CN108192795B - Tower-type gas-liquid two-state alcohol distillation and extraction system - Google Patents
Tower-type gas-liquid two-state alcohol distillation and extraction system Download PDFInfo
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- CN108192795B CN108192795B CN201810036392.5A CN201810036392A CN108192795B CN 108192795 B CN108192795 B CN 108192795B CN 201810036392 A CN201810036392 A CN 201810036392A CN 108192795 B CN108192795 B CN 108192795B
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- 238000004821 distillation Methods 0.000 title claims abstract description 57
- 239000007788 liquid Substances 0.000 title claims abstract description 47
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 title claims abstract description 36
- 238000000605 extraction Methods 0.000 title claims abstract description 15
- 238000001125 extrusion Methods 0.000 claims abstract description 29
- 238000009833 condensation Methods 0.000 claims description 5
- 230000005494 condensation Effects 0.000 claims description 5
- 238000007599 discharging Methods 0.000 claims description 5
- 230000001276 controlling effect Effects 0.000 claims description 3
- 238000001914 filtration Methods 0.000 claims description 3
- 230000001105 regulatory effect Effects 0.000 claims description 3
- 230000001737 promoting effect Effects 0.000 claims 1
- 238000004519 manufacturing process Methods 0.000 abstract description 3
- 239000002699 waste material Substances 0.000 abstract description 2
- 235000013339 cereals Nutrition 0.000 description 7
- 230000000694 effects Effects 0.000 description 3
- 238000005265 energy consumption Methods 0.000 description 3
- 238000010795 Steam Flooding Methods 0.000 description 2
- 238000001704 evaporation Methods 0.000 description 2
- 230000008020 evaporation Effects 0.000 description 2
- 125000002485 formyl group Chemical class [H]C(*)=O 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 235000016735 Manihot esculenta subsp esculenta Nutrition 0.000 description 1
- 241000658379 Manihot esculenta subsp. esculenta Species 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 238000000855 fermentation Methods 0.000 description 1
- 230000004151 fermentation Effects 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 235000000346 sugar Nutrition 0.000 description 1
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- C—CHEMISTRY; METALLURGY
- C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
- C12G—WINE; PREPARATION THEREOF; ALCOHOLIC BEVERAGES; PREPARATION OF ALCOHOLIC BEVERAGES NOT PROVIDED FOR IN SUBCLASSES C12C OR C12H
- C12G3/00—Preparation of other alcoholic beverages
-
- C—CHEMISTRY; METALLURGY
- C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
- C12H—PASTEURISATION, STERILISATION, PRESERVATION, PURIFICATION, CLARIFICATION OR AGEING OF ALCOHOLIC BEVERAGES; METHODS FOR ALTERING THE ALCOHOL CONTENT OF FERMENTED SOLUTIONS OR ALCOHOLIC BEVERAGES
- C12H6/00—Methods for increasing the alcohol content of fermented solutions or alcoholic beverages
- C12H6/02—Methods for increasing the alcohol content of fermented solutions or alcoholic beverages by distillation
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Health & Medical Sciences (AREA)
- Biochemistry (AREA)
- Bioinformatics & Cheminformatics (AREA)
- General Engineering & Computer Science (AREA)
- General Health & Medical Sciences (AREA)
- Genetics & Genomics (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Food Science & Technology (AREA)
- Vaporization, Distillation, Condensation, Sublimation, And Cold Traps (AREA)
Abstract
The invention belongs to the technical field of alcohol production, and particularly relates to a tower-type gas-liquid two-state alcohol distillation and extraction system which comprises a distillation box, a vinasse basket, a cylinder unit, an extrusion unit, a loosening unit and a condensing chamber, wherein the distillation box is arranged in the distillation box; the distillation box is arranged on the ground, a plurality of vinasse baskets are prevented from being arranged in the vertical direction, and the distillation box is used for distilling alcohol; the vinasse basket is positioned inside the distillation box and used for placing vinasse; the air cylinder units are positioned on two sides of the vinasse basket, the air cylinder units are fixedly connected with the vinasse basket, and the air cylinder units are used for lifting the vinasse basket; the extruding unit is positioned below the vinasse basket, fixedly connected with the vinasse basket, and used for extruding vinasse; the loosening unit is arranged below the extrusion unit and is used for loosening the compacted vinasse; the condensing chamber is used for condensing alcohol vapor. The invention can improve the distillation efficiency of alcohol and reduce energy waste.
Description
Technical Field
The invention belongs to the technical field of alcohol production, and particularly relates to a tower-type gas-liquid two-state alcohol distillation and extraction system.
Background
The wine can be made into edible alcohol by fermenting and distilling grains, cassava and sugar materials. With the national improvement of the standard of edible alcohol, the deterioration of domestic water resource conditions and the increasing shortage of global energy, it is urgent to find a new process which can improve the quality of edible alcohol, reasonably and fully utilize water resources, improve distillation efficiency and reduce energy consumption.
Some technical solutions for alcohol distillation also appear in the prior art, for example, a chinese patent with application number 201210450034.1 discloses an alcohol differential pressure distillation production apparatus, which comprises a mash tower, an aldehyde tower, a rectification tower, a condenser group, a preheater, a reboiler group and a flash evaporator, wherein the mash tower adopts reduced pressure distillation, the aldehyde tower adopts atmospheric distillation, and the rectification tower adopts a differential pressure distillation mode of pressure distillation. But the distillation device in the technical scheme has the advantages of complex structure, low distillation efficiency and high energy consumption.
In view of this, the tower-type gas-liquid two-state alcohol distillation and extraction system can greatly improve the distillation efficiency and reduce the energy waste.
Disclosure of Invention
In order to make up for the defects of the prior art, the invention provides a tower-type gas-liquid two-state alcohol distillation and extraction system which is mainly used for distilling alcohol, the utilization rate of a distillation box is improved by placing a plurality of vinasse baskets in the distillation box, and in addition, the distillation efficiency can be greatly improved by the equipment, and the use of energy sources is reduced.
The technical scheme adopted by the invention for solving the technical problems is as follows: the invention relates to a tower-type gas-liquid alcohol distillation extraction system, which comprises a distillation box, a vinasse basket, a cylinder unit, an extrusion unit, a loosening unit and a condensing chamber, wherein the distillation box is connected with the cylinder unit; the distillation box is rectangular, is placed on the ground, is provided with a plurality of vinasse baskets in the vertical direction and is used for distilling alcohol; the vinasse basket is positioned inside the distillation box and used for placing vinasse; the air cylinder units are positioned on two sides of the vinasse basket, the air cylinder units are fixedly connected with the vinasse basket, and the air cylinder units are used for lifting the vinasse basket; the extruding unit is positioned below the vinasse basket, the extruding unit is fixedly connected with the vinasse basket, the extruding unit is in a circular table shape, and the extruding unit is used for extruding vinasse; the loosening unit is arranged below the extrusion unit and is used for loosening the compacted vinasse; the condensation chamber is positioned at the top of the distillation box and is used for condensing alcohol vapor. When the device works, the air cylinder unit drives the vinasse basket to move downwards, the extrusion unit at the bottom of the vinasse basket compacts vinasse in the vinasse basket below the extrusion unit to extrude liquid in the vinasse, and the liquid flows into the circular-table-shaped cavity in the extrusion unit through the circular hole; when the cylinder unit drives the vinasse basket to move upwards, the loosening unit loosens the compacted vinasse, and the liquid in the truncated cone-shaped cavity can be discharged through the liquid outlet after the liquid is filled.
Preferably, the vinasse basket comprises a disc basket bottom, a basket wall and a lifting lug, wherein the disc basket bottom is used for fixing the vinasse basket, a circular hole is formed in the disc basket bottom, a filter screen is arranged in the circular hole, and the filter screen is used for filtering vinasse; the basket wall is fixed on the upper surface of the disc basket bottom, the basket wall is of a circular truncated cone structure, a circular truncated cone-shaped through hole is formed in the upper surface of the basket wall, the disc basket bottom and the basket wall are matched for containing vinasse, a circular hole is formed in the basket wall, and a filter screen is installed in the circular hole; the lifting lug is arranged on the upper part of the basket wall and used for lifting. During operation, the lees has been held in the lees basket, and the steam drives the alcohol evaporation through circular hole in the disc basket bottom, and for raising the efficiency, the lees basket can reciprocate, extrudees the lees in the lees basket of below for go out wine efficiency.
Preferably, the cylinder unit comprises a cylinder, a piston and a piston rod; the air cylinder is fixed on the upper surface of the vinasse basket and used for regulating and controlling the lifting of the vinasse basket; the piston is positioned in the cylinder and used for pushing the piston rod to move; the piston rod is connected with the lower surface of the piston, the lower end of the piston rod is fixedly connected with the next cylinder unit, and the piston rod is used for pushing the vinasse basket to vertically move. During operation, the air inlet of the air cylinder is filled with high-pressure steam, the piston rod drives the vinasse basket to move upwards, and the last extrusion unit extrudes vinasse in the vinasse basket, so that the vinasse discharging efficiency is accelerated.
Preferably, the extrusion unit comprises a truncated cone-shaped cavity, a steam inlet and a liquid outlet; the truncated cone-shaped cavity is welded below the vinasse basket and used for containing liquid flowing out of the vinasse basket and extruding vinasse in the vinasse basket below; the steam inlet is positioned on the right side wall of the circular truncated cone-shaped cavity and is provided with an electromagnetic door, and the steam inlet is used for the entry of high-pressure steam; the liquid outlet is positioned at the lower right corner of the truncated cone-shaped cavity and is provided with an electromagnetic door, and the liquid outlet is used for discharging the liquid in the truncated cone-shaped cavity. During operation, the extrusion unit is matched with the air cylinder unit and is matched with the air cylinder unit, and the extrusion unit moves up and down to extrude vinasse in the next vinasse basket.
Preferably, the loose unit comprises a strut and a barb; the support rod is fixed at the bottom of the extrusion unit and used for fixing the barb; the barb is located the lower extreme of branch, and the barb is used for loosening the lees in the lees basket. When the distiller's grains loosening device works, the loosening unit compacts the distiller's grains along with the extrusion unit, the loosening unit is immersed in the distiller's grains, and when the extrusion unit leaves the distiller's grains basket below, the barb of the loosening unit pulls the distiller's grains backwards to loosen the distiller's grains.
The invention has the beneficial effects that:
1. according to the tower-type gas-liquid two-state alcohol distillation and extraction system, the distillation effect of alcohol is accelerated mainly by utilizing the extrusion effect, high-pressure steam is used as the power of the air cylinder, the energy consumption is reduced, and in addition, a plurality of vinasse baskets can be placed in the distillation box to improve the utilization rate of the distillation box.
2. According to the tower-type gas-liquid two-state alcohol distillation and extraction system, the extrusion unit and the loosening unit are matched with each other, liquid is extruded out by extruding vinasse, and the vinasse is loosened by the loosening unit, so that steam can conveniently enter the vinasse later, and the alcohol distillation efficiency is improved.
3. According to the biogas fermentation tank with the cleaning function, the air cylinder unit utilizes high-pressure steam as power, so that energy is saved, and the source of the high-pressure steam is convenient.
Drawings
The invention will be further explained with reference to the drawings.
FIG. 1 is a front view of the present invention;
in the figure: the device comprises a distillation box 1, a vinasse basket 2, a disc basket bottom 21, a basket wall 22, a lifting lug 23, a cylinder unit 3, a cylinder 31, a piston 32, a piston rod 33, a squeezing unit 4, a truncated cone-shaped cavity 41, a steam inlet 42, a liquid outlet 43, a loosening unit 5, a support rod 51, a barb 52 and a condensing chamber 6.
Detailed Description
In order to make the technical means, the creation characteristics, the achievement purposes and the effects of the invention easy to understand, the invention is further described with the specific embodiments.
As shown in figure 1, the tower-type gas-liquid two-phase alcohol distillation and extraction system comprises a distillation box 1, a vinasse basket 2, a cylinder unit 3, an extrusion unit 4, a loosening unit 5 and a condensing chamber 6; the distillation box 1 is rectangular, the distillation box 1 is placed on the ground, a plurality of vinasse baskets 2 are placed in the vertical direction, and the distillation box 1 is used for distilling alcohol; the vinasse basket 2 is positioned inside the distillation box 1, and the vinasse basket 2 is used for placing vinasse; the air cylinder units 3 are positioned on two sides of the vinasse basket 2, the air cylinder units 3 are fixedly connected with the vinasse basket 2, and the air cylinder units 3 are used for lifting the vinasse basket 2; the extruding unit 4 is positioned below the vinasse basket 2, the extruding unit 4 is fixedly connected with the vinasse basket 2, the extruding unit 4 is in a circular table shape, and the extruding unit 4 is used for extruding vinasse; the loosening unit 5 is arranged below the extrusion unit 4, and the loosening unit 5 is used for loosening the compacted vinasse; the condensation chamber 6 is positioned at the top of the distillation box 1, and the condensation chamber 6 is used for condensing alcohol vapor. When the device works, the air cylinder unit 3 drives the vinasse basket 2 to move downwards, the extrusion unit 4 at the bottom of the vinasse basket 2 compacts vinasse in the vinasse basket 2 below, liquid in the vinasse is extruded out, and the liquid flows into the truncated cone-shaped cavity 41 in the extrusion unit 4 through the circular hole; when the cylinder unit 3 drives the vinasse basket 2 to move upwards, the loosening unit 5 loosens the compacted vinasse, and the liquid in the truncated cone-shaped cavity 41 can be discharged through the liquid outlet 43 after the liquid is full.
As an embodiment of the invention, the vinasse basket comprises a disc basket bottom, a basket wall and a lifting lug, wherein the disc basket bottom is used for fixing the vinasse basket, a circular hole is formed in the disc basket bottom, a filter screen is arranged in the circular hole, and the filter screen is used for filtering vinasse; the basket wall is fixed on the upper surface of the disc basket bottom, the basket wall is of a circular truncated cone structure, a circular truncated cone-shaped through hole is formed in the upper surface of the basket wall, the disc basket bottom and the basket wall are matched for containing vinasse, a circular hole is formed in the basket wall, and a filter screen is installed in the circular hole; the lifting lug is arranged on the upper part of the basket wall and used for lifting. During operation, the lees has been held in lees basket 2, and the steam drives the alcohol evaporation through circular hole in 21 at the bottom of the disc basket, and for raising the efficiency, lees basket 2 can reciprocate, extrudees the lees in lees basket 2 of below for go out wine efficiency.
As an embodiment of the present invention, the cylinder unit 3 includes a cylinder 31, a piston 32, and a piston rod 33; the cylinder 31 is fixed on the upper surface of the vinasse basket 2, and the cylinder 31 is used for regulating and controlling the lifting of the vinasse basket 2; the piston 32 is positioned in the cylinder 31, and the piston 32 is used for pushing the piston rod 33 to move; the piston rod 33 is connected with the lower surface of the piston 32, the lower end of the piston rod 33 is fixedly connected with the next cylinder unit 3, and the piston rod 33 is used for pushing the vinasse basket 2 to vertically move. During operation, the air inlet of the air cylinder 31 is filled with high-pressure steam, the piston rod 33 drives the vinasse basket 2 to move upwards, and the last extrusion unit 4 extrudes vinasse in the vinasse basket 2, so that the vinasse discharging efficiency is accelerated.
As an embodiment of the present invention, the extruding unit 4 includes a truncated cone shaped cavity 41, a steam inlet 42 and a liquid outlet 43; the truncated cone-shaped cavity 41 is welded below the vinasse basket 2, and the truncated cone-shaped cavity 41 is used for containing liquid flowing out of the vinasse basket 2 and extruding vinasse in the vinasse basket 2 below; the steam inlet 42 is positioned on the right side wall of the truncated cone-shaped cavity 41 and is provided with an electromagnetic door, and the steam inlet 42 is used for the entrance of high-pressure steam; the liquid outlet 43 is positioned at the lower right corner of the truncated cone-shaped cavity 41 and is provided with an electromagnetic door, and the liquid outlet 43 is used for discharging the liquid in the truncated cone-shaped cavity 41. During operation, 4 supporting of extrusion unit and 3 mutually supporting of cylinder unit, extrusion unit 4 reciprocates and extrudees the lees in the lees basket 2 next.
As an embodiment of the present invention, the loosening unit 5 includes a support rod 51 and a barb 52; the supporting rod 51 is fixed at the bottom of the extrusion unit 4, and the supporting rod 51 is used for fixing the barb 52; the barb 52 is positioned at the lower end of the support rod 51, and the barb 52 is used for loosening vinasse in the vinasse basket 2. In operation, the loosening unit 5 compacts the vinasse along with the extrusion unit 4, the loosening unit 5 is immersed in the vinasse, and when the extrusion unit 4 leaves the vinasse basket 2 below, the barbs 52 of the loosening unit 5 pull the vinasse backwards to loosen the vinasse.
When the device works, high-pressure steam enters the truncated cone-shaped cavity 41 through the steam inlet 42 of the extrusion unit 4, and the steam enters vinasse in the vinasse basket 2 through the circular hole and carries wine steam out; when high-pressure steam is introduced into an air inlet of the air cylinder 31, the piston rod 33 pushes the vinasse basket 2 to move upwards, the extruding unit 4 extrudes vinasse, extruded liquid flows out through the circular hole and flows into the truncated cone-shaped cavity 41, the truncated cone-shaped cavity 41 is provided with a liquid outlet 43, and the liquid can be discharged from the liquid outlet 43 when the liquid is full; when steam is discharged from the air outlet of the air cylinder 31, the vinasse basket 2 restores to the original position, and the barbs 52 immersed in the vinasse pull the vinasse backwards to loosen the vinasse.
The foregoing illustrates and describes the principles, general features, and advantages of the present invention. It will be understood by those skilled in the art that the present invention is not limited to the embodiments described above, which are given by way of illustration of the principles of the present invention, and that various changes and modifications may be made without departing from the spirit and scope of the invention as defined by the appended claims. The scope of the invention is defined by the appended claims and equivalents thereof.
Claims (5)
1. A tower gas-liquid two-state alcohol distillation extraction system is characterized in that: the device comprises a distillation box (1), a vinasse basket (2), a cylinder unit (3), an extrusion unit (4), a loosening unit (5) and a condensing chamber (6), wherein the distillation box (1) is rectangular, the distillation box (1) is placed on the ground, and the distillation box (1) is used for distilling alcohol; the vinasse basket (2) is positioned inside the distillation box (1), a plurality of vinasse baskets (2) are arranged in the vertical direction, and the vinasse baskets (2) are used for containing vinasse; the air cylinder units (3) are positioned on two sides of the vinasse basket (2), the air cylinder units (3) are fixedly connected with the vinasse basket (2), and the air cylinder units (3) are used for lifting the vinasse basket (2); the extruding unit (4) is positioned below the vinasse basket (2), the extruding unit (4) is fixedly connected with the vinasse basket (2), the extruding unit (4) is in a circular table shape, and the extruding unit (4) is used for extruding vinasse; the loosening unit (5) is arranged below the extruding unit (4), and the loosening unit (5) is used for loosening the compacted vinasse; the condensation chamber (6) is positioned at the top of the distillation box (1), and the condensation chamber (6) is used for condensing alcohol vapor.
2. The tower-type gas-liquid two-state alcohol distillation and extraction system according to claim 1, characterized in that: the vinasse basket (2) comprises a disc basket bottom (21), a basket wall (22) and a lifting lug (23), wherein the disc basket bottom (21) is used for fixing the vinasse basket (2), the disc basket bottom (21) is provided with a circular hole, a filter screen is arranged on the circular hole, and the filter screen is used for filtering vinasse; the basket wall (22) is fixed on the upper surface of the disc basket bottom (21), the basket wall (22) is of a circular truncated cone structure, a circular truncated cone-shaped through hole is formed in the upper surface of the basket wall (22), the disc basket bottom (21) and the basket wall (22) are matched for containing vinasse, a circular hole is formed in the basket wall (22), and a filter screen is installed in the circular hole; the lifting lug (23) is arranged on the upper part of the basket wall (22), and the lifting lug (23) is used for hoisting.
3. The tower-type gas-liquid two-state alcohol distillation and extraction system according to claim 1, characterized in that: the air cylinder unit (3) comprises an air cylinder (31), a piston (32) and a piston rod (33), the air cylinder (31) is fixed on the upper surface of the vinasse basket (2), and the air cylinder (31) is used for regulating and controlling the lifting of the vinasse basket (2); the piston (32) is positioned in the cylinder (31), and the piston (32) is used for pushing the piston rod (33) to move; piston rod (33) and piston (32) lower surface connect, piston rod (33) lower extreme and next cylinder unit (3) fixed connection, piston rod (33) are used for promoting lees basket (2) vertical movement.
4. The tower-type gas-liquid two-state alcohol distillation and extraction system according to claim 1, characterized in that: the extruding unit (4) comprises a truncated cone-shaped cavity (41), a steam inlet (42) and a liquid outlet (43), the truncated cone-shaped cavity (41) is welded below the vinasse basket (2), and the truncated cone-shaped cavity (41) is used for containing liquid flowing out of the vinasse basket (2) and extruding vinasse in the vinasse basket (2) below; the steam inlet (42) is positioned on the right side wall of the circular truncated cone-shaped cavity (41) and is provided with an electromagnetic door, and the steam inlet (42) is used for the entrance of high-pressure steam; the liquid outlet (43) is positioned at the lower right corner of the truncated cone-shaped cavity (41) and is provided with an electromagnetic door, and the liquid outlet (43) is used for discharging the liquid in the truncated cone-shaped cavity (41).
5. The tower-type gas-liquid two-state alcohol distillation and extraction system according to claim 1, characterized in that: the loosening unit (5) comprises a support rod (51) and a barb (52), the support rod (51) is fixed at the bottom of the extrusion unit (4), and the support rod (51) is used for fixing the barb (52); the barb (52) is positioned at the lower end of the support rod (51), and the barb (52) is used for loosening vinasse in the vinasse basket (2).
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CN201810036392.5A CN108192795B (en) | 2018-01-15 | 2018-01-15 | Tower-type gas-liquid two-state alcohol distillation and extraction system |
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CN108192795B true CN108192795B (en) | 2021-08-13 |
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Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104178406A (en) * | 2014-09-12 | 2014-12-03 | 易治虎 | High-efficiency energy-saving white wine continuous distillation method and device |
CN205275557U (en) * | 2015-12-31 | 2016-06-01 | 邵磊 | Alcohol distillation plant |
CN206167961U (en) * | 2016-11-03 | 2017-05-17 | 天津康巢生物医药股份有限公司 | Distillation and condensation device |
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2018
- 2018-01-15 CN CN201810036392.5A patent/CN108192795B/en active Active
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104178406A (en) * | 2014-09-12 | 2014-12-03 | 易治虎 | High-efficiency energy-saving white wine continuous distillation method and device |
CN205275557U (en) * | 2015-12-31 | 2016-06-01 | 邵磊 | Alcohol distillation plant |
CN206167961U (en) * | 2016-11-03 | 2017-05-17 | 天津康巢生物医药股份有限公司 | Distillation and condensation device |
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Effective date of registration: 20220413 Address after: 710082 room 20810, block B, Kaiai building, No. 1 xihuamen, Lianhu District, Xi'an City, Shaanxi Province Patentee after: SHAANXI HUATIAN WINE INDUSTRY Co.,Ltd. Address before: 150001 Harbin University of Technology, 92 Xidazhi Street, Nangang District, Harbin City, Heilongjiang Province Patentee before: Shen Shu |
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