CN108192018A - A kind of antistatic acrylic resin syntheses processes - Google Patents
A kind of antistatic acrylic resin syntheses processes Download PDFInfo
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- CN108192018A CN108192018A CN201711486139.1A CN201711486139A CN108192018A CN 108192018 A CN108192018 A CN 108192018A CN 201711486139 A CN201711486139 A CN 201711486139A CN 108192018 A CN108192018 A CN 108192018A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
- C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
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- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
- C09D133/14—Homopolymers or copolymers of esters of esters containing halogen, nitrogen, sulfur or oxygen atoms in addition to the carboxy oxygen
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/24—Electrically-conducting paints
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
- C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
- C08F220/1811—C10or C11-(Meth)acrylate, e.g. isodecyl (meth)acrylate, isobornyl (meth)acrylate or 2-naphthyl (meth)acrylate
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Abstract
The invention discloses a kind of antistatic acrylic resin syntheses processes, include the following steps：Input n-butanol in reaction kettle at normal temperatures, is warming up to 90 100 degree, stirs evenly；Monomer, the graphene oxide of methyl methacrylate, n-BMA, acrylic acid, n-butyl acrylate, 2 ethylhexyl of acrylic acid, isobornyl methacrylate, hydroxypropyl acrylate and dibenzoyl peroxide are put into, is stirred evenly；Methyl methacrylate, n-BMA, acrylic acid, butyl acrylate, Isooctyl acrylate monomer, isobornyl methacrylate, hydroxypropyl acrylate, benzoyl peroxide is at the uniform velocity added dropwise, it is dripped off with 23 hours, 120 130 degree are warming up to after dripping off, 70 80 degree of input water are cooled to after keeping the temperature 34 hours, 40 50 degree are cooled to again, neutralizer is put into, is stirred 40 50 minutes；Ammonium polyphosphate, tetramethylol methane, melamine are added in, is stirred 30 60 minutes.This synthetic method is made that resistance of coating rate is smaller, and antistatic property is good.
Description
Technical field
The present invention relates to technical field of aqueous paint, and in particular to a kind of antistatic acrylic resin syntheses processes.
Background technology
Since the 1990s, solvent based coating, paint and adhesives industry are by high pollution, high energy consumption, pole
Degree is increasingly turned to environmental-friendly, resource and energy conservation type product, various environmental protection dependent on the traditional category of petroleum industry product
Type kind continues to bring out, and wherein water paint and aqueous binder industry achieves significant progress.Water paint has price
It is low, safe to use, resource and the energy are saved, is reduced environmental pollution and the advantages that public hazards, thus become current development coating work
The Main way of industry.Water-based acrylic resin coating is with fastest developing speed, pollution-free coating that kind is most in water paint.
Acrylic resin is the resin made of esters of acrylic acid and methyl acrylic ester and other olefinic type monomers are copolymerized,
By the way that different resin structures, different formulas, production technology and solvent is selected to form, different type, different performance can be synthesized
With the acrylic resin of different application occasion.Common coating holds easy to produce static electricity in use since electrical insulating property is higher
Accumulation, has a large amount of electronic product because of electrostatic damage, therefore the field of antistatic coating just extends year by year every year.
Invention content
The technical problems to be solved by the invention are to provide a kind of antistatic acrylic resin syntheses processes, are aqueous painting
Material industry provide it is a kind of it is antistatic it is good, there is relatively strong ageing-resistant acrylic resin to be used for coating industry.
To achieve the above object, the present invention is achieved by the following technical solutions：A kind of antistatic acrylic tree
Fat synthetic method, includes the following steps：
(1) n-butanol is put into reaction kettle at normal temperatures, 90-100 degree is warming up to, stirs evenly；
(2) methyl methacrylate, n-BMA, acrylic acid, n-butyl acrylate, acrylic acid -2- are put into
Ethylhexyl, isobornyl methacrylate, hydroxypropyl acrylate and dibenzoyl peroxide monomer, graphene oxide, stirring
Uniformly；
(3) it is different that methyl methacrylate, n-BMA, acrylic acid, butyl acrylate, acrylic acid is at the uniform velocity added dropwise
Monooctyl ester, isobornyl methacrylate, hydroxypropyl acrylate, benzoyl peroxide are dripped off with 2-3 hour, are heated up after dripping off
To 120-130 degree, heat preservation is cooled to 70-80 degree input water, cools to 40-50 degree again, put into neutralizer, stir after 3-4 hours
It mixes 40-50 minutes；
(4) ammonium polyphosphate, tetramethylol methane, melamine are added in, is stirred 30-60 minutes, discharging is packaged to be anti-
Electrostatic acrylic resin.
As a preferred embodiment, the antistatic acrylic resin syntheses processes include the following steps：
(1) n-butanol is put into reaction kettle at normal temperatures, 90 degree is warming up to, stirs evenly；
(2) methyl methacrylate, n-BMA, acrylic acid, n-butyl acrylate, acrylic acid -2- are put into
Ethylhexyl, isobornyl methacrylate, hydroxypropyl acrylate and dibenzoyl peroxide monomer, graphene oxide, stirring
Uniformly；
(3) it is different that methyl methacrylate, n-BMA, acrylic acid, butyl acrylate, acrylic acid is at the uniform velocity added dropwise
Monooctyl ester, isobornyl methacrylate, hydroxypropyl acrylate, benzoyl peroxide are dripped off with 2.5 hours, heated up after dripping off
To 120 degree, heat preservation is cooled to 75 degree of input water after 2.5 hours, cool to 40 degree again, put into neutralizer, stir 45 minutes；
(4) ammonium polyphosphate, tetramethylol methane, melamine are added in, is stirred 40 minutes, discharging is packaged to be antistatic
Acrylic resin.
As a preferred embodiment, the antistatic acrylic resin syntheses processes include the following steps：
(1) n-butanol is put into reaction kettle at normal temperatures, 95 degree is warming up to, stirs evenly；
(2) methyl methacrylate, n-BMA, acrylic acid, n-butyl acrylate, acrylic acid -2- are put into
Ethylhexyl, isobornyl methacrylate, hydroxypropyl acrylate and dibenzoyl peroxide monomer, graphene oxide, stirring
Uniformly；
(3) it is different that methyl methacrylate, n-BMA, acrylic acid, butyl acrylate, acrylic acid is at the uniform velocity added dropwise
Monooctyl ester, isobornyl methacrylate, hydroxypropyl acrylate, benzoyl peroxide are dripped off with 2 hours, are warming up to after dripping off
127 degree, heat preservation is cooled to 70 degree of input water after 3 hours, cool to 43 degree again, put into neutralizer, stir 40 minutes；
(4) ammonium polyphosphate, tetramethylol methane, melamine are added in, is stirred 50 minutes, discharging is packaged to be antistatic
Acrylic resin.
As a preferred embodiment, the antistatic acrylic resin syntheses processes include the following steps：
(1) n-butanol is put into reaction kettle at normal temperatures, 100 degree is warming up to, stirs evenly；
(2) methyl methacrylate, n-BMA, acrylic acid, n-butyl acrylate, acrylic acid -2- are put into
Ethylhexyl, isobornyl methacrylate, hydroxypropyl acrylate and dibenzoyl peroxide monomer, graphene oxide, stirring
Uniformly；
(3) it is different that methyl methacrylate, n-BMA, acrylic acid, butyl acrylate, acrylic acid is at the uniform velocity added dropwise
Monooctyl ester, isobornyl methacrylate, hydroxypropyl acrylate, benzoyl peroxide are dripped off with 3 hours, are warming up to after dripping off
130 degree, heat preservation is cooled to 80 degree of input water after 4 hours, cool to 50 degree again, put into neutralizer, stir 50 minutes；
(4) ammonium polyphosphate, tetramethylol methane, melamine are added in, is stirred 60 minutes, discharging is packaged to be antistatic
Acrylic resin.
As a preferred embodiment, the acrylic resin of the antistatic acrylic resin syntheses processes is by following mass fraction
Raw material is prepared：9-10 parts of methyl methacrylate, 9-10 parts of n-BMA, 3-4 parts of acrylic acid, acrylic acid fourth
6-7 parts of ester, 6-7 parts of Isooctyl acrylate monomer, 12-14 parts of isobornyl methacrylate, 4-6 parts of hydroxypropyl acrylate, peroxidating
1-2 parts of benzoyl, 22-25 parts of water, 3-5 parts of neutralizer, 8-10 parts of n-butanol, 46-50 parts of ammonium polyphosphate, tetramethylol methane
20-25 parts, 20-25 parts of melamine, 2-14 parts of graphene oxide.
As a preferred embodiment, the acrylic resin of the antistatic acrylic resin syntheses processes is by following mass fraction
Raw material is prepared：9 parts of methyl methacrylate, 10 parts of n-BMA, 4 parts of acrylic acid, 6 parts of butyl acrylate,
6 parts of Isooctyl acrylate monomer, 13 parts of isobornyl methacrylate, 5 parts of hydroxypropyl acrylate, 2 parts of benzoyl peroxide, water 22
Part, 3 parts of neutralizer, 8 parts of n-butanol, 48 parts of ammonium polyphosphate, 22 parts of tetramethylol methane, 22 parts of trimerization cyanato-, graphene oxide 7
Part.
As a preferred embodiment, the acrylic resin of the antistatic acrylic resin syntheses processes is by following mass fraction
Raw material is prepared：9.2 parts of methyl methacrylate, 9 parts of n-BMA, 4.2 parts of acrylic acid, butyl acrylate 7
Part, 6.4 parts of Isooctyl acrylate monomer, 12 parts of isobornyl methacrylate, 4 parts of hydroxypropyl acrylate, 1 part of benzoyl peroxide,
24 parts of water, 4.6 parts of neutralizer, 9.1 parts of n-butanol, 46 parts of ammonium polyphosphate, 20 parts of tetramethylol methane, 20 parts of melamine,
2 parts of graphene oxide.
As a preferred embodiment, the acrylic resin of the antistatic acrylic resin syntheses processes is by following mass fraction
Raw material is prepared：10 parts of methyl methacrylate, 9.6 parts of n-BMA, 3 parts of acrylic acid, butyl acrylate 6.2
Part, 7 parts of Isooctyl acrylate monomer, 14 parts of isobornyl methacrylate, 6 parts of hydroxypropyl acrylate, 1.3 parts of benzoyl peroxide,
25 parts of water, 5 parts of neutralizer, 10 parts of n-butanol, 50 parts of ammonium polyphosphate, 25 parts of tetramethylol methane, 25 parts of melamine, oxidation
14 parts of graphene.
Beneficial effects of the present invention：
1st, resistance of coating rate made from antistatic acrylic resin syntheses processes volume of the present invention is smaller, antistatic property
It is good.
2nd, antistatic acrylic resin syntheses processes of the present invention are finer and close in material filming post-crosslinking reticular structure, increase
Coating adhesion enhances the ageing-resistant performance of coating.
3rd, synthetic method craft of the invention is simple, is stirred to react under lower temperature and condition of normal pressure, energy-saving safe, uses
Way is extensive, suitable for industrial production.
Specific embodiment
Embodiment 1：
The preparation method of this antistatic acrylic resin syntheses processes：
(1) n-butanol is put into reaction kettle at normal temperatures, 90 degree is warming up to, stirs evenly；
(2) methyl methacrylate, n-BMA, acrylic acid, n-butyl acrylate, acrylic acid -2- are put into
Ethylhexyl, isobornyl methacrylate, hydroxypropyl acrylate and dibenzoyl peroxide monomer, graphene oxide, stirring
Uniformly；
(3) it is different that methyl methacrylate, n-BMA, acrylic acid, butyl acrylate, acrylic acid is at the uniform velocity added dropwise
Monooctyl ester, isobornyl methacrylate, hydroxypropyl acrylate, benzoyl peroxide are dripped off with 2.5 hours, heated up after dripping off
To 120 degree, heat preservation is cooled to 75 degree of input water after 2.5 hours, cool to 40 degree again, put into neutralizer, stir 45 minutes；
(4) ammonium polyphosphate, tetramethylol methane, melamine are added in, is stirred 40 minutes, discharging is packaged to be antistatic
Acrylic resin.
Wherein the fineness of ammonium polyphosphate, tetramethylol methane, melamine is less than 70 μm.
Water soluble acrylic resin in the antistatic acrylic resin syntheses processes, by the raw material of following mass fraction
It is prepared：9 parts of methyl methacrylate, 10 parts of n-BMA, 4 parts of acrylic acid, 6 parts of butyl acrylate, propylene
Different 6 parts of the monooctyl ester of acid, 13 parts of isobornyl methacrylate, 5 parts of hydroxypropyl acrylate, 2 parts of benzoyl peroxide, 22 parts of water, in
With 3 parts of agent, 8 parts of n-butanol, 48 parts of ammonium polyphosphate, 22 parts of tetramethylol methane, 22 parts of trimerization cyanato-, 7 parts of graphene oxide.
Embodiment 2：
The preparation method of this antistatic acrylic resin syntheses processes：
(1) n-butanol is put into reaction kettle at normal temperatures, 95 degree is warming up to, stirs evenly；
(2) methyl methacrylate, n-BMA, acrylic acid, n-butyl acrylate, acrylic acid -2- are put into
Ethylhexyl, isobornyl methacrylate, hydroxypropyl acrylate and dibenzoyl peroxide monomer, graphene oxide, stirring
Uniformly；
(3) it is different that methyl methacrylate, n-BMA, acrylic acid, butyl acrylate, acrylic acid is at the uniform velocity added dropwise
Monooctyl ester, isobornyl methacrylate, hydroxypropyl acrylate, benzoyl peroxide are dripped off with 2 hours, are warming up to after dripping off
127 degree, heat preservation is cooled to 70 degree of input water after 3 hours, cool to 43 degree again, put into neutralizer, stir 40 minutes；
(4) ammonium polyphosphate, tetramethylol methane, melamine are added in, is stirred 50 minutes, discharging is packaged to be antistatic
Acrylic resin.
Wherein the fineness of ammonium polyphosphate, tetramethylol methane, melamine is less than 70 μm.
Water soluble acrylic resin in the antistatic acrylic resin syntheses processes, by the raw material of following mass fraction
It is prepared：9.2 parts of methyl methacrylate, 9 parts of n-BMA, 4.2 parts of acrylic acid, 7 parts of butyl acrylate, third
6.4 parts of the different monooctyl ester of olefin(e) acid, 12 parts of isobornyl methacrylate, 4 parts of hydroxypropyl acrylate, 1 part of benzoyl peroxide, water 24
Part, 4.6 parts of neutralizer, 9.1 parts of n-butanol, 46 parts of ammonium polyphosphate, 20 parts of tetramethylol methane, 20 parts of melamine, oxidation
2 parts of graphene.
Embodiment 3：
The preparation method of this antistatic acrylic resin syntheses processes：
(1) n-butanol is put into reaction kettle at normal temperatures, 100 degree is warming up to, stirs evenly；
(2) methyl methacrylate, n-BMA, acrylic acid, n-butyl acrylate, acrylic acid -2- are put into
Ethylhexyl, isobornyl methacrylate, hydroxypropyl acrylate and dibenzoyl peroxide monomer, graphene oxide, stirring
Uniformly；
(3) it is different that methyl methacrylate, n-BMA, acrylic acid, butyl acrylate, acrylic acid is at the uniform velocity added dropwise
Monooctyl ester, isobornyl methacrylate, hydroxypropyl acrylate, benzoyl peroxide are dripped off with 3 hours, are warming up to after dripping off
130 degree, heat preservation is cooled to 80 degree of input water after 4 hours, cool to 50 degree again, put into neutralizer, stir 50 minutes；
(4) ammonium polyphosphate, tetramethylol methane, melamine are added in, is stirred 60 minutes, discharging is packaged to be antistatic
Acrylic resin.
Water soluble acrylic resin in the antistatic acrylic resin syntheses processes, by the raw material of following mass fraction
It is prepared：10 parts of methyl methacrylate, 9.6 parts of n-BMA, 3 parts of acrylic acid, 6.2 parts of butyl acrylate,
7 parts of Isooctyl acrylate monomer, 14 parts of isobornyl methacrylate, 6 parts of hydroxypropyl acrylate, 1.3 parts of benzoyl peroxide, water 25
Part, 5 parts of neutralizer, 10 parts of n-butanol, 50 parts of ammonium polyphosphate, 25 parts of tetramethylol methane, 25 parts of melamine, graphite oxide
14 parts of alkene.
Water paint is prepared using water soluble acrylic resin's formula made from synthetic method of the present invention, to embodiment 1-3
Product tested, the results are shown in Table 1.
1 embodiment 1-3 product water paint testing results of table
Testing result show using acrylic resin used in water-borne coating volume resistivity made from synthetic method of the present invention compared with
Small, antistatic property is good, increases crosslink density, and the degree of cross linking of composite material is risen, the netted knot of material filming post-crosslinking
Structure is finer and close, increases coating adhesion, so as to enhance the ageing-resistant performance of coating.Meanwhile synthetic method of the invention
It is simple for process, it is stirred to react under lower temperature and condition of normal pressure, energy-saving safe is widely used, suitable for industrial production.
Basic principle of the invention and main feature and advantages of the present invention has been shown and described above.The skill of the industry
Art personnel it should be appreciated that the present invention is not limited to the above embodiments, the above embodiments and description only describe
The principle of the present invention, without departing from the spirit and scope of the present invention, various changes and improvements may be made to the invention, these
Changes and improvements all fall within the protetion scope of the claimed invention.The claimed scope of the invention by appended claims and
Its equivalent thereof.
Claims (8)
1. a kind of antistatic acrylic resin syntheses processes, which is characterized in that include the following steps：
(1) n-butanol is put into reaction kettle at normal temperatures, 90-100 degree is warming up to, stirs evenly；
(2) methyl methacrylate, n-BMA, acrylic acid, n-butyl acrylate, acrylic acid-2-ethyl are put into
Own ester, isobornyl methacrylate, hydroxypropyl acrylate and dibenzoyl peroxide monomer, graphene oxide, stir evenly；
(3) it is different pungent that methyl methacrylate, n-BMA, acrylic acid, butyl acrylate, acrylic acid is at the uniform velocity added dropwise
Ester, isobornyl methacrylate, hydroxypropyl acrylate, benzoyl peroxide are dripped off with 2-3 hour, are warming up to after dripping off
120-130 degree, heat preservation are cooled to 70-80 degree input water, cool to 40-50 degree again after 3-4 hours, put into neutralizer, stirring
40-50 minutes；
(4) ammonium polyphosphate, tetramethylol methane, melamine are added in, is stirred 30-60 minutes, discharging is packaged to be antistatic
Acrylic resin.
2. antistatic acrylic resin syntheses processes according to claim 1, which is characterized in that include the following steps：
(1) n-butanol is put into reaction kettle at normal temperatures, 90 degree is warming up to, stirs evenly；
(2) methyl methacrylate, n-BMA, acrylic acid, n-butyl acrylate, acrylic acid-2-ethyl are put into
Own ester, isobornyl methacrylate, hydroxypropyl acrylate and dibenzoyl peroxide monomer, graphene oxide, stir evenly；
(3) it is different pungent that methyl methacrylate, n-BMA, acrylic acid, butyl acrylate, acrylic acid is at the uniform velocity added dropwise
Ester, isobornyl methacrylate, hydroxypropyl acrylate, benzoyl peroxide are dripped off with 2.5 hours, are warming up to after dripping off
120 degree, heat preservation is cooled to 75 degree of input water after 2.5 hours, cool to 40 degree again, put into neutralizer, stir 45 minutes；
(4) ammonium polyphosphate, tetramethylol methane, melamine are added in, is stirred 40 minutes, discharging is packaged to be antistatic propylene
Acid resin.
3. antistatic acrylic resin syntheses processes according to claim 1, which is characterized in that include the following steps：
(1) n-butanol is put into reaction kettle at normal temperatures, 95 degree is warming up to, stirs evenly；
(2) methyl methacrylate, n-BMA, acrylic acid, n-butyl acrylate, acrylic acid-2-ethyl are put into
Own ester, isobornyl methacrylate, hydroxypropyl acrylate and dibenzoyl peroxide monomer, graphene oxide, stir evenly；
(3) it is different pungent that methyl methacrylate, n-BMA, acrylic acid, butyl acrylate, acrylic acid is at the uniform velocity added dropwise
Ester, isobornyl methacrylate, hydroxypropyl acrylate, benzoyl peroxide are dripped off with 2 hours, 127 are warming up to after dripping off
Degree, heat preservation are cooled to 70 degree of input water, cool to 43 degree again, put into neutralizer, stir 40 minutes after 3 hours；
(4) ammonium polyphosphate, tetramethylol methane, melamine are added in, is stirred 50 minutes, discharging is packaged to be antistatic propylene
Acid resin.
4. antistatic acrylic resin syntheses processes according to claim 1, which is characterized in that include the following steps：
(1) n-butanol is put into reaction kettle at normal temperatures, 100 degree is warming up to, stirs evenly；
(2) methyl methacrylate, n-BMA, acrylic acid, n-butyl acrylate, acrylic acid-2-ethyl are put into
Own ester, isobornyl methacrylate, hydroxypropyl acrylate and dibenzoyl peroxide monomer, graphene oxide, stir evenly；
(3) it is different pungent that methyl methacrylate, n-BMA, acrylic acid, butyl acrylate, acrylic acid is at the uniform velocity added dropwise
Ester, isobornyl methacrylate, hydroxypropyl acrylate, benzoyl peroxide are dripped off with 3 hours, 130 are warming up to after dripping off
Degree, heat preservation are cooled to 80 degree of input water, cool to 50 degree again, put into neutralizer, stir 50 minutes after 4 hours；
(4) ammonium polyphosphate, tetramethylol methane, melamine are added in, is stirred 60 minutes, discharging is packaged to be antistatic propylene
Acid resin.
5. according to claim 1-4 any one of them antistatic acrylic resin syntheses processes, which is characterized in that acrylic acid tree
Fat is prepared by the raw material of following mass fraction：9-10 parts of methyl methacrylate, 9-10 parts of n-BMA, third
3-4 parts of olefin(e) acid, 6-7 parts of butyl acrylate, 6-7 parts of Isooctyl acrylate monomer, 12-14 parts of isobornyl methacrylate, acrylic acid
4-6 parts of hydroxypropyl acrylate, 1-2 parts of benzoyl peroxide, 22-25 parts of water, 3-5 parts of neutralizer, 8-10 parts of n-butanol, ammonium polyphosphate 46-
50 parts, 20-25 parts of tetramethylol methane, 20-25 parts of melamine, 2-14 parts of graphene oxide.
6. antistatic acrylic resin syntheses processes according to claim 5, which is characterized in that acrylic resin is by following
The raw material of mass fraction is prepared：9 parts of methyl methacrylate, 10 parts of n-BMA, 4 parts of acrylic acid, propylene
6 parts of acid butyl ester, 6 parts of Isooctyl acrylate monomer, 13 parts of isobornyl methacrylate, 5 parts of hydroxypropyl acrylate, benzoyl peroxide
2 parts, 22 parts of water, 3 parts of neutralizer, 8 parts of n-butanol, 48 parts of ammonium polyphosphate, 22 parts of tetramethylol methane, 22 parts of trimerization cyanato-, oxygen
7 parts of graphite alkene.
7. antistatic acrylic resin syntheses processes according to claim 5, which is characterized in that acrylic resin is by following
The raw material of mass fraction is prepared：9.2 parts of methyl methacrylate, 9 parts of n-BMA, 4.2 parts of acrylic acid, third
7 parts of olefin(e) acid butyl ester, 6.4 parts of Isooctyl acrylate monomer, 12 parts of isobornyl methacrylate, 4 parts of hydroxypropyl acrylate, benzoyl peroxide
Formyl chloride-1 part, 24 parts of water, 4.6 parts of neutralizer, 9.1 parts of n-butanol, 46 parts of ammonium polyphosphate, 20 parts of tetramethylol methane, trimerization cyanato-
20 parts of amine, 2 parts of graphene oxide.
8. antistatic acrylic resin syntheses processes according to claim 5, which is characterized in that acrylic resin is by following
The raw material of mass fraction is prepared：10 parts of methyl methacrylate, 9.6 parts of n-BMA, 3 parts of acrylic acid, third
6.2 parts of olefin(e) acid butyl ester, 7 parts of Isooctyl acrylate monomer, 14 parts of isobornyl methacrylate, 6 parts of hydroxypropyl acrylate, benzoyl peroxide
.3 parts of formyl chloride-1,25 parts of water, 5 parts of neutralizer, 10 parts of n-butanol, 50 parts of ammonium polyphosphate, 25 parts of tetramethylol methane, trimerization cyanato-
25 parts of amine, 14 parts of graphene oxide.
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109232141A (en) * | 2018-10-30 | 2019-01-18 | 周守虎 | Safety and environmental protection fireworks composite material and preparation method |
| CN114875673A (en) * | 2022-06-22 | 2022-08-09 | 汕头市润丰纺织科技实业有限公司 | Antistatic agent, warm keeping cashmere protein hollow yarn, preparation method thereof and fabric |
| CN115926626A (en) * | 2022-11-19 | 2023-04-07 | 江苏康程新材料科技有限公司 | Preparation method of interior wall reinforced coating |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101613434A (en) * | 2009-07-15 | 2009-12-30 | 华南理工大学 | A kind of alcohol soluble polyacrylate resin and preparation method thereof and application |
| CN103992429A (en) * | 2014-05-17 | 2014-08-20 | 北京化工大学 | Cationic copolymer emulsion for waterborne wood coating and preparation method thereof |
-
2017
- 2017-12-29 CN CN201711486139.1A patent/CN108192018A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101613434A (en) * | 2009-07-15 | 2009-12-30 | 华南理工大学 | A kind of alcohol soluble polyacrylate resin and preparation method thereof and application |
| CN103992429A (en) * | 2014-05-17 | 2014-08-20 | 北京化工大学 | Cationic copolymer emulsion for waterborne wood coating and preparation method thereof |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109232141A (en) * | 2018-10-30 | 2019-01-18 | 周守虎 | Safety and environmental protection fireworks composite material and preparation method |
| CN114875673A (en) * | 2022-06-22 | 2022-08-09 | 汕头市润丰纺织科技实业有限公司 | Antistatic agent, warm keeping cashmere protein hollow yarn, preparation method thereof and fabric |
| CN115926626A (en) * | 2022-11-19 | 2023-04-07 | 江苏康程新材料科技有限公司 | Preparation method of interior wall reinforced coating |
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