CN108183266A - The agent of lead-acid accumulator Regeneration and Repair and method for restoring lead-acid battery - Google Patents
The agent of lead-acid accumulator Regeneration and Repair and method for restoring lead-acid battery Download PDFInfo
- Publication number
- CN108183266A CN108183266A CN201711470894.0A CN201711470894A CN108183266A CN 108183266 A CN108183266 A CN 108183266A CN 201711470894 A CN201711470894 A CN 201711470894A CN 108183266 A CN108183266 A CN 108183266A
- Authority
- CN
- China
- Prior art keywords
- lead
- acid
- repair agent
- acid battery
- battery repair
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/42—Methods or arrangements for servicing or maintenance of secondary cells or secondary half-cells
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/06—Lead-acid accumulators
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
Landscapes
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Secondary Cells (AREA)
- Battery Electrode And Active Subsutance (AREA)
Abstract
It is an object of the present invention to provide a kind of lead-acid battery repair agent and method for restoring lead-acid batteries, to can efficiently solve the technical issues of polar plate sulfation, shedding, argillization etc. are related to lead-acid accumulator aging, wherein, the lead-acid battery repair agent is made after uniformly being mixed by solute and solvent；The component of the solute includes：Silica, anhydrous sodium sulfate, calcium sulfate, stannous sulfate, graphene and sodium phosphate；The solvent is pure water.Method for restoring lead-acid battery includes the following steps：The gasket of lead-acid accumulator to be repaired is dispelled, exposes stomata；Foregoing lead-acid battery repair agent is injected in lead-acid accumulator；By pulse charger to being recharged by the lead-acid accumulator of injection lead-acid battery repair agent and uncharged reparation, the charging time is not less than 48 hours；Lead-acid accumulator and being electrically connected between pulse charger that the charging time meets 48 hours or more are cut off, lead-acid accumulator reparation is completed.
Description
Technical field
The present invention relates to lead-acid accumulator recovery technique field, more particularly, to a kind of lead-acid battery repair agent and lead
Acid accumulator restorative procedure.
Background technology
In the prior art, electric bicycle and electro-tricycle are flooded with each corner in streets and lanes, as above-mentioned
The core energy source of electric vehicle --- the service life of lead-acid batteries is usually 2 to three years, for indivedual moneys
Its service life of the lead-acid batteries of quality defect is even as low as 1 to two year, therefore lead-acid accumulator in the prior art
Service life is far below its 5 to 8 years floating charge projected life.Universally acknowledged global problem --- lead-acid accumulator is " no
Reversible vulcanization " is to result in being greatly lowered for service lifetime of accumulator, and then lead-acid accumulator is caused to scrap in advance.Plumbic acid
Accumulator scraps reason and is presented with the factor of battery inherent quality, the factor for also having battery application method and occasion, but 80%
Above or because lead-acid accumulators itself principle of electrochemical reaction institute extremely.Lead-acid accumulator is that can to carry out charge and discharge reversible
The power supply of reaction, after discharge the substance reaction in storage battery be converted to a kind of crystalline solid for being lead sulfate, sulfuric acid after charging
Lead is converted into lead and sulfuric acid again, so reacts reversible.But when reaction condition is not complete and abundant enough, lead sulfate just can not
It can be converted completely, so that causing the accumulation of lead sulfate, so as to reduce the amount of material for participating in reaction, be reflected in electricity
It is exactly that battery capacity is fewer and fewer in the output in pond, finally loses its basic charging/discharging function as waste.Lead acid storage battery
This phenomenon in pond is referred to as " vulcanizing " (also referred to as aging).Lead-acid accumulator is during charge and discharge are carried out, in electrode
Sulfuric acid leading crystal is gradually generated on plate.This phenomenon results in the aging of battery, shows as：Battery charging and discharging is difficult and electric
Tankage reduces；Lead-acid accumulator under above-mentioned charge and discharge electrical environment, battery fluid are further to the corrosion of electrode plate
Promote, and then constitute electric energy attenuation and dislike cycle, further reduce the service life of battery.
For repairing, the technological means of lead-acid accumulator is mainly based upon high current or pulse current is repaiied in the prior art
It is multiple；A kind of lead-acid accumulator increase-volume exciting agent, capacity increasing system are claimed in the patent application of Publication No. CN104993178A
And its compatibilizing method.Wherein, lead-acid accumulator increase-volume exciting agent is used and is mixed by aerosil, curing agent and deionized water
Close, curing agent include anhydrous sodium sulfate, lithium tetraborate, lauryl sodium sulfate, sodium sulfate of polyethenoxy ether of fatty alcohol,
Dibutyl tin dilaurate, N.N- double hydroxyethyls alkylamide, polyacrylamide, stannous sulfate, Sodium Polyacrylate.Plumbic acid stores
Battery compatibilizing method includes：The electrolyte containing increase-volume exciting agent is injected into written-off lead-acid accumulator, passes through increase-volume system
System acquisition, processing and scaled data, and it is adjusted to rational turbulent condition.Show though the technology can alleviate polar plate sulfation
As making accumulator recovered part capacity and then recycling, but above-mentioned technology repairing effect is unstable, and it is inclined to repair success rate
Low, used turbulent flow still needs to act on battery pole plates, so that sulfation solidfied material comes off, with the art
The high current or pulse current of generally use eliminate polar plate sulfation there is no the difference formed substantially, and to sulfate
Phenomena such as pole plate argillization other than change, repairing effect was not extremely good enough.
Therefore it provides a kind of lead-acid battery repair agent and method for restoring lead-acid battery, to can efficiently solve pole
The technical issues of plate sulfation, shedding, argillization etc. are related to lead-acid accumulator aging just becomes those skilled in the art urgently
Technical problem to be solved.
Invention content
The object of the present invention is to provide a kind of lead-acid battery repair agent and method for restoring lead-acid battery, to can
Efficiently solve the technical issues of polar plate sulfation, shedding, argillization etc. are related to lead-acid accumulator aging.
To achieve these goals, on the one hand, the present invention provides a kind of lead-acid battery repair agent, the lead acid storage battery
Pond renovation agent is made after uniformly being mixed by solute and solvent；The component of the solute includes：Silica, anhydrous sodium sulfate, sulphur
Sour calcium, stannous sulfate, graphene and sodium phosphate；The solvent is pure water.
Preferably, the composition proportion of the lead-acid battery repair agent is as follows by weight：70-80 parts of pure water, dioxy
8-15 parts of SiClx, 4-8 parts of anhydrous sodium sulfate, 1-5 parts of calcium sulfate, 1-3 parts of stannous sulfate, 0.5-1 parts of graphene, sodium sulphate 1-2
Part.
Preferably, the weight of the lead-acid battery repair agent is：Pure water 70-80%, silica 8-
15%th, anhydrous sodium sulfate 4-8%, calcium sulfate 1-5%, stannous sulfate 1-3%, graphene 0.5-1%, sodium sulphate 1-2%.
Preferably, the weight of the lead-acid battery repair agent is：Pure water 73%, silica 1 0%, nothing
Aqueous sodium persulfate 8%, calcium sulfate 5%, stannous sulfate 2%, graphene 0.5%, sodium sulphate 1.5%.
Preferably, the weight of the lead-acid battery repair agent is：Pure water 75%, silica 1 2%, nothing
Aqueous sodium persulfate 6%, calcium sulfate 3%, stannous sulfate 2%, graphene 0.6%, sodium sulphate 1.4%.
Preferably, the weight of the lead-acid battery repair agent is：Pure water 73%, silica 1 4%, nothing
Aqueous sodium persulfate 6%, calcium sulfate 3%, stannous sulfate 2%, graphene 0.75%, sodium sulphate 1.25%.
Preferably, the weight of the lead-acid battery repair agent is：Pure water 78.5%, silica 1 4%,
Anhydrous sodium sulfate 4%, calcium sulfate 1%, stannous sulfate 1%, graphene 0.5%, sodium sulphate 1%.
On the other hand, the present invention also provides a kind of method for restoring lead-acid battery, described method includes following steps：
The gasket of lead-acid accumulator to be repaired is dispelled, exposes stomata；
Foregoing lead-acid battery repair agent is injected in lead-acid accumulator；
By pulse charger to by injection lead-acid battery repair agent and the lead-acid accumulator of uncharged reparation again
Charging, charging time are not less than 48 hours；
Lead-acid accumulator and being electrically connected between pulse charger that the charging time meets 48 hours or more are cut off, plumbic acid stores
Battery reparation is completed.
Preferably, in step：" foregoing lead-acid battery repair agent is injected in lead-acid accumulator；" in, plumbic acid
The injection rate of accumulator renovation agent determines that method includes the following steps：
Obtain the random sample repaired with hospitality in lead-acid accumulator；
The gasket of lead-acid accumulator is dispelled to the lead-acid accumulator random sample of selection, exposes stomata；
Each lead-acid accumulator in the lead-acid accumulator random sample is injected separately into the right of various dose
It is required that the lead-acid battery repair agent described in any one of 1 to 7；
By pulse charger to being recharged by the lead-acid accumulator of injection lead-acid battery repair agent, the charging time
Not less than 48 hours；
The cut-out charging time meets being electrically connected between the lead-acid accumulator test sample of 48 hours or more and pulse charger
It connects；
The repairing effect of the lead-acid accumulator random sample is tested, records and effect is repaired in lead-acid accumulator random sample
The dosage for the lead-acid battery repair agent added in the best lead-acid accumulator of fruit is noted as lead-acid battery repair agent
Enter the standard dosage of amount.
Preferably, in step：" obtain the random sample repaired with hospitality in lead-acid accumulator；" in, sampling ratio 3
~5:100.
It is less than the lead of the standard dosage preferably for lead-acid battery repair agent additive amount in random sample
Acid accumulator, after lead-acid battery repair agent is further added to standard dosage, by pulse charger to being injected
After the lead-acid accumulator of lead-acid battery repair agent was recharged not less than 48 hours, lead-acid accumulator and pulse charge are cut off
Electrical connection between machine, lead-acid accumulator reparation are completed.
The present invention scraps lead-acid accumulator by providing a kind of lead-acid battery repair agent and can efficiently repair；Wherein, with
Discharge time first time repaired qualification determination standard at 100 minutes or more as capacity after reparation, with final cycle charge-discharge
Number repairs qualification determination standard at 150 times or more as cycle life, and capacity of the present invention repairs qualification rate and is up to 70%, cycle
Service life repairs qualification rate and is up to 60%, far above the reparation level of similar recovery technique of the same trade；Using the above-mentioned lead of the present invention
Polar plate sulfation, shedding, argillization etc. and the relevant skill of lead-acid accumulator aging can be efficiently solved after acid accumulator renovation agent
Art problem.
Further, the present invention is by further providing for a kind of method for restoring lead-acid battery, how to use above-mentioned lead
Acid accumulator renovation agent is provided using foundation, and the lead-acid accumulator repaired using the above method of the present invention can be carried substantially
It rises capacity and repairs qualification rate and cycle life reparation qualification rate, for being recycled with important for discarded lead-acid accumulator
Technical meaning.
Further, the injection method for determination of amount of the invention by further providing for lead-acid battery repair agent, subject to
The optimal use dosage for really holding lead-acid battery repair agent provides technical basis.Using the plumbic acid repaired after the above method
Its capacity of accumulator repairs qualification rate and cycle life repairs qualification rate and can obtain further promotion.
Specific embodiment
Embodiment 1：
In the present embodiment, the present invention provides a kind of lead-acid battery repair agent, and the lead-acid battery repair agent is by solute
It is made after uniformly being mixed with solvent；The component of the solute includes：Silica, anhydrous sodium sulfate, calcium sulfate, stannous sulfate,
Graphene and sodium phosphate；The solvent is pure water.
In use, deployed lead-acid battery repair agent is added in lead-acid accumulator to be repaired, open plumbic acid and store
Battery stomata then uses charger to charge using the chemical internal resistance of calculus potential measurement system feedback as according to adjustment in time
Pulse current makes the active ingredient in lead-acid battery repair agent evenly and rapidly be distributed in inside active substance of battery, most
Deeply adhere to form one layer of nano level conductive mesh on polar plate of lead acid storage battery surface afterwards, and then efficiently eliminate pole plate sulfate
The bad phenomenons such as change, shedding, argillization, again restore lead-acid accumulator capacity, and can electric discharge completely after can also be further
It recirculates and utilizes.The above-mentioned lead-acid battery repair agent of the present invention need not disassemble lead-acid accumulator in repair process, after reparation
Effectively recycling often, repair in order when can approach even with the discharge time of new battery and service life phase
Concordantly.It should be noted that the charger for being used to implement and examine charge and discharge effect in the present embodiment is the prior art, therefore its
Relevant technical details are not further illustrated and are repeated herein.
Preferably, in one of optimal technical scheme of the present embodiment, the ingredient of the lead-acid battery repair agent
Proportioning is as follows by weight：70-80 parts of pure water, 8-15 parts of silica, 4-8 parts of anhydrous sodium sulfate, 1-5 parts of calcium sulfate, sulphur
Sour stannous 1-3 parts, 0.5-1 parts of graphene, 1-2 parts of sodium sulphate.
Preferably, in one of optimal technical scheme of the present embodiment, the weight of the lead-acid battery repair agent
Part matches：Pure water 70-80%, silica 8-15%, anhydrous sodium sulfate 4-8%, calcium sulfate 1-5%, stannous sulfate 1-
3%th, graphene 0.5-1%, sodium sulphate 1-2%.
Preferably, in one of optimal technical scheme of the present embodiment, the weight of the lead-acid battery repair agent
Part matches：Pure water 73%, silica 1 0%, anhydrous sodium sulfate 8%, calcium sulfate 5%, stannous sulfate 2%, graphene
0.5%th, sodium sulphate 1.5%.
Preferably, in one of optimal technical scheme of the present embodiment, the weight of the lead-acid battery repair agent
Part matches：Pure water 75%, silica 1 2%, anhydrous sodium sulfate 6%, calcium sulfate 3%, stannous sulfate 2%, graphene
0.6%th, sodium sulphate 1.4%.
Preferably, in one of optimal technical scheme of the present embodiment, the weight of the lead-acid battery repair agent
Part matches：Pure water 73%, silica 1 4%, anhydrous sodium sulfate 6%, calcium sulfate 3%, stannous sulfate 2%, graphene
0.75%th, sodium sulphate 1.25%.
Preferably, in one of optimal technical scheme of the present embodiment, the weight of the lead-acid battery repair agent
Part matches：Pure water 78.5%, silica 1 4%, anhydrous sodium sulfate 4%, calcium sulfate 1%, stannous sulfate 1%, graphite
Alkene 0.5%, sodium sulphate 1%.
The present invention scraps lead-acid accumulator by providing above-mentioned lead-acid battery repair agent and can efficiently repair；Wherein, with
Discharge time first time repaired qualification determination standard at 100 minutes or more as capacity after reparation, with final cycle charge-discharge
Number repairs qualification determination standard at 150 times or more as cycle life, and capacity of the present invention repairs qualification rate and is up to 70%, cycle
Service life repairs qualification rate and is up to 60%, far above the reparation level of similar recovery technique of the same trade；Using the above-mentioned lead of the present invention
Polar plate sulfation, shedding, argillization etc. and the relevant skill of lead-acid accumulator aging can be efficiently solved after acid accumulator renovation agent
Art problem.
Embodiment 2：
The present embodiment furthermore provides a kind of method for restoring lead-acid battery on the basis of above-described embodiment, described
Method includes the following steps：
The gasket of lead-acid accumulator to be repaired is dispelled, exposes stomata；
Foregoing lead-acid battery repair agent is injected in lead-acid accumulator；
By pulse charger to by injection lead-acid battery repair agent and the lead-acid accumulator of uncharged reparation again
Charging, charging time are not less than 48 hours；
Lead-acid accumulator and being electrically connected between pulse charger that the charging time meets 48 hours or more are cut off, plumbic acid stores
Battery reparation is completed.
The present invention is by further providing for a kind of method for restoring lead-acid battery, how to use above-mentioned lead-acid accumulator
Renovation agent is provided using foundation, and the lead-acid accumulator repaired using the above method of the present invention can be substantially improved capacity and repair
Multiple qualification rate and cycle life repair qualification rate, anticipate for discarding being recycled for lead-acid accumulator with important technology
Justice.
Preferably, in one of optimal technical scheme of the present embodiment, in step：" foregoing plumbic acid is stored
In battery renovation agent injection lead-acid accumulator；" in, the injection rate of lead-acid battery repair agent determines that method includes the following steps：
Obtain the random sample repaired with hospitality in lead-acid accumulator；
The gasket of lead-acid accumulator is dispelled to the lead-acid accumulator random sample of selection, exposes stomata；
Each lead-acid accumulator in the lead-acid accumulator random sample, be injected separately into various dose as preceding
The lead-acid battery repair agent；
By pulse charger to being recharged by the lead-acid accumulator of injection lead-acid battery repair agent, the charging time
Not less than 48 hours；
The cut-out charging time meets being electrically connected between the lead-acid accumulator test sample of 48 hours or more and pulse charger
It connects；
The repairing effect of the lead-acid accumulator random sample is tested, records and effect is repaired in lead-acid accumulator random sample
The dosage for the lead-acid battery repair agent added in the best lead-acid accumulator of fruit is noted as lead-acid battery repair agent
Enter the standard dosage of amount.
Further, the injection method for determination of amount of the invention by further providing for lead-acid battery repair agent, subject to
The optimal use dosage for really holding lead-acid battery repair agent provides technical basis.Using the plumbic acid repaired after the above method
Its capacity of accumulator repairs qualification rate and cycle life repairs qualification rate and can obtain further promotion.
Preferably, in one of optimal technical scheme of the present embodiment, lead-acid accumulator in random sample is repaiied
Multiple agent additive amount is less than the lead-acid accumulator of the standard dosage, and lead-acid battery repair agent is further added to mark
It is not low to being recharged by the lead-acid accumulator of injection lead-acid battery repair agent by pulse charger after quasi- dosage
After 48 hours, lead-acid accumulator and being electrically connected between pulse charger are cut off, lead-acid accumulator reparation is completed.
The technique effect that can be obtained further to prove above-mentioned technical proposal of the present invention, spy will use the present invention
The repairing quality of lead-acid accumulator after above-mentioned lead-acid battery repair agent and method for restoring lead-acid battery reparation and existing skill
High current renovation technique, pulse current renovation technique and ultrasonic wave turbulence technique in art make following data comparison, are described in detail such as
Under：
(note：It it is 120 minutes with reference to new discharge time battery first time, the final cycle charge-discharge number that dispatches from the factory is not less than
200 times；Following capacity qualifications are with discharge time first time after repairing at 100 minutes or more for approving standard；Following cycle lives
Repairing qualification refers to final cycle-index at 150 times or more.)
First, high current renovation technique：
12V, 20A type power scrap 10 groups of lead-acid accumulator
Repair result：
Conclusion：Capacity repairs qualification rate 30%, and cycle life repairs qualification rate 0%.
2nd, pulse current renovation technique：
12V, 20A type power scrap 10 groups of lead-acid accumulator
Repair result：
Conclusion：Capacity repairs qualification rate 50%, and cycle life repairs qualification rate 0%.
3rd, ultrasonic wave turbulence technique：
12V, 20A type power scrap 10 groups of lead-acid accumulator
Repair result：
Conclusion：Capacity repairs qualification rate 60%, and cycle life repairs qualification rate 30%.
4th, nano net circulation and regeneration technology：Using lead-acid battery repair agent of the present invention and method for restoring lead-acid battery
It repairs
12V, 20A type power scrap 10 groups of lead-acid accumulator
Repair result：
Conclusion：Capacity repairs qualification rate 70%, and cycle life repairs qualification rate 60%.
5th, four kinds of technology comparisons：
As it can be seen that the above-mentioned lead-acid battery repair agent of the present invention can be repaired efficiently and scrap lead-acid accumulator, and can efficiently solve
The technical issues of certainly polar plate sulfation, shedding, argillization etc. are related to lead-acid accumulator aging.
The various embodiments described above are only the preferred embodiment of the present invention, in the art, every to be based on skill of the present invention
Changes and improvements in art scheme should not be excluded except protection scope of the present invention.
Claims (10)
1. a kind of lead-acid battery repair agent, which is characterized in that the lead-acid battery repair agent is uniformly mixed by solute and solvent
It is made after conjunction；
The component of the solute includes：Silica, anhydrous sodium sulfate, calcium sulfate, stannous sulfate, graphene and sodium phosphate；
The solvent is pure water.
2. lead-acid battery repair agent according to claim 1, which is characterized in that the lead-acid battery repair agent into
Distribution ratio is as follows by weight：70-80 parts of pure water, 8-15 parts of silica, 4-8 parts of anhydrous sodium sulfate, 1-5 parts of calcium sulfate,
1-3 parts of stannous sulfate, 0.5-1 parts of graphene, 1-2 parts of sodium sulphate.
3. lead-acid battery repair agent according to claim 1, which is characterized in that the weight of the lead-acid battery repair agent
Amount part, which matches, is：Pure water 70-80%, silica 8-15%, anhydrous sodium sulfate 4-8%, calcium sulfate 1-5%, stannous sulfate
1-3%, graphene 0.5-1%, sodium sulphate 1-2%.
4. lead-acid battery repair agent according to claim 3, which is characterized in that the weight of the lead-acid battery repair agent
Amount part, which matches, is：Pure water 73%, silica 1 0%, anhydrous sodium sulfate 8%, calcium sulfate 5%, stannous sulfate 2%, graphene
0.5%th, sodium sulphate 1.5%.
5. lead-acid battery repair agent according to claim 3, which is characterized in that the weight of the lead-acid battery repair agent
Amount part, which matches, is：Pure water 75%, silica 1 2%, anhydrous sodium sulfate 6%, calcium sulfate 3%, stannous sulfate 2%, graphene
0.6%th, sodium sulphate 1.4%.
6. lead-acid battery repair agent according to claim 3, which is characterized in that the weight of the lead-acid battery repair agent
Amount part, which matches, is：Pure water 73%, silica 1 4%, anhydrous sodium sulfate 6%, calcium sulfate 3%, stannous sulfate 2%, graphene
0.75%th, sodium sulphate 1.25%.
7. lead-acid battery repair agent according to claim 3, which is characterized in that the weight of the lead-acid battery repair agent
Amount part, which matches, is：Pure water 78.5%, silica 1 4%, anhydrous sodium sulfate 4%, calcium sulfate 1%, stannous sulfate 1%, graphite
Alkene 0.5%, sodium sulphate 1%.
8. a kind of method for restoring lead-acid battery, described method includes following steps：
The gasket of lead-acid accumulator to be repaired is dispelled, exposes stomata；
It will be in the lead-acid battery repair agent injection lead-acid accumulator described in any one of claim 1 to 7；
By pulse charger to being recharged by the lead-acid accumulator of injection lead-acid battery repair agent and uncharged reparation,
Charging time is not less than 48 hours；
Lead-acid accumulator and being electrically connected between pulse charger that the charging time meets 48 hours or more are cut off, lead-acid accumulator is repaiied
It is multiple to complete.
9. according to the method described in claim 8, it is characterized in that, in step：It " will be described in any one of claim 1 to 7
Lead-acid battery repair agent injection lead-acid accumulator in；" in, the injection rate of lead-acid battery repair agent determines that method is included such as
Lower step：
Obtain the random sample repaired with hospitality in lead-acid accumulator；
The gasket of lead-acid accumulator is dispelled to the lead-acid accumulator random sample of selection, exposes stomata；
Each lead-acid accumulator in the lead-acid accumulator random sample is injected separately into the claim 1 of various dose
To the lead-acid battery repair agent described in any one of 7；
By pulse charger to being recharged by the lead-acid accumulator of injection lead-acid battery repair agent, the charging time is not less than
48 hours；
Cut off lead-acid accumulator test sample and being electrically connected between pulse charger that the charging time meets 48 hours or more；
The repairing effect of the lead-acid accumulator random sample is tested, it is best to record repairing effect in lead-acid accumulator random sample
Lead-acid accumulator in add lead-acid battery repair agent dosage, the mark as lead-acid battery repair agent injection rate
Quasi- dosage.
10. according to the method described in claim 9, it is characterized in that, lead-acid battery repair agent in random sample is added
Lead-acid battery repair agent is further added to standard dosage by amount less than the lead-acid accumulator of the standard dosage
Afterwards, by pulse charger to being recharged by the lead-acid accumulator of injection lead-acid battery repair agent not less than 48 hours after,
Lead-acid accumulator and being electrically connected between pulse charger are cut off, lead-acid accumulator reparation is completed.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711470894.0A CN108183266A (en) | 2017-12-29 | 2017-12-29 | The agent of lead-acid accumulator Regeneration and Repair and method for restoring lead-acid battery |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711470894.0A CN108183266A (en) | 2017-12-29 | 2017-12-29 | The agent of lead-acid accumulator Regeneration and Repair and method for restoring lead-acid battery |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN108183266A true CN108183266A (en) | 2018-06-19 |
Family
ID=62548860
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201711470894.0A Pending CN108183266A (en) | 2017-12-29 | 2017-12-29 | The agent of lead-acid accumulator Regeneration and Repair and method for restoring lead-acid battery |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN108183266A (en) |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109037819A (en) * | 2018-07-24 | 2018-12-18 | 湖南欧翔科技有限公司 | A kind of battery refresh liquid, regeneration method and application |
| CN109256594A (en) * | 2018-10-15 | 2019-01-22 | 河南永业环保工程有限公司 | A kind of reparation liquid using storage battery |
| CN111180805A (en) * | 2019-08-07 | 2020-05-19 | 内蒙古华贵科技开发有限公司 | Waste lead-acid storage battery repairing activator and preparation method thereof |
| CN111509309A (en) * | 2019-02-19 | 2020-08-07 | 广州纳为新材料科技有限公司 | Graphene-containing lead-acid battery repairing agent and preparation method thereof |
| CN112259812A (en) * | 2020-12-22 | 2021-01-22 | 河南工学院 | Lead storage battery repairing agent and repairing method |
| CN112928347A (en) * | 2021-01-30 | 2021-06-08 | 靖江市创力智能制造有限公司 | Lead-acid storage battery repairing agent and preparation and use methods thereof |
| CN117276708A (en) * | 2023-11-16 | 2023-12-22 | 北京亿得宝控股集团有限公司 | Repairing agent for lead-acid storage battery and repairing method for lead-acid storage battery |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1102732A (en) * | 1993-11-08 | 1995-05-17 | 赵扬祯 | Accumulator potentiating agent |
| CN101431170A (en) * | 2008-03-12 | 2009-05-13 | 邢纪国 | Lead acid accumulator renovation system and method thereof |
| CN103779621A (en) * | 2014-01-09 | 2014-05-07 | 广州北峻工业材料有限公司 | Service life prolonging liquid of lead-acid storage battery and preparation method thereof |
| CN106450516A (en) * | 2016-08-30 | 2017-02-22 | 江苏海宝电池科技有限公司 | Repair technology of sulfated battery |
| CN106654392A (en) * | 2016-12-06 | 2017-05-10 | 天能集团（河南）能源科技有限公司 | Electrolyte additive of lead-acid storage battery and preparation method for electrolyte additive |
| CN107046152A (en) * | 2016-11-11 | 2017-08-15 | 中广核工程有限公司 | Used in nuclear power station lead-acid accumulator and its positive pole anti-corrosion method |
-
2017
- 2017-12-29 CN CN201711470894.0A patent/CN108183266A/en active Pending
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1102732A (en) * | 1993-11-08 | 1995-05-17 | 赵扬祯 | Accumulator potentiating agent |
| CN101431170A (en) * | 2008-03-12 | 2009-05-13 | 邢纪国 | Lead acid accumulator renovation system and method thereof |
| CN101431170B (en) * | 2008-03-12 | 2012-09-26 | 邢纪国 | Lead acid accumulator renovation system and method thereof |
| CN103779621A (en) * | 2014-01-09 | 2014-05-07 | 广州北峻工业材料有限公司 | Service life prolonging liquid of lead-acid storage battery and preparation method thereof |
| CN106450516A (en) * | 2016-08-30 | 2017-02-22 | 江苏海宝电池科技有限公司 | Repair technology of sulfated battery |
| CN107046152A (en) * | 2016-11-11 | 2017-08-15 | 中广核工程有限公司 | Used in nuclear power station lead-acid accumulator and its positive pole anti-corrosion method |
| CN106654392A (en) * | 2016-12-06 | 2017-05-10 | 天能集团（河南）能源科技有限公司 | Electrolyte additive of lead-acid storage battery and preparation method for electrolyte additive |
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109037819A (en) * | 2018-07-24 | 2018-12-18 | 湖南欧翔科技有限公司 | A kind of battery refresh liquid, regeneration method and application |
| CN109256594A (en) * | 2018-10-15 | 2019-01-22 | 河南永业环保工程有限公司 | A kind of reparation liquid using storage battery |
| CN111509309A (en) * | 2019-02-19 | 2020-08-07 | 广州纳为新材料科技有限公司 | Graphene-containing lead-acid battery repairing agent and preparation method thereof |
| CN111509309B (en) * | 2019-02-19 | 2022-05-17 | 广州纳为新材料科技有限公司 | Graphene-containing lead-acid battery repairing agent and preparation method thereof |
| CN111180805A (en) * | 2019-08-07 | 2020-05-19 | 内蒙古华贵科技开发有限公司 | Waste lead-acid storage battery repairing activator and preparation method thereof |
| CN112259812A (en) * | 2020-12-22 | 2021-01-22 | 河南工学院 | Lead storage battery repairing agent and repairing method |
| CN112928347A (en) * | 2021-01-30 | 2021-06-08 | 靖江市创力智能制造有限公司 | Lead-acid storage battery repairing agent and preparation and use methods thereof |
| CN112928347B (en) * | 2021-01-30 | 2024-05-28 | 上海烯海新能源科技有限公司 | Lead-acid storage battery repairing agent and preparation and use methods thereof |
| CN117276708A (en) * | 2023-11-16 | 2023-12-22 | 北京亿得宝控股集团有限公司 | Repairing agent for lead-acid storage battery and repairing method for lead-acid storage battery |
| CN117276708B (en) * | 2023-11-16 | 2024-02-02 | 北京亿得宝控股集团有限公司 | Repairing agent for lead-acid storage battery and repairing method for lead-acid storage battery |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN108183266A (en) | The agent of lead-acid accumulator Regeneration and Repair and method for restoring lead-acid battery | |
| CN105024103B (en) | The restorative procedure of waste and old lead acid accumulator | |
| RU2437190C2 (en) | Storage battery restoration method and device for its implementation | |
| CN102013534B (en) | Cathode protection-based valve control type lead-acid battery capacity activation solution | |
| CN105870530A (en) | Waste lead storage battery repair and activation method | |
| CN111180805B (en) | Waste lead-acid storage battery repairing activator and preparation method thereof | |
| CN101599559A (en) | Desulphurization recovery technology for battery | |
| CN103311586A (en) | Repairing reducing agent for lead-acid storage batteries | |
| CN104485487B (en) | A kind of battery recovery liquid | |
| CN110021796A (en) | A kind of method that retired battery recycling recycles | |
| CN105470594A (en) | Repairing reducing agent for lead-acid storage battery | |
| CN101834321B (en) | Lead-acid storage battery vulcanization repair process | |
| WO2006057083A1 (en) | Used lead battery regenerating/new lead battery capacity increasing method | |
| CN109860658A (en) | A kind of restoration methods of zinc bromine single flow battery performance | |
| CN101552364A (en) | Electrochemical repairing method of capacity loss of lithium ion secondary battery | |
| CN109164397A (en) | Consider that appraisal procedure is lost in the service life of lithium battery of charge rate and environment temperature | |
| CN104993178A (en) | Lead-acid storage battery capacity-increase exciting agent, capacity-increase system and capacity-increase method thereof | |
| CN104518248A (en) | Nano carbon sol lead-acid storage battery devulcanization repairing liquid | |
| CN110581319A (en) | neutral repair liquid for lead-acid storage battery and preparation process thereof | |
| CN101312262A (en) | Environment-friendly type accumulator rehabilitation liquor manufacture method | |
| CN116960498A (en) | Method for directly repairing waste ternary lithium battery anode material | |
| CN109473732B (en) | A kind of renovation agent of lead-acid accumulator and the restorative procedure of lead-acid accumulator | |
| CN105428730B (en) | A kind of online activation method of lead-acid accumulator | |
| CN107732335A (en) | A kind of restorative procedure of liquid metal cell | |
| CN107123835B (en) | A kind of electrochemical method and system of lead-acid accumulator desulfurization |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20180619 |
|
| RJ01 | Rejection of invention patent application after publication |