CN108201703A - Liquid vaporising unit and liquid evaporation technique - Google Patents

Liquid vaporising unit and liquid evaporation technique Download PDF

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Publication number
CN108201703A
CN108201703A CN201711366052.0A CN201711366052A CN108201703A CN 108201703 A CN108201703 A CN 108201703A CN 201711366052 A CN201711366052 A CN 201711366052A CN 108201703 A CN108201703 A CN 108201703A
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China
Prior art keywords
liquid
gas
disc
housing
evaporated
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CN201711366052.0A
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Chinese (zh)
Inventor
靳兆融
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Mei Qing Technology (beijing) Co Ltd
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Mei Qing Technology (beijing) Co Ltd
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Priority to CN201711366052.0A priority Critical patent/CN108201703A/en
Publication of CN108201703A publication Critical patent/CN108201703A/en
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D1/00Evaporating
    • B01D1/14Evaporating with heated gases or vapours or liquids in contact with the liquid
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D1/00Evaporating
    • B01D1/30Accessories for evaporators ; Constructional details thereof
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D3/00Distillation or related exchange processes in which liquids are contacted with gaseous media, e.g. stripping
    • B01D3/08Distillation or related exchange processes in which liquids are contacted with gaseous media, e.g. stripping in rotating vessels; Atomisation on rotating discs
    • B01D3/085Distillation or related exchange processes in which liquids are contacted with gaseous media, e.g. stripping in rotating vessels; Atomisation on rotating discs using a rotary evaporator
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D9/00Crystallisation
    • B01D9/0018Evaporation of components of the mixture to be separated
    • B01D9/0031Evaporation of components of the mixture to be separated by heating
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/02Treatment of water, waste water, or sewage by heating
    • C02F1/04Treatment of water, waste water, or sewage by heating by distillation or evaporation
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2103/00Nature of the water, waste water, sewage or sludge to be treated
    • C02F2103/08Seawater, e.g. for desalination

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Organic Chemistry (AREA)
  • Heat Treatment Of Water, Waste Water Or Sewage (AREA)
  • Vaporization, Distillation, Condensation, Sublimation, And Cold Traps (AREA)

Abstract

Provide liquid vaporising unit and liquid evaporation technique, liquid vaporising unit includes housing and rotor, and housing is open or closed, for accommodating liquid to be evaporated, rotor is installed in the inside of housing, liquid-inlet and liquid outlet for liquid inlet and outlet to be evaporated are configured on housing;Rotor includes rotation axis and fixed disc on the rotating shaft, and the outer surface of disc can be moistened by the solvent of liquid to be evaporated so that liquid to be evaporated forms one layer of liquid film on the outer surface of disc.Liquid vaporising unit provided by the invention can realize high-efficiency evaporating under liquid non-boiling state.The vaporising device of the present invention is simple in structure, easily fabricated, at low cost.The present invention can be used for the concentration of cryogenic liquid material, crystallization, can be used for carrying out distilation to liquid material;It can be particularly used for concentrating high-concentration waste water, crystallize to realize wastewater zero discharge or the preparing fresh from seawater or bitter.

Description

Liquid vaporising unit and liquid evaporation technique
Technical field
The present invention relates generally to a kind of liquid evaporating technology, is filled more particularly to that need not make the liquid evaporation of liquid boiling It puts and technique, is mainly used in chemical industry and water treatment field.
Background technology
So-called evaporation refers to mixing liquid to be separated heating (or taking decompression measure simultaneously) drawing life to boiling Into steam and condensation obtain condensate liquid, remaining liq is the concentrates different from former mixing liquid.It is evaporated to last can be achieved The separation of the solid matter of liquid and dissolving in a liquid.The main points of evaporation technology:First, to maintain the temperature and pressure of material It is typically that material is made accomplished continuously or intermittently to boil in certain range;Second is that steam is discharged from evaporator in time so that steam Send out saturated vapour pressure of the vapour pressure in device less than the material solvent under operating condition;Third, to prevent the entrainment with steam ejected Liquid.
For needing to be evaporated liquid material (such as seawater and waste water) concentration or making its crystallization therein so as to extract The occasion of dissolved solid, currently used method are to heat the liquid its boiling point or take decompression measure simultaneously, make its boiling It rises, it, in the process can be by cold so as to obtain the crystalline solid (such as concentrated seawater or concentration waste water) of concentrate or dissolved solid The mode of solidifying steam obtains condensate liquid (such as condensed water or distilled water/fresh water) and recycles a part of heat.Specific evaporation technology There are liquid film evaporation technique, flash process, vacuum flashing technique and multiple-effect evaporation technique etc., corresponding equipment includes climbing-film evaporation Device, falling film evaporator, flash distillation plant, vacuum flashing device etc..
In evaporation technology is boiled in traditional adding, in order to maintain the lasting progress of evaporation, liquid material needs constantly pass through heat Exchanger exchanges heat to keep higher temperature.With the progress of evaporation, liquid material constantly concentrates, until solute is just after saturated solution Start to be precipitated.Due to hot-spot on the heat-transfer area of heat exchanger, being more easy to precipitation solute leads to fouling on heat-transfer area, so as to cause Heat transfer efficiency drastically reduces, to maintain to evaporate frequent shutdown progress maintenance clean of having to.In order to improve heat transfer efficiency and delay Adverse effect caused by fouling, some occasions use multiple-effect evaporation technique, but this causes increasing considerably for equipment investment again.Make For special example, water as the various solution or mixed liquor of solvent or carrier evaporation and concentration (as pollutant concentration is very high Waste water), just it is faced with above-mentioned problem.
In addition, occasion existing for having heat mutability substance in not having corresponding heat source or liquid to be evaporated, does not permit Perhaps material is heated very high temperature.Low-temperature evaporation technique will be used in these cases, i.e., in the temperature less than boiling point of liquid Evaporation of the solvent is made to obtain concentrate or crystal under degree, the most commonly used is low-temperature reduced-pressure evaporations.Vacuum flashing technique is that low-temperature reduced-pressure steams One kind of technique is sent out, refers to maintain evaporimeter internal pressure not higher than the saturated vapour pressure of liquid under operation temperature, so as to make liquid Material boiling evaporates purpose to reach very fast.Although maintaining negative pressure that can realize rapid evaporation at a lower temperature, tie up The energy consumption for holding negative pressure is very big, and the cost of equipment is also high.
Do not make the evaporation technology energy consumption that material boils relatively low, but evaporation efficiency is also low, be in particular in that atmospheric low-temperature evaporates Evaporation capacity of the device in unit interval unit volume is extremely low.To reach the evaporation effect identical with other evaporation technologies, normal pressure is low Warm evaporation technology need to manufacture evaporator it is very huge, equipment and place investment greatly increase.
To improve atmospheric low-temperature evaporation efficiency, it is common practice to increase gas-liquid interface contact area and gas phase flow velocity, it is cold But tower is exactly to be designed according to such thinking.It is promoted at the top of tall and big cooling tower using pump handle water, then sprayed in tower Filler on, water flow through from top to bottom under gravity packing layer and the surface of filler formed liquid film.At the top of cooling tower Fan is installed and carries out exhausting, air is made the gap (channel) in filler to be passed through to flow from bottom to top entrainment of vapor, solution It is achieved that cooling and a degree of concentration.But the evaporator of cooling tower form cannot be used for material concentration or crystallization, Because with the progress of evaporation, solution is continuously available concentration, and viscosity is increasing, and the pump energy consumption of circulation conveying material is very big very To so that the pumping of material becomes not realizing, and the temperature of material is also difficult to maintain.
Invention content
In view of the existing evaporation technology evaporation efficiency that material is not made to boil is low, equipment investment is big and cannot be used for material The above situations such as concentration or crystallization, it is proposed that the present invention.It can be under liquid non-boiling state the object of the present invention is to provide one kind Realize the vaporising device and evaporation technology of high-efficiency evaporating.The vaporising device of the present invention is simple in structure, easily fabricated, at low cost.This Invention can be used for the concentration of cryogenic liquid material, crystallization, can be used for carrying out distilation to liquid material;Particularly may be used For being concentrated, being crystallized to realize wastewater zero discharge or the preparing fresh from seawater or bitter to high-concentration waste water.
According to an aspect of the invention, there is provided a kind of liquid vaporising unit, including housing (1) and rotor (2), wherein Housing is open or closed, for accommodating liquid to be evaporated, rotor (2) is equipped in the inside of housing (1), in housing (1) it is configured on for the liquid-inlet (101) and liquid outlet (102) of liquid inlet and outlet to be evaporated and for evacuation of liquid The emptying rate of liquid mouth (105) used;The rotor (2) includes rotation axis (201) and the disc being fixed in rotation axis (201) (202), the outer surface of disc (202) can be moistened by the solvent of liquid to be evaporated so that liquid to be evaporated is in the outer of disc One layer of liquid film is formed on surface.
Preferably, rotor (2) under the drive of driving mechanism (3) with certain rotating speed around the axis of the rotation axis (201) The heart rotates.
Optionally, liquid vaporising unit further includes is also configured on the housing (1) of wind turbine (4) and liquid vaporising unit Gas feed (103) and gas vent (104), gas feed (103) are connected with wind turbine (4), the work gas when wind turbine (4) operates Body passes through the gap of disc (202), goes out from gas vent.
Optionally, liquid vaporising unit further includes gas cavity (106) and gas distributor (1061), gas feed (103) it is connected by gas cavity (106) with gas distributor (1061), working gas enters gas when wind turbine (4) operates Import (103) is uniformly distributed in after gas cavity (106), gas distributor (1061) in the housing (1) of vaporising device.
Optionally, working gas is air, and gas temperature is for room temperature or in the range of 30~200 DEG C.
Optionally, disc (202) is round or regular polygon, they are in parallel, equidistant cloth on rotation axis (201) It puts, basal plane has certain gap to pass through for air-flow between rotation axis (201), adjacent disc (202), works as rotation axis (201) disc (202) rotates therewith as a whole when rotating.
Optionally, the both side surface of disc (202) is even surface or the non-even surface with protrusion/fold.
Optionally, liquid vaporising unit further includes gas-heating apparatus (5) and condensation/drying device (6), is connected by pipeline It connects so that housing (1) works as wind with wind turbine (4), gas-heating apparatus (5), condensation/drying device (6) one gas return path of formation The gas come out when machine operates from gas vent passes through condensation/drying device (6), wind turbine (4), gas-heating apparatus (5) successively, Then housing (1) is returned to through gas feed.
Optionally, spray equipment (7) is also equipped in the housing of liquid vaporising unit, for liquid to be evaporated spray to be arrived Disc surface.
Optionally, in the course of work of liquid vaporising unit so that in the initial level of liquid to be evaporated and/or work Liquid level be in the lower edge position of rotation axis.
Optionally, liquid vaporising unit is used for the concentration of brine, is further equipped with driving mechanism (3) and wind turbine (4), wherein In concentration process so that brine liquid level is higher than the minimum position of disc and less than the lower edge position equal to rotation axis;Operation is driven Motivation structure (3) makes the rotor (2) of liquid vaporising unit be rotated with set rate;Wind turbine (4) is operated, air is made to be blown into gas Body import (103) and be distributed to by flow deflector rotor (2) disc (202) gas feed side, air-flow passes through disc (202) Then liquid vaporising unit is discharged in gap and the surface of purged disc via the gas vent of opposite side (104).
Optionally, under the premise of maintaining the liquid level in liquid vaporising unit constant, by control the increment of brine with Ratio between the discharge capacity of strong brine after concentration controls the salt concentration of the strong brine of the concentration finally obtained or dense Demagnification number, discharge capacity=cycles of concentration of the strong brine after increment/concentration of brine.
Optionally, liquid vaporising unit is used for the crystallization of brine, is further equipped with driving mechanism (3), wind turbine (4), gas and adds Thermal (5) and liquid spraying device (7), liquid spraying device (7) is for strong brine dispersion spray to be concentrated to disc (202) outer surface, for gas-heating apparatus (5) for warm operation gas, the working gas after preheating is passed into shell through wind turbine The gas feed of body, wherein brine crystallization process are as follows:Start driving mechanism (3) and wind turbine (4) successively, be then turned on spray dress Put (7) and gas-heating apparatus (5);Treat that each equipment reaches the spray flow that steady operational status adjusts spray equipment (7) later, So that the hydrops of the bottom of housing (1) is less than predetermined amount.
Optionally, brine crystallization process further includes:So that liquid of the hydrops of housing (1) bottom via housing (1) bottom Evacuation port (105) discharges liquid vaporising unit and is sent to the container or pipeline that strong brine is supplied for spray equipment (7), obtains it Circulating and evaporating.
Optionally, it whenever the salinity crystallized on disc (202) reaches certain thickness, then shuts down, to being crystallized on disc (202) Salinity cleaned or cleared up, in order to avoid the overweight gap between disc (202) of disc (202) becomes too small.
Optionally, liquid vaporising unit is used for preparing fresh, liquid vaporising unit from seawater and is further equipped with driving mechanism (3), wind turbine (4), gas-heating apparatus (5) and gas condensation/drying device (6), is rich in from what liquid vaporising unit ejected The damp and hot air-flow of vapor transfers heat to condensation/drying device (6), then heat is transferred to gas-heating apparatus (5) and is released It releases, heat is transferred again to the working gas of gas coming through heating unit (5), at the same time, in gas condensation/drying At device (6), the Water vapor condensation in damp and hot air-flow is fresh water after collection into liquid water.
Optionally, liquid vaporising unit for evaporating waste water and realizes wastewater zero discharge, and the liquid vaporising unit is equipped with Driving mechanism (3), wind turbine (4), gas-heating apparatus (5), gas condensation/drying device (6) and waste water heating unit (8), evaporation technology includes:Waste water by preheating is by the disc (202) of spray to liquid vaporising unit and in its outer surface Liquid film is formed, between working gas blows over disc (202) under the promotion of wind turbine (4) after gas-heating apparatus (5) heating Gap takes away the moisture of evaporation, and heat is then transferred to gas heating dress when by gas condensation/drying device (6) (5) and/or waste water heating unit (8) are put, the moisture condensed out at gas condensation/drying device (6) is clean steaming Distilled water;And the solid that periodic cleaning and catch tray on piece crystallize.
Optionally, in liquid vaporising unit, gas-heating apparatus (5) and gas condensation/drying device (6) belong to heat pump The component part of system.
According to another aspect of the present invention, a kind of liquid evaporation work carried out using aforesaid liquid vaporising device is provided Skill, including:Liquid to be evaporated is accommodated in the housing so that at least part of disc is submerged in liquid to be evaporated;So that Rotor banding Moving plate piece rotates, rotary course discs different piece sequentially by Hquid to be evaporated, it is outer so as to disc Surface forms liquid film, realizes the evaporation of liquid.
Optionally, the liquid vaporising unit further includes also matches on the housing (1) of wind turbine (4) and liquid vaporising unit Gas feed (103) and gas vent (104) are equipped with, gas feed (103) is connected with wind turbine (4),
Optionally, liquid evaporation technique includes:Wind turbine (4) operates so that and working gas passes through the gap of disc (202), It goes out from gas vent.
Optionally, liquid vaporising unit further includes gas cavity (106) and gas distributor (1061), gas feed (103) it is connected by gas cavity (106) with gas distributor (1061), the liquid evaporation technique includes:Wind turbine (4) operates When working gas enter gas feed (103), be uniformly distributed in steaming after (1061) by gas cavity (106), gas distributor In the housing (1) of transmitting apparatus.
Optionally, the liquid vaporising unit further includes wind turbine (4), gas feed (103), gas vent (104), gas Heating unit (5) and condensation/drying device (6), the liquid evaporation technique include:So that it is preheated through gas-heating apparatus (5) Working gas enter gas feed through wind turbine, passed through from the gap of disc and the surface of purged disc, through gas vent from Liquid vaporising unit is discharged, and the damp and hot air-flow of discharge transfers heat to condensation/drying device (6), then by heating agent in heat pump system Heat is transferred to gas-heating apparatus (5) under the action of the compressor of system to release, so as to which heat is transferred again to stream Working gas through gas-heating apparatus (5).
Optionally, liquid evaporation technique is used for brine concentration technique, and wherein liquid vaporising unit is further equipped with driving mechanism (3) include with wind turbine (4), the liquid evaporation technique:In concentration process so that brine liquid level is higher than disc lowest order It puts and less than the lower edge position equal to rotation axis;Driving mechanism (3) is operated, makes the rotor (2) of liquid vaporising unit with pre- constant speed Rate rotates;Wind turbine (4) is operated, air is blown into gas feed (103) and the disc of rotor (2) is distributed to by flow deflector (202) gas feed side, air-flow passes through the gap of disc (202) and the surface of purged disc, then via opposite side Gas vent (104) discharges liquid vaporising unit.
Optionally, in liquid evaporation technique, by maintaining to control under the premise of the liquid level in liquid vaporising unit is constant Ratio between the discharge capacity of strong brine after the increment of salt manufacturing water and concentration controls the strong brine of the concentration finally obtained Salt concentration or cycles of concentration, discharge capacity=cycles of concentration of the strong brine after increment/concentration of brine.
Optionally, the liquid evaporation technique is used for the crystallization of brine, and liquid vaporising unit is further equipped with driving mechanism (3), wind turbine (4), gas-heating apparatus (5) and liquid spraying device (7), liquid spraying device (7) is for dense what is concentrated Brine dispersion sprays the outer surface to disc (202), and gas-heating apparatus (5) is for warm operation gas, the work after preheating Gas is passed into the gas feed (103) of housing (1) through wind turbine (4), and wherein brine crystallization process is as follows:Start driving machine successively Structure (3) and wind turbine (4), are then turned on spray equipment (7) and gas-heating apparatus (5);Treat that each equipment reaches steady operational status The spray flow of adjustment spray equipment (7) later so that the hydrops of the bottom of housing (1) is less than predetermined amount.
Optionally, brine crystallization process further includes:So that liquid of the hydrops of housing (1) bottom via housing (1) bottom Evacuation port (105) discharges liquid vaporising unit and is sent to the container or pipeline that strong brine is supplied for spray equipment (7), obtains it Circulating and evaporating.
Optionally, liquid evaporation technique further includes:Whenever the salinity crystallized on disc (202) reaches certain thickness, then stop Machine allows solid salinity to be detached from the surface of disc (202) to be collected.
Optionally, liquid evaporation technique is used for preparing fresh, liquid vaporising unit from seawater and is further equipped with driving mechanism (3), wind turbine (4), gas-heating apparatus (5) and gas condensation/drying device (6), prepares fresh water process and includes:From liquid evaporation The steam-laden damp and hot air-flow of richness that device ejects transfers heat to condensation/drying device (6), then heat is transferred to gas Body heating unit (5) releases, and heat is transferred again to the working gas of gas coming through heating unit (5), simultaneously, At gas condensation/drying device (6), the Water vapor condensation in damp and hot air-flow is fresh water after collection into liquid water.
Optionally, in liquid evaporation technique, gas-heating apparatus (5) and gas condensation/drying device (6) are heat pump systems The component part of system, wherein by heat pump system, the steam-laden damp and hot air-flow of richness ejected from liquid vaporising unit is warm Amount passes to condensation/drying device (6), then heat is transferred to gas under the action of the compressor of heat pump system by heating agent and is added Thermal (5) releases, and heat is transferred again to the working gas of gas coming through heating unit (5).
Optionally, the liquid evaporation technique for evaporating waste water and realizes wastewater zero discharge, the liquid vaporising unit It is equipped with driving mechanism (3), wind turbine (4), gas-heating apparatus (5), gas condensation/drying device (6) and waste water heating dress It puts (8), the evaporation technology includes:Waste water by preheating is by the disc (202) of spray to liquid vaporising unit and at it Outer surface forms liquid film, and working gas blows over disc under the promotion of wind turbine (4) after gas-heating apparatus (5) heating (202) moisture of evaporation is taken away in gap, and heat is then transferred to gas when by gas condensation/drying device (6) Body heating unit (5) and/or waste water heating unit (8), the moisture condensed out at gas condensation/drying device (6) are Clean distilled water;And the solid that periodic cleaning and catch tray on piece crystallize.
When needing accelerating liquid evaporation efficiency, on the housing (1) of liquid vaporising unit be configured gas feed (103) and Gas vent (104), gas feed (103) are connected with wind turbine (4), and working gas passes through disc (202) when wind turbine (4) operates Gap, go out from gas vent.
As shown in Figure 4, the working gas to make to be passed through can be uniformly distributed in the housing (1) of vaporising device, gas Import (103) can be connected by gas cavity (106) with gas distributor (1061).When wind turbine (4) operates working gas into Enter gas feed (103), the housing of vaporising device is uniformly distributed in after gas cavity (106), gas distributor (1061) (1) in.
Above-described working gas is generally air, and gas temperature is for room temperature or after preheating in 30~200 DEG C of models In enclosing.
The disc (202) is round or polygon, they are on rotation axis (201) in parallel, equidistant placement, base Face has certain gap to pass through for air-flow between rotation axis (201), adjacent disc (202), when rotation axis (201) turns Disc (202) rotates therewith as a whole when dynamic.The both side surface of disc (202) can be even surface or with protrusion/ The non-even surface of fold.
In the occasion for needing to preheat working gas and collect steam condensate, gas-heating apparatus (5) and cold is further included Solidifying/drying device (6).Housing (1) is connected with wind turbine (4), gas-heating apparatus (5), condensation/drying device by pipeline (6) form a gas return path, the gas come out from gas vent when wind turbine operate pass through successively condensation/drying device (6), Wind turbine (4), gas-heating apparatus (5), then return to housing (1), as shown in Figure 5 through gas feed.
Spray equipment (7) is also equipped in the housing of vaporising device, for spraying liquid to be evaporated to disc Surface.
For ensure liquid vaporising unit normal use, during the work time, should make liquid to be evaporated initial level and/or Liquid level in work is in the lower edge position of rotation axis.
Liquid vaporising unit recited above can be used for preparing fresh and waste water in brine concentration, salt water crystallization, seawater The processes such as zero-emission.
When the liquid vaporising unit is used for brine concentration, simplest situation only needs to be equipped with driving mechanism (3) With wind turbine (4).The process and principle of brine concentration are as follows:Start driving mechanism (3), make the rotor (2) of liquid vaporising unit with Set rate rotates, and then starts wind turbine (4), air is made to be blown into gas feed (103) and is distributed to rotor by flow deflector (2) the gas feed side of disc (202), air-flow pass through disc (202) gap and purged disc surface, then via Gas vent (104) the discharge liquid vaporising unit of opposite side.Ensure brine liquid level higher than disc most in concentration process Lower position and less than equal to rotation axis lower edge position.Under the premise of maintaining the liquid level in liquid vaporising unit constant, pass through Control brine increment and concentration after strong brine discharge capacity between ratio control the dense salt of the concentration finally obtained The salt concentration or cycles of concentration of water, discharge capacity=cycles of concentration of the strong brine after increment/concentration of brine.
When the crystallization for the liquid vaporising unit being used for brine, driving mechanism (3), wind turbine (4), gas can be equipped with Heating unit (5) and liquid spraying device (7).Liquid spraying device (7) is for strong brine dispersion spray to be concentrated to disk The outer surface of piece (202), for warm operation gas, the working gas after preheating is passed into gas-heating apparatus (5) through wind turbine The gas feed of housing.Wherein brine crystallization process is as follows:Start driving mechanism (3) and wind turbine (4) successively, be then turned on spraying Device (7) and gas-heating apparatus (5);Treat that each equipment reaches the spray stream that steady operational status adjusts spray equipment (7) later Amount so that the hydrops of the bottom of housing (1) is less than predetermined amount.The hydrops of housing (1) bottom is discharged by emptying rate of liquid mouth (105) Liquid vaporising unit is simultaneously sent to the container or pipeline that strong brine is supplied for spray equipment (7), it is made to obtain circulating and evaporating.Work as disc (202) salinity crystallized on reaches certain thickness, then shuts down, and the salinity crystallized on disc (202) is cleaned or cleared up, with Exempting from the overweight gap between disc (202) of disc (202) becomes too small.
The liquid vaporising unit is used for from seawater during preparing fresh, for liquid vaporising unit be equipped with driving mechanism (3), Wind turbine (4), gas-heating apparatus (5) and gas condensation/drying device (6).The process of preparing fresh and principle are as follows in seawater: The steam-laden damp and hot air-flow of richness ejected from liquid vaporising unit transfers heat to condensation/drying device (6), Ran Houre Amount is transferred to gas-heating apparatus (5) for warm operation gas via heat pump system.At the same time, in gas condensation/drying At device (6), the Water vapor condensation in damp and hot air-flow is fresh water after collection into liquid water.
When the liquid vaporising unit is used for evaporating waste water and realizes wastewater zero discharge process, driving mechanism can be equipped with (3), wind turbine (4), gas-heating apparatus (5), gas condensation/drying device (6) and waste water heating unit (8).Detailed process Including:Waste water by preheating is formed liquid film, work on the disc (202) of spray to liquid vaporising unit and in its outer surface Gas blows over the gap of disc (202) under the promotion of wind turbine (4) after gas-heating apparatus (5) heating, takes away evaporation Then heat is transferred to gas-heating apparatus (5) and/or waste water by moisture when by gas condensation/drying device (6) Heating unit (8), the moisture condensed out at gas condensation/drying device (6) are clean distilled water, periodic cleaning and The solid that catch tray on piece crystallizes.
When by aforesaid liquid vaporising device for brine concentration, salt water crystallization, preparing fresh and wastewater zero discharge in seawater During process, preparing fresh technique and waste water in brine concentration evaporation technology, brine crystallization and evaporation process, seawater have been corresponded to respectively Technique of zero discharge.More than four kinds of evaporation technologies compared with the existing other techniques being evaporated to non-boiling liquid have flow The advantages such as short, efficient and equipment investment is low.
In conclusion the advantages of various embodiments of the present invention and good effect include one or more of the following items:
(1) disk type designs, and the liquid film surface area that evaporator unit volume interior energy is formed is big, therefore equipment evaporation efficiency It is high.In addition, simple in equipment, easy to manufacture, equipment investment expense are low.
(2) rotatable disk type design, can very easily maintain the liquid film on disc outer surface, and form a film energy consumption It is low.
(3) the cooling tower vaporising device for being traditionally used for solution non-boiling state is not used to the field for needing to concentrate and crystallize It closes.The present apparatus cannot be only used for evaporating, concentrate and crystallizing, can also simultaneously recycling design.
(4) working gas can be natural air or the air by preheating or be by dry sky Gas.
(5) under conditions of having heat source, it is made to maintain to close in addition to warm operation gas can also heat liquid material simultaneously Suitable temperature, to obtain higher evaporation efficiency.
(6) crystallization/fouling occurs mainly on disc (the especially situation of heated working gas), to heat transfer efficiency Influence small, post processing is simple, energy-saving.
(7) liquid material can maintain relatively low temperature, disclosure satisfy that the needs of some special occasions, for example utilize waste heat Handle the situation of waste water or due to the situation for not allowing high temperature in liquid containing special composition.
Description of the drawings
From the detailed description below in conjunction with the accompanying drawings to the embodiment of the present invention, these and/or other aspects of the invention and Advantage will become clearer and be easier to understand, wherein:
Fig. 1 shows the summary schematic elevational view of liquid vaporising unit according to an exemplary embodiment of the present invention;
Fig. 2 shows the schematic left side elevational views of liquid vaporising unit according to an exemplary embodiment of the present invention;
Fig. 3 shows the schematic right-side view of liquid vaporising unit according to an exemplary embodiment of the present invention;
Fig. 4 shows the structure of the liquid vaporising unit according to an exemplary embodiment of the present invention for being used to carry out brine concentration With the schematic illustration of technique;
Fig. 5 shows the liquid evaporation dress according to an exemplary embodiment of the present invention for being used to carry out strong brine crystallization The structure and process schematic representation put;
Fig. 6 shows the structure of the liquid vaporising unit according to an exemplary embodiment of the present invention for being used to carry out sea water desalination And process schematic representation;
Fig. 7 shows the structure of the liquid vaporising unit according to an exemplary embodiment of the present invention for being used to carry out sea water desalination And process schematic representation.
In figure:
1 housing, 101 liquid-inlets, 102 liquid outlets, 103 gas feeds, 104 gas vents, 105 emptying rate of liquid mouths, 2 Rotor, 201 rotation axis, 202 discs, 3 driving mechanisms, 4 wind turbines, 5 gas-heating apparatus, 6 gas condensations/drying device, 106 gas Body cavity, 1061 gas distributors, 7 liquid spraying devices, 8 waste water heating units, 9 heat pump systems.
Specific embodiment
In order to which those skilled in the art is made to more fully understand the present invention, with reference to the accompanying drawings and detailed description to this hair It is bright to be described in further detail.
Fig. 1 shows the summary schematic elevational view of liquid vaporising unit according to an exemplary embodiment of the present invention;Fig. 2 shows The schematic left side elevational view of liquid vaporising unit according to an exemplary embodiment of the present invention is gone out;Fig. 3 is shown according to the present invention The schematic right-side view of the liquid vaporising unit of exemplary embodiment.
As shown in Figs. 1-3, liquid vaporising unit according to an exemplary embodiment of the present invention includes housing 1 and rotor 2.Housing 1 for accommodating liquid to be evaporated, can be open, such as 1 opened upper end of housing is positioned in air or housing 1 can Think it is enclosed, at this time should be equipped with general mood inlet and outlet channel.Be configured on housing 1 for liquid to be evaporated enter and The liquid-inlet 101 and liquid outlet 102 of discharge and the emptying rate of liquid mouth 105 used for evacuation of liquid;In the inside of housing 1 Rotor 2 is installed, the rotor 2 includes rotation axis 201 and the disc 202 being fixed in rotation axis 201, the appearance of disc 202 Face can be moistened by the solvent of liquid to be evaporated so that liquid to be evaporated forms one layer of liquid film on the outer surface of disc.
Housing 1 can also include the emptying rate of liquid mouth (105) used for evacuation of liquid.
In one example, rotor 2 under the drive of driving mechanism 3 with certain rotating speed around the axis of the rotation axis 201 The heart rotates.
In one example, gas feed 103 and gas vent 104, gas are configured on the housing of liquid vaporising unit 1 Body import 103 is connected with wind turbine 4, gap of the working gas across disc 202 when wind turbine 4 operates, from gas vent 104 It goes out.It is passed through the evaporation that gas is capable of accelerating liquid.
In one example, as shown in figure 4, the working gas to make to be passed through can be uniformly distributed in the housing of vaporising device In 1, gas feed 103 can be connected by gas cavity 106 with gas distributor 1061.When wind turbine 4 operates working gas into Enter gas feed 103, be uniformly distributed in the housing 1 of vaporising device after gas cavity 106, gas distributor 1061.
Above-described working gas is generally air, and gas temperature is for room temperature or after preheating in 30~200 DEG C of models In enclosing.
Disc 202 can be round or polygon, it is preferable that they are in parallel, equidistant placement on rotation axis 201, Its basal plane has certain gap to pass through for air-flow between rotation axis 201, adjacent disc 202, when rotation axis 201 rotates When disc 202 rotate therewith as a whole.The both side surface of disc 202 can be even surface or with protrusion/fold Non- even surface.
In the occasion for needing to working gas preheating and collecting steam condensate, liquid vaporising unit can be configured with gas Body heating unit 5 and condensation/drying device 6.By pipeline connect housing 1 and wind turbine 4, gas-heating apparatus 5, condense/ Drying device 6 forms a gas return path, and the gas come out when wind turbine is operated from gas vent fills successively by condensation/drying 6, wind turbine 4, gas-heating apparatus 5 are put, then returns to housing 1 through gas feed, as shown in Figure 5.
Spray equipment 7 is also equipped in the housing of vaporising device, for spraying liquid to be evaporated to disc table Face.
For ensure liquid vaporising unit normal use, during the work time, should make liquid to be evaporated initial level and/or Liquid level in work is in the lower edge position of rotation axis.
Liquid vaporising unit recited above can be used for preparing fresh and waste water in brine concentration, salt water crystallization, seawater The processes such as zero-emission.
When by aforesaid liquid vaporising device for brine concentration, salt water crystallization, preparing fresh and wastewater zero discharge in seawater During process, preparing fresh technique and waste water in brine concentration evaporation technology, brine crystallization and evaporation process, seawater have been corresponded to respectively Technique of zero discharge.More than four kinds of evaporation technologies compared with the existing other techniques being evaporated to non-boiling liquid have flow The advantages such as short, efficient and equipment investment is low.
In conclusion the advantages of embodiment of the present invention and good effect are as follows:
(1) disk type designs, and the liquid film surface area that evaporator unit volume interior energy is formed is big, therefore equipment evaporation efficiency It is high.In addition, simple in equipment, easy to manufacture, equipment investment expense are low.
(2) rotatable disk type design, can very easily maintain the liquid film on disc outer surface, and form a film energy consumption It is low.
(3) the cooling tower vaporising device for being traditionally used for solution non-boiling state is not used to the field for needing to concentrate and crystallize It closes.The liquid vaporising unit of the embodiment of the present invention cannot be only used for evaporating, concentrate and crystallizing, can also simultaneously recycling design.
About this point, it is explained in detail below.Traditional cooling tower is divided into have a filler and two kinds of non-filling, the former is heat Water pump, which is promoted to the top of cooling tower, is distributed spray to the top of filler, and hot water trickles from top to bottom in the gap of filler, Air then flows, that is, form convective motion from bottom to top under the action of the wind turbine of tower top, and gas takes away the moisture of evaporation So that remaining water is cooled down;The latter is also by pump handle hot water distribution spray to tower top, is poured down as raining in torrents, empty Gas then flows from bottom to top under the fan action of tower top, is equally to take away moisture water is made to cool down.Theoretically, such operation Process it is also possible that the liquid water stayed is concentrated, but on Practical Project not used for cooling tower in such purposes 's.The reason is that the cooling tower of filler is because filler is fixed filling, and piling height is usually all higher (in order to abundant Utilize the unsaturation humidity of air), the cost that the solid after crystallization/fouling in packing layer can not be cleared up or be cleared up is too big.Not yet The cooling tower for having filler evaporates moisture by the specific surface area of water droplet, and less efficient and small water droplet can be raised air-flow band It walks solute is caused to lose.Two kinds of cooling towers are not that its evaporation efficiency is low for concentrating/crystallizing another main cause in place, A small amount of moisture is evaporated so that liquid water temperature drop low ten is easily able to spend, but several times or more than ten times of liquid concentration (for example 10 times of concentration just needs 90% moisture evaporation for being equivalent to initial liquid weight to fall), needs most of moisture to steam Hair falls, and just too big with equipment volume if cooling tower, cost is too big.But cooling tower simple structure, it can be built into The structures (cooling tower of such as power plant is all tens meters of height) of the huge scale of construction, than the recirculated cooling water for being more suitable for big flow Cooling is handled.
(4) working gas can be natural air or the air by preheating or be by dry sky Gas.
(5) under conditions of having heat source, it is made to maintain to close in addition to warm operation gas can also heat liquid material simultaneously Suitable temperature, to obtain higher evaporation efficiency.
(6) crystallization/fouling occurs mainly on disc (the especially situation of heated working gas), to heat transfer efficiency Influence small, post processing is simple, energy-saving.
(7) liquid material can maintain relatively low temperature, disclosure satisfy that the needs of some special occasions, for example utilize waste heat Handle the situation of waste water or due to the situation for not allowing high temperature in liquid containing special composition.
This is described by taking preparing fresh in brine concentration, salt water crystallization, seawater and wastewater zero discharge process as an example individually below The application example of invention.
Application examples one:The concentration of strong brine
The application example belongs to the most basic application of the present invention, is simplest application mode.As shown in Figure 4, low temperature steams Transmitting apparatus is only configured with most basic corollary equipment --- driving mechanism 3 and wind turbine 4.Wind turbine 4 is placed in low-temperature evaporation dress in this example The gas feed side put, the air outlet of wind turbine 4 are connected with the gas feed 103 of low-temperature evaporation device.In this example, strong brine Liquid-inlet 101 through low-temperature evaporation device injects low-temperature evaporation device and is stored in the lower part of its housing 1, forms certain liquid Position.Its liquid level is the lower part to the lower edge position close to rotation axis 201 for flooding disc 202 in this example.Start driving machine Structure 3, the rate rotation that the rotor 2 of low-temperature evaporation device has been previously set, its rotating speed is 1~30 rev/min in this example. Subsequent start-up wind turbine 4, air be blown into gas feed 103 and be distributed to by flow deflector rotor 2 disc 202 gas into Mouth side, air-flow pass through the gap of disc 202 and the surface of purged disc, are then discharged via the gas vent of opposite side 104 Low-temperature evaporation device is simultaneously diffused into air.In this process, since the outer surface of disc 202 is hydrophilic, with dense The contact of brine one is i.e. wetted and forms liquid film in its outer surface.With the rotation of rotor 2, strong brine has wet whole discs All outer surfaces are simultaneously covered with liquid film on it.The rotation of rotor is with causing the different parts cycle alternation of disc 202 with strong brine Contact is then by gas flow purging.Disc 202 does not evaporate its liquid film then by the part that strong brine floods under the purging of air-flow In partial moisture, salinity is then retained in remaining liquid film.With the progress of evaporation process, disc 202 incessantly from Part strong brine is taken away in strong brine in the form of liquid film, partial moisture is then evaporated under the purging of air-flow, then salinity The strong brine or the salt grain of partially crystallizable that concentration becomes larger are taken back in the strong brine of 1 lower part of housing storage, and the disc 202 of rotation is again It takes away strong brine ... this process to thicken slightly to continue, strong brine will constantly dry out, the concentration of salinity Increasing, i.e., brine is concentrated.To the concentration or cycles of concentration of concentration brine that control finally obtains, only need to maintain to evaporate The ratio between the increment of brine and the discharge capacity of concentration brine, the benefit of brine are controlled under the premise of liquid level is constant in device To discharge capacity=cycles of concentration of amount/concentration brine.
In the application examples, the evaporation efficiency of liquid vaporising unit is influenced by operating condition.Air is drier, temperature more Height, the more big then evaporation efficiency of air velocity are higher.Therefore the most basic application be liquid vaporising unit efficiency it is lower should With can be used for strengthening the natural evaporation of high-concentration waste water under warm, dry weather conditions.In an experiment, when water temperature is 40 ~50 DEG C, temperature be 15~17 DEG C, the wind speed in disc gap is 1~3m/s, under conditions of air humidity 36%~75%, obtain Obtained the evaporation efficiency (water that every square metre of disc external surface area evaporated in one hour) of 1~2kg/m2/h.
Application examples two:The crystallization of strong brine
As shown in Figure 5, the application example is to carry out a kind of application of crystallization treatment to strong brine under conditions of having heat source Scene belongs to the basic application of low-temperature evaporation device.
In this example, driving mechanism 3, wind turbine 4, gas-heating apparatus 5 are equipped with for low-temperature evaporation device.In addition, this example In be also equipped with liquid spraying device 7 for low-temperature evaporation device.Liquid spraying device 7 in this example is located at the disc 202 of rotor 2 Gap in, effect be to be concentrated strong brine dispersion spray to disc 202 outer surface.When using the present invention, The position of spray equipment is not limited to the arrangement of this example, it can be arranged in low-temperature evaporation device other are any suitable Position, as long as the outer surface of disc can be drenched.
As the same manner as in Example 1, start driving mechanism 3 and wind turbine 4 successively, be then turned on spray equipment 7 and gas heating Device 5.Treat that each equipment reaches the spray flow that steady operational status can adjust spray equipment 7 later so that the bottom of housing 1 Slightly hydrops, to have given play to the evaporability of low-temperature evaporation device as much as possible.The hydrops of 1 bottom of housing can be via its bottom Emptying rate of liquid mouth 105 discharges low-temperature evaporation device and is sent to the container or pipeline that strong brine is supplied for spray equipment 7, obtains it Circulating and evaporating.Control it is proper if, the bottom of housing 1 does not have substantially or seldom hydrops, spray of the strong brine on disc 202 at this time Leaching rate substantially obtains balance with its evaporation rate, and moisture is substantially all to be evaporated, and salinity is then crystallized in the outer of disc 202 On surface.The salinity for treating to crystallize on disc 202 reaches certain thickness, should shut down, and takes measures that solid salinity is allowed to be detached from disc 202 surface is so as to be collected, and then cryogenic vaporizer can come into operation again.
The operating principle of the application example with process is with application examples 1, difference is for purging disc outer surface Air-flow is the air by preheating, it is hereby achieved that higher evaporation efficiency, an equal amount of low-temperature evaporation device can be sent out Shoot the evaporability of bigger.
In, the heating efficiency or power of gas-heating apparatus depend on the flow and Wen Sheng of working gas, and enter The temperature of the working gas of low-temperature evaporation device should be not higher than the material for being used for making disc and low-temperature evaporation device other component The highest tolerable temperature of material.
Application examples three:Sea water desalination
As shown in Figure 6, in the application example, low-temperature evaporation device is used for preparing fresh (distilled water) from seawater. Driving mechanism 3, wind turbine 4, gas-heating apparatus 5 and gas condensation/drying device 6 are equipped with to low-temperature evaporation device thus, Middle gas-heating apparatus 5 and gas condensation/drying device 6 are provided using heat pump, and gas-heating apparatus 5 and gas are cold in other words Solidifying/drying device 6 belongs to the component part of heat pump system.Its operation logic is about with process with the application examples of front 's.By heat pump, the steam-laden damp and hot air-flow of richness ejected from low-temperature evaporation device transfers heat to condensation/drying dress 6 are put, then heat is transferred to gas-heating apparatus 5 under the action of the compressor of heat pump system by heating agent and is released, heat Amount is transferred again to the working gas of gas coming through heating unit 5.At the same time, it is damp and hot at gas condensation/drying device 6 Water vapor condensation in air-flow is fresh water after collection into liquid water.
In the application examples, the seawater into low-temperature evaporation device can be natural seawater or pass through suitably The seawater of processing, including purified treatment and/or heat treatment.Such as include heating seawater work, heating source may be used But it is not limited to solar energy, electric energy or steam.
Application examples four:Wastewater zero discharge processing
As shown in Figure 7, in the application examples, low-temperature evaporation device is used for evaporating waste water and realizes wastewater zero discharge.
Thus driving mechanism 3, wind turbine 4, gas-heating apparatus 5, gas condensation/drying dress are equipped with to low-temperature evaporation device Put 6 and waste water heating unit 8.Wherein gas-heating apparatus 5 and gas condensation/drying device 6 belong to the composition portion of heat pump Point.The heat source of waste water heating unit 8 can be heat pump system or waste heat utilization system or other heat sources.
During operation, the waste water by preheating is sprayed on the disc 202 of low-temperature evaporation device and in its outer surface and is formed Liquid film, working gas blow over the gap of disc 202 after the heating of gas-heating apparatus 5 under the promotion of wind turbine 4, take away evaporation Moisture, then by transferring heat to the heating agent of heat pump system when gas condensation/drying device 6, then this portion Heat is divided to be transferred to gas-heating apparatus 5 and/or waste water heating unit 8.It is condensed out at gas condensation/drying device 6 Moisture be clean distilled water, for this part water recoverable or be discharged into environment.In low-temperature evaporation device Portion includes the solid for crystallizing to get off on disc and makees appropriate disposition after periodic cleaning, collection.
Various embodiments of the present invention are described above, above description is exemplary, and non-exclusive, and It is not limited to disclosed each embodiment.In the case of without departing from the scope and spirit of illustrated each embodiment, for this skill Many modifications and changes will be apparent from for the those of ordinary skill in art field.Therefore, protection scope of the present invention should This is subject to the protection scope in claims.

Claims (10)

1. a kind of liquid vaporising unit, including housing (1) and rotor (2), wherein
Housing is open or closed, for accommodating liquid to be evaporated, rotor (2) is equipped in the inside of housing (1), in shell It is configured on body (1) for the liquid-inlet (101) of liquid inlet and outlet to be evaporated and liquid outlet (102);
The rotor (2) includes rotation axis (201) and the disc (202) being fixed in rotation axis (201), disc (202) it is outer Surface can be moistened by the solvent of liquid to be evaporated so that liquid to be evaporated forms one layer of liquid film on the outer surface of disc.
2. liquid vaporising unit according to claim 1, it is characterised in that:Driving mechanism (3) is further included, rotor (2) exists It is rotated under the drive of driving mechanism (3) with certain rotating speed around the axle center of the rotation axis (201).
3. liquid vaporising unit according to claim 1 further includes the housing (1) of wind turbine (4) and liquid vaporising unit On be also configured with gas feed (103) and gas vent (104), gas feed (103) is connected with wind turbine (4), when wind turbine (4) transport Working gas passes through the gap of disc (202) when turning, and goes out from gas vent.
4. liquid vaporising unit according to claim 3 further includes gas cavity (106) and gas distributor (1061), Gas feed (103) is connected by gas cavity (106) with gas distributor (1061), the working gas when wind turbine (4) operates Into gas feed (103), the shell of vaporising device is uniformly distributed in after gas cavity (106), gas distributor (1061) In body (1).
5. liquid vaporising unit according to claim 3, working gas is air, gas temperature for room temperature or 30~ In the range of 200 DEG C.
6. liquid vaporising unit according to claim 1, disc (202) is round or regular polygon, they are in rotation axis (201) in parallel, equidistant placement on, basal plane have between rotation axis (201), adjacent disc (202) it is certain between Gap passes through for air-flow, and disc (202) rotates therewith as a whole when rotation axis (201) rotates.
7. the liquid vaporising unit according to claim 1 or 6, the both side surface of disc (202) is even surface or with convex Play/non-the even surface of fold.
8. according to claim 2 to 6 any one of them liquid vaporising unit, which is characterized in that further include gas-heating apparatus (5) and gas condensation/drying device (6) housing (1), is connected with wind turbine (4), gas-heating apparatus (5), cold by pipeline Solidifying/drying device (6) forms a gas return path, the gas come out from gas vent when wind turbine operate successively through condensation/ Drying device (6), wind turbine (4), gas-heating apparatus (5), then return to housing (1) through gas feed.
9. according to claim 1 to 6 any one of them liquid vaporising unit, spray equipment (7) is also equipped in middle casing, For spraying liquid to be evaporated to disc surface.
10. the liquid evaporation technique that a kind of liquid vaporising unit using claim 1 carries out, accommodates liquid to be evaporated in the housing Body so that at least part of disc is submerged in liquid to be evaporated;
So that the rotation of rotor banding Moving plate piece, rotary course discs different piece sequentially by Hquid to be evaporated, so as to The outer surface of disc forms liquid film, realizes the evaporation of liquid.
CN201711366052.0A 2017-12-18 2017-12-18 Liquid vaporising unit and liquid evaporation technique Pending CN108201703A (en)

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CN110530193A (en) * 2019-07-31 2019-12-03 朱玲燕 A kind of new-type cooling tower turntable and its corollary system
CN110844953A (en) * 2018-08-21 2020-02-28 国家能源投资集团有限责任公司 Evaporation device
CN111359245A (en) * 2020-04-01 2020-07-03 广东两山科技有限公司 Ionic liquid purification device and using method thereof
CN112255348A (en) * 2020-09-29 2021-01-22 江西志科检测技术有限公司 Pretreatment method for detecting content of dioxin in soil
CN113476871A (en) * 2021-06-03 2021-10-08 广西锦东自动化设备有限公司 Multi-effect evaporation control process for one-time tank passing by self pressure difference
CN113513799A (en) * 2021-07-23 2021-10-19 广东电网有限责任公司 Ventilation device

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CN113476871A (en) * 2021-06-03 2021-10-08 广西锦东自动化设备有限公司 Multi-effect evaporation control process for one-time tank passing by self pressure difference
CN113513799A (en) * 2021-07-23 2021-10-19 广东电网有限责任公司 Ventilation device

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Application publication date: 20180626