmental pollution, influences the physical and mental health of people,
And with great security risk.With the world environmental protection is increasingly enhanced and environmental protection legislation it is increasingly strict, have low stain,
It does not fire, have excellent performance, the research of the aqueous floor coatings for the features such as construction safety facilitates becomes trend.
Currently on the market in aqueous floor coatings based on water-base epoxy and water-based polyurethane two-component floor coatings, pass
The aqueous epoxy floor coating of system and aqueous polyurethane floor coatings are to produce epoxy resin or polyurethane resin by solvent method
It under the action of emulsifier, is distributed in water by mechanical means in specific device again, water-base resin is made, then with aqueous
Resin is mixed and made into water paint with solid powder slurry.The property of the floor coatings depends on the performance of Chinese quality completely.By
What it is in epoxy resin and polyurethane resin is the eternal solvent method synthesis of love, then carry out removing solvent during water and milk, therefore, is made
Water paint in solvent residual quantity will be far above acrylate polymerization processes in it is remaining(Generally in below 100PPM)
Content of monomer.Scene host agent and curing agent is needed now to match according to a certain percentage during use now to be made, and operation is relatively complicated, smart to metering
Degree and Personnel Skill Levels are more demanding, and above-mentioned coating has the advantages such as gloss is high, hardness is high, wearability is good.But with state
Increasing of the family to gold protection, product of the solvent based coating as high VOC emission have been included in restricted product, have made
It will be severely limited with place, usage amount.
Domestic market acrylate paint product is mainly used for Discussion on architecture wall device, reason one be building coating into
The performance of membrane substance lotion does not have self-crosslinking energy or self-crosslinking degree requirement height;Second is that the powder of building coating generally uses titanium white
Powder, fine particle calcium carbonate, coarse whiting etc., such substance layout, which has, promotes property monomer crosslinked in lotion;Third, in fine particle calcium carbonate, coarse whiting class product
Carbonate is met acidic materials and is easily decomposed;Fourth, the hardness of carbonate substance itself is relatively low, therefore, wear-resisting, anti-corrosive properties are being needed
Technology requirement can not be met in terms of the waste product coating and anticorrosive paint of energy.
Aqueous one-component acrylic acid floor coatings product because low VOC emission, without APEO, gloss is high, has excellent weather resistance, is resistance to
It is hot it is good, water-fast and resistant to chemical etching soaring market field strength strength is wide.The related introduction of water paint is as follows in the prior art:
CN102634273A discloses a kind of acrylate mono-component waterproofing paint, it is made of the component of following weight ratio:Third
Olefin(e) acid lotion 50-70, preservative 0.02-0.04, powdered whiting 5-7, titanium dioxide 10-20, thickener 0.1-0.3, dibutyl ester
3-6, ammonia neutralizer 0.04-0.06, cellulose 2-4, antifoaming agent 0.01-0.03, water 6-8, filler material 1-2.The invention is with pure third
Olefin(e) acid lotion adds in grease P fillers, and the one-component high polymer aqueous waterproofing paint that auxiliary agent configuration forms, it has good impervious
Property, cohesive force and flexibility, whole elasticity and ductility, can realize that coating water-repellent paint 2-3mm wide crackings occurs in concrete
And impermeable effect.But the crosslinking subtlety of acrylic acid ester emulsion is relatively low in the present invention, hardness etc. is poor.
Invention content
To solve the problems, such as that propylene element holds high that sub- lotion crosslinking degree is low to lead to poor-performing in the prior art, the present invention provides
A kind of one-component acrylic ester aquosity coating with anti-corrosion, wear-resisting property, wherein, it is anti-corrosion that prepared by the present invention have, resistance to
The one-component acrylic ester aquosity coating of mill performance has many advantages, such as high rigidity, high-wearing feature and anti-corrosive properties, and setting rate is fast.
In order to solve the above technical problems, present invention offer technical solution is as follows:On the one hand, the present invention provides a kind of with anti-
Rotten, wear-resisting property one-component acrylic ester aquosity coating, is made of the component of following parts by weight
Special acrylic acid ester emulsion 200-400 parts
1-10 parts of propylene glycol
20-40 parts of titanium dioxide
10-20 parts of blanc fixe
20-50 parts of coalescents
5-10 parts of dispersant
1-5 parts of antifoaming agent
0.1-1 parts of wetting agent
0.1-1 parts of fungicide
0.5-2 parts of multifunctional assistant
0.1-2.5 parts of thickener
0.1-2 parts of levelling agent.
There are choosing, a kind of one-component acrylic ester aquosity coating with anti-corrosion, wear-resisting property, by following weight
The component of part is made
Special acrylic acid ester emulsion 250-350 parts
1-5 parts of propylene glycol
20-30 parts of titanium dioxide
15-20 parts of blanc fixe
20-40 parts of coalescents
6-8 parts of dispersant
2-4 parts of antifoaming agent
0.5-1 parts of wetting agent
0.1-0.5 parts of fungicide
1-2 parts of multifunctional assistant
0.1-0.5 parts of thickener
0.1-0.5 parts of levelling agent.
Preferably, the one-component acrylic ester aquosity coating with anti-corrosion, wear-resisting property, by following parts by weight
Component is made
Special 300 parts of acrylic acid ester emulsion
2 parts of propylene glycol
20 parts of titanium dioxide
20 parts of blanc fixe
30 parts of coalescents
8 parts of dispersant
2.5 parts of antifoaming agent
0.5 part of wetting agent
0.3 part of fungicide
1.1 parts of multifunctional assistant
0.3 part of thickener
0.3 part of levelling agent.
As a kind of perferred technical scheme:The special acrylic acid ester emulsion is by with cross-linking monomer acetyl second
The acrylate core-shell latex coating that metallic compound is prepared is added in the lotion of acidic group ethyl methacrylate.
As a kind of perferred technical scheme:The metallic compound is the inorganic salts of zinc or aluminium, organic salt, oxide or
Hydroxide.
As a kind of perferred technical scheme:The levelling agent is organosilicon levelling agent 2020;The esters of acrylic acid
Thickener is ATX-01;The multifunctional assistant is AMP-95.
As a kind of perferred technical scheme:The titanium dioxide grain size is -3000 mesh of 1000 mesh;The sulfate precipitate granellae
Diameter is -3000 mesh of 1000 mesh.
As a kind of perferred technical scheme:The coating is for floor coatings, metal anti-corrosive paint, marine paint.
Preferably, it is of the invention by propylene glycol, titanium dioxide, blanc fixe, coalescents, dispersant, antifoaming agent, wetting
Agent, fungicide, multifunctional assistant, thickener, levelling agent are added in grinding machine, are added special acrylic acid ester emulsion, are started and stir
The machine of mixing is sufficiently stirred grinding 1-4.5h, sieving, and the coating of preparation can be used for floor coatings, metal anti-corrosive paint, crew quarter coating
Wait industrial antisepsis purposes.
Preferably, one-component acrylate paint of the invention is somebody's turn to do using special acrylic acid ester emulsion as adhesive
Contain acetoacetoxyethyl methacrylate in special third sub- acid esters lotion, can be selfed during emulsion film forming
Connection makes high molecular polymer form inierpeneirating network structure in film forming, improve the flexibility of polymeric membrane, impact resistance and it is resistance to from
Subtype;Meanwhile by adding special powder material, which can be anti-with complexing occurs with the existing carboxylic acid in lotion macromolecular chain
Should, formed metal Luohe not soluble in water without, further improve the crosslink density of coating, greatly improve coating water resistance,
Corrosion resistance and wearability;By two kinds of cross-linked forms, the drying setting rate of the coating of preparation is improved.
The beneficial effects of the invention are as follows:(1)Polymer that the present invention uses, host material meet VOC, without APEO environmental protection
Index, content of beary metal are met the requirements of the standard;(2)The present invention is easy for construction for acrylate but Xu Fen water paints;(3)It adopts
With dedicated acrylic acid ester emulsion, the self-crosslinking ingredient contained by itself increases flexibility, impact resistance of film forming etc.;
(4)Special powder is added by outside, it is made, with reacting, to pass through not dissolving in for formation with the carboxylic acid in special acrylic acid ester emulsion
The metal complex of water improves the crosslink density of coating, and the water resistance of coating, corrosion resistance and wear-resisting are further improved with this
Property;(5)Anti-corrosion prepared by the present invention, the one-component acrylic ester aquosity coating drying time of wear-resisting property be fast, good permeability, painting
Film not bubbling, do not fall off, while there is excellent chemicals-resistant aggressivity and the row of resistance to greasy dirt, can be -200C to 950C rings
It is used in border, available for the industrial antisepsis such as floor coatings, metal anti-corrosive paint, marine paint field.
Specific embodiment
To make the technical problem to be solved in the present invention, technical solution and a little clearer, below in conjunction with specific implementation
Example is described in detail.
Said program is described further below in conjunction with specific embodiment.It should be understood that these embodiments are for illustrating
The present invention rather than limit the scope of the invention, the implementation condition used in embodiment can be done according to the situation of specific product into
One step item adjusts, and not specified implementation condition is usually the condition in routine experiment.
The materials, reagents and the like used in the following examples can obtain from commercial channels.
The present invention provide it is a kind of with anti-corrosion, wear-resisting property one-component acrylic ester aquosity coating, detailed process referring to
Following embodiments.
Embodiment 1
A kind of one-component acrylic ester aquosity coating with anti-corrosion, wear-resisting property, is made of the component of following parts by weight
200 parts of HYD-5816
1 part of propylene glycol
20 parts of titanium dioxide
10 parts of blanc fixe
20 parts of benzyl alcohol
5 parts of COATEX PE737
1 part of polysiloxanes defoaming agents
0.1 part of BD-3032
0.1 part of KLN-15B
0.5 part of AMP-95
0.1 part of hydroxyethyl cellulose
2020 0.1 parts
0.1 part of ATX-01.
Embodiment 2
A kind of one-component acrylic ester aquosity coating with anti-corrosion, wear-resisting property, is made of the component of following parts by weight
250 parts of HYD-5816
1 part of propylene glycol
20 parts of titanium dioxide
15 parts of blanc fixe
20 parts of Lauryl Alcohol ester
40 6 parts of ECODIS
2 parts of silicone oil emulsion antifoaming agent
0.5 part of polysiloxanes
0.1 part of Bordeaux mixture
1 part of AMP-95
0.05 part of hydroxymethyl cellulose
0.05 part of hydroxyethyl cellulose
2020 0.1 parts
0.2 part of ATX-01.
Embodiment 3
A kind of one-component acrylic ester aquosity coating with anti-corrosion, wear-resisting property, is made of the component of following parts by weight
300 parts of HYD-5816
2 parts of propylene glycol
20 parts of titanium dioxide
20 parts of blanc fixe
30 parts of butyl glycol ether
8 parts of COATEX P90
2.5 parts of polysiloxanes defoaming agents
0.5 part of neopelex
0.3 part of KLN-16B
1.1 parts of AMP-95
0.3 part of hydroxyethyl cellulose
2020 0.3 parts
0.3 part of ATX-01.
Embodiment 4
A kind of one-component acrylic ester aquosity coating with anti-corrosion, wear-resisting property, is made of the component of following parts by weight
350 parts of HYD-5816
5 parts of propylene glycol
30 parts of titanium dioxide
20 parts of blanc fixe
40 parts of hexylene glycol monobutyl ether acetate
8 parts of COATEX P50
2 parts of polysiloxanes defoaming agents
2 parts of silicone oil emulsion antifoaming agent
1 part of polysiloxanes
0.5 part of KLN-19B
2 parts of AMP-95
0.5 part of hydroxymethyl cellulose
2020 0.5 parts
0.5 part of ATX-01.
Embodiment 5
A kind of one-component acrylic ester aquosity coating with anti-corrosion, wear-resisting property, is made of the component of following parts by weight
400 parts of HYD-5816
10 parts of propylene glycol
40 parts of titanium dioxide
15 parts of blanc fixe
50 parts of propylene glycol phenylate
80 10 parts of ECODIS
5 parts of silicone oil emulsion antifoaming agent
1 part of BD-3032
1 part of KLN-17B
2 parts of AMP-95
2.5 parts of hydroxymethyl cellulose
2020 2 parts
0.5 part of ATX-01.
To further illustrate the present invention the property with anti-corrosion, the one-component acrylic ester aquosity coating of wear-resisting property of preparation
Can, following comparative example is built by taking embodiment 3 as an example;
Comparative example 1
A kind of acrylate paint replaces special acrylic acid ester emulsion HYD-5816, remaining group with common commercially available acrylic emulsion
Divide and dosage is same as Example 3.
Comparative example 2
A kind of acrylate paint removes titanium dioxide, remaining component and dosage are same as Example 3.
Comparative example 3
A kind of acrylate paint removes blanc fixe, remaining component and dosage are same as Example 3.
The present invention also provides it is a kind of it is above-mentioned with anti-corrosion, wear-resisting property one-component acrylic ester aquosity coating application,
By propylene glycol, titanium dioxide, blanc fixe, coalescents, dispersant, antifoaming agent, wetting agent, fungicide, multifunctional assistant, increasing
Thick dose, levelling agent add in grinding machine in, add special acrylic acid ester emulsion, start blender be sufficiently stirred grinding 1-1.5h,
Sieving, the coating of preparation can be used for the industrial antisepsis purposes such as floor coatings, metal anti-corrosive paint, marine paint.
The acrylic ester aquosity coating prepared for embodiment 1-5 and comparative example 1-2 is according to HG/T3829-2006(It is slim)
Floor coatings standard carries out performance Jiang Ce.
The present invention prepare with anti-corrosion, wear-resisting property one-component acrylic ester aquosity coating compared with comparative example with
Solid content is high, drying time is fast, strong adhesive force, hardness are high, acid-alkali-corrosive-resisting is strong, while its flexility and wear-resisting property
Preferably.
This may be due on the one hand, having cross-linking monomer acetoacetate methacrylic acid in special acrylic acid ester emulsion
Ester(AAEMA)Presence, ambient self-crosslinking effect can be carried out, AAEMA is in polyalcohol emulsion particle shell with more double carbonyls
Base functional group, it is easier to which its self-crosslinking makes high molecular polymer form inierpeneirating network structure in film forming, improves polymeric membrane
Flexibility, impact resistance and resistance to ionic;On the other hand there are metal ion in special acrylic acid ester emulsion, the titanium with addition
Complex reaction occurs with the existing carboxylate radical in acrylic acid ester emulsion macromolecular chain jointly with barium, forms metal not soluble in water
Complex compound further improves the crosslink density of coating, greatly improves water resistance, corrosion resistance and the wearability of coating;Pass through
Two kinds of cross-linked forms improve the drying setting rate of the coating of preparation.
In summary, it is resistance to the present invention provides a kind of local anti-corrosion, the one-component acrylic ester aquosity coating of wear-resisting property
Aqueous, corrosion resistance and wearability are good, drying time is fast, good permeability, film not bubbling, do not fall off.It can be -200C to 950C
It is used in environment, available for the industrial antisepsis such as floor coatings, metal anti-corrosive paint, marine paint field.
Experiment provided above is only the preferred embodiments of the present invention, is not used to the protection orientation of the present invention.It should be pointed out that
For those skilled in the art, without departing from the principles of the present invention, if sea can be made
Dry improvements and modifications, these improvements and modifications also should be regarded as protection scope of the present invention.
Claims (8)
1. a kind of one-component acrylic ester aquosity coating with anti-corrosion, wear-resisting property, it is characterised in that:By following parts by weight
Component is made
Special acrylic acid ester emulsion 200-400 parts
1-10 parts of propylene glycol
20-40 parts of titanium dioxide
10-20 parts of blanc fixe
20-50 parts of coalescents
5-10 parts of dispersant
1-5 parts of antifoaming agent
0.1-1 parts of wetting agent
0.1-1 parts of fungicide
0.5-2 parts of multifunctional assistant
0.1-2.5 parts of thickener
0.1-2 parts of levelling agent.
2. a kind of one-component acrylic ester aquosity coating with anti-corrosion, wear-resisting property according to claim 1, special
Sign is:It is made of the component of following parts by weight
Special acrylic acid ester emulsion 250-350 parts
1-5 parts of propylene glycol
20-30 parts of titanium dioxide
15-20 parts of blanc fixe
20-40 parts of coalescents
6-8 parts of dispersant
2-4 parts of antifoaming agent
0.5-1 parts of wetting agent
0.1-0.5 parts of fungicide
1-2 parts of multifunctional assistant
0.1-0.5 parts of thickener
0.1-0.5 parts of levelling agent.
3. the one-component acrylic ester aquosity coating according to claim 1 with anti-corrosion, wear-resisting property, feature exist
In:It is made of the component of following parts by weight
Special 300 parts of acrylic acid ester emulsion
2 parts of propylene glycol
20 parts of titanium dioxide
20 parts of blanc fixe
30 parts of coalescents
8 parts of dispersant
2.5 parts of antifoaming agent
0.5 part of wetting agent
0.3 part of fungicide
1.1 parts of multifunctional assistant
0.3 part of thickener
0.3 part of levelling agent.
It is 4. special according to any one-component acrylic ester aquosity coating with anti-corrosion, wear-resisting property of claim 1-3
Sign is:The special acrylic acid ester emulsion is by the lotion with cross-linking monomer acetoacetoxyethyl methacrylate
The acrylate core-shell latex coating that middle addition metallic compound is prepared.
5. the one-component acrylic ester aquosity coating according to claim 4 with anti-corrosion, wear-resisting property, feature exist
In:The metallic compound is zinc or inorganic salts, organic salt, oxide or the hydroxide of aluminium.
It is 6. special according to any one-component acrylic ester aquosity coating with anti-corrosion, wear-resisting property of claim 1-3
Sign is:The levelling agent is organosilicon levelling agent 2020;The acrylic ester thickener is ATX-01;It is described multi-functional
Auxiliary agent is AMP-95.
It is 7. special according to any one-component acrylic ester aquosity coating with anti-corrosion, wear-resisting property of claim 1-3
Sign is:The titanium dioxide grain size is -3000 mesh of 1000 mesh;The blanc fixe grain size is -3000 mesh of 1000 mesh.
It is 8. special according to any one-component acrylic ester aquosity coating with anti-corrosion, wear-resisting property of claim 1-7
Sign is:The coating is for floor coatings, metal anti-corrosive paint, marine paint.
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CN113527926A (en) * | 2021-08-24 | 2021-10-22 | 江苏欣安新材料技术有限公司 | Inorganic nuclear power terrace coating and preparation method thereof |
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