CN108178884A - A kind of Flame-retardant environment-friendlymaterial material - Google Patents
A kind of Flame-retardant environment-friendlymaterial material Download PDFInfo
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- CN108178884A CN108178884A CN201711485897.1A CN201711485897A CN108178884A CN 108178884 A CN108178884 A CN 108178884A CN 201711485897 A CN201711485897 A CN 201711485897A CN 108178884 A CN108178884 A CN 108178884A
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- parts
- retardant
- flame
- colorant
- polypropylene
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L25/00—Compositions of, homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Compositions of derivatives of such polymers
- C08L25/02—Homopolymers or copolymers of hydrocarbons
- C08L25/04—Homopolymers or copolymers of styrene
- C08L25/08—Copolymers of styrene
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2207/00—Properties characterising the ingredient of the composition
- C08L2207/04—Thermoplastic elastomer
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Organic Insulating Materials (AREA)
Abstract
The invention discloses a kind of Flame-retardant environment-friendlymaterial materials, are made of thermoplastic styrene class elastomer, polypropylene, polyethylene octene elastomer, composite flame-retardant agent, compound antioxidant and colorant, and mass fraction ratio is：35~45 parts of thermoplastic styrene class elastomer, 5~20 parts of polypropylene, polyethylene octene is 5~10 parts elastic altogether, 0.05~0.15 part of colorant, 17 30 parts of composite flame-retardant agent, 0.8 5 parts of compound antioxidant, 17 parts of toughener, 0 35 parts of glass.Material metal oxide content produced by the invention is few, greatly reduces manufacture cost.The material of the present invention is tested through Chinese household electrical appliance detection institute according to EU criteria IEC60335 1：Fully meet the most harsh 1.5MM thickness of condition, 775 DEG C of glowing filament contact materials do not play open fire in 30 seconds.This undoubtedly substantially increases the material safety of the materials'use.
Description
Technical field
The present invention relates to environment-friendly materials technical field, specially a kind of Flame-retardant environment-friendlymaterial material.
Background technology
At present, one of material of usage amount maximum is polyvinyl chloride (PVC) in electric wire industry, it is a kind of halogen system
Material, chlorinty is up to 50% high molecular material, is also added into that a large amount of other are harmful in electric wire manufacturing process
Modified material, make PVC material not environmentally friendly enough.PVC material can generate halocarbon and other toxic gases (such as two in burning
Evil English) etc..When fire occurs, to the very harmful of human body, and death by suffocation is made one.In terms of the environmental-protecting performance of PVC material.
Insufficient and fire harmfulness, the application to PVC, American-European all states (such as U.S., Germany, Britain, Switzerland) and Japan and other countries
Hold most strong opposition attitude.The legislative bodies and coordination organization of these countries have worked out blue law, limit PVC material
Commercial Application, and the functional material for exploitation environmental protection of trying every possible means replaces PVC as early as possible.
In the prior art, well-known halogen-free low-smoke flame retardant material is using vistanex as base material, fills metallic hydrogen
Oxide does fire proofing, plasticizing forming is mixed together adding some function additives, with the processing of chemically or physically method
Into.Such halogen-free low-smoke flame retardant material is mainly used in various types, cable for various purposes, such as high-low pressure power cable, control
Cable processed, communication cable, cable for ship, vehicular cable, electronic cable etc..When such material be applied to electronic apparatus electric wire,
When low pressure wire rod, there are four aspects are insufficient for material property for electric wire, signal wire, earphone cable, tone frequency channel wire, USB line：It is first, low
The fire-retardant and filling system that cigarette bittern-free flame-proof material uses is metal hydroxide material, and filling content is up to more than 65%, leads
Product wire rod hydraulic performance decline is caused, in subsequently using process, easily occurs scraping the appearances phenomenons such as white scratch；Second is that due to metal
Hydroxide materials flame retarding efficiency is not high, and when application produces some complex structures, electric wire of wall thickness, wire rod is fire-retardant
Test can reach UL1581：The flame retardant rating of VW-1, but keep away thin wire rod at some and can not just pass through UL1581：VW-1's is fire-retardant
Level estimate；Third, a large amount of metal hydroxide materials are filled by such low-smoke halide-free fireproof composite polyolefine material system, hardness is big, shore
A often more than 90, can not meet requirement of the low pressure such as the electric wire and signal wire wire rod to flexibility；Fourth, such low smoke and zero halogen
A large amount of metal hydroxide materials are filled by flame retardant polyolefine material system, and cost is higher, and marketing uses difficult.
Invention content
It is an object of the invention to overcome the deficiencies of the prior art and provide a kind of Flame-retardant environment-friendlymaterial material, the present invention solves
The problem of traditional material cost is higher, and marketing is using difficulty, the material metal oxide content of the application production is few,
Greatly reduce manufacture cost.
The purpose of the present invention is achieved through the following technical solutions：
A kind of Flame-retardant environment-friendlymaterial material, by thermoplastic styrene class elastomer, polypropylene, polyethylene octene elastomer, compound resistance
It fires agent, compound antioxidant and colorant to form, mass fraction ratio is：35~45 parts of thermoplastic styrene class elastomer gathers
5~20 parts of propylene, 5~10 parts of elasticity, 0.05~0.15 part of colorant, compound 17-30 parts of composite flame-retardant agent polyethylene octene altogether
0.8-5 parts of antioxidant, 1-7 parts of toughener, 0-35 parts of glass.
Preferably, in the present invention, retardant synergist, compatilizer and white oil, the retardant synergist 3~10 are further included
Part, 2~10 parts of compatilizer, 10~40 parts of white oil.
Preferably, in the present invention, 40 parts of the thermoplastic styrene class elastomer, 15 parts of polypropylene, polyethylene is pungent
Alkene is 8 parts elastic altogether, 0.08 part of colorant, 20 parts of composite flame-retardant agent, 2 parts of compound antioxidant, 5 parts of toughener, 20 parts of glass.
Preferably, in the present invention, 8 parts of the retardant synergist, 8 parts of compatilizer, 20 parts of white oil.
The beneficial effects of the invention are as follows：Material metal oxide content produced by the invention is few, greatly reduces and is manufactured into
This, material of the invention is tested through Chinese household electrical appliance detection institute according to EU criteria IEC60335-1：Fully meet condition most
1 harsh .5MM thickness, 775 DEG C of glowing filament contact materials do not play open fire in 30 seconds, substantially increase the material of the materials'use
Safety.
Specific embodiment
In order to make the purpose , technical scheme and advantage of the present invention be clearer, below in conjunction with specific embodiment, to this
Invention is further elaborated.It should be appreciated that the specific embodiments described herein are merely illustrative of the present invention, not
For limiting the present invention.
Embodiment 1
A kind of Flame-retardant environment-friendlymaterial material, by thermoplastic styrene class elastomer, polypropylene, polyethylene octene elastomer, compound resistance
It fires agent, compound antioxidant and colorant to form, mass fraction ratio is：35 parts of thermoplastic styrene class elastomer, polypropylene 5
Part, polyethylene octene altogether elasticity 5 parts, 0.05 part of colorant, 17 parts of composite flame-retardant agent, 0.8 part of compound antioxidant, 1 part of toughener,
2 parts of glass.
Further include retardant synergist, compatilizer and white oil, 3 parts of the retardant synergist, 2 parts of compatilizer, 10 parts of white oil.
40 parts of the thermoplastic styrene class elastomer, 15 parts of polypropylene, polyethylene octene are total to 8 parts of elasticity, and 0.08 part of colorant is answered
Close 20 parts of fire retardant, 2 parts of compound antioxidant, 5 parts of toughener, 20 parts of glass.8 parts of the retardant synergist, 8 parts of compatilizer,
20 parts of white oil.
Embodiment 2
A kind of Flame-retardant environment-friendlymaterial material, by thermoplastic styrene class elastomer, polypropylene, polyethylene octene elastomer, compound resistance
It fires agent, compound antioxidant and colorant to form, mass fraction ratio is：40 parts of thermoplastic styrene class elastomer, polypropylene
10 parts, polyethylene octene altogether elasticity 8 parts, 0 .1 parts of colorant, 25 parts of composite flame-retardant agent, 3 parts of compound antioxidant, 5 parts of toughener,
10 parts of glass.
Further include retardant synergist, compatilizer and white oil, 7 parts of the retardant synergist, 7 parts of compatilizer, 20 parts of white oil.
40 parts of the thermoplastic styrene class elastomer, 15 parts of polypropylene, polyethylene octene are total to 8 parts of elasticity, and 0.08 part of colorant is answered
Close 20 parts of fire retardant, 2 parts of compound antioxidant, 5 parts of toughener, 20 parts of glass.8 parts of the retardant synergist, 8 parts of compatilizer,
20 parts of white oil.
Embodiment 3
A kind of Flame-retardant environment-friendlymaterial material, by thermoplastic styrene class elastomer, polypropylene, polyethylene octene elastomer, compound resistance
It fires agent, compound antioxidant and colorant to form, mass fraction ratio is：45 parts of thermoplastic styrene class elastomer, polypropylene
20 parts, polyethylene octene is 10 parts elastic altogether, 0.15 part of colorant, 30 parts of composite flame-retardant agent, 5 parts of compound antioxidant, toughener 7
Part, 35 parts of glass.
Further include retardant synergist, compatilizer and white oil, 10 parts of the retardant synergist, 10 parts of compatilizer, white oil 40
Part.40 parts of the thermoplastic styrene class elastomer, 15 parts of polypropylene, polyethylene octene is 8 parts elastic altogether, colorant 0.08
Part, 20 parts of composite flame-retardant agent, 2 parts of compound antioxidant, 5 parts of toughener, 20 parts of glass.8 parts of the retardant synergist, compatilizer
8 parts, 20 parts of white oil.
Material metal oxide content produced by the invention is few, greatly reduces manufacture cost.In the material warp of the present invention
Household electrical appliance detection institute of state tests according to EU criteria IEC60335-1：Fully meet the most harsh 1.5MM thickness of condition, 775
DEG C glowing filament contact material does not play open fire in 30 seconds.This undoubtedly substantially increases the material safety of the materials'use.
The foregoing is only a preferred embodiment of the present invention, but protection scope of the present invention be not limited thereto,
Any one skilled in the art in the technical scope disclosed by the present invention, according to the technique and scheme of the present invention and its
Inventive concept is subject to equivalent substitution or change, should be covered by the protection scope of the present invention.
Claims (4)
1. a kind of Flame-retardant environment-friendlymaterial material, it is characterised in that：It is total to by thermoplastic styrene class elastomer, polypropylene, polyethylene octene
Elastomer, composite flame-retardant agent, compound antioxidant and colorant are formed, and mass fraction ratio is：Thermoplastic styrene class elasticity
35~45 parts of body, 5~20 parts of polypropylene, polyethylene octene is 5~10 parts elastic altogether, 0.05~0.15 part of colorant, composite flame-proof
17-30 parts of agent, 0.8-5 parts of compound antioxidant, 1-7 parts of toughener, 0-35 parts of glass.
2. a kind of Flame-retardant environment-friendlymaterial material according to claim 1, which is characterized in that further include retardant synergist, compatilizer
And white oil, 3~10 parts of the retardant synergist, 2~10 parts of compatilizer, 10~40 parts of white oil.
A kind of 3. Flame-retardant environment-friendlymaterial material according to claim 1, which is characterized in that the thermoplastic styrene class elasticity
40 parts of body, 15 parts of polypropylene, polyethylene octene is 8 parts elastic altogether, 0.08 part of colorant, 20 parts of composite flame-retardant agent, compound antioxidant 2
Part, 5 parts of toughener, 20 parts of glass.
4. a kind of Flame-retardant environment-friendlymaterial material according to claim 2, which is characterized in that 8 parts of the retardant synergist, it is compatible
8 parts of agent, 20 parts of white oil.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711485897.1A CN108178884A (en) | 2017-12-29 | 2017-12-29 | A kind of Flame-retardant environment-friendlymaterial material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711485897.1A CN108178884A (en) | 2017-12-29 | 2017-12-29 | A kind of Flame-retardant environment-friendlymaterial material |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN108178884A true CN108178884A (en) | 2018-06-19 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201711485897.1A Withdrawn CN108178884A (en) | 2017-12-29 | 2017-12-29 | A kind of Flame-retardant environment-friendlymaterial material |
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Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105440553A (en) * | 2015-12-16 | 2016-03-30 | 无锡吉进环保科技有限公司 | Flame retardant environment-friendly material |
| CN107400301A (en) * | 2017-09-02 | 2017-11-28 | 绵阳凤面科技有限公司 | A kind of Flame-retardant environment-friendlymaterial material |
-
2017
- 2017-12-29 CN CN201711485897.1A patent/CN108178884A/en not_active Withdrawn
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105440553A (en) * | 2015-12-16 | 2016-03-30 | 无锡吉进环保科技有限公司 | Flame retardant environment-friendly material |
| CN107400301A (en) * | 2017-09-02 | 2017-11-28 | 绵阳凤面科技有限公司 | A kind of Flame-retardant environment-friendlymaterial material |
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Application publication date: 20180619 |