CN108187351A - It is a kind of to form the bubble liquid for stablizing very big foam - Google Patents
It is a kind of to form the bubble liquid for stablizing very big foam Download PDFInfo
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- CN108187351A CN108187351A CN201810042846.XA CN201810042846A CN108187351A CN 108187351 A CN108187351 A CN 108187351A CN 201810042846 A CN201810042846 A CN 201810042846A CN 108187351 A CN108187351 A CN 108187351A
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- Prior art keywords
- bubble liquid
- bubble
- big foam
- water
- form stable
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Classifications
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- A—HUMAN NECESSITIES
- A63—SPORTS; GAMES; AMUSEMENTS
- A63H—TOYS, e.g. TOPS, DOLLS, HOOPS OR BUILDING BLOCKS
- A63H33/00—Other toys
- A63H33/28—Soap-bubble toys; Smoke toys
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- Compositions Of Macromolecular Compounds (AREA)
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
- General Preparation And Processing Of Foods (AREA)
Abstract
Disclosed by the invention to belong to toy technique field, specially a kind of to form the bubble liquid for stablizing very big foam, according to weight percentage, the bubble liquid that can form stable very big foam is made of following components：Water：72.7 90.1%；PH sensitivity glue：0.5 1.5%；Water soluble polymer：0.1 0.3%；Surfactant：3 10%；Moisturizer：3 8%；PH buffer：3 7%；Preservative：0.3 0.5%, by adding in pH sensitivity glue in bubble liquid system, when bubble film absorbs Carbon Dioxide in Air, pH sensitivity xanthan molecules amount is shunk, with other water-soluble high-molecular materials crosslinking in system, winding, interpenetrating and form firm reticular structure, make very big foam that temporarily there is certain " rigidity " in the air, it is not easy to rupture, and add in certain pH buffer, make bubble liquid bubble is newly formed and continuous increase during keep pH constant.
Description
Technical field
The present invention relates to toy technique fields, specially a kind of to form the bubble liquid for stablizing very big foam.
Background technology
The bubble of bubble product blowout in the market is mostly in 2cm-20cm.It is formulated as water, colloid, surfactant, guarantor
Humectant, aromatic, preservative.For 1-2 meters of large bubble of diameter, due to the influence of dirt in air, moisture evaporation, gravity, wind,
Conventional formulation can not be competent at.Stable large bubble can be undoubtedly generated if the effect of these factors can be weakened.Most straightforward approach
It is the thickness for increasing vacuolar membrane, but overweight bubble is instead pullled vacuolar membrane formation and ruptured rapidly.For this purpose, a kind of it is proposed that energy
Form the bubble liquid for stablizing very big foam.
Invention content
The purpose of the present invention is to provide a kind of bubble liquid that can form stable very big foam, to solve above-mentioned background technology
The bubble film strength of the existing bubble product blowout of middle proposition is low, the problem of can not resisting factor unfavorable in environment.
To achieve the above object, the present invention provides following technical solution：It is a kind of to form the bubble liquid for stablizing very big foam,
According to weight percentage, the bubble liquid that can form stable very big foam is made of following components：
Water：72.7-90.1%；PH sensitivity glue：0.5-1.5%；Water soluble polymer：0.1-0.3%；Surfactant：
3-10%；Moisturizer：3-8%；PH buffer：3-7%；Preservative：0.3-0.5%.
Preferably, the water is deionized water.
Preferably, the pH sensitivities glue includes synthetic material and natural material, and the synthetic material includes polyacrylic acid, first
Base acrylic compounds and polyamine class, the natural material include polyaminoacid, chitosan and sodium alginate.
Preferably, the water soluble polymer includes foodstuff glue and cellulose, and the foodstuff glue includes guar gum, gelatin
And xanthans, the cellulose include carboxymethyl cellulose, hydroxyethyl cellulose and hydroxypropyl methyl cellulose, the water solubility
Macromolecule further includes polyvinyl alcohol and polyethylene glycol.
Preferably, mixture of the surfactant for anion surfactant and nonionic surfactant, institute
It states anion surfactant and includes metal carboxylate, Sulfates and Sulfonates, the nonionic surfactant includes ester
Class, ethers, amine and amides.
Preferably, the moisturizer is one or more in propylene glycol, glycerine and sorbierite.
Preferably, the pH buffer includes Glycine-NaOH and sodium bicarbonate-carbonate.
Preferably, the preservative includes Kathon CG class, parabens and sodium benzoate.
Compared with prior art, the beneficial effects of the invention are as follows：A kind of can be formed that the invention proposes stablizes very big foam
Bubble liquid, by adding in pH sensitivity glue in bubble liquid system, when bubble film absorbs Carbon Dioxide in Air, pH sensitivities glue point
Son amount shrink, in system other water-soluble high-molecular materials crosslinking, winding, interpenetrating and form firm reticular structure, make spy
Large bubble temporarily has certain " rigidity " in the air, it is not easy to rupture, and add in certain pH buffer, steep bubble liquid
Holding pH is constant during steeping newly formed and continuous increase.
Specific embodiment
The technical solution in the embodiment of the present invention will be clearly and completely described below, it is clear that described implementation
Example is only part of the embodiment of the present invention, instead of all the embodiments.Based on the embodiments of the present invention, this field is common
Technical staff's all other embodiments obtained without making creative work belong to the model that the present invention protects
It encloses.
The present invention provides a kind of bubble liquid that can form stable very big foam, and according to weight percentage, this can form stabilization
The bubble liquid of very big foam is made of following components：
Water：72.7-90.1%；PH sensitivity glue：0.5-1.5%；Water soluble polymer：0.1-0.3%；Surfactant：
3-10%；Moisturizer：3-8%；PH buffer：3-7%；Preservative：0.3-0.5%.
Wherein, the water is deionized water；The pH sensitivities glue includes synthetic material and natural material, the synthetic material
Including polyacrylic acid, methacrylic and polyamine class, the natural material include polyaminoacid, chitosan and sodium alginate,
The pH of the high sensing external environment of pH sensitivities glue energy declines, and strand is shunk, be crosslinked, wind with other macromolecules formation in system,
The network structure of interpenetrating；The water soluble polymer includes foodstuff glue and cellulose, and the foodstuff glue includes guar gum, gelatin
And xanthans, the cellulose include carboxymethyl cellulose, hydroxyethyl cellulose and hydroxypropyl methyl cellulose, the water solubility
Macromolecule further includes polyvinyl alcohol and polyethylene glycol, and viscosity of the water soluble polymer in addition to that can increase bubble liquid increases bubble
Film thickness, also acting as latching moisture prevents moisture from quickly volatilizing, and can also form crosslinking, winding, interpenetrating between pH sensitivity glue
Network structure, increase " toughness " of vacuolar membrane；The surfactant is anion surfactant and non-ionic surface active
The mixture of agent, the anion surfactant include metal carboxylate, and (wherein M is metal to general formula R COOM, and R is alkyl (C7-
C21), aromatic radical and other groups), such as sodium soap, Sulfates, general formula R OSO3(wherein M is metal to M, and R is alkyl
(C8-C18)), such as lauryl sodium sulfate, Sulfonates, general formula R SO3M (wherein M be metal, R for alkyl, aromatic radical and its
His group), such as neopelex, dodecly diphenyl ether sulfonate disodium salt, the nonionic surfactant includes
Esters, such as polyethylene glycol oxide carboxylate, polyol carboxylate, polyoxyethylated polyols carboxylate, such as ethers, polyoxyethylene
Allylic alkylation ether, polyethylene glycol oxide alkyl aryl ether, amine and amides, the surfactant can reduce the surface of aqueous solution
Power forms bubble；And the molecular layer of neat densification is formed in gas-liquid surface, stablize bubble；The moisturizer is propylene glycol, the third three
One or more in alcohol and sorbierite, moisturizer has stronger hygroscopicity, for slowing down the volatilization of moisture on bubble film, carries
The high bubble aerial duration；The pH buffer includes Glycine-NaOH and sodium bicarbonate-carbonate, institute
Stating pH buffer enables system to have cushioning effect when adding in a certain amount of acid or alkaline matter, and pH is kept not change.In this way
Bubble is newly formed and continuous increase during will not because of pH sensitivity glue chemical change and " rigidifying "；The preservative packet
Kathon CG class, parabens and sodium benzoate are included, the preservative has the function of certain antisepsis and sterilization under selected ph values, improves
The storage time of bubble liquid.
Embodiment 1
S1：Deionized water is added in agitator tank, 50 DEG C is heated to, under high velocity agitation, is sequentially added into high water solubility
Molecule and pH sensitivity glue, to be dissolved complete, cooling is for use；
S2：It is added in another agitator tank in remaining deionized water, opens stirring, be sequentially added into preservative, protect
Humectant and pH buffer after dissolving completely, are eventually adding surfactant；
S3：Liquid in the S1 to have cooled down is added in into the liquid in S2, is stirred evenly, with 10% sodium hydrate aqueous solution tune
PH value is saved to 9, is discharged.
In the present embodiment, pH sensitivities glue is sodium alginate；Water soluble polymer is guar gum and hydroxyethyl cellulose；
Surfactant is neopelex and fatty alcohol polyoxyethylene ether -9；Moisturizer is glycerine and propylene glycol；PH delays
Electuary is sodium bicarbonate and sodium carbonate；The preservative is Kathon CG, and according to weight percentage, and each component is as follows：Deionization
Water：83.7%；Sodium alginate：0.5%；Guar gum：0.2%；Hydroxyethyl cellulose：0.1%；Neopelex：
6%；Fatty alcohol polyoxyethylene ether -9：2%；Glycerine：3%；Propylene glycol：1%；Sodium bicarbonate：3%；Sodium carbonate：0.2；Card
Pine：0.3%.
Embodiment 2
S1：Deionized water is added in agitator tank, 50 DEG C is heated to, under high velocity agitation, is sequentially added into high water solubility
Molecule and pH sensitivity glue, to be dissolved complete, cooling is for use；
S2：It is added in another agitator tank in remaining deionized water, opens stirring, be sequentially added into preservative, protect
Humectant and pH buffer after dissolving completely, are eventually adding surfactant；
S3：Liquid in the S1 to have cooled down is added in into the liquid in S2, is stirred evenly, with 10% sodium hydrate aqueous solution tune
PH value is saved to 9, is discharged.
In the present embodiment, pH sensitivities glue is carboxymethyl chitosan；Water soluble polymer is gelatin and polyvinyl alcohol；Surface
Activating agent is lauryl sodium sulfate and coconut oil diethanol amide；Moisturizer is glycerine and sorbierite；PH buffer is sweet
Propylhomoserin and sodium hydroxide；The preservative is sodium benzoate, and according to weight percentage, and each component is as follows：Deionized water：
74.8%；Carboxymethyl chitosan：1.5%；Gelatin：0.1%；Polyvinyl alcohol：0.1%；Lauryl sodium sulfate：8%；Coconut oil
Diglycollic amide：2%；Glycerine：4%；Sorbierite：2%；Glycine：6.5%；Sodium hydroxide：0.5；Sodium benzoate：
0.5%.
Embodiment 3
S1：Deionized water is added in agitator tank, 50 DEG C is heated to, under high velocity agitation, is sequentially added into high water solubility
Molecule and pH sensitivity glue, to be dissolved complete, cooling is for use；
S2：It is added in another agitator tank in remaining deionized water, opens stirring, be sequentially added into preservative, protect
Humectant and pH buffer after dissolving completely, are eventually adding surfactant；
S3：Liquid in the S1 to have cooled down is added in into the liquid in S2, is stirred evenly, with 10% sodium hydrate aqueous solution tune
PH value is saved to 9, is discharged.
In the present embodiment, pH sensitivities glue is Y- polyglutamic acids；Water soluble polymer is polyethylene glycol and carboxymethyl cellulose
Element；Surfactant is sodium sulfate of polyethenoxy ether of fatty alcohol and Tween-80；Moisturizer is sorb
Alcohol and propylene glycol；PH buffer is sodium bicarbonate and sodium carbonate；The preservative is ethyl-para-hydroxybenzoate, and according to weight
Percentage composition, each component are as follows：Deionized water：84.05%；Y- polyglutamic acids：1.2%；Polyethylene glycol：0.2%；Carboxymethyl is fine
Dimension element：0.15%；Sodium sulfate of polyethenoxy ether of fatty alcohol：2%；Tween-80：1%；Sorbierite：
4%；Propylene glycol：4%；Sodium bicarbonate：2.8%；Sodium carbonate：0.2；Ethyl-para-hydroxybenzoate：0.4%.
Embodiment 4
S1：Deionized water is added in agitator tank, 50 DEG C is heated to, under high velocity agitation, is sequentially added into high water solubility
Molecule and pH sensitivity glue, to be dissolved complete, cooling is for use；
S2：It is added in another agitator tank in remaining deionized water, opens stirring, be sequentially added into preservative, protect
Humectant and pH buffer after dissolving completely, are eventually adding surfactant；
S3：Liquid in the S1 to have cooled down is added in into the liquid in S2, is stirred evenly, with 10% sodium hydrate aqueous solution tune
PH value is saved to 9, is discharged.
In the present embodiment, pH sensitivities glue is acrylonitrile and methacrylic acid copolymer；Water soluble polymer is xanthans
And hydroxypropyl methyl cellulose；Surfactant is methyl sodiosul foaliphatate and polyoxethylene octylphenyl phenol ether -10；Moisturizer
For glycerine；PH buffer is glycine and sodium hydroxide；The preservative is butyl p-hydroxybenzoate, and according to weight hundred
Divide content, each component is as follows：Deionized water：85.8%；Acrylonitrile and methacrylic acid copolymer：0.8%；Xanthans：
0.05%；Hydroxypropyl methyl cellulose：0.05%；Methyl sodiosul foaliphatate：3.5%；Polyoxethylene octylphenyl phenol ether -10：
1.5%；Glycerine：3%；Glycine：4.5%；Sodium hydroxide：0.5%；Butyl p-hydroxybenzoate：0.3%.
Respectively using the bubble liquid prepared in embodiment 1, embodiment 2, embodiment 3 and embodiment 4 and commercially available common bubble
Water carry out very big foam into bubble rate, stretching time and tensile elongation test, compare.
Into bubble rate：Indoors in no-wind environment, bubble liquid is picked with 1 meter of bubble ring of diameter, brandishes into bubble, bubble exists
2 seconds or more.Each bubble liquid is tested 10 times, is calculated as bubble rate.
Stretching time：In air compartment of the wind speed for 1.25 meter per seconds, bubble liquid is picked with 30 centimetres of bubble ring of diameter, it will
The bubble film of formation is vertically and wind direction, record start the time ruptured to vacuolar membrane.
Tensile elongation：Indoors in no-wind environment, bubble liquid is picked with 30 centimetres of bubble ring of diameter, with the speed of 1 meter per second
Degree movement, record start the distance ruptured to vacuolar membrane.
1 very big foam fluidity of table can compare
Compare the performance of very big foam liquid obtained by aforementioned four embodiment, it is known that embodiment exists compared to commercially available bubble-water
Being extremely improved property is shown in terms of very big foam.
It although an embodiment of the present invention has been shown and described, for the ordinary skill in the art, can be with
Understanding without departing from the principles and spirit of the present invention can carry out these embodiments a variety of variations, modification, replace
And modification, the scope of the present invention is defined by the appended.
Claims (8)
1. a kind of can form the bubble liquid for stablizing very big foam, it is characterised in that：According to weight percentage, this can form stabilization
The bubble liquid of very big foam is made of following components：
Water：72.7-90.1%；PH sensitivity glue：0.5-1.5%；Water soluble polymer：0.1-0.3%；Surfactant：3-
10%；Moisturizer：3-8%；PH buffer：3-7%；Preservative：0.3-0.5%.
2. a kind of bubble liquid that can form stable very big foam according to claim 1, it is characterised in that：The water is goes
Ionized water.
3. a kind of bubble liquid that can form stable very big foam according to claim 1, it is characterised in that：The pH is sensitive
Glue includes synthetic material and natural material, and the synthetic material includes polyacrylic acid, methacrylic and polyamine class, the day
Right material includes polyaminoacid, chitosan and sodium alginate.
4. a kind of bubble liquid that can form stable very big foam according to claim 1, it is characterised in that：The water solubility
Macromolecule includes foodstuff glue and cellulose, and the foodstuff glue includes guar gum, gelatin and xanthans, and the cellulose includes carboxylic
Methylcellulose, hydroxyethyl cellulose and hydroxypropyl methyl cellulose, the water soluble polymer further include polyvinyl alcohol and gather
Ethylene glycol.
5. a kind of bubble liquid that can form stable very big foam according to claim 1, it is characterised in that：It lives on the surface
Property mixture of the agent for anion surfactant and nonionic surfactant, the anion surfactant includes carboxylic acid
Salt, Sulfates and Sulfonates, the nonionic surfactant include esters, ethers, amine and amides.
6. a kind of bubble liquid that can form stable very big foam according to claim 1, it is characterised in that：The moisturizer
It is one or more in propylene glycol, glycerine and sorbierite.
7. a kind of bubble liquid that can form stable very big foam according to claim 1, it is characterised in that：The pH bufferings
Agent includes Glycine-NaOH and sodium bicarbonate-carbonate.
8. a kind of bubble liquid that can form stable very big foam according to claim 1, it is characterised in that：The preservative
Including Kathon CG class, parabens and sodium benzoate.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810042846.XA CN108187351A (en) | 2018-01-17 | 2018-01-17 | It is a kind of to form the bubble liquid for stablizing very big foam |
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| CN201810042846.XA CN108187351A (en) | 2018-01-17 | 2018-01-17 | It is a kind of to form the bubble liquid for stablizing very big foam |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108956038A (en) * | 2018-07-27 | 2018-12-07 | 山东溢华阀业有限公司 | A kind of standard mouth sealing performance test agent |
| CN109084938A (en) * | 2018-07-27 | 2018-12-25 | 山东溢华阀业有限公司 | A kind of standard mouth leaks hunting agent |
| CN109847376A (en) * | 2018-12-17 | 2019-06-07 | 钱怡成 | A kind of bubble-water and preparation method thereof |
| CN111437615A (en) * | 2020-04-20 | 2020-07-24 | 萍乡亨厚新材科技有限公司 | Preparation method of double-component instant safe bubble water concentration agent |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108956038A (en) * | 2018-07-27 | 2018-12-07 | 山东溢华阀业有限公司 | A kind of standard mouth sealing performance test agent |
| CN109084938A (en) * | 2018-07-27 | 2018-12-25 | 山东溢华阀业有限公司 | A kind of standard mouth leaks hunting agent |
| CN109847376A (en) * | 2018-12-17 | 2019-06-07 | 钱怡成 | A kind of bubble-water and preparation method thereof |
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| CN111437615B (en) * | 2020-04-20 | 2021-05-04 | 萍乡亨厚新材科技有限公司 | Preparation method of double-component instant safe bubble water concentration agent |
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Address after: 361000 07, unit 13, Po Ye tower, 66 East Taiwan Road, Guanyin Mountain, Xiamen, Fujian. Applicant after: Xiamen Cara wind Education Technology Co., Ltd. Address before: 361000 07, unit 13, Po Ye tower, 66 East Taiwan Road, Guanyin Mountain, Xiamen, Fujian. Applicant before: Xiamen Cara wind Entertainment Co., Ltd. |
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Application publication date: 20180622 |