CN108203306A - A kind of impermeabilisation LP blades aluminium melting furnace molten bath castable - Google Patents

A kind of impermeabilisation LP blades aluminium melting furnace molten bath castable Download PDF

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Publication number
CN108203306A
CN108203306A CN201611187398.XA CN201611187398A CN108203306A CN 108203306 A CN108203306 A CN 108203306A CN 201611187398 A CN201611187398 A CN 201611187398A CN 108203306 A CN108203306 A CN 108203306A
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parts
fine powder
blades
impermeabilisation
melting furnace
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CN201611187398.XA
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白明迅
高传甲
李哲
王太勇
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SHANDONG LUMING NEW MATERIALS CO Ltd
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SHANDONG LUMING NEW MATERIALS CO Ltd
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Priority to CN202310583558.6A priority Critical patent/CN116425557A/en
Priority to CN201611187398.XA priority patent/CN108203306A/en
Publication of CN108203306A publication Critical patent/CN108203306A/en
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/66Monolithic refractories or refractory mortars, including those whether or not containing clay
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/38Non-oxide ceramic constituents or additives
    • C04B2235/3817Carbides
    • C04B2235/3826Silicon carbides
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P10/00Technologies related to metal processing
    • Y02P10/20Recycling

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Ceramic Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Ceramic Products (AREA)
  • Furnace Housings, Linings, Walls, And Ceilings (AREA)

Abstract

The invention discloses a kind of impermeabilisation LP blades aluminium melting furnace molten bath castables, include the raw material of following parts by weight:50 70 parts of electrofused mullite particle, 5 15 parts of plate diamond spar particle, 1 10 parts of plate diamond spar fine powder, 1 10 parts of carbide fine powder, 3 12 parts of activated alumina of α types calcining, 18 parts of ρ types calcined alumina, 15 parts of kyanite, 28 parts of pure calcium aluminate cement, 16 parts of barium sulfate precipitate, 0.3 5 parts of industrial potassium titanate, 0.01 0.5 parts of water-reducing agent.The impermeabilisation LP blades aluminium melting furnace molten bath castable is compounded by raw material and plays synergistic effect, has the excellent ability resisted metal aluminum melt and corroded, and the impermeable and corrosion resistance of the slag to being formed in smelting is strong;And preparation method is simple, raw material is easy to get, and production cost is low.

Description

A kind of impermeabilisation LP blades aluminium melting furnace molten bath castable
Technical field
The present invention relates to a kind of unshape refractory, specifically a kind of impermeabilisation LP blades aluminium melting furnace molten bath cast Material.
Background technology
Aluminium melting furnace is a kind of novel high-efficiency and energy-saving aluminium melting furnace developed according to aluminium smelting technology, it can meet well In aluminium smelting technology, alloy composition requirement is tight, and production is discontinuous, and single heat size is larger to wait requirement, has reached reduction consumption, has reduced Scaling loss improves product quality, reduces labor intensity, the effect of improving working conditions and improve production efficiency, makees suitable for interval Melting more than industry, gold conjugate and foundry returns.Castable is also known as castable refractory, is that one kind adds in a certain amount of combination by refractory material Granular and pulverulent material made of agent has compared with high fluidity, with the molding unshape refractory of pouring type.
In terms of castable is widely used in aluminium melting furnace molten bath, but existing impermeabilisation LP blades aluminium melting furnace molten bath Castable still has problems with:The ability for resisting the erosion of metal aluminum melt is relatively low, and the slag to being formed in smelting Impermeable and corrosion resistance is smaller.Therefore, the present invention provides a kind of impermeabilisation LP blades aluminium melting furnace molten bath castable, has The excellent ability resisted metal aluminum melt and corroded, and the impermeable and corrosion resistance of the slag to being formed in smelting By force.
Invention content
The purpose of the present invention is to provide a kind of impermeabilisation LP blades aluminium melting furnace molten bath castable, to solve above-mentioned background The problem of being proposed in technology.
To achieve the above object, the present invention provides following technical solution:
A kind of impermeabilisation LP blades aluminium melting furnace molten bath castable includes the raw material of following parts by weight:Electrofused mullite 50-70 parts of particle, 5-15 parts of plate diamond spar particle, 1-10 parts of plate diamond spar fine powder, 1-10 parts of carbide fine powder, the calcining of α types are lived 3-12 parts of aluminium oxide of property, 1-8 parts of ρ type calcined aluminas, 1-5 parts of kyanite, 2-8 parts of pure calcium aluminate cement, barium sulfate precipitate 1-6 Part, 0.3-5 parts of industrial potassium titanate, 0.01-0.5 parts of water-reducing agent.
As further embodiment of the present invention:Include the raw material of following parts by weight:58-60 parts of electrofused mullite particle, 9-12 parts of plate diamond spar particle, 3-6 parts of plate diamond spar fine powder, 3-6 parts of carbide fine powder, 5-8 parts of activated alumina of α types calcining, ρ 3-5 parts of type calcined alumina, 2-3 parts of kyanite, 4-6 parts of pure calcium aluminate cement, 2-4 parts of barium sulfate precipitate, industrial potassium titanate 1-3 Part, 0.1-0.3 parts of water-reducing agent.
As further scheme of the invention:The grain size of the electrofused mullite particle is 1-5mm;The plate diamond spar The grain size of particle is 1mm;The granularity of the plate diamond spar fine powder is 0.046mm;The granularity of the carbide fine powder is 0.046mm;The granularity of the α types calcining activated alumina is 0.003mm;The granularity of the ρ types calcined alumina is 0.046mm;The granularity of the kyanite is 0.15mm.
As further scheme of the invention:Al in the electrofused mullite particle2O3Mass percentage content be 68-72%;Al in the plate diamond spar particle2O3Mass percentage content >=98%;Al in the plate diamond spar fine powder2O3 Mass percentage content >=98%;Mass percentage content >=95% of SIC in the carbide fine powder;The α types calcining Al in activated alumina2O3Mass percentage content >=99%;Al in the ρ types calcined alumina2O3Mass percent contain Amount >=85%;Al in the kyanite2O3Mass percentage content >=56%;Al in the pure calcium aluminate cement2O3Quality Degree >=70%;BaSO in the blanc fixe4Mass percentage content >=98%;In the industrial potassium titanate Al2O3Mass percentage content >=99%.
As further scheme of the invention:The water-reducing agent is powder polycarboxylic acids water reducing agent.
A kind of preparation method of impermeabilisation LP blades aluminium melting furnace molten bath castable, includes the following steps:
(1) each raw material is weighed according to above-mentioned formula, it is spare;
(2) by plate diamond spar fine powder, carbide fine powder, α types calcining activated alumina, ρ types calcined alumina, kyanite, Pure calcium aluminate cement, blanc fixe, industrial potassium titanate, which add in, carries out ball milling blending, Ball-milling Time 20- in tubulose ball mill 50 minutes, form blending milling component;
(3) electrofused mullite particle, plate diamond spar particle and water-reducing agent and blending milling component obtained by upper step are mixed It closes, is more than 1m using volume3Pressure planetary mixing and blending machine mixed material is stirred, the mixing time be 5-15 Minute.
As further scheme of the invention:The order of addition of the step (3) is:First add in electrofused mullite particle With plate diamond spar particle, then add blending milling component, be eventually adding water-reducing agent.
As further scheme of the invention:Ball-milling Time in the step (2) is 30 minutes.
As further scheme of the invention:The mixing time in the step (3) is 8 minutes.
Compared with prior art, the beneficial effects of the invention are as follows:
The impermeabilisation LP blades aluminium melting furnace molten bath castable is compounded by raw material and plays synergistic effect, has excellent support The ability that anti-metal aluminum melt corrodes, and the impermeable and corrosion resistance of the slag to being formed in smelting is strong;This is impervious The preparation method of saturating LP blades aluminium melting furnace molten bath castable is simple, and raw material is easy to get, and cost of material is low, and production process is less, Effectively reduce production cost;In addition, the application range of the impermeabilisation LP blades aluminium melting furnace molten bath castable is wider, product product Matter is good, and market popularization value is higher.
Specific embodiment
The technical solution of this patent is described in more detail With reference to embodiment.
Embodiment 1
A kind of impermeabilisation LP blades aluminium melting furnace molten bath castable includes the raw material of following parts by weight:Electrofused mullite 50 parts of particle, 5 parts of plate diamond spar particle, 1 part of plate diamond spar fine powder, 1 part of carbide fine powder, 3 parts of activated alumina of α types calcining, ρ 1 part of type calcined alumina, 1 part of kyanite, 2 parts of pure calcium aluminate cement, 1 part of barium sulfate precipitate, 0.3 part of industrial potassium titanate, diminishing 0.01 part of agent.
The grain size of the electrofused mullite particle is 1mm;The grain size of the plate diamond spar particle is 0.5mm;The plate The granularity of corundum fine powder is 0.02mm;The granularity of the carbide fine powder is 0.03mm;The grain of the α types calcining activated alumina It spends for 0.002mm;The granularity of the ρ types calcined alumina is 0.025mm;The granularity of the kyanite is 0.1mm.
Al in the electrofused mullite particle2O3Mass percentage content be 50-68%;In the plate diamond spar particle Al2O3Mass percentage content >=90%;Al in the plate diamond spar fine powder2O3Mass percentage content >=92%;It is described Mass percentage content >=90% of SIC in carbide fine powder;Al in the α types calcining activated alumina2O3Mass percent Content >=92%;Al in the ρ types calcined alumina2O3Mass percentage content >=78%;Al in the kyanite2O3's Mass percentage content >=50%;Al in the pure calcium aluminate cement2O3Mass percentage content >=65%;The precipitated sulfur BaSO in sour barium4Mass percentage content >=94%;Al in the industrial potassium titanate2O3Mass percentage content >=95%.
A kind of preparation method of impermeabilisation LP blades aluminium melting furnace molten bath castable, includes the following steps:
(1) each raw material is weighed according to above-mentioned formula, it is spare;
(2) by plate diamond spar fine powder, carbide fine powder, α types calcining activated alumina, ρ types calcined alumina, kyanite, Pure calcium aluminate cement, blanc fixe, industrial potassium titanate, which add in, carries out ball milling blending, Ball-milling Time 20- in tubulose ball mill 50 minutes, form blending milling component;
(3) electrofused mullite particle, plate diamond spar particle and water-reducing agent and blending milling component obtained by upper step are mixed It closes, is more than 1m using volume3Pressure planetary mixing and blending machine mixed material is stirred, be mixed the time be 5 points Clock.
The order of addition of the step (3) is:Blending milling component is first added in, then powers up molten mullite particle and plate is firm Beautiful particle, is eventually adding water-reducing agent.
Embodiment 2
A kind of impermeabilisation LP blades aluminium melting furnace molten bath castable includes the raw material of following parts by weight:Electrofused mullite 70 parts of particle, 15 parts of plate diamond spar particle, 10 parts of plate diamond spar fine powder, 10 parts of carbide fine powder, α types calcining activated alumina 12 Part, 5 parts of industrial potassium titanate, subtracts 8 parts of ρ types calcined alumina, 5 parts of kyanite, 8 parts of pure calcium aluminate cement, 6 parts of barium sulfate precipitate 0.5 part of aqua.
The grain size of the electrofused mullite particle is 5mm;The grain size of the plate diamond spar particle is 2mm;The plate is firm The granularity of beautiful fine powder is 0.05mm;The granularity of the carbide fine powder is 0.06mm;The granularity of the α types calcining activated alumina For 0.005mm;The granularity of the ρ types calcined alumina is 0.06mm;The granularity of the kyanite is 0.2mm.
Al in the electrofused mullite particle2O3Mass percentage content be 72-80%;In the plate diamond spar particle Al2O3Mass percentage content >=99%;Al in the plate diamond spar fine powder2O3Mass percentage content >=99%;It is described Mass percentage content >=97% of SIC in carbide fine powder;Al in the α types calcining activated alumina2O3Mass percent Content >=99%;Al in the ρ types calcined alumina2O3Mass percentage content >=90%;Al in the kyanite2O3's Mass percentage content >=70%;Al in the pure calcium aluminate cement2O3Mass percentage content >=78%;The precipitated sulfur BaSO in sour barium4Mass percentage content >=99%;Al in the industrial potassium titanate2O3Mass percentage content >=99%.
A kind of preparation method of impermeabilisation LP blades aluminium melting furnace molten bath castable, includes the following steps:
(1) each raw material is weighed according to above-mentioned formula, it is spare;
(2) by plate diamond spar fine powder, carbide fine powder, α types calcining activated alumina, ρ types calcined alumina, kyanite, Pure calcium aluminate cement, blanc fixe, industrial potassium titanate add in and ball milling blending are carried out in tubulose ball mill, and Ball-milling Time is 50 points Clock forms blending milling component;
(3) electrofused mullite particle, plate diamond spar particle and water-reducing agent and blending milling component obtained by upper step are mixed It closes, is more than 1m using volume3Pressure planetary mixing and blending machine mixed material is stirred, be mixed the time be 15 points Clock.
The order of addition of the step (3) is:Water-reducing agent is first added in, then adds blending milling component, is eventually adding electric smelting not Come stone particle and plate diamond spar particle.
Embodiment 3
A kind of impermeabilisation LP blades aluminium melting furnace molten bath castable includes the raw material of following parts by weight:Electrofused mullite 59 parts of particle, 11 parts of plate diamond spar particle, 4 parts of plate diamond spar fine powder, 5 parts of carbide fine powder, α types calcining 6 parts of activated alumina, 4 parts of ρ types calcined alumina, 2 parts of kyanite, 5 parts of pure calcium aluminate cement, 3 parts of barium sulfate precipitate, 2 parts of industrial potassium titanate, water-reducing agent 0.2 part.
The grain size of the electrofused mullite particle is 3mm;The grain size of the plate diamond spar particle is 1mm;The plate is firm The granularity of beautiful fine powder is 0.046mm;The granularity of the carbide fine powder is 0.046mm;The grain of the α types calcining activated alumina It spends for 0.003mm;The granularity of the ρ types calcined alumina is 0.046mm;The granularity of the kyanite is 0.15mm.
Al in the electrofused mullite particle2O3Mass percentage content be 68-72%;In the plate diamond spar particle Al2O3Mass percentage content >=98%;Al in the plate diamond spar fine powder2O3Mass percentage content >=98%;It is described Mass percentage content >=95% of SIC in carbide fine powder;Al in the α types calcining activated alumina2O3Mass percent Content >=99%;Al in the ρ types calcined alumina2O3Mass percentage content >=85%;Al in the kyanite2O3's Mass percentage content >=56%;Al in the pure calcium aluminate cement2O3Mass percentage content >=70%;The precipitated sulfur BaSO in sour barium4Mass percentage content >=98%;Al in the industrial potassium titanate2O3Mass percentage content >=99%.
The water-reducing agent is powder polycarboxylic acids water reducing agent.
A kind of preparation method of impermeabilisation LP blades aluminium melting furnace molten bath castable, includes the following steps:
(1) each raw material is weighed according to above-mentioned formula, it is spare;
(2) by plate diamond spar fine powder, carbide fine powder, α types calcining activated alumina, ρ types calcined alumina, kyanite, Pure calcium aluminate cement, blanc fixe, industrial potassium titanate add in and ball milling blending are carried out in tubulose ball mill, and Ball-milling Time is 30 points Clock forms blending milling component;
(3) electrofused mullite particle, plate diamond spar particle and water-reducing agent and blending milling component obtained by upper step are mixed It closes, is more than 1m using volume3Pressure planetary mixing and blending machine mixed material is stirred, be mixed the time be 8 points Clock.
The order of addition of the step (3) is:Electrofused mullite particle and plate diamond spar particle are first added in, then adds blending mill Powder component is eventually adding water-reducing agent.
The impermeabilisation LP blades aluminium melting furnace molten bath castable is compounded by raw material and plays synergistic effect, has excellent support The ability that anti-metal aluminum melt corrodes, and the impermeable and corrosion resistance of the slag to being formed in smelting is strong;This is impervious The preparation method of saturating LP blades aluminium melting furnace molten bath castable is simple, and raw material is easy to get, and cost of material is low, and production process is less, Effectively reduce production cost;In addition, the application range of the impermeabilisation LP blades aluminium melting furnace molten bath castable is wider, product product Matter is good, and market popularization value is higher.
The better embodiment of this patent is explained in detail above, but this patent is not limited to above-mentioned embodiment party Formula, can also be under the premise of this patent objective not be departed from the knowledge that one skilled in the relevant art has It makes a variety of changes.

Claims (9)

1. a kind of impermeabilisation LP blades aluminium melting furnace molten bath castable, which is characterized in that include the raw material of following parts by weight:Electricity Molten 50-70 parts of mullite particle, 5-15 parts of plate diamond spar particle, 1-10 parts of plate diamond spar fine powder, 1-10 parts of carbide fine powder, α 3-12 parts of activated alumina of type calcining, 1-8 parts of ρ type calcined aluminas, 1-5 parts of kyanite, 2-8 parts of pure calcium aluminate cement, sulfuric acid 1-6 parts of precipitated barium, 0.3-5 parts of industrial potassium titanate, 0.01-0.5 parts of water-reducing agent.
2. impermeabilisation LP blades aluminium melting furnace molten bath according to claim 1 castable, which is characterized in that including following heavy Measure the raw material of number:58-60 parts of electrofused mullite particle, 9-12 parts of plate diamond spar particle, 3-6 parts of plate diamond spar fine powder, carbonization 3-6 parts of silica fine powder, 5-8 parts of activated alumina of α types calcining, 3-5 parts of ρ type calcined aluminas, 2-3 parts of kyanite, pure calcium aluminate water 4-6 parts of mud, 2-4 parts of barium sulfate precipitate, 1-3 parts of industrial potassium titanate, 0.1-0.3 parts of water-reducing agent.
3. according to any impermeabilisation LP blades aluminium melting furnace molten bath castables of claim 1-2, which is characterized in that
The grain size of the electrofused mullite particle is 1-5mm;
The grain size of the plate diamond spar particle is 1mm;
The granularity of the plate diamond spar fine powder is 0.046mm;
The granularity of the carbide fine powder is 0.046mm;
The granularity of the α types calcining activated alumina is 0.003mm;
The granularity of the ρ types calcined alumina is 0.046mm;
The granularity of the kyanite is 0.15mm.
4. according to any impermeabilisation LP blades aluminium melting furnace molten bath castables of claim 1-2, which is characterized in that
Al in the electrofused mullite particle2O3Mass percentage content be 68-72%;
Al in the plate diamond spar particle2O3Mass percentage content >=98%;
Al in the plate diamond spar fine powder2O3Mass percentage content >=98%;
Mass percentage content >=95% of SIC in the carbide fine powder;
Al in the α types calcining activated alumina2O3Mass percentage content >=99%;
Al in the ρ types calcined alumina2O3Mass percentage content >=85%;
Al in the kyanite2O3Mass percentage content >=56%;
Al in the pure calcium aluminate cement2O3Mass percentage content >=70%;
BaSO in the blanc fixe4Mass percentage content >=98%;
Al in the industrial potassium titanate2O3Mass percentage content >=99%.
5. according to any impermeabilisation LP blades aluminium melting furnace molten bath castables of claim 1-2, which is characterized in that described Water-reducing agent is powder polycarboxylic acids water reducing agent.
6. a kind of preparation method of impermeabilisation LP blades aluminium melting furnace molten bath castable as described in claim 1-2 is any, It is characterized in that, includes the following steps:
(1) each raw material is weighed according to above-mentioned formula, it is spare;
(2) by plate diamond spar fine powder, carbide fine powder, α types calcining activated alumina, ρ types calcined alumina, kyanite, fine aluminium Sour calcium cement, blanc fixe, industrial potassium titanate add in and ball milling blending are carried out in tubulose ball mill, and Ball-milling Time is 20-50 points Clock forms blending milling component;
(3) electrofused mullite particle, plate diamond spar particle and water-reducing agent with blending milling component obtained by upper step are mixed, made It is more than 1m with volume3Pressure planetary mixing and blending machine mixed material is stirred, be mixed the time be 5-15 minutes.
7. the preparation method of impermeabilisation LP blades aluminium melting furnace molten bath according to claim 6 castable, which is characterized in that The order of addition of the step (3) is:Electrofused mullite particle and plate diamond spar particle are first added in, then adds blending milling component, It is eventually adding water-reducing agent.
8. the preparation method of impermeabilisation LP blades aluminium melting furnace molten bath according to claim 6 castable, which is characterized in that Ball-milling Time in the step (2) is 30 minutes.
9. the preparation method of impermeabilisation LP blades aluminium melting furnace molten bath according to claim 6 castable, which is characterized in that The mixing time in the step (3) is 8 minutes.
CN201611187398.XA 2016-12-20 2016-12-20 A kind of impermeabilisation LP blades aluminium melting furnace molten bath castable Pending CN108203306A (en)

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CN202310583558.6A CN116425557A (en) 2016-12-20 2016-12-20 Impervious anti-corrosion aluminum smelting furnace molten pool castable
CN201611187398.XA CN108203306A (en) 2016-12-20 2016-12-20 A kind of impermeabilisation LP blades aluminium melting furnace molten bath castable

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