CN108184989A - A kind of compound formulation of regulation and control Plant Ethylene physiological action - Google Patents
A kind of compound formulation of regulation and control Plant Ethylene physiological action Download PDFInfo
- Publication number
- CN108184989A CN108184989A CN201810083814.4A CN201810083814A CN108184989A CN 108184989 A CN108184989 A CN 108184989A CN 201810083814 A CN201810083814 A CN 201810083814A CN 108184989 A CN108184989 A CN 108184989A
- Authority
- CN
- China
- Prior art keywords
- physiological action
- ethylene
- regulation
- control plant
- compound formulation
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23B—PRESERVING, e.g. BY CANNING, MEAT, FISH, EGGS, FRUIT, VEGETABLES, EDIBLE SEEDS; CHEMICAL RIPENING OF FRUIT OR VEGETABLES; THE PRESERVED, RIPENED, OR CANNED PRODUCTS
- A23B7/00—Preservation or chemical ripening of fruit or vegetables
- A23B7/14—Preserving or ripening with chemicals not covered by groups A23B7/08 or A23B7/10
- A23B7/153—Preserving or ripening with chemicals not covered by groups A23B7/08 or A23B7/10 in the form of liquids or solids
- A23B7/154—Organic compounds; Microorganisms; Enzymes
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N3/00—Preservation of plants or parts thereof, e.g. inhibiting evaporation, improvement of the appearance of leaves or protection against physical influences such as UV radiation using chemical compositions; Grafting wax
- A01N3/02—Keeping cut flowers fresh chemically
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23B—PRESERVING, e.g. BY CANNING, MEAT, FISH, EGGS, FRUIT, VEGETABLES, EDIBLE SEEDS; CHEMICAL RIPENING OF FRUIT OR VEGETABLES; THE PRESERVED, RIPENED, OR CANNED PRODUCTS
- A23B7/00—Preservation or chemical ripening of fruit or vegetables
- A23B7/14—Preserving or ripening with chemicals not covered by groups A23B7/08 or A23B7/10
- A23B7/153—Preserving or ripening with chemicals not covered by groups A23B7/08 or A23B7/10 in the form of liquids or solids
- A23B7/157—Inorganic compounds
Abstract
The invention discloses a kind of compound formulations of regulation and control Plant Ethylene physiological action, formulation ingredients are mainly made of 1 methyl cyclopropene of ethylene physiological action inhibitor with stabilizer phosphoric acid and hydrochloric acid, one or more ingredients in preparation in addition Synthesis pathway inhibitor aminoethoxyvinyl glycine, aminooxoacetic acid, cobalt chloride and ethylene physiological action inhibitor silver nitrate, silver thiosulfate, the effect of 1 methyl cyclopropene is further enhanced, has very big application value in terms of the fresh-keeping health care of the plant products such as water fruits and vegetables, flowers.
Description
Technical field
The present invention relates to a kind of compound formulations of regulation and control Plant Ethylene physiological action, belong to fruits and vegetables, flowers preservation and freshness skill
Art field.
Background technology
Ethylene is the hormone for promoting plant maturation aging, in plant the biosynthesis of ethylene be using methionine as precursor,
And ACC（1-aminocyclopropane -1-carboxylic acid, 1- amino-cyclopropane -1- carboxylic acids）It is the direct of ethylene
Precursor.The ethylene generated in plant starts a series of signal approach and plays physiological action by being combined with receptor.
1- methyl cyclopropenes, English name 1-Methylcyclopropene, abbreviation 1-MCP are a kind of small cycloolefins, property
Matter is very active, molecular formula C4H6, molecular weight 54.09.Toxicity is low, belongs to practical nontoxic substance.1- methyl cyclopropenes exist
Exist under normal temperature condition with gaseous state, free from extraneous odour, boiling point is about 10 DEG C, but unstable in a liquid state.L-MCP can be with
It is competitively combined with plant cell ethylene receptor, the conduction and expression for causing ethylene action signal are obstructed, so as to ethene suppressing
Most physiological action.L-MCP extends the process of fruits and vegetables ripening and senscence well, extends freshness date；It keeps well
Hardness, the brittleness of product keep color, flavor, fragrance and nutritional ingredient, can effectively keep the disease resistance of plant, mitigate micro-
It rots caused by biology and mitigates physiological disease, and moisture evaporation can be reduced, prevent from wilting.Fruits and vegetables, flowers use 1- methyl rings
Propylene processing, freshness date greatly extend.
The preparation of 1- methyl cyclopropenes is mainly prepared using cyclodextrin etc. as absorbent at present, and major defect is that technique is answered
It is miscellaneous, equipment cost is high, not easy to operate, product absorptivity is low, of high cost, and product storage and transportation uses equal inconvenience.
Aminoethoxyvinyl glycine（Aminoethoxyvinylglycine, AVG）And aminooxoacetic acid
（Aminooxyacetic acid, AOA）It is two kinds of Synthesis pathway inhibitor, is applied in production.
Co2+It is the inhibitor of Synthesis pathway, it suppresses ACC to be converted into the reaction of ethylene；Ag+It is that ethylene physiology is made
One of most effective inhibitor, but the not synthesis of ethene suppressing, commonly used has silver nitrate or silver thiosulfate.
Invention content
The purpose of the present invention is to provide a kind of stability is good, the better compound formulation of ethene suppressing biological effect effect.
The present invention uses following technical scheme：
The compound formulation of present invention regulation and control Plant Ethylene physiological action, ingredient is mainly by 1-methyl of ethylene receptor inhibitor
Cyclopropylene and stabilizer phosphoric acid and hydrochloric acid composition.Aminoethoxyvinyl glycine, amino oxygen can be added on this basis
One or more ingredients in acetic acid, cobalt chloride, silver nitrate, silver thiosulfate, to further enhance ethene suppressing physiological action
Effect.The mass percent of compound formulation each component in the solution is：
1-methyl cyclopropene 0.01%~6%
Phosphoric acid 0.05%~25%
Hydrochloric acid 0%~5%
Aminoethoxyvinyl glycine 0%~5%
Aminooxoacetic acid 0%~5%
Cobalt chloride 0%~0.5%
Silver nitrate 0%~0.5%
Silver thiosulfate 0%~0.5%
Above-mentioned compound formulation, the mass percent of each component in the solution is when generating better effects：
1-methyl cyclopropene 0.02%~4%
Phosphoric acid 0.1%~15%
Hydrochloric acid 0.05%~3%
Aminoethoxyvinyl glycine 0.001%~2%
Aminooxoacetic acid 0.001%~2%
Cobalt chloride 0.0001%~0.1%
Silver nitrate 0.0001%~0.1%
Silver thiosulfate 0.0001%~0.1%
Above-mentioned compound formulation, the mass percent of each component in the solution is when generating optimum efficiency：
1-methyl cyclopropene 0.05%~3%
Phosphatase 11 %~10%
Hydrochloric acid 0.1%~2%
Aminoethoxyvinyl glycine 0.01%~1%
Aminooxoacetic acid 0.01%~1%
Cobalt chloride 0.001%~0.01%
Silver nitrate 0.001%~0.01%
Silver thiosulfate 0.001%~0.01%
Beneficial effects of the present invention：
Present invention employs the stabilizer of phosphoric acid and hydrochloric acid as 1- methyl cyclopropenes, the better stability of preparation of production, it is at low cost,
Storage and transportation and easy to use；The Synthesis pathway inhibitor aminoethoxyvinyl glycine that is added in preparation, amino oxygen second
Sour, cobalt chloride and ethylene physiological action inhibitor silver nitrate, silver thiosulfate etc. further enhance the effect of 1- methyl cyclopropenes
Fruit has very big application value in terms of the fresh-keeping health care of the plant products such as water fruits and vegetables, flowers.
Specific embodiment
Embodiment 1
The compound formulation of present embodiment regulation and control Plant Ethylene physiological action is by following component tune by weight percentage
With into solution：
1-methyl cyclopropene 3%, phosphoric acid 3%.
Embodiment 2
The compound formulation of present embodiment regulation and control Plant Ethylene physiological action is by following component tune by weight percentage
With into solution：
1-methyl cyclopropene 3%, phosphoric acid 3%, hydrochloric acid 0.1%.
Embodiment 3
The compound formulation of present embodiment regulation and control Plant Ethylene physiological action is by following component tune by weight percentage
With into solution：
1-methyl cyclopropene 3%, phosphoric acid 3%, hydrochloric acid 0.1%, aminoethoxyvinyl glycine 0.01%.
Embodiment 4
The compound formulation of present embodiment regulation and control Plant Ethylene physiological action is by following component tune by weight percentage
With into solution：
1-methyl cyclopropene 3%, phosphoric acid 3%, hydrochloric acid 0.5%, aminooxoacetic acid 0.01%.
Embodiment 5
The compound formulation of present embodiment regulation and control Plant Ethylene physiological action is by following component tune by weight percentage
With into solution：
1-methyl cyclopropene 3%, phosphoric acid 3%, hydrochloric acid 0.5%, cobalt chloride 0.001%.
Embodiment 6
The compound formulation of present embodiment regulation and control Plant Ethylene physiological action is by following component tune by weight percentage
With into solution：
1-methyl cyclopropene 3%, phosphoric acid 3%, hydrochloric acid 0.5%, silver nitrate 0.001%.
Embodiment 7
The compound formulation of present embodiment regulation and control Plant Ethylene physiological action is by following component tune by weight percentage
With into solution：
1-methyl cyclopropene 3%, phosphoric acid 3%, hydrochloric acid 0.5%, silver thiosulfate 0.001%.
Embodiment 8
The compound formulation of present embodiment regulation and control Plant Ethylene physiological action is by following component tune by weight percentage
With into solution：
1-methyl cyclopropene 3%, phosphoric acid 3%, hydrochloric acid 0.1%, aminoethoxyvinyl glycine 0.01%, silver thiosulfate
0.001%。
Embodiment 9
The compound formulation of present embodiment regulation and control Plant Ethylene physiological action is by following component tune by weight percentage
With into solution：
1-methyl cyclopropene 3%, phosphoric acid 3%, hydrochloric acid 0.5%, aminooxoacetic acid 0.01%, silver nitrate 0.001%.
Embodiment 10
The compound formulation of present embodiment regulation and control Plant Ethylene physiological action is by following component tune by weight percentage
With into solution：
1-methyl cyclopropene 3%, phosphoric acid 3%, hydrochloric acid 0.5%, cobalt chloride 0.001%, silver thiosulfate 0.001%.
Above-described embodiment is that the above of the present invention is described further, but should not be construed as the above-mentioned theme of the present invention
Range is only limitted to above-described embodiment.It is all to be all belonged to the scope of the present invention based on the technical products that the above is realized.
Claims (6)
1. a kind of compound formulation of regulation and control Plant Ethylene physiological action, it is characterised in that its ingredient is by ethylene receptor inhibitor
The solution of 1-methyl cyclopropene and stabilizer phosphoric acid composition.
2. the compound formulation of a kind of regulation and control Plant Ethylene physiological action according to right 1, it is characterised in that can in its ingredient
To add a small amount of stabilizer hydrochloric acid.
3. the compound formulation of a kind of regulation and control Plant Ethylene physiological action according to right 1,2, it is characterised in that in its ingredient
It can add one or more in following Synthesis pathway inhibitor or ethylene physiological action inhibitor：Amino ethoxy second
Alkenyl glycine, aminooxoacetic acid, cobalt chloride, silver nitrate, silver thiosulfate.
4. the compound formulation of a kind of regulation and control Plant Ethylene physiological action according to right 1,2,3, it is characterised in that described
The mass percent of each component in the solution is：
1-methyl cyclopropene 0.01%~6%
Phosphoric acid 0.05%~25%
Hydrochloric acid 0%~5%
Aminoethoxyvinyl glycine 0%~5%
Aminooxoacetic acid 0%~5%
Cobalt chloride 0%~0.5%
Silver nitrate 0%~0.5%
Silver thiosulfate 0%~0.5%.
5. the compound formulation of a kind of regulation and control Plant Ethylene physiological action according to right 1,2,3,4, it is characterised in that described
Each component mass percent in the solution be：
1-methyl cyclopropene 0.02%~4%
Phosphoric acid 0.1%~15%
Hydrochloric acid 0.05%~3%
Aminoethoxyvinyl glycine 0.001%~2%
Aminooxoacetic acid 0.001%~2%
Cobalt chloride 0.0001%~0.1%
Silver nitrate 0.0001%~0.1%
Silver thiosulfate 0.0001%~0.1%.
A kind of 6. compound formulation of regulation and control Plant Ethylene physiological action according to right 1,2,3,4,5, it is characterised in that institute
The mass percent of each component said in the solution is：
1-methyl cyclopropene 0.05%~3%
Phosphatase 11 %~10%
Hydrochloric acid 0.1%~2%
Aminoethoxyvinyl glycine 0.01%~1%
Aminooxoacetic acid 0.01%~1%
Cobalt chloride 0.001%~0.01%
Silver nitrate 0.001%~0.01%
Silver thiosulfate 0.001%~0.01%.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810083814.4A CN108184989A (en) | 2018-01-29 | 2018-01-29 | A kind of compound formulation of regulation and control Plant Ethylene physiological action |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810083814.4A CN108184989A (en) | 2018-01-29 | 2018-01-29 | A kind of compound formulation of regulation and control Plant Ethylene physiological action |
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| Publication Number | Publication Date |
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| CN108184989A true CN108184989A (en) | 2018-06-22 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201810083814.4A Pending CN108184989A (en) | 2018-01-29 | 2018-01-29 | A kind of compound formulation of regulation and control Plant Ethylene physiological action |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111279915A (en) * | 2018-12-07 | 2020-06-16 | 广西作物遗传改良生物技术重点开放实验室 | Method for inducing amphoteric flowers of momordica grosvenori |
| US11248109B2 (en) | 2018-04-27 | 2022-02-15 | Fresh Inset S.A. | Compositions and articles comprising complexes of 1-methylcycloproprene and alpha-cyclodextrin |
| US11730166B2 (en) * | 2020-02-03 | 2023-08-22 | Fresh Inset S.A. | Stable 1-methylcyclopropene compositions and uses thereof |
Citations (2)
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| CN1907046A (en) * | 2006-07-31 | 2007-02-07 | 济南营养源食品科技有限公司 | 1-methyl cyclopropene stable solution, preparation method thereof and preparation |
| CN1927002A (en) * | 2006-07-14 | 2007-03-14 | 赵永东 | Aerosol fresh-keeping agent |
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2018
- 2018-01-29 CN CN201810083814.4A patent/CN108184989A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1927002A (en) * | 2006-07-14 | 2007-03-14 | 赵永东 | Aerosol fresh-keeping agent |
| CN1907046A (en) * | 2006-07-31 | 2007-02-07 | 济南营养源食品科技有限公司 | 1-methyl cyclopropene stable solution, preparation method thereof and preparation |
Non-Patent Citations (4)
| Title |
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| 丁芳林等: "《食品化学(第二版)》", 31 January 2017, 华中科技大学出版社 * |
| 熊兴耀等: "《切花保鲜实用技术》", 31 August 1997, 湖南科学技术出版社 * |
| 胡婉峰等: "《多酚氧化酶导论》", 14 March 2007, 武汉大学出版社 * |
| 赵国防等: "《家庭简易插花》", 31 March 2006, 天津科学技术出版社 * |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US11248109B2 (en) | 2018-04-27 | 2022-02-15 | Fresh Inset S.A. | Compositions and articles comprising complexes of 1-methylcycloproprene and alpha-cyclodextrin |
| CN111279915A (en) * | 2018-12-07 | 2020-06-16 | 广西作物遗传改良生物技术重点开放实验室 | Method for inducing amphoteric flowers of momordica grosvenori |
| CN111279915B (en) * | 2018-12-07 | 2021-09-28 | 广西作物遗传改良生物技术重点开放实验室 | Method for inducing amphoteric flowers of momordica grosvenori |
| US11730166B2 (en) * | 2020-02-03 | 2023-08-22 | Fresh Inset S.A. | Stable 1-methylcyclopropene compositions and uses thereof |
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Application publication date: 20180622 |